WO2002034226A1 - Compositions de parfum - Google Patents

Compositions de parfum Download PDF

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Publication number
WO2002034226A1
WO2002034226A1 PCT/US2000/030373 US0030373W WO0234226A1 WO 2002034226 A1 WO2002034226 A1 WO 2002034226A1 US 0030373 W US0030373 W US 0030373W WO 0234226 A1 WO0234226 A1 WO 0234226A1
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WO
WIPO (PCT)
Prior art keywords
perfume raw
raw materials
less
fragrance oil
composition according
Prior art date
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PCT/US2000/030373
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English (en)
Inventor
Gabor Heltovics
Lynette Anne Makins Holland
Jerome Anthony Janszen
Jill Maureen Mattila
Jane Margaret Warwick
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU2001215831A priority Critical patent/AU2001215831A1/en
Priority to EP00978359A priority patent/EP1328247A1/fr
Publication of WO2002034226A1 publication Critical patent/WO2002034226A1/fr
Priority to US10/422,880 priority patent/US7413731B2/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations

Definitions

  • the present invention relates to compositions, in particular cosmetic compositions, more particularly fragrance compositions, which comprise a fragrance oil and an entrapment material, wherein the fragrance oil comprises a low level of "top note” perfume raw materials and a high level of "high odour impact” perfume raw materials. More particularly this invention relates to cosmetic compositions wherein the pleasant fragrance character of the "high odour impact” perfume raw materials remains detectable on the substrate for at least 2 hours after application. Compositions of the present invention are suitable for application to a wide variety of substrates but particularly to the skin and hair.
  • compositions including cosmetic compositions, that they comprise a fragrance oil for the purpose of delivering a pleasant smell. This can improve the overall consumer acceptance of the composition or mask unpleasant odours. In fact, it can be the sole purpose of some compositions to impart a pleasant odour to suitable substrates including the skin and or hair.
  • Fragrance oils used within such compositions usually comprise many different perfume raw materials. Each perfume raw material used differs from another by several important properties including individual character, and volatility. By bearing in mind these different properties, and others, the perfume raw material can be blended to develop a fragrance oil with an overall specific character profile. To date, characters are designed to alter and develop with time as the different perfume raw materials evaporate from the substrate and are detected by the user. For example perfume raw materials which have a high volatility and low substantivity are commonly used to give an initial burst of characters such as light, fresh, fruity, citrus, green or delicate floral to the fragrance oil which are detected soon after application. Such materials are commonly referred to in the field of fragrances as "top notes”.
  • perfume raw materials are typically used to give characters such as musk, sweet, balsamic, spicy, woody or heavy floral to the fragrance oil which, although may also be detected soon after application, also last for longer. These materials are commonly referred to as “middle notes” or “base notes”. Highly skilled perfumers are usually employed to carefully blend perfume raw materials so that the resultant fragrance oils have the desired overall fragrance character profile. The desired overall character is dependent both upon the type of composition in which the fragrance oil will finally be used and also the consumer preference for a fragrance.
  • odour detection threshold In addition to the volatility, another important characteristic of a perfume raw material is its olfactory detection level, otherwise known as the odour detection threshold. If a perfume raw material has a low odour detection threshold, otherwise known as “high odour impact”, only very low levels are required of the raw material within a composition for it to be detected by the user, sometimes as low as a few parts per billion. Conversely, if a perfume raw material has a high odour detection threshold, otherwise known as a "low odour impact", larger amounts of that material are required before it can be smelt by the user.
  • fragrance oil which will impart, in a new way, fragrance materials with a high odour impact, such that they can be experienced both initially, and over a substantial period of time, by the user.
  • fragrance oils may be formulated to include a higher proportion of perfume raw materials with a low volatility and which are therefore more substantive on the substrate.
  • Another approach has been to chemically, and reversibly, modify the perfume raw materials to a pro-perfume compound which is disclosed in patent applications WO 98/47477; WO 99/43667; WO 98/07405; WO 98/47478; all of which are incorporated herein by reference.
  • the resultant pro-perfumes are not themselves volatile but, after the chemical modification is reversed, usually by hydrolysis upon application to the substrate, the perfume raw material is released and can then evaporate in the usual way.
  • the release rate of the perfume raw materials is controlled by the reaction rate of the pro-perfume to perfume raw material transformation. Further disclosures have discussed improving the overall longevity of a fragrance by delaying the evaporation of the fragrance oils.
  • JP-A-6/287127 and JP-A- 8/176587 which disclose use of hydroxyalkylated cyclodextrins within cosmetic compositions to sustain the effect of the fragrance
  • JP-A-8/183719 and JP-A- 10/120541 which discloses a combination of cyclodextrin encapsulated fragrance and non encapsulated fragrance within a deodorant composition for prolonging the fragrance duration to at least 2 hours, all of which are incorporated herein by reference.
  • compositions and disclosures of the prior art provide useful teachings for prolonging the overall fragrance character of different compositions the approaches still have limitations.
  • the pro-perfume approach is limited by those chemical modifications that can suitably be made to the perfume raw materials.
  • prior art is restricted by pro chemistries used thus preventing the development of a fragrance oil which exhibits a broad range of top note characters over time.
  • entrapment materials when used in the traditional way, interact with a broad range of perfume materials including top, middle and base notes prolonging the overall character of the whole fragrance.
  • the prior art does not sufficiently teach how to preferentially delay the evaporation of a large range of high odour impact perfume raw materials within a single fragranced composition such that these distinct characters can be recognised throughout the usage period.
  • entrapment such as that described suppresses the evaporation of only a relatively small amount of the perfume raw materials, the low level of delayed release is often not noticeable to the user.
  • the prior art does not adequately teach how to provide a fragrance wherein the prolonged character has sufficient strength to be noticeable and remains distinctive over time.
  • compositions comprising a fragrance oil and a material which is able to delay the evaporation of the fragrance oil, wherein the fragrance oil is blended to comprise low levels of "top note” perfume raw materials and high levels of "high odour impact” perfume raw materials, can be used to create a long lasting fragrance character profile which has prolonged, and noticeable distinct characters.
  • the fragrance oil is blended to comprise low levels of "top note” perfume raw materials and high levels of "high odour impact” perfume raw materials
  • this use of high levels of "high odour impact” perfume raw materials can result in a reduction in the level of fragrance oil that is required in the final finished product which can reduce skin sensitisation and can have cost reduction benefits both for the manufacturer and the consumer.
  • this use of "high odour impact” perfume raw materials can also result in a reduction in the level of entrapment material required to achieve the desired benefit which can have both aesthetic benefits for the final formulation in addition to further cost saving benefits.
  • compositions according to the present invention when a composition according to the present invention is applied to a substrate an association exists between the perfume raw materials and the entrapment material such that the evaporation of the perfume raw materials is delayed. Over time, this association breaks down resulting in release of the perfume raw materials. Since the composition comprises a fragrance oil which has been developed with a high level of "high odour impact" perfume raw materials, the very low levels of materials that are released from the association over time are easily detected by the user. In addition, despite the fact that the fragrance oil is developed with very high levels of "high odour impact" perfume raw materials, the association that forms means that the fragrance is not overwhelming when it is first applied.
  • the volatilisation rate of any given ingredient has, until now, been mainly related to its own boiling point, it has not been possible to obtain recurring and intermittent blooms (or pulses) of specific fragrance characters throughout the complete usage period.
  • the fragrance can be refreshed over time, either naturally or deliberately, to release periodic and unexpected blooms of one or several fragrance characters. Whilst not wishing to be bound by theory, it is believed that this can be achieved by enhancing the natural decomposition rate of the fragrance oil entrapment material association for example by application of water, either naturally by breathing on the complex or by sweating, or artificially by spraying on a mist and the like.
  • compositions which impart a long lasting and noticeable fragrance character to the substrate on which they are applied. It is a further object of this invention to provide a fragrance which maintains its initial character profile over time in a noticeable way.
  • the present invention relates to a composition
  • a composition comprising: (a) a fragrance oil wherein the fragrance oil comprises:
  • the present invention relates to a composition
  • a composition comprising:
  • fragrance oil wherein the fragrance oil comprises:
  • an entrapment material which is selected from the group consisting of polymers; capsules, microcapsules and nanocapsules; liposomes; pro-perfumes; film formers; absorbents; cyclic oligosaccharides and mixtures thereof;
  • This invention further relates to methods of use for such compositions and the use of such compositions to delay the release of the perfume raw materials from the substrate.
  • compositions, or components thereof are suitable for use in contact with human skin without undue toxicity, incompatibility, instability, allergic response, and the like.
  • safe and effective amount means an amount of a compound, component, or composition sufficient to significantly induce a positive benefit, but low enough to avoid serious side effects, i.e. to provide a reasonable benefit to risk ratio, within the scope of sound medical judgement.
  • Active and other ingredients useful herein may be categorised or described herein by their cosmetic and/or therapeutic benefit or their postulated mode of action. However, it is to be understood that the active and other ingredients useful herein can in some instances provide more than one cosmetic and/or therapeutic benefit or operate via more than one mode of action. Therefore, classifications herein are made for the sake of convenience and are not intended to limit an ingredient to the particularly stated application or applications listed.
  • Compositions of the present invention comprise from about 0.01% to about 99%, preferably from about 0.25% to about 50%, more preferably from about 0.5% to about 40%, even more preferably from about 1% to about 25%, and most preferably from about 2.5% to about 25%, by weight, of the fragrance oil.
  • fragment oil relates to a perfume raw material, or mixture of perfume raw materials, that are used to impart an overall pleasant odour profile to a composition, preferably a cosmetic composition.
  • perfume raw material relates to any chemical compound which is odiferous when in an un-entrapped state, for example in the case of pro-perfumes, the perfume component is considered, for the purposes of this invention, to be a perfume raw material, and the pro-chemistry anchor is considered to be the entrapment material.
  • perfume raw materials are defined by materials with a ClogP value preferably greater than about 0J, more preferably greater than about 0.5, even more preferably greater than about 1.0.
  • ClogP means the logarithm to base 10 of the octanol / water partition coefficient. This can be readily calculated from a programme called “CLOGP” which is available from Daylight Chemical Information Systems Inc., Irvine CA, USA. Octanol / water partition coefficients are described in more detail in US-A-5, 578,563.
  • a fragrance oil can be achieved which, when used in a composition in conjunction with an entrapment material, is able to impart a particular long lasting character to the composition in which it is used.
  • the mixture of perfume raw materials used will be carefully chosen and blended to achieve a fragrance oil with the desired overall fragrance character profile.
  • the fragrance oil itself can comprise any perfume raw material suitable for use in the compositions of the present invention. Overall the fragrance oil will most often be liquid at ambient temperatures and consist of a single individual perfume raw material.
  • a wide variety of chemicals are known for fragrance uses, including materials such as aldehydes, ketones and esters. However, naturally occurring plant and animal oils and exudates comprising complex mixtures of various chemical components are also commonly known for use as fragrances.
  • the individual perfume raw materials which comprise a known natural oil can be found by reference to Journals commonly used by those skilled in the art such as "Perfume and Flavourist” or "Journal of Essential Oil Research". In addition some perfume raw materials are supplied by the fragrance houses as mixtures in the form of proprietary speciality accords.
  • boiling point measured at 1 atmosphere pressure.
  • BP boiling point
  • Perfume raw materials for use in the present invention are divided into volatile raw materials (which have a boiling point of less than, or equal to, about 250°C) and residual raw materials (which have a boiling point of greater than about 250°C, preferably greater than about 275°C).
  • Volatile raw materials, for the purposes of this invention are considered to be those that impart "top note” ie light, fresh, fruity, citrus, green or delicate floral characters to the fragrance oil and the like.
  • the residual perfume raw materials are considered to be those that impart "middle or base note” ie musk, sweet, balsamic, spicy, woody or heavy floral characters to the fragrance oil and the like. All perfume raw materials will preferably have boiling points (BP) of about 500°C or lower.
  • odour detection threshold which is defined as the lowest vapour concentration of that material which can be olfactorily detected.
  • the odour detection threshold and some odour detection threshold values are discussed in eg "Standardized Human Olfactory Thresholds", M. Devos et al, URL Press at Oxford University Press, 1990, and "Compilation of Odor and Taste Threshold Values Data", F. A. Fazzalar, editor ASTM Data Series DS 48 A, American Society for Testing and Materials, 1978, both of said publications being incorporated by reference.
  • Perfume raw materials for use in the present invention can be classified as those with a low odour detection (ie "high odour impact”) with a detection threshold of less than 50 parts per billion, preferably less than 10 parts per billion and those with a high odour detection (ie "low odour impact”) with a threshold of greater than 50 parts per billion (values as determined from the references above).
  • perfume raw materials refer to a single individual compound, their physical properties (such ClogP, boiling point, odour detection threshold) can be found by referencing the texts cited above.
  • the perfume raw material is a natural oil, which comprises a mixture of several compounds, the physical properties of the complete oil should be taken as the weighted average of the individual components.
  • the perfume raw material is a proprietary speciality accord the physical properties should be obtain from the Supplier.
  • the fragrance oil comprises greater than about 50%, preferably from about 50% to about 95%, more preferably from about 60% to about 90% and even more preferably from about 65% to about 85%, by weight of the fragrance oil, of high odour impact perfume raw materials which have an odour detection threshold of less than, or equal to, about 50 parts per billion.
  • Compositions of the second aspect of the present invention comprise from about greater than about 40% to about 50%, by weight of the fragrance oil, high odour impact perfume raw materials.
  • the high odour impact perfume raw materials have an odour detection threshold of less than, or equal to about 40 parts per billion, preferably about 30 parts per billion, more preferably about 20 parts per billion and even more preferably about 10 parts per billion.
  • the fragrance oil should also comprise less than about 5%, preferably less than about 4%, more preferably less than about 3% and even more preferably less than about 2%, by weight of the fragrance oil, of top note perfume raw materials.
  • compositions of the present invention can comprise lower levels of fragrance oil than would traditionally be present.
  • compositions of the present invention can preferably comprise from about 1% to about 15%, preferably from about 1% to about 8%, and more preferably from about 2% to about 6%, by weight, of fragrance oil.
  • perfume raw materials in general a broad range of suitable perfume raw materials can be found in US-A- 4,145,184, US-A-4,209,417, US-A-4,515,705, and US-A-4, 152,272.
  • suitable perfume raw materials which are useful for blending to formulate fragrance oils for the present invention are given below. Any perfume raw materials, natural oils or proprietary speciality accords known to a person skilled in the art can be used within the present invention.
  • Examples of residual "middle and base note” perfume raw materials having a boiling point of greater than 250°C, which have a low odour detection threshold are selected from, but are not limited to, ethyl methyl phenyl glycidate, ethyl vanillin, heliotropin, indol, methyl anthranilate, vanillin, amyl salicylate, coumarin.
  • residual perfume raw materials having a boiling point of greater than 250°C which are generally known to have a low odour detection threshold include, but are not limited to, ambrox, bacdanol, benzyl salicylate, butyl anthranilate, cetalox, ebanol, cis-3-hexenyl salicylate, lilial, gamma undecalactone, gamma dodecalactone, gamma decalactone, calone, cymal, dihydro iso jasmonate, iso eugenol, lyral, methyl beta naphthyl ketone, beta naphthol methyl ether, para hydroxyl phenyl butanone, 8-cyclohexadecen-l-one, oxocyclohexadecen-2-one / habanolide, florhydral, intreleven aldehyde.
  • Examples of volatile "top note” perfume raw materials having a boiling point of less than, or equal to, 250°C, with a low odour detection threshold are selected from, but are not limited to, anethol, methyl heptine carbonate, ethyl aceto acetate, para cymene, nerol, decyl aldehyde, para cresol, methyl phenyl carbinyl acetate, ionone alpha, ionone beta, undecylenic aldehyde, undecyl aldehyde, 2,6-nonadienal, nonyl aldehyde, octyl aldehyde.
  • volatile perfume raw materials having a boiling point of less than, or equal to, 250°C which are generally known to have a low odour detection threshold include, but are not limited to, phenyl acetaldehyde, anisic aldehyde, benzyl acetone, ethyl-2-methyl butyrate, damascenone, damascone alpha, damascone beta, flor acetate, frutene, fructone, herbavert, iso cyclo citral, methyl isobutenyl tetrahydro pyran, iso propyl quinoline, 2,6-nonadien-l-ol, 2-methoxy-3- (2-methylpropyl)- pyrazine, methyl octine carbonate, tridecene-2-nitrile, allyl amyl glycolate, cyclogalbanate, cyclal C, melonal, gamma nonalactone, cis
  • volatile "top note” perfume raw materials having a boiling point of less than, or equal to, 250°C which should be used in low levels in the present invention, but which have a high odour detection threshold, are selected from, but are not limited to, benzaldehyde, benzyl acetate, camphor, carvone, borneol, bornyl acetate, decyl alcohol, eucalyptol, linalool, hexyl acetate, iso-amyl acetate, thymol, carvacrol, limonene, menthol, iso-amyl alcohol, phenyl ethyl alcohol, alpha pinene, alpha terpineol, citronellol, alpha thujone, benzyl alcohol, beta gamma hexenol, dimethyl benzyl carbinol, phenyl ethyl dimethyl carbinol, adoxal, allyl
  • compositions of the present invention comprise an entrapment material preferably at a level of from about 0.1% to about 95%, preferably from about 0.5% to about 50%, more preferably from about 1% to about 25% and even more preferably from about 2% to about 8%, by weight, of an entrapment material.
  • an "entrapment material” is any material which, after application of the composition to a substrate, suppresses the volatility of the perfume raw materials within the fragrance oil thus delaying their evaporation. It is not necessary that the entrapment material forms an association with the perfume raw material within the composition itself, only that this association exists on the substrate after application of the composition.
  • Non limiting examples of mechanisms by which the delay in evaporation may occur are by the entrapment material reversibly or irreversibly, physically or chemically associating with the perfume raw material through complexing, encapsulating, occluding, absorbing, binding, or otherwise adsorbing the perfume raw materials of the fragrance oil.
  • reversible entrapment means that any entrapment material: perfume raw material association in which the association can be broken down so that the entrapment material and perfume raw materials are released from each other.
  • irreversible entrapment means that the entrapment material: perfume raw material association can not be broken down.
  • chemically associated means that the entrapment material and perfume raw material are linked through a covalent, ionic, hydrogen or other type of chemical bond.
  • physically associated means that the entrapment material and perfume raw material are linked through a bond with a weaker force such as a Nan der Waals force. Highly preferred is that, upon the substrate, the entrapment material and the perfume raw material form a reversible physical or chemical association.
  • to delay the evaporation of a perfume raw material means to slow down or inhibit the evaporation rate of said perfume raw material from the substrate such that the distinctive fragrance character of the perfume raw material is detectable for at least 2 hours after application to the substrate.
  • Entrapment materials for use herein are selected from polymers; capsules, microcapsules and nanocapsules; liposomes; pro-perfumes; film formers; absorbents; cyclic oligosaccharides and mixtures thereof. Preferred are pro-perfumes, absorbents and cyclic oligosaccharides and mixtures thereof. Highly preferred are cyclic oligosaccharides.
  • the weight ratio of high odour detection perfume raw material to entrapment material within the associated form is in the range from about 1:20 to about 20:1, preferably from about 1:10 to about 10:1, more preferably in the range from about 1 :7 to about 7:1, even more preferably in the range from about 1:5 to about 5:1, further more preferably from about 1:3 to about 3:1 and most preferably in the range from about 1 :2 to about 2:1.
  • compositions of the present invention that the entrapment material reversibly, chemically and physically complexes the perfume raw materials.
  • entrapment materials that can act in this way are cyclic oligosaccharides, or mixtures of different cyclic oligosaccharides.
  • cyclic oligosaccharide means a cyclic structure comprising six or more saccharide units.
  • Preferred for use herein are cyclic oligosaccharides having six, seven or eight saccharide units and mixtures thereof, more preferably six or seven saccharide units and even more preferably seven saccharide units. It is common in the art to abbreviate six, seven and eight membered cyclic oligosaccharides to ⁇ , ⁇ and ⁇ respectively.
  • the cyclic oligosaccharide of the compositions used for the present invention may comprise any suitable saccharide or mixtures of saccharides.
  • suitable saccharides include, but are not limited to, glucose, fructose, mannose, galactose, maltose and mixtures thereof.
  • preferred for use herein are cyclic oligosaccharides of glucose.
  • the preferred cyclic oligosaccharides for use herein are ⁇ - cyclodextrins or ⁇ - cyclodextrins, or mixtures thereof, and the most preferred cyclic oligosaccharides for use herein are ⁇ - cyclodextrins.
  • the cyclic oligosaccharide, or mixture of cyclic oligosaccharides, for use herein maybe substituted by any suitable substituent or mixture of substituents.
  • the use of the term "mixture of substituents" means that two or more different suitable substituents can be substituted onto one cyclic oligosaccharide.
  • the derivatives of cyclodextrins consist mainly of molecules wherein some of the OH groups have been substituted.
  • Suitable substituents include, but are not limited to, alkyl groups; hydroxyalkyl groups; dihydroxyalkyl groups; (hydroxyalkyl)alkylenyl bridging groups such as cyclodextrin glycerol ethers; aryl groups; maltosyl groups; allyl groups; benzyl groups; alkanoyl groups; cationic cyclodextrins such as those containing 2-hydroxy-3-(dimethylamino) propyl ether; quaternary ammonium groups; anionic cyclodextrins such as carboxyalkyl groups, sulphobutylether groups, sulphate groups, and succinylates; amphoteric cyclodextrins; and mixtures thereof.
  • Other cyclodextrin derivatives are disclosed in copending application US 09/32192 (27 th May 1999), all of which are incorporated herein by reference.
  • the substituents may be saturated or unsaturated, straight or branched chain.
  • Preferred substituents include saturated and straight chain alkyl groups, hydroxyalkyl groups and mixtures thereof.
  • Preferred alkyl and hydroxyalkyl substituents are selected from Ci-C 8 alkyl or hydroxyalkyl groups or mixtures thereof, more preferred alkyl and hydroxyalkyl substituents are selected from Ci-C 6 alkyl or hydroxyalkyl groups or mixtures thereof, even more preferred alkyl and hydroxyalkyl substituents are selected from C ⁇ -C alkyl or hydroxyalkyl groups and mixtures thereof.
  • Especially preferred alkyl and hydroxyalkyl substituents are propyl, ethyl and methyl, more especially hydroxypropyl and methyl and even more preferably methyl.
  • cyclic oligosaccharides for use in the present invention are unsubstituted, or are substituted by only saturated straight chain alkyl, or hydroxyalkyl substituents. Therefore, preferred examples of cyclic oligosaccharides for use herein are ⁇ -cyclodextrin, ⁇ - cyclodextrin, methyl- ⁇ -cyclodextrin, methyl- ⁇ -cyclodextrin, hydroxypropyl- ⁇ - cyclodextrin and hydroxypropyl- ⁇ -cyclodextrin. Most preferred examples of cyclic oligosaccharides for use herein are methyl- ⁇ -cyclodextrin and methyl- ⁇ -cyclodextrin. These are available from Wacker-Chemie GmbH Hanns-Seidel-Platz 4, Munchen, DE under the tradename Alpha W6 M and Beta W7 M respectively. Especially preferred is methyl- ⁇ -cyclodextrin.
  • the cyclic oligosaccharides of the compositions used for the present invention have an average degree of substitution of at least 1.6, wherein the term "degree of substitution” means the average number of substituents per saccharide unit.
  • Preferred cyclic oligosaccharides for use herein have an average degree of substitution of less than about 2.8. More preferably the cyclic oligosaccharides for use herein have an average degree of substitution of from about 1.1 to about 2.0.
  • the average number of substituents can be determined using common Nuclear Magnetic Resonance techniques known in the art.
  • the cyclic oligosaccharides of the compositions used for the present invention are preferably soluble in both water and ethanol.
  • soluble means at least about OJg of solute dissolves in 100ml of solvent, at 25°C and 1 atm of pressure.
  • the cyclic oligosaccharides for use herein have a solubility of at least about Ig/lOOml, at 25°C and latm of pressure. Preferred is that cyclic oligosaccharides are only present at levels up to their solubility limits in a given composition at room temperature.
  • Encapsulation of fragrances within capsules, micro-capsules or nanaocapsules which are broken down by environmental triggers can be used to reduce the volatility of fragrance oils by surrounding the oil by small droplets as a resistant wall. This may be either water sensitive or insensitive, h the first case the fragrance can be released when the encapsulated particle is affected by moisture loss from the skin; while in the second case the capsule wall must be ruptured mechanically before the fragrance is released.
  • Encapsulation techniques are well known in the art including DE 1,268,316; US 3,539,465; US 3,455,838.
  • Moisture sensitive capsules, micro-capsules and nanocapsules are preferably formed from, but not limited to, a polysaccharide polymer.
  • suitable polymers are dextrins, especially low-viscosity dextrins including maltodextrins.
  • a particularly preferred example of a low viscosity dextrin is one which, as a 50% dispersion in water has a viscosity at 25 °C, using a Brookfield Niscometer fitted with an "A" type T-Bar rotating at 20rpm in helical mode, of 330 ⁇ 20mPa.s. This dextrin is known as Encapsul 855 and is available from National Starch and Chemicals Ltd.
  • a further example of a polysaccharide that can be used to form the moisture sensitive capsules is gum acacia.
  • Time release micro-capsules are also suitable for use in compositions of the present invention for entrapping hydrophobic perfume raw materials.
  • Such compositions comprise the perfume raw materials encapsulated in a wax or polymer matrix which in turn is coated with a compatible surfactant.
  • the wax or polymers used to form the matrix have a melting point in the range from about 35°C to about 120°C at 1 atmosphere pressure. These are described in detail in EP-A-908,174.
  • Film formers can also be used to reduce the volatility profile of perfume raw materials. When the fragrance is applied to a substrate, such as the skin, it is believed that film formers entrap the fragrance oils during the evaporation of the volatile solvent thus hindering the release of the volatile material. Any film former which is compatible with the perfume raw materials may be used, preferably the film former will be soluble in water - ethanol mixture. Film former materials useful in this invention include, but are not limited to, ionic and non-ionic derivatives of water soluble polymers. Examples of suitable film forming materials are water soluble polymers containing a cationic moiety such as polyvinyl pyrrolidine and its derivatives having a molecular weight of 50,000 to 1,000,000.
  • ionic polymeric film forming materials are cationic cellulose derivatives sold under the trade names of Polymer TR (union Carbide), Khicel GM (hercules) and ethoxylated polyethyleneimine sold under the trade name PEI 600 (Dow).
  • suitable cellulosic derivatives such as hydroxymethyl cellulose, hydroxypropyl methylcellulose and hydroxyethyl cellulose.
  • film formers is benzophenone.
  • Non limiting examples of film forming materials are given in US 3,939,099.
  • polyacrylic acids and their water-soluble salts are useful in the present invention to delay the evaporation rate of certain amine-type odours.
  • Preferred polyacrylic acids and their alkali metal salts have an average molecular weight of less than about 20, 000, preferably less than 10, 000, more preferably from about 500 to about 5, 000.
  • Polymers containing sulphonic acid groups, phosphoric acid groups, phosphonic acid groups arid their water soluble salts, and their mixtures thereof, and mixtures with carboxylic acid and carboxylate groups, are also suitable.
  • Water soluble polymers containing both cationic and anionic functionalities are also suitable. Examples of these polymers are given in US Patent 4,909,986. Another example of water-soluble polymers containing both cationic and anionic functionalities is a copolymer of dimethyldiallyl ammonium chloride and acrylic acid, commercially available under the trade name Merquat 280® from Calgon. Pro-Perfumes
  • Pro-perfumes or pro-fragrances from perfume raw materials can result in compounds which impart a delayed release mechanism to that specific perfume raw material.
  • Pro-perfumes useful within the present invention preferably include those selected from more than 1 type of pro-chemistry which ensures that a wide range of possible perfume raw materials can be used.
  • the perfume raw material has been reacted with more than one type of chemical groups such as acetal, ketal, ester, hydrolysable inorganic -organic.
  • the perfume raw material is considered to constitute part of the fragrance oil and the chemical groups to constitute part of the entrapment material.
  • Pro-perfumes themselves are designed to be non- volatile, or else have a very low volatility.
  • the perfume raw material is released from the pro-perfume. Once released the perfume raw material has its original characteristics.
  • the perfume raw material may be released from the pro-perfume in a number of ways.
  • fragrances herein can be relatively simple in their compositions, comprising a single chemical , or can comprise highly sophisticated complex mixtures of natural and synthetic chemical components, all chosen to provide any desired odour.
  • Non-limiting pro-perfumes suitable for use in the present application are described in WO 98/47477, WO 99/43667, WO 98/07405, WO 98/47478 and copending applications US 60/105380 (23rd Oct 1998) and US 60/130108 (20 th April 1999).
  • odour absorbing materials such as zeolites and / or activated carbon can be used to modify the release rate of perfume raw materials.
  • a preferred class of zeolites is characterised as "intermediate" silicate / aluminate zeolites.
  • the intermediate zeolites are characterised by SiO 2 / AlO 2 molar ratios of less than about 10, preferably in the range from about 2 to about 10.
  • the intermediate zeolites have an advantage over the "high" zeolites since they have an affinity for amine-type odours, they are more weight efficient for odour absorption since they have a larger surface area and they are more moisture tolerant and retain more of their odour absorbing capacity in water than the high zeolites.
  • a wide variety of intermediate zeolites suitable for use herein are commercially available as Nalfor® CP301-68, Nalfor® 300-63, Nalfor® CP300-35 and Nalfor® 300-56 available from PQ Corporation, and the CBN 100® series of zeolites from Conteka.
  • Zeolite materials marketed under the trade name Abscents® and Smellrite® available from The Union Carbide Corporation and UOP are also preferred. These materials are typically available as a white powder in the 3-5 ⁇ m particle size range. Such materials are preferred over the intennediate zeolites for control of sulphur containing odours eg thiols, mercaptans.
  • Carbon materials suitable for use in the present invention are materials well known in commercial practice as absorbents for organic molecules and / or for air purification purposes. Often, such carbon material is referred to as "activated” carbon or "activated charcoal". Such carbon is available from commercial sources under trade names as; Calgon-Type CPG®; Type PCB®; Type SGL®; Type CAL®; and Type OL®.
  • odour absorbers suitable for use herein include silica molecular sieves, activated alumina, bentonite and kaolonite.
  • compositions of the second aspect of the present invention comprise greater than about 50%, by weight of the composition, of volatile solvent or mixture of volatile solvents whilst compositions of the first aspect of the present invention preferably comprise greater than about 50%, by weight, of a volatile solvent, or mixture of volatile solvents. In all aspects it is preferred that the compositions comprise from about 55% to about 99.9%, more preferably from about 60% to about 95%, even more preferably from about 65% to about 75%, by weight, of a volatile solvent or mixture of volatile solvents. Any volatile solvent suitable for use in the compositions can be used herein.
  • the solvents for use herein are preferably organic volatile solvents.
  • volatile refers to substances with a significant amount of vapour pressure under ambient conditions, as is understood by those in the art.
  • the volatile solvents for use herein will preferably have a vapour pressure of about 2kPa or more, more preferably about 6kPa or more at 25°C.
  • the volatile solvents for use herein will preferably have a boiling point under 1 atm, of less than about 150°C, more preferably less than about 100°C, even more preferably less than about 90°C, even more preferably still less than about 80°C.
  • the volatile solvents for use herein will be safe for use on a wide range of substrates, more preferably on human or animal skin or hair.
  • Suitable volatile solvents include, but are not limited to, those found in the CTFA International Cosmetic Ingredient Dictionary and Handbook, 7 f ' edition, volume 2 PI 670 - 1672, edited by Wenninger and McEwen (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D. C, 1997).
  • volatile solvents include C -C ⁇ 4 saturated and unsaturated, straight or branched chain hydrocarbons such as cyclohexane, hexane, heptane, isooctane, isopentane, pentane, toluene, xylene; halogenated alkanes such as perfluorodecalin; ethers such as dimethyl ether, diethyl ether; straight or branched chain alcohols and diols such as methanol, ethanol, propanol, isopropanol, n-butyl alcohol, t- butyl alcohol, benzyl alcohol, butoxypropanol, butylene glycol, isopentyldiol; aldehydes and ketones such as acetone; volatile silicones such as cyclomethicones for example octamethyl cyclo tetrasiloxane and decamethyl cyclopentane siloxane; volatile silane,
  • Preferred volatile solvents are ethers such as dimethyl ether, diethyl ether; straight or branched chain alcohols and diols such as methanol, ethanol, propanol, isopropanol, n-butyl alcohol, t- butyl alcohol, benzyl alcohol, butoxypropanol, butylene glycol, isopentyldiol; volatile silicones such as cyclomethicones for example octamethyl cyclo tetrasiloxane and decamethyl cyclopentane siloxane; propellants, and mixtures thereof. More preferred for use herein are C ⁇ -C straight chain or branched chain alcohols for example methanol, ethanol, propanol, isopropanol and butanol and mixtures thereof, and most preferred for use herein is ethanol.
  • compositions herein are useful for use a fragrance component to a wide variety of different types of compositions including those such as cosmetic compositions, fragrance compositions for human or animal use, air freshener compositions, aromatherapy compositions, laundry and cleaning compositions, fragranced paper, cloth or other substrate type products and the like, in fact in any type of composition which comprises a fragrance.
  • the compositions would comprise a variety of other optional ingredients which would render the compositions more acceptable or provide them with additional usage benefits.
  • Such conventional optional ingredients are well- known to those skilled in the art and will vary greatly depending upon the field in which the compositions are to be used.
  • compositions according to the second aspect of this invention comprise greater than 50% volatile solvent they should still be considered as being useful for inclusion in a wide variety of compositions with both cosmetic and non cosmetic benefits.
  • compositions can comprise any cosmetically acceptable ingredients such as those found in the CTFA International Cosmetic Ingredient Dictionary and Handbook, 7th edition, edited by Wenninger and McEwen, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1997).
  • cosmetically acceptable means a material (e.g., compound or composition) which is suitable for use in contact with skin, hair or other suitable substrate as defined herein below.
  • these ingredients are listed as useful for inclusion within a cosmetic composition does not preclude them from being incorporated into any other type of composition which comprises a fragrance formulated according to the present invention.
  • compositions of the present invention must comprise a volatile solvent they may also comprise "nonvolatile" solvents.
  • suitable non-volatile solvents include, but are not limited to, benzyl benzoate, diethyl phthalate, isopropyl myristate, and mixtures thereof.
  • low molecular weight polyol molecular wedge having from about 2 to about 12 carbon atoms, preferably from about 2 to about 6 carbon atoms and at least one -OH functional group, preferably at least 2 -OH functional groups are preferably used herein for further prolonging the fragrance character of the composition.
  • These polyols can further contain ether groups within the carbon chain. Suitable examples include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol and mixtures thereof.
  • these polyols are present at a level of from about 0.01% to about 20%, preferably from about 0.1% to about 10%, and especially from about 0.5% to about 5% by weight of composition. It is preferred that the molar ratio of molecular wedge material to oligosaccharide is from 10:1 to 1:10, preferably 1:1 or greater, especially 1:1.
  • the above mentioned molecular wedge molecules can form tertiary inclusion complexes with the complexed perfume material and the cyclic oligosaccharide.
  • These small dipolar molcules can fit into the cavity of the cyclic oligosaccharide and anchor via their OH groups onto the outside rim of the cyclic oligosaccharide through hydrogen bonding. This enables the inclusion of all or parts of the fragrance material into the cavity of the cyclic oligosaccharide such that the stability of the formed tertiary complex is increased versus the complex formed by the fragrance material and cyclic oligosaccharide alone.
  • compositions of the present invention may also comprise water. If present, the water will preferably comprise from about 0.1% to about 40%, more preferably from about 1% to about 30%, even more preferably about 5% to about 20%, by weight, of total composition. When the composition is a cosmetic composition the level of water should not be so high that the product becomes cloudy thus negatively impacting the product aesthetics.
  • compositions for cosmetic use include, but are not limited to, alcohol denaturants such as denatonium benzoate; UN stabilisers such as benzophenone-2; antioxidants such as tocopheryl acetate; preservatives such as phenoxyethanol, benzyl alcohol, methyl paraben, propyl paraben; dyes; pH adjusting agents such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; deodorants and anti-microbials such as farnesol and zinc phenolsulphonate; humectants such as glycerine; oils; skin conditioning agents such as allantoin; cooling agents such as trimethyl isopropyl butanamide and menthol; hair conditioning ingredients such as panthenol, panthetine, pantotheine, panthenyl ethyl ether, and combinations thereof; silicones
  • alcohol denaturants such as denatonium benzoate
  • UN stabilisers such as benzo
  • compositions for use in the present invention may take any form suitable for use, more preferably for cosmetic use. These include, but are not limited to, vapour sprays, aerosols, emulsions, lotions, liquids, creams, gels, sticks, ointments, pastes, mousses, powders, granular products, substrates, cosmetics (eg semi-solid or liquid make-up, including foundations) and the like.
  • the compositions for use in the present invention take the forai of a vapour spray.
  • Compositions of the present invention can be further added as an ingredient to other compositions, preferably cosmetic compositions, in which they are compatible. As such they can be used within solid composition or applied substrates etc.
  • compositions for use in the present invention will preferably comprise an acceptable carrier, preferably a cosmetically acceptable carrier.
  • carrier means one or more compatible solid or liquid fillers, diluents, extenders and the like.
  • compatible means that the components of the compositions of this invention are capable of being combined with the primary actives of the present invention, and with each other, in a manner such that there is no interaction which would substantially reduce the efficacy of the composition under ordinary use situations.
  • the type of carrier utilised in the present invention depends of the type of product desired and may comprise, but are not limited to, solutions, aerosols, emulsions (including oil-in- water or water-in-oil), gels, solids and liposomes.
  • compositions and fragrance oils for use in the present invention should be prepared according to procedures usually used and that are well known and understood by those skilled in the art; with materials of similar phase partitioning can be added in any order.
  • the entrapment of the perfume raw materials can occur at any reasonable stage in the preparation of the overall composition.
  • the fragrance oil can be prepared in its entirety, then entrapped with a suitable material before addition to the remainder of the composition.
  • the entrapment material can be added to the balance of the composition prior to addition of the complete fragrance oil.
  • the present invention preferably relates to compositions, particularly cosmetic compositions, and more particularly fragrance compositions, which comprise a fragrance oil, in combination with an entrapment material, such that the fragrance profile preferably remains detectable for at least about 2 hours after applying the composition to the substrate.
  • composition comprising:
  • fragrance oil wherein the fragrance oil comprises:
  • an entrapment material which is selected from the group consisting of polymers; capsules, microcapsules and nanocapsules; liposomes; pro-perfumes; film formers; absorbents; cyclic oligosaccharides and mixtures thereof; wherein the fragrance character, or mixture of raw material characters, remain detectable for greater than about 2 hours, preferably greater than about 4 hours, more preferably greater than about 6 hours, after the composition has been applied to the substrate.
  • suitable substrate means any surface to which the present composition may be applied without an unduly adverse effect. This can include a wide range of substrates including human or animal skin or hair, paper, furnishings, materials, and can also include the air in a room. Preferred substrates are the skin or hair, especially the skin.
  • compositions of the present invention may be used in a conventional manner for fragrancing a suitable substrate.
  • An effective amount of the composition typically from about l ⁇ l to about lOOO ⁇ l, preferably from about lO ⁇ l to about 250 ⁇ l, more preferably from about 25 ⁇ l to about lOO ⁇ l, is applied to the substrate.
  • the composition maybe applied by hand but is preferably applied utilising a vaporiser.
  • the composition is then left to dry.
  • the scope of the present invention should be considered to cover one of more distinct applications of a product or the continuous release of a composition via a vaporiser or other type of atomiser.
  • Periodic blooming of the compositions of the present invention can be achieved by application, either naturally or artificially, of a material, such as water, which will drive the disassociation of the fragrance oil from the entrapment material.
  • a material such as water
  • Such a bloom can be achieved naturally by seating, breathing on the fragranced substrate, rubbing the substrate and the like, hi order to achieve such a bloom artificially it is necessary to use a refresher spray in conjunction with the compositions described herein.
  • a refresher spray should comprise a material such as water which is capable of driving the break down of the fragrance oil entrapment material association.
  • the refresher spray would be applied to the substrate, for example from an atomiser, whenever the boom was desired for example each hour after application of the fragrance to the substrate initially.
  • fragrance blooms would be achieved. It is expected that each fragrance bloom would last for less than about 30 minutes, preferably less than about 15 minutes, more preferably less than about 10 minutes and even more preferably less than about 5 minutes. Throughout wear a fragrance could be expected to be capable of blooming at least about 2 times or more, preferably about 4 times or more and more preferably about 6 times or more.
  • fragrance oil examples I-V are non limiting examples of the fragrance oil.
  • the perfume raw materials were mixed with stirring at room temperature.
  • Beta W7 M available from Wacker-Chemie GmbH, Hanns-Seidel-Platz 4, Munchen, DE
  • the cyclic oligosaccharide was dissolved in ethanol at room temperature with stirring.
  • PMU Polyoxymethylene Urea

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Abstract

La présente invention concerne une composition comprenant: (a) une huile de parfum comprenant: (i) de une à plusieurs matières premières parfumées présentant un impact olfactif important et un seuil de détection olfactive inférieur ou égal à environ 50 parties par 109, (ii) moins d'environ 5 % en poids d'huile de parfum, d'une matière première parfumée conférant une note de tête, laquelle matière présente un point d'ébullition inférieur à 250 °C à une certaine pression atmosphérique; (b) une matière de piégeage choisie dans le groupe comprenant des polymères; des capsules, microcapsules et nanocapsules; des liposomes; des pro-parfums; des substances filmogènes; des absorbants; des oligosaccharides cycliques et des mélanges de ceux-ci. La matière première parfumée et la matière de piégeage sont présentes dans une forme associée sur le substrat et le rapport massique des matières premières parfumées présentant un impact olfactif important et un seuil de détection olfactive inférieur ou égal à environ 50 parties par 109 sur la matière de piégeage dans la forme associée est compris entre environ 1:20 et environ 20:1. La présente invention concerne des compositions dans lesquelles la caractéristique parfumée peut être détectée pendant plus de deux heures environs, de préférence, pendant plus de quatre heures, et mieux encore, pendant plus de six heures, après application de la composition sur le substrat. .
PCT/US2000/030373 2000-10-27 2000-11-03 Compositions de parfum WO2002034226A1 (fr)

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AU2001215831A AU2001215831A1 (en) 2000-10-27 2000-11-03 Fragrance compositions
EP00978359A EP1328247A1 (fr) 2000-10-27 2000-11-03 Compositions de parfum
US10/422,880 US7413731B2 (en) 2000-10-27 2003-04-24 Fragrance compositions

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PCT/US2000/029765 WO2002043684A1 (fr) 2000-10-27 2000-10-27 Compositions de parfums
USPCT/US00/29765 2000-10-27

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US7125835B2 (en) 2002-10-10 2006-10-24 International Flavors & Fragrances Inc Encapsulated fragrance chemicals
US7585824B2 (en) 2002-10-10 2009-09-08 International Flavors & Fragrances Inc. Encapsulated fragrance chemicals
EP2110118A1 (fr) * 2008-04-15 2009-10-21 Takasago International Corporation Composition de réduction des mauvaises odeurs et utilisations de celle-ci
FR2968939A1 (fr) * 2010-12-21 2012-06-22 Oreal Composition cosmetique comprenant un sel de zinc particulier et un ester gras
WO2014151555A1 (fr) * 2013-03-15 2014-09-25 The Procter & Gamble Company Compositions de soin personnel
WO2015035458A1 (fr) * 2013-09-12 2015-03-19 Thales Australia Limited Modificateur de taux de combustion

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CN107287033B (zh) * 2017-07-14 2021-10-12 宝鸡文理学院 一种檀香精油球形微胶囊的制备方法
CN109749877B (zh) * 2017-11-01 2021-05-11 中国石油化工股份有限公司 硫化亚铁钝化清洗用组合物及其应用

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EP0908174A2 (fr) * 1997-09-18 1999-04-14 INTERNATIONAL FLAVORS & FRAGRANCES INC. Compositions pour parfumer au moins un matériau parfumable et appareil pour évaluer la diffusion de parfum
US5919752A (en) * 1997-04-24 1999-07-06 Procter & Gamble Perfumes having odor longevity benefits
US6013618A (en) * 1997-04-24 2000-01-11 Procter & Gamble Company Perfumes having odor longevity benefits

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US5919752A (en) * 1997-04-24 1999-07-06 Procter & Gamble Perfumes having odor longevity benefits
US6013618A (en) * 1997-04-24 2000-01-11 Procter & Gamble Company Perfumes having odor longevity benefits
EP0908174A2 (fr) * 1997-09-18 1999-04-14 INTERNATIONAL FLAVORS & FRAGRANCES INC. Compositions pour parfumer au moins un matériau parfumable et appareil pour évaluer la diffusion de parfum

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7125835B2 (en) 2002-10-10 2006-10-24 International Flavors & Fragrances Inc Encapsulated fragrance chemicals
US7196049B2 (en) 2002-10-10 2007-03-27 International Flavors & Fragrances, Inc Encapsulated fragrance chemicals
US7585824B2 (en) 2002-10-10 2009-09-08 International Flavors & Fragrances Inc. Encapsulated fragrance chemicals
EP2110118A1 (fr) * 2008-04-15 2009-10-21 Takasago International Corporation Composition de réduction des mauvaises odeurs et utilisations de celle-ci
FR2968939A1 (fr) * 2010-12-21 2012-06-22 Oreal Composition cosmetique comprenant un sel de zinc particulier et un ester gras
WO2012084901A1 (fr) * 2010-12-21 2012-06-28 L'oreal Composition cosmétique comprenant un sel de zinc et un ester gras solide
WO2014151555A1 (fr) * 2013-03-15 2014-09-25 The Procter & Gamble Company Compositions de soin personnel
WO2014151171A1 (fr) * 2013-03-15 2014-09-25 The Procter & Gamble Company Compositions de soin personnel
CN105050577A (zh) * 2013-03-15 2015-11-11 宝洁公司 个人护理组合物
CN105120835A (zh) * 2013-03-15 2015-12-02 宝洁公司 个人护理组合物
JP2016512565A (ja) * 2013-03-15 2016-04-28 ザ プロクター アンド ギャンブル カンパニー パーソナルケア組成物
JP2016515867A (ja) * 2013-03-15 2016-06-02 ザ プロクター アンド ギャンブル カンパニー パーソナルケア組成物
WO2015035458A1 (fr) * 2013-09-12 2015-03-19 Thales Australia Limited Modificateur de taux de combustion
AU2014321144B2 (en) * 2013-09-12 2018-06-28 Thales Australia Limited Burn rate modifier

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