WO2000007490A1 - Lingettes humides empilees comportant des couches anti-evaporation - Google Patents

Lingettes humides empilees comportant des couches anti-evaporation Download PDF

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Publication number
WO2000007490A1
WO2000007490A1 PCT/US1999/017556 US9917556W WO0007490A1 WO 2000007490 A1 WO2000007490 A1 WO 2000007490A1 US 9917556 W US9917556 W US 9917556W WO 0007490 A1 WO0007490 A1 WO 0007490A1
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WO
WIPO (PCT)
Prior art keywords
stack
wipes
wet wipes
liquid composition
substrate
Prior art date
Application number
PCT/US1999/017556
Other languages
English (en)
Inventor
Maurizio Pucci
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP2000563178A priority Critical patent/JP2002522562A/ja
Priority to EP99938956A priority patent/EP1102555A1/fr
Priority to AU53330/99A priority patent/AU5333099A/en
Priority to CA002337867A priority patent/CA2337867A1/fr
Publication of WO2000007490A1 publication Critical patent/WO2000007490A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/24—Towel dispensers, e.g. for piled-up or folded textile towels; Toilet-paper dispensers; Dispensers for piled-up or folded textile towels provided or not with devices for taking-up soiled towels as far as not mechanically driven
    • A47K10/32—Dispensers for paper towels or toilet-paper
    • A47K10/42—Dispensers for paper towels or toilet-paper dispensing from a store of single sheets, e.g. stacked
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/24—Towel dispensers, e.g. for piled-up or folded textile towels; Toilet-paper dispensers; Dispensers for piled-up or folded textile towels provided or not with devices for taking-up soiled towels as far as not mechanically driven
    • A47K10/32—Dispensers for paper towels or toilet-paper
    • A47K2010/3266—Wet wipes
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/24—Towel dispensers, e.g. for piled-up or folded textile towels; Toilet-paper dispensers; Dispensers for piled-up or folded textile towels provided or not with devices for taking-up soiled towels as far as not mechanically driven
    • A47K10/32—Dispensers for paper towels or toilet-paper
    • A47K10/42—Dispensers for paper towels or toilet-paper dispensing from a store of single sheets, e.g. stacked
    • A47K2010/428—Details of the folds or interfolds of the sheets

Definitions

  • the present invention relates to stacks of wet wipes which are provided with an improved stacking configuration, such that the evaporation the volatile components of the liquid formulation is reduced.
  • Wet wipes are typically premoistened, disposable towelettes which may be utilised in a variety of applications both domestic and industrial and perform a variety of functions.
  • Wet wipes are typically used to wipe surfaces both animate and inanimate, and may provide numerous benefits such as cleaning, cleansing, disinfecting, and skin care benefits.
  • Wipes are commonly used for human cleansing and wiping such as anal, perineal cleansing and genital cleansing and face and hand cleansing for example as intimate hygiene wipes such as feminine wet wipes.
  • Wet wipes may also be used for application of substances to the body including removing and applying of make-up, skin conditioners and medications.
  • Another application of wipes is during diaper changes and also for the treatment of adult and baby dermatitis partly caused by the use of diapers and incontinence devices.
  • wet wipes are also applicable for wiping and or cleaning other surfaces or for the application of compositions to surfaces, for example kitchen and bathroom surfaces, eyeglasses, shoes and surfaces which require cleaning in industry for example surfaces of machinery or automobiles.
  • Wet wipes also include articles used for the cleaning or grooming of pets.
  • Wet wipes are commonly constructed of combinations of synthetic and natural fibres, such as polyolefin fibres, viscose fibres and cotton fibres, which are generally moistened with an aqueous composition which contains amongst others surfactants, preservatives, oils and scents.
  • the wet wipes are then typically provided in a folded stacked configuration within a covered container such as a tub-like container having a lid.
  • the wipes may be provided in tub containers having a dispensing aperture. In both cases this allows easy transportation and storage of the wipes.
  • the wipes are packaged in a plastic foil in order to protect the wet wipes prior to use.
  • the lotion comprises at least one component which is readily volatile under normal room temperature and pressure conditions.
  • the wet wipe packaging such as a dispensing box or flow wrap
  • the volatile components of the lotion can readily evaporate and thereby reduce the overall amount of lotion present in the wipe stack.
  • the problem of uneven distribution of the lotion throughout the stack of wipes is further exacerbated once the packaging is opened. Obviously, the lotion on the top of the stack will more easily evaporate than the lotion from the bottom of the stack and thus top wipes may become dry. Moreover, certain components of the lotion will be more readily evaporated that other components.
  • the composition of the lotion will not remain constant once the packaging has been opened and hence the performance of the lotion cannot be guaranteed.
  • wipes designed to provide disinfecting and antibacterial benefits by the presence of certain volatile components in the lotion will not necessarily provide optimum performance in use due to the absence of at least percentage of these components from the lotion due to evaporation.
  • Yet another problem that is related to the evaporation of the volatile components of the lotion concerns the resulting change in intensity and odour note of the lotion due to the evaporation process. Indeed depending on the conditions and the degree of volatility of the components the odour of the product can change considerably. Such a variation in odour of the lotion is of course completely unacceptable to consumers. Indeed, consumers are in general highly sensitive to the odour of such products, particularly if they are to be utilised on a delicate or sensitive area of the body, to such an extent that even despite the presence of improved cleaning performance benefits provided by the product for example.
  • wet wipe stacking configuration which is suitable for multiple applications such as baby wipes, which are strong, soft, absorbent and provide improved cleaning. It is further desirable to provide wet wipes whereby the loss of volatile components of the lotion by evaporation is reduced particularly once the package has been opened.
  • the present invention addresses these problems by providing a stack of wet wipes having inert hydrophobic layers, which are preferably liquid impermeable, inserted in between the wipes throughout the stack. In this manner the evaporation of the volatile lotion components can be significantly reduced.
  • the present invention hence relates to a wet wipe for wiping parts of the human body such as baby wipes and other inanimate surfaces.
  • the present invention relates to a stack of wet wipes, each of said wipes comprising a substrate and a liquid composition, characterised in that said liquid composition comprises at least one volatile component as defined herein and said stack further comprises at least one anti evaporation layer to prevent the evaporation of said volatile component.
  • Figure 1 Is a cross sectional schematic illustration of a stack of folded wipes in a container comprising anti evaporation layers.
  • Figure 2a Is a perspective view showing a folded wipe having a leading edge panel 9, a central panel 8 and a trailing edge panel 10 in a Z fold configuration.
  • Figure 2b Is a perspective view showing a preferred folded wipe configuration.
  • Figure 2c Is a cross sectional illustration of a folded wipe having a lip 36 on the leading edge panel.
  • the wet wipe comprises a substrate which is coated or impregnated with a liquid composition.
  • the substrate may be woven or nonwoven, foam, sponge, battings, balls, puffs or films, most preferably a nonwoven and may be composed or natural or synthetic fibres or mixtures thereof.
  • the fibre compositions are a mixed of hydrophilic fibre material such as viscose, cotton, or flax and a hydrophobic fibre material such as polyethylene tetraphthalate (PET) or polypropylene (PP) in a ratio of 10%-90% hydrophilic and 90%-10% hydrophobic material by weight.
  • PET polyethylene tetraphthalate
  • PP polypropylene
  • compositions are 50% viscose, 50%PP; and 50% viscose, 50 % PET; and 70% cellulose, 15% PET and 15% latex.
  • the substrate preferably has a basis weight of at least 20 gm-2 and preferably less than 150gm ⁇ 2, and most preferably the base weight is in the range of 20 gm ⁇ 2 to 100 gm"2, more preferably from 50 grrr 2 to 95 gm-2.
  • the substrate may have any caliper. Typically, when the substrate is made by an air laying process, the average substrate caliper is less than 1.0 mm. More preferably the average caliper of the substrate is from 0.1 mm to 0.9 mm. The substrate caliper is measured according to standard EDANA non woven industry methodology, reference method # 30.4-89.
  • the substrate can have other components or materials added thereto as known in the art.
  • the types of additives desirable will be dependent upon the particular end use of the substrate contemplated. For example, in wet wipe products such as moist toilet paper, paper towels, facial tissues, baby wipes and other similar air laid products, high wet strength is a desirable attribute. Thus, it is often desirable particularly for cellulose based substrates to add chemical substances known in the art as wet strength resins.
  • wet strength resins A general dissertation on the types of wet strength resins utilised in the paper art can be found in TAPPI monograph series No. 29, Wet Strength in Paper and Paperboard, Technical Association of the Pulp and Paper Industry (New York, 1965).
  • Particularly preferred resins are polyamide-epichlorohydrin, polyacrylamides, styrene-butiene latexes, dialdehyde starch and mixtures thereof.
  • wet strength additives it can also be desirable to include certain dry strength and lint control additives known in the art such as starch binders.
  • the substrate may also comprise agents to improve the optical characteristics of the substrate material such as opacifying agents, for example titanium dioxide.
  • the substrate may be produced by any methods known in the art.
  • nonwoven substrates can be formed by dry forming techniques such as air-laying or wet laying such as on a paper making machine.
  • Other nonwoven manufacturing techniques such as melt blown, spun bonded, needle punched and spun laced methods may also be used.
  • a preferred method is air laying.
  • the wipes are provided in a stacked configuration which may comprise any number of wipes.
  • the stack comprises from 3 to 150, more preferably from 5 to 100, most preferably from 10 to 60 of wipes.
  • the wipes may be provide in any configuration folded on unfolded. Most preferably the wipes are stacked in a folded configuration.
  • figure 1 is a cross sectional illustration of a stack of folded wipes 23 in a container 20.
  • the container 20 includes a tub portion 21 and a lid 22, pivotably joined to the tube portion, by for example a hinge mechanism.
  • the wipes can be stacked and then packaged in a moisture impervious wrapper, such as a foil or polymeric film wrapper, to provide a refill package for use in refilling the container.
  • Each folded wipe 1 extends lengthwise in the machine direction from a first, leading end edge 2, to a second, trailing end edge 3.
  • the folded webs also have side edges 4 and 5 which extend lengthwise from the first leading end edge 2 to the second trailing end edge 3.
  • Each folded wipe 1 can include a first panel fold 6 which is generally parallel to the leading edge 2, and which is generally perpendicular to the side edges 4, 5.
  • the first panel fold 6 is spaced lengthwise from the leading edge 2 to provide a leading edge panel 9 extending between the first panel fold 6 and the leading edge 2.
  • a panel is a portion of the wipe extending between two folds, or between a fold and an edge end.
  • the folded wipe can also include a second panel fold 7, and a first central panel 8, and a trailing edge panel 10.
  • the second panel fold 7 is generally parallel to, and spaced lengthwise from, the first panel fold 6.
  • the first central panel 8 is joined to the leading edge panel 9, at the first panel fold 6, and extends between the first panel fold 6 and the second panel fold 7.
  • the trailing edge panel 10 is joined to the first central panel 8 at the second panel fold 7.
  • the trailing edge panel 10 extends between the second panel fold 7 and the trailing end edge 3.
  • the wipe is folded at the first and second panel folds
  • FIG. 6 and 7 to provide the leading edge panel 9, first central panel 8, and trailing edge panel 10, in a Z-fold configuration, as best seen in Figure 2a.
  • panel 9 is adjacent to and overlies a portion of panel 8
  • panel 10 is adjacent to and underlies a portion of panel 8.
  • FIG. 2b A preferred folded configuration is shown in Figure 2b which comprises a second central panel 11 provided by a third panel fold 12.
  • the wipe may have additional panels.
  • the leading edge panel and or the trailing edge panel may also be provided with an additional fold so as to provide a leading edge panel lip 36 or a trailing edge panel lip as seen in Figure 2c.
  • Such a lip is formed by providing the leading edge panel or the trailing edge panel with a panel lip fold which is adjacent to and spaced from the leading or trailing edge of the folded substrate to provide a lip extending between the panel lip fold and the end edge.
  • the panel lip fold may be folded onto the lower surface of the leading edge panel such that the leading end edge is below the leading edge end panel. This configuration is particularly beneficial in facilitating grasping of the edge.
  • the leading edge panel may be folded such that the leading end edge rests on the upper surface of the leading edge panel.
  • the lip may also be positioned on the upper or lower surface of the trailing edge panel.
  • the folded wipes 1 are non-interfolded in the stack 23, so that each folded wipe 1 can be dispensed from the container 20 without disturbing the adjacent, underlying folded wipe 1.
  • a panel such as panel 10 on one folded wipe 1 , could be interleaved between panels 9 and 8 of an adjacent, underlying folded wipe.
  • the wipes are stacked in groups of discrete folded wipes. Multiple stacks of the discrete folded wipe can then be combined one on top of the other to provide a stack. The number of wipes in a discrete stack and the combination of stacks can be varied as required and depending on the container with which they are to be combined.
  • each folded wipe 1 (as shown in Figure 2b) can have an unfolded length of from 10 cm to 40 cm as measured lengthwise from the leading end edge 2 to the trailing end edge 3 and a width of from 10cm to 25cm.
  • the lengths of the leading edge panel 9 and trailing edge panel 10 can be from 2 cm to 7 cm.
  • the spacing between the first panel fold 6 and the leading end edge 2 and the second panel fold 7 and the trailing edge 3 is preferably from 3 cm to 6.
  • the spacing between the first panel fold 6 and the third panel fold 12 and the second panel fold 7 and the third panel fold 12 are preferably from 3 cm to 12 cm, and more preferably between about 8 cm and 12 cm.
  • the substrate material of the wipes is typically impregnated or coated with a liquid composition.
  • the composition may be aqueous, alcohol based or an emulsion, either a water-in-oil or a oil-in-water or a multiple emulsion, preferably the emulsion is a oil-in-water emulsion.
  • the liquid composition comprises as an essential component at least one volatile component.
  • the liquid composition comprises at least one volatile component, but may comprise any number of volatile components as required.
  • Said volatile component or components may comprise from 0.005% to 40%, preferably from 0.01 % to 20%, most preferably from 0.2% to 12% by weight of the total liquid composition of said volatile components.
  • volatile liquid refers to a liquid which has a vapour pressure of equal or greater than 17.5mm of mercury at 20°C.
  • any liquid component or components of the liquid composition utilised for the wet wipe may meet this volatility requirement as defined hereinabove.
  • these liquid components are solvents, perfumes, plant extracts, alcohols, ethers, acids aldehydes amines, essential oils and mixtures thereof.
  • Suitable volatile components typically utilised in said composition are alcohols, such as ethyl alcohol, isopropyl alcohol, allyl alcohol, acetaldehyde, formic aid, isopentylamine, butyl ethyl ether, butylamine and mixtures thereof.
  • the present of at least one anti evaporation layer inserted in between the wipes considerably reduces the evaporation of said volatile components from the composition applied to the wipes, particularly once the packaging has been opened.
  • the anti evaporation layers are typically inert, preferably hydrophobic layers which are typically prepared from material such as polypropylene and polyethylene. Preferably said layers are polyethylene.
  • the anti evaporation layers 24, may be provided in any desirable colour.
  • the layers are provided in a different colour to that of the wet wipes themselves such that the consumer can readily identify the layers from the wipes.
  • the anti-evaporation layers 24 are provided as transparent layers in order to enable the consumer to establish whether there are wipes remaining in the packaging.
  • the layers may also be provided with a visual or tactile signal such as embossing or printing to assist the consumer in the identification of the presence of an anti evaporation layer 24.
  • the anti evaporation layers 24, of the present invention may have any shape or size. Preferably, they are of similar shape and size to the wipe, in their folded configuration, and more preferably they are of substantially identical size of the folded wipe. Alternatively, the anti-evaporation layers 24, may be provided in dimensions greater than that of the folded wipes such that the layers extend over the length and width of the folded wipes and thereby create an additional sealing effect along the side edges of the stack of wipes.
  • the anti evaporation layers 24, are preferably provided as thin layers having a thickness of less than lOOmicrometers mm, preferably less than 80 micrometers, more preferably less than 70 micrometers.
  • the anti evaporation layers 24, may be inserted anywhere within the stack and are preferably inserted at regular intervals, preferably at a ratio of wipes to anti evaporation layer of from 1 :1 to 50:1 , preferably from 3:1 to 30:1 , most preferably from 5:1 to 10:1. Most preferably the uppermost wipe on the stack of wipes is covered by an anti evaporation layer 24.
  • the composition will comprise from 2% to 50% by weight of said composition of actives and from 50% to 98% water, preferably de-ionised or distilled.
  • active component preferably 2% to 20% are present in the oil phase and the remainder are present in the aqueous phase.
  • the liquid composition can provide a number of different benefits when released. For example, in wet-like cleaning wipes for perianal cleaning water component is released and thereby provides the primary cleansing action for these wipes.
  • the liquid composition (preferably comprising water as a major constituent) comprises a disinfecting component comprising an antimicrobial compound, preferably an essential oil or an active thereof, and a bleach, preferably a peroxygen bleach.
  • a disinfecting component comprising an antimicrobial compound, preferably an essential oil or an active thereof
  • a bleach preferably a peroxygen bleach.
  • effective disinfecting performance it is meant herein that the disinfecting wipes of the present invention allow significant reduction in the amount of bacteria on an infected surface. Indeed, effective disinfecting may be obtained on various micro-organisms including Gram positive bacteria like Staphylococcus aureus, and Gram negative bacteria like Pseudomonas aeruginosa, as well as on more resistant micro-organisms like fungi (e.g., Candida albicans) present on infected surfaces.
  • fungi e.g., Candida albicans
  • Another advantage of the disinfecting wipes according to the present invention is that besides the disinfecting properties delivered, good cleaning is also provided as the disinfecting polar phase may further comprise surfactants and/or solvents.
  • An essential element of such disinfecting liquid compositions is an antimicrobial compound typically selected from the group consisting of an essential oil and an active thereof, paraben (e.g., methyl paraben, ethyl paraben), glutaraldehyde and mixtures thereof.
  • paraben e.g., methyl paraben, ethyl paraben
  • glutaraldehyde e.g., glutaraldehyde
  • Essential oils or actives thereof are the preferred antimicrobial compounds to be used herein.
  • Suitable essential oils or actives thereof to be used herein are those essential oils which exhibit antimicrobial activity and more particularly antibacterial activity.
  • actives of essential oils it is meant herein any ingredient of essential oils that exhibits antimicrobial/antibacterial activity.
  • a further advantage of said essential oils and actives hereof is that they impart pleasant odour to the disinfecting wipes according to the present invention without the need of adding a perfume. Indeed, the disinfecting wipes according to the present invention deliver not only excellent disinfecting performance on infected surfaces but also good scent.
  • Such essential oils include, but are not limited to, those obtained from thyme, lemongrass, citrus, lemons, oranges, anise, clove, aniseed, cinnamon, geranium, roses, mint, lavender, citronella, eucalyptus, peppermint, camphor, sandalwood and cedar and mixtures thereof.
  • Actives of essential oils to be used herein include, but are not limited to, thymol (present for example in thyme), eugenol (present for example in cinnamon and clove), menthol (present for example in mint), geraniol (present for example in geranium and rose), verbenone (present for example in vervain), eucalyptol and pinocarvone (present in eucalyptus), cedrol (present for example in cedar), anethol (present for example in anise), carvacrol, hinokitiol, berberine, terpineol, limonene, methyl salycilate and mixtures thereof.
  • Preferred actives of essential oils to be used herein are thymol, eugenol, verbenone, eucalyptol, carvacrol, limonene and/or geraniol.
  • Thymol may be commercially available for example from Aldrich
  • eugenol may be commercially available for example from Sigma, Systems - Bioindustries (SBI) - Manheimer Inc.
  • the antimicrobial compound or mixtures thereof will be present in the liquid composition at a level of from 0.001% to 5%, preferably from 0.001% to 3%, more preferably from 0.005% to 1%, by weight of liquid composition.
  • An important element of the internal disinfecting polar phase is a bleach or mixtures thereof. Any bleach known to those skilled in the art may be suitable to be used herein including any chlorine bleach as well as any peroxygen bleach.
  • the presence of the bleach, preferably the peroxygen bleach, in the disinfecting wipes of the present invention contribute to the disinfecting properties of the wipes.
  • Suitable chlorine bleaches to be used herein include any compound capable of releasing chlorine when said compound is in contact with water.
  • Suitable chlorine bleaches include alkali metal dichloroisocyanurates as well as alkali metal hypohalites like hypochlorite and/or hypobromite.
  • Preferred chlorine bleaches are alkali metal hypochlorites.
  • Various forms of alkali metal hypochlorite are commercially available, for instance sodium hypochlorite.
  • Preferred bleaches for use herein are peroxygen bleaches, more particularly hydrogen peroxide, or a water soluble source thereof, or mixtures thereof. Hydrogen peroxide is particularly preferred.
  • Peroxygen bleaches like hydrogen peroxide are preferred herein as they are generally well accepted from an environmental point of view.
  • the decomposition products of hydrogen peroxide are oxygen and water.
  • a hydrogen peroxide source refers to any compound which produces perhydroxyl ions when said compound is in contact with water.
  • Suitable water-soluble sources of hydrogen peroxide for use herein include percarbonates, persilicates, persulphates such as monopersulfate, perborates, peroxyacids such as diperoxydodecandioic acid (DPDA), magnesium perphthalic acid, dialkylperoxides, diacylperoxides, performed percarboxylic acids, organic and inorganic peroxides and/or hydroperoxides and mixtures thereof.
  • DPDA diperoxydodecandioic acid
  • magnesium perphthalic acid dialkylperoxides
  • diacylperoxides performed percarboxylic acids, organic and inorganic peroxides and/or hydroperoxides and mixtures thereof.
  • the bleach or mixtures thereof is present at a level of from 0.001 % to 15% by weight of the liquid composition, preferably from 0.001 % to 5%, and more preferably from 0.005% to 2%.
  • the liquid composition may further comprise a detersive surfactant or a mixture thereof.
  • a detersive surfactant or a mixture thereof is present at a level of from 0.001% to 40% by weight of the total internal polar phase, preferably from 0.01 % to 10% and more preferably from 0.05% to 2%.
  • Suitable detersive surfactants to be used in the present invention include any surfactant known to those skilled in the art like nonionic, anionic, cationic, amphoteric and/or zwitterionic surfactants.
  • Preferred detersive surfactants to be used herein are the amphoteric and/or zwitterionic surfactants.
  • Suitable amphoteric detersive surfactants to be used herein include amine oxides of the formula R 1 R 2 R3NO, wherein each of R 1 , R 2 and R 3 is independently a saturated, substituted or unsubstituted, linear or branched hydrocarbon chain having from 1 to 30 carbon atoms.
  • Preferred amine oxide surfactants to be used according to the present invention are amine oxides of the formula R1 R2R3NO, wherein Rl is an hydrocarbon chain having from 1 to 30 carbon atoms, preferably from 6 to 20, more preferably from 8 to 16, most preferably from 8 to 12, and wherein R2 and R3 are independently substituted or unsubstituted, linear or branched hydrocarbon chains having from 1 to 4 carbon atoms, preferably from 1 to 3 carbon atoms, and more preferably are methyl groups.
  • R ⁇ may be a saturated, substituted or unsubstituted, linear or branched hydrocarbon chain.
  • Suitable amine oxides for use herein are for instance natural blend C-8-C- ⁇ o amine oxides as well as C12- 16 amine oxides commercially available from Hoechst. Amine oxides are preferred herein as they deliver effective cleaning performance and further participate to the disinfecting properties of the disinfecting wipes herein.
  • Suitable zwitterionic surfactants to be used herein contain both cationic and anionic hydrophilic groups on the same molecule at a relatively wide range of pH's.
  • the typical cationic group is a quaternary ammonium group, although other positively charged groups like phosphonium, imidazolinium and sulfonium groups can be used.
  • the typical anionic hydrophilic groups are carboxylates and sulfonates, although other groups such as sulfates, phosphonates, and the like can be used.
  • a generic formula for some zwitterionic surfactants to be used herein is
  • R1 -N+(R2)(R3)R4 X wherein R ⁇ is a hydrophobic group; R2 and R3 are each C1-C4 alkyl, hydroxy alkyl or other substituted alkyl group which can also be joined to form ring structures with the N; R4 is a moiety joining the cationic nitrogen atom to the hydrophilic group and is typically an alkylene, hydroxy alkylene, or polyalkoxy group containing from 1 to 10 carbon atoms; and X is the hydrophilic group which is preferably a carboxylate or sulfonate group.
  • Preferred hydrophobic groups R1 are alkyl groups containing from 1 to 24, preferably less than 18, more preferably less than 16 carbon atoms.
  • the hydrophobic group can contain unsaturation and/or substituents and/or linking groups such as aryl groups, amido groups, ester groups and the like.
  • substituents and/or linking groups such as aryl groups, amido groups, ester groups and the like.
  • simple alkyl groups are preferred for cost and stability reasons.
  • Highly preferred zwitterionic surfactants include betaine and sulphobetaine surfactants, derivatives thereof or mixtures thereof. Said betaine or sulphobetaine surfactants are preferred herein as they help disinfecting by increasing the permeability of the bacterial cell wall, thus allowing other active ingredients to enter the cell.
  • betaine or sulphobetaine surfactants are particularly suitable for the cleaning of delicate surfaces, e.g., hard surfaces in contact with food and/or babies. Betaine and sulphobetaine surfactants are also extremely mild to the skin and/or surfaces to be treated.
  • Suitable betaine and sulphobetaine surfactants to be used herein are the betaine/sulphobetaine and betaine-like detergents wherein the molecule contains both basic and acidic groups which form an inner salt giving the molecule both cationic and anionic hydrophilic groups over a broad range of pH values.
  • Some common examples of these detergents are described in U.S. Pat. Nos. 2,082,275, 2,702,279 and 2,255,082, incorporated herein by reference.
  • Preferred betaine and sulphobetaine surfactants herein are according to the formula
  • R1 is a hydrocarbon chain containing from 1 to 24 carbon atoms, preferably from 8 to 18, more preferably from 12 to 14, wherein R2 and R3 are hydrocarbon chains containing from 1 to 3 carbon atoms, preferably 1 carbon atom, wherein n is an integer from 1 to 10, preferably from 1 to 6, more preferably is 1 , Y is selected from the group consisting of carboxyl and sulfonyl radicals and wherein the sum of R " 1 , R2 and R3 hydrocarbon chains is from 14 to 24 carbon atoms, or mixtures thereof.
  • betaine surfactants include C12-C18 alkyl dimethyl betaine such as coconut-betaine and C ⁇ Q-C ⁇ Q alkyl dimethyl betaine such as laurylbetaine.
  • coconutbetaine is commercially available from Seppic under the trade name of Amonyl 265".
  • Laurylbetaine is commercially available from Albright & Wilson under the trade name Empigen BB/L".
  • each R ⁇ is a hydrocarbon, e.g. an alkyl group containing from 8 up to 20, preferably up to 18, more preferably up to 16 carbon atoms
  • each R 2 is either a hydrogen (when attached to the amido nitrogen), short chain alkyl or substituted alkyl containing from 1 to 4 carbon atoms, preferably groups selected from the group consisting of methyl, ethyl, propyl, hydroxy substituted ethyl or propyl and mixtures thereof, preferably methyl
  • each R3 is selected from the group consisting of hydrogen and hydroxy groups and each n is a number from 1 to 4, preferably from 2 to 3, more preferably 3, with no more than one hydroxy group in any (C(R3)2) moiety.
  • the R ⁇ groups can be branched and/or unsaturated.
  • the R2 groups can also be connected to form ring structures.
  • a surfactant of this type is a C ⁇
  • Suitable nonionic surfactants to be used herein are fatty alcohol ethoxylates and/or propoxylates which are commercially available with a variety of fatty alcohol chain lengths and a variety of ethoxylation degrees. Indeed, the HLB values of such alkoxylated nonionic surfactants depend essentially on the chain length of the fatty alcohol, the nature of the alkoxylation and the degree of alkoxylation. Surfactant catalogues are available which list a number of surfactants, including nonionics, together with their respective HLB values.
  • nonionic surfactants Particularly suitable for use herein as nonionic surfactants are the hydrophobic nonionic surfactants having an HLB (hydrophilic-lipophilic balance) below 16 and more preferably below 15. Those hydrophobic nonionic surfactants have been found to provide good grease cutting properties.
  • HLB hydrophilic-lipophilic balance
  • Preferred nonionic surfactants for use herein are nonionic surfactants according to the formula RO-(C2H4 ⁇ ) n (C3H6 ⁇ ) m H, wherein R is a CQ to C22 alkyl chain or a Cg to C28 alkyl benzene chain, and wherein n+m is from 0 to 20 and n is from 0 to 15 and m is from 0 to 20, preferably n+m is from 1 to 15 and, n and m are from 0.5 to 15, more preferably n+m is from 1 to 10 and, n and m are from 0 to 10.
  • the preferred R chains for use herein are the C ⁇ to C22 alkyl chains.
  • 2 and C-13 alkyl chains, n is 3 and m is 0), or Dobanol R 23-2 (HLB 6.2; R is a mixture of C12 and C13 alkyl chains,
  • Preferred herein are Dobanol R 91-2.5, or Lutensol R T03, or Lutensol R A03, or Tergitol R 25L3, or Dobanol R 23-3, or Dobanol R 23-2, or Dobanol R 23-10, or mixtures thereof.
  • DobanolR surfactants are commercially available from SHELL. LutensolR surfactants are commercially available from BASF and the Tergitol R surfactants are commercially available from UNION CARBIDE.
  • Suitable anionic surfactants to be used herein include water soluble salts or acids of the formula ROSO3M wherein R is preferably a C6-C24 hydrocarbyl, preferably an alkyl or hydroxyalkyl having a C8-C20 alkyl component, more preferably a C ⁇ -C-i ⁇ alkyl or hydroxyalkyl, and M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium), or ammonium or substituted ammonium (e.g., methyl-, dimethyl-, and trimethyl ammonium cations and quaternary ammonium cations, such as tetramethyl-ammonium and dimethyl piperdinium cations and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof, and the like).
  • R is preferably a C
  • anionic surfactants to be used herein include alkyl-diphenyl- ether-sulphonates and alkyl-carboxylates.
  • Other anionic surfactants can include salts (including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts) of soap, C9-C20 linear alkylbenzenesulfonates, C8-C22 primary or secondary alkanesulfonates, C8-C24 olefinsulfonates, sulfonated polycarboxylic acids prepared by sulfonation of the pyrolyzed product of alkaline earth metal citrates, e.g., as described in British patent specification No. 1 ,082,179, C8-C24 alkylpolyglycolethersulfates
  • alkyl ester sulfonates such as C-j4_
  • acyl glycerol sulfonates 16 methyl ester sulfonates; acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, paraffin sulfonates, alkyl phosphates, isethionates such as the acyl isethionates, N-acyl taurates, alkyl succinamates and sulfosuccinates, monoesters of sulfosuccinate (especially saturated and unsaturated C-12-C 8 monoesters) diesters of sulfosuccinate (especially saturated and unsaturated C5-C14 diesters), acyl sarcosinates, sulfates of alkylpolysaccharides such as the sulfates of alkylpolyglucoside (the nonionic nonsulfated compounds being described below), branched primary al
  • Resin acids and hydrogenated resin acids are also suitable, such as rosin, hydrogenated rosin, and resin acids and hydrogenated resin acids present in or derived from tall oil. Further examples are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch). A variety of such surfactants are also generally disclosed in U.S. Patent 3,929,678, issued December 30, 1975 to Laughlin, et al. at Column 23, line 58 through Column 29, line 23 (herein incorporated by reference).
  • Preferred anionic surfactants for use herein are the alkyl benzene sulfonates, alkyl sulfates, alkyl alkoxylated sulfates, paraffin sulfonates and mixtures thereof.
  • the internal disinfecting polar phase according to the present invention has a pH of from 1 to 12, preferably from 1.5 to 10, and more preferably from 2 to 9.
  • the pH can be adjusted by using alkalinizing agents or acidifying agents.
  • alkalinizing agents are alkali metal hydroxides, such as potassium and/or sodium hydroxide, or alkali metal oxides such as sodium and/or potassium oxide.
  • acidifying agents are organic or inorganic acids such as citric or sulfuric acid.
  • Solvents may be present in the liquid composition according to the present invention. These solvents will, advantageously, give an enhanced cleaning to the disinfecting wipes of the present invention.
  • Suitable solvents for incorporation herein include propylene glycol derivatives such as n-butoxypropanol or n- butoxypropoxypropanol, water-soluble CARBITOL, solvents or water-soluble
  • Water-soluble CARBITOL solvents are compounds of the 2-(2-alkoxyethoxy)ethanol class wherein the alkoxy group is derived from ethyl, propyl or butyl.
  • a preferred water-soluble carbitol is 2-(2- butoxyethoxy)ethanol also known as butyl carbitol.
  • Water-soluble CELLOSOLVE, solvents are compounds of the 2-alkoxyethoxyethanol class, with 2- butoxyethoxyethanol being preferred.
  • solvents are benzyl alcohol, methanol, ethanol, isopropyl alcohol and diols such as 2-ethyl-1 ,3-hexanediol and 2,2,4-trimethyl-1 ,3-pentanediol and mixture thereof.
  • Preferred solvents for use herein are n-butoxypropoxypropanol, butyl carbitol, and mixtures thereof.
  • a most preferred solvent for use herein is butyl carbitol,.
  • the liquid composition may further comprise other optional ingredients including radical scavengers, chelating agents, thickeners, builders, buffers, stabilizers, bleach activators, soil suspenders, dye transfer agents, brighteners, anti dusting agents, enzymes, dispersant, dye transfer inhibitors, pigments, perfumes, and dyes and the like.
  • Suitable radical scavengers for use herein include the well-known substituted mono and di hydroxy benzenes and derivatives thereof, alkyl- and aryl carboxylates and mixtures thereof.
  • Preferred radical scavengers for use herein include di-tert-butyl hydroxy toluene (BHT), p-hydroxy-toluene, hydroquinone (HQ), di-tert-butyl hydroquinone (DTBHQ), mono-tert-butyl hydroquinone (MTBHQ), tert-butyl-hydroxy anysole, p-hydroxy-anysol, benzoic acid, 2,5-dihydroxy benzoic acid, 2,5-dihydroxyterephtalic acid, toluic acid, catechol, t-butyl catechol, 4-allyl-catechol, 4-acetyl catechol, 2-methoxy-phenol, 2-ethoxy-phenol, 2-methoxy-4-(2-propenyl)phenol, 3,4-d
  • the radical scavenger, or a mixture thereof is present in the liquid composition up to a level of 5% by weight, preferably from 0.001% to 3% by weight, and more preferably from 0.001% to 1.5%.
  • Suitable chelating agents to be used herein may be any chelating agent known to those skilled in the art such as the ones selected from the group consisting of phosphonate chelating agents, amino carboxylate chelating agents or other carboxylate chelating agents, or polyfunctionally-substituted aromatic chelating agents and mixtures thereof.
  • Such phosphonate chelating agents may include etidronic acid (1- hydroxyethylidene-bisphosphonic acid or HEDP) as well as amino phosphonate compounds, including amino alkylene poly (alkylene phosphonate), alkali metal ethane 1 -hydroxy diphosphonates, nitrilo trimethylene phosphonates, ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates.
  • the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
  • Preferred phosphonate chelating agents to be used herein are diethylene triamine penta methylene phosphonates. Such phosphonate chelating agents are commercially available from Monsanto under the trade name DEQUEST.
  • Polyfunctionally-substituted aromatic chelating agents may also be useful herein. See U.S. Patent 3,812,044, issued May 21 , 1974, to Connor et al. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1 ,2-dihydroxy -3,5-disulfobenzene.
  • a preferred biodegradable chelating agent for use herein is ethylene diamine N,N'- disuccinic acid, or alkali metal, or alkaline earth, ammonium or substitutes ammonium salts thereof or mixtures thereof.
  • Ethylenediamine N,N'- disuccinic acids especially the (S,S) isomer have been extensively described in US patent 4, 704, 233, November 3, 1987 to Hartman and Perkins.
  • Ethylenediamine N,N'- disuccinic acid is, for instance, commercially available under the tradename ssEDDS, from Palmer Research Laboratories.
  • Suitable amino carboxylate chelating agents useful herein include ethylene diamine tetra acetate, diethylene triamine pentaacetate, diethylene triamine pentaacetate (DTPA), N-hydroxyethylethylenediamine triacetate, nitrilotri-acetate, ethylenediamine tetraproprionate, triethylenetetraaminehexa-acetate, ethanoldiglycine, propylene diamine tetracetic acid (PDTA) and methyl glycine di- acetic acid (MGDA), both in their acid form, or in their alkali metal, ammonium, and substituted ammonium salt forms.
  • DTPA diethylene triamine pentaacetate
  • DTPA diethylene triamine pentaacetate
  • N-hydroxyethylethylenediamine triacetate N-hydroxyethylethylenediamine triacetate
  • nitrilotri-acetate nitrilotri-acetate
  • DTPA diethylene triamine penta acetic acid
  • PDTA propylene diamine tetracetic acid
  • MGDA methyl glycine di-acetic acid
  • carboxylate chelating agents to be used herein includes malonic acid, salicylic acid, glycine, aspartic acid, glutamic acid, dipicolinic acid and derivatives thereof, or mixtures thereof.
  • the chelating agent, or a mixture thereof is present in the liquid composition at a level of from 0.001% to 5% by weight, preferably from 0.001% to 3% by weight and more preferably from 0.001% to 1.5%.
  • the disinfecting wipes according to the present invention are suitable for disinfecting various surfaces including animate surfaces (e.g. human skin) as well as inanimate surfaces including any hard-surfaces.
  • thickeners and viscosity modifiers include polyacrylic and hydrophobically modified polyacrylic resins such as Carbopol and Pemulen, starches such as corn starch, potato starch, tapioca, gums such as guar gum, gum arabic, cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, and the like. These thickeners and viscosity modifiers will typically be included in a concentration in the range of from about 0.05 to about 0.5% of the liquid composition.
  • water- soluble or dispersible materials that can be present in the internal phase include polycationic polymers to provide steric stabilization at the polar phase-lipid phase interface and nonionic polymers that also stabilize the emulsion.
  • Suitable polycationic polymers include Reten 201, Kymene® 557H and Acco 711.
  • Suitable nonionic polymers include polyethylene glycols (PEG) such as Carbowax and poly(propylene glycol) butyl ether. These polycationic and nonionic polymers will typically be included in a concentration in the range of from about 0.05 to about 1.0% of the liquid composition.
  • the composition may be aqueous, alcohol based or an emulsion, either a water-in-oil or an oil-in-water or a multiple emulsion, preferably the emulsion is a oil-in-water emulsion.
  • the composition will comprise from 2% to 50% by weight of said composition of actives and from 50% to 98% water, preferably de-ionised or distilled. Of the active component, preferably 2% to 20% are present in the oil phase and the remainder are present in the aqueous phase.
  • the wet wipes are provided with an emulsion composition
  • a oil phase in the range of 1% to 20%, preferably 2% to 10%, by weight of the composition.
  • the oil based phase is derived from natural resources such as from vegetable or animal oils or may be synthetic or any mixtures thereof.
  • Suitable vegetable and animal oils for use herein include waxes such as beeswax, lanolin, candelilla, and oils such as glycerine esters and glycerine ethers, fatty acid alcohols, fatty acid esters and fatty acid ethers such as caprylic and capric triglycerides and octylpalmitate.
  • Suitable mineral oils include petroleum based oils such as paraffin and petroleum jelly.
  • Synthetic oils for use herein include ethylenic polymers for example polyethylene wax or silicone based oils.
  • Suitable silicon oils include polydimethylsiloxanes, volatile cyclomethicones, dimethiconols, siloxysilicates and amino- and phenyl derivatives of siloxanes and mixtures thereof.
  • Examples include dimethicone (Dow Corning 200 Fluids), cyclomethicone and dimethiconol (Dow Corning 1401 Fluid), cetyl dimethicone (Dow Corning 2502 Fluid), dimethicone and trimethylsiloxysilicate (Dow Corning 593 Fluid), cyclomethicone (Dow Corning 244, 245, 344 or 345 Fluid), phenyl trimethicone (Dow Corning 556 Fluid), or combinations thereof.
  • the oil-in-water emulsions typically require emulsifying agents.
  • the emulsifying agents which may be used in the present invention are preferably capable of primary emulsification of oil-in-water emulsions.
  • the emulsifying agent is present in the range of 0.02% to 5.0%, preferably 0.02% to 3.0%, by weight of the composition.
  • the emulsifying agent is a polymeric type of emulsifying agent such as a copolymer of C10-C30 alkyl acrylates and one or more monomers of acrylic acid, methylacrylic acid or one of their simple esters cross linked with an allyl ether of sucrose or an allyl ether of pentaerythritol.
  • the emulsifying agents which are thus useful in the present invention include Ceteareth-12, Ceteareth-20 or Pemulen TR1 and TR2 which are available from B.F. Goodrich company of the USA.
  • emulsifying agents such as ethoxylated fatty alcohols, glycerine esters of fatty acids, soaps, sugar derived agents are also suitable for use herein.
  • Other useful emulsifying agents include those disclosed in detail in EP-A-328 355.
  • the composition may comprise a stability agent or preservative.
  • Stability agents suitable for use herein include phenoxyethanol preferably present in the range of from 0.1 to 1.0%, sodium benzoate, potassium sorbate, methylparaben, propylparaben, ethylparaben, butylparaben, sodium benzoate, potassium sorbate, benzalkonium chloride, and disodium salt ethylenediamine tetraacetic acid (hereinafter referred to as EDTA) or other EDTA salts (sequestrenes).
  • EDTA disodium salt ethylenediamine tetraacetic acid
  • Sequestrene is a series of complexing agents and metal complexes general of ethylenediaminetetraacetic acid and salts.
  • the total quantity of stability agents should be in the range of 0.1% to 4.0% by weight of the composition.
  • the composition of the present invention may further comprise from 0.02% to 5.0% by weight of said composition of an emollient or moisturiser.
  • the emollient is water soluble and includes polyhydric alcohols, such as propylene glycol, glycerin, and also water soluble lanolin derivatives.
  • the composition is applied to at least one surface of the substrate material.
  • the composition can be applied at any time during the manufacture of the wet wipe.
  • the composition can be applied to the substrate after the substrate has been dried.
  • Any variety of application methods that evenly distribute lubricious materials having a molten or liquid consistency can be used. Suitable methods include spraying, printing, (e.g. flexographic printing), coating (e.g. gravure coating or flood coating) extrusion whereby the composition is forced through tubes in contact with the substrate whilst the substrate passes across the tube or combinations of these application techniques.
  • spraying the composition on a rotating surface such as calender roll that then transfers the composition to the surface of the substrate.
  • the composition can be applied either to one surface of the substrate or both surfaces, preferably both surfaces.
  • the preferred application method is extrusion coating.
  • the composition can also be applied uniformly or non uniformly to the surfaces of the substrate.
  • non uniform it is meant that for example the amount, pattern of distribution of the composition can vary over the surface of the substrate.
  • some of the surface of the substrate can have greater or lesser amounts of composition, including portions of the surface that do not have any composition on it.
  • the composition is uniformly applied to the surfaces of the wipes.
  • the composition is typically applied in an amount of from about 0.5 g to 10 g per gram of substrate, preferably from 1.0 g to 5 g per gram of substrate, most preferably from 2 g to 4 g per gram of dry substrate.
  • the composition can be applied to the substrate at any point after it has been dried.
  • the composition can be applied to the substrate prior to calendering or after calendering and prior to being wound up onto a parent roll.
  • the application will be carried out on a substrate unwound from a roll having a width equal to a substantial number of wipes it is intended to produce. The substrate with the composition applied thereto is then subsequently severed to produce individual wipes.
  • the carrier is a air laid nonwoven substrate comprising 70% pulp, 15% PET and 15% latex.
  • the substrate has a basis weight of 82g/m 2 .
  • a liquid composition is prepared from the ingredients shown in Table I.
  • the liquid composition prepared in step B is applied to the carrier by spraying.
  • the coated carrier is then perforated, folded and stacked. Anti evaporation layers are then inserted in-between every 5 wipes. The stack is then sealed to yield finished product wipe. After folding and sealing, the composition coats both internal sides of the to provide an article of the present invention.

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  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention a trait à des lingettes (1) humides servant à essuyer des surfaces domestiques ou industrielles, en plus de leur utilisation sur le corps humain comme lingettes pour bébé, démaquillant et pour d'autres applications de soins de la peau. Les lingettes (1) humides se présentent dans une configuration empilée améliorée qui comprend l'insertion d'au moins une couche (24) anti-évaporation dans la pile pour réduire l'évaporation des constituants volatils de la formulation de lotion, notamment après l'ouverture du conditionnement.
PCT/US1999/017556 1998-08-03 1999-08-03 Lingettes humides empilees comportant des couches anti-evaporation WO2000007490A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2000563178A JP2002522562A (ja) 1998-08-03 1999-08-03 蒸発防止層を有する積み重ねられた濡れワイプ
EP99938956A EP1102555A1 (fr) 1998-08-03 1999-08-03 Lingettes humides empilees comportant des couches anti-evaporation
AU53330/99A AU5333099A (en) 1998-08-03 1999-08-03 Stacked wet wipes having anti evaporation layers
CA002337867A CA2337867A1 (fr) 1998-08-03 1999-08-03 Lingettes humides empilees comportant des couches anti-evaporation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98114513.9 1998-08-03
EP98114513A EP0978247A1 (fr) 1998-08-03 1998-08-03 Lingettes humides en pile ayant des couches anti évaporation

Publications (1)

Publication Number Publication Date
WO2000007490A1 true WO2000007490A1 (fr) 2000-02-17

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JP (1) JP2002522562A (fr)
AU (1) AU5333099A (fr)
CA (1) CA2337867A1 (fr)
WO (1) WO2000007490A1 (fr)

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US6168848B1 (en) * 1999-10-07 2001-01-02 Paper Converting Machine Co. Stack comprising W-Z folded sheets
JP2002085289A (ja) * 2000-09-18 2002-03-26 Uni Charm Corp シート積層体
JP3730105B2 (ja) * 2000-10-04 2005-12-21 ユニ・チャーム株式会社 シート包装体
JP2002160781A (ja) * 2000-11-21 2002-06-04 Uni Charm Corp シート包装体
US6946413B2 (en) 2000-12-29 2005-09-20 Kimberly-Clark Worldwide, Inc. Composite material with cloth-like feel
US20020132543A1 (en) 2001-01-03 2002-09-19 Baer David J. Stretchable composite sheet for adding softness and texture
US7176150B2 (en) 2001-10-09 2007-02-13 Kimberly-Clark Worldwide, Inc. Internally tufted laminates
US8147473B2 (en) 2005-02-17 2012-04-03 The Procter & Gamble Company Folded fibrous structures
DE102006035570A1 (de) * 2006-07-26 2008-01-31 Cmc Consumer Medical Care Gmbh Anordnung scheibenförmiger Faserverbundartikel in einem Verpackungsbehältnis
EP1982689A1 (fr) * 2007-04-18 2008-10-22 The Procter and Gamble Company Nettoyage antimicrobien sans conservateur
US20100009145A1 (en) * 2008-07-14 2010-01-14 Joerg Mueller Lotion Gradient Ratio In Stack Of Wet Substrates
US8097326B2 (en) 2008-10-27 2012-01-17 Paper Converting Machine Company Stack comprising multi-folded four panel sheets and folding boards therefor
EP2414254B1 (fr) * 2009-03-31 2014-08-20 Kimberly-Clark Worldwide, Inc. Cartouches de recharge de mouchoirs en papier pliés
DE102020108639B3 (de) 2020-03-27 2021-08-12 Dr. Schumacher Gmbh Packung mit Tuchprodukten

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EP0978247A1 (fr) 2000-02-09
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EP1102555A1 (fr) 2001-05-30
AU5333099A (en) 2000-02-28

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