WO2003096459A1 - Verfahren zur ermittlung eines gaslecks in einer pem-brennstoffzelle - Google Patents
Verfahren zur ermittlung eines gaslecks in einer pem-brennstoffzelle Download PDFInfo
- Publication number
- WO2003096459A1 WO2003096459A1 PCT/EP2003/004269 EP0304269W WO03096459A1 WO 2003096459 A1 WO2003096459 A1 WO 2003096459A1 EP 0304269 W EP0304269 W EP 0304269W WO 03096459 A1 WO03096459 A1 WO 03096459A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fuel cell
- voltage
- pem fuel
- leak
- pem
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04664—Failure or abnormal function
- H01M8/04679—Failure or abnormal function of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04544—Voltage
- H01M8/04559—Voltage of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04865—Voltage
- H01M8/0488—Voltage of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04895—Current
- H01M8/0491—Current of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04949—Electric variables other electric variables, e.g. resistance or impedance
- H01M8/04952—Electric variables other electric variables, e.g. resistance or impedance of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04238—Depolarisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04246—Short circuiting means for defective fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the invention relates to a method for determining a gas leak between the anode gas space and the cathode gas space of a PEM fuel cell.
- a gas-permeable, porous, electrically conductive collector is arranged on both sides of the membrane on the anode and on the cathode side, with a finely divided catalyst each between the collector and the membrane
- the anode side is supplied with fuel gas, in particular hydrogen or a gas containing hydrogen
- the cathode side is supplied with an oxidant, in particular oxygen or an oxygen-containing gas such as air.
- the hydrogen at the anode of the membrane is oxidized, and the protons that form diffuse through the membrane to the oxygen side. These protons recombine with reduced oxygen to water at the cathode.
- a leak in the membrane of the PEM fuel cell can lead to a so-called gas short-circuit, with hydrogen and / or oxygen reaching the opposite gas space and reacting there on the catalyst in an exothermic reaction.
- Such a leak on the one hand lowers the electrical power of the fuel cell, and on the other hand, particularly in the case of a larger leak, there is a risk of a fire occurring in the fuel cell.
- the test of the fuel cell membrane for leaks is therefore of great importance.
- a pressure maintenance test is often carried out as a simple leak test procedure. Larger leaks can be identified with this test.
- Several fuel cells are usually len to a fuel cell battery or a fuel cell stack.
- the pressure maintenance test has the disadvantage that a leak in a fuel cell stack that is determined with it can at least not be assigned to an individual fuel cell in the stack in a simple manner.
- the sensitivity of the pressure maintenance test is limited to relatively large leaks.
- the object of the invention is to provide a simple and reliable method for determining a gas leak between the anode gas space and the cathode gas space of a PEM fuel cell.
- a fuel cell is charged with a direct current.
- the time course of the electrical voltage at the fuel cell is measured.
- the cell voltage gradually increases to a maximum value. If the cell has a leak, hydrogen and oxygen react by means of a gas short-circuit and thus act to increase the cell voltage opposite.
- the leak test method by means of electrical charging of the fuel cell can be used both in the case of a new PEM fuel cell before it is started up and in a standstill phase of fuel cell operation. In any case, the cell must be sufficiently humidified before the procedure begins. With the aid of the method, the position of a defective fuel cell within a fuel cell stack can be ascertained without problems. All that is necessary is to measure the voltage at the individual cells within the stack individually.
- the current density is preferably 1 to 10 milliamperes per square centimeter. In this way, the method can be carried out quickly. At the same time, damage to the fuel cell during the test is excluded and a sufficiently high measuring sensitivity can be achieved.
- the voltage applied to the fuel cell during the charging process is preferably 0.5 volts to 2 volts, in particular at least 0.8 V and a maximum of 1.5 V.
- the charging voltage thus corresponds approximately to the fuel cell voltage, i.e. the voltage that a fault-free fuel cell delivers in regular energy supply operations.
- the method for determining a gas leak in a PEM fuel cell is supplemented by the following further method steps:
- the advantage of the invention is, in particular, that a leak test on a fuel cell stack is possible with little outlay on equipment, which is very sensitive even to the smallest leaks, but at the same time can also be used for large leaks, and indicates the exact position of defective cells within the fuel cell stack.
- FIG. 1 schematically shows a circuit diagram of a device for
- FIG. 2a, b Carrying out a fuel cell leak test method, FIG. 2a, b the time course of the voltage rise or - in the case of the fuel cell leak test method - with a device according to FIG. 1.
- FIG. 1 shows a fuel cell stack or a fuel cell battery 1 with a number of individual PEM fuel cells 2.
- a controllable power supply unit or a DC voltage source 5 is connected to the fuel cell stack 1 via leads 3 and two switches 4. Furthermore, a discharge resistor 7 that can be switched via a switch 6 is connected to the fuel cell stack 1.
- a voltage measuring device 8 is provided, which is individually connected to all PEM fuel cells 2. The execution of the leak test method is particularly illustrated with the aid of FIGS. 2a, b.
- the gas spaces of the individual PEM fuel cells 2 have a moisture content, ie a water content, on both the bottom and the cathode side. However, the fuel cells 2 are not flooded with water.
- a direct current is passed through the fuel cell stack 1 in such a way that the current density, based on the fuel cell membranes, is approximately 1 to 10 milliamperes per square centimeter.
- the charging voltage is selected such that, if the individual PEM fuel cells 2 are intact, a voltage of 1 volt is present at each cell after the charging process has ended.
- the charging process triggers 2 electrolysis processes in the PEM fuel cells, ie hydrogen and oxygen are formed from the at least small amounts of water in the cells 2.
- the reverse reaction of the chemical reaction takes place during the charging process, which takes place during regular fuel line operation, ie during the voltage supply through the fuel cells 2.
- the electrolysis processes during the charging process mean that after the charging process, the fuel cell stack 1 can be operated as an energy source at least for a short time.
- the small amounts of hydrogen and oxygen gas formed in the anode and cathode gas spaces of the individual PEM fuel lines 2 are sufficient for this.
- the usable voltage thus generated rises to 1 volt during the charging process with intact PEM fuel cells 2. However, if a PEM fuel cell 2 has a leak, the one formed in this cell reacts
- the different measurement curves A, B, C identify different fuel cells 2 which have the following properties:
- A There are three intact fuel cells 2. The slight differences between the individual measured fuel cells 2 are due in particular to the fact that the fuel cell membranes enable slight gas diffusion, the diffusion rates scattering slightly.
- the fuel cell 2 can be charged, but is significantly slower than an intact cell and not to the full cell voltage of IV.
- the cell has a relatively small leak. Gas formed in the anode and / or cathode gas space during the electrolysis process partially passes into the other gas space.
- the fuel cell 2 is almost not rechargeable. It can be concluded from this that the fuel cell 2 has a relatively large leak. Almost all of the hydrogen and oxygen formed in the fuel cell 2 reacts to water shortly after formation. However, since the electrolysis process is slow, this exothermic formation of water is not critical from a safety point of view.
- the position of the defective fuel cells 2 within the fuel cell stack 1 can easily be determined on the basis of the charging behavior of the cells.
- the leak test procedure is can also be carried out during the assembly of the fuel cell stack 1, before its completion.
- FIG. 2b illustrates the leak test on the discharge behavior of fuel cells 2. It is assumed that all fuel cells 2 tested with this method are either intact or at least have such a small leak that they can be charged up to the voltage of IV. After the fuel cells 2 to be tested have been charged to IV, they are discharged via a discharge resistor 7 (FIG. 1). The discharge behavior is shown in a family of curves A ⁇ for four fuel cells 2 and in two measurement curves BC ⁇ for a single fuel cell 2:
- a ⁇ The cell voltage gradually drops to 0V. The energy content accumulated in the fuel cells 2 during the previous charging is consumed. Although all fuel cells 2, the discharge behavior of which is shown in the family of measurement curves A, are intact, the family of curves A ⁇ has a relatively large spread, as is indicated by a double arrow. This illustrates the very high sensitivity of this test.
- the voltage at the fuel cell 2 drops comparatively quickly to 0V.
- the cell acts as a source of energy.
- the energy supply of the fuel cell 2 is used up more quickly than in the case of an intact cell.
- the fuel cell 2 has a very small leak.
- the voltage measured on the cell changes its sign, ie the fuel cell 2 acts as an ohmic resistance from this point in time.
- the energy supply is provided by the intact cells within the fuel line stack 1.
- the discharge behavior of the fuel cell 2 is similar to that shown in the measurement curve B ⁇ , but the fuel cell 2 has a somewhat larger leak.
- the voltage for charging the fuel cells 2 is applied to the entire fuel cell stack 1. However, it is also possible to selectively charge a charging voltage to an individual fuel cell 2 within the
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003236837A AU2003236837A1 (en) | 2002-05-07 | 2003-04-24 | Method for detecting a gas leak in a pem fuel cell |
US10/513,498 US20060035118A1 (en) | 2002-05-07 | 2003-04-24 | Method for detecting a gas leak in a pem fuel cell |
EP03735345A EP1502318A1 (de) | 2002-05-07 | 2003-04-24 | Verfahren zur ermittlung eines gaslecks in einer pem-brennstoffzelle |
CA002487242A CA2487242A1 (en) | 2002-05-07 | 2003-04-24 | Method for detecting a gas leak in a pem fuel cell |
JP2004504327A JP2005524951A (ja) | 2002-05-07 | 2003-04-24 | Pem燃料電池のガス漏れ検出方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02010338.8 | 2002-05-07 | ||
EP02010338A EP1361620A1 (de) | 2002-05-07 | 2002-05-07 | Verfahren zur Ermittlung eines Gaslecks in einer PEM-Brennstoffzelle |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003096459A1 true WO2003096459A1 (de) | 2003-11-20 |
Family
ID=29225620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/004269 WO2003096459A1 (de) | 2002-05-07 | 2003-04-24 | Verfahren zur ermittlung eines gaslecks in einer pem-brennstoffzelle |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060035118A1 (de) |
EP (2) | EP1361620A1 (de) |
JP (1) | JP2005524951A (de) |
AU (1) | AU2003236837A1 (de) |
CA (1) | CA2487242A1 (de) |
WO (1) | WO2003096459A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006008254A1 (de) * | 2006-02-22 | 2007-08-30 | Siemens Ag | Verfahren und Vorrichtung zur Erkennung eines Gaslecks in einer Brennstoffzellenanordnung |
US11404710B2 (en) * | 2018-12-17 | 2022-08-02 | Cummins Enterprise Llc | Assembled portion of a solid oxide fuel cell and methods for inspecting the same |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4222019B2 (ja) * | 2002-12-17 | 2009-02-12 | トヨタ自動車株式会社 | 燃料電池の診断方法 |
JP5105218B2 (ja) * | 2005-06-06 | 2012-12-26 | トヨタ自動車株式会社 | 異常判定装置 |
FR2925982B1 (fr) * | 2007-12-27 | 2010-07-30 | Air Liquide | Procede de diagnostic d'une pile a combustible |
JP5818227B2 (ja) * | 2010-10-25 | 2015-11-18 | 日産自動車株式会社 | 燃料電池システム |
DE102018209932A1 (de) * | 2018-06-20 | 2019-12-24 | Robert Bosch Gmbh | Verfahren und System zur Erkennung einer Leckage innerhalb einer Membran einer Brennstoffzelle |
DE102021206094A1 (de) * | 2021-06-15 | 2022-12-15 | Robert Bosch Gesellschaft mit beschränkter Haftung | Steuergerät für einen Brennstoffzellenstapel |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0927336A (ja) * | 1995-07-13 | 1997-01-28 | Toshiba Corp | 燃料電池スタックの診断方法 |
DE19649434C1 (de) * | 1996-11-28 | 1998-01-15 | Siemens Ag | Verfahren zur Ermittlung von Gaslecks in Brennstoffzellen |
JPH11260385A (ja) * | 1999-01-18 | 1999-09-24 | Mitsubishi Electric Corp | 燃料電池保護方法および保護装置ならびに燃料電池装置 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6096448A (en) * | 1997-12-23 | 2000-08-01 | Ballard Power Systems Inc. | Method and apparatus for operating an electrochemical fuel cell with periodic fuel starvation at the anode |
US6798221B2 (en) * | 2001-10-22 | 2004-09-28 | Ballard Power Systems Inc. | Method, apparatus and article to test fuel cells |
-
2002
- 2002-05-07 EP EP02010338A patent/EP1361620A1/de not_active Withdrawn
-
2003
- 2003-04-24 EP EP03735345A patent/EP1502318A1/de not_active Withdrawn
- 2003-04-24 AU AU2003236837A patent/AU2003236837A1/en not_active Abandoned
- 2003-04-24 WO PCT/EP2003/004269 patent/WO2003096459A1/de active Application Filing
- 2003-04-24 CA CA002487242A patent/CA2487242A1/en not_active Abandoned
- 2003-04-24 US US10/513,498 patent/US20060035118A1/en not_active Abandoned
- 2003-04-24 JP JP2004504327A patent/JP2005524951A/ja not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0927336A (ja) * | 1995-07-13 | 1997-01-28 | Toshiba Corp | 燃料電池スタックの診断方法 |
DE19649434C1 (de) * | 1996-11-28 | 1998-01-15 | Siemens Ag | Verfahren zur Ermittlung von Gaslecks in Brennstoffzellen |
JPH11260385A (ja) * | 1999-01-18 | 1999-09-24 | Mitsubishi Electric Corp | 燃料電池保護方法および保護装置ならびに燃料電池装置 |
Non-Patent Citations (2)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 05 30 May 1997 (1997-05-30) * |
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 14 22 December 1999 (1999-12-22) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006008254A1 (de) * | 2006-02-22 | 2007-08-30 | Siemens Ag | Verfahren und Vorrichtung zur Erkennung eines Gaslecks in einer Brennstoffzellenanordnung |
US11404710B2 (en) * | 2018-12-17 | 2022-08-02 | Cummins Enterprise Llc | Assembled portion of a solid oxide fuel cell and methods for inspecting the same |
Also Published As
Publication number | Publication date |
---|---|
US20060035118A1 (en) | 2006-02-16 |
JP2005524951A (ja) | 2005-08-18 |
CA2487242A1 (en) | 2003-11-20 |
EP1361620A1 (de) | 2003-11-12 |
AU2003236837A1 (en) | 2003-11-11 |
EP1502318A1 (de) | 2005-02-02 |
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