WO2003099098A1 - Dust removing cleaner - Google Patents

Dust removing cleaner Download PDF

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Publication number
WO2003099098A1
WO2003099098A1 PCT/JP2003/006549 JP0306549W WO03099098A1 WO 2003099098 A1 WO2003099098 A1 WO 2003099098A1 JP 0306549 W JP0306549 W JP 0306549W WO 03099098 A1 WO03099098 A1 WO 03099098A1
Authority
WO
WIPO (PCT)
Prior art keywords
dust
pressure
adhesive layer
sensitive adhesive
dust cleaner
Prior art date
Application number
PCT/JP2003/006549
Other languages
French (fr)
Japanese (ja)
Inventor
Akira Katakura
Katsunori Todaka
Original Assignee
Teraoka Seisakusho Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teraoka Seisakusho Co., Ltd. filed Critical Teraoka Seisakusho Co., Ltd.
Priority to KR1020047001194A priority Critical patent/KR100570176B1/en
Publication of WO2003099098A1 publication Critical patent/WO2003099098A1/en
Priority to HK04110084A priority patent/HK1067026A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L25/00Domestic cleaning devices not provided for in other groups of this subclass 
    • A47L25/005Domestic cleaning devices not provided for in other groups of this subclass  using adhesive or tacky surfaces to remove dirt, e.g. lint removers
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L25/00Domestic cleaning devices not provided for in other groups of this subclass 
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/26Cleaning or polishing of the conductive pattern
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/412Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of microspheres
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/01Tools for processing; Objects used during processing
    • H05K2203/0104Tools for processing; Objects used during processing for patterning or coating
    • H05K2203/0143Using a roller; Specific shape thereof; Providing locally adhesive portions thereon
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/01Tools for processing; Objects used during processing
    • H05K2203/0191Using tape or non-metallic foil in a process, e.g. during filling of a hole with conductive paste

Definitions

  • the present invention provides a method of directly pressing a floor carpet or tatami mat, a wall surface or a ceiling surface, or the like, or rotating contact with an adhesive roll pressed against an electronic material such as a printed circuit board or a liquid crystal panel, thereby reducing dust and dust.
  • the present invention relates to a dust cleaner that removes dust and the like by adhering to an adhesive layer. Background art
  • dust cleaners are required to have the following functions. (1) It has the ability and sustainability of instantaneously adhering dust and dirt.
  • the present invention that can solve the above-mentioned problems includes the following inventions.
  • An adhesive tape in which an adhesive layer in which elastic thermoplastic resin hollow fine particles previously produced in an adhesive are dispersed is applied to one surface of a base material, with the adhesive layer as an outside. Dust cleaner consisting of wound adhesive tape.
  • the hollow thermoplastic resin microparticles having elasticity are hollow microparticles formed by previously heating and foaming a synthetic resin micro-force capsule containing a heat-expandable material. 1) Dust cleaner described.
  • thermoplastic resin hollow fine particles are spherical hollow fine particles.
  • thermoplastic resin hollow particles are those having a specific gravity of 0. 0 1 ⁇ 0.
  • An adhesive rubber roller and the dust cleaner according to any one of (1) to (10) are provided, and the adhesive rubber roller captures dust and dirt from an object to be removed.
  • FIG. 1 is a cross-sectional view of an adhesive tape used for a dust cleaner according to the present invention. You.
  • FIGS. 2 and 3 schematically show an application example of a dust cleaner according to the present invention.
  • the dust cleaner of the present invention can be used to (i) directly remove dust and dust attached to an adherend, and (ii) temporarily remove the dust and dust on the adherend. (To be described later), and then remove dust and dirt attached to the surface of the adhesive rubber port with a dust cleaner with reverse winding adhesive tape called cleaning port ( Transfer method).
  • the pressure-sensitive adhesive tape used in the dust cleaner of the present invention has, for example, a layer configuration shown in FIG.
  • the pressure-sensitive adhesive tape 1 has a pressure-sensitive adhesive layer 2 in which elastic thermoplastic resin hollow fine particles 5 already expanded and formed on one surface of a tape base material 3 are uniformly dispersed.
  • a release agent layer 4 is provided on the opposite surface.
  • the opposite surface of the set Keru surface an adhesive layer of the tape base material Shi desirable that release treatment has been performed at stripper Rere 0
  • the tape base material a base material used for ordinary adhesive tapes, such as craft paper, cloth, nonwoven fabric, and film is used.
  • a film type is preferably used for reasons that dust and dust are unlikely to be generated.
  • special synthetic paper for example, trade name: made by Nuppo, Nippon Corporation
  • laterally easy-to-cut olefin fin for tape cut property
  • trade name: Trefan, manufactured by Toray is more preferably used.
  • the adhesive forming the adhesive layer includes a rubber-based adhesive and an acrylic-based adhesive.
  • Adhesives, urethane-based adhesives, silicone-based adhesives, vinyl ether-based adhesives, and the like can be used.
  • one elastomer component is selected from natural rubber or synthetic rubber such as SIS, and terpene resin or petroleum resin is used as a tackifying resin, in some cases a plasticizer, a filler, a vulcanizing agent, or an antiaging agent. Is used.
  • various acrylate monomers such as butyl acrylate and 2-ethylhexyl acrylate are copolymerized with monomers such as acryl acid, and a metal is used as a crosslinking agent.
  • Chelates aluminum, titanium, zirconium, etc.
  • isocyanates tolylene succinate adducts, hexamethylene diisocyanate adducts, etc.
  • epoxies epoxies
  • melamines Butylated melanin, methylated melanin, etc.
  • aziridines are used and cured.
  • rubber-based adhesives are used for removing dust and dirt adhering to household carpet mats, etc. due to their high adhesive strength.
  • an acrylic adhesive which has a small amount of migratory components and adverse substances to adherends is used. The adhesive strength of the adhesive layer of the dust cleaner of the present invention will be described later.
  • thermoplastic resin hollow fine particles thermoplastic resin hollow fine particles formed in advance and having elasticity are used.
  • Such hollow particles of a thermoplastic resin are thermally expandable microphones containing vinylidene chloride-acrylonitrile copolymer / acrylonitrile polymer as a shell wall and containing volatile gas hydrocarbons.
  • Hollow fine particles having elasticity which are formed by heating and expanding a low-pressure capsule, are commercially available. Those capable of forming a large number of independent pores having a property inside the pressure-sensitive adhesive layer can be used.
  • the thermoplastic resin hollow fine particles suitably used in the present invention have a particle size of about 1 ° to 100 ⁇ m.
  • the hollow fine particles include, for example, Matsumoto Microsphere F80ED manufactured by Matsumoto Yushi-Seiyaku Co., Ltd.
  • the thermoplastic resin hollow fine particles formed in advance are used, the characteristics, particle size, particle size distribution, etc. of the hollow fine particles to be used can be selected and freely controlled in advance, and further, the presence of air bubbles.
  • an elastic pressure-sensitive adhesive layer is formed by simply mixing and applying the preselected hollow fine particles with the pressure-sensitive adhesive, the dispersion and uniform dispersion of the hollow fine particles in the pressure-sensitive adhesive layer can be controlled. There is.
  • the difference between the dust cleaner of the present invention and the dust cleaner disclosed in the above-mentioned Japanese Patent Application Laid-Open No. 61-100224 is that the dust cleaner described in the publication is foamable. After mixing the spherical heat-expandable microcapsules containing the substance with the pressure-sensitive adhesive, the heat-expandable microphone opening capsule is heated and foamed and expanded in the pressure-sensitive adhesive layer.
  • the first liner is characterized in that it has a pressure-sensitive adhesive layer formed by uniformly mixing thermoplastic resin hollow fine particles that have been foam-formed in advance with a pressure-sensitive adhesive.
  • the present inventors have found that the dust cleaner disclosed in Japanese Patent Application Laid-Open No.
  • the LINA is characterized in that a suitable elasticity and a supporting force are provided without impairing the tackiness of the surface of the pressure-sensitive adhesive layer.
  • the dust cleaner of the present invention is excellent in its ability to adhere dust, dust and dirt instantaneously and in its sustainability is that it is necessary to have further research in the future.
  • a foamable substance is heated and foamed in a state where the substance is mixed with an adhesive
  • the adhesive in the adhesive layer will expand and the adhesive
  • the pressure-sensitive adhesive layer of the dust cleaner of the present invention has a tendency to cause foaming in the pressure-sensitive adhesive layer after the pressure-sensitive adhesive layer is applied and dried. It is presumed that the major factor is that there is no elongation of the adhesive.
  • the content of the hollow thermoplastic resin particles in the pressure-sensitive adhesive layer of the present invention is preferably 10 to 60% by volume, more preferably 30 to 50% by volume, based on the pressure-sensitive adhesive layer. Although it depends on the specific gravity of the hollow resin particles, it is generally preferably about 0.5 to 5% by weight, more preferably about 1.25 to 3.0% by weight. If this content is low, the elasticity (cushioning property) is insufficient, and the adhesion to the uneven adherend is lacking, and the operator is easily tired. Conversely, if the amount is too large, the pressure-sensitive adhesive layer becomes brittle and glue tends to remain on the adherend.
  • the adhesive strength of the pressure-sensitive adhesive layer is such that the 90 ° peel adhesive strength after 30 minutes of roll bonding is 0.5 to 3 N / 20 mm, more preferably 1 . 0 ⁇ 2.
  • pressure bonding conditions at 3 g / cm 2 to a stainless steel plate is 9 0 ° peel adhesion at low pressure conditions (adherend, measured immediately after compression It is preferable that the applied adhesive strength is 0.25 to 1.5 N / 20 mm, more preferably 0.5 to 1.5 ON / 20 mm.
  • the pressure-sensitive adhesive layer can have this adhesive force while maintaining appropriate elasticity.
  • the thickness of the pressure-sensitive adhesive layer is preferably larger than the average particle diameter of the hollow thermoplastic resin particles used, and the number of the hollow fine particles of the thermoplastic resin larger than the thickness of the pressure-sensitive adhesive layer is preferably small. If a large amount of thermoplastic resin hollow fine particles larger than the thickness of the pressure-sensitive adhesive layer are contained, streaky uncoated portions are likely to be generated in the pressure-sensitive adhesive layer. For example, if the average particle size of the hollow thermoplastic resin particles is 40 ⁇ m, Desirable thickness of the pressure-sensitive adhesive layer is 40 / m or more, more preferably 60 ⁇ m or more, and further preferably 70 ⁇ m or more. Also, it is desirable that the hollow fine particles of the thermoplastic resin used should be removed beforehand by a sieve or the like, in particular, hollow fine particles of a thermoplastic resin having a particle diameter larger than the thickness of the pressure-sensitive adhesive layer.
  • the pressure-sensitive adhesive and cross-linking agent, etc., and thermoplastic resin hollow fine particles are usually mixed, and if necessary, a diluting solvent such as toluene is used, and the mixture is stirred and mixed with an appropriate homogenizer and applied to the substrate. It is desirable to have a release liner on the outermost pressure-sensitive adhesive layer of the roll of pressure-sensitive adhesive tape, but the release agent used for this release liner is the side opposite to the pressure-sensitive adhesive layer of the pressure-sensitive adhesive tape. It is desirable to use a substrate provided with a release layer.
  • silicone-based and non-silicon-based release agents Silicone-based polyadducts of methylvinylpolysiloxane and methylhydridoenepolysiloxane with a catalyst such as platinum are generally known.
  • the typical release agent silicones are Shin-Etsu Chemical Co., Ltd., Toray Industries Co., Ltd., and Toshiba Silicone Co., Ltd., with a range of light to heavy peeling agents.
  • a release agent solution is applied by a wire par having a wire diameter of 0.2 mm at a wet application amount of 10 g / m 2 and dried at 100 ° C. for 2 minutes to form the release agent solution.
  • non-silicone-based products generally show heavier release than silicon-based release agents, and long-chain alkyl-based, fluorine-based, alkyd-based, and acrylic-based products are known.
  • a typical example is a long-chain alkyl type (such as Nichipan Gazette).
  • the dust cleaner of the present invention is obtained by winding the adhesive tape produced as described above on a suitable core material.
  • the dust cleaner of the present invention is used not only to directly remove dust and dirt adhering to an adherend, but also to capture dust and dust with an adhesive mouth. Therefore, a method can be used in which a dust cleaner is brought into contact with the adhesive rubber roll and rotated to remove dust and dirt attached to the adhesive roll.
  • FIG. 2 and Fig. 3 show the usage of such a dust cleaner.
  • a core member 11 is provided with a wound body 12 of a dust cleaner, and the core member 11 is rotatably connected to a handle 13.
  • the printed circuit board 21 is attached to an adhesive rubber roll 22, 22.
  • the adhesive rubber rolls 22, 22 ′ capture dust and dirt adhering to the surface of the printed circuit board 21 by passing through the gap, and then the adhesive rubber rolls 22, 22,
  • the dust cleaner 23, 23 ′ of the present invention is rotated by contact, and the dust and dust adhered to the surface of the adhesive rubber roll 22, 22 ′ are transferred to the dust cleaner 23, 23 ′.
  • the adhesive rubber mouth itself used for this purpose is known, various rubbers can be used for the adhesive rubber roll, but urethane rubber, fluorine rubber, polyisobutylene, butadiene rubber, Silicone rubber, Styrene butadiene rubber, Ethylene propylene rubber, Petinole Rubber, acrylic rubber, nitrile rubber, and the like can be used, and typically, silicone rubber, butyl rubber, and urethane rubber are used.
  • the diameter of the hole is not limited, but a diameter of about 30 to 15 Omm is used for dust removal of printed circuit boards.
  • Acrylic pressure-sensitive adhesive with a non-volatile content of 40% [trade name “SK Dine A-134” manufactured by Soken Chemical Co., Ltd.] Name “Microsphere F80 ED” manufactured by Matsumoto Yushi Seiyaku Co., Ltd .; average particle size 40 ⁇ m, particle size distribution 20-60 ⁇ m; specific gravity 27 kg / m 3 ; shell wall thickness Approximately 0.2 ⁇ ) 0.85 g of toluene-wet product (5 g) was stirred and mixed in “Homoday Spar” manufactured by Tokushu Kika Kogyo Co., Ltd.
  • Hardener (trade name “Aluminate A” manufactured by Kawaken Fine Chemical Co., Ltd.) 0.05 g was added, and the mixture was stirred and mixed in the “Homodisper”, and the mixture was further stirred and mixed. Then, the adhesive composition A was prepared by using a sieve to remove large particles such that the adhesive layer became streaked.
  • One side of a polyester film substrate having a thickness of 38 ⁇ m and a width of 2 Ocm was subjected to a release treatment with a silicone release agent, and the other side was coated with the pressure-sensitive adhesive composition A using a roll coater. Apply so that the thickness of the adhesive layer after drying is about 70 ⁇ . After drying, wind it up on a 38 mm inner diameter paper core so that the adhesive layer is on the outside, and use it for dust cleaner. An adhesive tape was made.
  • Comparative Example 1 Acrylic adhesive with a non-volatile content of 40% [trade name "SK Dyne A-1340" manufactured by Soken Chemical Co., Ltd.] 100 g and a thermally expandable microphone mouth capsule (trade name " Microcross F 80, manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) 0.85 g of toluene-wet product (5 g) was stirred and mixed in Tokushu Kika Kogyo Co., Ltd. “Homoday Spar”. To 25 g of toluene, 0.05 g of an aluminum chelate-based curing agent (trade name “Aluminate A” manufactured by Kawaken Fine Chemicals Co., Ltd.) was added, and the mixture was stirred and mixed in the above “Homodisperse”. These were combined and further stirred and mixed to prepare an adhesive composition B.
  • an aluminum chelate-based curing agent trade name “Aluminate A” manufactured by Kawaken Fine Chemicals Co., Ltd.
  • composition B was applied so that the thickness of the pressure-sensitive adhesive layer after expansion was about 70 // m, dried to remove the solvent, and then dried in an oven ("PH-200" After heating at 150 ° C to thermally expand the heat-expandable microcapsules in the adhesive layer, it is wound around a paper core with an inner diameter of 38 mm so that the adhesive layer is on the outside. Then, an adhesive tape for dust cleaner was prepared.
  • Adhesive layer thickness
  • the thickness of the pressure-sensitive adhesive tape of the samples of Examples and Comparative Examples was measured according to the method specified in JISZ 0237, and the thickness of the polyester film (38 ⁇ ) as the base material was subtracted. Calculated.
  • Adhesive force The samples of Examples and Comparative Examples were measured for 90-degree peel adhesion of the pressure-sensitive adhesive tape to a stainless steel plate in accordance with the method specified in JISZ 0237. However, the adhesive strength after 30 minutes of pressure bonding is applied to a stainless steel plate, and measured after 30 minutes of pressure bonding with a pressure roller. Immediately after low pressure bonding, the adhesive force is measured immediately after pressure bonding at 3 g Z cm 2 for 2 seconds. The measurement was performed, and the test was performed in place of instantaneous tackiness (tackiness).
  • the sample to which the above-mentioned metal powder was adhered was peeled off the adhesive tape to a stainless steel plate at 90 degrees by a method specified in JIS I0237 to measure the adhesive force. However, the measurement was performed by the above-described test method based on the adhesive force immediately after pressure bonding.
  • the dust cleaner according to the present invention is several times as rich as the conventional one, and has a high ability to instantly adhere dust, dust, and dirt, and has excellent sustainability. This eliminates the need to use a large amount of tape.
  • the object to be cleaned is a smooth surface, there is no problem that the adhesive tape is unwound, and even if the surface of the object has irregularities, it has good adaptability and can be easily cleaned. can do.
  • the dust cleaner of the present invention is used as a dust cleaner that is used by directly pressing it against a floor carpet, a tatami mat, a wall surface or a ceiling surface, and an adhesive that is pressed against an electronic material such as a print substrate or a liquid crystal plate. It is industrially useful as a dust cleaner that is brought into rotary contact with a roll to remove dust, dirt, and dirt from the adhesive layer.

Abstract

A dust removing cleaner which comprises an article having an pressure-sensitive adhesive tape wound around it, wherein the pressure-sensitive adhesive tape comprises a base material and, applied on one surface thereof, a pressure-sensitive adhesive composition formed through admixing spherical hollow thermoplastic resin particles having elasticity and an adhesive agent uniformly, and the tape is provided so as to have the pressure-sensitive adhesive composition layer on the outside thereof. The dust cleaner has a pressure sensitive adhesive tape being excellent in both tackiness and dust removing efficiency.

Description

明 細 書 除塵ク リーナー 発明の技術分野  Description Dust cleaner Technical field of the invention
本発明は、 床のカーペッ トや畳、 壁面や天井面などに直接に押し 付けて、 またプリ ント基板、 液晶板などの電子材料などに押し付け られる粘着ロールと回転接触させて、 埃や塵、 ゴミなどを粘着剤層 に付着させて除く除塵ク リーナーに関する。 背景技術  The present invention provides a method of directly pressing a floor carpet or tatami mat, a wall surface or a ceiling surface, or the like, or rotating contact with an adhesive roll pressed against an electronic material such as a printed circuit board or a liquid crystal panel, thereby reducing dust and dust. The present invention relates to a dust cleaner that removes dust and the like by adhering to an adhesive layer. Background art
従来、 粘着剤層面を外側にして巻かれた粘着テープを除塵ク リ一 ナ一と して使用することは、 例えば、 特開昭 6 1— 1 0 0 2 2 4号 公報及び実用新案第 2 5 3 0 1 1 3号登録公報などに示されている ように、 既に知られている。  Conventionally, the use of a pressure-sensitive adhesive tape wound with the pressure-sensitive adhesive layer surface outside as a dust cleaner is disclosed in, for example, Japanese Patent Application Laid-Open No. 61-100224 and Utility Model No. 2 It is already known, as shown in the publication No. 5301113.
このよ う に、 従来知られた除塵ク リーナーには、 さまざまなもの があるが、 前記の特開昭 6 1 — 1 0 0 2 2 4号公報及び実用新案第 2 5 3 0 1 1 3号登録公報に記載されている除塵ク リーナーは、 粘 着剤層が弾性を有していることから、 掃除対象物の凹凸面にも良く なじみ、 凹部の埃や塵、 ゴミをも良く付着させる機能を有していた しかしながら、 前記のような除塵ク リーナーは、 埃や塵、 ゴミを 瞬間的に付着する能力が不足しており、 粘着力がすぐに低下するた め、 常に新鮮な粘着剤層面が用意されている状態を保持する必要が あり、 多量のテープを使用することを余儀なく されていた。  As described above, there are various types of conventionally known dust cleaners. However, the above-mentioned Japanese Patent Application Laid-Open No. 61-100224 and Utility Model No. 2531013 are disclosed. The dust cleaner described in the registered gazette has a function to adhere well to the uneven surface of the object to be cleaned and to adhere the dust, dust and dirt in the recess well because the adhesive layer has elasticity. However, the above-mentioned dust cleaner lacks the ability to instantaneously adhere dust, dirt, and debris, and the adhesive strength is immediately reduced. Had to be kept ready, and a large amount of tape had to be used.
本来、 除塵ク リーナーには、 以下に示したような機能が求められ ている。 ( 1 ) 埃や塵、 ゴミを瞬間的に付着する能力及び持続性を有してい ること。 Originally, dust cleaners are required to have the following functions. (1) It has the ability and sustainability of instantaneously adhering dust and dirt.
(2) 掃除対象物の凹凸になじみ、 埃や塵、 ゴミを付着させる機能 を有していること。  (2) It has a function to adjust to the unevenness of the object to be cleaned and to attach dirt, dust and dirt.
(3) 掃除の対象物がタイルや壁面のよ うにフラッ トな場合、 粘着 テープと対象物との密着力が強すぎて、 除塵ク リーナーを前後に回 転させているときに、 粘着テープが対象物に卷き戻されないよ うな 剥離性を有していること。 発明の開示  (3) If the object to be cleaned is flat like a tile or a wall, the adhesive tape is too tight to adhere to the object, and the adhesive tape is rotated when the dust cleaner is rotated back and forth. It must have releasability so that it cannot be unwound onto the object. Disclosure of the invention
上記課題を解決することのできる本発明は、 以下の各発明を包含 する。  The present invention that can solve the above-mentioned problems includes the following inventions.
( 1 ) 粘着剤中に予め製造され弾性を有する熱可塑性樹脂中空微 粒子が分散されている粘着剤層が基材の片面に塗布されてなる粘着 テープを、 その粘着剤層を外側と して巻回した粘着テープ卷回体か らなる除塵ク リーナー。  (1) An adhesive tape in which an adhesive layer in which elastic thermoplastic resin hollow fine particles previously produced in an adhesive are dispersed is applied to one surface of a base material, with the adhesive layer as an outside. Dust cleaner consisting of wound adhesive tape.
(2) 前記弾性を有する熱可塑性樹脂中空微粒子は、 熱膨張性物 質を内包する合成樹脂製マイクロ力プセルを予め加熱発泡させて形 成されている中空微粒子であることを特徴とする上記 ( 1 ) 記載の 除塵ク リーナ一。  (2) The hollow thermoplastic resin microparticles having elasticity are hollow microparticles formed by previously heating and foaming a synthetic resin micro-force capsule containing a heat-expandable material. 1) Dust cleaner described.
(3 ) 前記粘着テープ卷回体は、 粘着剤面に剥離ライナーを有す ることを特徴とする上記 ( 1 ) 又は (2) に記載の除塵ク リーナー  (3) The dust cleaner according to the above (1) or (2), wherein the adhesive tape roll has a release liner on an adhesive surface.
( 4 ) 前記熱可塑性樹脂中空微粒子が球状の中空微粒子である上 記 (1 ) 〜 (3) のいずれかに記載の除塵ク リーナー。 (4) The dust cleaner according to any one of (1) to (3), wherein the thermoplastic resin hollow fine particles are spherical hollow fine particles.
( 5 ) 前記熱可塑性樹脂中空微粒子が 0. 0 1〜0. l O gZ c m 3 の比重を有するものである上記 ( 1 ) 〜 (4) のいずれかに記 载の除麈ク リーナ一。 (5) serial to any one of the thermoplastic resin hollow particles are those having a specific gravity of 0. 0 1~0. L O gZ cm 3 (1) ~ (4) 麈 No dust cleaner.
( 6 ) 熱可塑性樹脂中空微粒子の平均粒径が 2 0〜6 0 μ πιの範 囲内である上記 ( 1 ) 〜 ( 5 ) のいずれかに記載の除塵ク リーナー  (6) The dust cleaner according to any one of (1) to (5) above, wherein the average particle diameter of the hollow thermoplastic resin particles is in the range of 20 to 60 μπι.
( 7 ) 粘着剤層中の熱可塑性樹脂中空微粒子の含有量が粘着剤層 を基準に 1 0〜 6 0体積%の範囲内である上記 ( 1 ) 〜 ( 6 ) のい ずれかに記載の除塵ク リーナ一。 (7) The method according to any one of the above (1) to (6), wherein the content of the hollow thermoplastic resin particles in the pressure-sensitive adhesive layer is in the range of 10 to 60% by volume based on the pressure-sensitive adhesive layer. Cleaner cleaner.
( 8 ) 粘着剤層中の熱可塑性樹脂中空微粒子の含有量が粘着剤層 を基準に 0. 5〜 5重量%の範囲内である上記 ( 1 ) 〜 ( 7 ) のい ずれかに記載の除塵ク リーナー。 ■  (8) The method according to any one of (1) to (7) above, wherein the content of the hollow fine particles of the thermoplastic resin in the pressure-sensitive adhesive layer is in the range of 0.5 to 5% by weight based on the pressure-sensitive adhesive layer. Dust cleaner. ■
( 9 ) J I S Z 0 2 3 7に規定された方法に従い、 ロール圧 着 3 0分後の 9 0度剥離粘着力が 0. 5〜 3 NZ20mmである上記 ( 1 ) 〜 ( 8 ) のいずれかに記載の除塵ク リーナー。  (9) Any one of the above (1) to (8), in which the 90-degree peel adhesion after 30 minutes of roll pressing is 0.5 to 3 NZ20 mm according to the method specified in JISZ0237. Dust cleaner described.
( 1 0 ) J I S Z 0 2 3 7に規定された方法に準ずるが、 ス テンレス板へのテープの貼付 · 圧着条件は 3 g / c m 2 で 2秒間圧 着であり、 測定した 9 0度剥離粘着力が、 0. 2 5〜1. 5 NZ20 mmである上記 ( 1 ) 〜 ( 9 ) のいずれかに記載の除塵ク リーナー。 (1 0) JISZ 0 2 3 7 to but pursuant to the method specified, stuck-bonding conditions of the tape to the stainless plate is 2 seconds crimp at 3 g / cm 2, measured 9 0 degree peeling adhesive The dust cleaner according to any one of the above (1) to (9), wherein the force is 0.25 to 1.5 NZ20 mm.
( 1 1 ) プリ ン ト基板の除麈のための上記 ( 1 ) 〜 ( 1 0 ) のい ずれかに記載の除塵ク リーナ一。  (11) The dust cleaner according to any one of the above (1) to (10) for removing dust from a printed circuit board.
( 1 2 ) 粘着性ゴムローラと上記 ( 1 ) 〜 ( 1 0 ) のいずれかに 記載の除塵ク リーナーを具備し、 粘着性ゴムローラで除塵すべき対 象物から埃や塵などを捕獲し、 次いで該粘着性ゴムローラに捕獲さ れた埃や塵などを該粘着性ゴムローラと接触回転する前記除塵ク リ ーナ一に転写して除塵することを特徴とする除塵装置。 図面の簡単な説明  (12) An adhesive rubber roller and the dust cleaner according to any one of (1) to (10) are provided, and the adhesive rubber roller captures dust and dirt from an object to be removed. A dust remover, wherein the dust, dust, and the like captured by the adhesive rubber roller are transferred to the dust cleaner that rotates in contact with the adhesive rubber roller to remove dust. BRIEF DESCRIPTION OF THE FIGURES
図 1 は本発明の除麈ク リーナ一に用いる粘着テープの断面図であ る。 FIG. 1 is a cross-sectional view of an adhesive tape used for a dust cleaner according to the present invention. You.
図 2及び図 3は本発明の除麈ク リーナ一の応用例を模式的に示す  FIGS. 2 and 3 schematically show an application example of a dust cleaner according to the present invention.
発明の実施の形態 Embodiment of the Invention
本発明の除塵ク リーナーは、 従来と同様に、 (i )被着物の上に付 着した埃や塵を直接除去する場合、 並びに(i i )被着物上の埃や塵を 一旦、 粘着性ゴムロール (後述) で捕獲し、 その後、 ク リーニング 口ールと称される粘着テープを逆卷きした除塵ク リーナーで、 その 粘着性ゴム口ールの表面に付着した塵や埃を除去する場合 (転写法 ) に使用できるものである。  As in the conventional case, the dust cleaner of the present invention can be used to (i) directly remove dust and dust attached to an adherend, and (ii) temporarily remove the dust and dust on the adherend. (To be described later), and then remove dust and dirt attached to the surface of the adhesive rubber port with a dust cleaner with reverse winding adhesive tape called cleaning port ( Transfer method).
本発明の除塵クリーナーに使用される粘着テープは、 例えば、 図 1 に示す層構成を有している。 図 1 の粘着テープの場合、 粘着テー プ 1 は、 テープ基材 3の片面にすでに膨張形成されている弾性を有 する熱可塑性樹脂中空微粒子 5を均一分散させた粘着剤層 2を有し 、 反対面には剥離剤層 4を有している。 テープ基材の粘着剤層を設 ける面の反対面は剥離剤にて剥離処理がなされていることが望まし レヽ 0 The pressure-sensitive adhesive tape used in the dust cleaner of the present invention has, for example, a layer configuration shown in FIG. In the case of the pressure-sensitive adhesive tape of FIG. 1, the pressure-sensitive adhesive tape 1 has a pressure-sensitive adhesive layer 2 in which elastic thermoplastic resin hollow fine particles 5 already expanded and formed on one surface of a tape base material 3 are uniformly dispersed. On the opposite surface, a release agent layer 4 is provided. The opposite surface of the set Keru surface an adhesive layer of the tape base material Shi desirable that release treatment has been performed at stripper Rere 0
テープ基材としては、 クラフ ト紙、 布、 不織布、 フィルム等、 通 常の粘着テープに使用される基材が用いられる。 プリ ント基板製造 工程などのク リーンルーム内での徐塵用途には、 埃や塵が発塵しに くいとレヽ ぅ理由から、 フィルム系が好適に使用される。 また、 フィ ルム系基材のなかでも、 テープカッ ト性などの理由から、 特殊合成 紙 (例えば、 商品名 : ュポ、 ュポコーポレーショ ン製) や横方向易 カッ ト性ォレフインフイノレム (例えば、 商品名 : ト レファン、 東レ 製) がよ り好適に使用される。  As the tape base material, a base material used for ordinary adhesive tapes, such as craft paper, cloth, nonwoven fabric, and film is used. For dust reduction applications in a clean room such as a printed circuit board manufacturing process, a film type is preferably used for reasons that dust and dust are unlikely to be generated. Among the film-based materials, special synthetic paper (for example, trade name: made by Nuppo, Nippon Corporation) or laterally easy-to-cut olefin fin (for tape cut property) For example, trade name: Trefan, manufactured by Toray) is more preferably used.
粘着剤層を形成する粘着剤と しては、 ゴム系粘着剤、 アク リ ル系 粘着剤、 ウレタン系粘着剤、 シリ コーン系粘着剤、 ビニルエーテル 系粘着剤などを用いることができる。 ゴム系ではエラス トマ一成分 では、 天然ゴムや S I Sなどの合成ゴムから選択され、 粘着付与榭 脂と してテルペン樹脂や石油樹脂を場合によっては可塑剤、 充填材 、 加硫剤、 老化防止剤を配合して使用される。 また、 アク リル系で は、 アク リル酸プチル、 アク リル酸 2—ェチルへキシルなどの各種 ァク リル酸アルキルエステルモノマーとァク リル酸などのモノマー を共重合させ、 架橋剤と して金属キレー ト系 (アルミニウム系、 チ タン系、 ジルコニウム系など) 、 イ ソシァネー ト系 (ト リ レンジィ ソシァネート系付加物、 へキサメチレンジィソシァネート系付加物 など) 、 エポキシ系、 メ ラミ ン系 (ブチル化メ ラミ ン、 メチル化メ ラミ ンなど) 、 アジリ ジン系などを配合して硬化させたものが使用 される。 The adhesive forming the adhesive layer includes a rubber-based adhesive and an acrylic-based adhesive. Adhesives, urethane-based adhesives, silicone-based adhesives, vinyl ether-based adhesives, and the like can be used. In rubbers, one elastomer component is selected from natural rubber or synthetic rubber such as SIS, and terpene resin or petroleum resin is used as a tackifying resin, in some cases a plasticizer, a filler, a vulcanizing agent, or an antiaging agent. Is used. In the acrylic system, various acrylate monomers such as butyl acrylate and 2-ethylhexyl acrylate are copolymerized with monomers such as acryl acid, and a metal is used as a crosslinking agent. Chelates (aluminum, titanium, zirconium, etc.), isocyanates (tolylene succinate adducts, hexamethylene diisocyanate adducts, etc.), epoxies, melamines ( Butylated melanin, methylated melanin, etc.) and aziridines are used and cured.
一般的に、 家庭用のカーぺッ トゃ畳などの上に付着した埃や塵を 除去する用途には粘着性の強さより ゴム系粘着剤が、 プリ ント基板 などの精密印刷部品上の埃や塵をク リーンルーム内などで除去する 用途には、 移行成分や被着物への悪影響物質の少ないァク リル系粘 着剤が使用される。 本発明の除塵ク リ ーナ一の粘着剤層の粘着力に ついては後述する。  In general, rubber-based adhesives are used for removing dust and dirt adhering to household carpet mats, etc. due to their high adhesive strength. For applications where dust and dust are removed in a clean room, etc., an acrylic adhesive which has a small amount of migratory components and adverse substances to adherends is used. The adhesive strength of the adhesive layer of the dust cleaner of the present invention will be described later.
熱可塑性樹脂中空微粒子としては、 予め形成され弾性を有する熱 可塑性樹脂中空微粒子を用いる。 このよ うな熱可塑性樹脂中空微粒 子は、 塩化ビニリデン一アタ リ ロニ ト リル共重合物ゃァク リ ロニト リル重合物を殻壁と して、 揮発性ガスの炭化水素を内包する熱膨張 性マイク ロ力プセルを加熱膨張させて形成されている弾性を有する 中空微粒子が市販されている。 粘着剤層の内部に、 多数の弹性を有 する独立孔を形成することができるものが使用できる。 本発明で好 適に使用される熱可塑性樹脂中空微粒子は、 粒径約 1 ◦〜 1 0 0 μ m、 殻厚約 0. 0 5〜: 1 . 0 //m、 比重約 1 0〜: L 0 0 k g /m3 力 S 好ましく、 よ り好ましく は粒径約 2 0〜 6 0 μιη、 殼壁厚さ約 0. 1〜 0. 5 μ m、 比重約 3 0〜 7 0 k g / m 3 である球状が好適で ある。 上記中空微粒子の例と しては、 例えば、 松本油脂製薬株式会 社製のマツモ トマイク ロスフェアー F 8 0 E Dなどが用いられる。 本発明では、 予め形成した熱可塑性樹脂中空微粒子を使用するの で、 使用する中空微粒子の特性、 粒径、 粒径分布などを予め選択し て自由に制御できるし、 さ らに、 気泡を有して弾性のある粘着剤層 を形成する場合もその予め選択した中空微粒子を粘着剤と混合及び 塗布するだけであるので、 粘着剤層中の中空微粒子の分散、 均一分 散性も制御できる利点がある。 As the thermoplastic resin hollow fine particles, thermoplastic resin hollow fine particles formed in advance and having elasticity are used. Such hollow particles of a thermoplastic resin are thermally expandable microphones containing vinylidene chloride-acrylonitrile copolymer / acrylonitrile polymer as a shell wall and containing volatile gas hydrocarbons. Hollow fine particles having elasticity, which are formed by heating and expanding a low-pressure capsule, are commercially available. Those capable of forming a large number of independent pores having a property inside the pressure-sensitive adhesive layer can be used. The thermoplastic resin hollow fine particles suitably used in the present invention have a particle size of about 1 ° to 100 μm. m, shell thickness about 0.05 to: 1.0 // m, specific gravity about 10 to: L 0 kg / m 3 force S preferred, more preferably particle size about 20 to 60 μιη, shell A spherical shape having a wall thickness of about 0.1 to 0.5 μm and a specific gravity of about 30 to 70 kg / m 3 is preferable. Examples of the hollow fine particles include, for example, Matsumoto Microsphere F80ED manufactured by Matsumoto Yushi-Seiyaku Co., Ltd. In the present invention, since the thermoplastic resin hollow fine particles formed in advance are used, the characteristics, particle size, particle size distribution, etc. of the hollow fine particles to be used can be selected and freely controlled in advance, and further, the presence of air bubbles. When an elastic pressure-sensitive adhesive layer is formed by simply mixing and applying the preselected hollow fine particles with the pressure-sensitive adhesive, the dispersion and uniform dispersion of the hollow fine particles in the pressure-sensitive adhesive layer can be controlled. There is.
本発明の除塵ク リーナーと前記の特開昭 6 1 — 1 0 0 2 2 4号公 報などに示された除麈ク リーナーとの違いは、 該公報記載の除麈ク リーナ一が発泡性物質を内包した球状の熱膨張性マイクロカプセル を粘着剤と混合した後、 粘着剤層中で熱膨張性マイク口カプセルを 加熱発泡膨張させているものであるのに対して、 本発明の除塵ク リ ーナ一は、 予め発泡形成している熱可塑性樹脂中空微粒子を粘着剤 と均一混合して形成されている粘着剤層を有している点にある。 本 発明者らは、 特開昭 6 1 — 1 0 0 2 2 4号公報などに示された除塵 ク リーナ一では粘着剤層表面のタック性が損なわれているが、 本発 明の除塵ク リーナ一では粘着剤層表面のタック性が損なわれずに、 適度な弾力性と支持力が付与されることを特徴とする。  The difference between the dust cleaner of the present invention and the dust cleaner disclosed in the above-mentioned Japanese Patent Application Laid-Open No. 61-100224 is that the dust cleaner described in the publication is foamable. After mixing the spherical heat-expandable microcapsules containing the substance with the pressure-sensitive adhesive, the heat-expandable microphone opening capsule is heated and foamed and expanded in the pressure-sensitive adhesive layer. The first liner is characterized in that it has a pressure-sensitive adhesive layer formed by uniformly mixing thermoplastic resin hollow fine particles that have been foam-formed in advance with a pressure-sensitive adhesive. The present inventors have found that the dust cleaner disclosed in Japanese Patent Application Laid-Open No. 61-100224 impairs the tackiness of the surface of the pressure-sensitive adhesive layer. The LINA is characterized in that a suitable elasticity and a supporting force are provided without impairing the tackiness of the surface of the pressure-sensitive adhesive layer.
本発明の除塵ク リーナーが、 埃や塵、 ゴミを瞬間的に付着する能 力及び持続性に優れているこ との明確な理由は、 今後のさらなる研 究を持たなければならないが、 発泡性物質を粘着剤と混合した状態 で発泡性物質を加熱発泡させた場合、 形成されている粘着剤層中で 発泡性物質が膨張すると、 粘着剤層中の粘着剤が伸びるため粘着剤 が有する本来のタック性がどう しても低下してしまうのに対して、 本発明の除塵ク リーナ一の粘着剤層は、 粘着剤層が塗布乾燥された 後に粘着剤層中での発泡がないため粘着剤の伸びが生じないことが 大きな要因であると推測される。 The clear reason why the dust cleaner of the present invention is excellent in its ability to adhere dust, dust and dirt instantaneously and in its sustainability is that it is necessary to have further research in the future. When a foamable substance is heated and foamed in a state where the substance is mixed with an adhesive, if the foamable substance expands in the formed adhesive layer, the adhesive in the adhesive layer will expand and the adhesive In contrast to the inherent tackiness of the adhesive, the pressure-sensitive adhesive layer of the dust cleaner of the present invention has a tendency to cause foaming in the pressure-sensitive adhesive layer after the pressure-sensitive adhesive layer is applied and dried. It is presumed that the major factor is that there is no elongation of the adhesive.
本発明の粘着剤層における熱可塑性樹脂中空微粒子の含有量は、 熱可塑性樹脂中空微粒子が粘着剤層基準に 1 0〜 6 0体積%、 より 好ましく は 3 0〜 5 0体積%、 また熱可塑性樹脂中空微粒子の比重 に依存するが一般的には 0. 5〜 5重量%程度、 よ り好ましく は 1 . 2 5〜 3. 0重量%程度が好ましい。 この含有量が少ないと弾性 (クッショ ン性) が不足し、 凹凸被着物へのなじみ性に欠けるもの となり、 作業者が疲れやすい。 逆に多すぎると粘着剤層が脆くなり 、 被着物へ糊が残り易くなる。  The content of the hollow thermoplastic resin particles in the pressure-sensitive adhesive layer of the present invention is preferably 10 to 60% by volume, more preferably 30 to 50% by volume, based on the pressure-sensitive adhesive layer. Although it depends on the specific gravity of the hollow resin particles, it is generally preferably about 0.5 to 5% by weight, more preferably about 1.25 to 3.0% by weight. If this content is low, the elasticity (cushioning property) is insufficient, and the adhesion to the uneven adherend is lacking, and the operator is easily tired. Conversely, if the amount is too large, the pressure-sensitive adhesive layer becomes brittle and glue tends to remain on the adherend.
粘着剤層の粘着力は、 J I S Z 0 2 3 7に規定された方法に 従い、 ロール圧着 3 0分後の 9 0度剥離粘着力が 0. 5〜 3 N/20 mm, よ り好ましく は 1 . 0〜 2. O NZ20mm、 また低圧条件での 9 0度剥離粘着力 (被着体であるステンレス板へのテープ貼付 · 圧着 条件が 3 g / c m2 で 2秒間であり、 圧着直後に測定した粘着力) が 0. 2 5〜 1 . 5 N/20mm, よ り好ましく は 0 . 5〜 1 . O N/ 20mmであるこ とが好適である。 本発明の予め形成した熱可塑性樹脂 中空微粒子を用いることで、 粘着剤層は適当な弾性を保持しながら 、 この粘着力を有するこ とが可能である。 According to the method specified in JISZ 0 237, the adhesive strength of the pressure-sensitive adhesive layer is such that the 90 ° peel adhesive strength after 30 minutes of roll bonding is 0.5 to 3 N / 20 mm, more preferably 1 . 0~ 2. O NZ20mm, also a 2 seconds tape application, pressure bonding conditions at 3 g / cm 2 to a stainless steel plate is 9 0 ° peel adhesion at low pressure conditions (adherend, measured immediately after compression It is preferable that the applied adhesive strength is 0.25 to 1.5 N / 20 mm, more preferably 0.5 to 1.5 ON / 20 mm. By using the thermoplastic resin hollow fine particles formed in advance of the present invention, the pressure-sensitive adhesive layer can have this adhesive force while maintaining appropriate elasticity.
粘着剤層の厚さは、 用いる熱可塑性樹脂中空微粒子の平均粒径よ り大きいことが望ましく、 また粘着剤層の厚さよ り粒径が大きい熱 可塑性樹脂中空微粒子は少ないことが望ましい。 粘着剤層の厚さよ り大きい熱可塑性樹脂中空微粒子が多く含まれていると、 粘着剤層 にスジ状の未塗布部分が発生しやすい。 例えば、 熱可塑性樹脂中空 微粒子の平均粒径が 4 0 μ mの場合、 熱可塑性樹脂中空微粒子含有 粘着剤層の望ましい厚さは 4 0 / m以上、 よ り好ましく は 6 0 μ m 以上、 さ らには 7 0 μ m以上である。 また、 用いる熱可塑性樹脂中 空微粒子は予め必要以上に大きい粒子、 特に粘着剤層の厚さよ り粒 径が大きい熱可塑性樹脂中空微粒子を篩などで除いておく ことが望 ましい。 The thickness of the pressure-sensitive adhesive layer is preferably larger than the average particle diameter of the hollow thermoplastic resin particles used, and the number of the hollow fine particles of the thermoplastic resin larger than the thickness of the pressure-sensitive adhesive layer is preferably small. If a large amount of thermoplastic resin hollow fine particles larger than the thickness of the pressure-sensitive adhesive layer are contained, streaky uncoated portions are likely to be generated in the pressure-sensitive adhesive layer. For example, if the average particle size of the hollow thermoplastic resin particles is 40 μm, Desirable thickness of the pressure-sensitive adhesive layer is 40 / m or more, more preferably 60 μm or more, and further preferably 70 μm or more. Also, it is desirable that the hollow fine particles of the thermoplastic resin used should be removed beforehand by a sieve or the like, in particular, hollow fine particles of a thermoplastic resin having a particle diameter larger than the thickness of the pressure-sensitive adhesive layer.
粘着剤層の形成は、 粘着剤および架橋剤などと熱可塑性樹脂中空 微粒子を普通に混合し、 必要に応じて トルエンなどの希釈溶剤を用 い、 適当なホモジナイザーで攪拌混合し、 基材に塗布し、 乾燥する 粘着テープ卷回体の最外周の粘着剤層の上には剥離ライナーを有 することが望ましいが、 この剥離ライナーに用いる剥離剤と しては 粘着テープの粘着剤層と反対側に剥離層を設けたものを用いること が望ましい。  To form the pressure-sensitive adhesive layer, the pressure-sensitive adhesive and cross-linking agent, etc., and thermoplastic resin hollow fine particles are usually mixed, and if necessary, a diluting solvent such as toluene is used, and the mixture is stirred and mixed with an appropriate homogenizer and applied to the substrate. It is desirable to have a release liner on the outermost pressure-sensitive adhesive layer of the roll of pressure-sensitive adhesive tape, but the release agent used for this release liner is the side opposite to the pressure-sensitive adhesive layer of the pressure-sensitive adhesive tape. It is desirable to use a substrate provided with a release layer.
剥離剤と しては、 主に知られているのは、 シリ コーン系と非シリ コーン系がある。 シリ コーン系は、 メチルビニルポリ シロキサンと メチルハイ ドロジエンポリ シロキサンとを、 白金などの触媒による 重付加物が一般的に知られている。 剥離剤用シリ コーンは信越化学 工業、 東レダウコ一二ング、 東芝シリ コーンの各社が代表的で、 剥 離力の軽いものから重いものまで揃えられている。 例としては、 信 越化学工業の K S 8 4 7 Tを 1 0 gに白金系触媒 (P L 5 0 ) を 0 . l g添加し、 トルエン 1 2 0 gで希釈して約 2 . 4 %濃度の剥離 剤溶液を、 線径 0 . 2 m mのワイヤーパーでゥエツ ト塗布量 1 0 g / m 2 を塗布し、 1 0 0 °Cで 2分間乾燥して形成させるなどものが ある。 また、 非シリ コーン系は、 一般的にシリ コーン系剥離剤よ り も重い剥離を示すものが多く、 長鎖アルキル系、 フッ素系、 アルキ ッ ド系、 アク リル系などが知られているが、 代表的なものに長鎖ァ ルキル系 (ニチパン公報など) のものがある。 例と しては、 —方社 油脂製 (ピーロイル 1 0 1 0 ) l gを トルェン 1 0 0 g で希釈、 溶 解した溶液を、 前記のワイヤーパーでゥヱッ ト 1 0 g / m 2 塗布し 、 1 0 0 °Cで 2分間乾燥して形成させるものなどがある。 There are mainly silicone-based and non-silicon-based release agents. Silicone-based polyadducts of methylvinylpolysiloxane and methylhydridoenepolysiloxane with a catalyst such as platinum are generally known. The typical release agent silicones are Shin-Etsu Chemical Co., Ltd., Toray Industries Co., Ltd., and Toshiba Silicone Co., Ltd., with a range of light to heavy peeling agents. As an example, add 10 g of Shin-Etsu Chemical's KS847T to 0.1 g of a platinum-based catalyst (PL 50), dilute with 120 g of toluene, and dilute with 2.4 g of toluene. For example, a release agent solution is applied by a wire par having a wire diameter of 0.2 mm at a wet application amount of 10 g / m 2 and dried at 100 ° C. for 2 minutes to form the release agent solution. In addition, non-silicone-based products generally show heavier release than silicon-based release agents, and long-chain alkyl-based, fluorine-based, alkyd-based, and acrylic-based products are known. A typical example is a long-chain alkyl type (such as Nichipan Gazette). For example, Diluted Yushi the (Piroiru 1 0 1 0) lg in Toruen 1 0 0 g, a solution prepared by dissolve, Uwe' preparative 1 0 g / m 2 was applied in the wire par, dried for 2 minutes at 1 0 0 ° C And the like.
本発明の除塵ク リーナーは、 上記のよ うにして製造した粘着テー プを適当な芯材に卷回して得られる。  The dust cleaner of the present invention is obtained by winding the adhesive tape produced as described above on a suitable core material.
前記のよ うに、 本発明の除塵ク リーナーは、 被着物の上に付着し た埃ゃ麈を直接に除去するように使用するほか、 埃や塵を粘着性口 ールでー且捕獲してから、 その粘着性ゴムロールに除塵ク リーナー を接触回転させて粘着性ロールに付着した埃や塵を除去する方法で も使用できる。  As described above, the dust cleaner of the present invention is used not only to directly remove dust and dirt adhering to an adherend, but also to capture dust and dust with an adhesive mouth. Therefore, a method can be used in which a dust cleaner is brought into contact with the adhesive rubber roll and rotated to remove dust and dirt attached to the adhesive roll.
図 2及び図 3にそのよ うな除塵ク リーナーの使用態様を示す。 図 2では、 芯材 1 1に除塵ク リーナーの卷回体 1 2が取り付けら れ、 芯材 1 1 は取っ手 1 3に回転可能に接続されている。  Fig. 2 and Fig. 3 show the usage of such a dust cleaner. In FIG. 2, a core member 11 is provided with a wound body 12 of a dust cleaner, and the core member 11 is rotatably connected to a handle 13.
図 3 では、 例えば、 プリ ン ト基板の露光前、 ラミナ一ト前などで 表面に付着した埃や塵を除去するため、 プリ ン ト基板 2 1 を粘着性 ゴム ロール 2 2、 2 2, の間を通すこ とで、 粘着性ゴム ロール 2 2 、 2 2 ' がプリ ント基板 2 1の表面に付着した埃ゃ麈をー且捕獲し 、 その後、 この粘着性ゴムロール 2 2、 2 2, に本発明の除麈ク リ ーナー 2 3、 2 3 ' を接触回転させて、 .粘着性ゴムロール 2 2、 2 2 ' 表面に付着した埃や塵を除塵ク リーナー 2 3、 2 3 ' に転写す る。 除塵ク リーナー 2 3、 2 3 ' は、 汚れるとその部分が切り捨て られてその下の新鮮 (清浄) な除塵ク リーナー 2 3、 2 3 , の粘着 剤層が現れる。  In FIG. 3, for example, in order to remove dust and dirt attached to the surface of the printed circuit board before exposure, before laminating, etc., the printed circuit board 21 is attached to an adhesive rubber roll 22, 22. The adhesive rubber rolls 22, 22 ′ capture dust and dirt adhering to the surface of the printed circuit board 21 by passing through the gap, and then the adhesive rubber rolls 22, 22, The dust cleaner 23, 23 ′ of the present invention is rotated by contact, and the dust and dust adhered to the surface of the adhesive rubber roll 22, 22 ′ are transferred to the dust cleaner 23, 23 ′. You. When the dust cleaners 23, 23 'are soiled, their parts are cut off, and the adhesive layer of the fresh (clean) dust cleaners 23, 23, 23 underneath appears.
この目的に使用される粘着性ゴム口ール自体は知られているが、 粘着性ゴムロールには、 各種のゴムが使用できるが、 ウレタンゴム 、 フ ッ素ゴム、 ポ リ イ ソブチレェン、 ブタジエンゴム、 シリ コーン ゴム、 スチレンブタジエンゴム、 エチレンプロ ピレンゴム、 プチノレ ゴム、 アク リルゴム、 二 ト リ ルゴムなどが使用可能であ り 、 代表的 にはシリ コーンゴム、 ブチルゴム、 ウ レタ ンゴムが使用される。 口 ールの直径は限定されないが、 プリ ント基板の除塵用途では 3 0〜 1 5 O mmく らいのものが使用される。 実施例 Although the adhesive rubber mouth itself used for this purpose is known, various rubbers can be used for the adhesive rubber roll, but urethane rubber, fluorine rubber, polyisobutylene, butadiene rubber, Silicone rubber, Styrene butadiene rubber, Ethylene propylene rubber, Petinole Rubber, acrylic rubber, nitrile rubber, and the like can be used, and typically, silicone rubber, butyl rubber, and urethane rubber are used. The diameter of the hole is not limited, but a diameter of about 30 to 15 Omm is used for dust removal of printed circuit boards. Example
以下、 実施例によって本発明の具体例を説明するが、 本発明はこ れらの実施例等によつて限定されるものではない。  Hereinafter, specific examples of the present invention will be described with reference to examples, but the present invention is not limited to these examples and the like.
実施例 1 Example 1
不揮発分が 4 0 %であるアク リ ル系粘着剤 〔商品名 「 S Kダイ ン A— 1 3 4 0」 綜研化学 (株) 社製〕 1 0 0 g と、 熱可塑性樹脂中 空微粒子 (商品名 「マイクロスフヱァー F 8 0 E D」 松本油脂製薬 株式会社製 ; 平均粒径 4 0 μ m、 粒径分布 2 0〜 6 0 μ m ; 比重 2 7 k g / m 3 ; 殼壁厚さ約 0 . 2 μ πι ) 0 . 8 5 g の トルエン湿潤 品 5 g とを、 特殊機化工業社製 「ホモデイ スパー」 中で攪拌混合し 、 次いで、 別に、 トルエン 2 5 g中にアルミキレート系硬化剤 (商 品名 「アルミキレー ト A」 川研フ ァイ ンケミ カル社製) 0 . 0 5 g 添加して前記 「ホモディスパー」 中で攪拌混合したものを合し、 さ らに攪拌混合して、 篩を用いて粘着剤層がスジ状となってしまう よ うな大粒子をと り除き、 粘着剤組成物 Aを調製した。 Acrylic pressure-sensitive adhesive with a non-volatile content of 40% [trade name “SK Dine A-134” manufactured by Soken Chemical Co., Ltd.] Name “Microsphere F80 ED” manufactured by Matsumoto Yushi Seiyaku Co., Ltd .; average particle size 40 μm, particle size distribution 20-60 μm; specific gravity 27 kg / m 3 ; shell wall thickness Approximately 0.2 μπι) 0.85 g of toluene-wet product (5 g) was stirred and mixed in “Homoday Spar” manufactured by Tokushu Kika Kogyo Co., Ltd. Hardener (trade name “Aluminate A” manufactured by Kawaken Fine Chemical Co., Ltd.) 0.05 g was added, and the mixture was stirred and mixed in the “Homodisper”, and the mixture was further stirred and mixed. Then, the adhesive composition A was prepared by using a sieve to remove large particles such that the adhesive layer became streaked.
厚さ 3 8 μ 幅 2 O cmのポリ エステルフィルム基材の片面にシ リ コーン剥離剤にて剥離処理を施し、 反対面には、 ロールコータ一 を使用して上記粘着剤組成物 Aを、 乾燥後の粘着剤層厚さが約 7 0 μ πιになるように塗布し、 乾燥した後、 内径 3 8 mmの紙芯に粘着剤 層が外側になるように卷き取って除塵ク リーナー用粘着テープを作 製した。  One side of a polyester film substrate having a thickness of 38 μm and a width of 2 Ocm was subjected to a release treatment with a silicone release agent, and the other side was coated with the pressure-sensitive adhesive composition A using a roll coater. Apply so that the thickness of the adhesive layer after drying is about 70 μππι. After drying, wind it up on a 38 mm inner diameter paper core so that the adhesive layer is on the outside, and use it for dust cleaner. An adhesive tape was made.
比較例 1 不揮発分が 4 0 %であるアク リル系粘着剤 〔商品名 「 S Kダイン A— 1 3 4 0」 綜研化学 (株) 社製〕 1 0 0 g と、 熱膨張性マイク 口カプセル (商品名 「マイ ク ロスフェアー F 8 0」 松本油脂製薬株 式会社製) 0 . 8 5 g の トルエン湿潤品 5 g とを、 特殊機化工業社 製 「ホモデイ スパー」 中で攪拌混合し、 次いで、 別に、 トルエン 2 5 g中にアルミ キレー ト系硬化剤 (商品名 「アルミ キレー ト A」 川 研フ ァイ ンケ ミ カル社製) 0 . 0 5 g添加して前記 「ホモディスパ 一」 中で攪拌混合したものを合し、 さらに攪拌混合して、 粘着剤組 成物 Bを調製した。 Comparative Example 1 Acrylic adhesive with a non-volatile content of 40% [trade name "SK Dyne A-1340" manufactured by Soken Chemical Co., Ltd.] 100 g and a thermally expandable microphone mouth capsule (trade name " Microcross F 80, manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) 0.85 g of toluene-wet product (5 g) was stirred and mixed in Tokushu Kika Kogyo Co., Ltd. “Homoday Spar”. To 25 g of toluene, 0.05 g of an aluminum chelate-based curing agent (trade name “Aluminate A” manufactured by Kawaken Fine Chemicals Co., Ltd.) was added, and the mixture was stirred and mixed in the above “Homodisperse”. These were combined and further stirred and mixed to prepare an adhesive composition B.
厚さ 3 8 μ m , 幅 2 O cmのポ リ エステノレフイノレム基材の片面にシ リ コーン剥離剤にて剥離処理を施し、 反対面には、 ロールコーター を使用して上記粘着剤組成物 Bを、 膨張後の粘着剤層厚さが約 7 0 // mになるように塗布し、 乾燥して溶剤を除去し、 次いで、 オーブ ン ( 「 P H— 2 0 0」 タパイエスペック社製) 中を通して 1 5 0 °C で加熱し、 粘着剤層中の熱膨張性マイクロカプセルを熱膨張させた 後、 内径 3 8 mmの紙芯に粘着剤層が外側になるように卷き取って除 塵ク リ一ナー用粘着テープを作製した。  One side of a 38 μm thick, 2 Ocm wide polyestenolefinolene substrate is subjected to a release treatment with a silicone release agent, and the other surface is coated with the above adhesive using a roll coater. The composition B was applied so that the thickness of the pressure-sensitive adhesive layer after expansion was about 70 // m, dried to remove the solvent, and then dried in an oven ("PH-200" After heating at 150 ° C to thermally expand the heat-expandable microcapsules in the adhesive layer, it is wound around a paper core with an inner diameter of 38 mm so that the adhesive layer is on the outside. Then, an adhesive tape for dust cleaner was prepared.
実施例及び比較例で得られた粘着テープについて、 各項目の試験 (粘着剤層厚さ、 圧着 3 0分後粘着力、 圧着直後粘着力、 ゴミ付着 性能、 ゴミ付着持続性能、 後転テス ト、 除塵ク リーナー操作性) を 行い、 第 1表に示す結果を得た。  For the adhesive tapes obtained in Examples and Comparative Examples, tests of each item (adhesive layer thickness, adhesive force after 30 minutes of pressure bonding, adhesive force immediately after pressure bonding, dust adhesion performance, dust adhesion sustainability, post-rolling test , Dust elimination cleaner) and obtained the results shown in Table 1.
〔試験方法〕  〔Test method〕
粘着剤層厚さ : Adhesive layer thickness:
実施例及び比較例のサンプルを、 J I S Z 0 2 3 7に規定さ れた方法に従って粘着テープの厚さを測定し、 基材であるポリエス テルフィルム ( 3 8 μ πι ) の厚さを差し引いて、 算出した。  The thickness of the pressure-sensitive adhesive tape of the samples of Examples and Comparative Examples was measured according to the method specified in JISZ 0237, and the thickness of the polyester film (38 μπι) as the base material was subtracted. Calculated.
粘着力 : 実施例及び比較例のサンプルを、 J I S Z 0 2 3 7に規定さ れた方法に従って粘着テープのステンレス板に対する 9 0度剥離粘 着力を測定した。 但し、 圧着 3 0分後粘着力は、 ステンレス板に貼 り付け、 圧着ローラーにて圧着 3 0分後に測定を行い、 低圧着直後 粘着力は、 3 g Z cm 2 で 2秒間圧着した直後に測定を行い、 瞬間的 な粘着性 (タック性) を代用する試験と して行った。 Adhesive force : The samples of Examples and Comparative Examples were measured for 90-degree peel adhesion of the pressure-sensitive adhesive tape to a stainless steel plate in accordance with the method specified in JISZ 0237. However, the adhesive strength after 30 minutes of pressure bonding is applied to a stainless steel plate, and measured after 30 minutes of pressure bonding with a pressure roller. Immediately after low pressure bonding, the adhesive force is measured immediately after pressure bonding at 3 g Z cm 2 for 2 seconds. The measurement was performed, and the test was performed in place of instantaneous tackiness (tackiness).
ゴミ付着性能 : Dust adhesion performance:
実施例及び比較例のサンプルを、 ポリエステルフィルム上に金属 粉を均一に付着させた被着物に貼り付け、 剥離し、 粘着剤表面に付 着した金属粉 (平均粒径 5 /x m ) の付着状況を、 目視にて比較した ゴミ付着持続性能 :  The samples of Examples and Comparative Examples were attached to an adherend in which metal powder was uniformly attached on a polyester film, peeled off, and the adhesion of metal powder (average particle size 5 / xm) attached to the surface of the adhesive The garbage adherence persistence performance was compared visually:
前記の金属粉を付着させたサンプルを、 J I S Ζ 0 2 3 7に 規定された方法にて粘着テープのステンレス板に対する 9 0度剥離 粘着力を測定した。 但し、 測定は、 前記の圧着直後粘着力による試 験方法にて行った。  The sample to which the above-mentioned metal powder was adhered was peeled off the adhesive tape to a stainless steel plate at 90 degrees by a method specified in JIS I0237 to measure the adhesive force. However, the measurement was performed by the above-described test method based on the adhesive force immediately after pressure bonding.
後転テス ト : Back roll test:
実施例及び比較例のサンプルを、 被着物であるフローリ ング上に 付着させ、 除塵ク リーナーを前後に回転させたときに、 被着物であ るビニタイルにテープが卷き戻されるかどうかを試験した。  The samples of Examples and Comparative Examples were adhered onto the flooring as an adherend, and it was tested whether or not the tape was rewound on the vinylite as the adherent when the dust cleaner was rotated back and forth. .
除塵ク リーナー操作性 : Dust cleaner operation:
実施例及び比較例のサンプルを、 被着物であるフローリ ング上に 付着させ、 除塵ク リーナーを前後に回転させたと きの、 埃の取れ具 合や被着物とのなじみ性を試験した。 表 1 The samples of Examples and Comparative Examples were adhered to a flooring as an adherend, and the degree of dust removal and conformability to the adherend were tested when the dust cleaner was rotated back and forth. table 1
Figure imgf000014_0001
本発明に係る除塵ク リーナーは、 上記の実験に示されるように、 従来のものと比較して、 数倍、 埃や塵、 ゴミを瞬間的に付着する能 力に富み、 その持続力が優れているため、 多量のテープを使用する 必要がない。 また、 掃除の被着物が平滑な面であっても、 粘着テー プが卷き戻されるという ような不具合は生じず、 被着物表面の凹凸 があっても、 なじみ性がよく、 容易に掃除をすることができる。 産業上の利用可能性
Figure imgf000014_0001
As shown in the above experiment, the dust cleaner according to the present invention is several times as rich as the conventional one, and has a high ability to instantly adhere dust, dust, and dirt, and has excellent sustainability. This eliminates the need to use a large amount of tape. In addition, even if the object to be cleaned is a smooth surface, there is no problem that the adhesive tape is unwound, and even if the surface of the object has irregularities, it has good adaptability and can be easily cleaned. can do. Industrial applicability
本発明の除塵ク リーナーは、 床のカーペッ トや畳、 壁面や天井面 などに直接に押し付けて使用される除塵ク リーナーとして、 またプ リ ント基板、 液晶板などの電子材料などに押し付けられる粘着ロー ルと回転接触させて、 埃や塵、 ゴミなどを粘着剤層に付着させて除 く除塵ク リーナーと して産業上有用である。  The dust cleaner of the present invention is used as a dust cleaner that is used by directly pressing it against a floor carpet, a tatami mat, a wall surface or a ceiling surface, and an adhesive that is pressed against an electronic material such as a print substrate or a liquid crystal plate. It is industrially useful as a dust cleaner that is brought into rotary contact with a roll to remove dust, dirt, and dirt from the adhesive layer.

Claims

請 求 の 範 囲 The scope of the claims
1 . 粘着剤中に予め製造され弾性を有する熱可塑性樹脂中空微粒 子が分散されている粘着剤層が基材の片面に塗布されてなる粘着テ ープを、 その粘着剤層を外側と して卷回した粘着テープ巻回体から なる除塵ク リーナー。 1. An adhesive tape in which an adhesive layer preliminarily prepared in an adhesive and having elastic thermoplastic hollow particles dispersed therein is applied to one surface of a substrate, and the adhesive layer is set to the outside. Dust cleaner consisting of a roll of adhesive tape wound around.
2 . 前記弾性を有する熱可塑性樹脂中空微粒子は、 熱膨張性物質 を内包する合成樹脂製マイク口カプセルを予め加熱発泡させて形成 されている中空微粒子であることを特徴とする請求項 1記載の除塵 ク リーナ一。  2. The hollow thermoplastic resin microparticles having elasticity are hollow microparticles formed by previously heating and foaming a synthetic resin microphone opening capsule containing a heat-expandable substance. Dust cleaner.
3 . 前記粘着テープ卷回体は、 粘着剤面に剥離ライナーを有する ことを特徴とする請求項 1又は 2に記載の除塵ク リーナー。  3. The dust cleaner according to claim 1, wherein the adhesive tape roll has a release liner on an adhesive surface.
4 . 前記熱可塑性樹脂中空微粒子が球状の中空微粒子である請求 項 1〜 3のいずれかに記載の除塵ク リーナー。  4. The dust cleaner according to any one of claims 1 to 3, wherein the thermoplastic resin hollow fine particles are spherical hollow fine particles.
5 . 前記熱可塑性樹脂中空微粒子が 0 . 0 1〜0 . l O g Z c m 3 の比重を有するものである請求項 1〜4のいずれかに記載の除塵 ク リーナ一。 5. The thermoplastic resin hollow particles 0. 0 1~0. L O g Z cm 3 of those having a specific gravity according to claim 1 dust cleaners scratch.
6 . 熱可塑性樹脂中空微粒子の平均粒径が 2 0〜6 0 // πιの範囲 内である請求項 1〜5のいずれかに記載の除塵ク リーナー。  6. The dust cleaner according to any one of claims 1 to 5, wherein the average particle diameter of the hollow thermoplastic resin particles is in the range of 20 to 60 // πι.
7 . 粘着剤層中の熱可塑性樹脂中空微粒子の含有量が粘着剤層を 基準に 1 0〜 6 0体積%の範囲内である請求項 1〜 6 のいずれかに 記載の除塵ク リーナ一。  7. The dust cleaner according to any one of claims 1 to 6, wherein the content of the hollow fine particles of the thermoplastic resin in the pressure-sensitive adhesive layer is in the range of 10 to 60% by volume based on the pressure-sensitive adhesive layer.
8 . 粘着剤層中の熱可塑性樹脂中空微粒子の含有量が粘着剤層を 基準に 0 . 5〜 5重量%の範囲内である請求項 1〜 7のいずれかに 記載の除塵ク リーナ一。  8. The dust cleaner according to any one of claims 1 to 7, wherein the content of the hollow fine particles of the thermoplastic resin in the pressure-sensitive adhesive layer is in a range of 0.5 to 5% by weight based on the pressure-sensitive adhesive layer.
9 . J I S Z 0 2 3 7に規定された方法に従い、 ロール圧着 3 0分後の 9 0度剥離粘着力が 0 . 5〜 3 N / 20mmである請求項 1 〜 8のいずれかに記載の除塵ク リーナー。 9. The method according to JISZ 0 2 37, wherein the 90-degree peel adhesion after 30 minutes of roll bonding is 0.5 to 3 N / 20 mm. 9. The dust cleaner according to any one of to 8.
1 0. J I S Z 0 2 3 7に規定された方法に準ずるが、 ステ ンレス板へのテープ貼付 · 圧着条件は 3 g Z c m2 で 2秒間圧着で あり、 測定した 9 0度剥離粘着力が、 0. 2 5〜 1. 5 N/20mmで ある請求項 1〜 9のいずれかに記載の除塵クリーナー。 10. In accordance with the method specified in JISZ 0 2 37, affixing the tape to the stainless steel plate.The crimping condition was 3 g Z cm 2 for 2 seconds. The dust cleaner according to any one of claims 1 to 9, which has a thickness of 0.25 to 1.5 N / 20 mm.
1 1. プリ ント基板の除塵のための請求項 1〜1 0のいずれかに 記載の除塵ク リーナ一。  1 1. The dust cleaner according to any one of claims 1 to 10, for dust removal of a printed circuit board.
1 2. 粘着性ゴムローラと請求項 1〜 1 0のいずれかに記載の除 塵タ リ一ナーを具備し、 粘着性ゴムローラで除塵すべき対象物から 埃や塵などを捕獲し、 次いで該粘着性ゴムローラに捕獲された埃や 塵などを該粘着性ゴムローラと接触回転する前記除塵ク リーナーに 転写して除塵することを特徴とする除塵装置。  1 2. Equipped with an adhesive rubber roller and a dust remover according to any one of claims 1 to 10, wherein the adhesive rubber roller captures dust and dirt from an object to be dust-removed, A dust removal device that transfers dust and dirt caught by a conductive rubber roller to the dust cleaner that rotates in contact with the adhesive rubber roller to remove the dust.
PCT/JP2003/006549 2002-05-27 2003-05-26 Dust removing cleaner WO2003099098A1 (en)

Priority Applications (2)

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KR1020047001194A KR100570176B1 (en) 2002-05-27 2003-05-26 Dust removing cleaner
HK04110084A HK1067026A1 (en) 2002-05-27 2004-12-21 Dust removing cleaner

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JP2002-151939 2002-05-27
JP2002151939A JP3979635B2 (en) 2002-05-27 2002-05-27 Dust cleaner

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CN103040423A (en) * 2012-12-13 2013-04-17 郑运婷 Hair sticking roll
EP2737840A4 (en) * 2011-07-26 2015-04-08 Nitoms Kk Adhesive cleaner for plate surfaces

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JP2006181122A (en) * 2004-12-27 2006-07-13 Duskin Co Ltd Cleaning fiber product
JP2007051222A (en) * 2005-08-18 2007-03-01 Nitto Denko Corp Adhesive sheet for removing solvent-containing substance
CN104259143A (en) * 2014-08-25 2015-01-07 曹国柱 Method for cleaning rubber rollers
CN104475962A (en) * 2014-11-26 2015-04-01 山东神工海特电子科技有限公司 Lithium battery tab ultrasonic bonder with dust removal function and welding method
CN215462970U (en) * 2020-11-09 2022-01-11 魏荣宗 Exhaust gas purification system
KR102280533B1 (en) * 2021-01-04 2021-07-26 주식회사 라온티알엠 High performance adhesive roll cleaner

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JPH0571246B2 (en) * 1984-10-24 1993-10-06 Sekisui Chemical Co Ltd
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EP2737840A4 (en) * 2011-07-26 2015-04-08 Nitoms Kk Adhesive cleaner for plate surfaces
US9003591B2 (en) 2011-07-26 2015-04-14 Kabushiki Kaisha Nitoms Pressure-sensitive adhesive cleaner for plate surfaces
CN103040423A (en) * 2012-12-13 2013-04-17 郑运婷 Hair sticking roll

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CN1533256A (en) 2004-09-29
TWI222858B (en) 2004-11-01
JP3979635B2 (en) 2007-09-19
JP2003339617A (en) 2003-12-02
HK1067026A1 (en) 2005-04-01
CN1283205C (en) 2006-11-08
KR100570176B1 (en) 2006-04-12
TW200401622A (en) 2004-02-01
KR20040021657A (en) 2004-03-10

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