WO2001085630A2 - Dispositif de formage de verre en feuilles - Google Patents
Dispositif de formage de verre en feuilles Download PDFInfo
- Publication number
- WO2001085630A2 WO2001085630A2 PCT/US2001/014900 US0114900W WO0185630A2 WO 2001085630 A2 WO2001085630 A2 WO 2001085630A2 US 0114900 W US0114900 W US 0114900W WO 0185630 A2 WO0185630 A2 WO 0185630A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass
- trough
- sheet
- molten glass
- forming
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
Definitions
- the invention pertains generally to the manufacture of glass sheet, and, more particularly to glass sheet formed from an overflow process. DESCRIPTION OF RELATED ART
- This invention relates to the manufacture of glass sheet that is currently used for the production of TFT/LCD display devices that are widely used for computers now and are expected to be used for television sets in the future.
- the glass that is used for these semiconductor powered display applications must have very high surface quality to allow the successful application of semiconductor type material.
- Sheet glass made using the apparatus of U.S. patent number 3,338,696, incorporated herein by reference makes the highest quality glass as formed and does not require post-processing.
- the patent teaches a manufacturing process termed: "the overflow process".
- the key feature of the overflow process is that the glass moves through the glass forming equipment and the untouched, "virgin glass", overflows and becomes the outside surface of the glass. Glass made using other processes requires grinding and/or polishing and thus does not have as fine a surface finish.
- a major drawback of the present overflow process is the limited range of production rates that can be accommodated by a given apparatus.
- Simple mathematics teaches that the mathematical product of glass flow, glass viscosity, and the tangent of the tilt angle must be a constant to make glass of uniform thickness for a given apparatus. In practice the angle of tilt has practical limitations and the simple mathematical assumptions fail because of non-linearity, thus the limited range of production rate .
- glass forming processes are intended to be run for years if possible. Stopping the line may take a month and re-starting another month. The whole system is run at extreme temperature, so the materials used are under constant stress and often wear or need to be adjusted. Stopping the production to make these adjustments or repairs is a highly undesirable option.
- the apparatus of "The Overflow Process" makes excellent glass during stable operating conditions, but it recovers from transient conditions very slowly. This is because the flow of glass through the forming apparatus is quite non-uniform.
- the glass that flows into the apparatus and forms the inflow end of the sheet has a different time history than the glass forming the far end of the sheet. Because the glass flow is from one end to the other, on the order of 10 percent of the glass on the far end of the sheet is at least one hour older than the equivalent glass on the near end. An additional time differential is caused by the rectangular cross-section of the trough which has regions of glass where the flow velocity is very slow.
- U.S. Patent number 3,338,696 Another drawback of the apparatus shown in U.S. Patent number 3,338,696 is that its physical size becomes larger as production rate is increased. Apparatus durability often requires that parts of the device are made from or coated with refractory metal, i.e. platinum. Thus increasing the size of the system substantially raises the cost of the manufacturing apparatus.
- the weir overflow process apparatus becomes large as production rates increase because the flow of glass in the trough, channeling glass to the overflow weirs, relies on gravitational flow. As the glass flow rate increases, either the trough must be larger, the slope of the weirs steeper, or the glass viscosity lower to accommodate this increased glass flow. Therefore, the range of production rates that can be accommodated by a given size apparatus is limited
- Another drawback is that the apparatus can only make glass sheet of a fixed width.
- the present invention includes design features that can be used alone or in combination to facilitate faster, more uniform flow of glass through the apparatus and allows the thickness of the sheet to be adjusted.
- An overflow device is provided at the far end of the trough and is used in conjunction with tilting of the apparatus to expand the range of glass flow rate and glass viscosity for which this invention will produce satisfactory product.
- the overflow device may be used in conjunction with tilting of the apparatus, changes in glass flow rate, and changes in glass viscosity (temperature) to regulate the thickness profile of the sheet, hi addition, the forming apparatus can be made with non-linear weirs to provide a greater range of flow rates.
- the glass flow in the inflow pipe can be modulated to provide more uniform time dependent flow for forming the sheet.
- a contoured trough cross-section is taught which can minimize the quiescent flow regions.
- the forming apparatus can include an orifice on top of the trough and glass can be moved through the apparatus using pressure.
- the orifice is narrow at the inlet end and wider at the far end to accommodate for the loss in static pressure of the glass as it flows to that end.
- a forming apparatus can be provided with additional orifices on the bottom or sides to allow greater variability in sheet thickness. Effectively, an additional orifice adds glass to the middle of the formed sheet.
- Irregularities in the thickness of the formed glass sheet may be corrected by selective heating of the glass in the trough, heating the weirs or orifice. This requires selective heating of the glass flowing down the outside of the apparatus to restore temperature uniformity at the bottom of the apparatus where the sheet is formed.
- a flow control plug can be inserted into the trough, such that flow dynamics can be altered during hot operation by insertion, removal or position adjustment of the flow control plug.
- Figures la, lb and lc show a top, side and an inlet view of a typical overflow glass forming apparatus.
- Figures 2a, 2b, 2c and 2d show a top, side, end and an inlet view of an embodiment of a forming apparatus that has a trough with straight sloped weirs, a contoured bottom and an overflow device.
- Figures 3a, 3b, 3c and 3d show a top, side, end and an inlet view of an embodiment of a forming apparatus that has a trough with contoured weirs and a contoured bottom.
- Figures 4a, 4b, 4c and 4d show a top, side, end and an inlet view of an embodiment of a forming apparatus that has a trough with contoured weirs and a flat bottom.
- Figure 5 is an illustration of the velocity distribution of the glass flow through the inflow pipe and the trough of the forming apparatus.
- Figures 6a, 6b and 6c are illustrations of cross-sections of the inflow pipe of the forming apparatus through the section shown in Figure 6d.
- Figures 7a, 7b and 7c are illustrations of cross-sections of the trough of the forming apparatus through the section shown in Figure 7d.
- Figures 8a, 8b and 8c show a top, side and an inlet view of an embodiment that would be typical of a relatively low inlet pressure.
- Figures 9a, 9b and 9c show a top, side and an inlet view of an embodiment that would be typical of a relatively high inlet pressure.
- Figures 10a, 10b and 10c show a top, side and an inlet view of an embodiment that has a simple trough shape and a relatively low inlet pressure.
- Figures 1 la, 1 lb and lie show a top, side and an inlet view of an embodiment that has a simple trough, an orifice that is not in a horizontal plane, and a relatively low inlet pressure.
- Figures 12a, 12b and 12c show a top, side and an inlet view of an embodiment that has a simple trough shape, an internally mounted flow control plug and a relatively high inlet pressure.
- Figures 13a, 13b and 13c show a top, side and an inlet view of an internal flow control plug.
- Figures 14a, 14b and 14c show a top, side and an inlet view of an embodiment with a horizontal top orifice, a horizontal bottom orifice, and a shaped trough.
- Figures 15a, 15b and 15c show a top, side and an inlet view of one of two sides of the apparatus shown in Figures 14a-14c, which are in this instance mirror images.
- Figures 16a, 16b and 16c show a top, side and an inlet view of an embodiment with a horizontal top orifice, a horizontal bottom orifice, and a constant cross section trough.
- Figures 17a, 17b and 17c show a top, side and an inlet view of an embodiment which is the same as that shown in Figures 16a- 16c, but with an internal plug which is used to vary sheet width.
- Figures 18a, 18b and 18c show a top, side and an inlet view of an internal flow control plug used in the embodiment shown in Figures 17a- 17c.
- Figures 19a, 19b and 19c show a top, side and an inlet view of an embodiment with a sloped top surface with a weir on each side, a horizontal bottom orifice, and a shaped trough.
- Figures 20a, 20b and 20c show a top, side and an inlet view of an embodiment where the elements form a horizontal top orifice and two horizontal side orifices.
- Figures 21a, 21b and 21c show a top, side and an inlet view of the two side elements and the bottom forming wedge of the apparatus shown in Figures 20a-20c.
- Figures 22a, 22b and 22c show a top, side and an inlet view of an embodiment where the elements form a sloped top surface with weirs at each side and two horizontal side orifices.
- Figures 23 a, 23b and 23 c show a top, side and an inlet view of the two side elements and the bottom forming wedge of the apparatus shown in Figures 22a-22c.
- Figures 24a-24c show a top, side and an inlet view of an embodiment that has radiant top heating devices and radiant side heating devices.
- the present invention teaches that faster, more uniform flow of glass can be accomplished in the overflow glass process by modifying the forming apparatus in substantial ways. This process is currently used for making glass sheets that go into TFT/LCD display devices.
- the glass must have very high surface quality and sheet glass made using the overflow process has this quality.
- the overflow process is defined as a process that: 1) moves molten glass into a trough; 2) allows the glass to overflow the sides of the trough; and 3) the glass overflowing each side comes together such that the outside surface of the glass sheet is formed from glass that has not touched the surface of the glass forming equipment (post mixing). This untouched, "virgin glass", forms an extremely uniform and clean outside surface of the glass sheet. Any modifications to the process or apparatus must provide this high quality glass surface.
- the flow dynamics in all embodiments of this invention are such that the outside surfaces of the glass sheet are formed from thoroughly mixed virgin glass that comes from the center of the glass stream flowing into the forming apparatus and thus has not contacted a refractory or refractory metal surface. This produces the highest possible surface quality.
- This pristine surface is essential for the manufacture of LCD/TFT semiconductor display devices.
- the glass flow into this apparatus from a stirring device or alternately from a forehearth bowl must be thoroughly mixed to eliminate cord and insure homogenous glass.
- a suitable overflow chamber may be required to insure that the glass flowing to the process is of the most uniform quality. Stirring and overflow chambers are satisfactorily understood glass manufacturing technology to those of skill in the art and the various possible designs are not specifically disclosed.
- FIG. lc an overflow glass sheet forming apparatus is shown.
- the cross-sectional view of Figure lc shows that the forming apparatus body (1) resembles an elongated wedge with the glass sheet being formed at the downward facing point of the wedge, called the root (25).
- Molten glass (2) enters an inflow pipe (3) that conducts the glass (2) to a trough (4) on the top of the forming apparatus (1).
- the glass (2) entering the forming apparatus (1) should be uniformly heated to a molten state and experience laminar flow as it moves through the inflow pipe (3) after mixing. From the inflow pipe (3) the glass (2) enters the trough (4) of the forming apparatus (1), flowing substantially parallel to the root (25) in a substantially horizontal direction.
- the trough (4) The trough (4)
- the glass (2) 'distributes the glass (2) to two substantially parallel weirs (5) located on the top edge of the apparatus (1).
- the weirs (5) which are on each side of the top of the apparatus (1) form the sides of the trough (4) and are aligned with the pointed edge of the wedge.
- the major portion of the glass (2) flows over the top of weirs (5) on each side of the trough (4) and down the sloped sides of the wedge, joining at the root (25) to form a flat sheet of molten glass (2).
- the distribution of flow out of the horizontal trough (4) and onto the sides of the forming apparatus (1) is controlled by the contoured shape of the bottom and sides of the trough (4) and the shape and height of the weirs (5) on each side of the top of the apparatus (1).
- the molten glass (2) is subsequently cooled until it is a solid sheet.
- the flow must be compensated at each end of the forming apparatus (1) to account for end effects caused by surface tension. This compensation requires a localized adjustment in the shape of the weirs (5) and/or the shape of the trough (4) bottom. Surface tension affects the flow down the sides of the forming apparatus (1) and the flow in the free space below the forming apparatus (1) before the molten glass (2) has cooled to a solid form.
- Devices similar to the "Sheet Glass Edge Control Device" of patent #3,451,798, incorporated herein by reference, maybe employed on all embodiments but are not shown in the figures.
- the glass sheet is formed it is processed with known equipment for handling the glass sheet. It is essentially, "drawn down" from the bottom of the sheet forming apparatus (1). hi general, the edges of the sheet are trimmed, so most handling, if not all, is done by machine touching just the edges. In addition, the equipment will prevent rapid temperature fluctuation to avoid degrading the quality of the glass. Such equipment is well known in the art and is not discussed in detail here. This invention is directed specifically to the overflow glass forming apparatus (1).
- the entire apparatus may be clad in a refractory metal envelope if maximum durability is required.
- the use of molybdenum is an option for the construction of the apparatus (1) because of the smaller size of the apparatus.
- Each of the side flow control elements and perhaps even the forming wedge element would be made of molybdenum.
- Molybdenum must be protected from oxidation when it is used at glass forming temperatures. This is accomplished by either covering the molybdenum with platinum, coating the glass contact areas with glass prior to high temperature exposure to oxygen, or surrounding the apparatus with a controlled non-oxidizing atmosphere.
- the present invention teaches that the glass forming apparatus (1) can be designed to avoid many of the problems associated with the previous designs for the overflow trough (4).
- the apparatus and process of the present invention allows a degree of adjustment that has been previously unknown to this process. Many of the parts are designed to be adjusted or exchanged while the glass is hot.
- the output of glass sheet is interrupted for a brief period, but the production line continues such that the months of delay for shut down and start-up are avoided, i addition, novel features are provided that allow the system to run under pressure to increase glass flow.
- the present invention provides a forming apparatus (1) that can be used to make substantially constant thickness glass (2) over an expended range of values of the mathematical product of glass flow and glass viscosity by using a combination of the tilt of the apparatus (1) with a change in glass flow through an overflow device (10) at the far end of the apparatus (1).
- the forming apparatus shown in Figures 2a-2d has straight sloped weirs (5) that are close to parallel with the pointed edge of the wedge shaped portion of the forming apparatus (1) but sloped slightly downward in the direction away from the inflow pipe (3).
- Glass (2) enters the trough (4) through an inflow pipe (3).
- the bottom and sides of the trough (4) are contoured in a manner to provide even distribution of glass to the top of each side weir (5).
- the major portion of the glass (2) then flows over the top of each side weir (5), down each side of the wedge shaped portion of the forming apparatus (1), and joins at the bottom of the wedge to form a sheet of molten glass (2).
- the molten glass (2) is then cooled to form a solid glass sheet of substantially uniform thickness.
- a small portion of the glass (2) passes through the forming trough (4) and out the far end through an overflow device (10).
- the overflow device (10) incorporated at the far end of the trough (4) is used in conjunction with tilting of the apparatus (1), changes in glass flow rate, and changes in glass viscosity to regulate the thickness profile of the sheet.
- the sheet glass forming apparatus is designed for constant temperature operation in the region of the forming trough (4) and the weirs (5).
- the linear sheet thickness differential from one end of the sheet to the other end is called wedge.
- the nonlinear sheet thickness variations from one end of the sheet to the other end is called curvature.
- the wedge and curvature are primarily a function of the trough (4) shape and the shape of the weirs (5) on each side of the trough (4).
- the glass (2) sheet thickness distribution is the same for a given value of the mathematical product of glass flow rate times the glass viscosity. A change in either of these variables independent of the other will produce wedge and/or curvature in the sheet thickness distribution.
- Operational adjustment of any wedge or curvature in the sheet thickness may be effected by tilting the apparatus (1) and by varying the portion of glass (2) flowing to the overflow device (10). For instance, if the glass (2) at the far end is thinner than at the inlet end, lowering the far end will flow more glass (2) to that end, consequently thickening the sheet at the far end. Conversely, increasing the portion of glass (2) flowing to the overflow (10) will decrease the glass thickness at the far end of the forming apparatus. Since the two effects are nonlinear, different combinations of tilt and overflow glass can produce corrections in both curvature and in wedge. This will allow for a longer production campaign with a given forming apparatus, thus reducing manufacturing down time with a resultant cost saving.
- FIGS 3a-3d show an embodiment that is the same as the embodiment shown in Figures 2a-2d except that both of the weirs (5) and the bottom of the trough (4) are contoured such that the flow over the weirs (5) is uniform over their entire length.
- Figures 4a-4d show an embodiment that is the same as the embodiment shown in Figures 2a-2d except that trough (4) has a flat bottom and only the weirs (5) are contoured such that the flow over the weirs (5) is uniform over their entire length.
- the trough (4) bottom is shown horizontal but may be sloped.
- the exact shape of the trough (4) and weirs (5) can be calculated by solving the Navier Stokes Equations using any of a number of computational fluid dynamics software packages such as CFD2000TM, Fluent TM, and Flow 3D TM.
- the criteria for a satisfactory design is to have a substantially even distribution of glass (2) in the longitudinal direction flowing at the desired rate from the root (25) of the apparatus (1).
- a spatial grid is constructed to represent the proposed internal geometry of the inflow pipe (3), the trough (4) internal cavity and the shape of the top surface of the weirs (5).
- the fluid properties are imposed along with boundary conditions to represent the walls, the free surfaces, and the required process glass flow rate.
- a trial solution is executed and the size and shape of the components are revised until the solution produces a flow distribution at the root (25) of the apparatus (1) that satisfies the design criteria.
- One of the objectives of the present invention is to significantly reduce the time difference between the glass forming the near end of the sheet and the far end of the sheet. This can be accomplished by redesigning the inflow pipe (3) to the trough (4) such that the glass (2) that enters the trough (4) and forms the near end is delayed relative to the glass (2) that enters the trough (4), flows the length of the forming trough (4), and forms the far end of the sheet.
- Figure 5 is an illustration of the velocity distribution of the glass flow through the inflow pipe (3) and the trough (4) of the forming apparatus.
- the length of the arrows in the figure are proportional to the glass flow velocity.
- the inflow pipe (3) is shaped to be narrower at its top than at its bottom. This causes the flow of glass (2) to be slower at the top of the inflow pipe (3) than at its bottom.
- the glass flowing through the top of this shaped inflow pipe (3) goes to the near end of the weirs (5) and the glass (2) flowing through the bottom goes to the far end of the weirs (5).
- FIGS. 6a, 6b and 6c are illustrations of cross-sections of the inflow pipe (3) of the forming apparatus (l).
- the cross-section of the inflow pipe (3) is determined by the requirements of the application which would include such considerations as flow modulation, heat losses, and ease of manufacture.
- Figures 7a, 7b and 7c are illustrations of cross-sections of the trough of the forming apparatus.
- the shape of the forming trough (4) cross-section is also determined by the requirements of the application, the primary one of which is the flow distribution through the trough (4) to the weirs (5). Other considerations such as ease of manufacture, erosion of the weirs (5), and stress levels in the material of construction are important. Elimination of the square lower corners of the rectangular trough (4) is important to minimize slow glass flow in these regions.
- the glass sheet formed will have substantially uniform thickness over an expanded range of glass flow and glass viscosity. This will facilitate process development and allow the manufacture of substantially different products on the same apparatus.
- the glass entering the apparatus from the inflow pipe would have a static pressure between 0.025 and 5.0 bar.
- the specification of low or high pressure is relative to this defined pressure range.
- Figures 8a-8c show an embodiment of a overflow glass forming apparatus (1) that would be typical of a system operating under relatively low inlet pressure.
- Glass (2) enters the apparatus (1) from the inflow pipe (3).
- the trough (4) is tapered toward the far end to minimize residence time of glass flowing to that end of the apparatus (1).
- the orifice (20) is on the top surface of the apparatus (1) and extends horizontally from near the inlet end to near the far end.
- the orifice (20) is narrow at the inlet end and very wide at the far end to accommodate for the loss in static pressure of the glass (2) as it flows to that end.
- the complex shape of the orifice (20) is designed to produce the desired uniform flow from the trough (4) to the sides of the apparatus (1).
- Figures 9a-9c is an embodiment that would be typical of a higher inlet pressure than the pressure used in the embodiment shown in Figures 8a-8c.
- the orifice (20) is very narrow at the inlet end and slightly wider at the far end to accommodate for the loss in static pressure of the glass (2) as it flows to that end.
- the tapered shape of the orifice (20) is less exaggerated in this higher pressure embodiment as the static pressure loss due to glass flow in the trough (4) has a lower effect on flow through the orifice (20) to the sides of the apparatus (1).
- the orifice (20) may be made from refractory or to increase durability the orifice (20) could be made from refractory metal, i.e. platinum, reinforced as required by refractory, i.e. alumina.
- the orifice (20) may be either sprayed, via a molten platinum spraying process, directly on shaped refractory or fabricated from sheet.
- the body of the forming apparatus (1) is most likely made from refractory. It may be clad in a refractory metal envelope to insure long life. The envelope for the refractory may be either sprayed on or fabricated from sheet.
- the flow is compensated at each end of the orifice (20) to account for end effects caused by surface tension as it affects the flow down the sides of the forming apparatus (1) and the flow in the free space below the forming apparatus (1) before the glass (2) has cooled to a final form.
- This compensation will require a localized adjustment in the width of the orifice (20) at each end. This end compensation is be applied to each orifice (20) shape.
- the sheet thickness will be a function of the quantity of glass flow and glass viscosity at the root (25) (wedge shaped bottom of apparatus (1) where the glass (2) joins to form the sheet).
- the sheet thickness distribution (wedge) will be a primary function of the trough (4) shape and the orifice (20) shape and substantially independent of the glass flow and viscosity.
- any wedge in the sheet thickness may be adjusted by tilting the apparatus (1). For instance, if the glass (2) at the far end is thinner than at the inlet end, lowering the far end will flow more glass (2) to that end, consequently thickening the sheet at the far end.
- Figures 10a- 10c show an embodiment that has a simple trough (4) shape and a relatively low inlet pressure.
- Glass (2) enters the forming apparatus body (1) from the inflow pipe (3).
- the trough (4) has substantially the same cross section for the length of the apparatus (1) and access from both ends during manufacture.
- the orifice (20) is on the top surface of the apparatus (1) and extends horizontally from near the inlet end to near the far end.
- the orifice (20) is narrow at the inlet end and wider at the far end to accommodate for the loss in static pressure of the glass as it flows to that end. Note that the width change is less than the embodiment shown in Figures 8a-8c as the loss in static pressure of the glass (2) flowing to the far end is less.
- the complex (somewhat parabolic) shape of the orifice (20) is designed to produce the desired uniform flow from the trough (4) to the sides of the apparatus.
- Figures 1 la-1 lc show an embodiment that has a simple trough (4) shape, an orifice (20) that is not confined to a horizontal plane, and a relatively low inlet pressure.
- Glass (2) enters the apparatus from a inflow pipe (3).
- the trough (4) has substantially the same cross section for the length of the apparatus (1) and access from both ends during manufacture.
- the trough (4) has a pent roof shape such that a vee shaped orifice (20) may be formed.
- the orifice (20) is narrow at the inlet end and wider at the far end to accommodate for the loss in static pressure of the glass (2) as it flows to that end. Note that the width change is less than in figures 8a-8c and lOa-lOc as the loss in static pressure of the glass flowing to the far end is compensated for in part by the increase in static pressure at the far end caused by gravitational forces.
- the orifice (20) also has a more complex shape because of the interaction of flow and the gravitational forces.
- the orifice (20) is designed to produce the desired uniform flow from the trough (4) to the sides of the apparatus (1).
- An advantage of this embodiment is that the orifice (20) is cut such that its exposed surfaces face either the trough (4) or the outside of the device.
- This general design would provide a geometry whereby both the trough (4) and the orifice (20) surface may be coated with refractory metal by a spraying process.
- the embodiment would, however, have a more limited range of operating flow conditions much like the apparatus in patent #3,338,696 because of the influence of gravitational forces.
- sloping and shaping the orifice (20) out of a horizontal plane may produce superior flow characteristics and/or provide for simplified construction. This would normally be at the expense of somewhat limiting the range of operation of a given apparatus (1).
- One of the discoveries of the present invention is that an improvement can be provided such that flow dynamics can be altered during hot operation by insertion, removal or adjustment of a flow control plug.
- Figures 12a- 12c show an embodiment that has a simple trough (4) shape and an internally mounted flow control plug (30).
- the orifice (20) is designed for a relatively high inlet pressure.
- the trough (4) has substantially the same cross section for the length of the apparatus (1) and access from both ends during manufacture.
- the flow control plug (30) is designed to modulate the flow in the trough (4) such that the static pressure at the inlet to the orifice (20) is constant along its entire length.
- the orifice (20) is narrow and substantially the same width its entire length. Because the static pressure change in the glass flowing through the orifice
- the plug (30) can be moved vertically in the trough (4) to alter the flow distribution to cause a convex or concave shape in the sheet thickness. This can be used to compensate for the changes in sheet thickness distribution caused by apparatus degradation.
- Figures 13a- 13c show one example of flow control plug (30), many other shapes are possible and the intention is that the plug (30) would facilitate both theoretical and empirical operational modifications to a running system, such that a particular facility might have a number of plugs (30) on hand to quickly adapt to a change in the system. For example, if wear was developing in a trending pattern that was being corrected by plugs (30), the future wear could be projected and next few plugs (30) could be designed and constructed well in advance of when they would be needed.
- a flow control plug (30) with a conical, cylindrical, or prismatic shape Another shape that would have a particular utility would be a flow control plug (30) with a conical, cylindrical, or prismatic shape.
- a unique irregularly shaped flow control plug (30) with an eccentric axis could be located in the center of the trough (4) or partially embedded in the bottom of the trough (4).
- the plug (30) could be rotated about its axis to alter the flow distribution and thereby compensate for changes in sheet thickness distribution. It could also be tilted and/or moved horizontally or vertically to produce the desired sheet thickness correction.
- One embodiment of the invention provides a forming apparatus with multiple orifices to allow greater variability in sheet thickness.
- the forming apparatus proper consists of two independent sides that are most likely but not necessarily mirror images of each other.
- the outside shape is essentially that of an elongated wedge with the point facing downward.
- the glass enters one end of a trough formed by the two sides of the forming apparatus under pressure and flows out of a top and bottom orifice formed by the two pieces. Effectively, the bottom orifice adds glass to the middle of the formed sheet.
- Figures 14a, 14b and 14c show a top, side and an inlet view of an embodiment with a horizontal top orifice (20), a horizontal bottom orifice (35) and a shaped trough (4).
- Glass (2) enters the apparatus from the inflow pipe (3).
- the trough (4) formed by the two independently mounted sides (36) and the end cap (34). It is tapered toward the far end to minimize the residence time of glass flowing to that end of the apparatus (1).
- An individual side (36) is shown in Figure 15a-15c.
- the orifice (20) on the top surface of the apparatus (1) extends horizontally from near the inlet end to near the far end. It is wider at the far end to compensate for the loss in static pressure caused by the glass flow in the trough (4).
- the orifice (35) on the bottom is also wider at the far end being shaped for a specified flow distribution along its length.
- the molten glass (2) is subsequently cooled until it is a solid sheet and processed such that once the molten glass (2) leaves the root (25) it has essentially the same physical dimensions as a sheet formed without a bottom orifice (35).
- the distribution of flow out of the horizontal trough (4) is controlled by the size and shape of each of the contoured orifices (20) and (35) at the top and bottom of the apparatus (1) and the shape of the trough (4).
- the sum flow of glass (2) through the top and bottom orifices (20) and (35) along the length of the forming apparatus (1) as a total must be substantially uniform in order that the sheet of glass has uniform thickness when formed.
- the designed shape of the trough (4) and the contoured orifices of the forming apparatus (1) are determined by the solution of the Navier-Stokes equations and confirmed by operational test.
- Figures 16a, 16b and 16c show a top, side and an inlet view of an embodiment with a horizontal top orifice, a horizontal bottom orifice, and a constant cross section trough.
- the trough (4) formed by the two independently mounted sides (36) and end cap (34) and has substantially the same cross section for its total length.
- the orifice (20) on the top surface of the apparatus (1) extends horizontally from near the inlet end to near the far end. It is wider at the far end to compensate for the loss in static pressure caused by flow in the trough (4).
- the orifice (35) on the bottom is also wider at the far end being shaped for a specified flow distribution along its length.
- the taper of the top and bottom orifices (20) and (35) is less than the taper shown in Figures 14a- 14c as less static pressure loss compensation is required.
- the flow is compensated at each end of the forming apparatus (1) to account for end effects caused by surface tension as it affects the flow down the sides of the forming apparatus (1) and the flow in the free space below the forming apparatus (1) before the glass (2) has cooled to a final form.
- This compensation requires a localized adjustment in the width of the orifice (20) and/or the height of the weirs (5) at each end. This end compensation is applied to each orifice (20) shape.
- the sheet thickness will be a function of the quantity of glass flow and glass viscosity at the root (25).
- the sheet thickness distribution (wedge) will be a primary function of the trough (4) shape and the size and shape of the orifices (20) and (35) and weirs (5).
- any wedge in the sheet thickness may be adjusted by tilting the apparatus (1). For instance, if the glass (2) at the far end is thinner than at the inlet end, lowering the far end will flow more glass (2) to that end, consequently thickening the sheet at the far end.
- Additional wedge correction may be accomplished by selectively moving the appropriate end of the two sides (36) of the apparatus (1) together or apart to change the width of the orifices (20) and (35). At each end of the apparatus (1) there is variable width gap with a glass seal (37) that allows this movement. Applying torque to the ends of the apparatus sides (36) can effect changes in the thickness contour. Each side (36) can be bowed or made S- shape to effect a uniquely shaped orifice opening.
- the two sides (36) of the apparatus (1) maybe adjusted by displacement, rotation, and torque relative to each other to affect the width and shape of these orifices (20) and (35).
- the bottom orifice (35) may be shaped such that the glass flowing out of the center portion is thicker or thinner than that flowing out of the ends.
- the top orifice (20) would be designed so that the flow distribution at the root (25) is uniform. With this shape moving the individual sides (36) together or apart would produce a curvature correction in the sheet thickness.
- FIGS. 17a, 17b and 17c show a top, side and an inlet view of an embodiment which is the same as that shown in
- FIGs 16a- 16c Figures 16a- 16c, but with an internal plug (30) which is used to vary sheet width.
- Figures 18a, 18b and 18c show a top, side and an inlet view of an internal flow control plug (30) used in the embodiment shown in Figures 17a-17c.
- This plug (30) is designed to be removable while the forming apparatus (1) is at elevated temperature and to modulate the flow in the trough (4) in a manner that limits the flow of glass (2) out of each end of the top and bottom orifices (20) and (35).
- Use of the flow control plug (30) will control the width of the glass sheet manufactured.
- Figures 19a, 19b and 19c show a top, side and an inlet view of an embodiment with a sloped top surface with a weir (5) on each side, a horizontal bottom orifice (35), and a shaped trough (4).
- This embodiment more closely resembles the apparatus of U.S. Patent number 3,338,696 in that it has two sloped weirs (5) on top, one on each side, instead of the top orifice (20). Unlike the device taught in the prior patent, it has a bottom orifice (35). Glass (2) enters the forming apparatus body (1) from the inflow pipe (3).
- the top surface of the apparatus (1) that extends horizontally from the inlet end to the far end has a downward slope to insure even glass flow out of the top of the apparatus and over the weirs (5).
- the trough (4) formed by the two independently mounted sides (36) is tapered, being smaller, toward the far end to control the glass flow over the weirs (5) on the top of the apparatus (1).
- the orifice on the bottom (35) is also shaped for a specified flow distribution along its length. It is wider at the far end to compensate for the loss in static pressure caused by flow in the trough (4).
- the apparatus (1) is formed by two side flow control elements (38), an end cap (34) and a bottom shaped wedge (39) creating a top and two side orifices (20) and (40).
- Figures 20a, 20b and 20c show a top, side and an inlet view of an embodiment where the elements form a horizontal top orifice (20) and two horizontal side orifices (40).
- Figures 21a, 21b and 21c show a top, side and an inlet view of the two side elements (38) and the bottom forming wedge (39) of the apparatus (1) shown in Figures 20a-20c.
- the system would be run at a pressure equal to or higher than the local atmospheric pressure. ).
- Glass (2) enters the forming apparatus body (1) from the inflow pipe (3).
- the glass (2) flows into the trough (4) and exits by a top orifice (20) and two side orifices (40).
- the glass (2) exiting the top orifice (20) flows down the sides of the apparatus (1) to the location of the side orifices (40) and covers the glass (2) exiting from these side orifices (40).
- a significant portion of the glass (2) that forms the sheet flows out of each side orifice (40).
- the combined flows then continues down each side of the forming wedge
- the distribution of flow out of the horizontal trough (4) is controlled by the size and shape of each of the contoured orifices (20) and (40) at the top and sides of the apparatus (1) and the shape of the trough (4).
- the shape of the trough (4) may be either simple for ease of manufacture or contoured to assist in the flow and distribution of the glass (2).
- the orifices (20) and (40) on the top surface and sides of the apparatus (1) extend horizontally from near the inlet end to near the far end. They are wider at the far end to compensate for the loss in static pressure caused by the glass flow in the trough (4), being shaped for uniform flow along the entire orifice length.
- the width of and thus the flow through the side orifices (40) may be adjusted by vertical movement of the side flow control elements (38). This provides for process adjustment thus enabling different operating conditions.
- the sheet thickness will be a function of the quantity of glass flow and glass viscosity at the root (25).
- the sheet thickness distribution (wedge) will be a primary function of the trough (4) shape and the size and shape of the orifices (20) and (40) and weirs (5).
- any wedge in the sheet thickness may be adjusted by tilting the apparatus (1). For instance, if the glass at the far end is thinner than at the inlet end, lowering the far end will flow more glass to that end, consequently thickening the sheet at the far end.
- Wedge correction may be accomplished by selectively moving the appropriate end of either of the two sides (38) of the apparatus (1) relative to the bottom wedge (39) to change the width of the orifices (40).
- the two sides (38) of the apparatus (1) maybe adjusted by displacement, rotation, and torque relative to each other to affect the width and shape of the orifices (20) and (40).
- Each side (38) can be bowed or made S- shape to effect a uniquely shaped orifice (40) opening.
- a glass seal (37) at each end allows this adjustment.
- the sum flow of glass (2) through the top and bottom orifices (20) and (40) along the length of the forming apparatus (1) as a total must be substantially uniform in order that the sheet of glass has uniform thickness when formed.
- the designed shape of the trough (4) and the contoured orifices (20) and (40) of the forming apparatus (1) are determined by the solution of the Navier-Stokes equations and confirmed by operational test.
- the side orifices (40) maybe shaped such that the glass flowing out of the center portion is thicker or thinner than that flowing out of the ends.
- the top orifice (20) would be designed so that the flow distribution at the root (25) is uniform. With this shape moving the individual sides (38) vertically would produce a curvature correction in the sheet thickness.
- the flow out of the top and side orifices (20) and (40) may be further modified by a replaceable interior plug (30) which can modify the flow to the orifices (20) and (40).
- This plug (30) may be used to substantially alter the width of the formed sheet to permit economical manufacture of a broad range of product widths, hi any of the embodiments the glass flow to the orifices (20) and (40) may be altered by contouring the internal shape of the bottom forming wedge (39) element and/or the side flow control elements (38).
- a formed body or plug (30) attached to either of the end plates may also be used to alter the flow pattern in the trough (4). This plug (30) may be extended into the trough (4) to effectively shorten the length of the orifices such that narrower sheet may be manufactured.
- FIG. 22a, 22b and 22c show a similar embodiment in Figures 22a, 22b and 22c but the elements form a sloped top surface with weirs (5) at each side and two horizontal side orifices (40).
- Figures 23a, 23b and 23c show a top, side and an inlet view of the two side elements (38), the end cap (34) and the bottom forming wedge (39) of the apparatus shown in Figures 22a-22c.
- the glass (2) flows into the trough (4) and exits over weirs (5) on each side of the top surface and by orifices (40) on sides of the cavity.
- the glass exiting the top weirs (5) flows down the sides of the apparatus (1) to the location of the side orifices (40) and covers the glass exiting from these side orifices.
- the combined flows then continue down each side of the forming wedge (39) and all join at the bottom of the forming wedge (39), where they are solidified into a glass sheet.
- the weirs (5) on the top surface extend horizontally from near the inlet end to near the far end and are sloped to produce uniform flow over the entire length.
- the orifices (40) on the sides of the apparatus (1) extend horizontally from near the inlet end to near the far end. They are wider at the far end to compensate for the loss in static pressure caused by the glass flow in the trough (4), being shaped for uniform flow along the entire orifice length.
- the width of and thus the flow through the side orifices (40) may be adjusted by vertical movement of the side flow control elements (38). This provides for process adjustment thus enabling different operating conditions. Heating and Cooling of Glass
- Prior art requires that the molten glass (2) be maintained at a constant temperature in the inlet pipe (3), the full length of the trough (4), over the weirs (5) and on the upper part of the forming apparatus body (1).
- the glass is uniformly cooled as it approaches the root (25) of the forming apparatus body (1) in preparation to becoming a solid sheet.
- Additional thickness correction may be accomplished by selective heating or cooling of the molten glass (2) in the trough (4) and/or heating the weirs and thus the molten glass (2) flowing over the weirs and/or heating the orifice (20) and thus the molten glass (2) flowing through the orifice.
- One caveat with this approach is that the molten glass (2) flowing from the root (25) of the apparatus (1) must be of substantially uniform temperature. Therefore, the glass molten (2) would need to be selectively cooled or heated as it flows down the outside of the apparatus in order to produce the required substantially uniform temperature.
- FIGS 24a-24c show an embodiment that has a simple trough (4) with sloped weirs (5), radiant top heating devices (42) and radiant side heating devices (44).
- the top heating devices (42) would be individually powered to either heat or cool the molten glass (2) as it flows through the trough (4).
- the lowered viscosity of the molten glass caused by a heating strategy would flow substantial molten glass (2) to the far end of the forming apparatus body (1).
- This heating or cooling effect could be made linear thus effecting the wedge in glass sheet thickness or nonlinear thus effecting the curvature of the glass sheet thickness.
- the side heating devices would be selectively powered to restore the molten glass (2) to a substantially uniform temperature as it reaches the root (25) of the forming apparatus body (1).
- An additional embodiment would be an electrical heating system inserted in the trough. If the two parallel elements of the flow control plug shown in figures 13a-13c were constructed as individual isolated electrodes, they may be used as a pair of electrodes for introducing electrical energy through the electrically conductive molten glass (2) from one side to the other side of the trough (4). Numerous other methods of heating the weirs (5), the orifice (20), and/or the molten glass (3) in the trough (4) are possible. If the weirs (5) are made from molybdenum or are clad with platinum they may be used as a pair of electrodes for firing electrical energy through the electrically conductive molten glass (2) from one side to the other side of the trough (4).
- weirs (5) or the orifice (20) are clad with platinum they may used as a conductor in an electric circuit to heat the molten glass (2). If either the weirs (5) or the orifice (20) are made from molybdenum or are clad with platinum and the flow control plug (30) is an electrode, an electric circuit may be established to heat the electrically conductive molten glass (2) in the trough (4). All of the above heating techniques would require some type of selectively powered side heating devices (44) to restore the molten glass (2) to a substantially uniform temperature as it reaches the root (25) of the forming apparatus body (1).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2001261291A AU2001261291A1 (en) | 2000-05-09 | 2001-05-09 | Sheet glass forming apparatus |
Applications Claiming Priority (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20258100P | 2000-05-09 | 2000-05-09 | |
US60/202,581 | 2000-05-09 | ||
US20534700P | 2000-05-18 | 2000-05-18 | |
US60/205,347 | 2000-05-18 | ||
US20690400P | 2000-05-25 | 2000-05-25 | |
US60/206,904 | 2000-05-25 | ||
US21990200P | 2000-07-21 | 2000-07-21 | |
US60/219,902 | 2000-07-21 | ||
US22769600P | 2000-08-24 | 2000-08-24 | |
US60/227,696 | 2000-08-24 | ||
US24587500P | 2000-11-04 | 2000-11-04 | |
US60/245,875 | 2000-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2001085630A2 true WO2001085630A2 (fr) | 2001-11-15 |
WO2001085630A3 WO2001085630A3 (fr) | 2002-03-21 |
Family
ID=27558935
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2001/014900 WO2001085630A2 (fr) | 2000-05-09 | 2001-05-09 | Dispositif de formage de verre en feuilles |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU2001261291A1 (fr) |
WO (1) | WO2001085630A2 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003051783A1 (fr) * | 2001-12-14 | 2003-06-26 | Corning Incorporated | Appareil et procede permettant de fabriquer des plaques de verre par fusion a ecoulement d'exces descendant |
DE10305141A1 (de) * | 2003-02-08 | 2004-08-19 | Eglass Platinum Technology Gmbh | Vorrichtung zur Herstellung von dünnem Flachglas |
WO2005110934A2 (fr) * | 2004-05-11 | 2005-11-24 | Boettger Diether | Procede et dispositif pour controler la temperature lors de la production de verre |
WO2018098114A1 (fr) | 2016-11-22 | 2018-05-31 | Corning Incorporated | Corps de formage pour le formage de rubans de verre continus et appareils de formage du verre en comprenant |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1759229A (en) * | 1928-02-01 | 1930-05-20 | Libbey Owens Glass Co | Method and apparatus for drawing sheet glass |
GB982153A (en) * | 1961-02-27 | 1965-02-03 | Corning Glass Works | Downflow glass sheet drawing method and apparatus |
BE663561A (fr) * | 1964-05-06 | 1965-11-08 | ||
GB1151288A (en) * | 1966-04-04 | 1969-05-07 | Corning Glass Works | Sheet Glass Edge Control |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09110443A (ja) * | 1995-10-24 | 1997-04-28 | Nippon Electric Glass Co Ltd | ガラス板の製造装置 |
JPH10291827A (ja) * | 1997-04-16 | 1998-11-04 | Hoya Corp | ガラス板の製造方法及び製造装置 |
-
2001
- 2001-05-09 AU AU2001261291A patent/AU2001261291A1/en not_active Abandoned
- 2001-05-09 WO PCT/US2001/014900 patent/WO2001085630A2/fr active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1759229A (en) * | 1928-02-01 | 1930-05-20 | Libbey Owens Glass Co | Method and apparatus for drawing sheet glass |
GB982153A (en) * | 1961-02-27 | 1965-02-03 | Corning Glass Works | Downflow glass sheet drawing method and apparatus |
BE663561A (fr) * | 1964-05-06 | 1965-11-08 | ||
GB1151288A (en) * | 1966-04-04 | 1969-05-07 | Corning Glass Works | Sheet Glass Edge Control |
Non-Patent Citations (2)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 08, 29 August 1997 (1997-08-29) & JP 09 110443 A (NIPPON ELECTRIC GLASS CO LTD), 28 April 1997 (1997-04-28) * |
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 02, 26 February 1999 (1999-02-26) & JP 10 291827 A (HOYA CORP;NIPPON SHEET GLASS CO LTD), 4 November 1998 (1998-11-04) * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003051783A1 (fr) * | 2001-12-14 | 2003-06-26 | Corning Incorporated | Appareil et procede permettant de fabriquer des plaques de verre par fusion a ecoulement d'exces descendant |
US7386999B2 (en) | 2001-12-14 | 2008-06-17 | Corning Incorporated | Defect control in the making of sheet glass by the fusion process |
DE10305141A1 (de) * | 2003-02-08 | 2004-08-19 | Eglass Platinum Technology Gmbh | Vorrichtung zur Herstellung von dünnem Flachglas |
WO2005110934A2 (fr) * | 2004-05-11 | 2005-11-24 | Boettger Diether | Procede et dispositif pour controler la temperature lors de la production de verre |
WO2005110934A3 (fr) * | 2004-05-11 | 2006-01-19 | Diether Boettger | Procede et dispositif pour controler la temperature lors de la production de verre |
WO2018098114A1 (fr) | 2016-11-22 | 2018-05-31 | Corning Incorporated | Corps de formage pour le formage de rubans de verre continus et appareils de formage du verre en comprenant |
EP3544931A4 (fr) * | 2016-11-22 | 2020-04-22 | Corning Incorporated | Corps de formage pour le formage de rubans de verre continus et appareils de formage du verre en comprenant |
Also Published As
Publication number | Publication date |
---|---|
AU2001261291A1 (en) | 2001-11-20 |
WO2001085630A3 (fr) | 2002-03-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6748765B2 (en) | Overflow downdraw glass forming method and apparatus | |
EP1756017B1 (fr) | Distribution homogene en masse pour former des substrats de verre | |
KR100754758B1 (ko) | 시트 글래스 형성 장치 | |
US8230699B2 (en) | Sheet width control for overflow downdraw sheet glass forming apparatus | |
US8001805B2 (en) | Overflow downdraw glass forming method and apparatus | |
CN102471121B (zh) | 玻璃板的制造方法及制造装置 | |
US8474286B2 (en) | Overflow downdraw glass forming method and apparatus | |
US20080047300A1 (en) | Defect reduction in manufacture glass sheets by fusion process | |
CA2107841C (fr) | Methode et four pour le cintrage des feuilles de verre | |
US20050016214A1 (en) | Continuous method and system for manufacturing a crystallized glass plate | |
KR101133391B1 (ko) | 유리 시트 형성 장치 | |
KR100812753B1 (ko) | 유리 리본 지지 장치 | |
JP4120910B2 (ja) | 溶融ガラスの供給方法 | |
KR20090016564A (ko) | 증가된 엣지 안정성을 갖는 유기 기판을 형성하는 장치 및 방법 | |
CN105036529B (zh) | 无碱玻璃的玻璃板的制造方法 | |
US3850787A (en) | Manufacture of flat glass utilizing a reaction to traction across the width of the molten glass | |
WO2001085630A2 (fr) | Dispositif de formage de verre en feuilles | |
KR101740082B1 (ko) | 디스플레이용 유리 기판 및 그의 제조 방법 | |
CN108328909B (zh) | 玻璃生产装置及其生产工艺 | |
JPH02217327A (ja) | ガラス板製造方法 | |
WO2013102922A2 (fr) | Appareil et procédé pour ajuster l'épaisseur d'une plaque de verre | |
CN209352771U (zh) | 用于压延机的唇砖组件和供料装置 | |
TW564240B (en) | Sheet glass forming apparatus | |
CN109836029B (zh) | 浮法玻璃制造装置、浮法玻璃制造方法以及浮法玻璃 | |
KR101206122B1 (ko) | 유리 기판을 형성하기 위한 아이소파이프 질량 분포 방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
AK | Designated states |
Kind code of ref document: A3 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
122 | Ep: pct application non-entry in european phase | ||
NENP | Non-entry into the national phase in: |
Ref country code: JP |