WO2001006037A1 - Method for applying products without rinsing on moving metal strips - Google Patents
Method for applying products without rinsing on moving metal strips Download PDFInfo
- Publication number
- WO2001006037A1 WO2001006037A1 PCT/EP2000/006398 EP0006398W WO0106037A1 WO 2001006037 A1 WO2001006037 A1 WO 2001006037A1 EP 0006398 W EP0006398 W EP 0006398W WO 0106037 A1 WO0106037 A1 WO 0106037A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solution
- metal strips
- treatment
- roller
- fleece
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
- B05C1/0808—Details thereof, e.g. surface characteristics
Definitions
- the invention is in the field of corrosion-protective surface treatment of metal strips. It relates in particular to the application of so-called no-rinse products, that is, products that are dried immediately after application without an intermediate rinse with water. This means that all non-volatile components of the treatment solution used and the reaction products with the metal surface remain on the metal.
- An advantage of this technique is that there is no product-contaminated rinse water that has to be disposed of in a complex manner.
- the treatment solutions are applied to the metal belts, known as chemcoaters or rollcoaters, using rollers with a hard surface.
- spray / dip squeeze technology in which the surface is briefly brought into contact with the treatment solution to be applied by spraying or dipping, immediately after which the treatment solution is squeezed off by means of rollers and then dried.
- a disadvantage of the chemcoater is the high investment and operating costs.
- a disadvantage of the spray / dip squeeze process is a wet film thickness which is dependent on the running time of the squeeze roller, with different film layers also being obtained when the width changes in the edge regions. The coating of the tape is therefore uneven. Since the wet film is still very thin after being squeezed off (generally thinner than 2 ⁇ m), small changes in the wet film thickness have a very noticeable effect on the layer coverage achieved.
- the object of the invention is to provide an improved application system for no-rinse products which does not have the disadvantages mentioned above.
- the invention relates to a process for the chemical treatment of metal strips, wherein a treatment liquid is applied to one or both sides of the surface of the metal strips with an application roller and dried without intermediate rinsing, characterized in that a fleece roller is used as the application roller.
- Fleece rollers referred to as soft rolls in the Anglo-Saxon language area, are currently used in the belt industry as squeeze rollers.
- the surface of these rollers consists of a soft layer, usually made of chemical-resistant random fibers. Examples are polyamide (nylon) fibers or polypropylene fibers. In general, all fibers can be used that have a sufficient absorption volume and sufficient resistance to strongly acidic or alkaline solutions. In the method according to the invention, these rollers can rotate in opposite or parallel directions with the metal strip.
- the gap between the fleece rollers is preferably adjusted as a function of the sheet thickness so that the treatment liquid is applied to the surface of the metal strips with a wet film thickness in the range from 1 to 10 ⁇ m. This is the case, for example, with a gap width between approximately 0.3 and approximately 0.8 mm.
- the roller gap is preferably set such that a wet film thickness in the range from 2 to 6 ⁇ m (corresponding to ml / m 2 ) is set on the surface of the metal strips.
- treatment solutions which are suitable for no-rinse processes can be applied by the process according to the invention.
- these treatment liquids are either acidic (pH between 0 and 7) or alkaline (pH between 7 and 14).
- the composition of the treatment solutions is usually chosen so that a chemical reaction with the metal surface occurs.
- a large number of such treatment solutions are known in the prior art. Examples include: Phosphating solutions: acidified, phosphoric acid-containing solutions that produce a crystalline or amorphous metal phosphate layer on the metal surface.
- These solutions usually contain zinc ions as cations, often together with manganese and / or nickel ions.
- Chromating solutions acidic solutions containing Cr (VI) ions and often also Cr (III) ions.
- Acidic or alkaline passivation solutions aqueous solutions which usually contain transition metal ions and which, after drying, produce a corrosion-protecting amorphous (mixed) oxide layer.
- Treatment solutions based on complex fluorides usually acidic solutions of, for example, hexafluorozirconic acid, hexafluorotitanic acid, hexafluorosilicic acid and their salts.
- Solutions or dispersions of organic film formers for example polyacrylates.
- the solution can contain inorganic reactive components such as complex fluorides. This creates an inorganic / organic-polymer mixed layer.
- Such treatment solutions are currently used for the treatment of different substrates in conventional application processes. They are adjusted to the metal surface to be treated and are suitable, for example, for the treatment of steel, galvanized or alloy-galvanized steel, of alloy-aluminized steel and for the treatment of aluminum and its alloys. Accordingly, the method according to the invention can be used using treatment liquids of this type for the treatment of tapes made from the materials mentioned.
- the treatment solution can be applied to the surface of the fleece roller in different ways. For example, it is possible to spray them on spray on the surface of the fleece roller. Alternatively, it can be transferred from a storage container to the surface of the fleece roller via scoop rollers.
- treatment liquid is applied to the surface of the fleece roller via the interior of the fleece roller.
- the wall of the fleece roller can be made permeable to liquid. Treatment liquid supplied into the interior of the fleece roller, for example through a hollow roller shaft, can therefore reach the surface of the roller through holes in the wall of the roller.
- the treatment solution is preferably applied to the metal strips at a temperature in the range from about 15 to about 40 ° C., in particular in the range between 20 and 30 ° C.
- the metal strips are then dried without intermediate rinsing.
- the time between the application of the treatment liquid by the fleece roller and the start of drying should not be less than 1 second and not longer than 15 seconds.
- the drying itself can be carried out, for example, in a forced air oven, as is also the case with conventional no-rinse processes.
- the fleece roller is designed so that the treatment liquid is supplied to the surface through its interior, the rinsing is preferably also carried out via the interior of the fleece roller.
- the process according to the invention has the advantage that even with changing bandwidths, a uniform application of the treatment liquid over the entire bandwidth is made possible. This prevents different areas of the strips from being coated to different extents.
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002378935A CA2378935A1 (en) | 1999-07-15 | 2000-07-06 | Method for applying products without rinsing on moving metal strips |
AT00944008T ATE233831T1 (en) | 1999-07-15 | 2000-07-06 | METHOD FOR APPLYING NO-RINSE PRODUCTS TO RUNNING METAL BELTS |
AU58258/00A AU5825800A (en) | 1999-07-15 | 2000-07-06 | Method for applying products without rinsing on moving metal strips |
EP00944008A EP1198617B1 (en) | 1999-07-15 | 2000-07-06 | Method for applying products without rinsing on moving metal strips |
DE50001405T DE50001405D1 (en) | 1999-07-15 | 2000-07-06 | METHOD FOR APPLYING NO-RINSE PRODUCTS TO CURRENT METAL STRIPS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19933186A DE19933186A1 (en) | 1999-07-15 | 1999-07-15 | Process for applying no-rinse products to running metal belts |
DE19933186.3 | 1999-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001006037A1 true WO2001006037A1 (en) | 2001-01-25 |
Family
ID=7914900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/006398 WO2001006037A1 (en) | 1999-07-15 | 2000-07-06 | Method for applying products without rinsing on moving metal strips |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1198617B1 (en) |
AT (1) | ATE233831T1 (en) |
AU (1) | AU5825800A (en) |
CA (1) | CA2378935A1 (en) |
DE (2) | DE19933186A1 (en) |
TR (1) | TR200103548T2 (en) |
TW (1) | TW469179B (en) |
WO (1) | WO2001006037A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002079541A2 (en) * | 2001-03-28 | 2002-10-10 | Henkel Kommanditgesellschaft Auf Aktien | Post-passivation of a phosphatized metal surface in a continuous process |
WO2004074511A1 (en) * | 2003-02-21 | 2004-09-02 | Garvan Institute Of Medical Research | Diagnosis and treatment of baff-mediated autoimmune diseases and cancer |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10027444A1 (en) * | 2000-06-02 | 2002-02-14 | Basf Coatings Ag | Coil coating process with powder coating dispersions (powder slurries) |
DE10357912A1 (en) * | 2003-12-11 | 2005-07-14 | Lutz Freyer | Lubricating device for lubricating sheet metal strips |
DE102016203771A1 (en) | 2016-03-08 | 2017-09-14 | Henkel Ag & Co. Kgaa | Fluoride-free zirconium-based metal pretreatment for passivation |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3961991A (en) * | 1972-11-22 | 1976-06-08 | Nippon Paint Co., Ltd. | Method for chemical treatment of the surface of an iron substrate with phosphoric acid solutions |
GB2018632A (en) * | 1978-04-13 | 1979-10-24 | Bicc Ltd | Sheet processing |
JPH01149972A (en) * | 1987-12-07 | 1989-06-13 | Kobe Steel Ltd | Manufacture of chromated steel sheet |
EP0441061A1 (en) * | 1990-02-05 | 1991-08-14 | Sermatech International, Incorporated | Organic coatings with ion reactive pigments especially for active metals |
-
1999
- 1999-07-15 DE DE19933186A patent/DE19933186A1/en not_active Withdrawn
-
2000
- 2000-06-15 TW TW089111682A patent/TW469179B/en active
- 2000-07-06 EP EP00944008A patent/EP1198617B1/en not_active Expired - Lifetime
- 2000-07-06 DE DE50001405T patent/DE50001405D1/en not_active Expired - Fee Related
- 2000-07-06 AT AT00944008T patent/ATE233831T1/en not_active IP Right Cessation
- 2000-07-06 CA CA002378935A patent/CA2378935A1/en not_active Abandoned
- 2000-07-06 WO PCT/EP2000/006398 patent/WO2001006037A1/en active IP Right Grant
- 2000-07-06 TR TR2001/03548T patent/TR200103548T2/en unknown
- 2000-07-06 AU AU58258/00A patent/AU5825800A/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3961991A (en) * | 1972-11-22 | 1976-06-08 | Nippon Paint Co., Ltd. | Method for chemical treatment of the surface of an iron substrate with phosphoric acid solutions |
GB2018632A (en) * | 1978-04-13 | 1979-10-24 | Bicc Ltd | Sheet processing |
JPH01149972A (en) * | 1987-12-07 | 1989-06-13 | Kobe Steel Ltd | Manufacture of chromated steel sheet |
EP0441061A1 (en) * | 1990-02-05 | 1991-08-14 | Sermatech International, Incorporated | Organic coatings with ion reactive pigments especially for active metals |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 013, no. 414 (C - 635) 13 September 1989 (1989-09-13) * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002079541A2 (en) * | 2001-03-28 | 2002-10-10 | Henkel Kommanditgesellschaft Auf Aktien | Post-passivation of a phosphatized metal surface in a continuous process |
WO2002079541A3 (en) * | 2001-03-28 | 2003-12-31 | Henkel Kgaa | Post-passivation of a phosphatized metal surface in a continuous process |
WO2004074511A1 (en) * | 2003-02-21 | 2004-09-02 | Garvan Institute Of Medical Research | Diagnosis and treatment of baff-mediated autoimmune diseases and cancer |
Also Published As
Publication number | Publication date |
---|---|
EP1198617A1 (en) | 2002-04-24 |
DE19933186A1 (en) | 2001-01-18 |
TR200103548T2 (en) | 2002-06-21 |
EP1198617B1 (en) | 2003-03-05 |
ATE233831T1 (en) | 2003-03-15 |
CA2378935A1 (en) | 2001-01-25 |
TW469179B (en) | 2001-12-21 |
DE50001405D1 (en) | 2003-04-10 |
AU5825800A (en) | 2001-02-05 |
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