WO2001005931A1 - Compositions nettoyantes abrasives liquides - Google Patents

Compositions nettoyantes abrasives liquides Download PDF

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Publication number
WO2001005931A1
WO2001005931A1 PCT/EP2000/006592 EP0006592W WO0105931A1 WO 2001005931 A1 WO2001005931 A1 WO 2001005931A1 EP 0006592 W EP0006592 W EP 0006592W WO 0105931 A1 WO0105931 A1 WO 0105931A1
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WO
WIPO (PCT)
Prior art keywords
abrasive
compositions according
surfactant
compositions
contain
Prior art date
Application number
PCT/EP2000/006592
Other languages
English (en)
Inventor
Richard John Curtis
John Duffy
Peter Graham
Geoffrey Newbold
Claire Frances Stanley
Stefano Icaro Gianoli
Original Assignee
Unilever N.V.
Unilever Plc
Hindustan Lever Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever N.V., Unilever Plc, Hindustan Lever Ltd filed Critical Unilever N.V.
Priority to EP00954475A priority Critical patent/EP1196535A1/fr
Priority to BR0012492-3A priority patent/BR0012492A/pt
Priority to AU66920/00A priority patent/AU6692000A/en
Priority to MXPA02000596A priority patent/MXPA02000596A/es
Priority to PL00353006A priority patent/PL353006A1/xx
Publication of WO2001005931A1 publication Critical patent/WO2001005931A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1233—Carbonates, e.g. calcite or dolomite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

Definitions

  • the invention relates to aqueous liquid compositions which include an abrasive and a polymeric thickening agent to keep the abrasive suspended in the liquid.
  • Liquid abrasive cleaning compositions are well known in the art and typically comprise a combination of detergent surfactants, particularly anionic and nonionic surfactants, which together form a lamellar micelle phase and thereby cause thickening of the liquid.
  • the lamellar phase acts as a suspending system to keep the solid abrasive in a stable suspension.
  • an electrolyte is added to further improve the stability of the suspension.
  • liquid abrasive cleaning compositions comprising 0.02-20% of detergent, 1-70% of particulate abrasive and 0.01-10% of a thickening mixture consisting of a linear non-starch type polymer and a branched starch type polymer (amylopectin) .
  • the non-starch type polymers include various natural gums and synthetic polymers. Partially acetylated xanthan is particularly preferred. In practice the required amounts of thickening mixture are around 3% by weight of the total composition and the examples all specify 1.5% of non-ionic surfactant.
  • liquid abrasive cleaning compositions comprising a cross-linked polyacrylate, either at least one non-ionic surfactant or a combination of an anionic surfactant and a nonionic surfactant, a pH adjusting agent, and a calcium carbonate abrasive.
  • the compositions are said to contain 0.1-2% of polyacrylate, 0.1-10% of nonionic, up to 10% anionic and 5-60% abrasive. In practice, according to the examples they contain 0.25- 0.4% polymer, 0.5% or more nonionic and 40% abrasive. The nonionic is required to provide the right viscosity characteristics.
  • Similar compositions are disclosed in EP 649898 with the extra proviso that they contain hypochlorite and that the surfactant is bleach-stable.
  • liquid abrasive cleaning compositions comprising 10-30% of inorganic abrasive and a thickening system which consists of at least a cross-linked polyacrylate polymer and a smectite-type clay whereby the latter preferably forms about 50-80% of the thickening system.
  • the thickening system preferably comprises 1-2.5% of the composition.
  • the cleaning compositions all contain at least 0.5 of polyacrylate and at least 0.75% of clay.
  • EP 0 352 358 describes suspensions of very fine silica based powders, such as zeolites, comprising organic polymeric compounds with hydroxylic groups and a molecular weight above 1500 as suspending agents and requiring the presence of certain cationic or zwitterionic surfactants as stabilizers.
  • the particle size of the zeolites to be suspended is generally between 0.5 and 10 ⁇ m, with the bulk of the material having a particle size below 6 ⁇ m.
  • the only polymers exemplified are combinations of guar and xanthan gums.
  • an aqueous thickener composition suitable for a variety of end applications which comprises 0.04-30% w/w of a mixture of at least two surfactants in a specific ratio and with a difference in HLB of at least 1 unit and 0.01-5% w/w of an associative thickener selected from hydrophobically modified hydroyethylcellulose, hydrophobically modified nonionic polyol and hydrophobically modified alkali-soluble emulsion polymer.
  • an associative thickener selected from hydrophobically modified hydroyethylcellulose, hydrophobically modified nonionic polyol and hydrophobically modified alkali-soluble emulsion polymer.
  • the amount of associative thickener is 1-2% and the amount of surfactant mixture 1-10%.
  • EP 0 301 885 discloses liquid abrasive cleaning compositions comprising up to 70% of abrasive, an aqueous suspending medium made of a combination of anionic surfactants and electrolyte and also comprising a polyacrylate material having a molecular weight of between 500 and 3000.
  • the compositions in practice contain at least 3.5% of surfactant.
  • Liquid abrasive cleaning compositions are normally sold in a ready to use form which contains 10-50%, generally 20-45% solid abrasive. Such compositions cannot be diluted to e.g. 10-20% solid abrasive content without losing their stability leading to sedimentation. Although in the patent literature abrasive contents of up to 70% are quoted, such contents are not normally found in commercial products.
  • aqueous abrasive cleaning compositions which may be provided either in ready-to-use form, or in a concentrated form to be diluted by the consumer to a ready to use product without losing long term stability. Accordingly, the invention provides liquid aqueous abrasive cleaning compositions comprising an insoluble abrasive and an anionic thickening polymer.
  • liquid refers to products which are easily pourable, as well as to products which are thick, almost paste-like, but because of their flow properties can physically still be classified as liquids
  • aqueous liquid abrasive cleaning compositions according to the invention comprise 10-95% of a solid abrasive
  • a dispersed, suspended solid particulate abrasive is an essential ingredient of the liquid abrasive compositions according to the present invention.
  • the amount of abrasive is at least 20% and for practical purposes generally not more than 80%, more preferably at most 75%.
  • the products may be formulated and packaged as ready-to-use compositions having an abrasives content as specified above.
  • Such compositions may have the form of thick, viscous, almost paste-like products, or they may have the form of easily pourable liquids, which can easily be dispensed from a bottle with a relatively narrow opening and are similar in appearance to the products presently well known in the trade as "liquid abrasive cleaners".
  • the thick-viscous type of ready-to-use products preferably have a high abrasives content of at least 45%, more preferably more than 50%, even more preferably at least 55%, most preferably at least 60%.
  • the pourable liquid type of ready-to-use compositions on the other hand, preferably have a low abrasives content i.e. below 55%, more preferably 50% or less, even more preferably at most 45%.
  • compositions of the invention may be formulated and packaged as concentrates which are diluted before use by the addition of a suitable amount of water.
  • Such compositions have the advantage that they require smaller packaging for the same ultimate amount of ready-to- use product and thus provide an advantage in storage and transport. They may be prepared and transported in bulk as intermediates to a production facility close to the consumers where they are diluted with water and then packaged and sold as ready-to-use products. On the other hand, they may also be packaged directly and sold as concentrates, to be diluted with water by the consumer at home .
  • These products also have a high abrasives content of preferably at least 45%, more preferably more than 50%, even more preferably at least 55%, most preferably at least 60%.
  • Preferred abrasives have a Moh hardness of below 6, but above 1, although higher hardness abrasives can be employed for specialist applications.
  • the hardness is at least 2.
  • Suitable abrasives can be selected from inorganic abrasives such as zeolites, silicas, silicates, carbonates, aluminas, and organic polymeric abrasives such as polyethylene, polycarbonate, polyurethane, polystyrene, polypropylene, polyethylene terephthalate, polymethylmethacrylate and nylon, and mixtures thereof.
  • Preferred abrasives are: calcium carbonate (as calcite) , mixtures of calcium and magnesium carbonates (as dolomite) , zeolite, alumina, hydrated alumina, feldspar, talc and silica. Calcite and dolomite and mixtures thereof with lower amounts of silica, especially amorphous silica, are particularly preferred due to their low cost and good abrasive properties.
  • Preferred weight average particle sizes for the abrasives fall in the range 0.5-500 microns, with values of 10-100 microns being particularly preferred. In this range an acceptable compromise between good cleaning behaviour and low substrate damage is achieved. Nevertheless, for silica to be used in combination with calcite or dolomite an average particle size in the range of 100-500 microns is very suitable as well.
  • the anionic polymers are used for obtaining a stable suspension of the abrasive particles in the aqueous medium. They are available in various forms and from many suppliers, e.g. as aqueous suspensions or in solid powdered form. Furthermore, they may be hydrophobically modified and/or cross-linked. For "high abrasives content" products, i.e. products in which the amount of abrasive is at least 45%, more preferably more than 50%, even more preferably at least 55%, most preferably at least 60%, the polymers are preferably used in an amount of at least
  • the maximum level of polymers generally does not exceed 0.65% and is preferably at or below 0.60, more preferably less than 0.50 or even 0.45%, most preferably below 0.40 or even 0.35%.
  • the amount of polymer is preferably at least 0.07% and more preferably at least 0.10%, with maximum levels preferably being less than 0.50%, more preferably at most 0.40% or even 0.35%, most preferably at or below 0.30 or even 0.25%.
  • Suitable polymers are high molecular weight products , i.e. having a molecular weight of at least 10,000, particularly at least 50,000 or even 100,000. Suitable polymers are to be found among the polycarboxylate type polymers, such as various polyacrylate homopolymers and copolymers which generally have a molecular weight of 500,000 or more, often well over 1000,000, and various polysaccharides, such as carboxy-methylcelluloses, hydroxyethyl cellulose, hydroxypropyl-methylcellulose, carrageen, alginate, tragacanth gum, locust bean gum, guar gum, xanthan gum.
  • polycarboxylate type polymers such as various polyacrylate homopolymers and copolymers which generally have a molecular weight of 500,000 or more, often well over 1000,000, and various polysaccharides, such as carboxy-methylcelluloses, hydroxyethyl cellulose, hydroxypropyl-methylcellulose, carrageen, alginate, trag
  • synthetic polycarboxylate polymers e.g. hydrophobically modified emulsion polymers and carbomers (solid powdered polyacrylic acids) .
  • the former are particularly useful for the "low abrasives content” products, while the latter are particularly useful for the
  • suitable hydrophobically 5 modified emulsion polymers should preferably have ⁇ 0 of at least 1000 Pa.s.
  • Genaminox CSLTM (TM for amine oxide marketed by Clariant) , for meaning of ⁇ 0 : see below) .
  • Suitable polymers include:
  • ACUSOL HASE and ASE series such as 820 and 842;
  • POLYGEL/NEUTRAGEL series such as W30, DA, DS, DR and DB;
  • RHEOVIS series such as CRX 15 CARBOPOL series such as Aqua 30, ETD 2690, ETD 2691, ETD
  • PEMULEN Series such as TR1 and TR2 ;
  • ACUSOL is a trademark of Rohm & Haas
  • CARBOPOL and PEMULEN are trademarks of B F Goodrich
  • POLYGEL and NEUTRAGEL are trademarks of Sigma 3V
  • 25 RHEOVIS is a trademark of Ciba Specialities
  • STRUCTURE is a trademark of National Starch & Chemical Co.
  • ALCOGUM is a trademark of Alco.
  • thickening agents such as thickening clays or thickening silica are not necessary to achieve the required suspension stability and preferred embodiments of the invention do not contain such thickeners.
  • Nonionic, anionic, zwitterionic and amphote ⁇ c surfactants may be used. Nonionic surfactants are preferred. Nonionic surfactants may be combined with other classes of surfactants, particularly with anionic surfactants. Generally, the presence of zwitterionic or cationic surfactants, although possible, does not serve any useful purpose and compositions without such surfactants are a preferred embodiment of the invention.
  • Suitable nonionic surfactants can be broadly described as compounds produced by the condensation of alkylene oxides which are hydrophilic with an organic hydrophobic compound which may be aliphatic or alkylaromatic .
  • the length of the hydrophilic polyalkyleneoxy group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
  • Particular examples include the condensation product of aliphatic alcohols having from 8 to 22 carbon atoms in either straight or branched chain configuration with ethylene oxide, such as a coconut oil ethylene oxide condensate having from 2 to 15 moles of ethylene oxide per mole of coconut alcohol; condensates of alkylphenols whose alkyl group contains from 6 to 12 carbon atoms with 5 to 25 moles of ethylene oxide per mole of alkylphenol; condensates of the reaction product of ethylenediamine and propylene oxide with ethylene oxide, the condensate containing from 40 to 80% of ethyleneoxy groups by weight and having a molecular weight of from 5,000 to 11,000; tertiary amine oxides of structure R 3 NO, where one group R is an alkyl group of 8 to 18 carbon atoms and the others are each methyl, ethyl or hydroxyethyl groups, for instance dimethyldodecylamine oxide; tertiary phosphine oxides of structure R 3
  • the nonionic can also be selected from a range of alkyl polyglycosides .
  • Particularly suitable are the ethoxylated aliphatic alcohol surfactants, such as C9-C11 5EO, C12-C13 6.5EO and C13-C15 7EO (EO numbers are averages), and the tertiary amine oxides such as dimethyldodecylamine oxide and dimethyldecylamine oxide or amine oxide mixtures containing a large proportion of these.
  • Suitable anionic surfactants are water-soluble salts of organic sulphuric acid esters and of sulphonic acids which have in the molecular structure an alkyl group containing 6- 22 C-atoms. They are usefully added to provide the compositions with good foaming properties, which are often considered desirable by the consumer.
  • anionic surfactants are water soluble salts of: long chain (i.e. 8-22 C-atom) alcohol sulphates (hereinafter referred to as PAS) , especially those obtained by sulphating the fatty alcohols produced by reducing the glycerides of tallow or coconut oil; alkyl benzene sulphonates, such as those in which the alkyl group contains from 6 to 20 carbon atoms; secondary alkanesulphonates (hereinafter referred to as SAS) .
  • PAS long chain alcohol sulphates
  • SAS secondary alkanesulphonates
  • alkyl glyceryl ether sulphates especially those ethers of the fatty alcohols derived from tallow and coconut oil; fatty acid monoglyce ⁇ de sulphates; sulphates of the reaction product of one mole of a fatty alcohol and from 1 to 6 moles of ethylene oxide; salts of alkylphenol ethyleneoxy-ether sulphates with from 1 to 8 ethyleneoxy units per molecule and in which the alkyl groups contain from 4 to 14 carbon atoms; and mixtures thereof.
  • the preferred water-soluble synthetic anionic surfactants are the sodium, potassium, magnesium and ammonium salts of alkyl-benzenesulphonates, olefmsulphonates and alkyl sulphates, and the fatty acid mono-glyce ⁇ de sulphates.
  • Amphote ⁇ c surfactants that optionally can be employed are derivatives of aliphatic secondary and tertiary amines containing an alkyl group of 8 to 18 carbon atoms and an aliphatic group substituted by an anionic water-solubilismg group, for instance sodium 3-dodecylammo-prop ⁇ onate, sodium 3-dodecylammopropane sulphonate and sodium N-2- hydroxydodecyl-N-methyl taurate.
  • anionic water-solubilismg group for instance sodium 3-dodecylammo-prop ⁇ onate, sodium 3-dodecylammopropane sulphonate and sodium N-2- hydroxydodecyl-N-methyl taurate.
  • surfactants are compounds commonly used as surface-active agents mentioned m the well-known textbooks "Surface Active Agents”, Volume I by Schwartz and Perry and “Surface Active Agents and Detergents", Volume II by Schwartz, Perry and Berch.
  • compositions according to the invention may contain a total amount of 0-1% of surfactant, preferably below 0.5%. More preferably the total level of surfactant does not exceed 0.4% or even 0.3%. For a useful increase in cleaning and/or foaming properties a minimum level of 0.01% of total surfactant is advisable, preferably at least 0.02%, more preferably at least 0.05%, or even 0.1%.
  • the level of nonionic surfactant should preferably be below 0.5%, more preferably be at or below 0.45% and most preferably at or below 0.35% or even 0.3%.
  • the level of nonionic is preferably at least 0.01%, more preferably at least 0.02%.
  • the amount of nonionic is more preferably at least 0.02%, most preferably at least 0.03%.
  • compositions according to the invention are alkaline, more particularly they have pH above 8, preferably 9 or higher.
  • the compositions can be made alkaline with use of a suitable base such as an alkali metal hydroxide or carbonate, ammonia or an organic base with pKa above 9 such as triethylamine, amino-methylpropanol (AMP) , aminobutanol, mono-, di- or tri-ethanolamine, monoisopropylamine or aminomethylpropanediol .
  • AMP is particylarly useful, and preferably if added in an amount of up to 0.5%, more preferably 0.2-0.4% in the absence of another base or 0.1- 0.2% in the presence of another base.
  • compositions according to the invention generally do not need any extra electrolyte other than the possible anionic surfactant and the base for setting the pH .
  • level of additional electrolyte is below 0.3%, more preferably below 0.2%.
  • the abrasive compositions according to the invention may contain optional components which improve their cleaning properties such as organic solvents known in the art for use in abrasive cleaning compositions, particularly solvents of which the molecules bear a polar group, such as hexanol, ethylene- and propylene glycol alkyl ethers. They may also contain bleaching agents, particularly halogen bleaching agents, more particularly hypochlo ⁇ te provided that hypochlonte stable polymers and surfactants are used.
  • components to further increase their attraction to the consumer such as colorants, optical b ⁇ ghteners and particularly perfumes (perfumes may have a further positive influence on the stability of the suspension) ; preservatives to prevent microbial contamination.
  • liquid abrasive cleaning compositions according to the invention have such fluid flow characteristics that they are stable suspensions when not in use, but thin enough to pour the liquid from the packaging container and spread it on the soiled surface without appearing thin and watery.
  • the liquid product preferably has the following liquid flow properties :
  • ⁇ o is at least 1500 Pa .
  • s ⁇ c is 2.5-25 ⁇ 2 ⁇ is at least 0.1 Pa .
  • ⁇ 0 is the viscosity at zero shear rate (determined by extrapolation)
  • ⁇ c is the shear stress at which the viscosity is 0.1.
  • ⁇ o is the viscosity at a shear rate of 21 s -1 .
  • ⁇ 0 is at least 2000Pa.s, more preferably at least
  • ⁇ 2 ⁇ is 0.3-5.0, more preferably 0.6-1.8, most preferably 1.0-1.5 Pa . s .
  • CSL 100 (TA Instruments) with vane and basket measuring system (basket internal diameter 48mm, vane diameter 38mm and height 24.5mm) to measure viscosity from a stress ( ⁇ ) of 0.01 Pa to the stress required to give a shear rate of 1
  • Satisfactory "high abrasives content” concentrated liquid abrasive cleaning compositions are liquids or pastes which are suitable for dilution with water to 1.2-4 times, preferably 1.5-3 times, more preferably 2-3 times the original volume, thereby producing a stable ready-to-use liquid abrasive cleaning composition, preferably a cleaning composition with the liquid flow properties specified above.
  • ready-to-use liquid abrasive cleaning compositions are generally viscous, or almost paste-like liquids. Although they do not generally spread easily when put on a surface, they do obtain a smooth and "undisturbed” surface again when left alone for a few minutes to a few hours in the container.
  • Such products are preferably not packaged in a container from which they have to be dispensed by pouring, however, containers such as a tub or tin, from which suitable amounts can be taken out on a suitable applicator such as a wet cloth or sponge, or containers from which they can be dispensed by squeezing, such as a tube, are very useful.
  • compositions according to the invention may simply be prepared by mixing the various components. It is preferred to first make a dilute (e.g. 1-2%) aqueous solution or dispersion of the polymer and then mix in the other components subsequently.
  • the other components may be first made into a slurry with the remaining amount of water after which the solution (dispersion) and the slurry are mixed. Sometimes it is advantageous to neutralize the aqueous polymer solution with part of the base before mixing it with the other components.
  • Liquid abrasive cleaning compositions according to the Examples 1-4 in Table I below were prepared.
  • compositions were prepared by first diluting the 30wt% ACUSOL solution to lwt% and neutralising it with NaOH solution.
  • the ACUSOL solution is stirred at room temperature until it appears homogeneous, while taking care that the solution is not aerated.
  • the remaining components and the remainder of the water of the formula are made into an aqueous slurry and the ACUSOL solution is carefully added while stirring. Stirring is continued until a homogeneous suspension is obtained, again taking care that aeration is avoided.
  • a composition identical to Example 1 was prepared by diluting a quantity of the composition of Example 3 with an equal volume of water followed by shaking or stirring.
  • Example 4 a composition identical to Example 2 was prepared by diluting a quantity of Example 4 with an equal volume of water .
  • Concentrated abrasive cleaning compositions having the composition described in Table II were prepared by making a 2% dispersion of the polymer in water and adding this, with stirring, to a slurry of calcite, surfactant, NaOH and perfume in the remaining amount of water. Stirring was continued until a homogeneous mixture was obtained.
  • the compositions could be diluted by adding an equal volume of water and shaking briefly, to obtain ready to use cleaning compositions containing 45% abrasive.
  • the polymer was Polygel DR, the amine oxide was Genaminox CSL, the calcite was Omyacarb 30. All examples additionally contained 0.4% perfume.
  • a "high abrasives content" ready-to-use product was prepared having the composition described below:
  • the product had pH 9.8 and a density of 1.8 g/cm . It was stored in a tub from which it could easily be taken on a wet cloth to be applied to a surface to be cleaned. The surface of the product remaining in the tub restored its smooth and level appearance again after being left for half an hour.

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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
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Abstract

L'invention concerne des compositions nettoyantes abrasives, liquides et aqueuses, qui renferment 10 à 95 % d'un abrasif solide, 0,05 à 0,70 % d'un polymère anionique épaississant, et jusqu'à 1,0 % d'un tensioactif. Ces compositions nettoyantes, qui peuvent se présenter sous une forme concentrée contenant 45 % ou plus d'un abrasif, sont aptes à être utilisées telles quelles ou à être diluées pour obtenir une composition abrasive prête à l'emploi. Dans une variante, ces compositions peuvent se présenter sous une forme prête à l'emploi renfermant 55 % ou moins d'un abrasif.
PCT/EP2000/006592 1999-07-16 2000-07-11 Compositions nettoyantes abrasives liquides WO2001005931A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP00954475A EP1196535A1 (fr) 1999-07-16 2000-07-11 Compositions nettoyantes abrasives liquides
BR0012492-3A BR0012492A (pt) 1999-07-16 2000-07-11 Composições de limpeza abrasivas lìquidas aquosas
AU66920/00A AU6692000A (en) 1999-07-16 2000-07-11 Liquid abrasive cleaning compositions
MXPA02000596A MXPA02000596A (es) 1999-07-16 2000-07-11 Composiciones de limpieza, abrasivas, liquidas.
PL00353006A PL353006A1 (en) 1999-07-16 2000-07-11 Liquid abrasive cleaning compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99305641 1999-07-16
EP99305641.5 1999-07-16

Publications (1)

Publication Number Publication Date
WO2001005931A1 true WO2001005931A1 (fr) 2001-01-25

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PCT/EP2000/006592 WO2001005931A1 (fr) 1999-07-16 2000-07-11 Compositions nettoyantes abrasives liquides

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EP (1) EP1196535A1 (fr)
CN (1) CN1230514C (fr)
AR (1) AR024769A1 (fr)
AU (1) AU6692000A (fr)
BR (1) BR0012492A (fr)
HU (1) HUP0202631A3 (fr)
MX (1) MXPA02000596A (fr)
PL (1) PL353006A1 (fr)
RU (1) RU2265044C2 (fr)
TR (1) TR200200081T2 (fr)
WO (1) WO2001005931A1 (fr)
ZA (1) ZA200110007B (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1251163A1 (fr) * 2001-04-19 2002-10-23 Minebea Co., Ltd. Composition de nettoyage liquide
WO2003031554A1 (fr) * 2001-10-05 2003-04-17 Unilever N.V. Compositions liquides de nettoyage abrasif
WO2004085597A1 (fr) * 2003-03-25 2004-10-07 Henkel Kommanditgesellschaft Auf Aktien Produit de lavage ou de nettoyage
EP2173847A2 (fr) * 2007-07-31 2010-04-14 The Dial Corporation Nettoyant abrasif liquide distribuable, à fluidification par cisaillement, présentant des propriétés améliorées d'élimination des salissures, d'aptitude au rinçage et de stabilité de phases
US7982624B2 (en) 2002-07-19 2011-07-19 Ident Technology Ag System and method for accident prevention
US8263540B2 (en) 2010-08-27 2012-09-11 Ecolab Usa Inc. Detergent compositions with combinations of acrylic and maleic acid homopolymers and/or salts thereof for aluminum protection
US8691018B2 (en) * 2010-08-27 2014-04-08 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications

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JP5902669B2 (ja) * 2010-04-21 2016-04-13 ザ プロクター アンド ギャンブル カンパニー 液体クリーニング及び／又はクレンジング組成物
CN102834499B (zh) * 2010-04-21 2017-05-31 宝洁公司 液体清洁和/或净化组合物
EP2992073B1 (fr) * 2013-04-29 2018-12-05 Unilever PLC, a company registered in England and Wales under company no. 41424 Procédé pour épaissir une composition de détergent liquide
CN104046520A (zh) * 2014-05-19 2014-09-17 梁晓 一种无磷洗涤剂组合物

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Cited By (17)

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Publication number Priority date Publication date Assignee Title
EP1251163A1 (fr) * 2001-04-19 2002-10-23 Minebea Co., Ltd. Composition de nettoyage liquide
US6670318B2 (en) 2001-04-19 2003-12-30 Minebea Co., Ltd. Liquid cleanser
WO2003031554A1 (fr) * 2001-10-05 2003-04-17 Unilever N.V. Compositions liquides de nettoyage abrasif
AU2002337139B2 (en) * 2001-10-05 2006-03-09 Unilever Plc Liquid abrasive cleaning compositions
US7982624B2 (en) 2002-07-19 2011-07-19 Ident Technology Ag System and method for accident prevention
WO2004085597A1 (fr) * 2003-03-25 2004-10-07 Henkel Kommanditgesellschaft Auf Aktien Produit de lavage ou de nettoyage
EP2173847A2 (fr) * 2007-07-31 2010-04-14 The Dial Corporation Nettoyant abrasif liquide distribuable, à fluidification par cisaillement, présentant des propriétés améliorées d'élimination des salissures, d'aptitude au rinçage et de stabilité de phases
EP2173847A4 (fr) * 2007-07-31 2012-02-15 Dial Corp Nettoyant abrasif liquide distribuable, à fluidification par cisaillement, présentant des propriétés améliorées d'élimination des salissures, d'aptitude au rinçage et de stabilité de phases
US8263540B2 (en) 2010-08-27 2012-09-11 Ecolab Usa Inc. Detergent compositions with combinations of acrylic and maleic acid homopolymers and/or salts thereof for aluminum protection
US8480808B2 (en) 2010-08-27 2013-07-09 Ecolab Usa Inc. Detergent compositions with combinations of acrylic and maleic acid homopolymers and/or salts thereof for aluminum protection
US8691018B2 (en) * 2010-08-27 2014-04-08 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US20140162928A1 (en) * 2010-08-27 2014-06-12 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US9029314B2 (en) * 2010-08-27 2015-05-12 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US20150210962A1 (en) * 2010-08-27 2015-07-30 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US9567552B2 (en) 2010-08-27 2017-02-14 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US20170107314A1 (en) * 2010-08-27 2017-04-20 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications
US10472438B2 (en) 2010-08-27 2019-11-12 Ecolab Usa Inc. High molecular weight polyacrylates for aluminum protection in warewash applications

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BR0012492A (pt) 2002-04-02
ZA200110007B (en) 2003-02-26
AR024769A1 (es) 2002-10-23
HUP0202631A2 (hu) 2002-11-28
AU6692000A (en) 2001-02-05
RU2265044C2 (ru) 2005-11-27
PL353006A1 (en) 2003-09-22
CN1230514C (zh) 2005-12-07
MXPA02000596A (es) 2002-07-02
EP1196535A1 (fr) 2002-04-17
CN1361819A (zh) 2002-07-31
HUP0202631A3 (en) 2005-02-28
TR200200081T2 (tr) 2002-05-21

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