WO2001083447A3 - Ligand halopyrrole s'utilisant dans un systeme catalytique - Google Patents

Ligand halopyrrole s'utilisant dans un systeme catalytique Download PDF

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Publication number
WO2001083447A3
WO2001083447A3 PCT/ZA2001/000052 ZA0100052W WO0183447A3 WO 2001083447 A3 WO2001083447 A3 WO 2001083447A3 ZA 0100052 W ZA0100052 W ZA 0100052W WO 0183447 A3 WO0183447 A3 WO 0183447A3
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WO
WIPO (PCT)
Prior art keywords
halopyrrole
pyrrole
ligand
catalyst system
derivative
Prior art date
Application number
PCT/ZA2001/000052
Other languages
English (en)
Other versions
WO2001083447A2 (fr
Inventor
John Thomas Dixon
Jacobus Johannes Cronje Grove
Alta Ranwell
Original Assignee
Sasol Tech Pty Ltd
John Thomas Dixon
Jacobus Johannes Cronje Grove
Alta Ranwell
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd, John Thomas Dixon, Jacobus Johannes Cronje Grove, Alta Ranwell filed Critical Sasol Tech Pty Ltd
Priority to AU2001263526A priority Critical patent/AU2001263526A1/en
Publication of WO2001083447A2 publication Critical patent/WO2001083447A2/fr
Publication of WO2001083447A3 publication Critical patent/WO2001083447A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/52—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Pyrrole Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un ligand pyrrole destiné à un système catalytique d'oligomérisation d'oléfine dans lequel le ligand pyrrole est intégré dans une source halogène et consiste en un halopyrrole ou un dérivé de celui-ci. L'halopyrrole peut être un composé à base d'halopyrrole. Ce composé peut être n'importe quel dérivé pyrrole de la formule générale X-(CH2)n-C4H4N, X pouvant être un halide choisi dans le groupe constitué de fluorure, de chlorure, de bromure et/ou d'iodure, et n prenant la valeur de n'importe quel nombre supérieur à 0. Généralement, les composés à base d'halopyrrole de l'invention comprennent entre 4 et environ 20 atomes de carbone par molécule. Ces composés comprennent des dérivés de pyrrole possédant un groupe bromoalkyle lié au noyau pyrrole.
PCT/ZA2001/000052 2000-05-04 2001-05-04 Ligand halopyrrole s'utilisant dans un systeme catalytique WO2001083447A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001263526A AU2001263526A1 (en) 2000-05-04 2001-05-04 A halopyrrole ligand for use in a catalyst system

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US20190300P 2000-05-04 2000-05-04
US60/201,903 2000-05-04
ZA200002165 2000-05-04
ZA2000/2165 2000-05-04

Publications (2)

Publication Number Publication Date
WO2001083447A2 WO2001083447A2 (fr) 2001-11-08
WO2001083447A3 true WO2001083447A3 (fr) 2002-02-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ZA2001/000052 WO2001083447A2 (fr) 2000-05-04 2001-05-04 Ligand halopyrrole s'utilisant dans un systeme catalytique

Country Status (2)

Country Link
AU (1) AU2001263526A1 (fr)
WO (1) WO2001083447A2 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003053891A1 (fr) 2001-12-20 2003-07-03 Sasol Technology (Pty) Ltd. Trimerisation et oligomerisation d'olefines au moyen d'un catalyseur a base de chrome
US7300904B2 (en) 2001-12-20 2007-11-27 Sasol Technology (Pty) Ltd. Trimerisation and oligomerisation of olefins using a chromium based catalyst
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
KR100929954B1 (ko) 2004-02-20 2009-12-04 셰브론 필립스 케미컬 컴퍼니 엘피 올레핀 올리고머화 촉매의 제조 방법
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) * 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
GB0520085D0 (en) 2005-10-03 2005-11-09 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
KR101057576B1 (ko) 2007-08-16 2011-08-17 에스케이종합화학 주식회사 선택적 에틸렌 올리머고화 촉매계
JP5462179B2 (ja) 2007-11-28 2014-04-02 リンデ アーゲー エチレンのオリゴマー化のための触媒組成物およびプロセス
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
CN114029091B (zh) * 2021-12-23 2024-01-16 浙江智英石化技术有限公司 用于乙烯选择性三聚的双配体催化体系及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856257A (en) * 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
WO2001038270A1 (fr) * 1999-11-26 2001-05-31 Sasol Technology (Pty) Ltd Traitement de conversion d'hydrocarbures

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856257A (en) * 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
WO2001038270A1 (fr) * 1999-11-26 2001-05-31 Sasol Technology (Pty) Ltd Traitement de conversion d'hydrocarbures

Also Published As

Publication number Publication date
WO2001083447A2 (fr) 2001-11-08
AU2001263526A1 (en) 2001-11-12

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