WO2004031459A1 - Method for producing highly stable polypropylene fibres - Google Patents
Method for producing highly stable polypropylene fibres Download PDFInfo
- Publication number
- WO2004031459A1 WO2004031459A1 PCT/EP2003/010453 EP0310453W WO2004031459A1 WO 2004031459 A1 WO2004031459 A1 WO 2004031459A1 EP 0310453 W EP0310453 W EP 0310453W WO 2004031459 A1 WO2004031459 A1 WO 2004031459A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fiber strands
- drafting
- stretching
- stage
- rollers
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D13/00—Complete machines for producing artificial threads
Definitions
- the invention relates to a process for producing high-strength polypropylene fibers with high strength and low elongation by continuous shrink spinning, drawing off, stretching and cutting fiber strands to form the polypropylene fibers.
- the fiber strands are passed directly into a water bath after spinning for the purpose of cooling and then drawn in a drawing zone with a high drawing ratio of up to 10: 1.
- the relatively rapid cooling of the fiber strands in the water bath results in a relatively high degree of preorientation in the edge region of the individual fibers, with the result that they are difficult to stretch.
- the known method is also only suitable for relatively coarse fibers with a single titer in the range of greater than 3 dtex. manufacture. The higher friction effect on the individual filaments caused by the water bath alone does not allow the spinning of fibers with finer titers.
- a polypropylene fiber is known from EP 0 535 373 A1, which shows a necessary fineness with high strength, but can only be produced in a complex two-stage process.
- the fiber is temporarily stored after spinning and drawing, with additional treatment by impregnation.
- the fiber strands are then taken up again in a second stage, dried and cut.
- Another object of the invention is to provide an apparatus for performing the method.
- the invention is characterized in that, on the one hand, the low melt temperature during spinning in conjunction with a slow take-off speed favors a partial molecular orientation of the undrawn fibers and therefore a higher strength of the fiber is established. Due to the slow withdrawal speeds, significantly lower internal tensions between the polymer chains in the filaments occur during the Cooling process after spinning.
- the subsequent drawing in three successive drawing stages taking into account that 70% of the total drawing is already introduced into the fiber in the first drawing step, enables a steady slow polymer crystallization to be produced in the fibers, so that in addition to the high strength, a low residual elongation and a corresponding one Fineness in the fibers.
- the partial stretching of the fiber strands is carried out higher in the second stretching stage than in the subsequent third stretching stage.
- the total drawing takes place in the drawing stages with a decreasing drawing ratio.
- the fiber strands are drawn off after the melt spinning by a first drawing device with several drawing rollers, the jacket surfaces of which are cooled.
- the fiber strands are then passed through a hot stretching channel within the first plug-in stage and heated to a temperature of above 100 ° C. for stretching.
- the fiber strands are continuously heated to a temperature of> 100.degree. C. after passing through the first drawing stage until they enter the third drawing stage by guiding them over several heated drawing rollers.
- the drafting rollers of the drafting units forming the second drafting stage are preferably heated.
- a further heat treatment of the fiber strands can be carried out through a further hot stretching channel within the second stretching stage.
- the fiber strands can be heated both by hot air or by superheated steam within the hot stretching channels. It has been found to be particularly advantageous that the fiber strands in the first Stretching zone with hot air and in the second stretching zone with a superheated steam.
- the fiber strands are preferably cooled by guiding them over several cooled drawing rolls on a fourth drawing device at the end of the third drawing step.
- a further process variant is given in that the fiber strands are crimped after stretching and before cutting.
- the fiber strands are preferably extruded through an annular or rectangular spinneret with a large number of approximately 60,000 to 120,000 nozzle bores.
- the device according to the invention for carrying out the method according to the invention is characterized by the formation and division of the drawing stages, so that polypropylene fibers with a high strength of more than 6 cN / dtex. at low elongation of below 40%, preferably below 20%, can be produced with the appropriate fineness in the individual titers.
- the drafting rollers of the middle drafting systems are preferably designed to be heatable in order to obtain a uniform and continuous temperature control of the fiber strands during drawing.
- the drafting devices at the inlet and at the outlet of the overall drawing zone are preferably designed with cooled drawing rolls.
- FIG. 1 shows schematically a first embodiment of an apparatus according to the invention for performing the method according to the invention
- Fig. 2 schematically shows another embodiment of the device according to the invention
- a first exemplary embodiment of a device according to the invention for the one-step production of polypropylene fibers is shown schematically.
- Such devices are generally known in the art as compact spinning systems for the production of staple fibers, preferably made of polypropylene.
- the compact systems are spinning speeds in the range of max. 250 m min. operated. This means that very high production capacities of up to 501 per day can be achieved.
- the device according to the invention corresponds to such compact systems and for this purpose has a spinning device 1 with a plurality of spinning stations 2.1, 2.2 and 2.3 arranged next to one another.
- the number of spinning positions of the exemplary embodiment shown in FIG. 1 is exemplary.
- Each of the spinning stations 2.1 to 2.3 is constructed identically, so that this is explained in more detail using the spinning station 2.1.
- a preferably ring-shaped spinneret 3 which has a large number of nozzle bores on its underside. For example, up to 120,000 nozzle bores can be arranged in an annular or rectangular arrangement in the spinneret 3.
- the spinneret 3 is connected to a melt source (not shown here) which supplies the spinneret 3 with a melt stream under pressure.
- a melt source not shown here
- extruders, pumps or combinations of both are suitable as melt sources in order to supply a melt stream to the spinneret 3.
- the spinnerets 3 of the spinning stations 2.1, 2.2 and 2.3 are arranged in a heated spinning beam 15.
- Cooling device 4 arranged below the spinning beam 15 is in the spinning station 2.1 essentially centrally to the spinneret 3 Cooling device 4 arranged.
- the cooling device 4 is designed as a blower in which a cooling air flow is generated from an annular blowing nozzle, so that the cooling air penetrates the annular veil formed by the fiber strands from the inside to the outside and leads to cooling of the fiber strands.
- the cooling air is fed to the cooling device 4 from above through the spinning beam 15.
- the treatment device 1 is followed by a plurality of treatment devices.
- a take-off device 6 is assigned directly to the spinning device 1.
- the take-off device 6 contains devices for preparing and guiding the fiber strands 5 per spinning station. For example, during the preparation, a preparation agent can be applied to the fiber strands by rolling.
- the take-off device 6 is arranged below the spinning device 1.
- the plurality of fiber strands 5, which are also referred to as tow or spinning bucket, are drawn off by a first drafting system 7.1.
- the drafting system 7.1 is arranged directly next to the trigger device 6.
- the drafting system 7.1 is followed by a total of three further drafting systems 7.2, 7.3 and 7.4.
- a drafting stage is formed between the drafting systems 7.1, 7.2, 7.3 and 7.4.
- a first drafting stage 9.1 is thus formed between the first drafting system 7.1 and the second drafting system 7.2.
- a second drafting stage 9.2 is formed between the drafting systems 7.2 and 7.3 and the third drafting stage 9.3 between the drafting systems 7.3 and 7.4.
- Each of the drafting systems 7.1 to 7.4 each has a plurality of drafting rollers 8 which guide the fiber strands 5 with a single loop.
- the drafting rollers 8 of the drafting systems 7.1 to 7.4 are driven, the drafting rollers 8 of the drafting systems 7.1 to 7.4 in Depending on the desired stretching ratio can be operated at different peripheral speeds.
- the drawing rollers 8 of the drafting devices 7.1 to 7.4 can have a cooled roller jacket or a heated roller jacket, depending on the requirements.
- a hot drawing duct 10 is provided for the thermal treatment of the fiber strands between the first drafting device 7.1 and the second drawing device 7.2 in the first drawing stage 9.1.
- the fiber strands 5 can be tempered to a predetermined temperature by means of hot air or by means of a superheated steam.
- a further hot stretching duct 10 is likewise arranged between the drafting units 7.2 and 7.3.
- a tension control device 11 and a cutting device 12 are provided in order to continuously cut the fiber strands into staple fibers with a predetermined fiber length.
- a polymer melt made of polypropylene is first extruded in the spinning device 1 via the spinnerets 3 of the spinning stations 2.1 to 2.3 under pressure to form a large number of fiber strands.
- the fiber strands 5 emerging from the spinnerets 2 are pulled by the spinnerets 3 via the draw-off device 6 through the drafting system 7.1 at a take-off speed of less than 100 m / min. preferably with a take-off speed below 50 m / min. deducted.
- the fiber strands 5 are cooled by means of the cooling device 4 by means of a foggy or gaseous cooling medium stream, preferably made of air, then prepared and brought together to form a tow containing all the fiber strands when they leave the extraction device 6.
- the drafting rollers 8 of the first drafting system 7.1 are driven at the take-off speed, with a further cooling of the fiber strands taking place at the circumference of the drafting rollers 8 of the first drafting system 7.1.
- the drafting rollers 8 of the first drafting system 7.1 are formed with cooled jacket surfaces.
- the fiber strands 5 are stretched in a total of three stretching stages 9.1, 9.2 and 9.3, each with different stretching ratios.
- the total draw ratio is above 4: 1. This involves stretching the fiber strands. executed in the stages with different intensities.
- the fiber strands are stretched in the first stretching stage 9.1 with a partial stretching, which makes up at least 70% of the total stretching.
- the fiber strands 5 in the hot drawing duct 10 are preferably heated to a temperature of> 100 ° C. by hot air and then passed over the drawing rollers 8 of the second drawing device 7.2, which are also heated to a temperature of over 100 ° C.
- the second partial drawing of the fiber strands 5 takes place in the second drawing stage 9.2, whereby treatment in a hot drawing duct 10 is also provided.
- the fiber strands are further partially drawn by the third drafting system 7.2, the partial drawing in the second drawing stage 9.2 being higher than the last partial drawing in the third drawing stage 9.3.
- the rollers 8 of the third drafting device 7.3 are also heated to a surface temperature of> 100 ° C. in order to obtain a uniform, continuous drawing.
- the fiber strands 5 are cooled by the cooled drawing rolls 8, the fourth drawing device 7.4 and then cut evenly into fibers of the specified fiber length.
- fibers with a fiber length of 6.6 mm, alternatively 13 mm could be produced in several test series, which had a single titer in the range from 0.9 to 1.6 dtex., A strength in the range from 8 to 9 cN / dtex. and showed an elongation in the range of 18 to 21%.
- the melt temperature during the spinning of the fiber strands was set to a value ⁇ 250 ° C.
- the nozzle plate had one circular arrangement of the nozzle bores with a number of several 10,000 nozzle bores.
- the rollers of the first drafting system 7.1 were at a take-off speed in the range from 25 to 40 / min., The drafting rollers of the second drafting system 7.2 at a speed in the range of 80 to 115 m / min., The drafting rollers of the third drafting system 7.3 at a speed in Range from 100 to 140 m / min. and the drafting rollers of the fourth drafting system 7.4 at a speed of 110 to 160 m / min. driven.
- the surface temperatures of the drafting rollers 8 were approximately 30 ° C. for the first drafting system 7.1,> 100 ° C. for the second drafting system 7.2, also> 100 ° C. for the third drafting system 7.3 and approximately 30 ° C.
- the temperature of the fiber strands was carried out in the first stretching stage through the hot stretching duct 10 using hot air which has a temperature of above 100 ° C.
- the fiber strands were treated with superheated steam at a temperature ⁇ 100 ° C.
- the partial stretchings achieved in this way for the production of the fibers mentioned were in the range from 2.8 to 3.2: 1 in the first stretching stage 9.1, in the range from 1.05 to 1.5: 1 in the second stretching stage 9.2 and in the range 1, 05 to 1.3: 1 in the third stretch 9.3.
- This slow and steady crystallization has the consequence that a high strength with low residual elongation is achieved.
- the multi-stage stretching enables a particularly fine fiber with individual titers below 2 dtex. produce.
- FIG. 2 A further exemplary embodiment of a device according to the invention for carrying out the method according to the invention is shown schematically in FIG.
- the Spinning device 1 and the Ab ⁇ igs worn 6 are identical to the previous exemplary embodiment, so that reference is made to the preceding description.
- Crimping device 13 a drying device 14, and the tension control device
- the drafting systems 7.1 to 7.4 are essentially identical to the previous exemplary embodiment, only the number of drafting rollers 8 used per drafting system is different.
- the fiber strands 5 are crimped after being stretched by the crimping device 13.
- the crimping device 13 is usually designed as a stowage chamber crimping device in which the fiber strands are pressed into a stuffer box by a conveying means.
- the fiber strands of the drying device 14 are guided and then fed in by the tension adjusting device 11 with a defined tension of the cutting device 12.
- a cable junction and a damping channel (both not shown) are usually connected upstream of the crimping device.
- the structure of the exemplary embodiments according to FIGS. 1 and 2 for the device according to the invention are exemplary in the number and the choice of treatment devices. In principle, there is the possibility of introducing additional treatments and treatment stages, for example by means of a cable junction to set a fiber assignment that is suitable for the crimp. Likewise, more than three stretching stages can be formed one after the other.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE50312095T DE50312095D1 (en) | 2002-09-26 | 2003-09-19 | METHOD FOR THE PRODUCTION OF HIGH-STRENGTH POLYPROPYLENE FIBERS |
BR0314746-0A BR0314746A (en) | 2002-09-26 | 2003-09-19 | Highly resistant polypropylene fiber production process |
AU2003273907A AU2003273907A1 (en) | 2002-09-26 | 2003-09-19 | Method for producing highly stable polypropylene fibres |
EP03757872A EP1543184B1 (en) | 2002-09-26 | 2003-09-19 | Method for producing highly stable polypropylene fibres |
US11/070,557 US7585445B2 (en) | 2002-09-26 | 2005-03-02 | Method for producing high tenacity polypropylene fibers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10244830.2 | 2002-09-26 | ||
DE10244830 | 2002-09-26 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/070,557 Continuation US7585445B2 (en) | 2002-09-26 | 2005-03-02 | Method for producing high tenacity polypropylene fibers |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004031459A1 true WO2004031459A1 (en) | 2004-04-15 |
Family
ID=32049164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/010453 WO2004031459A1 (en) | 2002-09-26 | 2003-09-19 | Method for producing highly stable polypropylene fibres |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1543184B1 (en) |
KR (1) | KR20050061480A (en) |
CN (1) | CN1328423C (en) |
AU (1) | AU2003273907A1 (en) |
BR (1) | BR0314746A (en) |
DE (1) | DE50312095D1 (en) |
RU (1) | RU2318085C2 (en) |
WO (1) | WO2004031459A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016003796A1 (en) | 2015-05-06 | 2016-11-10 | Oerlikon Textile Gmbh & Co. Kg | Method and apparatus for hiding a plurality of melt-spun fiber strands |
CN109591330A (en) * | 2019-01-18 | 2019-04-09 | 无锡盛烨特邦新材料科技有限公司 | It is a kind of exempt from glue fiber bar production line exempt from glue fiber bar heat setting machine |
EP3540107A4 (en) * | 2016-11-08 | 2020-08-05 | Braskem S.A. | Method and equipment for producing a polypropylene thread |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100347354C (en) * | 2006-04-17 | 2007-11-07 | 东华大学 | Device for preparing polypropylene fiber |
CN102453986B (en) * | 2010-10-21 | 2013-12-04 | 盟鑫工业股份有限公司 | Drawing and twisting equipment |
US9057148B2 (en) * | 2011-05-30 | 2015-06-16 | Toyota Jidosha Kabushiki Kaisha | High-strength polypropylene fiber and method for producing the same |
KR101335659B1 (en) * | 2012-02-08 | 2013-12-03 | 건국대학교 산학협력단 | Method for manufacturing structural reinforcing polymer fiber |
ITMI20130821A1 (en) * | 2013-05-21 | 2013-08-20 | M A E S P A | EQUIPMENT FOR IRONING FIBERS OF ACRYLICS IN A PRESSURE STEAM ATMOSPHERE AND AN AUTOMATIC ENTRY DEVICE FOR SUCH EQUIPMENT. |
CN108570721A (en) * | 2018-06-25 | 2018-09-25 | 张家港市金星纺织有限公司 | A kind of preparation facilities of polypropylene fibre |
CN109295513A (en) * | 2018-12-17 | 2019-02-01 | 广东蒙泰高新纤维股份有限公司 | A kind of method that melt-spun-wet spinning technology prepares super High-strength low-shrinkage polypropylene filament yarn |
CN112853624B (en) * | 2020-12-30 | 2022-12-06 | 天鼎丰聚丙烯材料技术有限公司 | Special polypropylene filament needle-punched drainage geotextile for tunnel, preparation method and preparation system |
CN113774505B (en) * | 2021-09-14 | 2023-08-01 | 徐工集团工程机械股份有限公司 | Polypropylene fiber, preparation method and sweeping brush |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5846654A (en) * | 1995-06-02 | 1998-12-08 | Hercules Incorporated | High tenacity, high elongation polypropylene fibers, their manufacture, and use |
DE19860335A1 (en) * | 1997-12-25 | 1999-07-01 | Chisso Corp | Fiber for reinforcing concrete |
-
2003
- 2003-09-19 BR BR0314746-0A patent/BR0314746A/en not_active IP Right Cessation
- 2003-09-19 EP EP03757872A patent/EP1543184B1/en not_active Expired - Fee Related
- 2003-09-19 AU AU2003273907A patent/AU2003273907A1/en not_active Abandoned
- 2003-09-19 CN CNB038230348A patent/CN1328423C/en not_active Expired - Fee Related
- 2003-09-19 DE DE50312095T patent/DE50312095D1/en not_active Expired - Lifetime
- 2003-09-19 WO PCT/EP2003/010453 patent/WO2004031459A1/en not_active Application Discontinuation
- 2003-09-19 KR KR1020057005042A patent/KR20050061480A/en not_active Application Discontinuation
- 2003-09-19 RU RU2005112708/04A patent/RU2318085C2/en not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5846654A (en) * | 1995-06-02 | 1998-12-08 | Hercules Incorporated | High tenacity, high elongation polypropylene fibers, their manufacture, and use |
DE19860335A1 (en) * | 1997-12-25 | 1999-07-01 | Chisso Corp | Fiber for reinforcing concrete |
Non-Patent Citations (1)
Title |
---|
WIEDERMANN R: "CONTINUOUS SPIN-DRAW-TEXTURIZING. \ SPUN DYED BCF YARN AND STAPLE FIBER", INTERNATIONAL FIBER JOURNAL, MCMICKLE PUBLICAIONS, ATLANTA, US, vol. 6, no. 5, 1 October 1991 (1991-10-01), pages 43 - 44,46, XP000258358, ISSN: 1049-801X * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016003796A1 (en) | 2015-05-06 | 2016-11-10 | Oerlikon Textile Gmbh & Co. Kg | Method and apparatus for hiding a plurality of melt-spun fiber strands |
EP3540107A4 (en) * | 2016-11-08 | 2020-08-05 | Braskem S.A. | Method and equipment for producing a polypropylene thread |
CN109591330A (en) * | 2019-01-18 | 2019-04-09 | 无锡盛烨特邦新材料科技有限公司 | It is a kind of exempt from glue fiber bar production line exempt from glue fiber bar heat setting machine |
CN109591330B (en) * | 2019-01-18 | 2024-02-06 | 无锡盛烨特邦新材料科技有限公司 | Glue-free fiber bar heat setting machine of glue-free fiber bar production line |
Also Published As
Publication number | Publication date |
---|---|
BR0314746A (en) | 2005-07-26 |
KR20050061480A (en) | 2005-06-22 |
CN1328423C (en) | 2007-07-25 |
RU2318085C2 (en) | 2008-02-27 |
DE50312095D1 (en) | 2009-12-17 |
CN1685092A (en) | 2005-10-19 |
EP1543184A1 (en) | 2005-06-22 |
AU2003273907A1 (en) | 2004-04-23 |
RU2005112708A (en) | 2007-05-20 |
EP1543184B1 (en) | 2009-11-04 |
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