WO2004046264A1 - Hybrid protective covers of metal surfaces, especially of water-wall tubes in power boilers - Google Patents

Hybrid protective covers of metal surfaces, especially of water-wall tubes in power boilers Download PDF

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Publication number
WO2004046264A1
WO2004046264A1 PCT/PL2003/000121 PL0300121W WO2004046264A1 WO 2004046264 A1 WO2004046264 A1 WO 2004046264A1 PL 0300121 W PL0300121 W PL 0300121W WO 2004046264 A1 WO2004046264 A1 WO 2004046264A1
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WO
WIPO (PCT)
Prior art keywords
aluminum
agent
water
dichromate
layer
Prior art date
Application number
PCT/PL2003/000121
Other languages
French (fr)
Inventor
Marek Danielewski
Ryszard Gajerski
Aleksander Gil
Andrzej Malecki
Zbigniew Zurek
Original Assignee
Enter-Eko Sp. Z O.O.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enter-Eko Sp. Z O.O. filed Critical Enter-Eko Sp. Z O.O.
Priority to AU2003286982A priority Critical patent/AU2003286982A1/en
Publication of WO2004046264A1 publication Critical patent/WO2004046264A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/74—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C09D5/103—Anti-corrosive paints containing metal dust containing Al
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18—After-treatment
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00—Component parts or details of steam boilers
    • F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10—Water tubes; Accessories therefor
    • F22B37/107—Protection of water tubes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings

Definitions

  • the subject of invention is the hybrid protective cover of metal surfaces, used for climatic protection, protection against high temperature oxidation in exhaust gases, especially used for covering of water-wall tubes in power boilers.
  • the cover may be also used as electrochemical corrosion protection.
  • covers which include anticorrosion agents manufactured on the base of phosphate-chromate glazes, with magnesium as alkalizing metal, where metallic powder is dispersed.
  • anticorrosion agent for obtaining protective covers which is the water solution including phosphate, dichromate, magnesium, chromate and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 ⁇ m, in the quantity up to 1600 g in one decimeter of solution. Proportion of dichromate and phosphate ions is 0,25-0,35.
  • covers which include, as protection agents, dispersions of spherical and/or flakes aluminum, silicon powders and aluminum-sihcon compounds in silicon resins and mixtures of organic solvents.
  • Silicon resins, used as binding material in high temperature protection covers, include methyl and phenyl groups having the general formula: (RlR2SiO)n, where Rl - CH 3 , R2 - H 5 .
  • Hybrid protective cover for metal surfaces, especially for water-wall tubes in power boilers, according to invention which includes anticorrosion agent X, consisting of water solution including phosphate, dichromate, magnesium and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 ⁇ m, in the quantity 1600g for one decimeter of solution, and the proportion of dichromate to phosphate ions is 0,25-0,35, and the protective agent Y, consisting of dispersion of spherical and/or flakes aluminum, silicon powders and duminum-silicon compounds in silicon resins and organic solvents mixtures, characterized in that consists of internal layer, directly adhering to the protected metal surface, including anticorrosion agent, and of external layer, including protection agent.
  • anticorrosion agent X consisting of water solution including phosphate, dichromate, magnesium and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 ⁇ m, in the quantity 1600g for one decimeter of solution, and the proportion
  • the thickness of internal layer is in the range of 15 to 100 ⁇ m, and thickness of external layer is also in range of 15 to 100 ⁇ m. To achieve possibly high surface quality, especially of external layer, it is beneficial to use powders with grain size not bigger than 5 ⁇ m.
  • hybrid cover obtained this way is that it protects metallic surfaces against most of organic compounds as solvents, aldehydes, ketones, derivates of crudesoil, esters and organic acids, ammonia and ammonated salts.
  • This cover is also corrosion protection in oxidizing atmosphere, in temperatures 20 - 600°C, increases resistance to thermal shocks, effectively protects against electrochemical corrosion.
  • Two-layers cover, according to invention is characterized also by perfect inter-layer adherence. The cover has no character of diffusion cover, what means that in high temperatures it does not re-diffuse. The cover has perfect adherence to metallic surfaces.
  • Fig. 1 shows cross section of metallic surface with the protection cover.
  • the hybrid protection cover of metallic surfaces consists of directly adhering to protected metallic surface 1, internal layer A, including anticorrosion agent X, and interconnected outer layer B, including the protection agent Y.
  • the thickness a of outer layer A is in the range of 15 to 100 ⁇ m
  • the thickness b of external layer B is in the range of 15 to 100 ⁇ m.
  • Grain size of internal layer A and/or external layer B is not bigger than 8 ⁇ m.
  • the anticorrosion agent X of internal layer A consists of: 85% H 3 P0 4 in the quantity 339 g, MgC0 3 in the quantity 124 g, Cr0 3 in the quantity 80g, H 2 0 supplementary to 1 dcm 3 , aluminum powder in the quantity of 1150g per one 1 dcm 3 of solution; proportion of dichromate to phosphate ions is 0,33.
  • the anticorrosion agent Y of outer layer B is dispersion of spherical aluminum powders in the quantity 55% by weight in silicon resin (methyl-phenyl polysiloxane) and mixture of organic solvents (xylene, cyclohexanol).
  • the anticorrosion agent X of internal layer A consists of: Mg/H 2 PO- ⁇ /2 " 3H 2 0 in the quantity of 400g, Cr0 3 in the quantity of 90 g, H 0 supplementary to 1 dcm , aluminum powder in the quantity 1150g per 1 dcm 3 of solution; proportion of dichromate to phosphate ions is 0,33.
  • the anticorrosion agent Y of outer layer B is a dispersion of flakes powder aluminum in the quantity of 55% by weight, in the mixture of silicon resin (methyl-phenyl polysiloxane) and mixture of polar solvents (xylen, cyclohexanol).
  • the anticorrosion agent X of internal layer A includes: MgCr 2 07 ⁇ 6H 2 0 in the quantity of 139g, ' 3H 2 0 in the quantity of 292g, 85%H 3 P0 4 in the quantity of 91,5g, H 2 0 supplementary to 1 dcm 3 , aluminum powder in the quantity of 1150g per 1 dcm 3 of solution; proportion of dichromate to phosphate ions is 0,33.
  • the anticorrosion agent Y of outer layer B is a dispersion of spherical uminum powder and aluminum-silicon compounds in the quantity of 55% by weight in silicon resin (methyl-phenyl polysiloxane) and mixture organic solvents (xylen, cyclohexanol).
  • the anticorrosion agent X of internal layer A includes: MgCr 2 0 7 • 6H 2 0 in the quantity of 120g, MgO in the quantity of 43g, 85%H 3 P0 4 in the quantity of 339g, H 2 0 supplementary to 1 dcm 3 , proportion of dichromate to phosphate ions is 0,27.
  • the anticorrosion agent Y of outer layer B is a dispersion of flakes aluminum powder in the quantity of 55% by weight in mixture of silicon resin (methyl- phenyl polysiloxane) and mixture of polar solvents (xylen, cyclohexanol).

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

Hybrid protective cover of metallic surfaces, especially of water-wall tubes of power boilers, which includes the anticorrosive agent X, which is a water solu­tion, including phosphate, dichromate, magnesium, chromium and aluminum ions and spherical aluminum powder with oxidized surface, with grain size below 8 µm in the concentration of up to 1600 g per decimeter of solution., and where the pro­portion of dichromate to phosphate ions is 0,25-0,35, and the protective agent Y, which consists of dispersions of spherical and/or flakes powders of aluminum, sili­con and aluminum-silicon compounds in silicon resins and mixtures of organic solvents, characterized in that it comprises internal layer (A), directly adhering to protected metallic surface (1), containing the anticorrosion agent (X), and inter­connected outer layer (B), containing the protective agent (Y).

Description

Hybrid protective covers of metal surfaces, especially of water-wall tubes in power boilers
The subject of invention is the hybrid protective cover of metal surfaces, used for climatic protection, protection against high temperature oxidation in exhaust gases, especially used for covering of water-wall tubes in power boilers. The cover may be also used as electrochemical corrosion protection.
There are known covers, which include anticorrosion agents manufactured on the base of phosphate-chromate glazes, with magnesium as alkalizing metal, where metallic powder is dispersed.
There is known, from the Polish patent description No 136 843, anticorrosion agent for obtaining protective covers, which is the water solution including phosphate, dichromate, magnesium, chromate and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 μm, in the quantity up to 1600 g in one decimeter of solution. Proportion of dichromate and phosphate ions is 0,25-0,35.
There are also known covers, which include, as protection agents, dispersions of spherical and/or flakes aluminum, silicon powders and aluminum-sihcon compounds in silicon resins and mixtures of organic solvents. Silicon resins, used as binding material in high temperature protection covers, include methyl and phenyl groups having the general formula: (RlR2SiO)n, where Rl - CH3, R2 - H5.
There is known, from the Polish patent description No P279617, method for protection of internal boiler surfaces against the corrosive and erosive environment influence, where the first layer in protection cover is aluminum and the second and next layers are obtained through mixing the water-glass, having the silicate modulus over 3,6, with metallic fluid, where the grain size is below 8 μm, and the proportion is 1 kg of metallic powder for 0,4 - 0,5 1 of water-glass.
Hybrid protective cover for metal surfaces, especially for water-wall tubes in power boilers, according to invention, which includes anticorrosion agent X, consisting of water solution including phosphate, dichromate, magnesium and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 μm, in the quantity 1600g for one decimeter of solution, and the proportion of dichromate to phosphate ions is 0,25-0,35, and the protective agent Y, consisting of dispersion of spherical and/or flakes aluminum, silicon powders and duminum-silicon compounds in silicon resins and organic solvents mixtures, characterized in that consists of internal layer, directly adhering to the protected metal surface, including anticorrosion agent, and of external layer, including protection agent. The thickness of internal layer is in the range of 15 to 100 μm, and thickness of external layer is also in range of 15 to 100 μm. To achieve possibly high surface quality, especially of external layer, it is beneficial to use powders with grain size not bigger than 5 μm.
The advantage of hybrid cover obtained this way, according to invention, is that it protects metallic surfaces against most of organic compounds as solvents, aldehydes, ketones, derivates of crudesoil, esters and organic acids, ammonia and ammonated salts. This cover is also corrosion protection in oxidizing atmosphere, in temperatures 20 - 600°C, increases resistance to thermal shocks, effectively protects against electrochemical corrosion. Two-layers cover, according to invention, is characterized also by perfect inter-layer adherence. The cover has no character of diffusion cover, what means that in high temperatures it does not re-diffuse. The cover has perfect adherence to metallic surfaces.
The invention is presented in general execution example on the drawing, where Fig. 1 shows cross section of metallic surface with the protection cover.
The hybrid protection cover of metallic surfaces consists of directly adhering to protected metallic surface 1, internal layer A, including anticorrosion agent X, and interconnected outer layer B, including the protection agent Y. The thickness a of outer layer A is in the range of 15 to 100 μm, and the thickness b of external layer B is in the range of 15 to 100 μm. Grain size of internal layer A and/or external layer B is not bigger than 8 μm. hi the first execution example, the anticorrosion agent X of internal layer A consists of: 85% H3P04 in the quantity 339 g, MgC03 in the quantity 124 g, Cr03 in the quantity 80g, H20 supplementary to 1 dcm3, aluminum powder in the quantity of 1150g per one 1 dcm3 of solution; proportion of dichromate to phosphate ions is 0,33.
The anticorrosion agent Y of outer layer B, is dispersion of spherical aluminum powders in the quantity 55% by weight in silicon resin (methyl-phenyl polysiloxane) and mixture of organic solvents (xylene, cyclohexanol). i the second execution example, the anticorrosion agent X of internal layer A consists of: Mg/H2PO-ι/2 " 3H20 in the quantity of 400g, Cr03 in the quantity of 90 g, H 0 supplementary to 1 dcm , aluminum powder in the quantity 1150g per 1 dcm3 of solution; proportion of dichromate to phosphate ions is 0,33.
The anticorrosion agent Y of outer layer B, is a dispersion of flakes powder aluminum in the quantity of 55% by weight, in the mixture of silicon resin (methyl-phenyl polysiloxane) and mixture of polar solvents (xylen, cyclohexanol).
In the third execution example, the anticorrosion agent X of internal layer A, includes: MgCr207 ■ 6H20 in the quantity of 139g,
Figure imgf000005_0001
' 3H20 in the quantity of 292g, 85%H3P04 in the quantity of 91,5g, H20 supplementary to 1 dcm3, aluminum powder in the quantity of 1150g per 1 dcm3 of solution; proportion of dichromate to phosphate ions is 0,33.
The anticorrosion agent Y of outer layer B, is a dispersion of spherical uminum powder and aluminum-silicon compounds in the quantity of 55% by weight in silicon resin (methyl-phenyl polysiloxane) and mixture organic solvents (xylen, cyclohexanol). i the fourth execution example, the anticorrosion agent X of internal layer A, includes: MgCr207 • 6H20 in the quantity of 120g, MgO in the quantity of 43g, 85%H3P04 in the quantity of 339g, H20 supplementary to 1 dcm3, proportion of dichromate to phosphate ions is 0,27.
The anticorrosion agent Y of outer layer B, is a dispersion of flakes aluminum powder in the quantity of 55% by weight in mixture of silicon resin (methyl- phenyl polysiloxane) and mixture of polar solvents (xylen, cyclohexanol).

Claims

Claims
1. Hybrid protection cover for metallic surfaces, especially water-wall tubes of power boilers, which includes the anticorrosion agent X, which is a water solution with phosphate, dichromate, magnesium, chromium and aluminum ions and spherical aluminum powder, with oxidized surface and grain size below 8 μm in the quantity up to 1600 g per one dcm3 of solution, and proportion of dichromate to phosphate ions is 0,25-0,35 and the protective agent Y, which is a dispersion of spherical and/or flakes aluminum, silicon powders and alunrinum- silicon compounds in silicon resins and mixtures of organic solvents, characterized in that it consists of internal layer (A) adhering directly to protected metallic surface (1), of outer layer (A), which includes the anticorrosion agent (X), and of interconnected outer layer (B), which includes the protective agent (Y).
2. The hybrid protective layer, according to claim 1, characterized in that thickness (a) of internal layer (A) is in the range of 15 to 100 μm, whereas thickness (b) of outer layer (B) is in the range 15 to 100 μm.
3. Hybrid protective layer, according to claim 1, characterized in that grain diameter of internal layer (A) powder and/or outer layer (B) is lesser or equal to 8 μm.
PCT/PL2003/000121 2002-11-15 2003-11-14 Hybrid protective covers of metal surfaces, especially of water-wall tubes in power boilers WO2004046264A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003286982A AU2003286982A1 (en) 2002-11-15 2003-11-14 Hybrid protective covers of metal surfaces, especially of water-wall tubes in power boilers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL357145A PL202259B1 (en) 2002-11-15 2002-11-15 Hybrid protective coating for metallic surfaces, particularly water wall tubes in power boilers
PLP-357145 2002-11-15

Publications (1)

Publication Number Publication Date
WO2004046264A1 true WO2004046264A1 (en) 2004-06-03

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010043708A1 (en) * 2008-10-16 2010-04-22 Ewald Dörken Ag Method for electrochemically protecting a metal surface from corrosion
EP2428730A1 (en) * 2010-09-09 2012-03-14 Siemens Aktiengesellschaft Method for producing condenser or heat exchanger tubes
WO2024172796A1 (en) * 2023-02-14 2024-08-22 Uysal Makina Sanayi Ithalat Ihracat Ve Ticaret Anonim Sirketi A coating with high anti-corrosive effectiveness and a method for coating said coating on substrates

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248251A (en) * 1963-06-28 1966-04-26 Teleflex Inc Inorganic coating and bonding composition
PL136843B1 (en) * 1982-11-12 1986-03-31 Akad Gorniczo Hutnicza Corrosion preventing agaent
US5116672A (en) * 1990-02-05 1992-05-26 Sermatech International, Inc. Organic coatings with ion reactive pigments especially for active metals
PL160625B1 (en) * 1989-05-23 1993-04-30 Gorniczo Hutniczy Miedzi Method of protecting internal surfaces of a recuperative boiler against corrosive and erosive effects of its environment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248251A (en) * 1963-06-28 1966-04-26 Teleflex Inc Inorganic coating and bonding composition
PL136843B1 (en) * 1982-11-12 1986-03-31 Akad Gorniczo Hutnicza Corrosion preventing agaent
PL160625B1 (en) * 1989-05-23 1993-04-30 Gorniczo Hutniczy Miedzi Method of protecting internal surfaces of a recuperative boiler against corrosive and erosive effects of its environment
US5116672A (en) * 1990-02-05 1992-05-26 Sermatech International, Inc. Organic coatings with ion reactive pigments especially for active metals

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010043708A1 (en) * 2008-10-16 2010-04-22 Ewald Dörken Ag Method for electrochemically protecting a metal surface from corrosion
EP2428730A1 (en) * 2010-09-09 2012-03-14 Siemens Aktiengesellschaft Method for producing condenser or heat exchanger tubes
EP2428729A1 (en) * 2010-09-09 2012-03-14 Siemens Aktiengesellschaft Method for producing condenser or heat exchanger tubes
WO2024172796A1 (en) * 2023-02-14 2024-08-22 Uysal Makina Sanayi Ithalat Ihracat Ve Ticaret Anonim Sirketi A coating with high anti-corrosive effectiveness and a method for coating said coating on substrates

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PL357145A1 (en) 2004-05-17
PL202259B1 (en) 2009-06-30

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