WO2001004887A1 - Supports optiques jetables et procede de fabrication - Google Patents

Supports optiques jetables et procede de fabrication Download PDF

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Publication number
WO2001004887A1
WO2001004887A1 PCT/US2000/018944 US0018944W WO0104887A1 WO 2001004887 A1 WO2001004887 A1 WO 2001004887A1 US 0018944 W US0018944 W US 0018944W WO 0104887 A1 WO0104887 A1 WO 0104887A1
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WO
WIPO (PCT)
Prior art keywords
substrate
optical
optical media
disk
lacquer
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Application number
PCT/US2000/018944
Other languages
English (en)
Inventor
Yannis Bakos
Erik Brynjolfsson
Original Assignee
Flexplay Technologies, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flexplay Technologies, Inc. filed Critical Flexplay Technologies, Inc.
Priority to EP00945338A priority Critical patent/EP1212752A1/fr
Priority to IL14754300A priority patent/IL147543A0/xx
Priority to CA002379104A priority patent/CA2379104A1/fr
Priority to BR0012382-0A priority patent/BR0012382A/pt
Priority to JP2001509031A priority patent/JP4243059B2/ja
Priority to AU59301/00A priority patent/AU777945B2/en
Publication of WO2001004887A1 publication Critical patent/WO2001004887A1/fr
Priority to IL147543A priority patent/IL147543A/en
Priority to HK02109047.2A priority patent/HK1049227A1/zh

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Classifications

    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
    • G11B23/0014—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture record carriers not specifically of filamentary or web form
    • G11B23/0021—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture record carriers not specifically of filamentary or web form discs
    • G11B23/0028—Details
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
    • G11B23/02—Containers; Storing means both adapted to cooperate with the recording or reproducing means
    • G11B23/03—Containers for flat record carriers
    • G11B23/032—Containers for flat record carriers for rigid discs
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
    • G11B23/02—Containers; Storing means both adapted to cooperate with the recording or reproducing means
    • G11B23/03—Containers for flat record carriers
    • G11B23/0327—Containers for flat record carriers for special applications not otherwise provided for
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
    • G11B23/28—Indicating or preventing prior or unauthorised use, e.g. cassettes with sealing or locking means, write-protect devices for discs
    • G11B23/281—Indicating or preventing prior or unauthorised use, e.g. cassettes with sealing or locking means, write-protect devices for discs by changing the physical properties of the record carrier
    • G11B23/282—Limited play
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
    • G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
    • G11B7/2534—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins polycarbonates [PC]
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
    • G11B7/2542—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of organic resins
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
    • G11B7/259—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on silver
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
    • G11B7/2595—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on gold

Definitions

  • the invention relates generally to the field of optical media. More particularly, the invention relates to time sensitive disposable optical media.
  • Optical disks such as CDs and DVDs are sold and rented to consumers for use at home.
  • the content of the optical disks may be music, movies, software or data.
  • the cost is associated not primarily with the manufacturing cost of the optical disks, but with the value of the information, such as movies or software, encoded on the disks.
  • Content providers such as movie studios or software companies, do not want to sell at a low cost copies of their material that will have a long lifetime in the marketplace. Rentals of CDs and DVDs enable consumers to access the information at a lower cost, but the need to return the rentals on time is inconvenient.
  • CDs and DVDs are generally manufactured according to the following process. This information was downloaded from the web site of Disctronics Manufacturing (UK) Ltd., Southwater Business Park, Southwater, Westshire, England on January 26, 1999, and has been slightly edited.
  • Mastering of CDs and CD-ROMs is a complex process needed to create a stamper (used to mould the CDs) from the premastered data.
  • the processes are carried out in a class 1,000 clean room. Operators wear special clothing including face masks and footwear to minimize any particles.
  • the surface of the clean glass master is then coated with a primer and then a photo resist layer 140 to 150 microns thick by spin coating.
  • the thickness should be matched to the molding cycle time. Shorter cycle times imply a thicker resist layer to ensure good pit geometry.
  • the uniformity of the layer is measured with an infra red laser.
  • the photo resist coated glass master is then baked at about 80° C for 30 minutes. This hardens the photo resist layer ready for exposing by laser light.
  • LBR Laser Beam Recorder
  • the laser can be blue, violet or (for DVD and CD mastering) ultra violet.
  • the laser beam is modulated to expose the photoresist where pits should be while the glass master spins at exactly the correct linear velocity and is moved gradually and smoothly to maintain the correct track pitch and linear velocity.
  • the LBR is controlled by a PC based system which formats the data from the source CD, U-matic or Exabyte tape with the CIRC error protection and EFM modulation. If an error occurs which cannot be corrected during mastering the controller will abort recording.
  • Speed of laser beam recording depends on the machine and input media. At one time when every CD was audio, U-matic was the only media used and only allow single speed mastering. Other newer media allow faster mastering up to 4 times, with even faster speeds possible. The following table summarizes the mastering speeds for different media.
  • Audio data is often transferred offline to a faster format before mastering
  • CD 4x Faster if LBR capable
  • CD-R 4x Depends on quality of CD-R media used and speed of LBR
  • Hard disk 4x Faster if LBR capable
  • the absolute limit of speed is dictated by the robustness of the glass. For 240 mm glass plates, the practical limit is around 6x for CD mastering.
  • Network mastering is a new development whereby the data content of Exabytes, CDs etc (containing the audio or other data) is transferred to a server and mastering carried out from this data (which can be checked prior to mastering) via a high speed network.
  • Several LB s can be connected to the network and mastering jobs can be scheduled in advance. The result is higher speed, more reliable mastering.
  • the exposed photoresist surface is developed to remove the photoresist exposed by the laser and therefore create pits in the surface. These pits should extend right through the photoresist to the glass underneath to achieve good pit geometries as specified in the Red Book.
  • the glass itself is unaffected by this process and acts merely as a carrier for the photoresist.
  • the active surface (i.e. containing pits) of the developed glass master is then metallized either with nickel or nickel alloy created by sputtering or with silver by evaporation. If nickel or nickel alloy is used this becomes part of the Father which is created by electroforming so the pit geometry is maintained. If silver is used, the nickel Father is grown on top of the silver resulting in some distortion of the pit shapes, but this is not usually enough seriously to impair the resultant pits.
  • the father is electroformed from the metallized glass master and then the surface containing the 'bumps' is oxidized ready for the next stage. (This allows the mother to be separated from the father). The mother is then electroformed from the father and is an essential intermediate stage from which the stamper(s) are then electroformed in a similar way.
  • the father can then be used as a stamper. Only mothers are needed for subsequent stampers. Additional stampers are created for long runs of CDs.
  • the photoresist on the glass master is then removed and the glass cleaned ready to be used again. If silver is used, it is recovered and recycled.
  • stamper is checked visually, the back polished, it is punched to the required outside diameter, a hole accurately punched in the center and finally it is checked on a stamper player before being fitted to the press.
  • stamper finishing is an important stage as it will affect the quality of the final disc.
  • the center hole must be accurately cut to avoid eccentricity which could affect the playability of CD-ROMs using modern high speed CD-ROM drives.
  • the stamper thickness must be uniform to avoid unbalance problems in the finished discs.
  • Finished stampers are stored in protective plastic packages ready to be fitted to a molding machine.
  • a complete replication line comprising molding machine, metallizer, lacquer unit, printer (normally 3 color) and inspection. Good and bad discs are transferred to different spindles. Finished discs are removed on spindles for packing.
  • An alternative to this does not include a printer. This allows a new job to continue without being stopped while the printer is being setup.
  • a replication line comprising two molding machines, metallizer, lacquer unit and inspection. This provides a better match between molding machine and downstream equipment cycle times and is currently the most flexible solution.
  • Each molding machine can run different titles, the discs being separated after inspection and placed on different spindles. Also called Duoline.
  • Optical grade polycarbonate is 'baked' to remove any moisture and is injection molded in a high pressure molding machine (press) using the stamper mounted in the mould fixed to the press.
  • This mould is in two parts and provides a cavity which ensures that perfectly molded discs are produced with the correct dimensions every time.
  • One half of the mould contains the stamper while the other half contains the mirror block to ensure a smooth surface.
  • the hydraulic press applies a force to the two halves of the mould which are closed. Molten polycarbonate is then injected into the cavity and held in place by the applied pressure while the disc cools and solidifies. Pressed discs, after cooling, are transferred by robot arms to a spindle for the next stage in the process.
  • Molding parameters which can affect the resultant CD include stamper geometry, mould temperature, polycarbonate temperature, compression force and cycle time.
  • Cycle times for injection molding have decreased substantially from over 10 seconds some 10 years ago to under 4 seconds for the latest presses and moulds. Cycle times of under 3 seconds are also becoming possible.
  • the polycarbonate discs after molding are transparent. In order that the laser can read the pits they need to be covered by a mirror surface to reflect the laser light.
  • the next stage is therefore to metalize the active surface of each disc with aluminum by sputtering.
  • Sputtering requires the transparent polycarbonate discs to be transferred to the sputtering chamber which is then quickly evacuated of air and filled with argon gas.
  • the argon ions are attracted to the aluminum target by the use of a high voltage. As the ions strike the target, particles of aluminum are ejected and are deposited onto the CD surface.
  • Modern metalizers are capable of cycle times of under 2 seconds allowing them to be used in duolines where one metallizer can handle the output from two molding machines.
  • the fastest metallizers can achieve cycle times of 1.5 seconds.
  • Lacquering The back of the aluminum layer is protected by a lacquer which is spread as a liquid evenly across the surface of the disc by spin coating. The centrifugal force created by spinning the disc ensures that the lacquer covers the whole disc in an even layer.
  • lacquer overlaps the aluminum therefore sealing it from the elements. If left exposed, aluminum will start to oxidize within a few days.
  • the lacquer is cured by ultra-violet (UV) light producing a hard protective surface.
  • UV ultra-violet
  • Lacquering involves two steps in the spin-coating process, lacquer deposition and spin-off. Cycle times of under 2 seconds are normally achieved by either splitting the two steps into two stations or using two spin coating stations.
  • the upper surface of a finished disc is printed with up to five colors by a flat silk screen process. Each color requires a different screen created from label films produced as color separations from the artwork. Each color is printed using a squeegee which pushes the ink through the mesh of the screen on to the disc surface. The inks are then cured using UV light to produce a durable surface.
  • DVD Manufacture DVD discs are more difficult to manufacture than CDs, requiring new, purpose designed equipment rather than upgraded equipment. DVD discs are different from CDs in the following ways:
  • the differences between DVD and CD means that much of the mastering process for DVD needs new equipment including improved glass master preparation, laser beam recording and developing.
  • the photo-resist layer should, ideally be about 120 nm in thickness (instead of 140 nm for CD) but successful mastering using the same thickness as for CDs is possible. Any defects or variations in thickness of this layer must be kept very small.
  • Laser beam recording requires a smaller spot size, higher numerical aperture and tighter tolerances than for CDs.
  • Many LBRs designed for DVD mastering use a UV laser (instead of the blue or violet laser used for CDs). To handle CD and DVD mastering, it is necessary to change the numerical aperture from 0.6 for CD to 0.9 for DVD mastering.
  • DVD data is formatted differently from CDs and requires new formatting hardware/software to handle the RSPC error correction, 8 to 16 modulation and the higher channel data rate.
  • Stamper finishing requires more care than for CDs, since tilt (variations in flatness of the final disc) is critical for DVD.
  • D VD-9 (dual layer) discs require the upper layer (layer 1 ) to be mastered with the turntable rotating in the reverse direction. Also, the direction of writing will be either from the inside to outside (parallel track) or outside to inside (opposite track), depending on the application requirements.
  • CSS Content Scrambling System
  • DVD-5 and DVD- 10 were the first discs to be manufactured.
  • DVD-9 has proved to be considerably more difficult and there is a shortage in manufacturing capacity for these dual layer discs.
  • All DVD discs comprise two substrates each 0.6mm thick and molded separately. »For DVD-5 discs, the active substrate is metallized and then bonded with the blank, non-metallized substrate.
  • the layer 1 aluminum layer must be uniform in thickness to avoid jitter.
  • DVD molding is similar to CD molding but with some important differences. »Two pressings are needed for each final DVD disc
  • the thinner disc also requires different molding parameters, such as a shorter injection time and higher mould temperature.
  • Hot melt bonding is the method used for Laserdiscs where the two substrates just need to be glued together. It is also suitable for single layer (single or double sided) DVDs. The process is simple and relatively inexpensive.
  • UV Cured bonding is suitable for dual layer discs because it is transparent. It involves coating one or both of the substrates with a UV cured resin similar to normal lacquer.
  • Disctronics use Radical UV Cured bonding which is compatible with all DVD formats. DVD-9 bonding is particularly difficult as the bonding layer must *be of uniform thickness within close tolerances
  • Finishing comprises label printing, for which there are a number of options, and adding the Burst Cutting Area.
  • BCA Burst Cutting Area
  • DVD inspection and testing requires the use of some different techniques, new parameters to be tested and new readers.
  • DVD inspection is similar to CD inspection but includes tilt. Discs must be inspected after bonding as this stage can introduce tilt and other defects. DVD-
  • Jewel case (the most common) comprises a transparent plastic case with hinged lid, a plastic tray, inlay card and booklet.
  • a range of outer packaging is used particularly for CD-ROM discs e.g. to hold a printed manual.
  • Discs are packed in standard jewel or slimlines cases with paper parts by automated machines and overwrapped and packed into boxes as required.
  • the packaged CD can have stickers automatically added and, optionally, can be over- wrapped.
  • Machines operate at speeds up to 100 CDs per minute or more. For smooth operation at these speeds it is essential that cases and paper parts adhere to the specified dimensions and other physical properties.
  • a typical optical disk for use in a computer's optical readout system data is stored as a series of lands and pits. This is accomplished by stamping along spiral tracks on a transparent plastic disk, overlaying this with a reflective coating, and thereafter superimposing a protective layer over this coating.
  • Light from a semiconductor laser is directed toward the lands and pits from below and the reflected light impinges upon a photodetector which converts the presence or absence of the pits into a binary electrical signal. Because the focused laser spot is so minute, the amount of information that can be stored onto the surface of the disk is immense. Adjacent tracks need only be spaced apart by approximately 1.6 microns and, hence, approximately 40,000 tracks may be available on a conventional 120 mm diameter (5 inch) optical disk.
  • the electrical signals delivered to the optical readout system correspond to the magnitude of reflected light which either increases or decreases due to interference and/or diffraction by the preformatted data structures.
  • an optical disk which is adapted for use in an optical readout system of a computer that includes a light source operative to produce an interrogating beam of light for reading data structures.
  • the optical disk according to the present invention includes a substrate and a metallic layer encoded with information stored as a plurality of data structures that are readable by the interrogating beam of light.
  • the substrate is disposed in a confronting relationship with the metallic layer, and a film of a reactive compound is superimposed over at least some of these data structures.
  • the reactive compound is selected to be of a type which is operative to change physical characteristics in response to a selected stimulus, thereby to affect readability of the data by the interrogating beam.
  • the reactive compound is disposed between the light source's interrogating beam and the metallic layer.
  • This reactive compound may be interposed between the substrate and the metallic layer and have a thickness in a range of 0.1-10 microns, and preferably 1-5 microns. Alternatively, it may be disposed on an outer surface of the substrate.
  • the metallic layer is preferably contoured to include a sequence of pits and lands which define the plurality of data structures, with the reactive compound superimposed over at least some of these pits and lands.
  • the selected stimulus to which the reactive compound responds is selected to be either visible light, infrared light, an ambient environment containing light and oxygen, or simply air.
  • the reactive compound may be a photoreactive material and preferably one selected from a spiropyran class of photochromic compounds —for example, 6-nitro-l'3'3'- trimethylspiro-(2H-lbenzothiopyran-2,2'-indoline), or 6-nitro-l -S-BIPS for short, and other related compounds.
  • the reactive compound would therefore be photoreactive with oxygen and preferably operate to change its physical characteristics in response to an interrogating beam of light having a wavelength of approximately 650 nanometers (nm), which is encountered with digital versatile disk (DVD) readers.
  • the reactive compound may be one which is operative after an accumulated duration of time to oxidize and alter an optical characteristic thereof.
  • a reactive compound would change from an optically transparent condition to an optically opaque condition wherein it absorbs light having a wavelength within a desired range. This wavelength could be either 650 nanometers (nm), as discussed above, but may also be approximately 780 nanometers (nm).
  • the oxidizing reactive compound may be selected from a group of dyes consisting of methylene blue, brilliant cresyl blue, basic blue 3 and toluidine blue 0.
  • Smith et al also teach packaging of the disk in an inert environment:
  • such an optical disk would preferably be contained in a package in the form of an aluminum bag coated with polyethylene.
  • an inert gaseous environment such as argon or dry nitrogen.
  • a goal of the invention is to simultaneously satisfy the above-discussed requirements of low cost, limited content lifetime, avoidance of rental returns and minimum changes to existing manufacturing processes which, in the case of the prior art, are not simultaneously satisfied.
  • One embodiment of the invention is based on an optical disk, comprising: a substrate; a metal layer coupled to said substrate; and a lacquer coupled to said metal layer, wherein optical properties of said substrate change upon an exposure of said substrate to air, said exposure degrading readability of data recorded on said optical disk.
  • Another embodiment of the invention is based on a package containing an optical disk, said optical disk comprising: a substrate, a metal layer coupled to said substrate; and a lacquer coupled to said metal layer, wherein opening said package triggers a process that changes optical properties of said substrate, thereby degrading an ability to read data recorded on said optical disk.
  • Another embodiment of the invention is based on an optical disk, comprising: a substrate; a metal layer coupled to said substrate; and a lacquer coupled to said metal layer, wherein at least one member selected from the group consisting of said substrate and said lacquer permit controlled exposure of said metal layer to air, thereby degrading readability of data recorded on said optical disk.
  • Another embodiment of the invention is based on a package containing an optical disk, said optical disk comprising: a substrate, a metal layer coupled to said substrate; and a lacquer coupled to said metal layer, wherein opening said package triggers a process that changes reflective properties of said metal layer, thereby degrading an ability to read data recorded on said optical disk.
  • our invention consists of a "trench" or set of pores over the table of contents area is filled with a material that turns opaque or cloudy upon exposure to oxygen or other substances in the environment.
  • a controlled environment e.g., inside the packaging
  • a coating or substrate might be transparent in a hydrogen environment but gradually become opaque or cloudy in most or all other environments including normal air.
  • the substrate to be the one or more layers through which the laser light passes before impinging on the metal layer.
  • the substrate layer is polycarbonate or PMMA, but other materials known to those skilled in the art may be used.
  • the lacquer to be the layer or layers not in the path of the laser light during the process of reading data from the disk.
  • One or more of these layers may be composed a material identical or similar to the one used for the substrate.
  • the laser light is not intended to pass through the lacquer.
  • a one-sided disk such as a CD or a DVD-5
  • the lacquer will typically include a layer binding together the two sides of the disk.
  • One aspect of our invention consists of attacking solely, primarily or first the table of contents (or directory) information on an optical disk.
  • Benefits include higher manufacturability because a smaller part of the disk may need to be rendered inoperable, and more abrupt deterioration, as instead of deteriorating parts of the video content on a DVD, possibly in a gradual process, attacking the table of contents will prevent the player from accessing entire sections of the video content, and render the disk unplayable in a relatively sharp time frame. This is likely to be preferable to having an extended period during which the disk is playable, but not at full quality. It should be noted that because of the much stronger error correction in the table of contents, previous approaches such as Smith et al, would likely result in the table of contents failing last.
  • an aspect of our invention consists of increasing the thickness of the material that interferes with reading of the optical data. For instance instead of a coating of a few microns, our invention would allow a layer of material up to the thickness of the substrate, possibly reaching all the way to the metal layer. That would facilitate interfering with the reading laser.
  • this invention would consist of pores or trenches of appropriate dimensions that are imprinted on the substrate during the molding process, by using a specially engineered molding plate instead of the standard flat plate ("mirror"). In another embodiment the shape of these pores or trenches would help prevent the reading of data.
  • a trench (or set of pores) with angled walls over the directory area of a DVD could be filled with a material that changes its refractive index upon exposure to the environment, or physically shrinks allowing air, other gases or vacuum to fill in the gap, or expands.
  • the laser beam may be reflected at the boundary of the trench or its interior, thus being prevented from reliably reading the data on the disk.
  • small bubbles, crystals, particles or cracks could form in the coating or substrate, making the data unreadable.
  • a substance in gas, solid or other state
  • this approach may more successfully interfere with the readability of the disk.
  • user action triggers the process of destroying information.
  • One embodiment would place a cover on the data side of the disk, over the table of contents/directory area, or over the entire area, or over part thereof. The user would need to remove the cover to play the disk. Removal of the cover would trigger the process that renders the disk unreadable. For example, it could expose an oxidizing coating, or would release a substance that starts a chemical reaction affecting the substrate and/or the metal layer. The substance could be released by breaking microcapsules on the cover itself or on the disk.
  • the cover itself might provide the only barrier protecting the coating or the substance from the environment, or it could do so in combination with other means, such as airtight packaging in an inert environment.
  • the cover might be an adhesive label, special printing or other type of barrier.
  • a water-soluble opaque substance over the table of contents or the entire surface of the disk would prevent the disk from being played.
  • the user would need to wipe off with a wet cloth this substance, in order to make the disk playable.
  • the water and moisture would then trigger the process that renders the disk unplayable.
  • Other embodiments could require user actions such as heating or cooling the disk, squeezing or shaking, exposing to microwave radiation in a microwave oven, exposure to bright light, exposure to ultraviolet light dipping in water or other substances, wiping or otherwise exposing the disk to some chemical, or removing or changing some component of the disk.
  • the users actions would relatively quickly render the disk (temporarily) playable.
  • the disk could be made unplayable without changing its optical properties, by changing its mechanical/physical properties.
  • a DVD disk consisting of two substrates could be warped by uneven expansion or other physical changes in the two substrates, or by expansion or other physical changes in an adhesive layer, or by expansion or other physical changes in a specially placed layer that changes upon exposure to moisture or content.
  • the disk might be rendered unplayable through fractures, either because of thereby induced mechanical failure or because of interference of these fractures with the ability of the laser to read the encoded data.
  • the central hole could be enlarged, possibly as a result of materials that deteriorate either with exposure to the environment or because of the mechanical stresses of playing (for example, DVDs rotate at speeds up to 1600 rpm).
  • Playing a DVD on a standard player involves rotation at speeds up to 1600 rpm. Multi-speed DVD drives may utilize even higher speeds. This rotation could provide the triggering and/or sustaining mechanism for the process that renders the disk unplayable.
  • centrifugal forces similar to a mini- centrifuge.
  • these centrifugal forces could trigger the diffusion or mixing of substances that cause the disk to be unplayable.
  • microcapsules would break when exposed to sustained centrifugal forces, and trigger a reaction resulting in rendering the disk unplayable.
  • binary substances could react to produce an opaque substance interfering with reading of the optical data, or a reactive agent or a catalyst could be released that attacks the metal layer or the substrate.
  • One approach would be to put such substances in small radial, spiraling or circular trenches or tubules in the disk.
  • FIGS, la- lb illustrate schematic side views of an optical disk, representing an embodiment of the invention.
  • FIGS. 2a-2b illustrate schematic side views of another optical disk, representing another embodiment of the invention.
  • the context of the invention includes reading data from an optical media.
  • Optical disks represent a generic class of optical media.
  • the sub-generic class of DVD-ROM can contain any digital information.
  • DVD-Video is based on DVD-ROM standard and also on the standards represented by MPEG-2 and Dolby Digital.
  • the invention can utilize data processing methods that transform signals produced from the data encoded on the optical media so as to actuate interconnected discrete hardware elements; for example, to start, stop and/or actuate other functions of the media reader (device) that is accessing the data on the optical media.
  • the concept of the invention includes disposable optical media, such as, for example time-sensitive disposable digital video disk (DDVD).
  • DDVD disposable digital video disk
  • a DVD could be manufactured or packaged in such a way that it can only be used for a limited time period or a limited number of uses.
  • the DVD could react with oxygen in the air so that once it was removed from an air-tight package, the surface would obscure a fraction of the underlying data. For instance, some plastics may be come cloudy, or black.
  • the DVD could react with other constituents of air such as moisture or other gases so that once it was removed from an air-tight package, the surface would obscure a fraction of the underlying data. Again, some plastics may be come cloudy, or black.
  • the DVD could react to light, such as the laser light that is used to read data, so that it could not be read again after some number of readings.
  • This could be a photochemical process similar to photography or the clouding of a substance when exposed to light.
  • the DVD could react to ambient room light so that it could not be read again after some number of readings. Again, this could be a photochemical process similar to photography or the clouding of a substance when exposed to light.
  • An electrostatic or mechanical reaction could occur when the DVD is removed from the packaging which sets in motion a timed destruction of the data.
  • the effect could be powered by a small battery or simply the energy released when the DVD is removed from the package.
  • the process of removing the DVD from the packaging or playing it in a device could set off the timing in any other way.
  • removing the DVD from the packaging might break a seal exposing either the data side or the label side of a single- sided DVD to reactants contained within either the DVD or the packaging materials, thus triggering the process that renders the DVD unusable after a certain period of time or a certain number of uses.
  • the DVD player could actively read some encrypted identifying information from the DVD and refuse to play it again. This could be implemented either by actively modifying the DVD or by storing this information in the player or in a network.
  • the degradation can be relatively sudden (S-shaped), if possible, so that there would be minimal affect on the data for some initial period, and then a rapid loss of data.
  • S-shaped relatively sudden
  • the degradation can be relatively sudden (S-shaped), if possible, so that there would be minimal affect on the data for some initial period, and then a rapid loss of data.
  • by including in the DVD a finite, controlled quantity of antioxidant along with a substance that reacts to oxygen it could be possible to initially protect the data, and then when the anti-oxidant was used up, rapidly have the DVD degrade.
  • the invention can readily apply to related media such as compact discs (CDs), Laser disks, CD-ROMs, tapes, etcetera.
  • Applications of the invention include storage of limited-viewing movies, which could supplant the video rental market.
  • Other applications of the invention include "trial" disks with music, software or other digital information, mail order catalogs for music, videos, software, data, games, etcetera; hybrid disks with some permanent components (e.g., coming attractions), games with limited time for completion, etcetera.
  • the time during which the data would be useable could range from less than a few seconds to more than several weeks.
  • the time during which the data would be useable could be limited to a single playing, some finite number of uses, or even a random number of uses.
  • An extra layer on the disk is not required to achieve the desired results. In one embodiment, exposure to the ambient environment will damage the performance of the metal layer.
  • substrate is defined herein to be the one or more layers through which the laser light passes before impinging on the metal layer.
  • the substrate can be polycarbonate, but other materials known to those skilled in the art may be used.
  • lacquer is defined herein to be the layer or layers on the back of the disk. One or more of these layers may be composed of a material identical, or similar, to the one used for the substrate. The laser light is not intended to pass through the lacquer.
  • a one-sided disk such as a CD or a DVD-5
  • the lacquer will typically include a layer binding together the two sides of the disk.
  • the invention includes an optical disk on which the metallic layer containing the data is not completely protected from the ambient environment.
  • a portion of the surface may deliberately not be coated by the lacquer or substrate. This permits the unprotected portion of the metallic layer to be acted upon by the ambient environment.
  • the reflective metal may react with a component of air.
  • an aluminum layer may be oxidized by the oxygen in air to aluminum oxide. After a period of exposure to the ambient environment the quality of the signal reflected by the metallic layer will degrade, resulting in poor data quality or even the inability to read the data on the disk.
  • the rate of degradation can be defined by the metal. It is accelerated when the metal is magnesium or silver and is decelerated when the metal is aluminum. If the metal is in electrical contact with a second metal, the degradation is accelerated. For example, contacting of aluminum with silver, gold or copper accelerates the degradation. In general, contacting of magnesium or aluminum with a more noble metal accelerates the degradation of the magnesium or the aluminum layer.
  • the rate of degradation can be adjusted through the ratio of their exposed areas. When the two different metals are overlapping films, the rate of degradation is also determined by the overlap. It is not necessary that the entire surface be unprotected. For example, it is sufficient to leave unprotected only key portions of the optical disk that contain data necessary to read the remainder of the disk.
  • a substrate or lacquer may be chosen such that the flux of oxygen, nitrogen, water or hydrogen sulfide reaching the metallic surface is a function of the thickness of the layer.
  • the materials comprising the substrate or lacquer may be chosen such that layers of equal thickness have different permeabilities to oxygen, water or hydrogen sulfide. In such a way optical disks can be designed to fail at a desired time after exposing them to the destructive environment, e.g., one hour, six hours, 24 hours, 48 hours, 72 hours or one week.
  • compositions that performs a similar function is one in which the substrate itself is modified over time.
  • the modification of the substrate could cause it to change its optical qualities, thereby degrading the signal reaching the reader. These optical qualities could include its index of refraction or its transparency.
  • the modification of the substrate could cause the underlying metal layer to change its optical properties, as described above.
  • a time-sensitive substrate and/or lacquer could be combined with a reflective layer that becomes non-reflective.
  • the transparency of a polymer film can be changed by the following: reaction of the film with water; reaction of the film with oxygen; or crystallization of the polymer, meaning increased alignment of polymer molecules in the film.
  • a substrate could be chosen that is changed by components in air such as oxygen or water.
  • oxygen could oxidize the substrate, causing a change in its transparency or its index of refraction.
  • the substrate could be designed to absorb water in the air, causing it to swell and change its optical properties.
  • the substrate could change its permeability to oxygen over time, thereby permitting the oxidation of the metallic layer.
  • the overall time sensitivity of the optical media could be a function of the properties of both the substrate and/or lacquer and the reflective layer.
  • the substrate or the metallic layer could also be made sensitive to specific wavelengths of light. Exposure to these wavelengths would cause a change in the optical qualities of the layer, thereby degrading the signal reaching the reader.
  • Examples include photodepolymerization of the substrate; photogeneration of acid; photogeneration of singlet oxygen; and unzipping of the polymers (e.g., fissure of cross linking hydrogen bonds). Incorporation of light-activated catalysts into the substrate or the metallic layer can assist in this process.
  • the data quality of the disk remains high for the intended period of use and then decays rapidly.
  • One method of accomplishing this is to print a layer of metallic silver on the back of the disk, over the lacquer. Upon exposure to air the silver serves as a cathode, on which 02 is reduced; aluminum serves as an anode. Corrosion is fast only if a short develops between the silver and the aluminum layers. The development of the short results from the growth of a silver dendrite through the lacquer.
  • the lacquer is a polyacrylate. If the polyacrylate is slightly hydrolyzed, or if it is, for example, a 2-hydroxyethylacrylate copolymer, there will be some ionic conductivity.
  • Preferred are co-polymers of poly(acrylonitrile), or of poly(4- vinylpyridine), or of poly(l-vinylimidazole). All of these should conduct silver, copper or thallium ions (Ag + Cu + or Tl + ). Thallium is less preferred due to its toxicity. The chemical equations are as follows:
  • Ag + is reduced by aluminum, which is oxidized (if Ag + is mobile in the lacquer, which is designed to conduct Ag + )
  • a silver dendrite starts growing from the aluminum to the silver.
  • the "switch" between a battery's (Al) anode and (Ag) cathode is closed. Corrosion is rapid and catastrophic.
  • Al and Ag may be substituted for Al and Ag in this example.
  • the aluminum and silver coatings could be sputter deposited.
  • the lacquer could be spin coated.
  • compositions comprising a degradable optical disk as described in this section packaged in an enclosure and atmosphere that protects it from the environmental stimulus that causes its failure.
  • the optical disk described above could be packaged in a metallized foil package containing a gas such as carbon dioxide, nitrogen or argon.
  • the pressure of gas(es) in the package can be sub- atmospheric, preferably less than 1 torr. Inert gases such as argon are preferred. This would serve to protect the optical disk from oxygen, water, and/or light of certain wavelengths.
  • Another aspect of the invention is a method of manufacturing the degradable optical disk described above.
  • the method involves coating the substrate or lacquer described above onto the metallic layer so that it partially or completely covers the disk, so that the optical signal from the disk degrades when exposed to a preselected environmental stimulus.
  • Another aspect of the invention is a method of manufacturing the degradable optical disk with a process that changes the optical properties of the substrate and/or the reflective properties of the metal layer in a way that can be partially or fully reversed, resulting in a fully or partially reversible loss of the ability to read the data on the optical disk.
  • the disk can be exposed to a "reversing environment” that partially or fully reverses the impact of the previous step.
  • the disk is subsequently packaged in a "preserving environment" (which may be identical to or different from the reversing environment). Opening the package results in a loss of the "preserving environment” and/or exposure to ambient conditions of oxygen, moisture and/or light, which will result in renewed degradation or loss of the ability to read data from the disk within a certain time period. It is preferable that this last degradation of the disk be difficult or impractical to reverse.
  • certain salts could be mixed with the polycarbonate pellets used in injection molding of the substrate.
  • these salts may interact with oxygen, carbon dioxide and/or water to form opaque compounds that modify the optical properties of the substrate.
  • the optical disks could be chemically reduced in a hydrogen atmosphere, once again rendering the polycarbonate substrate transparent to the reading laser. Subsequently the disks could be packaged in a hydrogen environment. Opening the package would result in the loss of the reducing hydrogen and exposure to atmospheric oxygen, moisture and carbon dioxide, rendering the polycarbonate substrate opaque after a controlled time period.
  • Another aspect of the invention is a mechanical device which sets in motion a timed destruction of the data when the optical disk is removed from the packaging.
  • removing the disk from the packaging might break a seal exposing either the data side or the label side of a single-sided disk to reactants contained within either the disk itself or the packaging materials, thus triggering the process that renders the disk unusable after a certain period of time or a certain number of viewings.
  • a reducing gas could be stored in a compartment of the package apart from the disk.
  • the disk comprises a protective layer that prevents oxidation of the underlying substrate or metal.
  • the package is designed such that when the package is opened for the first time a seal is broken and the reducing gas contacts a surface of the disk, thereby causing the protective layer to be destroyed.
  • the substrate or metal layer that had been protected from oxidation by the protective layer would then be susceptible to oxidation by air, as described above.
  • a timed destruction of the data can be triggered by electric current or charge provided by a small battery, or simply the energy released when the disk is removed from the package.
  • a reversible chromophore could be used. The chromophore is reduced to a colorless state when the potential is applied. When the potential is removed, the chromophore is gradually regenerated by oxidation by oxygen in air. In the regenerated state the chromophore absorbs light.
  • a charge storing device such as a small battery built into the packaging material, could provide an electric field that inhibits the reaction that destroys the disk's ability to read data.
  • the process of removing the optical disk from its packaging would then interrupt the inhibiting field, thus triggering the process that destroys the disk's ability to read data.
  • the battery applies a potential to the metal layer which maintains the metal layer in a reduced state.
  • the metal layer begins to oxidize when contacted with an oxidizer such as oxygen in the air.
  • Another aspect of the invention is a method of manufacturing the degradable optical disk and packaging it in an enclosure and/or atmosphere that protects it from the environmental stimulus that causes its failure.
  • the invention further comprises controlling the exposure of the finished optical disk to the environmental stimulus that causes its failure during the manufacturing and/or the packaging operations. For example, optical disks manufactured today may sit unpackaged for a substantial amount of time before being packaged.
  • the optical disk should be packaged in the protective enclosure and/or atmosphere within 24 hours of its production, preferably within 8 hours of its production, more preferably within one hour of its production and most preferably within 30 minutes of its production. Stated a different way, the optical disk should be packaged in its protective enclosure and/or atmosphere in a time period of less than 20% and preferably less than 10% of its expected degradation time. It is also possible to manufacture and/or store the unpackaged optical disk in an environment that does not cause its degradation. Such an environment might be, for example, a nitrogen atmosphere, substantially zero air, or controlled lighting.
  • Another aspect of the invention is a method of use of the optical disk described above, comprising packaging the disk in an enclosure and/or atmosphere that protects it from the environmental stimulus that causes its failure, then opening the package and exposing it to the environmental stimulus that causes its failure.
  • the level of degradation be minimal for some initial period, and then speed up resulting in a rapid degradation of the ability to read data off the optical disk.
  • One method of accomplishing this is the growth of dendrites through the lacquer, as described above.
  • Another means for accomplishing this is to include a finite, controlled quantity of antioxidant along with a substance that reacts with oxygen.
  • the anti-oxidant would protect the data from oxidation reactions until such time as the anti-oxidant was consumed, at which time the disk would rapidly degrade.
  • an organometallic compound that reacts with oxygen can be packaged with the disk to protect the disk from oxidation while in the package.
  • the organometallic compound can be incorporated into the substrate, thus continuing to protect the metal layer for a period of time after the package has been opened.
  • Coupled is defined as connected, although not necessarily directly, and not necessarily mechanically.
  • substantially is defined as approximately (e.g., preferably within 10% of, more preferably within 1% of, most preferably within 0.1% of).
  • the particular material used for the substrates can be any substantially transparent material.
  • Polymeric materials are preferred, such as, for example, polycarbonate, acrylic (polymethylmethacralate PMMA) or polyolefine.
  • polycarbonate acrylic (polymethylmethacralate PMMA) or polyolefine.
  • the particular material selected for the substrate is not essential to the invention, as long as it provides the described function. Normally, those who make or use the invention will select the best commercially available material based upon the economics of cost and availability, the expected application requirements of the final product, and the demands of the overall manufacturing process.
  • preferred embodiments of the invention can be identified one at a time by testing for an accurate and precise time-sensitive decay of optical properties. More specifically, both the onset and duration of decay should be predictable. A sudden deterioration (brief duration of decay) is preferred, for example, approximately one hour.
  • preferred embodiments of the invention can be identified one by one by testing for the presence of a narrow standard distribution of the time from activating event (e.g., exposure to air) to 50% optical deterioration (e.g., 50% loss of transmissivity or 50% loss of reflectivity). Many other optical (e.g., material property) tests are possible. Examples of a narrow standard distribution of the time from activating event (e.g., exposure to air) to 50% optical deterioration (e.g., 50% loss of transmissivity or 50% loss of reflectivity). Many other optical (e.g., material property) tests are possible. Examples
  • Example 1 Referring to FIGS, la- lb, edge views of an optical disk 100 with a pseudo- transmissive read inhibitor are shown.
  • the optical disk 100 includes a substrate 1 10, a reflective layer 120 and a lacquer layer 130.
  • FIG. la shows the optical disk 100 in a first state wherein the substrate 110 is substantially optically transmissive.
  • FIG. lb shows the optical disk 100 in a second state wherein the substrate is substantially optically non- transmissive.
  • the transformation from the first state to the second state is at-least-in-part a function of time from an initializing event, in this particular example, the opening of a substantially gas impermeable membrane (not shown) that encloses the optical disk 100 while it is packed, shipped and sold.
  • Example 2 Example 2
  • FIGS. 2a-2b edge views of an optical disk 200 with a pseudo- reflective read inhibitor are shown.
  • the optical disk 200 includes a substrate 210, a data encoded component 220 and a lacquer layer 230.
  • the data encoded component 220 is a thin film of metal.
  • FIG. la shows the optical disk 200 in a first state wherein the data encoded component 220 is substantially optically reflective.
  • FIG. lb shows the optical disk 200 in a second state wherein the data encoded component 220 is substantially optically non-reflective.
  • the transformation from the first state to the second state is at-least-in-part a function of time from an initializing event, in this second example, the opening of a substantially air tight laminated polymeric container (not shown) that encloses the optical disk 200 while it is packed, shipped and sold.
  • An optical media with time-sensitive properties representing an embodiment of the invention, can be cost effective and advantageous for at least the following reasons.
  • the invention allows a low cost retail product.
  • the invention yields a product having the potential of a limited content lifetime.
  • the invention permits the avoidance of rental returns.
  • the individual components need not be formed in the disclosed shapes, or assembled in the disclosed configuration, but could be provided in virtually any shape, and assembled in virtually any configuration. Further, the individual components need not be fabricated from the disclosed materials, but could be fabricated from virtually any suitable materials. Further, although the optical media described herein can be a physically separate module, it will be manifest that the optical media may be integrated into the apparatus with which it is associated. Furthermore, all the disclosed elements and features of each disclosed embodiment can be combined with, or substituted for, the disclosed elements and features of every other disclosed embodiment except where such elements or features are mutually exclusive.

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Abstract

La présente invention concerne des systèmes et des procédés permettant d'inhiber la lisibilité d'un support optique au moyen de modifications affectant la matière pseudo-réfléchissante qui compose le support optique après que ce dernier a été exposé à l'air pendant une durée prédéterminée. L'invention se rapporte à un support optique comprenant un composant à données codées. Au moins une partie du composant à données codées se transforme, passant d'un état de réflexion optique sensible à un état de non réflexion optique sensible comme une fonction, au moins partielle, du temps s'écoulant à partir d'un événement d'initialisation. Les systèmes et procédés de l'invention offrent des avantages tels qu'un faible coût, une durée de vie du contenu limitée, la suppression de la nécessité de rendre les supports loués et des modifications minimales à apporter aux processus de fabrication existants.
PCT/US2000/018944 1999-07-12 2000-07-12 Supports optiques jetables et procede de fabrication WO2001004887A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP00945338A EP1212752A1 (fr) 1999-07-12 2000-07-12 Supports optiques jetables et procede de fabrication
IL14754300A IL147543A0 (en) 1999-07-12 2000-07-12 Disposable optical storage media and manufacturing method
CA002379104A CA2379104A1 (fr) 1999-07-12 2000-07-12 Supports optiques jetables et procede de fabrication
BR0012382-0A BR0012382A (pt) 1999-07-12 2000-07-12 Meio de armazenamento óptico descartável e método de fabricação
JP2001509031A JP4243059B2 (ja) 1999-07-12 2000-07-12 使捨て式光学記憶媒体とその製造方法
AU59301/00A AU777945B2 (en) 1999-07-12 2000-07-12 Disposable optical storage media and manufacturing method
IL147543A IL147543A (en) 1999-07-12 2002-01-09 Disposable optical storage device and method of manufacture
HK02109047.2A HK1049227A1 (zh) 1999-07-12 2002-12-12 一次性光學存貯介質及其生產方法

Applications Claiming Priority (3)

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US14347499P 1999-07-12 1999-07-12
US60/143,474 1999-07-12
US09/628,328 2000-06-29

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CN (1) CN1308943C (fr)
BR (1) BR0012382A (fr)
CA (1) CA2379104A1 (fr)
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WO (1) WO2001004887A1 (fr)

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FR2856498A1 (fr) * 2003-06-19 2004-12-24 Goulven Jean Alain Vernois Distribution sous atmosphere controlee
WO2005007527A1 (fr) * 2003-07-03 2005-01-27 General Electric Company Procede de protection d'un article optique sensible a la lumiere
WO2006002530A1 (fr) * 2004-06-30 2006-01-12 Robert Prust Dispositif de mise en memoire d'informations pouvant deteriorer l'integrite optique d'un support de donnees optique de celui-ci

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WO1998041979A1 (fr) * 1997-03-14 1998-09-24 Hide And Seek Technologies, Inc. Dispositif support optique pouvant etre protege contre la copie, et methodologie associee
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WO1999041738A1 (fr) * 1998-02-11 1999-08-19 Mazer Terrence B Support de donnees pour lecture optique a usage limite
WO1999067085A1 (fr) * 1998-06-25 1999-12-29 Spectradisc Corporation Procedes et dispositifs servant a rendre illisible un support code optiquement

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US5815484A (en) * 1995-12-28 1998-09-29 Hide And Seek Technologies L.L.C. Copy protectable optical media device and methodology therefor
WO1998011539A1 (fr) * 1996-09-16 1998-03-19 Quixote Corporation Disque optique exploitable par machine a agent empechant la lecture
WO1998041979A1 (fr) * 1997-03-14 1998-09-24 Hide And Seek Technologies, Inc. Dispositif support optique pouvant etre protege contre la copie, et methodologie associee
WO1999041738A1 (fr) * 1998-02-11 1999-08-19 Mazer Terrence B Support de donnees pour lecture optique a usage limite
WO1999067085A1 (fr) * 1998-06-25 1999-12-29 Spectradisc Corporation Procedes et dispositifs servant a rendre illisible un support code optiquement

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Publication number Priority date Publication date Assignee Title
JP2004528667A (ja) * 2001-03-14 2004-09-16 ゼネラル・エレクトリック・カンパニイ 限定再生型情報記憶媒体及びその上のデータへのアクセスを限定する方法
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FR2856498A1 (fr) * 2003-06-19 2004-12-24 Goulven Jean Alain Vernois Distribution sous atmosphere controlee
WO2005004115A2 (fr) * 2003-06-19 2005-01-13 Goulven Vernois Distributeur sous atmosphere controlee
WO2005004115A3 (fr) * 2003-06-19 2005-04-07 Goulven Vernois Distributeur sous atmosphere controlee
WO2005007527A1 (fr) * 2003-07-03 2005-01-27 General Electric Company Procede de protection d'un article optique sensible a la lumiere
WO2006002530A1 (fr) * 2004-06-30 2006-01-12 Robert Prust Dispositif de mise en memoire d'informations pouvant deteriorer l'integrite optique d'un support de donnees optique de celui-ci

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CN1408114A (zh) 2003-04-02
IL147543A0 (en) 2002-08-14
BR0012382A (pt) 2002-07-16
CA2379104A1 (fr) 2001-01-18
EP1212752A1 (fr) 2002-06-12

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