Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/50—Perfumes
  • C11D3/502—Protected perfumes
  • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/001—Softening compositions
  • C11D3/0015—Softening compositions liquid
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers

Definitions

• This invention relates to the perfuming of rinse conditioner compositions.
• Rinse conditioners are products which are designed to be added to water used for the rinsing of laundry after washing with a detergent composition. Such conditioners contain a material whose function is to confer a benefit to the laundry after the laundry has been rinsed and dried.
• One of the main benefits delivered by such products is softness .
• US-A-4446032 discloses rinse conditioner compositions which contain perfume trapped within carrier particles which may be porous or alternatively may be closed capsules with an impervious layer surrounding the perfume. This document teaches that a suspending agent should be included in the composition .
• JP-A-63/122796 discloses the addition of a polymer latex which contains cationic or tertiary amino groups to a detergent composition, for the purpose of enhancing perfume deposition.
• 098/28396 discloses perfume absorbed within organic polymer particles and which have a further polymer at their exterior.
• the polymer particles disclosed desirably have an average particle size of at least 10 ⁇ m.
• WO 98/28339 discloses polymer particles comprising a hydrophobic organic matrix and located at the exterior free cationic groups and a further polymer which comprises free hydroxy groups.
• the polymer particles disclosed desirably have an average particle size of at least 10 ⁇ m.
• EP 397 246 discloses perfume particles comprising perfume dispersed within certain water-insoluble polymeric materials and encapsulated in a protective shell by coating with a friable coating material.
• EP 617 051 discloses that the controlled release of a fragrance can be provided by incorporating it during emulsion polymerisation of water insoluble monomeric material in which it is dissolved, and by controlling the monomer blend composition and the Tg of the resultant polymer.
• the present invention provides a composition for use in the rinsing of laundry, containing particles with perfume located or absorbed in or on the particles, wherein the particles are formed of cross-linked organic polymeric material and have a mean particle size not greater than 1 micron .
• the polymeric material is a latex.
• cross-linked latices give superior delivery of perfume to fabrics and better physical stability to the product
• this invention is concerned with rinse conditioner compositions which incorporate a material effective to soften fabrics.
• a rinse conditioner composition containing a material effective to soften fabrics, and particles with perfume located or absorbed in or on the particles, characterised in that the particles are formed of cross- linked organic polymeric material, and have a mean particle size not greater than 1 micron.
• this invention provides the use of particles of cross-linked organic polymeric material with a mean particle size of not greater than 1 micron and with perfume absorbed therein, in a rinse conditioner.
• a method of treating laundry comprising contacting said laundry with a composition as herein described is also provided.
• this invention provides a method of making a rinse conditioner which comprises mixing (i) a fabric softening material and (ii) particles of cross-linked organic polymeric material with a mean particle size not greater than 1 micron and with perfume located or absorbed therein or thereon.
• the invention can provide a way to incorporate perfume into a rinse conditioner composition while avoiding or mitigating adverse effects on viscosity.
• perfume can produce adverse changes to the viscosity of rinse conditioner compositions, especially when these contain a substantial percentage of fabric softener.
• the addition of perfume to a concentrated rinse conditioner composition can cause it to gel and become immobile.
• the fabric softening material may be cationic fabric softening material in an amount which is at least half of the total quantity of fabric softening material present and in addition is at least 8% by weight of the composition, especially at least 12% by weight of the composition.
• this invention is particularly concerned with cross-linked polymer lactices whose particles have the perfume trapped therein.
• cross-linked latices give superior delivery of perfume to fabrics and better physical stability to the product.
• this invention provides a product for use in the rinsing of laundry, containing perfume trapped within particles of an organic cross-linked polymeric latex, whose particles have a mean particle size not greater than 1 micron.
• compositions in which this invention may be applied and materials used, will now be discussed in more detail.
• a variety of materials are effective to soften fabrics and can be delivered to fabric from an aqueous composition.
• a fabric-softening agent functions to give fabric a softer handle. Frequently such agents also provide an anti-static benefit .
• Fabric softening agents used in rinse conditioner compositions are usually materials with low solubility in water. Typically the solubility in acidified water at pH 2.5 and 20°C is less than lOg/litre, preferably less than lg/litre. When added to rinse water such materials form a dispersed phase which is then able to deposit on fabrics which are being rinsed in the water.
• Amphoteric, zwitterionic and cationic fabric softening materials include a polar group and usually one or more hydrophobic aliphatic chains such as alkyl or alkenyl groups each of which contains at least 6 carbon atoms, e.g. a range from 6 to 50 carbon atoms in a continuous hydrocarbon chain or a hydrocarbon chain interrupted by a hereoatom. In many such materials there are either a single aliphatic chain containing 12 to 50 carbon atoms, or a plurality of aliphatic chains each containing 6 to 30 carbon atoms. Such aliphatic chains many be interrupted by a heteroatom as for instance in an
• hydrophobic aliphatic chain does not incorporate more than one interrupting heteroatom.
• a nonionic fabric softening material will generally include a polar group and an aliphatic hydrocarbon chain of 6 to 30 carbon atoms, optionally interrupted by a heteroatom as mentioned above, although hydrocarbon chains of 6 to 18, carbon atoms especially 6 to 11 carbon atoms are preferably without any interruption.
• Cationic fabric softeners are of special commercial importance and are a preferred type of softener according to the invention.
• Preferred forms of this invention include cationic fabric softener, optionally with nonionic, amphoteric or zwitterionic fabric softener present in addition.
• the amount of cationic fabric softening agent may be equal to, or greater than, the amount of any softening agent or surfactant which is not cationic.
• fabric softening agents are organic compounds containing nitrogen, and at least one hydrocarbon chain of 6 to 50 carbon atoms.
• the nitrogen atom may well be quaternary, but need not be, as for example in amines and imidazolines which protonate to a quaternary form in acidic solution.
• fabric softening agents Some specific instances of fabric softening agents are:
• each Qi is a hydrocarbyl group containing from 15 to 22 carbon atoms.
• Q 2 is a saturated alkyl or hydroxy alkyl group containing from 1 to 4 carbon atoms.
• Q 3 may be as defined for Qi or Q 2 or may be phenyl,
• Q 4 may be defined as for Qi or Q 2 , and
• X ⁇ is an anion preferably selected from halide, acetate, methyl sulphate and ethyl sulphate radicals .
• hydrocarbyl group refers to alkyl or alkenyl groups optionally substituted or interrupted by functional groups such as -OH, -0-, CONH, -COO-, etc.
• quaternary softeners include tallow trimethyl ammonium methyl sulphate or chloride; ditallow dimethyl ammonium chloride; ditallow dimethyl ammonium methyl sulphate; dihexadecyl dimethyl ammonium chloride; di (hydrogenated tallow) dimethyl ammonium methyl sulphate or chloride; di (coconut) dimethyl ammonium chloride dihexadecyl diethyl ammonium chloride; dibehenyl dimethyl ammonium chloride.
• ditallow dimethyl ammonium chloride di (hydrogenated tallow) dimethyl ammonium chloride, di (coconut) dimethyl ammonium chloride and di (coconut) dimethyl ammonium methosulphate .
• Examples of commercially available materials in this class are ARQUAD 2C, ARQUAD 2HT, ARQUAD 2T (all ex Akzo) , PRAPAGEN WK, PRAPAGEN WKT, DODIGEN 1829 (all ex Clariant), QUERTON 4BG, QUERTON 442 (all ex Akzo), AMMONYX KP, AMMONYX SKD (all ex Millchem) , SYNPROLAM FS ( ex Unichema) .
• the product names are believed to be trademarks. Alkoxylated Polyamines
• Alkoxylated polyamines of general formula (II) are known
• Each Q 4 is a hydrocarbyl group containing from 10 to 30 carbon atoms.
• the Qs groups may be the same or different each representing hydrogen, (-C 2 H 4 0)pH, (C 3 H 6 0) q H, (C 2 H 4 0) p ,
• X- is an anion.
• Alkoxylated polyamines suitable for use herein include N- tallowyl, NN'N'-tris (2 hydroxethyl) -1, 3- propane diamine di-hydro chloride; N-cocyl N,N,N',N' pentamethyl-1, 3 propane diammonium dichloride or dimethosulphate; N-stearyl N,N',N' tris (2-hydroxyethyl) N, Nl' dimethyl-1, 3 propanediammonium dimethyl sulphate; N-palmityl N,N',N'tris (3-hydroxyprolyl) -1, 3-propanediammonium dihydrobromide; N- tallowyl N-(3 aminopropyl) -1, 3-propanediamine trihydrochloride .
• Diamido Quaternary Ammonium Salts Diamido quaternary salts of general formula (III) are also known to be useful as fabric softening agents. 0 Q 2 0
• Q ⁇ is a divalent alkylene group containing from 1 to 3 carbon atoms.
• Qi, Q 2 , Qs and X ⁇ are as defined previously.
• suitable materials are methylbis (tallowamidoethyl) (2-hydroxyethyl) ammonium methyl sulphate and methyl bis (hydrogenated tallowamido ethyl) (2- hydroxyethyl) ammonium methyl sulphate. These materials are available from Goldsch idt under trade names VARISOFT 222 and VARISOFT 110 respectively and under the trade name ACCOSOFT from Stepan.
• ester group containing quaternary ammonium salts including those disclosed in EP 345842 A2 (Procter & Gamble), EP 239910 (Procter & Gamble) and US 4137180
• Q 7 is a hydrocarbyl group containing 1 to 4 carbon atoms
• Qe is (CH 2 ) n -Z-Q ⁇ 0 where n is an integer from 1 to 4 or -Qio.
• Q 9 is an alkyl or hydroxyalkyl group of 1 to 4 carbon atoms, or is as defined for Q 8 .
• Q 10 is a hydrocarbyl group containing from 12 to 22 carbon atoms and Y can be -CH(OH)-CH 2 - or Q 5 , as previously defined.
• Z can be -0-C(0)-0, C (0) -0 or -O-C(O)- and X " is an anion.
• suitable materials based on formula IV are methyl bis- [ethyl (tallowyl) ] -2-hydroxyethyl ammonium methyl sulphate (or its olelyl equivalent), N,N-di (tallowyl- oxyethyl) -N, N-dimethyl ammonium chloride; N,N-di(2- tallowyloxy-2-oxo-ethyl) -N, -dimethyl ammonium chloride; N, N-di (2-tallowyloxyethylcarbonyl oxyethyl) -N, N-dimethyl ammonium chloride; N- (2-tallowloxy-2-ethyl) -N- (2-tallowyl oxo-2-oxyethyl) -N, N-dimethyl ammonium chloride; N,N,N- tri (tallowyl-oxyethyl) -N-methyl ammonium chloride; N-(
• Tallowyl may be replaced with cocoyl, palmoyl, lauryl, oleyl, stearyl and palmityl groups.
• An illustrative example of a formula V material is 1, 2- (hardened) ditallowyloxy-3-trimethyl ammonium propane chloride.
• Examples of commercially available materials can be obtained under the trade name STEPANTEX VRH 90 (ex Stepan) , AKYPOQUAT (ex Kao) and as mixtures of mono and ditallow esters of 2, 3-dihydroxy propane trimethyl ammonium chloride (ex Clarient ) .
• a further class of cationic softener materials is the imidazolinium salts of generic formula (VI) .
• Q is a hydrocarbyl gro s up containing from 6 to 24 carbon atoms
• G is -N(H)-, or -0-, or NQ 2
• n is an integer between 1 and 4
• Q 7 is as defined above.
• Preferred imidazolinium salts include 1-methyl-l- (tallowylamido) ethyl-2tallowyl-4 , 5 dihydro imidazolinium methosulphate and 1-methyl-l- (palmitoylamido) ethyl-2- octadecyl-4 , 5-dihydroimidazolinium chloride.
• Other useful imidazolinium materials are 2-heptadecyl-l-methyl-l- (2 stearylamido) ethyl imidazolinium chloride and 2- lauryl-1- hydroxyethyl-1-olayl imidazolinium chloride.
• the imidazolinium fabric softening components of US 4127489 incorporated here by reference Representative commercially available materials are VARISOFT 475 (ex Goldschmidt) and REWOQUAT W7500 (ex Rewo)
• a particular aspect of the invention relates to compositions wherein the amount of fabric softening material which is cationic is a majority of the fabric softening material present.
• Q is a hydrocarbyl group containing form 6 to 24 carbon atoms
• Q i2 is hydrogen or a hydrocarbyl group containing from 1 to 22 carbon atoms
• Q ⁇ 3 can be hydrogen or Q .
• amines are protonated with hydrochloric acid, orthophosphoric acid or citric acid or any other similar acids for use in fabric conditioning compositions of this invention.
• Alkoxylated amines of general formula (VIII) are also useful as components of this invention.
• Qi - N H CH 2 ) 2 -N
• Q 14 is (C 2 H 4 0) x H
• Qis is (C 2 H 4 0) y H
• Q i6 is (C 2 H 4 0) Z H and x+y is within the range 2 to 15 and x+y+z is within the range 3 to 15, m can be 0, 1 or 2 and Qi is as previously defined.
• Examples of these materials are monotallowdipolyethoxyamine containing from 2 to 30 ethylene oxide units, tallow N, N' , N' tris (2-hydroxythyl) -1, 3 propylene diamine or C ⁇ 0 to C ⁇ 8 alkyl-N-bis (2-hydroxyethyl) amines .
• Examples of commercially available materials are available under the trade names ETHOMEEN and ETHODUOMEEN (ex Akzo) .
• the groups Q i7 are independently selected from hydrocarbyl groups containing from 3 to 30 carbon atoms and A can be oxygen (-0-) or nitrogen (-N-), preferably nitrogen; B is selected from Q 5 as defined earlier or the group -Q i3 -T-C(0) - where Q ⁇ 8 is either Q5 or (-C 2 H0-) m with m being an integer from 1 to 8 and T being selected from oxygen or NQ i3 .
• the broken line shows a possible double bond between A and C. If absent, it is replaced by bond(s) to additional hydrogen (s).
• Illustrative materials are 12-stearyl oxyethyl-2-stearyl imidazoline, 1-stearyl oxyethyl-2-palmityl imidazoline, 1- stearyl oxyethyl myristyl imidazoline, 1-palmityl oxyethyl- 2-palmityl imidazoline, 1-palmityl oxyethyl-2-myristyl imidazoline, 1-stearyl oxyethyl-2-tallow imidazoline, 1- myristyl oxyethyl-2-tallow imidazoline, 1-palmityl oxyethyl-2-tallow imidazoline, 1-coconut oxyethyl-2-coconut imidazoline, 1-tallow oxyethyl-2-tallow imidazoline and mixtures thereof.
• stearyl hydroxyethyl imidazoline available commercially as MONAZOLINE S (ex Unichema) , 1-tallow amido ethyl-2-tallow imidazoline and Methyl-1-tallow amidoethyl-2-tallow imidazoline.
• Suitable fabric softening materials are the condensation products formed from the reaction of fatty acids with a polyamine selected from the group consisting of hydroxyalkyl, alkylene diamines and dialkylenetriamines and mixtures thereof.
• Suitable materials are disclosed in EP-A-199382 (Procter) . Preferred among these are mixtures of molecules of the generic formula X and corresponding salts obtained by partial protonation.
• W is selected from hydrogen and the group -C(0)-Q ⁇ and other symbols are as previously defined.
• Commercially available materials of this class can be obtained from Clariant as Ceranine HC39, HCA and HCPA.
• Ql9 wherein the groups Q ⁇ 9 are selected independently from Q 7 , Qn and Q i4 ;
• Q 20 is a divalent alkylene group containing 1 to 3 carbon atoms and may be interrupted by -0-, -CONH, - C(0)0-, etc; and
• Z- is an anionic water solubilising group (e.g. carboxy, sulphate, sulpho or phosphonium) .
• Examples of commercially available materials are the EMPIGEN CD and BS series (ex Albright & Wilson) , the REWOTERIC AM series (ex Goldschmidt) and the Tegobetaine F, H, L and N series (ex GOLDSCHMIDT) .
• the hardened equivalent may also be used, for example tallow or hardened tallow.
• nonionic material with cationic, amphoteric or zwitterionic softening materials as a means of improving dispersion of the product in rinse waters and enhancing the fabric softening properties of the softener blend.
• Suitable nonionic adjuncts include lanolin and lanolin derivatives, fatty acids containing from 10 to 18 carbon atoms, esters of fatty acids containing from 8 to 24 carbon atoms with monohydric alcohols containing from 1 to 3 carbon atoms, and polyhydric alcohols containing 2 to 14 carbon atoms eg 2 to 12 carbon atoms such as sucrose, sorbitan, together with alkoxylated fatty acids, alcohols and lanolins containing an average of not more than 7 alkylene oxide groups per molecule.
• EP-A-88520 Unilever
• EP-A-122141 Unilever
• GB 2157728A Unilever
• GB 8410321 Unilever
• EP-A-159918 Unilever
• EP-A-159922 Unilever
• EP-A- 79746 Procter
• the composition may additionally or alternatively comprise, as a fabric softening agent, an oily sugar derivative which is a liquid or soft solid derivative of a cyclic polyol or of a reduced saccharide, said derivative resulting from 35 to 100% of the hydroxyl groups in said polyol or in said saccharide being esterified or etherified.
• the derivative has two or more ester or ether groups independently attached to a C 8 -C 22 alkyl or alkenyl chain.
• the oily sugar derivative contains 35% by weight tri or higher esters, eg at least 40%.
• W098/16538 (Unilever) discloses such derivatives and is incorporated herein by reference.
• 35 to 85% most preferably 45 to 70% of the hydroxyl groups in said cyclic polyol or reduced saccharide are esterified or etherified to produce the derivative.
• the tetra etc prefixes used refer to the average degrees of esterification or etherification; the compounds exist as a mixture comprising the monoester to fully esterified ester.
• the derivatives do not have substantial crystalline character at 20°C.
• the starting material is esterified or etherified with said alkyl or alkenyl chains to an extent so as to produce the derivatives as a liquid or soft solid.
• the derivative has 3 or more, preferably 4 or more, eg 3 to 5, ester or ether groups or mixtures thereof.
• the derivative may be obtained from a saccharide, e.g. monosaccharides including xylose, arabinose, galactose, fructose, sorbose and especially glucose, or, disaccharides including maltose, lactose, cellobiose and especially sucrose.
• a reduced saccharide is sorbitan. If based on a disaccharide it is preferred if the disaccharide has 3 or more ester or ether groups attached to it e.g. include sucrose tri, tetra and penta esters.
• suitable derivatives include esters of alkyl (poly) glucosides, in particular alkyl glucoside esters having a degree of polymerisation from 1 to 2.
• the derivative may have branched or linear alkyl or alkenyl chains (of varying degrees of branching) , mixed chain lengths and/or unsaturation. Those having unsaturated and/or mixed alkyl chain lengths are preferred. For example, predominantly unsaturated fatty chains may be attached to the ester/ether groups, e.g. those derived from rape oil, cotton seed oil, soybean oil, oleic, tallow, palmitoleic, linoleic, erucic or other sources of unsaturated vegetable fatty acids.
• suitable oily sugar derivatives include sucrose tetratallowate, sucrose tetrarapeate, sucrose tetraoleate, sucrose tetraesters of soybean oil or cotton seed oil, cellobiose tetraoleate, sucrose trioleate, sucrose triapeate, sucrose pentaoleate, sucrose pentarapeate, sucrose hexaoleate, sucrose hexarapeate, sucrose triesters, pentaesters and hexaesters of soybean oil or cotton seed oil, glucose trioleate, glucose tetraoleate, xylose trioleate, sucrose tetralinoleate or sucrose tetra-, tri-, penta- or hexa- esters with any mixture of predominantly unsaturated fatty acid chains.
• sucrose pentalaurate sucrose pentaerucate
• sucrose tetraerucate Suitable materials include some of the Ryoto series available from Mitsubishi Kagaku Foods Corporation.
• the liquid or soft solid derivatives are characterised as materials having a solid: liquid ratio of between 50:50 and 0:100 at 20 °C as determined by T 2 relaxation time NMR, preferably between 43:57 and 0:100, most preferably between 40:60 and 0:100, such as, 20:80 and 0:100.
• the T 2 NMR relaxation time is commonly used for characterising solid: liquid ratios in soft solid products such as fats and margarines.
• any component of the NMR signal with a T 2 of less than 100 microsecond is considered to be a solid component and any component with T 2 greater than 100 microseconds is considered to be a liquid component.
• oily sugar derivatives can be prepared by a variety of methods well known to those skilled in the art. Typical preparations of these materials are disclosed in US 4 386 213 and AU 14416/88 (Procter and Gamble) .
• Fabric softening compositions generally do not contain anionic detergent active nor bleach, nor detergency builder. It is desirable that the amounts (of any) of anionic detergent active, bleach and detergency builder are all less than the amount of the fabric softening agent. The amount of each one of these may well be less than 5% by weight of the whole composition.
• a rinse conditioner composition according to this invention will usually contain from 0.5% to 90% by weight of the fabric softening material, for example 0.5-40%. More specifically, so called dilute compositions generally contain from 1% to about 8% by weight of fabric softening agent while compositions containing from about 8% up to 20% by weight of the fabric softening material have been classed as "concentrated”. Higher concentrations, in the range of at least 8%, at least 12% or up to 40% by weight are also possible, but even this is not the upper limit. Still higher concentrations from 40% up to 80% or even 90% by weight are possible in a very concentrated product. As mentioned above, either nonionic or cationic fabric softening agents may be used.
• perfume denotes materials which are used in perfumery and mixtures of such materials. Frequently the perfume will be a mixture of perfumery materials. Examples of commentaryable perfumes are to be found in "Perfume and flavour Chemicals" by Steffen Erctander (Library of Congress Catalogue Card no. 75-91398).
• the perfume may function solely to impart fragrance. However, perfumes can perform other functions, such as to reduce the onset of body malodour as disclosed in US-A-
• deodorant perfumes are within the scope of this invention and may or may not impart fragrance.
• Deodorant perfumes with low perceptible odour are disclosed in EP-A-404470.
• cross-linked organic polymer particles Preferably have the perfume trapped therein.
• the particles are composed of cross-linked organic polymeric material.
• Such particles may be made from a variety of organic monomers, although in general these are olefinically unsaturated materials. Preparation may be by an emulsion polymerisation process, as will be explained further below.
• the particles have a mean diameter which is not more than lum. Particles of such small size can remain in colloidal suspension. As is known, particles of colloidal dimensions are kept in suspension by Brownian motion and by the effect of charges on the particles surfaces, which cause the particles to repel each other and stay apart. Also, because the particles size is small in relation to the wavelength of light, they are generally not visible although they give an appearance of turbidity. Hence, a rinse conditioner composition containing them can appear translucent.
• Method A is to synthesise a polymer latex by emulsion polymerisation in the presence of the perfume.
• the monomers used may include some polyfunctional monomer so as to produce cross-linking in the polymer. This enhances the strength and rigidity of the polymer.
• a low level of cross- linking provides the ability of particles to hold perfume.
• the polymer particle size range is preferably between 50 and 200 nanometres.
• emulsion polymerisation Techniques for the production of a latex of small particles by emulsion polymerisation are well known.
• the polymerisation is normally carried out in the presence of a surfactant which functions as an emulsifier. Raising the concentration of surfactant leads to smaller particle sizes, but does not generally lead to particle sizes smaller than 50 nanometres unless a special method, e.g. a microemulsion process, is used.
• Particle size is also affected by temperature and hence rate of reaction, stirring speed and monomer/initiator ratio. Fast rates of polymerisation and higher stirring speeds lead to small particles. High proportions of monomer and low proportions of initiator favour the production of bigger particles.
• Method B which is particularly preferred, is to commence with a pre-formed cross-linked polymer latex as a dispersion in liquid, e.g. water.
• the perfume is dissolved in a low boiling organic solvent which is able to swell the polymer particles.
• the solution is brought into contact with the polymer latex, causing the polymer particles to swell and absorb the perfume.
• the solvent is then evaporated, leaving the perfume trapped in latex particles.
• residual monomer can be removed from the polymer before the polymer comes into contact with the perfume.
• a latex of colloidal polymer particles will generally contain from 3% to 50% polymer, usually from 3% to 40%.
• Various polymerisation methods may be used for making polymers. Natural or modified natural polymers might also be used, e.g. a natural rubber latex.
• Suitable monomers for radical addition polymerisation are those containing polymerisable olefinic unsaturation.
• Monomers which may be used include styrene, vinyl acetate, ethylene, propylene, vinyl pyrrolidone, vinyl chloride, acylonitrile, methyl methacrylate, and other acrylates and methacrylates.
• the monomers may be used either singly or in combination.
• Examples of polyfunctional monomers which may be used to effect cross-linking include divinyl benzene, divinyl ether, ethyleneglycol dimethacrylate, penta- erythritol triacrylate and polyallyl sucrose.
• Suitable radical initiators include sodium or potassium persulphate, 2, 2' -azobis-isobutyronitrile (AIBN) and 4,4'-azobis (4- cyanovaleric acid) .
• a water soluble initiator is preferable.
• Polymerisation temperature is preferentially in the range 40-90°C.
• Method B it is possible to use natural and modified natural polymers, e.g. cellulose, modified cellulose, cellulose acetate, cellulose butyrate and hydroxy ethyl cellulose, as well as synthetic latices made from the polymers referred to above.
• natural and modified natural polymers e.g. cellulose, modified cellulose, cellulose acetate, cellulose butyrate and hydroxy ethyl cellulose, as well as synthetic latices made from the polymers referred to above.
• the perfume should preferably be soluble in the monomer and compatible with the polymer.
• the perfume should also be compatible with the polymer itself. This prevents phase separations which may cause problems .
• the absorptions of perfume by polymer may be by absorption into open pores through capillary action, or by encapsulation or dissolution in the polymer so that release of perfume is by diffusion through the polymer, or it may be adsorption onto the hydrophobic polymer material. More than one of these modes of absorption may occur at the same time .
• a polymer with absorbed perfume may have the polymer and the perfume in a weight ratio lying in the range from 25:1 to 2:1, especially 20:1 to 3:1.
• the amount of polymer particles with absorbed perfume included in a rinse conditioning composition is preferably such an amount that the perfume is present in an amount from 0.1 to 10% by weight of the composition.
• the amount of polymer with absorbed perfume is likely to be such that its perfume amounts to 0.1% to 3%, or even 0.1% to 2% by weight of the composition.
• a composition according to this invention may incorporate additional perfume which is not located or absorbed in or on the particles (i.e. it is outside the particles and not absorbed thereon) in addition to the perfume which is absorbed onto or into such particles.
• references herein to the amount of absorbed perfume in the particles is to be construed as the amount of perfume located in or on the particles, but not perfume separately added to the composition.
• the perfume which is not absorbed onto particles which principally provides the fragrance of the rinse conditioner composition itself, does not exhibit high substantivity towards the fabrics. It may also be desirable that the weight ratio of perfume which is and respectively is not absorbed or included in or on particles lies in a range from 10:1 to 1:4, especially from 10:1 or 4:1 to 1:1.
• the polymer melts when heated to ironing temperatures so that perfume which is absorbed onto the polymer particles is released and provides a perceptible fragrance during ironing. If this is desired it will be appropriate for the organic polymer of the porous polymer particles to soften and flow at a temperature in the range from 100°C to 220°C (that is, to have a melting temperature lying in the range 100°C-220°C) .
• Choice of polymer characteristics can affect the ease with which perfume is released. Using monomers which give a more crystalline polymer, and incorporating cross-linking will both inhibit the release of the perfume, so that the perfume may be released more slowly over a longer period or may be released when ironing melts the polymer.
• cross-linking between at least 0.5% by number of the total number of monomer residues present. There may be cross-linking between up to 10% by number of the monomer residues, or possibly even more eg. up to 15% by number. Preferred is a range of 0.5% or 1% up to 5% or 8% by number of the monomer residues in the polymer.
• Rinse conditioner compositions may contain a number of materials in addition to the fabric softening material, the porous particles and perfume. Materials which may be present include optical brightening agents, colourants, opacifiers, hydrotropes, viscosity control agents such as electrolyte, stabilisers such as guar gum and polyethyleneglycol, anti-static agents and ironing aids. Silicones may be used for the latter purpose.
• Rinse conditioner compositions in accordance with the invention preferably have a pH of less than 6.0, more preferably a pH ranging from 2.0 to 5.0.
• Rinse conditioning compositions may contain pH-buffering agents such as weak acids and salts thereof, e.g. phosphoric, benzoic or citric acids and salts of these acids.
• the amount of buffering material included in a composition may lie in the range from 0.5-10% by weight, preferably not more than 5% by weight .
• Rinse conditioner compositions of this invention are generally in the form of aqueous liquids which will generally contain at least 10%, usually at least 20% by weight water and often from 50% or 60% to 97% by weight of water.
• Other product forms may be envisaged, however, including powders, creams, pastes, blocks or tablets. Suitable types of blocks and tablets are disclosed in European Patent Specification No. EP-A-255 779 (UNILEVER) .
• EP-A-255 779 (UNILEVER) .
• the ability of colloidal particles to remain in suspension is of course most relevant to products in liquid form.
• compositions according to this invention are preferably added to a much larger volume of water to form a liquor which is than used to contact the fabrics to be treated.
• a liquor can be formed by adding a composition by hand or by way of an automatic dispensing device to water in a washing machine.
• rinse conditioning compositions in accordance with this invention will not contain ion exchange aluminosilicate builder, nor any other water-insoluble inorganic material nor sodium tripolyphosphate nor any other water-soluble electrolyte in quantities greater than the quantity of the rinse conditioner material. It is likely that the compositions will be entirely free of tripolyphosphate and of any water-insoluble inorganic materials.
• a cross-linked polystrene latex with perfume absorbed therein was prepared by method A referred to above.
• styrene 8.8 gram divinylbenzene (55% concentration) 0.17 gram perfume 1 gram cetyl trimethylammonium bromide (CTAB) 0.4 gram polymerisation initiator 0.25 gram water 100 ml.
• CTAB cetyl trimethylammonium bromide
• the CTAB was dissolved in most of the water (90ml) and the solution degassed.
• the perfume was dissolved in the styrene divinylbenzene mixture and the resulting solution was added to the surfactant solution in the flask. After 10 minutes the initiator in the remaining water was added and the polymerisation reaction allowed to proceed for 6-8 hours while the contents of the flask were heated to 70°C. Emulsion polymerisation took place during this time giving a latex consisting of a colloidal suspension of polymer particles in the water. The mean particle size was approximately O.l ⁇ . Unreacted monomer was removed by steam distillation. This led to some loss of perfume, but about 90% of the perfume remained in the polymer latex. A higher quantity of perfume could be incorporated into the latex particles by increasing the quantity of perfume, up to about 2.5 gram.
• perfume was incorporated into performed latex in accordance with method B above.
• a latex of cross-linked polystyrene particles of mean size approximately O.l ⁇ was prepared using the following materials :
• a second stage used perfume 1 gram CTAB 0.3 gram dichloromethane 27 gram.
• the perfume was dissolved in the dichloromethane solvent. This was then mixed with the CTAB and 50 grams of the latex prepared as above. The heavy organic layer was dispersed throughout the mixture by shaking and then by application of ulta-sound. This produced an opaque emulsion from which the solvent was removed using a rotary evaporator.
• Example 3 A typical conditioner composition contains:
• a chemical preservative could well be included, e.g. 0.02% by weight of 2-brom-2-nitropropane-l, 3-diol available under the Registered Trade Mark "Bronopol”.
• An additional amount of the same perfume, or different, perfume as used in the latex particles can be included in conventional amounts.
• dimethyl di-hardened tallow ammonium chloride can be partially, or totally, replaced by 1, 2- (hardened) ditallowyloxy-3-trimethyl ammonium propane chloride or a nonionic oily sugar derivative as described in the text above under nonionic compounds.
• Example 4
• Each latex was used to deliver perfume to fabric in accordance with the following procedure which used three fabrics namely 70-30 polyester/cotton, a bulked acrylic fabric and cotton terry towelling.
• Latex No. Monomers Solids % Perfume Avge Particle size ( ⁇ m)
• the rinse conditioner contained 5% by weight cationic fabric softener (which was dimethyldistearyl ammonium chloride) . In some experiments the rinse conditioner contained sufficient latex to provide 0.25% by weight perfume. In other experiments the quantity of latex was halved, but compared with a control containing 0.25% by weight perfume. In other experiments the quantity of latex was halved, but compared with a control containing 0.25% by weight of perfume.
• Example 6 A fabric softening composition was prepared containing 20% by weight of 1, 2-ditallowyloxy-3-trimethyl ammonium propane chloride.
• the suspension was a mobile white emulsion.
• the same emulsion was mixed with a latex which was the cross-linked latex I of Example 5. The amount was sufficient to provide 1% by weight perfume in the composition. The emulsion remained very mobile.
• a linear polymeric latex was prepared in the presence of perfume as a comparative example (7A) .
• the materials employed were:
• N,N' -dimethylaminoethyl acrylate 4.3g polyoxyethylene (30) nonylphenyl ether 38. Og perfume 36.
• Ig polymerisation initiator 1.2g deionised water 500 ml
• Example 2 Polymerisation was carried out in a similar apparatus to that of Example 1.
• the nonionic surfactant and the polymerisation initiator were dissolved in the water which was then degassed, after which it was stirred and heated to 62 °C.
• the two acrylate monomers were mixed with the perfume and the resulting solution was added drop-wise to the water over a period of two hours.
• the polymerisation reaction was allowed to continue for a further 7 hours while the contents of the flask were stirred at the same temperature of 62°C. After this the mixture was stem distilled to remove most of the residual monomer.
• the resulting latex was than concentrated on a rotary evaporator reducing its volume by about 50% and in doing so removing remaining monomer to provide an odourless latex which was filtered through glass wool. 503g of a latex of 37 wt% solids content and O.ll ⁇ m average particle size was obtained.
• a cross-linked polymeric latex was prepared using the following materials (example 7B) : n-butyl acrylate 140 g
• N,N' -dimethylaminoethyl acrylate 4.3 g ethylene glycol di (methylacrylate) (EGDMA) 6.0 g cetyl trimethyl ammonium bromide (CTAB) 30 g Polymerisation initiator 1.2 g deionised water 500 ml
• Example 7A and 7B were used to incorporate perfume into a rinse conditioner composition containing 5% by weight of dimethyl distearyl ammonium chloride as in Example 6.
• the amount of each ⁇ atex was calculated so as to introduce 0.25% perfume in the rinse conditioner composition assuming that all perfume used in the preparation of the latex has been retained in the latex.
• the resulting rinse conditioner compositions were compared with a composition containing the same fabric softener and 0.25% by weight perfume without latex.
• Example 5 Using the same test procedure, a comparison was made between latex III of Example 5, the above cross-linked latex based on butyl acrylate (Example 7B) and perfume without latex. As before, the amount of each latex added to the rinse conditioner composition was calculated so as to introduce 0.25% perfume. Some of the test cloths were ironed before assessment. The results are set out in the following Table 5.
• both cross-linked latices provided an increase in the perceptibility of the perfume delivered to the fabric. This was particularly apparent with the cross-linked styrene latex after the test cloths had been ironed.

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• 1999
  • 1999-05-05 GB GBGB9910389.7A patent/GB9910389D0/en not_active Ceased
• 2000
  • 2000-04-12 ES ES00926888T patent/ES2220460T3/es not_active Expired - Lifetime
  • 2000-04-12 AT AT00926888T patent/ATE270322T1/de not_active IP Right Cessation
  • 2000-04-12 WO PCT/EP2000/003279 patent/WO2000068352A1/en active IP Right Grant
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