WO2000009796A1 - Fabric treatments and methods for using them - Google Patents

Fabric treatments and methods for using them Download PDF

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Publication number
WO2000009796A1
WO2000009796A1 PCT/US1999/017987 US9917987W WO0009796A1 WO 2000009796 A1 WO2000009796 A1 WO 2000009796A1 US 9917987 W US9917987 W US 9917987W WO 0009796 A1 WO0009796 A1 WO 0009796A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
carpet
dust
vacuuming
fabric
Prior art date
Application number
PCT/US1999/017987
Other languages
French (fr)
Inventor
Marygrace G. Horner
Thomas D. Gueldenzopf
Original Assignee
S.C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S.C. Johnson & Son, Inc. filed Critical S.C. Johnson & Son, Inc.
Priority to AU54717/99A priority Critical patent/AU5471799A/en
Publication of WO2000009796A1 publication Critical patent/WO2000009796A1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06Processes in which the treating agent is dispersed in a gas, e.g. aerosols

Definitions

  • the present invention relates to compositions for treating carpets and other interior fabrics. These compositions suppress dust levels in room air. House dust can create an unsightly appearance.
  • the present invention provides a fabric treating composition which has at least 10% by weight of benzyl benzoate, and at least 20% (preferably at least 50%) by weight of a volatile alcohol having less than four carbons. Preferably there is also between 5 and 20% by weight of water.
  • Ethanol is a highly preferred alcohol because of its volatility and known toxicity characteristics.
  • suitable volatile alcohols such as methanol, propanol and isopropanol .
  • hydrocarbon propellant that permits delivery of the composition from an aerosol can.
  • the hydrocarbon propellant can be propane, butane, isobutane, pentane, and various mixtures thereof. Other standard aerosol hydrocarbon propellants may also be used.
  • compositions of the present invention may also include a variety of other fabric treating components which enhance effectiveness, modify physical appearance or fragrance, extend the life of the container, or add other desired features.
  • Such optional components include (without limitation) perfumes, chelating agents, preservatives and corrosion inhibitors, each typically present in an amount from 0 - 2%.
  • the invention provides methods of reducing the level of airborne dust in a carpeted room.
  • the application is by spraying the composition on the carpet and the vacuuming step occurs after the composition has dried on the carpet surface. It is preferable to wait two or more hours before the first vacuuming. There is no criticality to the time between the first and any future vacuuming.
  • higher levels of benzyl benzoate in the presence of high levels of alcohol serve to trap dust in and on the carpet (or other room fabric) between vacuuming, yet permit release of the dust into a vacuum cleaner during conventional vacuuming.
  • the carpet, drapes, upholstery, and other interior room fabric surprisingly act as a "filtering" system for the air in the room.
  • the objects of the invention therefore include providing compositions of the above kind which:
  • a composition of the present invention has the following content :
  • dusty carpets were simulated by taking collection bag residue from a vacuum cleaner, passing the residue through a sieve to select for dust size particles, and then dirtying clean carpet samples (12 inch by 14 inch nylon carpet) with the dust.
  • the above composition was sprayed on the dirty carpet at a concentration of 11 gm per square yard. The carpet was then allowed to dry for two hours. The carpet was then raked to force dust from the carpet into the air. The airborne dust level was monitored.
  • each carpet square was placed in a monitoring chamber and then agitated by stroking a squeegee five times against the carpet. Dust levels in the chamber were monitored at one minute intervals for the next six minutes.
  • the carpeting was then placed in a foot traffic location for four weeks. At weekly intervals the carpets were removed, vacuumed, and tested as noted above. Dust levels with treated carpets averaged significantly less than for untreated carpets (e.g. at the end of week one, at five minutes after squeegeeing, the control count was about 270,000 particles and the treated count was about 120,000; at the end of week three, after three minutes, the control count was about 190,000 particles and the treated count was about 45,000) .
  • the fabric need not be nylon. It can be a wide variety of natural and synthetic fibers commonly used for carpeting, upholstery or drapery such as acrylics sold under the trademarks “Verel” , “Orion” , and “Acrilan” ; polyesters sold under the trademarks “Kodel” and “Dacron” ; wool; cotton; and blends of such fibers.
  • compositions and methods of the present invention can treat interior fabrics in a way which reduces airborne dust.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Detergent Compositions (AREA)

Abstract

Fabric treating compositions are provided which have at least 10 % benzyl benzoate and at least 20 % alcohol. The compositions preferably also contain water. They trap dust from room air between vacuuming, yet permit ready release of the dust into a vacuum cleaner. The carpet thus becomes a room air filter. Methods for using these treating compositions are also disclosed.

Description

FABRIC TREATMENTS AND METHODS FOR USING THEM CROSS REFERENCES TO RELATED APPLICATIONS Not Applicable STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH
Not Applicable
The present invention relates to compositions for treating carpets and other interior fabrics. These compositions suppress dust levels in room air. House dust can create an unsightly appearance.
Further, many people have allergic reactions to house dust. A portion of the dust commonly found in homes is caused by the excrement of house dust mites. It has therefore been proposed to treat their preferred habitats with an acaricide. For example, in U.S. patent 4,666,940 it was suggested to include such acaricides in carpet treating compositions. This approach had little effect on the level of dust already in room air, or on dust caused by other sources. Further, the 4,666,940 treatment created a pulverulent residue of small particles (that were suitable for ingestion by dust mites) . These particles themselves are an additional potential source of "dust" .
A variety of complex electrical room air filtration systems have also been developed. However, this approach is quite expensive.
It can therefore be seen that a need exists for an improved way of controlling dust levels in room air. BRIEF SUMMARY OF THE INVENTION In one aspect the present invention provides a fabric treating composition which has at least 10% by weight of benzyl benzoate, and at least 20% (preferably at least 50%) by weight of a volatile alcohol having less than four carbons. Preferably there is also between 5 and 20% by weight of water.
Ethanol is a highly preferred alcohol because of its volatility and known toxicity characteristics. However, other suitable volatile alcohols may be used such as methanol, propanol and isopropanol .
It is also preferred that there be a hydrocarbon propellant that permits delivery of the composition from an aerosol can. The hydrocarbon propellant can be propane, butane, isobutane, pentane, and various mixtures thereof. Other standard aerosol hydrocarbon propellants may also be used.
The compositions of the present invention may also include a variety of other fabric treating components which enhance effectiveness, modify physical appearance or fragrance, extend the life of the container, or add other desired features. Such optional components include (without limitation) perfumes, chelating agents, preservatives and corrosion inhibitors, each typically present in an amount from 0 - 2%.
In another aspect, the invention provides methods of reducing the level of airborne dust in a carpeted room. One can apply the above compositions to a carpet surface in the room and thereafter vacuum the carpet. Preferably, the application is by spraying the composition on the carpet and the vacuuming step occurs after the composition has dried on the carpet surface. It is preferable to wait two or more hours before the first vacuuming. There is no criticality to the time between the first and any future vacuuming. Apart from the acaricidal effect of even low levels of benzyl benzoate on dust mites, higher levels of benzyl benzoate in the presence of high levels of alcohol serve to trap dust in and on the carpet (or other room fabric) between vacuuming, yet permit release of the dust into a vacuum cleaner during conventional vacuuming. The carpet, drapes, upholstery, and other interior room fabric surprisingly act as a "filtering" system for the air in the room. The objects of the invention therefore include providing compositions of the above kind which:
(a) help reduce the amount of airborne dust in a room;
(b) which can both treat carpets and prevent dust that falls on the carpet from being reintroduced into room air; and
(c) which dry quickly and have acceptable flammability, odor and other characteristics.
These and other objects and advantages of the present invention (e.g. providing methods for using such compositions) will be apparent from the description which follows. The description is merely of the preferred embodiments. To evaluate the full scope of the invention the claims should be reviewed. DETAILED DESCRIPTION
Example 1
A composition of the present invention has the following content :
Ingredient %wt water 12.60 benzyl benzoate 18.00 isobutane 10.0 ethanol 58.32 sodium nitrate (preservative) 0.36 perfume 0.72 Testing
In one set of experiments dusty carpets were simulated by taking collection bag residue from a vacuum cleaner, passing the residue through a sieve to select for dust size particles, and then dirtying clean carpet samples (12 inch by 14 inch nylon carpet) with the dust.
The above composition was sprayed on the dirty carpet at a concentration of 11 gm per square yard. The carpet was then allowed to dry for two hours. The carpet was then raked to force dust from the carpet into the air. The airborne dust level was monitored.
Before the raking the carpet was first vacuumed in a second, similar comparative experiment. In another (control) experiment dust levels were measured when there was no treatment by a composition of the present invention ("untreated") . The untreated carpet was raked without vacuuming. In a fourth experiment the untreated carpet was raked after vacuuming.
Each of the four experimental conditions was repeated four times, and air particle levels were averaged for each condition. The following are the results :
(a) treatment plus vacuuming - 1215 particles per cubic foot of air;
(b) treatment without vacuuming - 1676 particles per cubic foot of air,- (c) no treatment and no vacuuming - 4323 particles per cubic foot of air; and
(d) no treatment, but with vacuuming - 5830 particles per cubic foot of air. Thus, in the absence of treatment with a composition of the present invention, vacuuming tended to spread dust into the air. Use of the compositions of the present invention reduced dust levels regardless of whether there was vacuuming. Further, it increased the efficiency of vacuuming (so that vacuuming helped suppress the airborne dust level) .
In another set of experiments 12" x 12" nylon carpet squares were soiled in a standard manner using composite vacuum cleaner soil. Six of such squares were selected, with three being controls that were not treated with a formulation of the present invention, and three being treated with a formulation of the present invention.
At a first time each carpet square was placed in a monitoring chamber and then agitated by stroking a squeegee five times against the carpet. Dust levels in the chamber were monitored at one minute intervals for the next six minutes.
The carpeting was then placed in a foot traffic location for four weeks. At weekly intervals the carpets were removed, vacuumed, and tested as noted above. Dust levels with treated carpets averaged significantly less than for untreated carpets (e.g. at the end of week one, at five minutes after squeegeeing, the control count was about 270,000 particles and the treated count was about 120,000; at the end of week three, after three minutes, the control count was about 190,000 particles and the treated count was about 45,000) .
While the above describes preferred embodiments of the invention, it will be appreciated that various changes can be made to the above embodiment without departing from the concept. For example, the fabric need not be nylon. It can be a wide variety of natural and synthetic fibers commonly used for carpeting, upholstery or drapery such as acrylics sold under the trademarks "Verel" , "Orion" , and "Acrilan" ; polyesters sold under the trademarks "Kodel" and "Dacron" ; wool; cotton; and blends of such fibers.
Also, a wide variety of other formulations having high levels of benzyl benzoate and volatile alcohol can be used (albeit aqueous ethanol aerosol formulations are highly preferred) .
INDUSTRIAL APPLICABILITY The compositions and methods of the present invention can treat interior fabrics in a way which reduces airborne dust.

Claims

CLAIMS We claim:
1. A fabric treating composition, comprising: at least 10% by weight of benzyl benzoate; and at least 20% by weight of an alcohol having less than four carbons .
2. The fabric treating composition of claim 1, wherein at least 50% by weight of the composition is such an alcohol .
3. The fabric treating composition of claim 1, wherein the composition further comprises at least 5% by weight of hydrocarbon propellant.
4. The fabric treating composition of claim 1, wherein the composition is a carpet treatment .
5. The fabric treatment composition of claim 1, wherein the alcohol is ethanol.
6. A method of reducing the level of airborne dust in a carpeted room, comprising the steps of : applying the claim 1 composition to a surface of a carpet in the room; and thereafter vacuuming the carpet surface.
7. The method of claim 6, wherein the carpet surface is vacuumed at least twice after the application of the claim 1 composition.
8. The method of claim 6, wherein the application is by spraying the composition on the carpet.
9. The method of claim 6, wherein the vacuuming step occurs after the composition has dried on the carpet surface .
PCT/US1999/017987 1998-08-12 1999-08-09 Fabric treatments and methods for using them WO2000009796A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU54717/99A AU5471799A (en) 1998-08-12 1999-08-09 Fabric treatments and methods for using them

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9630098P 1998-08-12 1998-08-12
US60/096,300 1998-08-12

Publications (1)

Publication Number Publication Date
WO2000009796A1 true WO2000009796A1 (en) 2000-02-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/017987 WO2000009796A1 (en) 1998-08-12 1999-08-09 Fabric treatments and methods for using them

Country Status (3)

Country Link
AR (1) AR022362A1 (en)
AU (1) AU5471799A (en)
WO (1) WO2000009796A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1368657A (en) * 1973-05-16 1974-10-02 Roberts Lab Ltd Acaricidal compositions
EP0173229A2 (en) * 1984-08-20 1986-03-05 Werner & Mertz GmbH Means for destroying house dust mites, and its use
EP0612469A1 (en) * 1993-02-26 1994-08-31 MERCK PATENT GmbH Preparation with acaricidal activity
WO1998036640A1 (en) * 1997-02-20 1998-08-27 Reckitt & Colman Inc. Dust mite control compositions containing benzyl benzoate and alcohol

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1368657A (en) * 1973-05-16 1974-10-02 Roberts Lab Ltd Acaricidal compositions
EP0173229A2 (en) * 1984-08-20 1986-03-05 Werner & Mertz GmbH Means for destroying house dust mites, and its use
EP0612469A1 (en) * 1993-02-26 1994-08-31 MERCK PATENT GmbH Preparation with acaricidal activity
WO1998036640A1 (en) * 1997-02-20 1998-08-27 Reckitt & Colman Inc. Dust mite control compositions containing benzyl benzoate and alcohol
US5916917A (en) * 1997-02-20 1999-06-29 Reckitt & Colman Inc. Dust mite control compositions containing benzyl benzoate and alcohol

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CLINICAL AND EXPERIMENTAL ALLERGY, vol. 22, no. 10, 1992, pages 923 - 928 *
DATABASE BIOSIS BIOSCIENCES INFORMATION SERVICE, PHILADELPHIA, PA, US; HART,B.J. ET AL.: "In vitro evaluation of acaricidal and fungicidal activity of the house dust mite acaricide, Allerbiocid", XP002124622 *
DATABASE CROPU [online] Derwent information ltd.; MANJRA A ET AL: "The effects of a single treatment of an acaricide, Acarosan, and a detergent, Metsan, on Der p 1 allergen levels in the carpets and mattresses of asthmatic children.", XP002124652, retrieved from STN Database accession no. 1994-84971 *
S.AFR.MED.J. (84, NO. 5, 278-80, 1994) 2 TAB. 14 REF. CODEN: SAMJAF, Univ.Cape-Town *

Also Published As

Publication number Publication date
AR022362A1 (en) 2002-09-04
AU5471799A (en) 2000-03-06

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