WO2002045665A1 - Novel use of polyhydroxy compounds - Google Patents

Abstract

The restructuring of fibres, especially keratin fibres, is significantly improved by the use of polyhydroxy compounds.

Description

 "New use of polyhydroxy compounds"

The invention relates to the use of polyhydroxy compounds for restructuring keratin fibers and as a component of an active ingredient combination and the use of the active ingredient combination in skin and hair treatment compositions, preferably in hair care products.

The cosmetic treatment of skin and hair is an important part of human body care. So today human hair is treated in a variety of ways with hair cosmetic preparations. These include cleaning the hair with shampoos, care and regeneration with rinses and cures, as well as bleaching, dyeing and shaping the hair with dyes, tinting agents, waving agents and styling preparations. Means for changing or balancing the color of the scalp hair play an outstanding role. Apart from the bleaching agents, which bring about an oxidative brightening of the hair by breaking down the natural hair dyes, there are essentially three types of hair dye in the area of hair coloring:

So-called oxidation dyes are used for permanent, intensive dyeings with appropriate fastness properties. Such colorants usually contain oxidation dye precursors, so-called developer components and coupler components. The developer components form the actual dyes under the influence of oxidizing agents or atmospheric oxygen with one another or under coupling with one or more coupler components. The oxidation coloring agents are characterized by excellent, long-lasting coloring results. For natural-looking dyeings, however, a mixture of a large number of oxidation dye precursors usually has to be used; in many cases will continue direct dyes used for shading. If the dyes formed or used directly in the course of the color formation have distinctly different fastness properties (e.g. UN stability, fastness to perspiration, fastness to washing, etc.), a recognizable and therefore undesirable color shift can occur over time. This phenomenon increases when the hairstyle has hair or hair zones with different degrees of damage. One example of this is long hair, in which the hair tips, which have been exposed to all possible environmental influences for a long time, are generally significantly more damaged than the relatively freshly regrown hair zones.

Coloring agents or tinting agents which contain so-called direct draws as the coloring component are usually used for temporary dyeings. These are dye molecules that attach directly to the hair and do not require an oxidative process to form the color. These dyes include, for example, henna, which is known from antiquity for coloring body and hair. These dyeings are generally much more sensitive to shampooing than the oxidative dyeings, so that a much undesired shift in shade or even a visible "discoloration" occurs much more quickly.

After all, a novel dyeing process has received great attention recently. In this process, precursors of the natural hair dye melanin are applied to the hair; These then form naturally analogous dyes in the hair as part of oxidative processes. Such a process with 5,6-dihydroxyindoline as a dye precursor was described in EP-Bl-530 229. When using agents with 5,6-dihydroxyindoline, in particular several times, it is possible to reproduce the natural hair color for people with gray hair. The coloring can take place with atmospheric oxygen as the only oxidizing agent, so that no further oxidizing agents have to be used. For people with originally medium blonde to brown hair, indoline can be used as the sole dye precursor. On the other hand, satisfactory results can be obtained for use in people with originally red and in particular dark to black hair color can often only be achieved by using additional dye components, in particular special oxidation dye precursors.

Not least because of the heavy stress on the hair, for example through dyeing or perming, as well as through cleaning the hair with shampoos and due to environmental pollution, the importance of care products with a long-lasting effect is increasing. Care products of this type influence the natural structure and properties of the hair. Following such treatments, for example, the wet and dry combability of the hair, the hold and the fullness of the hair can be optimized or the hair can be protected from an increased split rate.

It has therefore long been customary to subject the hair to a special after-treatment. Here, usually in the form of a rinse, the hair is treated with special active ingredients, for example quaternary ammonium salts or special polymers. Depending on the formulation, this treatment improves the combability, hold and fullness of the hair and reduces the split rate.

In addition, so-called combination preparations have recently been developed in order to reduce the complexity of the conventional multi-stage processes, in particular when used directly by consumers.

In addition to the usual components, for example for cleaning the hair, these preparations additionally contain active ingredients which were formerly reserved for the hair aftertreatment agents. The consumer thus saves one application step; At the same time, the packaging effort is reduced because one product is used less.

The active ingredients available both for separate aftertreatment agents and for combination products generally act preferentially on the hair surface. So Haa grooming agents are known which give the hair shine, hold, fullness, better wet or dry combability or prevent split ends. Just as important as the external appearance of the hair is the internal structural cohesion Hair fibers, which can be strongly influenced in particular in oxidative and reductive processes such as dyeing and permanent waves.

There is therefore still a need for active ingredients or combinations of active ingredients for cosmetic compositions with good care properties and good biodegradability. In particular in formulations containing dyes and / or electrolytes, there is a need for additional caring active ingredients which can be incorporated into known formulations without problems.

Surprisingly, it has now been found that the internal structure of fibers, in particular keratinic fibers, can be significantly restructured by using polyhydroxy compounds as active ingredients. Structural strengthening, that is to say restructuring in the sense of the invention, is to be understood as a reduction in the damage to keratin fibers caused by a wide variety of influences. Here, for example, the restoration of natural strength plays an important role. Restructured fibers are characterized, for example, by an improved sheen, by an improved handle and by easier combing. In addition, they have optimized strength and elasticity. Successful restructuring can be demonstrated physically as an increase in melting point compared to the damaged fiber. The higher the melting point of the hair, the stronger the structure of the fiber. A precise description of the determination of the melting range of hair can be found in DE 196 173 95 AI.

Polyhydroxy compounds have been known for a long time and are used in a wide variety of technical applications. For example, the use of glucose as a structuring agent to increase the combability of fine hair is known (manuscript by H. Hensen and J. Kahre for the advanced training event of the German Society for Applied and Scientific Cosmetics 1998 in Aachen). Other polyhydroxy compounds such as cellulose derivatives are used to reduce wet and dry combing work. To adjust viscosities in cosmetic products for example xanthans used. Diols and triols such as glycol, glycerin, propanediols, etc. are used as moisturizers (see A. Domsch, "Die kosmetische Preparate", 4th edition, 1992, volume II, page 8, following, Verlag für die chemischen Industrie, H. Ziolkowsky, Augsburg) or penetration aid widely used. EP 0 287 876 B1 discloses an active ingredient combination of panthenol and mono- or disaccharides as a hair-regenerating preparation. However, there is no evidence of hair restructuring in the sense of the present invention in any of the documents listed.

A first subject of the present invention is therefore cosmetic compositions containing polyhydroxy compounds (A) as active ingredients for the restructuring of fibers.

According to the invention, keratin fibers are understood to mean furs, wool, feathers and in particular human hair.

Polyhydroxy compounds in the sense of the invention are understood to mean all substances which meet the definition in Römpp's Lexikon der Chemie, Version 2.0 of the CD-ROM edition of 1999, published by Georg Thieme. Accordingly, polyhydroxy compounds are understood to mean organic compounds with at least two hydroxyl groups. For the purposes of the present invention, this includes in particular:

Polyols with at least two hydroxyl groups, such as trimethylolpropane,

- carbohydrates, sugar alcohols and sugar and their salts,

- In particular monosaccharides, disaccharides, trisaccharides and oligosaccharides, these also in the form of aldoses, ketoses and / or lactoses, and protected by customary and known in the literature -OH - and -NH - protective groups, such as the triflate group, the trimethylsilyl group or Acyl groups as well as in the form of methyl ethers and as phosphate esters,

- Aminodeoxy sugar, deoxy sugar, thio sugar, these also in the form of aldoses, ketoses and / or lactoses, and protected by customary and in the )

-OH - and -NH - protecting groups known in the literature, such as, for example, the triflate group, the trimethylsilyl group or acyl groups and also in the form of the methyl ether and as phosphate esters, may be very particularly preferred, including monosaccharides having 3 to 8 carbon atoms, such as triosen , Tetroses, pentoses, hexoses, heptoses and octoses, these also in the form of aldoses, ketoses and / or lactoses and protected by customary and known in the literature -OH - and -NH - protective groups, such as the triflate group, the trimethylsilyl group or Acyl groups and also in the form of methyl ethers and as phosphate esters,

Furthermore, very particularly preferred are oligosaccharides with up to 50 monomer units, these also being in the form of aldoses, ketoses and / or lactoses and protected by customary OH and NH protecting groups, such as the triflate group and the trimethylsilyl group, which are known in the literature or acyl groups and also in the form of the methyl ether and as a phosphate ester.

Examples of the polyols according to the invention include sorbitol, inositol, mannitol, tetrite, pentite, hexite, threitol, erythritol, adonite, arabitol, xylitol, dulcitol, erythrose, threose, arabinose, ribose, xylose, lyxose, glucose, galactose, mannose, allose , Altrose, gulose, idose, talose, fructose, sorbose, psicose, tegatose, deoxyribose, glucosamine, galactosamine, rhamnose, digitoxose, thioglucose, sucrose, lactose, trehalose, maltose, cellobiose, melibiose, gestiobiose, cellulose, rutinose, raffinose. Furthermore, reference is made to the relevant specialist literature, such as Beyer-Walter, Textbook of Organic Chemistry, S. Hirzel Verlag Stuttgart, 19th Edition, Section III, pages 393 and the following.

Of course, the teaching according to the invention includes all isomeric forms, such as ice-trans isomers, diastereomers, epimers, anomers and chiral isomers. According to the invention, it is also possible to use a mixture of several active ingredients (A).

The active compounds (A) according to the invention are in the compositions in concentrations of from 0.01% by weight to 20% by weight, preferably from 0.05% by weight to 15% by weight and very particularly preferably in amounts of 0.1 % By weight up to 10% by weight.

According to a first embodiment of the teaching according to the invention, it may be preferred to incorporate the structuring active ingredient (A) directly into coloring or tinting agents, which means to use the active ingredient (A) according to the invention in combination with dyes and / or dye precursors.

Oxidation dye precursors of the developer (B1) and coupler type (B2), natural and synthetic direct dyes (C) and precursors of nature-analogous dyes, such as indole and indoline derivatives, and mixtures of representatives of one or more of these groups can be used as such ,

Primary aromatic amines with a further free or substituted hydroxy or amino group in the para or ortho position, diaminopyridine derivatives, heterocyclic hydrazones, 4-aminopyrazole derivatives and 2,4, are usually used as oxidation dye precursors of the developer type (B1). 5,6-tetraaminopyrimidine and its derivatives used. Suitable developer components are, for example, p-phenylenediamine, p-toluenediamine, p-aminophenol, o-aminophenol, 1- (2'-hydroxyethyl) -2,5-diaminobenzene, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 2- (2,5-diamino-phenoxy) -ethanol, 4-amino-3-methylphenol, 2,4,5,6-tetraaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 4 -Hydroxy-2,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine, 2-dimethylamino-4,5,6-triaminopyrimidine, 2-hydroxymethylamino-4-amino-phenol, bis- (4- aminophenyl) amine, 4-amino-3-fluorophenol, 2-aminomethyl-4-aminophenol, 2-hydroxymethyl-4-aminophenol, 4-amino-2 - ((diethylamino) -methyι) - phenol, bis- (2-hydroxy -5-aminophenyl) methane, 1,4-bis- (4-aminophenyι) diazacycloheptane, 1,3-bis (N (2-hydroxyethyl) -N (4-aminophenylamino)) -2-propanol, 4- i

Amino-2- (2-hydroxyethoxy) phenol, 1, 10-bis (2,5-diaminophenyl) -1, 4,7, 10-tetraoxadecane and 4,5-diaminopyrazole derivatives according to EP 0 740 741 or WO 94/08970 such as e.g. B. 4,5-diamino-l- (2'-hydroxyethyl) pyrazole. Particularly advantageous developer components are p-phenylenediamine, p-toluenediamine, p-aminophenol, 1- (2'-hydroxyethyl) -2,5-diaminobenzene, 4-amino-3-methylphenol, 2-aminomethyl-4-aminophenol, 2,4 , 5,6-tetraaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine.

M-Phenylenediamine derivatives, naphthols, resorcinol and resorcinol derivatives, pyrazolones and m-aminophenol derivatives are generally used as oxidation dye precursors of the coupler type (B2). Examples of such coupler components are m-aminophenol and its derivatives such as 5-amino-2-methylphenol, 5- (3-hydroxypropylamino) -2-methylphenol, 3-amino-2-chloro-6-methylphenol, 2-hydroxy-4 - aminophenoxyethanol, 2,6-dimethyl-3-aminophenol, 3 -trifluoroacetylamino-2-chloro-6-methylphenol, 5-amino-4-chloro-2-methylphenol, 5-amino-4-methoxy-2-methylphenol, 5 - (2'-Hydroxyethyl) amino-2-methylphenol, 3- (diethylamino) phenol, N-cyclopentyl-3-aminophenol, 1, 3-dihydroxy-5- (methylamino) benzene, 3- (ethylamino) - 4-methylphenol and 2,4-dichloro-3-aminophenol, o-aminophenol and its derivatives, m-diaminobenzene and its derivatives such as, for example, 2,4-diaminophenoxyethanol, 1,3-bis (2,4-diaminophenoxy) propane , 1-methoxy-2-amino-4- (2'-hydroxyethylamino) benzene, 1, 3-bis (2,4-diaminophenyl) propane, 2,6-bis (2-hydroxyethylamino) -l-methylbenzene and 1-amino-3-bis (2'-hydroxyethyl) aminobenzene, o-diaminobenzene and its derivatives such as 3,4-diaminobenzoic acid and 2,3- Diamino-l-methylbenzene, di- or trihydroxybenzene derivatives such as resorcinol, resorcinol monomethyl ether, 2-methylresorcinol, 5-methylresorcinol, 2,5-dimethylresorcinol, 2-chlororesorcinol, 4-chlororesorcinol, pyrogallol and 1,2,4 -Trihydroxybenzol,

Pyridine derivatives such as 2,6-dihydroxypyridine, 2-amino-3-hydroxypyridine, 2-amino-5-chloro-3-hydroxypyridine, 3-amino-2-methylamino-6-methoxypyridine, 2,6-dihydroxy-3 , 4-dimethylpyridine, 2,6-dihydroxy-4-methylpyridine, 2,6-diaminopyridine, 2,3-diamino-6-methoxypyridine and 3,5-diamino-2,6-dimethoxypyridine, Naphthalene derivatives such as 1-naphthol, 2-methyl-1-naphthol, 2-hydroxymethyl-1-naphthol, 2-hydroxyethyl-1-naphthol, 1,5-dihydroxynaphthalene, 1,6-dihydroxy-naphthalene, 1.7 -Dihydroxynaphthalin, 1,8-dihydroxynaphthalene, 2,7-dihydroxynaphthalene and 2,3-dihydroxynaphthalene, morpholine derivatives such as 6-hydroxy-benzomorpholine and 6-amino-benzomorpholine, quinoxaline derivatives such as 6-methyl-l, 2,3,4 tetrahydroquinoxaline, pyrazole derivatives such as, for example, l-phenyl-3-methylpyrazol-5-one, indole derivatives such as, for example, 4-hydroxyindole, 6-hydroxyindole and 7-hydroxyindole, methylenedioxybenzene derivatives such as, for example, l-hydroxy-3,4-methylenedioxybenzene, l-amino- 3,4-methylenedioxybenzene and l- (2'-hydroxyethyi) - amino-3, 4-methylenedioxybenzene.

Particularly suitable coupler components are 1-naphthol, 1,5-, 2,7- and 1,7-dihydroxynaphthalene, 3-aminophenol, 5-amino-2-methylphenol, 2-amino-3-hydroxypyridine, resorcinol, 4-chlororesorcinol, 2-chloro-6-methyl-3-aminophenol, 2-methylresorcinol, 5-methylresorcinol, 2,5-dimethylresorcinol and 2,6-dihydroxy-3,4-dimethylpyridine.

Direct dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols. Particularly suitable direct dyes are those with the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, Basic Yellow 57, Disperse Orange 3, HC Red 3, HC Red BN, Basic Red 76, HC Blue 2, HC Blue 12, Disperse Blue 3, Basic Blue 99, HC Niolet 1, Disperse Niolet 1, Disperse Niolet 4, Disperse Black 9, Basic Brown 16 and Basic Brown 17 known compounds as well as 1,4-bis- (ß- hydroxyethyl) - amino-2-nitrobenzene, 4-amino-2-nitrodiphenylamine-2 '-carboxylic acid, 6-Νitro-l, 2,3,4-tetrahydroquinoxaline, hydroxyethyl-2-nitro-toluidine, picramic acid, 2-amino- 6-chloro-4-nitrophenol, 4-ethylamino-3-nitrobenzoic acid and 2-chloro-6-ethylamino-1-hydroxy-4-nitrobenzene. Directly occurring dyes found in nature include, for example, henna red, henna neutral, chamomile flowers, sandalwood, black tea, sapwood, sage, blue wood, madder root, catechu, sedre and alkanna root.

It is not necessary that the oxidation dye precursors or the substantive dyes each represent uniform compounds. Rather, in the hair colorants according to the invention, due to the manufacturing process for the individual dyes, minor components may also be present, provided that these do not adversely affect the coloring result or for other reasons, e.g. B. toxicological, must be excluded.

With regard to the dyes which can be used in the hair dyeing and tinting agents according to the invention, reference is also expressly made to the monograph Ch. Zviak, The Science of Hair Care, chapter 7 (pages 248-250; direct dyes) and chapter 8, pages 264-267; Oxidation dye precursors), published as Volume 7 of the "Dermatology" series (ed .: Ch., Culnan and H. Maibach), Marcel Dekker Inc., New York, Basel, 1986, and the "European inventory of cosmetic raw materials ", published by the European Community, available in diskette form from the Federal Association of German Industry and Commerce for Medicinal Products, Health Care Products and Personal Care Products, Mannheim.

For example, indoles and indolines and their physiologically tolerable salts are used as precursors of nature-analogous dyes. Those indoles and indolines are preferably used which have at least one hydroxyl or amino group, preferably as a substituent on the six-membered ring. These groups can carry further substituents, e.g. B. in the form of etherification or esterification of the hydroxy group or an alkylation of the amino group. 5,6-Dihydroxyindoline, N-methyl-5,6-dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-propyl-5,6-dihydroxyindoline, N-butyl-5,6- dihydroxyindoline, 5,6-dihydroxyindoline-2-carboxylic acid, 6-hydroxyindoline, 6-aminoindoline and 4-aminoindoline as well as 5,6-dihydroxyindole, N-methyl-5,6-dihydroxyindole, N-ethyl-5,6- dihydroxyindole, N-propyl-5,6-dihydroxyindole, N-butyl-5,6- dihydroxyindole, 5,6-dihydroxyindole-2-carboxylic acid, 6-hydroxyindole, 6-aminoindole and 4-aminoindole.

Of particular note within this group are N-methyl-5,6-dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-propyl-5,6-dihydroxyindoline, N-butyl-5,6-dihydroxyindoline and especially that 5,6-dihydroxyindoline and N-methyl-5,6-dihydroxyindole, N-ethyl-5,6-dihydroxyindole, N-propyl-5,6-dihydroxyindole, N-butyl-5,6-dihydroxyindole and in particular the 5 6-dihydroxyindole.

The indoline and indole derivatives in the colorants used in the process according to the invention both as free bases and in the form of their physiologically tolerable salts with inorganic or organic acids, for. B. the hydrochlorides, sulfates and hydrobromides, are used.

When using dye precursors of the indoline or indole type, it may be preferred to use these together with at least one amino acid and / or at least one oligopeptide. Preferred amino acids are amino carboxylic acids, especially α-amino carboxylic acids and ω-amino carboxylic acids. Arginine, lysine, ornithine and histidine are again particularly preferred among the - aminocarboxylic acids. A very particularly preferred amino acid is arginine, in particular in free form, but also used as the hydrochloride.

Both the oxidation dye precursors and the direct dyes and the precursors of nature-analogous dyes are preferably in the inventive compositions in amounts of 0.01 to 20% by weight, preferably 0.1 to 5% by weight, based in each case on the total composition, contain.

Hair colorants, especially if the coloring is oxidative, be it with atmospheric oxygen or other oxidizing agents such as hydrogen peroxide, are usually set slightly acidic to alkaline, ie to pH values in the range from about 5 to 11. For this purpose, the colorants contain alkalizing agents, usually alkali or alkaline earth metal hydroxides, ammonia or organic amines. Preferred alkalizing agents are monoethanolamine, monoisopropanolamine, 2-amino-2-methyl-propanol, 2-amino-2-methyl-l, 3-propanediol, 2-amino-2-ethyl-l, 3-propanediol, 2-amino-2 -methylbutanol and triethanolamine as well as alkali and alkaline earth metal hydroxides. Monoethanolamine, triethanolamine and 2-amino-2-methyl-propanol and 2-amino-2-methyl-1,3-propanediol are particularly preferred in this group. The use of ω-amino acids such as ω-aminocaproic acid as an alkalizing agent is also possible.

If the actual hair colors are formed as part of an oxidative process, customary oxidizing agents, such as in particular hydrogen peroxide or its adducts with urea, melamine or sodium borate, can be used. However, oxidation with atmospheric oxygen as the only oxidizing agent can be preferred. It is also possible to carry out the oxidation with the aid of enzymes, the enzymes being used both for producing oxidizing per compounds and for enhancing the action of a small amount of oxidizing agents present, or else enzymes which use electrons from suitable developers. components (reducing agents) transferred to atmospheric oxygen. Oxidases such as tyrosinase, ascorbate oxidase and laccase are preferred, but also glucose oxidase, uricase or pyruvate oxidase. Furthermore, the procedure should be mentioned to increase the effect of small amounts (e.g. 1% and less, based on the total agent) of hydrogen peroxide by peroxidases.

The preparation of the oxidizing agent is then expediently mixed with the preparation with the dye precursors immediately before dyeing the hair. The resulting ready-to-use hair color preparation should preferably have a pH in the range from 6 to 10. It is particularly preferred to use the hair dye in a weakly alkaline environment. The application temperatures can be in a range between 15 and 40 ° C., preferably at the temperature of the scalp. After an exposure time of approx. 5 to 45, in particular 15 to 30, minutes, the hair dye is removed from the hair to be colored by rinsing. The Rinsing with a shampoo is not necessary if a carrier with a high tenside content, e.g. B. a coloring shampoo was used.

In the case of hair that is difficult to color, the preparation with the dye precursors can be applied to the hair without prior mixing with the oxidation component. After an exposure time of 20 to 30 minutes, the oxidation component is then applied, if necessary after an intermediate rinse. After a further exposure time of 10 to 20 minutes, the skin is rinsed and, if required, re-shampooed. In this embodiment, according to a first variant, in which the previous application of the dye precursors is said to bring about better penetration into the hair, the corresponding agent is adjusted to a pH of about 4 to 7. According to a second variant, air oxidation is initially aimed for, the agent applied preferably having a pH of 7 to 10. In the subsequent accelerated postoxidation, the use of acidified peroxidisulfate solutions as the oxidizing agent can be preferred.

Furthermore, the formation of the color can be supported and increased by adding certain metal ions to the agent. Such metal ions are, for example, Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Fe ³⁺ , Mn ²⁺ , Mn ⁴⁺ , Li ⁺ , Mg ²⁺ , Ca ²⁺ and Al ³⁺ . Zn ²⁺ , Cu ²⁺ and Mn ²⁺ are particularly suitable. In principle, the metal ions can be used in the form of any physiologically acceptable salt. Preferred salts are the acetates, sulfates, halides, lactates and tartrates. By using these metal salts, the formation of the coloring can be accelerated and the color shade can be influenced in a targeted manner.

In a further preferred embodiment of the invention, the action of the active ingredient (A) according to the invention can be further increased by fatty substances (D). Fat substances are to be understood as meaning fatty acids, fatty alcohols, natural and synthetic waxes, which can be present both in solid form and in liquid form in aqueous dispersion, and natural and synthetic cosmetic oil components. Linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms can be used as fatty acids (DI). Fatty acids with 10-22 carbon atoms are preferred. Among these were, for example, to name the isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, gadacholeic acid, elaoleolearic acid, elaeanolearic acid and erucic acid and their technical mixtures, which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or in the dimerization of unsaturated fatty acids. The fatty acid cuts which are obtainable from coconut oil or palm oil are usually particularly preferred; the use of stearic acid is generally particularly preferred.

The amount used is 0.1-15% by weight, based on the total agent. The amount is preferably 0.5-10% by weight, with amounts of 1-5% by weight being very particularly advantageous.

Saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols having C ₆ -C ₃₀ , preferably C ₁₀ -C ₂₂ and very particularly preferably C ₁₂ -C ₂₂ carbon atoms are used as fatty alcohols (D2). For the purposes of the invention, for example, decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinol alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, capryl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol , as well as their Guerbet alcohols, whereby this list is meant to be exemplary and not limiting. However, the fatty alcohols are derived from preferably natural fatty acids, and it can usually be assumed that they are obtained from the esters of the fatty acids by reduction. According to the invention It is also possible to use fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® , for example Stenol ^® 1618 or Lanette ^® , for example Lanette ^® O or Lorol ^®, for example Lorol ^® C8, Lorol ^® C14, Lorol ^® C18, Lorol ^® C8-18, HD-Ocenol ^® , Crodacol ^® , e.g. Crodacol ^® CS, Novol ^® , Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or Isocarb ^® 24 is commercially available. Of course, the invention also Wollwachsalkohole as Swan ^®, Coronet ^® Fluilan ^®, for example, under the names ite Corona ^®, WI or available for purchase, can be used. The fatty alcohols are used in amounts of 0.1-30% by weight, based on the entire preparation, preferably in amounts of 0.1-20% by weight.

Solid paraffins or isoparaffms, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, walnut, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes made of PE or PP can be used according to the invention as natural or synthetic waxes (D3). Such waxes are available, for example, from Kahl & Co., Trittau. The amount used is 0.1-50% by weight, based on the total agent, preferably 0.1

- 20 wt.% »And particularly preferably 0.1 - 15 wt.% Based on the total agent.

The natural and synthetic cosmetic oil bodies (D4) which can increase the effect of the active ingredient according to the invention include, for example:

- vegetable oils. Examples of such oils are sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, parish seed oil and the liquid components of coconut oil. However, other triglyceride oils such as the liquid portions of beef tallow and synthetic triglyceride oils are also suitable. liquid paraff oils, isoparaffin oils and synthetic hydrocarbons as well as di-n-alkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms Atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-Decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether as well as di-tert-butyl ether, di-isopentyl ether, di-3-ethyl decyl ether, tert-butyl-n-octyl ether , iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether. The compounds are available as commercial products l, 3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ^® S), and di-n-octyl ether (Cetiol ^® OE) may be preferred.

Esteröle. Ester oils are understood to be the esters of C ₆ -C ₃₀ fatty acids with C ₂ -C ₃₀ fatty alcohols. The monoesters of fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid moieties in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, Isotridecan- acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, Behenic acid and erucic acid as well as their technical mixtures, which occur, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or in the dimerization of unsaturated fatty acids. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaololeyl alcohol, elaidolyl alcohol Behenyl alcohol, erucyl alcohol and brassidyl alcohol, as well as their teclinic mixtures, which occur, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxosynthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols. According to the invention, particular preference is given to isopropyl myristate (Rilanit ^® IPM), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid 2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, caprinate acrylate (Cetiol ^® LC), n-butyl stearate, olerlerucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® IPP), oleyl oleates (Cetiol ^® ), lauric acid hexyl ester (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B) . Myristyl myristate (Cetiol ^® MM), cetearyl isononanoate (Cetiol ^® SN), oleic acid decyl ester (Cetiol ^® V).

- Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecylacelate as well as diol esters such as ethylene glycol dioleate, ethylene glycol di-isotridecanoate, propylene glycol di (2 -ethylhexanoate), propylene glycol di-isostearate, propylene glycol di-pelargonate, butanediol di-isostearate, neopentyl glycol dicaprylate,

- symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example described in DE-OS 197 56 454, glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),

Trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol,

- Fatty acid partial glycerides are monoglycerides, diglycerides and their technical mixtures. When using technical products, small quantities of triglycerides may still be present due to the manufacturing process. The partial glycerides preferably follow the formula (D4-I),

I

CHO (CH ₂ CH ₂ O) _n R ² (D4-I)

CH ₂ O (CH ₂ CH ₂ O) _q R ³

in which R ¹ , R ² and R ³ independently of one another represent hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms, with the proviso that at least one of these groups represents a Acyl radical and at least one of these groups represents hydrogen. The sum (m + n + q) represents 0 or numbers from 1 to 100, preferably 0 or 5 to 25. R ¹ preferably represents an acyl radical and R ² and R ^{3 represents} hydrogen and the sum (m + n + q) is 0. Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, Petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Oleic acid monoglycerides are preferably used.

The amount of natural and synthetic cosmetic oil bodies used in the agents used according to the invention is usually 0.1-30% by weight, based on the total agent, preferably 0.1-20% by weight, and in particular 0.1-15% by weight. -%.

The total amount of oil and fat components in the agents according to the invention is usually 0.5-75% by weight, based on the total agent. Quantities of 0.5-35% by weight are preferred according to the invention.

The combination of active ingredient (A) with surfactants (E) has also proven to be advantageous. In a further preferred embodiment, the agents used according to the invention contain surfactants. The term surfactants is understood to mean surface-active substances which form adsorption layers on surfaces and interfaces or which can aggregate into micelle colloids or lyotropic mesophases in nolumen phases. A distinction is made between anionic surfactants consisting of a hydrophobic residue and a negatively charged hydrophilic head group, amphoteric surfactants, which carry both a negative and a compensating positive charge, cationic surfactants, which in addition to a hydrophobic residue have a positively charged hydrophilic group, and nonionic surfactants, which have no charges but strong dipole moments and are highly hydrated in aqueous solution. Further definitions and properties of surfactants can be found in "H.-D. Dörfler, interfacial and colloid chemistry, NCH Nerlagsgesellschaft mbH. Weinheim, 1994 ". The definition given above can be found from p. 190 in this publication.

All anionic surface-active substances suitable for use on the human body are suitable as anionic surfactants (E1) in preparations according to the invention. These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 8 to 30 carbon atoms. In addition, the molecule can contain glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts with 2 to 4 carbon atoms in the alkanol group,

- linear and branched fatty acids with 8 to 30 carbon atoms (soaps),

- Ether carboxylic acids of the formula RO- (CH2-CH2θ) _χ -CH2 "COOH, in which R is a linear

Alkyl group with 8 to 30 carbon atoms and x = 0 or 1 to 16,

Acyl sarcosides with 8 to 24 carbon atoms in the acyl group,

Acyl taurides with 8 to 24 carbon atoms in the acyl group,

Acyl isethionates with 8 to 24 carbon atoms in the acyl group,

- Monosulfonic acid and dialkyl sulfosuccinates with 8 to 24 carbon atoms in the alkyl group and mono-alkyl polyoxyethyl sulfosuccinic acid with 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups,

linear alkanesulfonates with 8 to 24 carbon atoms,

linear alpha-olefin sulfonates with 8 to 24 carbon atoms,

- Alpha-sulfofatty acid methyl esters of fatty acids with 8 to 30 carbon atoms,

Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in which R is a preferably linear alkyl group with 8 to 30 C atoms and x = 0 or 1 to 12,

Mixtures of surface-active hydroxysulfonates according to DE-A-37 25 030, sulfated hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol ethers according to DE-A-37 23 354,

Sulfonates of unsaturated fatty acids with 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344,

Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols having 8 to 22 carbon atoms,

Alkyl and / or alkenyl ether phosphates of the formula (El-I),

O

II

R ^ OCHaCHa) ,, - O _ P - OR ² (El-I) ox in R ¹ preferably for an aliphatic hydrocarbon radical with 8 to 30

Carbon atoms, R ² for hydrogen, a radical (CH ^ H _j OR ¹ or X, n for

Numbers from 1 to 10 and X for hydrogen, an alkali or alkaline earth metal or

NR ³ R ⁴ R ⁵ R ⁶ , with R ³ to R ⁶ independently of one another represent hydrogen or one

Cl to C4 - hydrocarbon radical, stands, sulfated fatty acid alkylene glycol esters of the formula (El -II)

R ⁷ CO (AlkO) _n SO ₃ M (El-II) in R ⁷ CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or

CH ₂ CHCH ₃ , n stands for numbers from 0.5 to 5 and M stands for a cation, as described in DE

OS 197 36 906.5 are described,

Monoglyceride sulfates and monoglyceride ether sulfates of the formula (EI-III)

CH ₂ O (CH ₂ CH ₂ O) _z - SO ₃ X (El-III)

in which R ⁸ CO stands for a linear or branched acyl radical with 6 to 22 carbon atoms, x, y and z in total for 0 or for numbers from 1 to 30, preferably 2 to 10, and X stands for an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates which are suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride as well as their ethylene oxide adducts or their formulas with sulfuric acid trioxide with sulfuric acid trioxide or their sulfuric acid adducts with sodium sulfate trichloride. Monoglyceride sulfates of the formula (III) are preferably used, in which R ⁸ CO represents a linear acyl radical having 8 to 18 carbon atoms, as described, for example, in EP-Bl 0 561 825, EP-Bl 0 561 999, DE-Al 42 04 700 or from AKBiswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) and FUAhmed in J.Am.Oil.Chem.Soc. 67, 8 (1990), Amidether carboxylic acids as described in EP 0 690 044,

- Condensation products from C ₈ - C ₃₀ fatty alcohols with protein hydrolyzates and / or amino acids and their derivatives, which are known to the person skilled in the art as protein fatty acid condensates, such as the Lamepon ^® types, Gluadin ^® types, Hostapon ^® KCG or the Amisoft ^® types ,

Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl ester with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, monoglycer disulfates, alkyl and alkenyl ether phosphates and protein fatty acid condensates.

Zwitterionic surfactants (E2) are surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ⁽⁾ or -SO ₃ ^(_) group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyl dimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the coconut acylaminopropyl dimethylammonium glycinate, and 2-alkyl -3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.

Ampholytic surfactants (E3) are understood to mean those surface-active compounds which, in addition to a C ₈ -C ₂₄ alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO ₃ H group in the molecule and for the formation of internal ones Salts are capable. Examples of suitable ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N- alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N- Alkyltaurines, N-alkyl sarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each with about 8 to 24 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylamino propionate and C ₁₂ -C ₁₈ acyl sarcosine.

Nonionic surfactants (E4) contain e.g. a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such connections are, for example

- Adducts of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear and branched fatty alcohols with 8 to 30 C atoms, with fatty acids with 8 to 30 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group,

- Adducts of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide end-capped with a methyl or C ₂ -C ₆ -alkyl radical to linear and branched fatty alcohols with 8 to 30 C atoms, to fatty acids with 8 to 30 C- atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as the type available under the commercial names Dehydol ^® LS, Dehydol ^® LT (Cognis),

C ₁₂ -C ₃₀ fatty acid monoesters and diesters of adducts of 1 to 30 moles of ethylene oxide with glycerol,

Adducts of 5 to 60 moles of ethylene oxide with castor oil and hardened castor oil,

- polyol, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol - types (Cognis), alkoxylated triglycerides,

alkoxylated fatty acid alkyl esters of the formula (E4-I)

R ¹ CO- (OCH ₂ CHR ² ) _w OR ³ (E4-I)

in the R'CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ² for hydrogen or methyl, R ³ for li linear or branched alkyl radicals with 1 to 4 carbon atoms and w represents numbers from 1 to 20, amine oxides,

Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters such as, for example, the polysorbates,

Sugar fatty acid esters and adducts of ethylene oxide with sugar fatty acid esters,

Addition products of ethylene oxide with fatty acid alkanolamides and fatty amines, sugar surfactants of the alkyl and alkenyl oligoglycoside type according to formula (E4-II),

R ⁴ O- [G] _p (E4-II)

in which R ^{4 is} an alkyl or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10. They can be obtained according to the relevant procedures in preparative organic chemistry. Representative of the extensive Scl rifttum is the review by Biermann et al. in Starch /force 45, 281 (1993), B. Salka in Cosm.Toil. 108, 89 (1993) and J. Kahre et al. in SÖFW-Journal Issue 8, 598 (1995).

The alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably from glucose. The preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides. The index number p in the general formula (E4-II) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10. While p in the individual molecule must always be an integer and here can assume the values p = 1 to 6, the value p for a certain alkyl oligoglycoside is an analytically determined arithmetic parameter, which usually represents a fractional number. Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, such alkyl and / or alkenyl oli- goglycosides preferred, the degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4. The alkyl or alkenyl radical R ⁴ can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capro alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from Roelen's oxosynthesis. Alkyl oligoglucosides of chain length C ₈ -C ₁₀ (DP = 1 to 3) are preferred, which are obtained as a preliminary step in the separation of technical C ₈ -C ₁₈ coconut fatty alcohol by distillation and with a proportion of less than 6% by weight of C ₁₂ - Alcohol can be contaminated and alkyl oligoglucosides based on technical C _9/11 oxo alcohols (DP = 1 to 3). The alkyl or alkenyl radical R ¹⁵ can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures, which can be obtained as described above. Alkyl oligoglucosides based on hardened C _12/14 coconut alcohol with a DP of 1 to 3 are preferred.

Sugar surfactants of the fatty acid-Ν-alkylpolyhydroxyalkylamide type, a nonionic surfactant of the formula (E4-III), R ⁶

I

R ⁵ CO-Ν- [Z] (E4-III)

in which R ⁵ CO for an aliphatic acyl radical having 6 to 22 carbon atoms, R ⁶ for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 12 carbon atoms and 3 to 10 hydroxyl groups stands. The fatty acid N-alkylpolyhydroxyalkylamides are known substances which are usually obtained by reductive amination of a reducing sugar with ammonia, one Alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride can be obtained. With regard to the processes for their production, reference is made to US Pat. Nos. 1,985,424, 2,016,962 and 2,703,798 and international patent application WO 92/06984. An overview of this topic by H. Kelkenberg can be found in Tens. Surf. Det. 25, 8 (1988). The fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose. The preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides as represented by the formula (E4-IV):

R ⁸ OH OH OH

R ⁷ CO-N-CH, -CH-CH-CH-CH-CH, OH (E4-IV)

OH

The preferred fatty acid N-alkylpolyhydroxyalkylamides used are glucamides of the formula (E4-IN) in which R ^{8 represents} hydrogen or an alkyl group and R ⁷ CO represents the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures. Fatty acid äure-alkylglucamides of the formula (E4-IV) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative are particularly preferred. Furthermore, the polyhydroxyalkylamides can also be derived from maltose and palatinose.

The preferred nonionic surfactants are the alkylene oxide adducts with saturated linear fatty alcohols and fatty acids, each with 2 to 30 moles of ethylene oxide per Mole of fatty alcohol or fatty acid has been proven. Preparations with excellent properties are also obtained if they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.

These connections are characterized by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.

Furthermore, very particularly preferred nonionic surfactants are the sugar surfactants. These can be present in the agents used according to the invention preferably in amounts of 0.1-20% by weight, based on the total agent. Amounts of 0.5-15% by weight are preferred, and amounts of 0.5-7.5% by weight are very particularly preferred.

The compounds with alkyl groups used as surfactant can each be uniform substances. However, it is generally preferred to start from natural vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.

In the case of the surfactants, which are addition products of ethylene and / or propylene oxide onto fatty alcohols or derivatives of these addition products, both products with a "normal" homolog distribution and those with a narrowed homolog distribution can be used. “Normal” homolog distribution is understood to mean mixtures of homologues which are obtained as catalysts when fatty alcohol and alkylene oxide are reacted using alkali metals, alkali metal hydroxides or alkali metal alcoholates. By contrast, narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of Ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates can be used as catalysts. The use of products with a narrow homolog distribution can be preferred.

The surfactants (E) are used in amounts of 0.1-45% by weight, preferably 0.5-30% by weight and very particularly preferably 0.5-25% by weight, based on the total agent used according to the invention ,

Cationic surfactants (E5) of the type of the quaternary ammonium compounds, the esterquats and the amidoamines can also be used according to the invention. Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. B. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, and the compounds known under the INCI names Quaternium-27 and Quaternium-83 compounds imidazolium. The long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are sold, for example, under the trademarks Stepantex ^® , Dehyquart ^® and Armocare ^® . The products Armocare ^® VGH-70, an N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80 and Dehyquart ^® AU-35 are examples of such esterquats ,

The alkylamidoamines are usually produced by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An invented According to the invention, a particularly suitable compound from this group of substances is the stearamidopropyldimethylamine commercially available under the name Tegoamid ^® S 18.

The cationic surfactants (E5) are preferably present in the agents used according to the invention in amounts of 0.05 to 10% by weight, based on the total agent. Amounts of 0.1 to 5% by weight are particularly preferred.

Anionic, nonionic, zwitterionic and / or amphoteric surfactants and mixtures thereof can be preferred according to the invention.

In a further preferred embodiment, the action of the active ingredient according to the invention can be increased by emulsifiers (F). Emulsifiers cause water or oil-stable adsorption layers to form at the phase interface, which protect the dispersed droplets against coalescence and thus stabilize the emulsion. Like surfactants, emulsifiers are therefore made up of a hydrophobic and a hydrophilic part of the molecule. Hydrophilic emulsifiers preferably form O / W emulsions and hydrophobic emulsifiers preferably form W / O

- emulsions. An emulsion is to be understood as a droplet-like distribution (dispersion) of a liquid in another liquid with the expenditure of energy in order to create stabilizing phase interfaces by means of surfactants. The selection of these emulsifying surfactants or emulsifiers is based on the substances to be dispersed and the particular external phase as well as the fine particle size of the emulsion. Further definitions and properties of emulsifiers can be found in “H. -D.Dörfler, interfacial and colloid chemistry, VCH Verlagsgesellschaft mbH. Weinheim, 1994 ". Emulsifiers which can be used according to the invention are, for example

Addition products of 4 to 30 mol of ethylene oxide and / or 0 to 5 mol of propylene oxide with linear fatty alcohols with 8 to 22 C atoms, with fatty acids with 12 to 22 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group,

C ₁₂ -C ₂₂ fatty acid monoesters and diesters of addition products of 1 to 30 moles of ethylene oxide with polyols with 3 to 6 carbon atoms, in particular with glycerol, - Ethylene oxide and polyglycerol adducts with methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,

C ₈ -C ₂₂ alkyl mono- and oligoglycosides and their ethoxylated analogs, degrees of oligomerization from 1.1 to 5, in particular 1.2 to 2.0, and glucose as the sugar component being preferred,

Mixtures of alkyl (oligo) glucosides and fatty alcohols, for example the commercially available product Montanov ^® 68,

Adducts of 5 to 60 moles of ethylene oxide with castor oil and hardened castor oil,

Partial esters of polyols with 3-6 carbon atoms with saturated fatty acids with 8 to 22 C atoms,

Sterols. Sterols are understood to be a group of steroids which carry a hydroxyl group on the C atom 3 of the steroid structure and which are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Sterols, the so-called mycosterols, are also isolated from fungi and yeasts.

Phospholipids. These include primarily the glucose phospholipids, e.g. as lecithins or phosphatidylcholines from e.g. Egg yolks or plant seeds (e.g. soybeans) are understood.

Fatty acid esters of sugars and sugar alcohols, such as sorbitol,

- polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hy- droxystearat (Dehymuls ^® PGPH commercial product)

- Linear and branched fatty acids with 8 to 30 C atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The compositions according to the invention preferably contain the emulsifiers in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total composition.

The compositions according to the invention can preferably contain at least one non-ionic emulsifier with an HLB value of 8 to 18, according to those in the Römpp lexicon Chemistry (Ed. J. Falbe, M. Regitz), 10th edition, Georg Thieme Verlag Stuttgart, New York, (1997), page 1764, contain the definitions listed. Nonionic emulsifiers with an HLB value of 10-15 can be particularly preferred according to the invention.

It has also proven to be advantageous that polymers (G) can support the action of the active ingredient (A) according to the invention. In a preferred embodiment, polymers are therefore added to the agents used according to the invention, both cationic, anionic, amphoteric and nonionic polymers having proven to be effective.

Cationic polymers (G1) are understood to mean polymers which have a group in the main and / or side chain which can be “temporary” or “permanent” cationic. According to the invention, "permanently cationic" refers to those polymers which have a cationic group regardless of the pH of the agent. These are generally polymers which contain a quaternary nitrogen atom, for example in the form of an ammonium group. Preferred cationic groups are quaternary ammonium groups Polymers in which the quaternary ammonium group is bonded via a Cl-4 hydrocarbon group to a polymer main chain composed of acrylic acid, methacrylic acid or their derivatives have proven to be particularly suitable.

Homopolymers of the general Fonnel (Gl-I), R ¹

I - [CH ₂ -C-] _n X- (Gl-I)

I CO-O- (CH ₂ ) _m -N ⁺ R ² R ³ R ⁴

in which R ^{1 =} -H or -CH ₃ , R ² , R ³ and R ^{4 are} independently selected from Cl-4-alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4, na natural Number and X ^"is a physiologically compatible organic or inorganic anion, and copolymers consisting essentially of the monomer units listed in formula (Eq-I) and nonionic monomer units are particularly preferred cationic polymers. Within the scope of these polymers, those preferred according to the invention are those for the at least one of the following conditions applies: R ¹ stands for a methyl group R ² , R ³ and R ⁴ stand for methyl groups m has the value 2.

Suitable physiologically compatible counterions X ^" are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Halide ions, in particular chloride, are preferred.

A particularly suitable homopolymer is, if desired crosslinked, poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37. If desired, the crosslinking can be carried out with the aid of polyolefinically unsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylene bisacrylamide, diallyl ether, polyallyl polyglyceryl ether, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylene bisacrylamide is a preferred wetting agent.

The homopolymer is preferably used in the form of a non-aqueous polymer dispersion which should not have a polymer content below 30% by weight. Such polymer dispersions are available under the names Salcare ^® SC 95 (approx. 50%> polymer content, further components: mineral oil (IΝCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene ether (IΝCI name: PPG-l-Trideceth -6)) and Salcare ^® SC 96 (approx. 50% polymer content, further components: mixture of diesters of propylene glycol with a mixture of caprylic and capric acid (IΝCI name: Propylene Glycol Dicaprylate / Dicaprate) and tridecyl-polyoxypropylene-polyoxyethylene- ether (IΝCI name: PPG-l-trideceth-6)) commercially available. Copolymers with monomer units of the formula (Gl-I) preferably contain, as nonionic monomer units, acrylamide, methacrylamide, acrylic acid-C _M alkyl ester and methacrylic acid-C 1-4 alkyl ester. Among these nonionic monomers, acrylamide is particularly preferred. As in the case of the homopolymers described above, these copolymers can also be crosslinked. A preferred copolymer according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium cliloride copolymer. Such copolymers in which the monomers are present in a weight ratio of about 20:80, commercially available as about 50% non-aqueous polymer dispersion under the name Salcare ^® SC 92nd

Other preferred cationic polymers are, for example, quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially. The compounds Celquat ^® H 100, Celquat ^® L 200 and Polymer JR ^® 400 are preferred quaternized cellulose derivatives,

cationic alkyl polyglycosides according to DE-PS 44 13 686,

cationized honey, for example the commercial product Honeyquat ^® 50,

cationic guar derivatives, such as, in particular, the products marketed under the trade names Cosmedia ^® Guar and Jaguar ^® ,

- polysiloxanes with quaternary groups, such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized Trimethylsilylamo- dimethicone), Dow Corning ^® 929 Emulsion (containing a hydroxylamino-modi fied silicone, which is also known as amodimethicone ), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt), diquaternary polydimethylsiloxanes, Quaternium-80),

- Polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid. The products commercially available under the names Merquat ^® 100 (poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers, - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as, for example, vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the names Gafquat ^® 734 and Gafquat ^® 755,

- vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552, quaternized polyvinyl alcohol,

- And the known under the names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 polymers with quaternary nitrogen atoms in the main polymer chain.

Can be used as cationic polymers (. B. commercial product, Quatrisoft ^® LM 200) under the designations Polyquaternium-24, known polymers. Likewise usable according to the invention are the copolymers of vinyl pyrrolidone, as are available as commercial products Copolymer 845 (manufacturer: ISP), Gaffix ^® NC 713 (manufacturer: ISP), Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 are.

Other cationic polymers of the invention are the "temporarily cationic" polymers. These polymers usually contain an amino group present at certain pH values as a quaternary ammonium group and thus cationic are preferred, for example, chitosan and its derivatives, such as, for example, under the trade designations Hydagen ^®. CMF, Hydagen ^® HCMF, Kytamer ^® PC and Chitolam ^® ΝB / 101 are freely available commercially.

According to the invention preferred cationic polymers are cationic cellulose derivatives and chitosan and its derivatives, in particular the commercial products Polymer ^® JR 400, Hydagen ^® HCMF and Kytamer ^® PC, cationic guar derivatives, cationic honey derivatives, in particular the commercial product Honeyquat ^® 50, cationic Alkylpolyglycodside according to DE-PS 44 13 686 and polymers of the type Polyquaternium-37. Furthermore, cationized protein hydrolyzates are to be counted among the cationic polymers, the underlying protein hydrolyzate being derived from animals, for example from collagen, milk or keratin, from plants, for example from wheat, corn, rice, potatoes, soy or almonds, from marine life forms, for example from fish collagen or algae, or biotechnologically obtained protein hydrolyzates. The protein hydrolysates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acidic hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis. The hydrolysis of proteins usually results in a protein hydrolyzate with a molecular weight distribution of approximately 100 daltons up to several thousand daltons. Preferred cationic protein hydrolyzates are those whose underlying protein content has a molecular weight of 100 to 25,000 Daltons, preferably 250 to 5000 Daltons. Cationic protein hydrolyzates also include quaternized amino acids and their mixtures. The quaternization of the protein hydrolyzates or the amino acids is often carried out using quaternary ammonium salts such as, for example, N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides. Furthermore, the cationic protein hydrolyzates can also be further derivatized. Typical examples of the cationic protein hydrolyzates and derivatives according to the invention are those under the INCI names in the "International Cosmetic Ingredient Dictionary and Handbook" (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 * Street, NW, Suite 300 , Washington, DC 20036-4702) and commercially available products: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk A ino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HC1, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Ca be hydroxypropyltri- monium hydrolyzed collagen, hydroxypropyltrimonium hydrolyzed conchiolin protein, hydroxypropyltrimonium hydrolyzed keratin, hydroxypropyltrimonium hydrolyzed rice branch protein, hydroxyproypltrimonium hydrolyzed silk, hydroxypropyltrimonium hydrolyzed soy protein, hydroxypropyl hydrolyzed hydrolyzed wheat protein, hydroxypropyltrimonium hydrolyzed wheatonate protein, hydroxypropyltrimonium hydrolyzed wheatonate protein Soy Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein / Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzedium Sodium, Lauryldimonium Hydroxypropyl Hydrolyzedium Hydrolyzed collagen, steardimonium hydroxypropyl Hydrolyzed keratin, steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Negetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartrimonium Hydroxyethyl Hydrolyzed Collagen, Quaternium-76 Hydrolyzed-Collagen 79, Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 , Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein.

The cationic protein hydrolysates and derivatives based on plants are very particularly preferred.

The anionic polymers (G2), which can support the action of the active ingredient (A) according to the invention, are anionic polymers which have carboxylate and / or sulfonate groups. Examples of anionic monomers from which such polymers can consist are acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups can be wholly or partly as sodium, potassium, ammonium, Mono- or triethanolammom ^' um salt are present. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer have proven to be very particularly effective, it being possible for the sulfonic acid group to be present in whole or in part as the sodium, potassium, ammonium, mono- or triethanolammonium salt ,

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid is obtainable for example under the name Rheothik ^® 11-80 commercially.

In this embodiment, it may be preferred to use copolymers of at least one anionic monomer and at least one nonionic monomer. With regard to the anionic monomers, reference is made to the substances listed above. Preferred nonionic monomers are acrylamide, methacrylamide, acrylic acid ester, methacrylic acid ester, vinyl pyrrolidone, vinyl ether and vinyl ester.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with monomers containing sulfonic acid groups. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, the sulfonic acid group being wholly or partly as sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer can also be crosslinked, the crosslinking agents used preferably being polyolefinically unsaturated compounds such as tetraallyloxyethane, allyl sucrose, allylpentaerythritol and methylene bisacrylamide. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. The use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ₁₃ -C ₁₄ isoparaffin) and a nonionic emulsifier (Laureth-7), has proven to be particularly advantageous in the context of the teaching according to the invention. Also, as a compound with isohexadecane and sold under the name Simulgel ^® 600 Polysorbate-80 sodium acryloyldimethyltaurate copolymers have proven effective as in the present invention particularly.

Also preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. AUyl ethers of pentaerythritol, sucrose and propylene can be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-preserving polymers. A cross-linked with 1,9-decadiene maleic acid-methyl vinyl ether copolymer is available under the name Stabileze® ^® QM.

Furthermore, amphoteric polymers (G3) can be used as polymers to increase the action of the active ingredient (A) according to the invention. The term amphoteric polymers includes both those polymers which contain both free amino groups and free -COOH or SO ₃ H groups in the molecule and are capable of forming internal salts, and also zwitterionic polymers which contain quaternary ammonium groups and -COO in the molecule Contain ^" - or -SO ₃ ^" groups, and summarize those polymers which contain -COOH or SO ₃ H groups and quaternary ammonium groups.

An example of the present invention amphopolymer suitable is that available under the name Amphomer ^® acrylic resin which is a copolymer of ethyl methacrylate tert-butylamino, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group Acrylic acid, methacrylic acid and their simple esters.

Further amphoteric polymers which can be used according to the invention are those described in British Offenlegungsschrift 2 104 091, European Offenlegungsschrift 47 714, the European European Patent Application 217 274, European Patent Application 283 817 and German Patent Application 28 17 369.

Amphoteric polymers used with preference are those polymers which essentially consist of one another

(a) Monomers with quaternary ammonium groups of the general formula (G3-I), R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ° (G3- I) in which R ¹ and R ² independently of one another represent hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A is the anion of an organic or inorganic acid, and

(b) monomeric carboxylic acids of the general formula (G3-II), R ⁶ -CH = CR ⁷ -COOH (G3-II) in which R ⁶ and R ^{7 are} independently hydrogen or methyl groups.

According to the invention, these compounds can be used both directly and in salt form, which is obtained by neutralizing the polymers, for example with an alkali metal hydroxide. With regard to the details of the preparation of these polymers, reference is expressly made to the content of German laid-open specification 39 29 973. Those polymers in which monomers of type (a) are used, in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and A ^{Θ is} a halide, methoxysulfate or ethoxysulfate ion, are very particularly preferred ; Acrylamido-propyl-trimethyl-ammonium chloride is a particularly preferred monomer (a). Acrylic acid is preferably used as monomer (b) for the polymers mentioned.

In a further embodiment, the agents according to the invention can contain nonionic polymers (G4).

Suitable nonionic polymers are, for example:

Vinylpyrrolidone / Vinylester copolymers, as are marketed, for example under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.

Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropylcellulose, as they are for example sold under the trademark Culminal® ^® and Benecel ^® (AQUALON). Polyvinylpyrrolidones, as are marketed under the name Luviskol ^® (BASF) - shellac.

Siloxanes. These siloxanes can be both water-soluble and water-insoluble. Both volatile and non-volatile siloxanes are suitable, non-volatile siloxanes being understood to mean those compounds whose boiling point at normal pressure is above 200 ° C. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups. Glycosidically substituted silicones according to EP 0612759 B1.

It is also possible according to the invention that the preparations used contain several, in particular two different polymers of the same charge and / or each contain an ionic and an amphoteric and / or non-ionic polymer.

The polymers (G) are preferably present in the agents used according to the invention in amounts of 0.05 to 10% by weight, based on the total agent. Amounts from 0.1 to 5, in particular from 0.1 to 3% by weight are particularly preferred.

Protein hydrolyzates and / or amino acids and their derivatives (H) may also be present in the preparations used according to the invention. Protein hydrolyzates are product mixtures that are obtained by acidic, basic or enzymatically catalyzed breakdown of proteins (proteins). According to the invention, the term protein hydrolyzates also includes total hydrolyzates and individual amino acids and their derivatives, as well as mixtures of different amino acids Roger that. According to the invention, polymers constructed from amino acids and amino acid derivatives are furthermore to be understood under the term protein hydrolyzates. The latter include, for example, polyalanine, polyasparagine, polyserine, etc. Further examples of compounds which can be used according to the invention are L-alanyl-L-proline, polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride. Of course, ß-amino acids and their derivatives such as ß-alanine, anthranilic acid or hippuric acid can also be used according to the invention. The molecular weight of the protein hydrolyzates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.

According to the invention, protein hydrolyzates of plant, animal, marine or synthetic origin can be used.

Animal protein hydrolyzates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolyzates, which can also be in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois ^® (Interorgana), Collapuron ^® (Cognis), Nutrilan ^® (Cognis), Gelita-Sol ^® (Deutsche Gelatine Fabriken Stoess & Co), Lexein ^® (Inolex) and Kerasol ^® (Croda) expelled.

According to the invention, the use of protein hydrolysates of plant origin, e.g. B. soy, almond, pea, potato and wheat protein hydrolyzates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), DiaMin ^® (Diamalt), Lexein ^® (Inolex), Hydrosoy ^® (Croda), Hydrolupin ^® (Croda), Hydrosesame ^® (Croda), Hydrotritium ^® (Croda) and Crotein ^® (Croda) available.

Although the use of the protein hydrolyzates as such is preferred, amino acid mixtures obtained in some other way can optionally be used in their place. It is also possible to use derivatives of the protein hydrolyzates, for example in the form of their fatty acid condensation products. Such products are, for example sold under the names Lamepon ^® (Cognis), Lexein ^® (Inolex), Crolastin ^® (Croda) or Crotein ^® (Croda).

The protein hydrolyzates or their derivatives are contained in the agents used according to the invention preferably in amounts of 0.1 to 10% by weight, based on the total agent. Amounts of 0.1 to 5% by weight are particularly preferred.

Furthermore, in a preferred embodiment of the invention, the action of the active ingredients (A) can be increased by UV filters (I). The structure and physical properties of the UV filters to be used according to the invention are not subject to any general restrictions. Rather, all UV filters that can be used in the cosmetics sector are suitable, the absorption maximum of which lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC (<280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from approximately 280 to approximately 300 nm, are particularly preferred.

The UN filters used according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.

Examples of UN filters which can be used according to the invention are 4-amino-benzoic acid, Ν, Ν, Ν-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methyl sulfate, 3, 3, 5-trimethyl-cyclohexyl salicylate (homosalates ), 2-Hydroxy-4-methoxy-benzophenone (Benzophenone-3; Uvinul ^® M 40, Uvasorb ^® MET, Neo Heliopan ^® BB, Eusolex ^® 4360), 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and Triethanolamine salts (phenylbenzimidazole sulfonic acid; Parsol ^® HS; Neo Heliopan ^® Hydro), 3,3 '- (1,4-phenylenedimethylene) - bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept-l-yl-methane-sulfonic acid) and salts thereof, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-l, 3-dione (butyl methoxydibenzoyl- methane; Parsol ^® 1789 Eusolex ^® 9020), α- (2-oxoborn-3-ylidene) toluene-4-sulfonic acid and its salts, ethyl ethoxylated 4-aminobenzoate (PEG-25 PABA; Uvinul ^® P 25), 4-dimethylaminobenzoic acid 2- ethylhexyl ester (octyl dimethyl PABA; Uvasorb ^® DMO, Escalol ^® 507, Eusolex ^® 6007), salicylic acid 2-ethylhexyl ester (octyl salicylate; Escalol ^® 587, Neo Heliopan ^® OS, Uvinul ^® O18), 4-methoxycinnamic acid isopentyl ester (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000 ), 2-ethylhexyl 4-methoxycinnamate (octyl methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan ^® AV), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb ^® S 5), 3- (4'-methylbenzylidene) -D, L-camphor (4-methylbenzylidene camphor; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene cam - Phor), 4-isopropylbenzyl salicylate, 2,4,6-trianilino- (p-carbo-2'-ethylhexyl-oxi) -l, 3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester , Polymers of N - {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl} acrylamide, 2,4-dihydroxybenzophenone (benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400), l, -Diphenylacrylonitrilsäure-2-ethylhexyl ester (Octocrylene; Eusolex ^® OCR, Neo Heliopan Type 303, Uvinul ^® N 539 SG), o-aminobenzoic benzoic acid menthyl (Menthyl Anthranilate; Neo Heliopan ^® MA), 2,2 ', 4,4'-tetrahydroxybenzophenone (Benzophenone-2; Uvinul ^® D-50), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (Benzophenone-6 ), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate and 2-cyano-3,3-diphenylacrylic acid 2'-ethylhexyl ester. 4-Amino-benzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methyl sulfate, 3,3,5-trimethyl-cyclohexylsalicylate, 2-hydroxy-4-methoxy-benzophenone are preferred , 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxobicyclo- [2.2. 1] hept-l-yl-methanesulfonic acid) and its salts, l- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione, - (2-oxoborn -3-ylidene) -toluene-4-sulfonic acid and its salts, ethoxylated ethyl 4-aminobenzoate, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 4-methoxycinnamate 2-ethylhexyl ester, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-methylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzylsalicylate, 2, 4,6-tri-anilino- (p-carbo-2'-ethylhexyl-oxi) -l, 3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N- { (2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl} acrylamide. According to the invention, 2-hydroxy-4-methoxy-benzophenone, 2-phenylbenzimidazole-5-sulfonic acid and their potassium, sodium and triethyl hanolamine salts, 1 - (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1, 3-dione, 4-methoxycinnamic acid 2-ethylhexyl ester and 3- (4 '-methylbenzylidene) - D, L-camphor.

Preferred UV filters are those whose molar extinction coefficient at the absorption maximum is above 15,000, in particular above 20,000.

Furthermore, it was found that in structurally similar UN filters, the water-insoluble compound has, in the context of the teaching according to the invention, the higher activity compared to those water-soluble compounds which differ from it by one or more additional ionic groups. Within the scope of the invention, water-insoluble UV filters are understood to be those which do not never dissolve 1% by weight, in particular not more than 0.1% by weight, in water at 20 ° C. Furthermore, these compounds should be at least 0.1, in particular at least 1% by weight soluble in conventional cosmetic oil components at room temperature). The use of water-insoluble UN filters can therefore be preferred according to the invention.

According to a further embodiment of the invention, such UN filters are preferred which have a cationic group, in particular a quaternary ammonium group.

These UN filters have the general structure U - Q.

The structural part U stands for a UN radiation-absorbing group. In principle, this group can be derived from the known UN filters mentioned above, which can be used in the cosmetics sector, in which a group, usually a hydrogen atom, of the UN filter is replaced by a cationic group Q, in particular with a quaternary amino function. is replaced. Connections from which the structural part U can be derived are, for example

- substituted benzophenones,

p-aminobenzoic acid esters, diphenylacrylic acid esters,

- cinnamic acid esters, salicylic acid,

- benzimidazoles and

o-aminobenzoic acid esters.

Structural parts U which are derived from cinnamic acid amide or from N, N-dimethylamino-benzoic acid amide are preferred according to the invention.

The structural parts U can in principle be chosen so that the absorption maximum of the UV filter can be both in the UVA (315-400 nm) and UVB (280-315 nm) or in the UVC (<280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from approximately 280 to approximately 300 nm, are particularly preferred.

Furthermore, the structural part U, also depending on the structural part Q, is preferably chosen such that the molar extinction coefficient of the UV filter at the absorption maximum is above 15,000, in particular above 20,000.

The structural part Q preferably contains a quaternary ammonium group as the cationic group. In principle, this quaternary ammonium group can be directly connected to the structural part U, so that the structural part U is one of the four substituents of the positively charged nitrogen atom. However, one of the four substituents on the positively charged nitrogen atom is preferably a group, in particular an alkylene group having 2 to 6 carbon atoms, which functions as a connection between the structural part U and the positively charged nitrogen atom.

Advantageously, the group Q has the general structure - (CH ₂ ) _X -N ⁺ R ¹ R ² R ³ X ^" , in which x represents an integer from 1 to 4, R ¹ and R ² independently of one another represent C _M ~ Alkyl groups, R ³ stands for a C _{1, 22} alkyl group or a benzyl group and X ^" for a physiologically compatible anion. In the context of this general structure, x preferably represents the number 3, R ¹ and R ² each represents a methyl group and R ³ either represents one Methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain with 8 to 22, in particular 10 to 18, carbon atoms.

Physiologically compatible allions are, for example, inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions, and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid-trimethylammonium chloride (quat Incro- ^® UN-283), and dodecyl tosylate (Escalol ^® HP 610).

Of course, the teaching of the invention also includes the use of a combination of several UV filters. In the context of this embodiment, the combination of at least one water-insoluble UN filter with at least one UV filter with a cationic group is preferred.

The UV filters (I) are usually contained in the agents used according to the invention in amounts of 0.1-5% by weight, based on the total agent. Amounts of 0.4-2.5% by weight are preferred.

The activity of the active ingredient (A) according to the invention can be further increased by a 2-pyrrolidinone-5-carboxylic acid and its derivatives (J). Another object of the invention is therefore the use of the active ingredient in combination with derivatives of 2-pyrrolidinone-5-carboxylic acid. The sodium, potassium, calcium, magnesium or ammonium salts are preferred, in which the ammonium ion carries one to three C _r to C ₄ alkyl groups in addition to hydrogen. The sodium salt is very particularly preferred. The amounts used in the agents according to the invention are 0.05 to 10% by weight, based on the total agent, particularly preferably 0.1 to 5 and in particular 0.1 to 3% by weight. The combination of active ingredient (A) with vitamins, provitamins and vitamin precursors and their derivatives (K) has also proven to be advantageous.

Vitamins, pro-vitamins and vitamin precursors which are usually assigned to groups A, B, C, E, F and H are preferred according to the invention.

The group of substances called vitamin A includes retinol (vitamin A,) and 3,4-didehydroretinol (vitamin A ₂ ). The ß-carotene is the provitamin of retinol. According to the invention, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate come into consideration as vitamin A components. The preparations used according to the invention preferably contain the vitamin A component in amounts of 0.05-1% by weight, based on the entire preparation.

The vitamin B group or the vitamin B complex include u. a.

- Vitamin B _λ (thiamine)

- Vitamin B ₂ (riboflavin)

- Vitamin B ₃ . The compounds nicotinic acid and nicotinamide (niacinamide) are often listed under this name. According to the invention, preference is given to nicotinic acid amide, which is preferably present in the agents used according to the invention in amounts of 0.05 to 1% by weight, based on the total agent.

- Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Within this group, panthenol and / or pantolactone is preferably used. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate and the cationic panthenol derivatives disclosed in WO 92/13829. The compounds of the vitamin B ₅ type mentioned are preferably present in the agents used according to the invention in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5% by weight are particularly preferred. - Vitamin B ₆ (pyridoxine as well as pyridoxamine and pyridoxal).

Vitamin C (ascorbic acid). Vitamin C is used in the agents used according to the invention preferably in amounts of 0.1 to 3% by weight, based on the total agent. Use in the form of the palmitic acid ester, the glucosides or phosphates can be preferred. Use in combination with tocopherols may also be preferred.

Vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, which include in particular the esters such as acetate, nicotinate, phosphate and succinate, are preferably present in the agents used according to the invention in amounts of 0.05-1% by weight, based on the total agent ,

Vitamin F. The term “vitamin F” usually means essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

Vitamin H. The compound (3aS, 4S, 6aR) -2-oxohexa- hydrotlionienol [3,4-rf] imidazole-4-valeric acid is referred to as vitamin H, but for which the trivial name biotin has now become established. Biotin is contained in the agents used according to the invention preferably in amounts of 0.0001 to 1.0% by weight, in particular in amounts of 0.001 to 0.01% by weight.

The agents used according to the invention preferably contain vitamins, provitamins and vitamin precursors from groups A, B, E and H.

Panthenol, pantolactone, pyridoxine and its derivatives as well as nicotinamide and biotin are particularly preferred.

Finally, the effect of the active ingredient (A) can also be increased by the combined use with plant extracts (L). These extracts are usually produced by extracting the entire plant. In individual cases, however, it may also be preferred to produce the extracts exclusively from flowers and / or leaves of the plant.

With regard to the plant extracts which can be used according to the invention, reference is made in particular to the extracts which are listed in the table beginning on page 44 of the 3rd edition of the guide to the declaration of ingredients of cosmetic products, published by the Industry Association for Personal Care and Detergents (IKW), Frankfurt.

According to the invention, the extracts from green tea, oak bark, nettle, witch hazel, hops, henna, chamomile, burdock root, horsetail, hawthorn, linden flowers, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime , Wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, cuckoo flower, quendel, yarrow, thyme, lemon balm, hake, coltsfoot, marshmallow, meristem, ginseng and ginger root preferred.

The extracts from green tea, oak bark, nettle, witch hazel, hops, chamomile, burdock root, horsetail, linden flowers, almond, aloe vera, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, are particularly preferred. Rosemary, birch, cuckoo flower, quendel, yarrow, harrow, meristem, ginseng and ginger root.

The extracts from green tea, almond, aloe vera, coconut, mango, apricot, lime, wheat, kiwi and melon are particularly suitable for the use according to the invention.

Water, alcohols and mixtures thereof can be used as extractants for the production of the plant extracts mentioned. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant and in Mix with water, preferred. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.

According to the invention, the plant extracts can be used both in pure and in diluted form. If they are used in dilute form, they usually contain about 2 to 80% by weight of active substance and, as a solvent, the extractant or mixture of extractants used in their extraction.

Furthermore, it may be preferred to use mixtures of several, in particular two, different plant extracts in the agents according to the invention.

In addition, it can prove to be advantageous if, in addition to the active ingredient (A) according to the invention, penetration aids and / or swelling agents (M) are present. These include, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example propylene glycol monoethyl ether, carbonates, hydrogen carbonates, hydrogen carbonates Diols and triols, and in particular 1,2-diols and 1,3-diols such as, for example, 1,2-propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1 , 6-hexanediol, 1,5-pentanediol, 1,4-butanediol.

Advantageously in the sense of the invention, short-chain carboxylic acids (N) can additionally support the restructuring of the active ingredient (A). Short-chain carboxylic acids and their derivatives in the context of the invention are understood to mean carboxylic acids which can be saturated or unsaturated and / or straight-chain or branched or cyclic and / or aromatic and / or heterocyclic and have a molecular weight of less than 750. For the purposes of the invention, preference may be given to saturated or unsaturated straight-chain or branched carboxylic acids with a chain length of 1 to 16 carbon atoms in the chain, very particularly preferred are those with a chain length of 1 to 12 carbon atoms in the chain. The short-chain carboxylic acids in the sense of the invention can have one, two, three or more carboxy groups. For the purposes of the invention, preference is given to carboxylic acids with meleric carboxy groups, in particular di- and tricarboxylic acids. The carboxy groups can be present in whole or in part as an ester, acid anhydride, lactone, amide, imidic acid, lactam, lactim, dicarboximide, carbohydrazide, hydrazone, hydroxam, hydroxime, amidine, amidoxime, nitrile, phosphonic or phosphate ester. The carboxylic acids according to the invention can of course be substituted along the carbon chain or the ring structure. The substituents of the carboxylic acids according to the invention include, for example, Cl-C8-alkyl, C2-C8-alkenyl, aryl, aralkyl and aralkenyl, hydroxymethyl, C2-C8-hydroxyalkyl, C2-C8-hydroxyalkenyl,

Aminomethyl, C2-C8-aminoalkyl, cyano, formyl, oxo, thioxo, hydroxy, mercapto, amino, carboxy or imino groups. Preferred substituents are C1-C8 alkyl, hydroxymethyl, hydroxyl, amino and carboxy groups. Substituents in the α position are particularly preferred. Very particularly preferred substituents are hydroxyl, alkoxy and amino groups, where the amino function can optionally be further substituted by alkyl, aryl, aralkyl and / or alkenyl radicals. Furthermore, preferred carboxylic acid derivatives are the phosphonic and phosphate esters.

Examples of carboxylic acids according to the invention are formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, pivalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, glyceric acid, glyoxylic acid, adipic acid, pimelic acid, suberic acid, propelic acid, sebacic acid, sebacic acid, sebacic acid - acid, isocrotonic acid, elaidic acid, maleic acid, fumaric acid, muconic acid, citraconic acid, mesaconic acid, camphoric acid, benzoic acid, o, m, p-phthalic acid, naphthoic acid, toluoyl acid, hydratropic acid, atropic acid, cinnamic acid, isonicotinic acid, nicotinic acid, bicarbamic acid, bicarboxylic acid, Dicyano-6,6'-binicotinic acid, 8-

Carbamoyloctanoic acid, 1,2,4-pentane tricarboxylic acid, 2-pyrrolecarboxylic acid, 1,2,4,6,7-naphthalene pentaacetic acid, malonaldehyde acid, 4-hydroxy-phthalamic acid, 1-pyrazole carboxylic acid, gallic acid or propane tricarboxylic acid, a dicarboxylic acid selected from the group consisting of is formed by compounds of the general formula (NI),

in the Z stands for a linear or branched alkyl or alkenyl group with 4 to 12 carbon atoms, n for a number from 4 to 12 and one of the two groups X and Y for a COOH group and the other for hydrogen or a methyl or Ethyl radical, dicarboxylic acids of the general formula (NI) which additionally carry 1 to 3 methyl or ethyl substituents on the cyclohexene ring and dicarboxylic acids which formally form from the dicarboxylic acids of the formula (NI) by addition of a molecule of water to the double bond in the cyclohexene ring.

Dicarboxylic acids of the formula (N-I) are known in the literature.

A manufacturing process can be found, for example, in US Pat. No. 3,753,968. German patent specification 22 50 055 discloses the use of these dicarboxylic acids in liquid soap compositions. From German published patent application 28 33 291 deodorising agents are known which contain zinc or magnesium salts of these dicarboxylic acids. Finally, from German Offenlegungsschrift 35 03 618 agents for washing and rinsing the hair are known, in which the addition of these dicarboxylic acids gives a noticeably improved hair cosmetic effect of the water-soluble ionic polymers contained in the agent. Finally, means for hair treatment are known from German published patent application 197 54 053, which have nourishing effects.

The dicarboxylic acids of the formula (NI) can be prepared, for example, by reacting polyunsaturated dicarboxylic acids with unsaturated monocarboxylic acids in the form of a Diels-Alder cyclization. A polyunsaturated fatty acid will usually be used as the dicarboxylic acid component. The linoleic acid accessible from natural fats and oils is preferred. As a monocarboxylic acid component acrylic acid are particularly preferred, but also, for example, methacrylic acid and crotonic acid. Diels-Alder reactions usually produce mixtures of isomers in which one component is present in excess. According to the invention, these isomer mixtures can be used just like the pure compounds.

In addition to the preferred dicarboxylic acids of the formula (NI), those dicarboxylic acids which differ from the compounds of the formula (NI) by 1 to 3 methyl or ethyl substituents on the cyclohexyl ring or formally from these compounds by addition of one molecule of water can also be used according to the invention to form the double formation of the cyclohexene ring.

The dicarboxylic acid (mixture) which results from the reaction of linoleic acid with acrylic acid has proven to be particularly effective according to the invention. It is a mixture of 5- and 6-carboxy-4-hexyl-2-cyclohexen-l-octanoic acid. Such compounds are commercially available under the designations Westvaco Diacid 1550 Westvaco Diacid ^{® ®} 1595 (manufacturer: Westvaco).

In addition to the short-chain carboxylic acids themselves according to the invention, which have been exemplified above, their physiologically tolerable salts can also be used according to the invention. Examples of such salts are the alkali, alkaline earth, zinc and ammonium salts, which in the context of the present application are also to be understood as the mono-, di- and trimethyl-, -ethyl- and -hydroxyethyl-A monium salts. However, acids which are neutralized with alkaline amino acids, such as arginine, lysine, ornithine and histidine, can very particularly preferably be used in the context of the invention. For formulation reasons, it may furthermore be preferred to select the carboxylic acid from the water-soluble representatives, in particular the water-soluble salts.

Furthermore, it is preferred according to the invention to combine hydroxycarboxylic acids, in particular the dihydroxy, trihydroxy and polyhydroxycarboxylic acids and also the dihydroxy, trihydroxy and polyhydroxydi, tri and polycarboxylic acids to use the active ingredient (A). It has been shown here that, in addition to the hydroxycarboxylic acids, the hydroxycarboxylic acid esters and the mixtures of hydroxycarboxylic acids and their esters as well as polymeric hydroxycarboxylic acids and their esters can be very particularly preferred. Preferred hydroxycarboxylic acid esters are, for example, full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid. Other basically suitable hydroxycarboxylic acid esters are esters of β-hydroxypropionic acid, tartronic acid, D-gluconic acid, sugar acid, mucic acid or glucuronic acid. Suitable alcohol components of these esters are primary, linear or branched aliphatic alcohols with 8-22 carbon atoms, for example fatty alcohols or synthetic fatty alcohols. The esters of C12-C15 fatty alcohols are particularly preferred. Esters of this type are commercially available, eg under the trademark Cosmacol® ^® EniChem, Augusta Industriale. Particularly preferred polyhydroxy polycarboxylic acids are polylactic acid and poly-tartaric acid and their esters.

In principle, the active ingredient (A) according to the invention can be added directly to the colorant, the waving agent or the fixation. However, the restructuring active ingredient can also be applied to the keratin fiber in a separate step, either before or after the actual dyeing or corrugating process. The teaching according to the invention also encompasses separate treatments, possibly even days or weeks before or after the hair treatment, for example by dyeing or waving. However, the active ingredient according to the invention can preferably be used after the corresponding hair treatment, such as dyeing or waving, in particular in the corresponding hair treatment compositions.

The term dyeing process includes all processes known to the person skilled in the art, in which a dye is applied to the optionally moistened hair and either left on the hair for a time between a few minutes and about 45 minutes and then with water or a surfactant-containing agent is rinsed out or left entirely on the hair. In this context it is expressly referred to the known monographs, e.g. BKH Schrader, basics and recipes of the Cosmetics, 2nd edition, Hüthig Buch Verlag, Heidelberg, 1989, which reflect the relevant knowledge of the expert.

The term waving process includes all processes known to the person skilled in the art, in which a waving agent is applied to the optionally moistened and twisted hair on curlers and either left on the hair for a time between a few minutes and about 45 minutes and then with water or a surfactant-containing agent is rinsed out, then a permanent wave fixation is applied to the hair and this is left on the hair for a time between a few minutes and about 45 minutes and then rinsed out with water or a surfactant-containing agent. In this context, it is expressly referred to the known monographs, e.g. B. K. H. Schrader, Fundamentals and Recipes of Cosmetics, 2nd edition, Hüthig Buch Verlag, Heidelberg, 1989, referring to the corresponding knowledge of the expert.

There are no fundamental restrictions with regard to the manner in which the active ingredient according to the invention is applied to the keratin fiber, in particular human hair. These preparations include, for example, creams, lotions, solutions, water, emulsions such as W / O, O / W, PIT emulsions (emulsions based on the teaching of phase inversion, PIT), microemulsions and multiple emulsions, gels, sprays, Suitable aerosols and foam aerosols. The pH of these preparations can in principle be between 2 and 11. It is preferably between 5 and 11, values from 6 to 10 being particularly preferred. Virtually any acid or base that can be used for cosmetic purposes can be used to adjust this pH. In the context of the invention, the use of the active ingredient (A) according to the invention is also particularly preferred for adjusting the pH. Preferred bases are ammonia, alkali metal hydroxides, monoethanolamine, triethanolamine and N, N, N ', N' tetrakis (2-hydroxypropyl) ethylenediamine.

Preparations remaining on the hair have proven to be effective and can therefore represent preferred embodiments of the teaching according to the invention. Under on According to the invention, the hair remaining is understood to mean those preparations which are not rinsed out of the hair again after a period of a few seconds to an hour with the aid of water or an aqueous solution. Rather, the preparations remain on the hair until the next hair wash, ie generally more than 12 hours.

According to a second preferred embodiment, these preparations are formulated as a hair treatment or hair conditioner. The preparations according to the invention according to this embodiment can be rinsed out with water or an at least predominantly water-containing agent after this exposure time has expired; however, as stated above, they could be left on the hair. It may be preferred to apply the preparation according to the invention to the hair before using a cleaning agent, a waving agent or other hair treatment agents. In this case, the preparation according to the invention serves as structural protection for the subsequent applications.

According to further preferred embodiments, however, the agents according to the invention can also be, for example, cleaning agents such as shampoos, conditioning agents such as rinses, setting agents such as hair setting agents, foam setting agents, styling gels and hair dryer shafts, permanent shaping agents such as permanent waving and fixing agents, and in particular as part of a permanent waving process pretreatment agents or rinses used in the dyeing process.

In addition to the restructuring agent which is absolutely necessary according to the invention and the further preferred components mentioned above, these preparations can in principle contain all further components known to the person skilled in the art for such cosmetic agents.

Other active ingredients, auxiliaries and additives are, for example non-ionic polymers such as, for example, vinyl pyrrolidone / vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers and polysiloxanes,

Thickeners such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. B. methyl cellulose, hydroxyalkyl cellulose and carboxymethyl cellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such as. B. bentonite or fully synthetic hydrocolloids such. B. polyvinyl alcohol, hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, and silicone oils, perfume oils, dimethyl isosorbide and cyclodextrins,

Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol, symmetrical and asymmetrical, linear and branched dialkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as di-n-octyl ether , Di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether and di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n -Undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether as well as di-tert-butyl ether, di-isopentyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, isopentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether,

Fatty alcohols, in particular linear and / or saturated fatty alcohols with 8 to 30 carbon atoms,

Monoesters from C8 to C30 - fatty acids with alcohols with 6 to 24 carbon atoms, active ingredients that improve fiber structure, in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fructose, fructose and lactose, conditioning active ingredients such as paraffin oils, vegetable oils, e.g. , B. sunflower oil, orange oil, almond oil, wheat germ oil and peach kernel oil and phospholipids, for example soy lecithin, egg lecithin and cephalins, quaternized amines such as methyl l-alkylamidoethyl-2-alkylimidazolinium methosulfate, defoamers such as silicones, dyes for coloring the agent, - anti-dandruff agents such as piroctone olamine, zinc omadine and climbazol,

- active ingredients such as allantoin and bisabolol,

- cholesterol,

- consistency agents such as sugar esters, polyol esters or polyol alkyl ethers,

- fats and waxes such as walrus, beeswax, montan wax and paraffins,

- fatty acid alkanolamides,

Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,

Swelling and penetration substances such as primary, secondary and tertiary phosphates,

- opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers

Pearlescent agents such as ethylene glycol mono- and distearate and PEG-3 distearate,

- pigments,

- Reducing agents such. B. thioglycolic acid and its derivatives, thiolactic acid, cytamine, thio malic acid and α-mercaptoethanesulfonic acid,

Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,

- antioxidants.

With regard to further optional components and the amounts of these components used, reference is expressly made to the relevant manuals known to the person skilled in the art, e.g. B. referred to the above monograph by K. H. Schrader.

The invention also relates to agents for restructuring fibers, in particular keratin fibers, which comprise a combination of a. the active ingredient (A) and b. contain a polymer (G).

With regard to further components of these agents, reference is made to what has been said above.

A third subject of the invention is a process for restructuring fibers, in particular keratin fibers, in which an agent with the active ingredient according to the invention, as used in one of claims 1 to 9, is applied to the fibers, where if desired, the agent is rinsed out again after an exposure time of 1 to 45 minutes. Examples

Unless otherwise noted, all quantities are parts by weight.

1. Proof of effectiveness a) Pretreatment

Strands from Alkinco (0.5 g, code 6634) were subjected to conventional permanent wave treatments with the commercial product Poly Lock-Normal permanent wave. In the course of this permanent wave treatment, the fibers were exposed to the reducing solution (containing 7.9% by weight thioglycolic acid) in a first step for 40 minutes at room temperature, rinsed with pure water and then fixed at room temperature for 10 minutes (oxidation solution containing 2 , 6 wt .-% hydrogen peroxide). After the oxidative treatment, the fibers were rinsed and dried.

b) post-treatment

The strands were immersed at a temperature of 23 ° C. for 10 minutes in a 1% aqueous solution of the respective active ingredients at a pH of 3, which was adjusted with sodium hydroxide solution or hydrochloric acid. Each strand of hair was then rinsed with clear water for 1 minute, dried and left to stand for 16 hours.

c) Evidence of the hair structuring effect using HP-DSC

The following melting points shown in Table 1 were determined by means of a DSC analysis (Perkin Elmer DSC-7). A precise description of the method can be found, for example, in DE 196 173 95 AI

applications

1. Hair conditioner

Eumulgin ^® B2 ¹ 0.3

Cetyl / stearyl alcohol 3.3

Isopropyl myristate 0.5

Lamesoft ^® PO 65 ⁴ 0.5

Dehyquart ^® A-CA ² 2.0

Salcare ^® SC 96 ⁵ 1.0

Citric acid 0.4

Gluadin ^® WQ ⁶ 2.0

Pyridoxine 1.0

D-glucose 0.8

D-glucose-6-phosphate 0.2

Tartaric acid 0.7

^Phenonip®3 0.8

Water ad 100

^L Cetylstearyl alcohol + 20 EO (INCI name: Ceteareth-20) (COGNIS)

² 'trimethylhexadecylammonium chloride approx. 25%> active substance (INCI name:

Cetrimonium Chloride) (COGNIS) ³ 'methyl hydroxybenzoate-hydroxybenzoate ethyl ester-hydroxybenzoic acid propyl ester-hydroxybenzoic acid butyl ester-phenoxyethanol mixture (approx. 28%

Active substance; INCI name: phenoxyethanol, methyl paraben, ethyl paraben,

Propylparaben, Butylparaben) (NIPA) ⁴ 'Mixture of alkyl polyglycoside and fatty acid monoglyceride (INCI name g:

Coco-Glucoside (and) Glyceryl Oleate) ⁵ "N, N, N-Trimethyl-2 [(methyl-l-oxo-2-propenyl) oxy] -ethanaminium chloride homopolymer (50%> active substance; INCI name): Polyquaternium-37 (and) propylene glycol dicaprilate dicaprate (and) PPG-1 trideceth-6) (ALLIED COLLOIDS) ^6- cationized wheat protein hydrolyzate approx. 31% active substance (INCI name:

Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein) (COGNIS) 2. Conditioner

Eumulgin ^® B2 0.3

Cetyl / stearyl alcohol 3.3

Isopropyl myristate 0.5

Paraffin oil perliquidum 15 cSt. DAB 9 0.3

Dehyquart ^® L 80 ⁷ 0.4

Lamesoft ^® PO 65 1.5

Cosmedia Guar ^® C 261 ⁸ 1.5

Promois® ^® Milk-CAQ ⁹ 3.0

Citric acid 0.4

D erythrosis 0.5

Phenonip ^® 0.8

Water ad 100

⁷ 'bis (cocoylethyl) hydroxyethyl methyl ammonium methosulfate (approx. 76% active substance in propylene glycol; INCI name: dicocoylethyl hydroxyethylmonium methosulfate, propylene glycol) (COGNIS)

⁸ "guar hydroxypropyltrimethylammonium chloride; INCI name: guar hydroxypropyltrimonium chloride (COGNIS)

⁹ 'INCI name: Cocodimonium Hydroxypropyl Hydrolyzed Casein (SEIWA KASEI)

3. Hair treatment

Dehyquart ^® F75 ¹⁰ 4.0

Cetyl / stearyl alcohol 4.0

Paraffin oil perliquidum 15 cSt DAB 9 1.5

Dehyquart® ^® A-CA 4.0

Lamesoft ^® PO 65 1.0

Salcare ^® SC 96 1.5

Glucosamine hydrochloride 2.5

Glyoxylic acid 0.5 Amisafe-LMA-60 ^®11 1.0

Gluadin ^® W 20 ¹² 3.0

Germall ^® 115 ¹³ 1.0

Citric acid 0.15

Phenonip ^® 0.8

Water ad 100

10. Fettalkohole-Methyltriethanolammoniiimmethylsulfatdialkylester mixture (INCI name: Distearoylethyl Hydroxyethylmonium Methosulfate, Cetearyl Alcohol) (COGNIS) π. INCI name Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl (Ajinomoto)

12. Wheat protein hydrolyzate (20% active ingredient in water; INCI name: Aqua (and) Hydrolized Wheat Protein (and) Sodium Benzoate (and) Phenoxyethanol (and) Methylparaben (and) Propylparaben) (COGNIS)

13. INCI name: Imidazolidinyl Urea (Sutton Laboratories)

4. Hair treatment

Dehyquart ^® L80 2.0

Cetyl / stearyl alcohol 6.0

Paraffin oil perliquidum 15 cSt DAB 9 2.0

Rewoquat ^® W 75 ¹⁴ 2.0

Cosmedia Guar C261 ^® 0.5

Lamesoft ^® PO 65 0.5

Sepigel ^® 305 ¹⁵ 3.5

Honeyquat ^® 50 ¹⁶ 1.0

Gluadin ^® WQ 2.5

Gluadin ^® W 20 3.0

Rhamnose 1.0

Citric acid 0.15

Phenonip ^® 0.8

Water ad 100 ¹ l-methyl-2-nortalgalkyl-3-tallow fatty acid amidoethylimidazolinium methosulfate (approx. 75% active substance in propylene glycol; INCI name: Quaternium-27, propylene glycol) (WITCO)

^15- copolymer of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid (INCI name: polyacrylamide (and) C ₁₃ -C ₁₄ isoparaffin (and) Laureth-7) (SEPPIC)

^16- INCI - Name: Hydroxypropyltrimonium Honey (BROOKS)

5. Hair treatment

Dehyquart ^® F75 0.3

Salcare ^® SC 96 5.0

Gluadin ^® WQ 1.5

Lamesoft ^® PO 65 0.5

Dow ^Corning® 200 Fluid, 5 cSt. ¹⁷ 1, 5

Gafquat ^® 755N ¹⁸ 1.5

Sorbitol 1.5

Biodocarb® ¹⁹ 0.02

Perfume oil 0.25

Water ad 100

¹⁷ - polydimethylsiloxane (INCI name: Dimethicone) (DOW CORNING)

^1S "dimethylaminoethyl methacrylate-vinylpyrrolidone copolymer, quaternized with diethyl sulfate (19% active substance in water; INCI name: Polyquaternium-11) (GAF)

^19- 3-iodo-2-propynyl-n-butyl carbamate (INCI name: iodopropynyl butyl carbamate) (MILKER & GRÜNING)

6. Hair treatment

Sepigel ^® 305 5.0

Dow Corning ^® Q2-5220 ²⁰ 1.5

Promois ^® Milk Q ²¹ 3.0

Lamesoft ^® PO 65 0.5

Polymer P 1 according to DE 3929173 0.6 Genamin ^® DSAC ²² 0.3

L-Arabitol 1.8

Phenonip ^® 0.8

Perfume oil 0.25

Water ad 100

^{20 '} silicone-glycol copolymer (INCI name: Dimethicone Copolyol) (DOW CORNING)

^21, INCI name hydroxypropyltrimonium hydrolyzed casein approx. 30%> active substance (SEIWA KASEI)

^2λ dimethyldistearylammonium chloride (INCI name: Distearyldimonium Chloride) (CLARIANT)

7. Shampoo

Texapon.RTM ^® NSO ²³ 40.0

Dehyton ^® G ²⁴ 6.0

Polymer JR 400 ^®25 0.5

Cetiol ^® HE ²⁶ 0.5

Ajidew ^® NL 50 ²⁷ 1.0

Lamesoft® PO 65 3.0

Gluadin ^® WQT ²⁸ 2.5

Gluadin ^® W 20 0.5

Panthenol (50%) 0.3

Pentaerythritol 2.0

Vitamin E 0.1

Vitamin H 0.1

Glutamic acid 0.2

Citric acid 0.5

Sodium benzoate 0.5

Perfume 0.4

NaCl 0.5

Water ad 100 ^{23 "} sodium lauryl ether sulfate approx. 28%) active substance (INCI - name: Sodium Laureth Sulfate) (COGNIS)

2nd INCI name: Sodium Cocoamphoacetate, approx. 30% »active substance in water) (COGNIS)

25. quaternized hydroxyethyl cellulose (INCI - designation: Polyquaternium-10) (UNION CARBIDE)

26. Polyol fatty acid ester (INCI - name: PEG-7 Glyceryl Cocoate) (COGNIS)

27. Sodium salt of 2-pyrrolidinone-5-carboxylic acid (50% active substance: INCI name: Sodium PCA) (AJINOMOTO)

28. INCI name: Hydroxypropyltrimonium Hydrolyzed Wheat Protein (COGNIS)

8. Shampoo

Texapon.RTM ^® NSO 43.0

Dehyton ^® K ²⁹ 10.0

Plantacare ^® 1200 UP ³⁰ 4.0

Lamesoft ^® PO 65 2.5

Euperlan ^® PK 3000 ³¹ 1.6

Arquad ^® 316 ³² 0.8

Polymer ^JR® 400 0.3

Gluadin ^® WQ 4.0

Lactic acid 0.5

Tannin 0.5

Catechin 0.5

Glucamate ^® DOE 120 ³³ 0.5

Sodium chloride 0.2

Water ad 100

^29- INCI - Name: Cocamidopropyl Betaine approx. 30% active substance (COGNIS)

³⁰ - C 12 - C 16 fatty alcohol glycoside approx. 50% active substance (INCI - name: Lauryl Glucoside) (COGNIS) ^{31 "} Liquid dispersion of pearlescent substances and amphoteric surfactant (approx. 62% _{> active} substance; CTFA name: Glycol Distearate (and) Glycerin (and) Laureth-4 (and) Cocoamidopropyl Betaine) (COGNIS)

^32- tri-Ci g-alkylmethylammonium chloride (AKZO)

^33- ethoxylated methyl glucoside dioleate (CTFA name: PEG-120 methyl glucose dioleates) (AMERCHOL)

9. Shampoo

Texapon ^® N 70 ³⁴ 21.0

Plantacare ^® 1200 UP 8.0

Lamesoft ^® PO 65 3.0

Gluadin ^® WQ 1.5

Cutina ^® EGMS ³⁵ 0.6

Honeyquat ^® 50 2.0

Ajidew ^® NL 50 2.8

Antil ^® 141 ³⁶ 1.3

Adonit 2.0

Sodium chloride 0.2

Magnesium hydroxide ad pH 4.5

Water ad 100

^34, sodium lauryl ether sulfate with 2 mol EO approx. 70%> active substance (INCI name:

Sodium Laureth Sulfate) (COGNIS)

35, ethylene glycol monostearate (approx. 25-35% monoester, 60-70% diester;

INC designation: Glycol Stearate) (COGNIS)

36. Polyoxyethylene propylene glycol dioleate (40% active substance; INCI name:

Propylene Glycol (and) PEG-55 Propylene Glycol Oleate) (GOLDSCHMIDT)

10. Shampoo

Texapon ^® K 14 S ³⁷ 50.0

Dehyton ^® K 10.0

Plantacare ^® 818 UP ³⁸ 4.5 Lamesoft ^® PO 65 2.0

Polymer Pl, according to DE 39 29 973 0.6

Cutina ^® AGS ³⁹ 2.0

D-panthenol 0.5

Fructose 1.0

Salicylic acid 0.4

Sodium chloride 0.5

Gluadin ^® WQ 2.0

Water ad 100

³⁷ 'sodium lauryl myristyl ether sulfate ca 28% active substance (INCI - designation: sodium myreth sulfate) (COGNIS)

^38- C 8 - C 16 fatty alcohol glycoside approx. 50% active substance (INCI - name: Coco Glucoside) (COGNIS)

^39- ethylene glycol stearate (approx. 5-15% monoester, 85-95% diester; INCI name: glycol distearate) (COGNIS)

11. Hair treatment

Celquat ^® L 200 ⁴⁰ 0.6

Luviskol ^® K30 ⁴¹ 0.2

D-panthenol 0.5

Polymer Pl, according to DE 39 29 973 0.6

Dehyquart® ^® A-CA 1.0

Lamesoft ^® PO 65 0.5

Isomalt 1.0

Aspartic acid 0.3

Gluadin ^® W 40 ⁴² 1.0

Natrosol ^® 250 HR ⁴³ 1.1

Gluadin ^® WQ 2.0

Water ad 100

^40- quaternized cellulose derivative (95% active substance; CTFA name: Polyquaternium-4) (DELFT NATIONAL) - Polyvinylpyrrolidone (95% active substance; CTFA name: PVP) (BASF) - Partial hydrolyzate from wheat approx. 40% active substance (INCI - Name: Hydrolyzed Wheat Gluten Hydrolyzed Wheat Protein) (COGNIS) - Hydroxyethyl cellulose (AQUALON)

12. Coloring cream

C ₁₂ . ₁₈ fatty alcohol 1.2

Lanette ^® O ⁴⁴ 4.0

Eumulgin ^® B 2 0.8

Cutina ^® KD 16 ⁴⁵ 2.0

Lamesoft ^® PO 65 4.0

Sodium sulfite 0.5

L (+) - ascorbic acid 0.5

Ammonium sulfate 0.5

1,2-propylene glycol 1,2

Polymer ^JR® 400 0.3 p-aminophenol 0.35 p-toluenediamine 0.85

2-methylresorcinol 0.14

6-methyl-m-aminophenol 0.42

Cetiol OE ^{® 46} 0.5

Honeyquat 50 ^® 1.0

Ajidew ^® NL 50 1.2

Gluadin ^® WQ 1.0

Arabite 0.5

Ammonia 1.5

Water ad 100 ^44, cetylstearyl alcohol (INCI - name: Cetearyl Alcohol) (COGNIS)

^45- Self-emulsifying mixture of mono- / diglycerides of higher saturated fatty acids with potassium stearate (INCI - name: Glyceryl Stearate SE) (COGNIS)

⁴⁶ - Di-n-octyl ether (INCI - name: dicaprylyl ether) (COGNIS)

13. developer dispersion for coloring cream 12 Texapon.RTM ^® NSO 2.1 hydrogen peroxide (50%) 12.0 Turpinal ^® SL ⁴⁷ 1.7

Latekol D ⁴⁸ 12.0

Lamesoft ^® PO 65 2.0

Gluadin ^® WQ 0.3

Salcare ^® SC 96 1.0

Aspartic acid 0.1

Mannitol 0.8

Water ad 100

^47- 1-hydroxy ethane-l, l-diphosphonic acid (60% active substance; INCI - Designation:

Etidronic Acid) (COGNIS)

48 acrylic ester-methacrylic acid copolymer (25% active substance) (BASF)

14. Tinting shampoo

Texapon ^® N 70 14.0

Dehyton ^® K 10.0

Akypo ^® RLM 45 NV ⁴⁹ 14.7

Plantacare ^® 1200 UP 4.0

Lamesoft ^® PO 65 3.0

Polymer Pl, according to DE 39 29 973 0.3

Cremophor ^® RH 40 ⁵⁰ 0.8

Cellobiose 0.3

Sucrose 0.3

Elaidic acid 0.3

Dye C.I. 12 719 0.02

Dye C.I. 12 251 0.02

Dye C.I. 12 250 0.04

Dye C.I. 56,059 0.03

Preservation 0.25

Perfume oil q.s.

Eutanol ^® G ⁵¹ 0.3

Gluadin ^® WQ 1.0 Honeyquat 50 ^® 1.0

Salcare ^® SC 96 0.5

Water ad 100

^49- lauryl alcohol + 4.5 ethylene oxide-acetic acid sodium salt (20.4% active substance) (CHEM-Y)

⁵⁰ - castor oil, hydrogenated + 45 ethylene oxide (INCI - designation: PEG-40 Hydrogenated Castor Oil) (BASF)

⁵ 2-Octyldodecanol (Guerbet alcohol) (INCI - name: Octyldodecanol) (COGNIS)

15. Cream permanent wave corrugated cream

Plantacare ^® 810 UP ⁵² 5.0

Thioglycolic acid 8.0

Turpinal ^® SL 0.5

Ammonia (25%) 7.3

Ammonium carbonate 3.0

Cetyl / stearyl alcohol 5.0

Lamesoft ^® PO 65 0.5

Guerbet alcohol 4.0

Salcare ^® SC 96 3.0

Gluadin ^® WQ 2.0

Lactose 0.2

Perfume oil q.s.

Water ad 100

⁵² 'C ₈ -C ₁₀ alkyl glucoside with degree of oligomerization 1.6 (approx. 60% active substance) (COGNIS)

fixing

Plantacare ^® 810 UP 5.0 hardened castor oil 2.0

Lamesoft ^® PO 65 1.0

Potassium bromate 3.5

Nitrilotriacetic acid 0.3

Citric acid 0.2

Merquat ^® 550 ⁵³ 0.5

Hydagen ^® HCMF ⁵⁴ 0.5

Tartaric acid 0.5

Gluadin ^® WQ 0.5

Maltose 0.3

Perfume oil q.s.

Water ad 100

^{53 "} dimethyldiallylammonium chloride-acrylamide copolymer (8% active substance; INCI name: Polyquartemium 7) (MOBIL OIL)

54. Chitosan powder (INCI - name: Chitosan) (COGNIS)

Claims

claims

1. Use of polyhydroxy compounds (A) in cosmetic compositions as an active ingredient for restructuring keratin fibers.

2. Use according to claim 1, characterized in that the cosmetic compositions contain, in addition to the active ingredient (A), polymers (G).

3. Use according to one of claims 1 to 2, characterized in that the cosmetic compositions contain surfactants (E) in addition to the active ingredient (A).

4. Use according to one of claims 1 to 3, characterized in that in the cosmetic compositions in addition to the active ingredient (A) fatty substances (D) are included.

5. Use according to one of claims 1 to 4, characterized in that in the cosmetic compositions in addition to the active ingredient (A) protein hydrolyzates and / or their derivatives (H) are included.

6. Use according to one of claims 1 to 5, characterized in that in addition to the active ingredient (A), UV filters (J) are contained in the cosmetic compositions.

7. Use according to one of claims 1 to 6, characterized in that in the cosmetic compositions in addition to the active ingredient (A) oxidation dye precursors (B) are included.

8. Use according to one of claims 1 to 7, characterized in that in the cosmetic compositions in addition to the active ingredient (A) direct dyes (C) are included.

9. A process for restructuring fibers, in particular keratin fibers, characterized in that an agent is used according to one of claims 1 to 8. The active ingredients are applied to the fibers and rinsed out after an exposure time of 1 to 45 minutes.

10. Agents for restructuring fibers, in particular keratin fibers, which are a combination of a. the active ingredient (A) and b. contain a polymer (G).