WO2003087457A1 - Tissu non tisse d'image renouvelable comprenant des fibres reconstituees - Google Patents
Tissu non tisse d'image renouvelable comprenant des fibres reconstituees Download PDFInfo
- Publication number
- WO2003087457A1 WO2003087457A1 PCT/US2003/010710 US0310710W WO03087457A1 WO 2003087457 A1 WO2003087457 A1 WO 2003087457A1 US 0310710 W US0310710 W US 0310710W WO 03087457 A1 WO03087457 A1 WO 03087457A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nonwoven fabric
- reconstituted
- fiber
- fibers
- fibrous
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
- D04H1/495—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet for formation of patterns, e.g. drilling or rearrangement
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/689—Hydroentangled nonwoven fabric
Definitions
- the present invention relates generally to nonwoven fabrics, and more particularly, to a nonwoven fabric comprising reconstituted or regenerated fibers, said nonwoven fabric exhibiting improved aesthetic and physical performance, permitting use of the fabric in a wide variety of consumer applications.
- the imaged nonwoven fabric is constructed such that durability is imparted by the controlled distribution and variation in fiber density and/or localized basis weight, and can be deconstructed to its component fiber composition and that fibrous component utilized to make new imaged nonwoven fabrics having equivalent aesthetic and/or physical performance.
- Nonwoven fabrics are suitable for use in a wide variety of applications where the efficiency with which the fabrics can be manufactured provides a significant economic advantage for these fabrics versus traditional textiles.
- nonwoven fabrics have commonly been disadvantaged when fabric properties are compared to conventional textiles, particularly in terms of resistance to elongation, strength when wetted, and abrasion resistance.
- Hydroentangled fabrics have been developed with improved properties, by the formation of complex composite structures in order to provide a necessary level of fabric integrity. Subsequent to entanglement, fabric durability has been further enhanced by the application of binder compositions and/or by thermal stabilization of the entangled fibrous matrix.
- hydroentanglement techniques have been developed which impart images or patterns to the entangled fabric by effecting hydroentanglement on three-dimensional image transfer devices. Such three- dimensional image transfer devices are disclosed in U.S. Patent No. 5,098,764, which is hereby incorporated by reference; with the use of such image transfer devices being desirable for providing a fabric with enhanced physical properties as well as an aesthetically pleasing appearance.
- Fiber selection for forming hydroentangled nonwoven fabrics are a critical factor when evaluating potential end-use applications. It has been typically found that simple and low cost fibers are unsuitable for fabricating semi-durable or durable end-use articles. In order to improve suitability of such fibers, exogenous binder fibers or other topically-applied adhesive agents have been necessarily incorporated. While a nonwoven fabric embodying such performance improvement means can be employed for semi-durable and durable applications, due to the inherent heterogeneity of the resulting fibrous constructs, such materials can not be readily recycled or reclaimed into equivalent type articles.
- the present invention is directed to a nonwoven fabric comprising reconstituted or regenerated fibers (hereinafter referred to as reconstituted fiber or reconstituted fibers), said nonwoven fabric exhibiting improved aesthetic and physical performance, thus permitting use of the fabric in a wide variety of consumer applications.
- the nonwoven fabric exhibits a three- dimensional image that is durable to both converting and end-use application.
- the present invention contemplates that a fabric is formed from a precursor web comprising at least one reconstituted fiber, which when subjected to hydroentanglement on a moveable imaging surface of a three- dimensional image transfer device, an enhanced product is achieved.
- a nonwoven fabric By specific control of fiber distribution and variation in localized fiber density and/or basis weight, a nonwoven fabric is formed which is resistant to elongation, wet strength failure and degradation due to abrasion, and which does not require further inclusion or application of exogenous binding agents.
- a method of making a nonwoven fabric embodying the present invention includes the steps of providing a precursor web comprising a fibrous matrix of at least one reconstituted fiber type. While use of natural, finite length fibers may be employed, as exemplified by reconstituted cotton, the fibrous matrix may further include, in part or whole, finite length fibers of synthetic composition. In a particularly preferred form, the fibrous matrix comprises finite length fibers, which are carded to form a precursor web. Optionally, the carded precursor web may be subjected to reorientation, such as by air-randomization or cross-lapping.
- the precursor web is subjected to pre-entangling on a foraminous-forming surface.
- one or more layers of fibrous matrix comprising either reconstituted fibers, virgin fibers, or the blends thereof, are juxtaposed with a first reconstituted fiber layer, the layered construct then being pre-entangled on a foraminous surface to form a precursor web.
- the present method further contemplates the provision of a three- dimensional image transfer device having a movable imaging surface.
- the image transfer device may comprise a drum-like apparatus, which is rotatable with respect to one or more hydroentangling manifolds.
- the reconstituted fiber precursor web is advanced onto the imaging surface of the image transfer device. Hydroentanglement of the precursor web is effected to form a three-dimensionally imaged fabric.
- a reconstituted fiber exhibiting a prevalence of equal to or less than 10% by weight deleterious fiber artifacts, such fiber artifacts including very short fibers ("fines") or exceedingly knotted or un-processable fibrous components (“neps”), and a three-dimensional image transfer device allows for the controlled distribution and variation in regional density and/or basis weight of fibers to impart significant and useful durability, without necessarily incorporating exogenous adhesive agents.
- the reconstituted imaged fabric may be subjected to one or more variety of post-entanglement treatments.
- Such treatments may include: application of dyes, printing of patterns or logos, mechanical compaction, application of surfactant or electrostatic compositions, and like processes.
- FIGURE 1 is a schematic drawing of a process by which an image transfer is employed in the manufacture of a nonwoven fabric in accordance with the present invention
- FIGURE 2 is top plan view of a representative three-dimensional surface topography of an image transfer device, referred to as "small-square" .
- the present invention is directed to a nonwoven fabric comprising reconstituted fibers, said nonwoven fabric exhibiting improved aesthetic and physical performance, permitting use of the fabric in a wide variety of consumer applications.
- the nonwoven fabric exhibits a three-dimensional image that is durable to both converting and end-use application.
- the present invention contemplates that a fabric is formed from a precursor web comprising at least one reconstituted fiber, which when subjected to hydroentanglement on a moveable imaging surface of a three- dimensional image transfer device, an enhanced product is achieved.
- a nonwoven fabric By specific control of fiber distribution and variation in localized or regional fiber density and/or basis weight, a nonwoven fabric is formed which is resistant to elongation, wet strength failure, and degradation due to abrasion, and which does not require further inclusion or application of exogenous binding or adhesive agents.
- a method of manufacturing a nonwoven fabric embodying the present invention includes the steps of providing a precursor web comprising a fibrous matrix of at least one reconstituted fiber type. While use of natural, finite length fibers may be employed, as exemplified by reconstituted cotton, the fibrous matrix may further include, in part or whole, finite length fibers of synthetic composition. In a particularly preferred form, the fibrous matrix comprises finite length fibers, which are carded to form a precursor web. Optionally, the carded precursor web may be subjected to reorientation, such as by air-randomization or cross-lapping. In one embodiment of the present invention, the precursor web is subjected to pre-entangling on a foraminous- forming surface.
- one or more layers of fibrous matrix comprising either reconstituted fibers, virgin fibers, or the blends thereof, are juxtaposed with a first reconstituted fiber layer, the layered construct then being pre-entangled on a foraminous surface to form a precursor web.
- Serial Number 09/755,523 is directed to a sequential process whereby specific mechanisms are employed to "deconstruct" a pre-existing fibrous fabric back into a free-fiber state.
- pre-existing or pre-formed fibrous fabrics are initially subjected to various means whereby the fabric is reduced to pieces of substantially smaller size and volume. These pieces are then conveyed through, and acted upon, by devices which render-out the fibrous components.
- the fibrous components are further treated with elevated temperature water vapor and incubation with reducing enzymes, thus removing fiber finishes and other topical additives from the freed fibers.
- the fibers are then optionally retreated with a new fiber finish, such as an agent to enhance the ability to card such fiber, and are reformed into bales.
- Reconstituted fibers are selected from natural, synthetic, or blended natural/synthetic composition, of homogeneous or mixed finite fiber length.
- Suitable natural fibers include, but are not limited to, cotton, wood pulp and viscose rayon.
- Synthetic fibers which may be blended in whole or part, include thermoplastic and thermoset polymers.
- Thermoplastic polymers suitable for use as reconstituted fibers include poly olef ins, polyamides and polyesters.
- the thermoplastic polymers may be further selected from; homopolymers, copolymers, conjugates and other derivatives including those thermoplastic polymers having incorporated melt additives or surface-active agents.
- Finite fiber lengths of the reconstituted fibers are selected in the range of about 0.13 inch to 1.0 inch, the range of 0.25 to 0.75 inches being preferred and the fiber denier selected in the range of 1.0 to 22.0, the range of 1.2 to 6.0 denier being preferred for general applications.
- the cross-sectional profile of the fiber is not a limitation to the applicability of the present invention.
- the fabric is formed from a fibrous matrix, which typically comprises finite length fibers, of either natural or synthetic composition, or the combinations thereof.
- the fibrous matrix is preferably carded and optionally cross-lapped to form a fibrous batt, designated F.
- the fibrous batt comprises 100% cross-lapped fibers, that is, all of the fibers of the web have been formed by cross-lapping a carded web so that the reconstituted fibers are oriented at an angle relative to the machine direction of the resultant web.
- U.S. Patent No. 5,475,903, hereby incorporated by reference illustrates such a web drafting apparatus.
- the apparatus in FIGURE 1 includes a foraminous-forming surface in the form of belt 10 upon which the reconstituted fiber precursor web P is positioned for pre-entangling by entangling manifold 12 so as to impart an initial level of working structural integrity to precursor web. Pre-entangling of the precursor web is subsequently effected by movement of the web P sequentially over a drum 14 having a foraminous-forming surface, with entangling manifold 16 effecting entanglement of the web.
- the entangling apparatus of FIGURE 1 further includes a three- dimensional imaging drum 24 comprising a three-dimensional image transfer device for effecting fiber distribution and localized or regional variations in fiber density and/or basis weight.
- the image transfer device includes a moveable imaging surface which moves relative to a plurality of entangling manifolds 26 which act in cooperation with three-dimensional elements defined by the topography of the imaging surface of the image transfer device to effect imaging and functional patterning of the fabric being formed.
- Suitable finishing compositions or the like may be applied at 30, with the fabric dried on suitable drying cans 32.
- Nonwoven fabrics formed in accordance with the present invention have proven to exhibit sufficient resistance to elongation, strength when wetted, and abrasion resistance to warrant use in many end-use applications.
- the absorbency of nonwoven fabric comprising reconstituted cotton fibers has been sufficiently retained so as to be useful in personal hygiene article and garments, such as make-up removing pads, wash clothes and bathing robes.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002481419A CA2481419A1 (fr) | 2002-04-08 | 2003-04-07 | Tissu non tisse d'image renouvelable comprenant des fibres reconstituees |
AU2003221681A AU2003221681A1 (en) | 2002-04-08 | 2003-04-07 | Renewable imaged nonwoven fabric comprising reconstituted fibers |
EP03718259A EP1492913A4 (fr) | 2002-04-08 | 2003-04-07 | Tissu non tisse d'image renouvelable comprenant des fibres reconstituees |
MXPA04009751A MXPA04009751A (es) | 2002-04-08 | 2003-04-07 | Tela no tejida con diseno renovable, que contiene fibras reconstituidas. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37089602P | 2002-04-08 | 2002-04-08 | |
US60/370,896 | 2002-04-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003087457A1 true WO2003087457A1 (fr) | 2003-10-23 |
Family
ID=29250602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/010710 WO2003087457A1 (fr) | 2002-04-08 | 2003-04-07 | Tissu non tisse d'image renouvelable comprenant des fibres reconstituees |
Country Status (6)
Country | Link |
---|---|
US (1) | US20040248493A1 (fr) |
EP (1) | EP1492913A4 (fr) |
AU (1) | AU2003221681A1 (fr) |
CA (1) | CA2481419A1 (fr) |
MX (1) | MXPA04009751A (fr) |
WO (1) | WO2003087457A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9560950B2 (en) | 2010-11-22 | 2017-02-07 | Kao Corporation | Bulky sheet and method for producing same |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITBS20020068A1 (it) * | 2002-07-31 | 2004-02-01 | Sanitars S R L | Tessuto non tessuto in cotone idrofilizzato e suo processo produttivo. |
US20080032611A1 (en) * | 2006-08-01 | 2008-02-07 | The Wooster Brush Company | System for surface preparation |
US20100173568A1 (en) * | 2006-08-01 | 2010-07-08 | The Wooster Brush Company | System for surface preparation |
US20080166940A1 (en) * | 2006-11-16 | 2008-07-10 | Sustainable Solutions, Inc. | Multi-layer nonwoven composite material and method of manufacture |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4995133A (en) * | 1988-05-02 | 1991-02-26 | Newell Robert D | Mop head comprising capacitive web elements, and method of making the same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5098764A (en) * | 1990-03-12 | 1992-03-24 | Chicopee | Non-woven fabric and method and apparatus for making the same |
SE503272C2 (sv) * | 1994-08-22 | 1996-04-29 | Moelnlycke Ab | Nonwovenmaterial framställt genom hydroentangling av en fiberbana samt förfarande för framställning av ett sådant nonwovenmaterial |
US5475903A (en) * | 1994-09-19 | 1995-12-19 | American Nonwovens Corporation | Composite nonwoven fabric and method |
EP1268907B1 (fr) * | 2000-01-20 | 2011-04-06 | Polymer Group, Inc. | Non-tisse portant une image durable |
MXPA03003769A (es) * | 2000-11-10 | 2003-07-28 | Kimberly Clark Co | Estructuras compuestas no tejidas hidroenredadas que contienen materiales fibrosos sinteticos reciclados. |
US6378179B1 (en) * | 2001-01-05 | 2002-04-30 | Gary F. Hirsch | System and method for reconstituting fibers from recyclable waste material |
-
2003
- 2003-04-07 WO PCT/US2003/010710 patent/WO2003087457A1/fr not_active Application Discontinuation
- 2003-04-07 AU AU2003221681A patent/AU2003221681A1/en not_active Abandoned
- 2003-04-07 EP EP03718259A patent/EP1492913A4/fr not_active Withdrawn
- 2003-04-07 CA CA002481419A patent/CA2481419A1/fr not_active Abandoned
- 2003-04-07 MX MXPA04009751A patent/MXPA04009751A/es unknown
- 2003-04-07 US US10/408,719 patent/US20040248493A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4995133A (en) * | 1988-05-02 | 1991-02-26 | Newell Robert D | Mop head comprising capacitive web elements, and method of making the same |
Non-Patent Citations (1)
Title |
---|
See also references of EP1492913A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9560950B2 (en) | 2010-11-22 | 2017-02-07 | Kao Corporation | Bulky sheet and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
EP1492913A1 (fr) | 2005-01-05 |
CA2481419A1 (fr) | 2003-10-23 |
MXPA04009751A (es) | 2004-12-13 |
EP1492913A4 (fr) | 2005-07-06 |
US20040248493A1 (en) | 2004-12-09 |
AU2003221681A1 (en) | 2003-10-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6669799B2 (en) | Durable and drapeable imaged nonwoven fabric | |
EP1325182B1 (fr) | Textile non tisse a fibres enchevetrees differentiellement | |
US20030118777A1 (en) | Imaged nonwoven fabrics in hygienic wipe applications | |
EP1434904A2 (fr) | Tissu non tisse a images comprenant des fibres lyocell | |
US20060234591A1 (en) | Three-dimensional nonwoven fabric with improved loft and resiliancy | |
CA2436604A1 (fr) | Procede de formation d'un tissu composite imprime | |
EP1504144A1 (fr) | Non-tisses avec intercalage d'images tridimensionnelles | |
US7047606B2 (en) | Two-sided nonwoven fabrics having a three-dimensional image | |
US20040248493A1 (en) | Renewable imaged nonwoven fabric comprising reconstituted fibers | |
US7013541B2 (en) | Nonwoven fabrics having compound three-dimensional images | |
NZ540184A (en) | Nonwoven secondary carpet backing | |
TW200301792A (en) | Bonded polyester fiberfill battings with a sealed outer surface having improved stretch capabilities | |
US20030124942A1 (en) | Differentially entangled nonwoven fabric for use as wipes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2481419 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2004/009751 Country of ref document: MX Ref document number: 2003718259 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 2003718259 Country of ref document: EP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2003718259 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: JP |