WO2002092204A3 - Verfahren zur aktivierung und immobilisierung kationischer übergangsmetallkatalysatoren unter verwendung von ionischen flüssigkeiten und komprimiertem co¿2? - Google Patents

Verfahren zur aktivierung und immobilisierung kationischer übergangsmetallkatalysatoren unter verwendung von ionischen flüssigkeiten und komprimiertem co¿2? Download PDF

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Publication number
WO2002092204A3
WO2002092204A3 PCT/EP2002/004903 EP0204903W WO02092204A3 WO 2002092204 A3 WO2002092204 A3 WO 2002092204A3 EP 0204903 W EP0204903 W EP 0204903W WO 02092204 A3 WO02092204 A3 WO 02092204A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
compressed
activating
cationic transition
metal catalysts
Prior art date
Application number
PCT/EP2002/004903
Other languages
English (en)
French (fr)
Other versions
WO2002092204A2 (de
Inventor
Giancarlo Francio
Maurizio Solinas
Edo Janssen
Walter Leitner
Andreas Boesmann
Peter Wasserscheid
Joerg Zimmermann
Danielle Ballivet-Tkatchenko
Michel Picquet
Stefanie Stutzmann
Original Assignee
Studiengesellschaft Kohle Mbh
Giancarlo Francio
Maurizio Solinas
Edo Janssen
Walter Leitner
Andreas Boesmann
Peter Wasserscheid
Joerg Zimmermann
Danielle Ballivet-Tkatchenko
Michel Picquet
Stefanie Stutzmann
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Studiengesellschaft Kohle Mbh, Giancarlo Francio, Maurizio Solinas, Edo Janssen, Walter Leitner, Andreas Boesmann, Peter Wasserscheid, Joerg Zimmermann, Danielle Ballivet-Tkatchenko, Michel Picquet, Stefanie Stutzmann filed Critical Studiengesellschaft Kohle Mbh
Priority to AU2002342232A priority Critical patent/AU2002342232A1/en
Publication of WO2002092204A2 publication Critical patent/WO2002092204A2/de
Publication of WO2002092204A3 publication Critical patent/WO2002092204A3/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00Asymmetric syntheses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/008Processes carried out under supercritical conditions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00042Features relating to reactants and process fluids
    • B01J2219/00047Ionic liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/54Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Die Erfindung beschreibt ein neuartiges Verfahren zur Aktivierung von kationische Übergangsmetallkatalysatoren unter Verwendung eines Lösungsmittelgemisches, das eine oder mehrere ionische Flüssigkeiten und komprimiertes CO2 enthält, wobei der kationische Übergangsmetallkatalysator gleichzeitig immobilisiert werden kann. Eine kontinuierliche Reaktionsführung ist möglich. Bevorzugt wird als Katalysator (I) zur Durchführung einer Hydrovinylierung eingesetzt.
PCT/EP2002/004903 2001-05-15 2002-05-04 Verfahren zur aktivierung und immobilisierung kationischer übergangsmetallkatalysatoren unter verwendung von ionischen flüssigkeiten und komprimiertem co¿2? WO2002092204A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002342232A AU2002342232A1 (en) 2001-05-15 2002-05-04 Method for activating and immobilizing cationic transition metal catalysts using ionic fluids and compressed co2

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10123467.8 2001-05-15
DE10123467A DE10123467A1 (de) 2001-05-15 2001-05-15 Verfahren zur Aktivierung und Immobilisierung kationischer Übergangsmetallkatalysatoren unter Verwendung von ionischen Flüssigkeiten und komprimiertem CO¶2¶

Publications (2)

Publication Number Publication Date
WO2002092204A2 WO2002092204A2 (de) 2002-11-21
WO2002092204A3 true WO2002092204A3 (de) 2003-02-20

Family

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PCT/EP2002/004903 WO2002092204A2 (de) 2001-05-15 2002-05-04 Verfahren zur aktivierung und immobilisierung kationischer übergangsmetallkatalysatoren unter verwendung von ionischen flüssigkeiten und komprimiertem co¿2?

Country Status (3)

Country Link
AU (1) AU2002342232A1 (de)
DE (1) DE10123467A1 (de)
WO (1) WO2002092204A2 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
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US6624127B1 (en) * 2002-11-15 2003-09-23 Intel Corporation Highly polar cleans for removal of residues from semiconductor structures
WO2006088348A1 (en) * 2005-02-18 2006-08-24 Technische Universiteit Delft Process for carrying out a chemical reaction with ionic liquid and carbon dioxide under pressure
US8936719B2 (en) 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
WO2014138810A1 (en) 2013-03-15 2014-09-18 Ultraclean Pty Ltd Process for removing sulphur compounds from hydrocarbons

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002002218A1 (en) * 2000-07-01 2002-01-10 The University Court Of The University Of St. Andrews Catalysis in an ionic fluid, supercritical fluid two phase system
EP1201634A1 (de) * 2000-10-27 2002-05-02 Celanese Chemicals Europe GmbH Verfahren zur Telomerisierung von konjugierten Dienen

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DE19702025A1 (de) * 1997-01-23 1998-07-30 Studiengesellschaft Kohle Mbh Verwendung perfluoralkylsubstituierter Phosphorverbindungen als Liganden für die homogene Katalyse in überkritischem Kohlendioxid
GB9707842D0 (en) * 1997-04-18 1997-06-04 Bp Chem Int Ltd Oligomerisation process
GB9820698D0 (en) * 1998-09-24 1998-11-18 Bp Chem Int Ltd Ionic liquids
GB9821628D0 (en) * 1998-10-06 1998-11-25 Bp Chem Int Ltd Ionic salts
DE19901524A1 (de) * 1999-01-16 2000-07-20 Wilhelm Keim Verfahren zur Stabilisierung homogener Katalysatoren bei der destillativen Produktabtrennung unter Verwendung ionischer Flüssigkeit und der damit verbundenen Möglichkeit der Katalysator-Wiederverwendung der homogenen Katalyse
DE19915904A1 (de) * 1999-04-08 2000-10-12 Studiengesellschaft Kohle Mbh Verfahren zur übergangsmetallkatalysierten Dimerisierung oder Codimerisierung von Alkenen in komprimiertem Kohlendioxid als Lösungsmittel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002002218A1 (en) * 2000-07-01 2002-01-10 The University Court Of The University Of St. Andrews Catalysis in an ionic fluid, supercritical fluid two phase system
EP1201634A1 (de) * 2000-10-27 2002-05-02 Celanese Chemicals Europe GmbH Verfahren zur Telomerisierung von konjugierten Dienen

Non-Patent Citations (15)

* Cited by examiner, † Cited by third party
Title
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BRASSE C C ET AL: "IONIC PHOSPHINE LIGANDS WITH COBALTOCENIUM BACKBONE: NOVEL LIGANDS FOR THE HIGHLY SELECTIVE, BIPHASIC, RHODIUM-CATALYZED HYDROFORMYLATION OF 1-OCTENE IN IONIC LIQUIDS", ORGANOMETALLICS, WASHINGTON, DC, US, vol. 19, no. 19, 2000, pages 3818 - 3823, XP000993463, ISSN: 0276-7333 *
BROWN, R.A. ET AL.: "Asymmetric Hydrogenation and Catalyst Recycling Using Ionic Liquid and Supercritical Carbon Dioxide", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 123, no. 6, 17 January 2001 (2001-01-17), pages 1254 - 1255, XP002218388 *
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Publication number Publication date
AU2002342232A1 (en) 2002-11-25
DE10123467A1 (de) 2002-11-21
WO2002092204A2 (de) 2002-11-21

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