CN100479802C - Hair treatment compositions - Google Patents
Hair treatment compositions Download PDFInfo
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- CN100479802C CN100479802C CNB2005800185971A CN200580018597A CN100479802C CN 100479802 C CN100479802 C CN 100479802C CN B2005800185971 A CNB2005800185971 A CN B2005800185971A CN 200580018597 A CN200580018597 A CN 200580018597A CN 100479802 C CN100479802 C CN 100479802C
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- treatment composition
- acid
- disaccharide
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
Abstract
The invention provides a hair treatment composition such as a shampoo or conditioner comprising a disaccharide, alkali metal salt and a di-acid or salt thereof. Use of said composition for smoothing and aligning hair, for preventiv damage to the hair.
Description
Technical field
The present invention relates to a kind of hair-treatment composition.More specifically, the present invention relates to a kind of hair-treatment composition that comprises the particular combinations of active substance.Said composition is specially adapted to be applied on the hair, to repair and to restore impaired hair and make hair fixing, so that hair style is kept under moisture state.
Background technology
Multiple reason can make hair impaired, for example: be exposed under UV and the chlorine; Chemical affect cleans as bleaching, hair-waving, the coarse surfactants based shampoo compositions of excessively frequent use; And mechanical influence, as long-time use thermal finalization apparatus.
The infringement of hair self typically shows to from hair fiber loss horny layer and protein, hair fiber fragility, breakage, wearing and tearing or terminal bifurcated.
Moreover consumer requires their hair to become to handle easily, if promptly during hair fixing hair will be long-time and can under a series of adverse environment conditions such as for example high humility, keep this hair style.
Be disclosed in the organic acid that contains wide region in skin and the hair care composition among the WO 97/14401 (Kao Corporation).
Disclose among the WO 01/68040 (L ' Oreal) and utilize sugar and plant extract protection collenchyme.Disclose among the WO 01/01948 with trehalose and strengthen the elasticity of skin and/or prevent to wear out.
Disclose the combination of sugar and acid among WO 02/45665 (Henkel), EP 0 383 467 (Strydom Andries JC), GB2 092 570 (Richter Gedeon Vegyeszeti) and the DE 26 25 398 (PhilipsPatentverwaltung).
Summary of the invention
The present invention has now found that the compositions of certain particular combinations that comprises sugar, acid and salt can be effective to the cardinal symptom of repairing and preventing damaged hair, and these combinations also further have the advantage of the handlability (manageability) that helps to improve hair.
Invention is described
First aspect the invention provides a kind of hair-treatment composition, and it comprises i) disaccharide of the 0.001wt% to 8wt% of total composition; The ii) alkali metal salt of the 0.001wt% to 10wt% of total composition and iii) diacid or its salt.
Another aspect of the present invention is that above-mentioned composition is used for along sliding (Smoothing) hair, makes hair marshalling (aligning) and prevent the application that hair is impaired.
The invention still further relates to a kind of method of treatment of hair, it carries out on hair by using above-mentioned composition.
Describe in detail
Disaccharide
The present invention comprises disaccharide as neccessary composition of the present invention, and preferred disaccharide comprises pentose or hexose, and more preferably disaccharide comprises two hexose.
Disaccharide can be reducing sugar or non-reducing sugar.Preferred non-reducing sugar.
The disaccharide of D (+) type is preferred.Particularly preferably be trehalose and cellobiose or its mixture.Disaccharide is trehalose most preferably.
The level of the disaccharide that in whole preparation, exists be total composition 0.001 to 8wt%, preferred 0.05wt% to 5wt%, more preferably 0.2 to 3wt%, most preferably 0.5wt% to 2wt%.
Alkali metal salt
Compositions comprises alkali metal salt, alkali metal salt preferably sulfuric acid salt, more preferably sodium sulfate.
The level that alkali metal salt exists is more than the 0.001wt% of total composition, more than the preferred 0.05wt%, most preferably more than the 0.1wt%.The maximum horizontal of salt is lower than 10wt%, preferably is lower than 7wt%, more preferably less than 5wt%.
Diacid
Have diacid in the compositions of the present invention, specially suitable is the diacid with following molecular formula:
HOOC-(CH
2)n-COOH
Wherein n is 2～8 integer, and more preferably n equals 2 or 4 (being respectively succinic acid and adipic acid).
In total preparation, the optimum amount of diacid is the 0.01wt%～5wt% of total composition, more preferably the level of 0.1wt%～2wt%.
The weight ratio of diacid and disaccharide is 1: 10～20: 1, more preferably 1: 5～5: 1.
In addition, Suan optimum amount is a diacid: the disaccharide mol ratio is 0.1: 1～10: 1, is preferably 0.1: 1～2: 1.
The pH value scope of preparation of the present invention is pH3～pH6, more preferably uses pH3-5.
Product form
The final product form of hair-treatment composition of the present invention, can be suitable be, for example: shampoo, conditioner, hair spray, mousse, hair gel, pomade or shampoo.Particularly preferred product form is shampoo, wash the back conditioner (keep and wash off) and such as hair treatment product such as hair essence and hair mousses.
Shampoo compositions preferably comprises one or more and make up to go up acceptable and be suitable for the clean surface activating agent of hair topical application.Surfactant can be further used as emulsifying agent and exist.
Suitable clean surface activating agent is selected from anion surfactant, amphoteric surfactant and zwitterionic surfactant, and their mixture.The clean surface activating agent can be the surfactant identical with emulsifying agent, or can be different.
Anion clean surface activating agent
Shampoo compositions typical case of the present invention is contained one or more and make up to be gone up acceptable and be suitable for the anion clean surface activating agent of hair topical application.
The example of suitable anion clean surface activating agent is: alkyl sulfate, alkyl ether sulfate, alkylaryl sulfonate, alkanoyl isethionate, alkyl succinate, alkyl sulfo succinate, N-alkyl sarcosine salt, alkylphosphonic, alkyl ether phosphate, alkyl ether carboxy acid salt; and alpha-alkene sulfonate; particularly their sodium salt, magnesium salt, ammonium salt, and single, double and triethanolamine salt.This alkyl and acyl group generally comprise 8～18 carbon atoms, can be undersaturated.Can comprise 1～10 oxirane or propylene oxide units among the alkyl ether sulfate of per molecule, alkyl ether phosphate and the alkyl ether carboxy acid salt.
The anion clean surface activating agent that typically is used for shampoo compositions of the present invention comprises: oleoyl sodium sulfosuccinate, lauryl 2-Sulfosuccinic acid ammonium, ammonium lauryl sulfate, cocoyl (cocoyl) sodium isethionate, lauryl sodium isethionate and N-sodium lauryl sarcosinate.Most preferred anion surfactant is sodium lauryl sulfate, sodium laureth sulfate (n) EO (wherein n is 1～3), ammonium lauryl sulfate and Zetesol AP (n) EO (wherein n is 1～3).
The total content of anion clean surface activating agent is generally 5～30wt% of total composition, preferred 6～20wt%, more preferably 8～16wt% in the shampoo compositions of the present invention.
Cosurfactant
Can choose wantonly in the shampoo compositions and comprise cosurfactant, preferred both sexes or zwitterionic surfactant, its content range is 0～about 8wt%, preferred 1～4wt%.
The example of both sexes or zwitterionic surfactant comprises: alkyl betaine, alkyl amido CAB, alkyl sulfobetaines (sultaines), alkyl glycinate, alkyl carboxyl glycinate, alkyl both sexes (ampho) propionate, alkyl both sexes glycinate, alkyl amido propyl hydroxy sulfobetaines, acyl taurine salt and acyl glutamate, wherein alkyl and acyl group have 8～19 carbon atoms.The typical both sexes and the zwitterionic surfactant that use in the shampoo compositions of the present invention comprise: lauryl amine oxide, cocoyl (coco) dimethyl sulfopropyl betaine, preferred lauryl betaine, cocoamidopropyl and cocoyl both sexes sodium propionate.
Another kind of preferred cosurfactant is a non-ionic surface active agent, and it can comprise that content range can be 0～8wt% of total composition, preferred 2～5wt%.
For example, the representational non-ionic surface active agent that can comprise in the shampoo compositions of the present invention comprises aliphatic series (C
8～C
18) uncle or the alcohol of the straight or branched of the second month in a season or the condensation product of phenol and alkylene oxide, alkylene oxide is an oxirane usually, and generally has 6～30 ethylene oxide groups.
Further, the non-ionic surface active agent that can comprise in the shampoo compositions of the present invention is APG (APGs).Typically, APG is the group that contains and be connected to the alkyl on (optional by the bridging base) one or more glycosyl blocks.Preferred APGs is defined by following formula:
RO-(G)n
Wherein R is side chain or straight chain C
5～C
20Alkyl or alkenyl, G is a glycosyl, n is 1～10.
The sugared deutero-non-ionic surface active agent of other that can comprise in the shampoo compositions of the present invention comprises C
10-C
18N-alkyl (C
1-C
6) polyhydroxy fatty acid amide, for example: C
12-C
18The N-methyl glucose amide is as disclosing among WO 92 06154 and the US 5 194 639; And N-alkoxyl polyhydroxy fatty acid amide, for example C
10-C
18N-(3-methoxy-propyl) glucamide.
Shampoo compositions also can randomly comprise one or more cation cosurfactants, and its content is 0.01～10wt% of total composition, more preferably 0.05～5wt%, most preferably 0.05～2wt%.Useful cationic surfactant described herein is relevant with conditioner composition.
The total amount of the surfactant in the shampoo compositions of the present invention (comprising any cosurfactant and/or any emulsifying agent) is generally 5～50wt%, preferred 5～30wt%, more preferably 10～25wt%.
Cationic polymer
Can there be cationic polymer.Cationic polymer can be homopolymer or is formed by the monomer of two or more types.The molecular weight of polymer is generally 5000～10000000, is typically at least 10000, and preferred 100000～about 2000000.Polymer has the cation nitrogen-containing group, for example quaternary ammonium or protonated amino, perhaps their mixture.
In the CTFA cosmetic composition catalogue (Cosmetic Ingredient Directory) (third edition) suitable cation polymer with nitrogen has been described.
Cationic conditioning polymer can comprise derived from amine-and/or the monomer of quaternary ammonium-replacement with and/or the mixture of the monomeric unit of compatibility spacer monomers.
Suitable cationic conditioning polymer comprises: the copolymer (the CTFA name is called Polyquaternium-16) of 1-vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazole salts; The copolymer (the CTFA name is called Polyquaternium-11) of 1-vinyl-2-pyrrolidine and methacrylic acid (dimethylaminoethyl) ester; Particularly the cation diallyl contains quaternary ammonium polymer (CTFA Polyquaternium-6 and Polyquaternium-7); U.S. patent 4,009, the inorganic acid salt of the homopolymer of the unsaturated carboxylic acid that discloses in 256 and the aminoalkyl ester of copolymer; Cation is gathered propionic acid amide. (as described in WO95/22311).
The cationic polysaccharide polymer that is applicable to compositions of the present invention comprises the cationic polysaccharide polymer with anhydroglucose residue, for example starch or cellulose.Cationic cellulose can derive from Amerchol Corp. (Edison, NJ, the polymer of PolymerJR USA) (trade mark) and LR (trade mark) series reacts the salt that obtains as hydroxyethyl-cellulose and trimethylammonium substituted epoxide, and (CTFA) is called Polyquaternium 10 in industrial quarters.Another kind of cationic cellulose comprises the high molecular quaternary that the epoxide reaction of hydroxyethyl-cellulose and the replacement of lauryl dimethylammonium obtains, and (CTFA) is called Polyquaternium 24 in industrial quarters.These materials derive from Amerchol Corp., and (USA), trade mark is called Polymer LM-200 for Edison, NJ.
Other suitable cationic polysaccharide polymer comprises the cellulose esters (as 3,962,418 records of U.S. patent) that contains quaternary nitrogen, and the copolymer of etherified cellulose and starch (as 3,958,581 records of U.S. patent).
The cationic polysaccharide polymer of available special adequate types is a cationic guar derivative, for example chlorination melon glue Hydroxyproyl Trimethyl ammonium (trimonium) (commercially available in the JAGUAR of Rhone-Poulenc trade mark series).Particularly preferred cationic polymer is JAGUARC13S, JAGUAR C14, JAGUAR C15, JAGUAR C17 and JAGUAR C16, Jaguar CHT and JAGUAR C162.
The content that exists of cationic conditioning polymer is generally 0.01～5wt% of total composition, preferred 0.05～1wt%, more preferably 0.08～0.5wt% in the compositions of the present invention.
Conditioning surfactant
Conditioner composition comprises one or more usually and make up to go up acceptable and be suitable for the conditioning surfactant of hair topical application.
Suitable conditioning surfactant is selected from cationic surfactant, can be used alone or as a mixture.
The cationic surfactant that is used for compositions of the present invention comprises amino or quaternary ammonium group hydrophilic segment, and is when it is dissolved in the waterborne compositions of the present invention, positively charged.
The example of suitable cationic surfactants is to meet those of following general formula:
[N(R
1)(R
2)(R
3)(R
4)]
+(X)
-
R wherein
1, R
2, R
3And R
4Independently be selected from the aliphatic group that (a) has 1～22 carbon atom, perhaps (b) aromatic group, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or have the alkylaryl that is up to 22 carbon atoms; X is for becoming salt anionic, as is selected from halogen (as chloride, bromide), acetate, citrate, lactate, glycolic root, phosphate radical, nitrate anion, sulfate radical and alkyl sulfate group those.
Aliphatic group beyond de-carbon and the hydrogen atom, can comprise ehter bond, and other group (for example amino).Longer chain aliphatic groups (for example those contain the group of have an appointment 12 or more carbon atoms) can be for saturated or unsaturated.
The most preferably cationic surfactant that is used for conditioner composition of the present invention is the monoalkyl quaternary ammonium compound, and wherein alkyl chain length is C16～C22.
The example of suitable cationic surfactants comprises quaternary ammonium compound, particularly the QAE chemical compound.
Preferred quaternary ammonium compound comprises: chlorination cetyl trimethylammonium, zephiran chloride trimethylammonium (BTAC), cetylpyridinium chloride, tetramethyl-ammonium chloride, tetraethyl ammonium chloride(TEAC, chlorination octyl group trimethylammonium, dodecyltrimethyl ammonium chloride, chlorination cetyl trimethylammonium, chlorination octyldimethyl hexadecyldimethyl benzyl ammonium, chlorination decyl dimethyl benzyl ammonium, octadecyl dimethyl benzyl ammonium chloride, the two dodecyl dimethylammoniums of chlorination, chlorination dioctyl dimethylammonium, chlorination Adeps Bovis seu Bubali trimethylammonium, chlorination cocoyl trimethylammonium, chlorination PEG-2 oil base (oleyl) ammonium, and their salt, wherein chlorine is by halogen (as bromide), acetate, citrate, lactate, oxyacetate, phosphate, nitrate, sulfate and alkyl sulfate replace.Other suitable cationic surfactants comprises that the CTFA name is called the material of Quaternium-5, Quaternium-31 and Quaternium-18.Any mixture of above-mentioned substance also is suitable for.The useful especially cationic surfactant that is used for hair conditioner of the present invention is, chlorination cetyl trimethylammonium, and the commercial commodity that get for example are GENAMIN CTAC, ex Hoechst Celanese.
Primary aliphatic amine, secondary fatty amine, and the salt of uncle's fatty amine also is suitable cationic surfactants.Alkyl in these amine preferably has 12～22 carbon atoms, can be replacement or unsubstituted.
Useful especially is uncle's fatty amine that acylamino-replaces, and particularly has a C
12～C
22Alkyl chain or the tertiary amine of alkenylene chain.Amine used herein comprises: stearyl aminopropyl dimethyl amine, stearyl aminopropyl diethylamide, stearyl amino-ethyl diethylamide, stearyl amino-ethyl dimethyl amine, hexadecanoyl aminopropyl dimethyl amine, hexadecanoyl aminopropyl diethylamide, hexadecanoyl amino-ethyl diethylamide, hexadecanoyl amino-ethyl dimethyl amine, docosane acylamino-propyl-dimethyl amine, docosane acylamino-propyl group diethylamide, docosane acylamino-ethyl diethylamide, docosane acylamino-ethyl dimethyl amine, eicosane acylamino-propyl-dimethyl amine, eicosane acylamino-propyl group diethylamide, eicosane acylamino-ethyl diethylamide, eicosane acylamino-ethyl dimethyl amine, the octadecanoid acid lignocaine ethyl ester.Dimethyl octadecane amine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, tetradecylamine, tridecyl amine, ethyl octadecane amine, N-tallow propane diamidogen, ethoxylation (using 5 moles of ethylene oxide) octadecane amine, dihydroxy ethyl octadecane amine, and eicosyl docosane amine also is useful.
Typically, these amine are used in combination with acid, so that each cationoid to be provided.Preferred acid used herein comprises L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, L-glutamic acid hydrochloride, and their mixture; More preferably L-glutamic acid, lactic acid, citric acid.United States Patent (USP) 4,275,055 (Nachtigal etc. authorized on June 23rd, 1981) discloses the cationic amine surfactant useful to the present invention.
H in amine that can be protonated and the acid
+Mol ratio be preferably about 1: 0.3～1: 1.2, more preferably about 1: 0.5～about 1: 1.1.
In the conditioner of the present invention, the content of cationic surfactant is preferably 0.01～10wt% of total composition, more preferably 0.05～5wt%, most preferably 0.1～2wt%.
The cationic surfactant that this part is described in detail also is applicable to the following aspect among the present invention: wherein before the conditioning material was sneaked in the final Wo 2008069000, cationic surfactant fully mixed with thermotropic liquid-crystalline (thermotropic mesogenic) material and oiliness conditioning material.
Fatty material
Preferably contain fatty material in the conditioner composition of the present invention in addition.Think in care composition, to be used in combination fatty material and cationic surfactant is useful especially, be scattered in wherein structure phase because cause forming cationic surfactant like this.
" fatty material " is meant aliphatic alcohol, alkoxy fatty alcohols, fatty acid, perhaps their mixture.
Preferably the alkyl chain of fatty material is all saturated.
Representational fatty material comprises 8～22 carbon atoms, more preferably 16～22 carbon atoms.The example of suitable aliphatic alcohol comprises, as hexadecanol, octadecanol and their mixture.It is favourable using these materials, because they also help the integral body conditioning character of compositions of the present invention.
The aliphatic alcohol that has the alkoxylate (as ethoxylation or propoxylation) of about 12～about 18 carbon atoms on the available alkyl chain replaces aliphatic alcohol itself, or uses therewith.Excellent suitable example comprises: ethylene glycol cetyl ether, polyoxyethylene (2) octadecyl ether, polyoxyethylene (4) cetyl ether, and their mixture.
The content of fatty alcohol material is suitable for 0.01～15wt% in the conditioner of the present invention, preferred 0.1～10wt%, more preferably 0.1～5wt%.The weight ratio of suitable cationic surfactants and aliphatic alcohol is 10: 1～1: 10, and preferred 4: 1～1: 8, the best was 1: 1～1: 7 (for example 1: 3).
Suspensoid
Preferred embodiment, hair-treatment composition when it is shampoo compositions, further contains the suspensoid of 0.1～5wt% especially.Suitable suspensoid is selected from cross-linked copolymer, heteropolysaccharide glue glue and the crystallinity long acyl derivant of copolymer, acrylic acid and the acrylate of the copolymer of polyacrylic acid, acrylic acid cross linked polymer, acrylic acid and hydrophobic monomer, the monomer that contains carboxylic acid and acrylate.The long acyl derivant can be selected from ideally ethylene glycol stearate, have the alkanolamide of the fatty acid of 16～22 carbon atoms and their mixture.3 pairs of stearates of preferred Ethylene Glycol Distearate of long acyl derivant and Polyethylene Glycol.The polyacrylic commodity that get are Carbopol 420, Carbopol 488 or Carbopol 493.Also can use acrylic acid and multifunctional dose of crosslinked polymer; It can get commodity is Carbopol910, Carbopol 934, Carbopol 941 and Carbopol 980.The example that contains the suitable copolymers of the monomer of carboxylic acid and acrylate is Carbopol 1342.Can obtain all Carbopol (trade mark) material from Goodrich.
The cross linked polymer that acrylic acid and acrylate are suitable is Pemulen TR1 or PemulenTR2.Suitable heteropolysaccharide glue is xanthan gum, and for example can get commodity is Kelzan mu.
Conditioner
Silicone conditioning agent
Compositions of the present invention can contain the silicone conditioning agent emulsion droplet, in order to strengthen conditioning performance.
Suitable siloxanes comprises polydiorganosiloxanepolyurea, polydimethylsiloxane particularly, and its CTFA name is called simethicone (dimethicone).Polydimethylsiloxane with terminal hydroxyl also is applicable to compositions of the present invention (particularly shampoo and conditioner), and its CTFA name is called diformazan silanol (dimethiconol).Siloxane glue as described low crosslinking degrees such as WO 96/31188 also is applicable to compositions of the present invention.
The viscosity of emulsifying siloxanes (not being emulsion or final Wo 2008069000) itself is at least 10 typically at 25 ℃, 000cst, the viscosity of siloxanes itself preferably at least 60,000cst, most preferably at least 500,000cst, ideally be at least 1,000,000cst.Viscosity preferably is no more than 10
9Cst is to be easy to preparation.
The emulsifying siloxanes that is used for shampoo compositions of the present invention drips size at the average siloxanes of compositions and is typically less than 30 μ m, preferably less than 20 μ m, is more preferably less than 10 μ m, and ideal is 0.01～1 μ m.Usually the silicone emulsion that average siloxanes is dripped size≤0.15 μ m is called microemulsion.
The example of suitable pre-emulsion comprises emulsion DC2-1766, DC2-1784, DC-1785, DC-1786 and microemulsion DC2-1865 and DC2-1870, all can obtain from Dow Corning.These are the emulsion/microemulsion of diformazan silanol.The crosslinking silicone glue that helps being easy to prepare also can the pre-emulsion form obtain.The material DCX2-1787 of preferred example for obtaining from Dow Corning, it is the emulsion of crosslinked diformazan silanol glue.The material DC X2-1391 of preferred example for obtaining from Dow Corning, it is the microemulsion of crosslinked diformazan silanol glue.
The siloxanes of the another kind of preferred type that contains in shampoo of the present invention and the conditioner is the amino functional siloxanes." amino functional siloxanes " is meant the siloxanes that contains at least one primary amine, secondary amine or tertiary amine groups or quaternary ammonium group.The example of suitable amino functional siloxanes comprises: the CTFA name is called the polysiloxanes of " amino simethicone (aminodimethicone) ".
The object lesson that is applicable to amino functional siloxanes of the present invention is amino silicone oil DC2-8220, DC2-8166, DC2-8466 and DC2-8950-114 (all from DowCorning), and GE1149-75 (from General Electric Silicones).
Disclose among the EP-A-0 530 974 suitable quaternary ammonium (quaternary) siloxane polymer is arranged.Preferred quaternary ammonium siloxanes polymer is the K3474 from Goldschmidt.
Same suitable be amino functional silicone oil and nonionic with and/or the emulsion of cationic surfactant.Also can be from obtain the pre-emulsion of amino functional siloxanes as silicone oil suppliers such as Dow Corning and General Electric.Object lesson comprises: DC929 cation emulsion, DC939 cation emulsion, and non-ionic emulsion DC2-7224, DC2-8467, DC2-8177 and DC2-8154 (all from Dow Corning).
For some shampoo, the preferred especially combination of using amino and non-amino functional siloxanes.
The total amount of siloxanes is preferably 0.01～10wt% of total composition, more preferably 0.3～5wt%; Most preferably 0.5～3wt% is the level that is fit to.
(ii) non-silicone oiliness conditioning ingredients
Compositions of the present invention also can contain dispersive, nonvolatile, water-insoluble oiliness conditioner.
" insoluble " be meant in this material water insoluble (distilled water or coordinate), and the concentration under 25 ℃ is 0.1% (w/w).
Suitable oily matter or fatty material are selected from hydrocarbon ils, fatty acid ester and their mixture.The straight chain hydrocarbon ils preferably contains 12～about 30 carbon atoms of having an appointment.That same suitable is the higher hydrocabon of alkenyl monomer, for example C
2-C
6Alkenyl monomer.
The concrete example of suitable hydrocarbon ils comprises: paraffin oil, mineral oil, saturated and unsaturated dodecane, saturated and unsaturated tridecane, the saturated and unsaturated tetradecane, saturated and unsaturated pentadecane, saturated and unsaturated hexadecane, and their mixture.Also can use these chemical compounds and the branched chain isomer of the hydrocarbon of long-chain more.
Being characterized as of suitable fatty acids ester has at least 10 carbon atoms, and comprise and derived from the ester of hydrocarbyl chain from fatty acid or alcohol, monocarboxylic esters comprise chemical formula be R ' COOR alcohol with and/or acid ester, wherein R ' and R independently represent alkyl or alkenyl, and the total number of carbon atoms among R ' and the R is at least 10, preferably at least 20.Also can use dialkyl and the trialkyl ester and the alkenyl esters of carboxylic acid.
Particularly preferred fatty acid ester is monoglyceride, diglyceride and triglyceride, more particularly glycerol and such as C
1-C
22The long-chain carboxylic acid's of carboxylic acid etc. monoesters, diester and three esters.Preferred material comprises cocoa butter, palm stearines, Oleum helianthi, soybean oil and Oleum Cocois.
The suitable amount of oiliness or fatty material is 0.05～10wt%, preferred 0.2～5wt%, more preferably from about 0.5～3wt%.
Contain conditioner in the hair-treatment composition, preferably also there is cationic polymer in it.
The moulding polymer
If product is that then preferably there is the moulding polymer in it with product in moulding.
If contain the forming hair polymer in the compositions of the present invention, the then preferred 0.001 weight % of its content～10 weight %, more preferably 0.1 weight %～10 weight %, for example 1 weight %～8 weight %.
The forming hair polymer is many known.Suitable forming hair containing of comprising that commerce can get provides the polymer that is essentially cation, anion, both sexes or nonionic part for polymer with polymer.Suitable forming hair comprises with polymer, for example block and graft copolymer.This polymer can be synthetic or natural deutero-.
Adjuvant
Compositions of the present invention also can contain the adjuvant that is suitable for hair nursing.Usually, the level that these compositions are included separately is the 2wt% that is up to of total composition, preferably is up to 1wt%.
Suitable hair nursing adjuvant comprises aminoacid and ceramide.
The invention will be further described by following non-limiting example now.
The numeral embodiments of the invention; The letter representation comparative example.
Except as otherwise noted, otherwise all percent of being quoted is meant the percentage by weight based on gross weight.
The specific embodiment
Embodiment
Preparation following examples:
The following basic shampoo compositions of preparation:
Being used for measuring parts that the equipment of distortion stiffness customizes by use measures the natural hunting frequency of hair embodiment A and embodiment 1 is tested.In order to measure, an end of single hair fiber is from being connected on vertical hanging on the anchor clamps on the motor, and another free end of sample hangs up the pendulum of a known quality.Apply evocatory by actuating motor and induce the hair fiber sample to freely swing, it makes sample with radially 135 ° of rotations.Use infrared inductor to write down the cycle that each individual fibers sample freely swings naturally.
The result of free swing period (second) is as follows:
| Embodiment A | Embodiment 1 |
| 5.0871 | 5.0007 |
| 4.9519 | 4.905 |
| 6.6815 | 6.6414 |
| 4.5652 | 4.5036 |
| 7.129 | 7.0347 |
| 4.8925 | 4.8015 |
| 4.8151 | 4.7431 |
| 3.8916 | 3.8567 |
| 5.1004 | 5.0119 |
| 4.6265 | 4.5799 |
| 4.8822 | 4.8169 |
| 5.6561 | 5.5989 |
| 5.4973 | 5.4246 |
| 5.3323 | 5.2707 |
| 4.1675 | 4.1231 |
| 6.6153 | 6.481 |
| 4.6152 | 4.5438 |
| 3.7158 | 3.6273 |
| 5.1573 | 5.0875 |
| 5.3998 | 5.3271 |
| 5.139 | 5.069 |
| 0.879 | 0.871 |
| 0.39 | 0.39 |
Compare with the identical fibre of handling through embodiment A, the cycle of the natural hunting period under the hair fiber distortion after embodiment 1 handles significantly reduces.The reduction of this nature hunting period shows that the torsion modulus after embodiment 1 handles increases.The torsion modulus increase of hair meets consumer and feels the impaired less sensation of hair, and this is owing to having improved handlability, because hair can keep being discharged to neatly and the less entanglement that becomes very much of high level under as distortion stimulations such as a walking or nature motions.
Table 3-shampoo preparation
On the hair of consumer to embodiment 2 relatively and comparative example B test.Find to significantly improve the handlability of hair and be easy to typing with the hair that embodiment 2 handles.Compare with the hair of handling with comparative example, the hair of handling with embodiment 2 also shows less damage.
Table 4 mousse formulations
| Composition | Basic recipe | The raw material supplier |
| The crosslinked diformazan silanol emulsion of CF2259 (50% activity) | 3 | Toray?Dow Corning |
| HC Polymer 3M (20% activity) Po1yquaternium 11 | 3.0 | Osaka?Organic Chemicals |
| Volpo CS50 Ethoxy (50) cetearyl alcohol | 0.3 | Croda Oleochemicals |
| Ethanol | 8 | |
| Water | To 100% | |
| CAP40 | 8 | Calor |
| Sodium sulfate | 0.1 |
Claims (13)
1. hair-treatment composition, it comprises i) disaccharide of the 0.001wt% to 8wt% of total composition; The ii) alkali metal salt of the 0.001wt% to 10wt% of total composition; And iii) diacid or its salt, it has chemical formula:
HOOC-(CH
2)
n-COOH
Wherein n is 2～8 integer.
2. hair-treatment composition according to claim 1, wherein disaccharide has two hexose rings.
3. according to the described hair-treatment composition of above-mentioned any one claim, wherein disaccharide is selected from trehalose, cellobiose or its mixture.
4. hair-treatment composition according to claim 1, wherein disaccharide is a trehalose.
5. hair-treatment composition according to claim 1, wherein the n in the diacid chemical formula equals 2 or 4.
6. hair-treatment composition according to claim 5, wherein diacid is an adipic acid.
7. hair-treatment composition according to claim 1, wherein alkali metal salt is a sodium sulfate.
8. hair-treatment composition according to claim 1, it further comprises surfactant.
9. hair-treatment composition according to claim 1, it comprises aqueous matrix.
10. be used for the suitable foxy application of sending out according to the described compositions of above-mentioned any one claim.
11. be used to make the application of hair marshalling according to any one described compositions in the claim 1～9.
12. be used to the application that prevents that hair is impaired according to any one described compositions in the claim 1～9.
13. the method for a treatment of hair, it carries out on hair by using according to any one described compositions in the claim 1～9.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04252059 | 2004-04-07 | ||
| EP04252059.3 | 2004-04-07 | ||
| EP04252982.6 | 2004-05-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1964693A CN1964693A (en) | 2007-05-16 |
| CN100479802C true CN100479802C (en) | 2009-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005800185971A Active CN100479802C (en) | 2004-04-07 | 2005-03-23 | Hair treatment compositions |
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| CN (1) | CN100479802C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106029054B (en) * | 2015-08-03 | 2018-12-14 | 拉芳家化股份有限公司 | A kind of aqueous hair quality modifying composition of suitable straight hair sizing and its application |
| CN108778232B (en) * | 2016-03-18 | 2021-11-12 | 联合利华知识产权控股有限公司 | Hair treatment composition |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1220969B (en) * | 1964-11-25 | 1966-07-14 | Ernst Kruegermeyer & Co Seruba | Process for improving structurally damaged hair |
| DE2625398A1 (en) * | 1976-06-05 | 1977-12-15 | Philips Patentverwaltung | Seed potato germination stimulation - with agents contg. cysteine, kinetin and calcium glycerophosphate and/or calcium pantothenate |
| GB2092570A (en) * | 1981-02-09 | 1982-08-18 | Richter Gedeon Vegyeszet | Ergot alkaloids |
| EP0383467A2 (en) * | 1989-02-06 | 1990-08-22 | Andries Johannes Cornelus Strydom | Medicament for use in combatting hair loss and/or dandruff |
| CN1147545A (en) * | 1996-02-09 | 1997-04-16 | 耿传芝 | Kuangmei shampoo |
| WO2002045665A1 (en) * | 2000-12-09 | 2002-06-13 | Henkel Kommanditgesellschaft Auf Aktien | Novel use of polyhydroxy compounds |
| WO2004054526A1 (en) * | 2002-12-13 | 2004-07-01 | Unilever Plc | Hair treatment compositions |
-
2005
- 2005-03-23 CN CNB2005800185971A patent/CN100479802C/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1220969B (en) * | 1964-11-25 | 1966-07-14 | Ernst Kruegermeyer & Co Seruba | Process for improving structurally damaged hair |
| DE2625398A1 (en) * | 1976-06-05 | 1977-12-15 | Philips Patentverwaltung | Seed potato germination stimulation - with agents contg. cysteine, kinetin and calcium glycerophosphate and/or calcium pantothenate |
| GB2092570A (en) * | 1981-02-09 | 1982-08-18 | Richter Gedeon Vegyeszet | Ergot alkaloids |
| EP0383467A2 (en) * | 1989-02-06 | 1990-08-22 | Andries Johannes Cornelus Strydom | Medicament for use in combatting hair loss and/or dandruff |
| CN1147545A (en) * | 1996-02-09 | 1997-04-16 | 耿传芝 | Kuangmei shampoo |
| WO2002045665A1 (en) * | 2000-12-09 | 2002-06-13 | Henkel Kommanditgesellschaft Auf Aktien | Novel use of polyhydroxy compounds |
| WO2004054526A1 (en) * | 2002-12-13 | 2004-07-01 | Unilever Plc | Hair treatment compositions |
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|---|---|
| CN1964693A (en) | 2007-05-16 |
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