WO2000053153A1 - Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule - Google Patents
Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule Download PDFInfo
- Publication number
- WO2000053153A1 WO2000053153A1 PCT/FR2000/000584 FR0000584W WO0053153A1 WO 2000053153 A1 WO2000053153 A1 WO 2000053153A1 FR 0000584 W FR0000584 W FR 0000584W WO 0053153 A1 WO0053153 A1 WO 0053153A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- cosmetic agent
- solution
- agent according
- chosen
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/04—Nail coating removers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/51—Chelating agents
Definitions
- the subject of the present invention is a cosmetic makeup-removing agent intended for eliminating, on any keratinous substrate, film-forming coatings in crosslinked hybrid material obtained from various cosmetic formulations in particular of hair products, make-up products and care products. the skin.
- keratin substrate it should be understood, according to the invention, that makeup removal applies not only to hair, eyelashes, eyebrows and nails but also to the skin.
- non-reversible is understood to mean obtaining a coating having very good adhesion to the substrate and which can withstand over time not only numerous washes with water but also various organic solvents. without its properties being affected.
- compositions may manifest the desire to be able to nevertheless eliminate them after a certain period of time.
- the coating of a crosslinked hybrid material is obtained from a composition of the sol / gel type by mixing: (a ) at least one organometallic (or metallo-organic) compound,
- a sol / gel reaction takes place, leading, after evaporation of the solvent (s), to the formation of a hybrid material by polycondensation and crosslinking on a nanometric scale.
- the structure of the crosslinked hybrid material essentially consists of mineral nodules originating from the organometallic compound and chains of the organic or silicone polymer, the nodules being linked physically or chemically to the chains of the organic or silicone polymer.
- the object of the present invention is to provide an agent for removing makeup from cosmetic products, the film-forming substance of which consists of a coating of a crosslinked hybrid material.
- the present invention therefore relates to a cosmetic agent allowing the removal, on any keratinous substrate, of a film-forming coating of a crosslinked hybrid material obtained by sol / gel reaction characterized in that said agent is a chelating agent used either alone or in solution in a solvent, said chelator or its solution being chosen such that it forms with said film-forming coating a contact angle of less than 90 °.
- the mechanism for removing makeup by removing the coating of crosslinked hybrid material is essentially based on replacing the interactions between the organic or silicone polymer and the organometallic compound with interactions between the chelating compound and the organometallic compound, which causes " disintegration "of the coating of crosslinked hybrid material.
- the present invention is based on the replacement of organic phase / mineral phase interactions with chelating / mineral phase interactions.
- the chelating agent alone if it is liquid, or its solution, forms with the coating of crosslinked hybrid material a contact angle of less than 90 °.
- Certain compounds having varied structures such as for example ⁇ -diketones such as acetylacetone and 2,4-dione hexane, ⁇ -ketoesters, such as methyl or ethyl acetylacetate, dipyridyl (2,2 'or 4,4') and tetraphenylporphine.
- Some of these chelating agents are liquid and not very aggressive so that they can be used alone, that is to say without putting them in solution. This is the case, for example, with acetylacetone and acetic acid which constitute excellent makeup-removing agents for nail varnishes, the coating of which is made of a crosslinked hybrid material.
- the chelating agent is however in aqueous solution or in an organic solvent or in a mixture of these.
- organic solvents which can be used according to the invention, and which can lead to solutions of some of the non-water-soluble chelating agents mentioned above, mention may especially be made of hexane, cyclohexane, benzene, toluene, and ethanol, as well as certain lipophilic solvents such as for example volatile fluid silicones such as cyclomethicones and in particular cyclotetramethylsiloxane, cyclopentamethylsiloxane and cyclohexamethylsiloxane and their mixtures.
- volatile fluid silicones such as cyclomethicones and in particular cyclotetramethylsiloxane, cyclopentamethylsiloxane and cyclohexamethylsiloxane and their mixtures.
- the choice of solvent is important in order to obtain good makeup removal, since the solvent, in the presence of the chelating agent, must have, with respect to the coating , good wettability.
- the chelating agent can then better penetrate the surface of the coating and cause the phenomena of interactions allowing the disintegration of the crosslinked hybrid material.
- the concentration of chelating agent is generally at least 0.1% up to the limit of solubility in the chosen solvent but is preferably between 0.5 and 15%, and more commonly between 1 and 10% by weight relative to the composition.
- the makeup-removing agent according to the invention may optionally contain, depending on its destination, certain usual cosmetic ingredients.
- the present invention also relates to a process for removing makeup from a film-forming coating of a crosslinked hybrid material formed on a keratinous substrate.
- This process consists in applying the cosmetic make-up removing agent as defined above to the entire film-forming coating, allowing it to act for a sufficient period of time, of the order of a few minutes, then removing the residue. formed by wiping with a cloth or paper or by washing.
- Example 1 A nail varnish was prepared according to application WO 98/44906 by mixing the following ingredients:
- the varnish thus obtained is then applied to the surface of the nails and leads, after drying, to the formation of a homogeneous glossy film having excellent persistence with water, detergents and also with alcohol. a) Removing the nail polish
- a 2% by weight solution of ascorbic acid in ethanol was prepared and then applied uniformly to the surface of the nails using a brush.
- the nails were then wiped with a textile material and a total removal of the varnish from the surface of the nails was observed.
- the contact angle of the makeup removal solution above was determined visually by applying the solution to a glass plate coated with a layer of varnish made of hybrid material according to Example 1. This determination made it possible to highlight that the contact angle was about 60 °.
- a colored fixing composition for hair was prepared according to application WO 98/44906 as follows:
- the dry extract of the solution is then brought to 25% by addition of a volatile silicone oil (D5 from the company Dow Corning).
- a volatile silicone oil D5 from the company Dow Corning
- 2.5 g of the ⁇ - ⁇ -hydroxy / oxo silicone (viscosity 6500 cSt) from the company Dow Corning are then added.
- the final solution obtained is then packaged in a container suitable for spraying on hair.
- an anti-wrinkle composition was prepared from the following ingredients:
- composition thus obtained is then applied in the form of a thin layer to the wrinkles surrounding the eyes. After evaporation of the volatile components, a transparent and invisible film is formed which exerts a tightening effect attenuating perceptibly the wrinkles around the eyes.
- a 2% solution of ascorbic acid in ethanol was prepared and applied to the eye area using a cotton pad. After leaving to act for about a minute, the eye area was then wiped off with a tissue and a very good removal of the film was observed.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU32955/00A AU3295500A (en) | 1999-03-10 | 2000-03-09 | Cosmetic agent for removal of a film formed by cross-linked hybrid material |
EP00910914A EP1158951A1 (fr) | 1999-03-10 | 2000-03-09 | Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule |
JP2000603642A JP2003504305A (ja) | 1999-03-10 | 2000-03-09 | 架橋ハイブリッド物質からなる皮膜形成被膜を除去するためのクレンジング用化粧剤 |
CA002364177A CA2364177A1 (fr) | 1999-03-10 | 2000-03-09 | Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9902947A FR2790664B1 (fr) | 1999-03-10 | 1999-03-10 | Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule |
FR99/02947 | 1999-03-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000053153A1 true WO2000053153A1 (fr) | 2000-09-14 |
Family
ID=9543014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2000/000584 WO2000053153A1 (fr) | 1999-03-10 | 2000-03-09 | Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1158951A1 (fr) |
JP (1) | JP2003504305A (fr) |
AU (1) | AU3295500A (fr) |
CA (1) | CA2364177A1 (fr) |
FR (1) | FR2790664B1 (fr) |
WO (1) | WO2000053153A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1172079A1 (fr) * | 2000-07-13 | 2002-01-16 | L'oreal | Utilisation d'un composé métallo-organique pour protéger et/ou renforcer les matières kératiniques, et procédé de traitement |
FR2910316A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Procede de demaquillage des cheveux recouverts d'un film polymere particulier |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR414816A (fr) * | 1910-04-14 | 1910-09-12 | Charles Philip Lowndes Titherl | Produit hygroscopique pour nettoyer la peau |
FR1464035A (fr) * | 1965-11-16 | 1966-07-22 | Solutions acides tamponnées pour la cosmétologie | |
FR2019719A1 (fr) * | 1968-10-02 | 1970-07-03 | Gillette Co |
-
1999
- 1999-03-10 FR FR9902947A patent/FR2790664B1/fr not_active Expired - Fee Related
-
2000
- 2000-03-09 CA CA002364177A patent/CA2364177A1/fr not_active Abandoned
- 2000-03-09 WO PCT/FR2000/000584 patent/WO2000053153A1/fr not_active Application Discontinuation
- 2000-03-09 AU AU32955/00A patent/AU3295500A/en not_active Abandoned
- 2000-03-09 EP EP00910914A patent/EP1158951A1/fr not_active Withdrawn
- 2000-03-09 JP JP2000603642A patent/JP2003504305A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR414816A (fr) * | 1910-04-14 | 1910-09-12 | Charles Philip Lowndes Titherl | Produit hygroscopique pour nettoyer la peau |
FR1464035A (fr) * | 1965-11-16 | 1966-07-22 | Solutions acides tamponnées pour la cosmétologie | |
FR2019719A1 (fr) * | 1968-10-02 | 1970-07-03 | Gillette Co |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1172079A1 (fr) * | 2000-07-13 | 2002-01-16 | L'oreal | Utilisation d'un composé métallo-organique pour protéger et/ou renforcer les matières kératiniques, et procédé de traitement |
FR2811549A1 (fr) * | 2000-07-13 | 2002-01-18 | Oreal | Utilisation d'un compose metallo-organique pour proteger et/ou renforcer les matieres keratiniques, et procede de traitement |
FR2910316A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Procede de demaquillage des cheveux recouverts d'un film polymere particulier |
Also Published As
Publication number | Publication date |
---|---|
FR2790664A1 (fr) | 2000-09-15 |
AU3295500A (en) | 2000-09-28 |
EP1158951A1 (fr) | 2001-12-05 |
FR2790664B1 (fr) | 2001-05-18 |
JP2003504305A (ja) | 2003-02-04 |
CA2364177A1 (fr) | 2000-09-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0471054B1 (fr) | COMPOSITION RESISTANTE A l'EAU POUR LE REVETEMENT DES CILS, ET SON PROCEDE DE PREPARATION | |
EP1216022B1 (fr) | Composition cosmetique a base de composes organiques du silicium comportant au moins une fonction solubilisante non-basique | |
EP1767187B1 (fr) | Composition cosmétique comprenant un composé organique du silicium, et procédé de mise en forme des cheveux | |
EP0971685A1 (fr) | Composition cosmetique ou dermatologique formant, sur un substrat keratinique, un revetement en un materiau hybride reticule | |
EP1172079A1 (fr) | Utilisation d'un composé métallo-organique pour protéger et/ou renforcer les matières kératiniques, et procédé de traitement | |
CA1310585C (fr) | APPLICATION COSMETIQUE DE POLYSILOXANES A FONCTION .beta.-CETOESTER ET COMPOSITIONS MISE EN OEUVRE | |
FR2982155A1 (fr) | Composition cosmetique comprenant au moins un alcoxysilane | |
EP0558423B1 (fr) | Composition cosmétique ou dermatologique sous la forme d'une dispersion d'un composé organofluoré hydrocarboné dans une solution aqueuse d'un polymère filmogène hydrosoluble, susceptible de former des films composites | |
FR2736824A1 (fr) | Composition capillaire a base de minoxidil a faible teneur en solvant gras | |
EP1321126A1 (fr) | Compositions cosmétiques comprenant des polymères à fonctions chimiques complémentaires | |
FR2891141A1 (fr) | Composition cosmetique comprenant un compose organique du silicium, et procede de mise en forme des cheveux | |
FR3007286A1 (fr) | Composition comprenant l'association d'un polymere acrylique, d'un copolymere silicone et d'un amino-acide ou derive d'amino-acide | |
EP0583459B1 (fr) | Composition cosmetique ou dermatologique sous la forme d'une dispersion huile-dans-l'eau susceptible de former des films composites | |
WO2000053153A1 (fr) | Agent cosmetique pour le demaquillage d'un revetement filmogene en materiau hybride reticule | |
FR2798063A1 (fr) | Composition cosmetique a base de composes organiques du silicium, peu ou pas polymerises, solubles dans l'eau, et partiellement neutralises | |
FR2774902A1 (fr) | Composition cosmetique a base de polyurethannes associatifs et de silicones quaternaires | |
EP1064926A1 (fr) | Composition cosmétique multiphases à base d'une huile fluorée volatile | |
EP1221929B1 (fr) | Procede d'amelioration des proprietes de non-transfert de compositions cosmetiques | |
FR3004932A1 (fr) | Composition cosmetique de revetement des ongles | |
FR3004933A1 (fr) | Composition cosmetique de revetement des ongles | |
FR3076718A1 (fr) | Agent pour la modification de la couleur de matières kératiniques comportant au moins un alcool, un minéral argileux modifié et un pigment de couleur | |
FR2822061A1 (fr) | Dispositif aerosol contenant une composition capillaire comprenant un polysaccharide greffe par un polysiloxane | |
CA2319947A1 (fr) | Dispositif aerosol contenant une composition capillaire comprenant au moins un copolymere silicone/acrylate | |
FR2783167A1 (fr) | Composition cosmetique a base de composes organiques du silicium, peu ou pas polymerises, solubles dans l'eau et comportant au moins une fonction solubilisante non-basique | |
BE1000685A3 (fr) | Procede de nettoyage a sec des cheveux et produit pour sa mise en oeuvre. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2000910914 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref country code: JP Ref document number: 2000 603642 Kind code of ref document: A Format of ref document f/p: F |
|
ENP | Entry into the national phase |
Ref document number: 2364177 Country of ref document: CA Ref country code: CA Ref document number: 2364177 Kind code of ref document: A Format of ref document f/p: F |
|
WWE | Wipo information: entry into national phase |
Ref document number: 09913712 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 2000910914 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2000910914 Country of ref document: EP |