WO2002037590A1 - Energy efficient gas separation for fuel cells - Google Patents

Energy efficient gas separation for fuel cells Download PDF

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Publication number
WO2002037590A1
WO2002037590A1 PCT/CA2001/001522 CA0101522W WO0237590A1 WO 2002037590 A1 WO2002037590 A1 WO 2002037590A1 CA 0101522 W CA0101522 W CA 0101522W WO 0237590 A1 WO0237590 A1 WO 0237590A1
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WO
WIPO (PCT)
Prior art keywords
fuel cell
gas
gas stream
fuel
oxygen
Prior art date
Application number
PCT/CA2001/001522
Other languages
English (en)
French (fr)
Inventor
Bowie G. Keefer
Denis J. Connor
Carl F. Hunter
Original Assignee
Questair Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CA002325072A external-priority patent/CA2325072A1/en
Application filed by Questair Technologies Inc. filed Critical Questair Technologies Inc.
Priority to AU13716/02A priority Critical patent/AU780651B2/en
Priority to CA002394924A priority patent/CA2394924A1/en
Priority to JP2002540232A priority patent/JP2004512665A/ja
Priority to BR0107399-0A priority patent/BR0107399A/pt
Priority to EP01982015A priority patent/EP1334529A1/en
Publication of WO2002037590A1 publication Critical patent/WO2002037590A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • CCHEMISTRY; METALLURGY
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0259Physical processing only by adsorption on solids
    • CCHEMISTRY; METALLURGY
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/104Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
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    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01DSEPARATION
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    • B01D2253/25Coated, impregnated or composite adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/16Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/102Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2257/50Carbon oxides
    • B01D2257/502Carbon monoxide
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7022Aliphatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0208Other waste gases from fuel cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40003Methods relating to valve switching
    • B01D2259/40005Methods relating to valve switching using rotary valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/414Further details for adsorption processes and devices using different types of adsorbents
    • B01D2259/4141Further details for adsorption processes and devices using different types of adsorbents within a single bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/0476Vacuum pressure swing adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/261Drying gases or vapours by adsorption
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
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    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86Carbon dioxide sequestration
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    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
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    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
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    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
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    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Fuel Cell (AREA)
  • Separation Of Gases By Adsorption (AREA)
PCT/CA2001/001522 2000-10-30 2001-10-26 Energy efficient gas separation for fuel cells WO2002037590A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU13716/02A AU780651B2 (en) 2000-10-30 2001-10-26 Energy efficient gas separation for fuel cells
CA002394924A CA2394924A1 (en) 2000-10-30 2001-10-26 Energy efficient gas separation for fuel cells
JP2002540232A JP2004512665A (ja) 2000-10-30 2001-10-26 燃料電池用エネルギー高効率ガス分離
BR0107399-0A BR0107399A (pt) 2000-10-30 2001-10-26 Separação de gás com energia eficiente para células de combustìvel
EP01982015A EP1334529A1 (en) 2000-10-30 2001-10-26 Energy efficient gas separation for fuel cells

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CA2,325,072 2000-10-30
CA002325072A CA2325072A1 (en) 2000-10-30 2000-10-30 Gas separation for molten carbonate fuel cell
US32316901P 2001-09-17 2001-09-17
US60/323,169 2001-09-17

Publications (1)

Publication Number Publication Date
WO2002037590A1 true WO2002037590A1 (en) 2002-05-10

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PCT/CA2001/001522 WO2002037590A1 (en) 2000-10-30 2001-10-26 Energy efficient gas separation for fuel cells

Country Status (7)

Country Link
EP (1) EP1334529A1 (ru)
JP (1) JP2004512665A (ru)
CN (1) CN1258829C (ru)
AU (1) AU780651B2 (ru)
BR (1) BR0107399A (ru)
RU (1) RU2280925C2 (ru)
WO (1) WO2002037590A1 (ru)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002067353A1 (en) * 2001-02-21 2002-08-29 Ballard Power Systems Inc. Fuel cell system having a pressure swing adsorption unit
WO2002073728A1 (en) * 2001-03-14 2002-09-19 Questair Technologies Inc. Electronic current generation system comprising a fuel cell and a rotary pressure swing absorption unit
WO2004025767A2 (en) * 2002-09-13 2004-03-25 Prototech As Power generation apparatus
WO2004030130A2 (en) * 2002-09-27 2004-04-08 Questair Technologies Inc. Solid oxide fuel cell systems
EP1620906A2 (en) * 2003-04-09 2006-02-01 Ion America Corporation Co-production of hydrogen and electricity in a high temperature electrochemical system
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FR2881578A1 (fr) * 2005-02-01 2006-08-04 Renault Sas Dispositif de pile a combustible equipe d'un element d'enrichissement en oxygene
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US8071246B2 (en) 2003-04-09 2011-12-06 Bloom Energy Corporation Method of optimizing operating efficiency of fuel cells
AT507853B1 (de) * 2009-02-11 2014-09-15 Vaillant Group Austria Gmbh Sofc-brennstoffzelle mit einem externen dampfreformer
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Cited By (19)

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WO2002067353A1 (en) * 2001-02-21 2002-08-29 Ballard Power Systems Inc. Fuel cell system having a pressure swing adsorption unit
WO2002073728A1 (en) * 2001-03-14 2002-09-19 Questair Technologies Inc. Electronic current generation system comprising a fuel cell and a rotary pressure swing absorption unit
WO2004025767A2 (en) * 2002-09-13 2004-03-25 Prototech As Power generation apparatus
WO2004025767A3 (en) * 2002-09-13 2004-07-29 Prototech As Power generation apparatus
WO2004030130A2 (en) * 2002-09-27 2004-04-08 Questair Technologies Inc. Solid oxide fuel cell systems
WO2004030130A3 (en) * 2002-09-27 2004-09-16 Questair Technologies Inc Solid oxide fuel cell systems
JP4800919B2 (ja) * 2003-01-14 2011-10-26 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 電気及び高濃度二酸化炭素の生成方法
JP2006515106A (ja) * 2003-01-14 2006-05-18 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 電気及び高濃度二酸化炭素の生成方法
EP1620906A2 (en) * 2003-04-09 2006-02-01 Ion America Corporation Co-production of hydrogen and electricity in a high temperature electrochemical system
US8663859B2 (en) 2003-04-09 2014-03-04 Bloom Energy Corporation Method of optimizing operating efficiency of fuel cells
EP1620906A4 (en) * 2003-04-09 2010-03-24 Bloom Energy Corp COPRODUCTION OF HYDROGEN AND ELECTRICITY IN A HIGH TEMPERATURE ELECTROCHEMICAL SYSTEM
US8071246B2 (en) 2003-04-09 2011-12-06 Bloom Energy Corporation Method of optimizing operating efficiency of fuel cells
US8071241B2 (en) 2003-04-09 2011-12-06 Bloom Energy Corporation Method for the co-production of hydrogen and electricity in a high temperature electrochemical system
FR2881578A1 (fr) * 2005-02-01 2006-08-04 Renault Sas Dispositif de pile a combustible equipe d'un element d'enrichissement en oxygene
EP2112709A4 (en) * 2007-02-07 2011-03-30 Central Res Inst Elect GENERATING INSTALLATION
EP2112709A1 (en) * 2007-02-07 2009-10-28 Central Research Institute of Electric Power Industry Power generating installation
AT507853B1 (de) * 2009-02-11 2014-09-15 Vaillant Group Austria Gmbh Sofc-brennstoffzelle mit einem externen dampfreformer
WO2010094391A1 (de) * 2009-02-19 2010-08-26 Daimler Ag Brennstoffzellensystem mit wenigstens einer brennstoffzelle
WO2024078724A1 (en) * 2022-10-14 2024-04-18 Volvo Truck Corporation A fuel cell system

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EP1334529A1 (en) 2003-08-13
JP2004512665A (ja) 2004-04-22
RU2280925C2 (ru) 2006-07-27
AU780651B2 (en) 2005-04-07
AU1371602A (en) 2002-05-15
CN1394368A (zh) 2003-01-29
RU2002120185A (ru) 2004-02-20
CN1258829C (zh) 2006-06-07

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