WO2004018198A2 - Film polyolefine multicouche, procede pour le produire et son utilisation - Google Patents

Film polyolefine multicouche, procede pour le produire et son utilisation Download PDF

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Publication number
WO2004018198A2
WO2004018198A2 PCT/EP2003/009077 EP0309077W WO2004018198A2 WO 2004018198 A2 WO2004018198 A2 WO 2004018198A2 EP 0309077 W EP0309077 W EP 0309077W WO 2004018198 A2 WO2004018198 A2 WO 2004018198A2
Authority
WO
WIPO (PCT)
Prior art keywords
polyolefin
film
film according
amorphous
layers
Prior art date
Application number
PCT/EP2003/009077
Other languages
German (de)
English (en)
Other versions
WO2004018198A3 (fr
Inventor
Dirk Heukelbach
Ekkehard Beer
Wolfram Goerlitz
Original Assignee
Ticona Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ticona Gmbh filed Critical Ticona Gmbh
Priority to AU2003255450A priority Critical patent/AU2003255450A1/en
Publication of WO2004018198A2 publication Critical patent/WO2004018198A2/fr
Publication of WO2004018198A3 publication Critical patent/WO2004018198A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00—Labels, badges

Definitions

  • Polyolefin multilayer film a process for producing this film and its use
  • the invention relates to a polyolefin multilayer film with defined shrink properties from at least three layers, comprising either a) a core layer A, which acts as a base layer, and consists of at least one polyolefin and two cover layers B and C on both sides, which are the same or different, made of at least one amorphous polyolefin with one T g of 35 to 180 ° C or b) a core layer A made of at least one amorphous polyolefin with a T g of 35 to 180 ° C and two outer layers B and C, which are the same or different, made of at least one polyolefin.
  • the polyolefin layers in a) and b) can also additionally contain at least one amorphous polyolefin.
  • One of the cover layers B and C in a) can also be mixed with at least one polyolefin.
  • the invention further relates to a method for. Production of this film and its use.
  • Shrink films made of different polymers are often used as all-round labels, also called “sleeves", for plastic or glass containers, since they are easy to apply and after use of the container they are either discarded, separated or reprocessed together, i.e. recycled.
  • the invention relates to a polyolefin multilayer film comprising at least three layers, comprising either a) a core layer A functioning as a base layer and comprising at least one polyolefin and two cover layers B and C on both sides, which are the same or different and consist of at least one amorphous polyolefin with a T g from 35 to 180 ° C or b) a core layer A made of at least one amorphous polyolefin with a Tg of 35 to 180 ° C and two outer layers B and C, which are the same or different, made of at least one polyolefin.
  • the polyolefin layers in a) and b) can also additionally contain at least one amorphous polyolefin.
  • One of the cover layers B and C in a) can also be mixed with at least one polyolefin.
  • the invention further relates to a method for producing this film and its use, which creates a new, significantly improved generation of "sleeve"
  • COC as a polyolefin with an amorphous character retains this property at every stage of processing, e.g. when melting, plasticizing, as a film, when stretching, and therefore does not take - like semi-crystalline materials, e.g. Polypropylene or polyester - by stretching in its crystallinity. It does not change its shrinking force and speed. COC remains stable in the non-shrinking direction during shrinkback, i.e. in contrast to other materials, there is generally no elongation or shortening transverse to the direction of shrinkage.
  • the amorphous polyolefins used are either used as individual components, ie they have a uniform glass transition point T g , or as blends with different T g 's.
  • the influence of adding a polyolefin to the amorphous polyolefins has already been mentioned above.
  • the proportion of the amorphous polyolefin in the respective layer is in the range from 20 to 100%, preferably 60 to 95%, in particular 70 to 90%.
  • the cycloolefin polymer generally contains 0.1% by weight to 100.0% by weight, preferably 0.1% by weight to 99.9% by weight, based on the total mass of the cycloolefin copolymer, of polymerized units which are each other deriving from at least one polycyclic olefin of the formulas I, II, II ', III, IV, V or VI
  • cycloolefin copolymers with polymerized units derived from acyclic olefins with terminal double bonds, such as ⁇ -olefins having 2 to 20 carbon atoms, in particular ethylene or propylene, for example ethylene / norbornene and ethylene / tetracyclododecene copolymers.
  • Preferred terpolymers are ethylene / norbomene / vinyl norbornene, ethylene / norbomene / norbomadiene, ethylene / tetracyclododecene, vinyl norbornene, ethylene / tetracyclododecene / vinyltetracyclododecene or ethylene / norbomene / dicyclopentadiene terpolymers.
  • the use of the amorphous polymer not only improves the sealability and slippage of the film, but also increases the color adhesion when writing or printing when it is used in the cover layers.
  • the cycloolefin copolymers can be prepared in a known manner at temperatures from -78 to 200 ° C. and a pressure of 0.01 to 200 bar, in the presence of one or more catalyst systems which contain at least one transition metal compound and optionally a cocatalyst and optionally a support material.
  • Metallocenes in particular stereorigid metallocenes, are suitable as transition metal compounds.
  • catalyst systems suitable for the preparation of the cycloolefin copolymers are e.g. described in US-A-5,008,356, EP-A-0407870, EP-A-0485893 and EP-A-0 503 422, which are incorporated by reference.
  • Amorphous polyolefins are understood to mean those polyolefins which, despite an irregular arrangement of the molecular chains at room temperature, are solids. They are essentially non-crystalline and their degree of crystallinity is generally below 5%, preferably below 2%, or is 0%, determined by X-ray if fractometry.
  • the heat resistance of the cycloolefin copolymers can be adjusted over a wide range.
  • the glass transition temperature for cycloolefin copolymers measured in accordance with DIN EN ISO 11357-1 with the aid of a DSC, can be used as a guide for the heat resistance, as can be determined on injection moldings in accordance with ISO 75 Part 1 and Part 2.
  • the cycloolefin copolymers described have glass transition temperatures in the range from 35 to 180 ° C., preferably from 50 to 170 ° C., in particular from 55 to 140 ° C.
  • the temperature at which cross stretching is performed can vary. In general, it is carried out at 35 to 150 ° C, preferably 80 to 120 ° C - adapted to the respective T g 's.
  • T A temperature when shrinking 10% [° C]
  • T E temperature when shrinking 70% [° C]
  • ⁇ T difference T E - T A [K]

Landscapes

  • Laminated Bodies (AREA)

Abstract

La présente invention concerne un film polyoléfine multicouche de propriétés de rétrécissement définies, composé d'au moins trois couches et comprenant: soit a) un couche centrale A qui sert de couche de base et comprend au moins une polyoléfine, et deux couches de recouvrement B et C bilatérales qui sont identiques ou différentes et comprennent au moins une polyoléfine amorphe dont la Tg vaut 35 à 180 °C; soit b) une couche centrale A qui comprend au moins une polyoléfine amorphe dont la Tg vaut 35 à 180 °C, et deux couches de recouvrement B et C qui sont identiques ou différentes et comprennent au moins une polyoléfine. Les couches polyoléfine de a) et b) peuvent également comprendre au moins une polyoléfine amorphe. L'une des couches de recouvrement B et C de a) peut également être mélangée à au moins une polyoléfine. L'invention a également pour objet un procédé pour produire ce film et son utilisation.
PCT/EP2003/009077 2002-08-21 2003-08-16 Film polyolefine multicouche, procede pour le produire et son utilisation WO2004018198A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003255450A AU2003255450A1 (en) 2002-08-21 2003-08-16 Polyolefin multilayered film, method for the production of said film and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10238515.7 2002-08-21
DE10238515A DE10238515A1 (de) 2002-08-21 2002-08-21 Polyolefin-Mehrschichtfolie, ein Verfahren zur Herstellung dieser Folie sowie ihre Verwendung

Publications (2)

Publication Number Publication Date
WO2004018198A2 true WO2004018198A2 (fr) 2004-03-04
WO2004018198A3 WO2004018198A3 (fr) 2004-05-13

Family

ID=31197247

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/009077 WO2004018198A2 (fr) 2002-08-21 2003-08-16 Film polyolefine multicouche, procede pour le produire et son utilisation

Country Status (3)

Country Link
AU (1) AU2003255450A1 (fr)
DE (1) DE10238515A1 (fr)
WO (1) WO2004018198A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8663810B2 (en) 2008-10-24 2014-03-04 Jindal Films Americas Llc Multilayer shrink films, labels made therefrom and use thereof
WO2016102742A1 (fr) * 2014-12-22 2016-06-30 Upm Raflatac Oy Étiquettes rétractables
US9637264B2 (en) 2010-01-28 2017-05-02 Avery Dennison Corporation Label applicator belt system
US9695306B2 (en) 2008-10-24 2017-07-04 Jindal Films Europe Virton Sprl Multilayer shrink films, labels made therefrom and use thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7258930B2 (en) 2004-04-28 2007-08-21 Cryovac, Inc. Oxygen scavenging film with cyclic olefin copolymer
KR20070041439A (ko) * 2004-05-18 2007-04-18 군제 가부시키가이샤 다층 열수축성 필름 및 포장전지
AT501412A1 (de) 2004-11-29 2006-08-15 Ebert Folien Ndl Der Haendler Dreheinschlagfolie sowie deren verwendung als verpackungsfolie
EP3037262B1 (fr) * 2014-12-22 2024-05-08 UPM Raflatac Oy Étiquettes thermorétractables
BR112018011444B1 (pt) * 2015-12-18 2022-03-22 Dow Global Technologies Llc Filme de múltiplas camadas e artigo

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US6017616A (en) * 1996-11-20 2000-01-25 Ticona Gmbh Biaxially oriented film made from cycloolefinic polymers, its use, and process for its production
JP2000202951A (ja) * 1999-01-18 2000-07-25 Mitsubishi Plastics Ind Ltd 熱収縮性ポリオレフィン系積層フィルム
JP2000305461A (ja) * 1999-04-22 2000-11-02 Fuji Seal Inc ストレッチシュリンクラベル
JP2000305459A (ja) * 1999-04-22 2000-11-02 Fuji Seal Inc ストレッチラベル
JP2001162725A (ja) * 1999-12-10 2001-06-19 C I Kasei Co Ltd 熱収縮性ポリオレフィン系フイルム
JP2001206379A (ja) * 1999-11-16 2001-07-31 Fuji Seal Inc ラベル付き容器
WO2001064435A1 (fr) * 2000-03-02 2001-09-07 C.I. Kasei Company, Limited Film polyolefinique thermoretractable
JP2002052632A (ja) * 2000-08-10 2002-02-19 Mitsubishi Plastics Ind Ltd ポリオレフィン系熱収縮性積層チューブ
JP2002128133A (ja) * 2000-10-27 2002-05-09 Fuji Seal Inc シュリンクラベル
EP1213138A1 (fr) * 2000-12-06 2002-06-12 Huhtamaki Deutschland GmbH & Co. KG Procédé de fabrication d'une feuille stratifiée
JP2002234115A (ja) * 2001-02-13 2002-08-20 Gunze Ltd 多層熱収縮性フィルムとこれを用いた収縮性ラベルと容器
EP1364777A1 (fr) * 2002-05-24 2003-11-26 Ticona GmbH Produit multicouche laminé, matériau d'emballage et emballages fabriqués au moyen de celui-ci
WO2004012938A1 (fr) * 2002-08-05 2004-02-12 Cryovac, Inc. Film a reprise elastique presentant un indice de retrecissement libre eleve, un coefficient d'elasticite eleve ainsi qu'une faible tension de retrecissement

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EP0849074A3 (fr) * 1996-12-19 2002-01-02 Ticona GmbH Feuilles orientées et scellables comprenant au moins un copolymère cyclooléfinique
JPH1177924A (ja) * 1997-09-12 1999-03-23 Tousero Kk 捻り包装用積層フィルム
DE19828867A1 (de) * 1998-06-29 1999-12-30 Ticona Gmbh Extrusionsbeschichtete Folie
DE19943545A1 (de) * 1999-04-09 2001-03-15 Ticona Gmbh Mehrschichtbehälter mit verbesserter Haftung zwischen den Polymerschichten und hervorragenden Barriereeigenschaften
DE20116341U1 (de) * 2001-10-05 2002-01-17 Ticona Gmbh Polyolefin-Mehrschichtfolie

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US6017616A (en) * 1996-11-20 2000-01-25 Ticona Gmbh Biaxially oriented film made from cycloolefinic polymers, its use, and process for its production
JP2000202951A (ja) * 1999-01-18 2000-07-25 Mitsubishi Plastics Ind Ltd 熱収縮性ポリオレフィン系積層フィルム
JP2000305461A (ja) * 1999-04-22 2000-11-02 Fuji Seal Inc ストレッチシュリンクラベル
JP2000305459A (ja) * 1999-04-22 2000-11-02 Fuji Seal Inc ストレッチラベル
JP2001206379A (ja) * 1999-11-16 2001-07-31 Fuji Seal Inc ラベル付き容器
JP2001162725A (ja) * 1999-12-10 2001-06-19 C I Kasei Co Ltd 熱収縮性ポリオレフィン系フイルム
WO2001064435A1 (fr) * 2000-03-02 2001-09-07 C.I. Kasei Company, Limited Film polyolefinique thermoretractable
JP2002052632A (ja) * 2000-08-10 2002-02-19 Mitsubishi Plastics Ind Ltd ポリオレフィン系熱収縮性積層チューブ
JP2002128133A (ja) * 2000-10-27 2002-05-09 Fuji Seal Inc シュリンクラベル
EP1213138A1 (fr) * 2000-12-06 2002-06-12 Huhtamaki Deutschland GmbH & Co. KG Procédé de fabrication d'une feuille stratifiée
JP2002234115A (ja) * 2001-02-13 2002-08-20 Gunze Ltd 多層熱収縮性フィルムとこれを用いた収縮性ラベルと容器
EP1364777A1 (fr) * 2002-05-24 2003-11-26 Ticona GmbH Produit multicouche laminé, matériau d'emballage et emballages fabriqués au moyen de celui-ci
WO2004012938A1 (fr) * 2002-08-05 2004-02-12 Cryovac, Inc. Film a reprise elastique presentant un indice de retrecissement libre eleve, un coefficient d'elasticite eleve ainsi qu'une faible tension de retrecissement

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8663810B2 (en) 2008-10-24 2014-03-04 Jindal Films Americas Llc Multilayer shrink films, labels made therefrom and use thereof
US9695306B2 (en) 2008-10-24 2017-07-04 Jindal Films Europe Virton Sprl Multilayer shrink films, labels made therefrom and use thereof
US9637264B2 (en) 2010-01-28 2017-05-02 Avery Dennison Corporation Label applicator belt system
WO2016102742A1 (fr) * 2014-12-22 2016-06-30 Upm Raflatac Oy Étiquettes rétractables

Also Published As

Publication number Publication date
DE10238515A1 (de) 2004-03-04
WO2004018198A3 (fr) 2004-05-13
AU2003255450A1 (en) 2004-03-11
AU2003255450A8 (en) 2004-03-11

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