WO2000007048A1 - Long haul single mode waveguide - Google Patents
Long haul single mode waveguide Download PDFInfo
- Publication number
- WO2000007048A1 WO2000007048A1 PCT/US1999/016615 US9916615W WO0007048A1 WO 2000007048 A1 WO2000007048 A1 WO 2000007048A1 US 9916615 W US9916615 W US 9916615W WO 0007048 A1 WO0007048 A1 WO 0007048A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- range
- segment
- single mode
- radius
- segments
- Prior art date
Links
- 239000000835 fiber Substances 0.000 claims abstract description 33
- 239000006185 dispersion Substances 0.000 claims abstract description 29
- 230000003287 optical effect Effects 0.000 claims abstract description 14
- 230000010287 polarization Effects 0.000 claims abstract description 6
- 238000007373 indentation Methods 0.000 claims description 7
- 239000013307 optical fiber Substances 0.000 claims 8
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000009792 diffusion process Methods 0.000 description 6
- 230000009021 linear effect Effects 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 4
- 230000009022 nonlinear effect Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000006121 base glass Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000012821 model calculation Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/036—Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
- G02B6/03616—Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
- G02B6/03638—Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 3 layers only
- G02B6/03644—Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 3 layers only arranged - + -
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/12—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
- G02B6/122—Basic optical elements, e.g. light-guiding paths
- G02B6/125—Bends, branchings or intersections
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02004—Optical fibres with cladding with or without a coating characterised by the core effective area or mode field radius
- G02B6/02009—Large effective area or mode field radius, e.g. to reduce nonlinear effects in single mode fibres
- G02B6/02014—Effective area greater than 60 square microns in the C band, i.e. 1530-1565 nm
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02214—Optical fibres with cladding with or without a coating tailored to obtain the desired dispersion, e.g. dispersion shifted, dispersion flattened
- G02B6/02219—Characterised by the wavelength dispersion properties in the silica low loss window around 1550 nm, i.e. S, C, L and U bands from 1460-1675 nm
- G02B6/02252—Negative dispersion fibres at 1550 nm
- G02B6/02257—Non-zero dispersion shifted fibres, i.e. having a small negative dispersion at 1550 nm, e.g. ITU-T G.655 dispersion between - 1.0 to - 10 ps/nm.km for avoiding nonlinear effects
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02214—Optical fibres with cladding with or without a coating tailored to obtain the desired dispersion, e.g. dispersion shifted, dispersion flattened
- G02B6/02285—Characterised by the polarisation mode dispersion [PMD] properties, e.g. for minimising PMD
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/028—Optical fibres with cladding with or without a coating with core or cladding having graded refractive index
- G02B6/0286—Combination of graded index in the central core segment and a graded index layer external to the central core segment
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/036—Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
- G02B6/03605—Highest refractive index not on central axis
- G02B6/03611—Highest index adjacent to central axis region, e.g. annular core, coaxial ring, centreline depression affecting waveguiding
Definitions
- the invention is directed to a single mode optical waveguide fiber designed for long repeater spacing, high data rate telecommunication systems.
- the single mode waveguide combines excellent bend resistance, low attenuation, and large effective area, A eff , features that are desired for undersea applications.
- a waveguide having large effective area reduces non-linear optical effects, including self phase modulation, four wave mixing, cross phase modulation, and non-linear scattering processes, all of which can cause degradation of signals in high power systems.
- a mathematical description of these non-linear effects includes the ratio, P/A er f, where P is optical power.
- a non-linear optical effect can be described by an equation containing a term, exp [P x L e rf A eff ], where L e « is effective length.
- optical waveguides such as high strength, fatigue resistance, and bend resistance.
- high power is an optical power greater than about 10 mw.
- signal power levels of 1 mW or less are still sensitive to non-linear effects, so that A ⁇ f f is still an important consideration in such lower power systems.
- a long distance is one in which the distance between electronic regenerators can be in excess of 100 km.
- the regenerators are to be distinguished from repeaters which make use of optical amplifiers. Repeater spacing, especially in high data density systems, can be less than half the regenerator spacing.
- the total dispersion should be low, but not zero, and have a low slope over the window of operating wavelength.
- the total dispersion of the waveguide fiber should be negative, so that the linear dispersion cannot counteract the non-linear self phase modulation which occurs for high power signals.
- a typical application for such a waveguide fiber is undersea systems that, in order to be economically feasible, must carry high information rates over long distances without regenerators and over an extended window of wavelengths.
- the present invention describes a novel profile that is singularly suited to for use in these stringent conditions.
- the desired properties of the waveguide fiber for such a system are set forth in detail below.
- the radii of the segments of the core are defined in terms of the index of refraction.
- a particular segment has a first and a last refractive index point.
- the radius from the waveguide centerline to the location of this first refractive index point is the inner radius of the core region or segment.
- the radius from the waveguide centerline to the location of the last refractive index point is the outer radius of the core segment.
- the segment radius may be conveniently defined in a number of ways, as will be seen in the description of Figs. 1 & 2 below.
- the radii of the index profile segments are defined as follows, where the reference is to a chart of ⁇ % vs. waveguide radius:
- the outer radius, r 2 of the first annular segment is measured from the axial centerline of the waveguide to the intersection of the first annular segment profile with a vertical line drawn through the ⁇ % point which is half of the ⁇ % difference between the first and the second annular segment profile;
- the outer radius, r 3 of the second annular segment is measured from the axial centerline of the waveguide to the intersection of the second annular segment profile with a vertical line drawn through the ⁇ % point which is half of the ⁇ % difference between the second and third annular segment profile;
- index profile geometry No particular significance is attached to a particular definition of index profile geometry. Of course, in carrying out a model calculation the definitions must be used consistently as is done herein.
- a e ff 2 ⁇ (JE 2 r dr) 2 /(
- the effective area is wavelength dependent.
- the wavelength at which the effective area is calculated is the wavelength at or near the center of the operating window for which the waveguide fiber is designed.
- More than one A ⁇ rf may be assigned to a waveguide fiber which operates over a range of the order of hundreds of nanometers.
- Effective diameter, D eff may be defined as,
- ⁇ % 100 x (n ⁇ - n 2 2 )/2n 1 2 , where ⁇ is the maximum refractive index of the index profile segment 1 , and n 2 is a reference refractive index which is taken to be, in this application, the refractive index of the clad layer.
- refractive index profile or simply index profile is the relation between ⁇ % or refractive index and radius over a selected portion of the core.
- ⁇ -profile refers to a refractive index profile expressed in terms of ⁇
- index profiles include a step index, a trapezoidal index and a rounded step index, in which the rounding is typically due to dopant diffusion in regions of rapid refractive index change.
- - Total dispersion is defined as the algebraic sum of waveguide dispersion and material dispersion. Total dispersion is sometimes called chromatic dispersion in the art. The units of total dispersion are ps/nm-km.
- the bend test used is 5 turns of the waveguide fiber around a 20 mm diameter mandrel, a more demanding test which is required for the more severe operating environment of the present waveguide fiber.
- novel single mode waveguide fiber of this application meets the high performance telecommunication system requirements set forth herein.
- a first aspect of the invention is a single mode optical waveguide fiber having a segmented core of at least two segments, surrounded by a cladding glass layer.
- the waveguide fiber has an effective area greater than 60 ⁇ m 2 , and preferably greater than 65 ⁇ m 2 , over the wavelength range of about 1530 nm to 1570 nm, attenuation at 1550 nm less than 0.25 dB/km and preferably less than 0.22 dB/km, a zero dispersion wavelength in the range of about 1565 nm to 1600 nm, a dispersion slope which provides a dispersion at 1560 nm more negative than about -0.5 ps/nm-km and a preferred 1560 dispersion about -2 ps/nm-km. Typically the slope is in the range of about 0.10 to 0.14 ps/nm 2 -km.
- the total dispersion of the waveguide fiber is in the range of about
- the mode field diameter is in the range of about 7.9 to 9.75 ⁇ m over the 1530 nm to 1570 nm wavelength range.
- the index profiles of the respective segments can be any of those defined above, including an ⁇ -profile, a step index profile, or a trapezoidal profile. Unless special steps are inserted in the process, the refractive index profiles will be rounded at points where the refractive index changes sharply. The rounding is due to diffusion of the dopant materials used to change the base glass refractive index. Thus any of these index profiles may be rounded at particular points. For example, a step index profile, having a positive ⁇ % will typically have rounded upper and lower corners.
- the core segments all have a positive ⁇ %.
- the core comprises three segments, the first being an ⁇ -profile, the second a step profile and the third a rounded step profile. Examples of this embodiment are set forth in Table 1 below.
- the core region comprises three segments and the center has been compensated for dopant diffusion so that the refractive index on or near the waveguide fiber centerline is not reduced relative to the remainder of the center profile.
- An example of such centerline compensation is shown in Fig. 3 wherethe dopant is germanium.
- the diffusion compensated embodiment shows an average improvement in polarization mode dispersion of about a factor of 5 relative to a comparable uncompensated waveguide fiber profile.
- the polarization mode dispersion of the novel waveguide fiber is less than 0.08 ps/(km) 1/2 and typically less than about 0.04 ps/(km) 1 2 .
- the segmented core is described by the parameters: - ⁇ i % in the range of about 0.75 to 1.25;
- a preferred range is: - ⁇ i % in the range of about 0.85 to 1.20;
- a more preferred embodiment is:
- the total dispersion at 1560 nm is more negative than about -1 ps/nm-km.
- centerline diffusion is either uncompensated or partially compensated so that there is an indentation of refractive index on centerline having a minimum ⁇ % of no more than about 0.20 of ⁇ %.
- the indentation is typically of the shape of an inverted cone, i.e., the apex of the cone points downward, and the radius at the widest part of the cone is no greater than about 0.4 ⁇ m.
- Figs. 1 a & b are charts of ⁇ % vs. radius each illustrating a modeled index profile similar to that of the invention.
- Fig. 2 is a ⁇ % vs. radius chart showing the definitions of radius and width used in this application.
- Fig. 3 is a chart of ⁇ % vs. radius showing an embodiment of the invention. Detailed Description of the Invention
- the novel single mode optical waveguide is characterized by its segmented core design that provides the unusual combination of properties set forth above. These properties are achieved by selecting a proper refractive index profile shape of each of the segments and selecting the appropriate relative refractive index delta, ⁇ i %, and radial extent, n, of the segments.
- the profile parameters are known to interact. For example, a center region ⁇ - profile having an ⁇ of about 1 , will have a radius different from a center region having a trapezoidal index to provide fibers having essentially identical properties.
- the definitions of radius used herein are shown in Fig. 2.
- the radius of the central segment is shown by line n drawn from the core centerline to the intersection of extrapolated line 14 with the horizontal axis.
- the outer radius of segment is line r 2 drawn from the centerline to the vertical line descending from the point 18 which marks the point where the relative index is half the difference between ⁇ 2 %, the relative index of segment 16, and ⁇ 3 %, the relative index of segment 20.
- the radius r 3 of the final annular segment 20 is draw to the center point 26 of that segment.
- the geometry is fully specified when the width w of the final segment is selected. This width is shown as line w that lies between points 18 and 22, the respective points of half index differences between segments 16 and 20, and segment 20 and clad 24.
- the radius of the centerline indentation is shown as line 30 drawn horizontally from the centerline at the widest point of the inverted cone indentation.
- Three computer generated profiles, 2, 4, and 6, are shown in Fig. 1
- the center segments and the associated outer annular segments have corresponding numbers for purposes of clarity.
- Each profile has an inverted cone indentation on centerline.
- the properties of a waveguide fiber having that segmented core shape may be calculated.
- profile 4 provides the desired fiber characteristics.
- Fig. 1 b shows three additional segmented core profiles, 8, 10, and 12.
- profile 10 yields the desired fiber properties.
- the profile shown in Fig. 3 is a measured profile of a waveguide fiber having a refractive index profile in accord with the invention. Table 1 gives the core index profile parameters for this embodiment.
- the centerline diffusion is compensated in this design.
- the manufacturing results provide a waveguide fiber suitable in every respect for use in severe environments such as undersea telecommunications cables.
- the manufacturing results also serve to validate the computer model.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Optical Communication System (AREA)
- Glass Compositions (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002339010A CA2339010A1 (en) | 1998-07-31 | 1999-07-22 | Long haul single mode waveguide |
BR9912650-8A BR9912650A (en) | 1998-07-31 | 1999-07-22 | Long-drag single-mode optical waveguide |
AU52232/99A AU5223299A (en) | 1998-07-31 | 1999-07-22 | Long haul single mode waveguide |
JP2000562782A JP2003522337A (en) | 1998-07-31 | 1999-07-22 | Single mode optical waveguide for long distance communication |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9499698P | 1998-07-31 | 1998-07-31 | |
US60/094,996 | 1998-07-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000007048A1 true WO2000007048A1 (en) | 2000-02-10 |
Family
ID=22248424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/016615 WO2000007048A1 (en) | 1998-07-31 | 1999-07-22 | Long haul single mode waveguide |
Country Status (9)
Country | Link |
---|---|
JP (1) | JP2003522337A (en) |
KR (1) | KR100667408B1 (en) |
CN (1) | CN1134680C (en) |
AU (1) | AU5223299A (en) |
BR (1) | BR9912650A (en) |
CA (1) | CA2339010A1 (en) |
ID (1) | ID28769A (en) |
WO (1) | WO2000007048A1 (en) |
ZA (1) | ZA994882B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6789960B2 (en) | 2001-07-06 | 2004-09-14 | Corning Incorporated | Method of connecting optical fibers, an optical fiber therefor, and an optical fiber span therefrom |
JP2006525551A (en) * | 2003-05-02 | 2006-11-09 | コーニング・インコーポレーテッド | High SBS threshold optical fiber with large effective area |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100485889B1 (en) * | 2002-10-30 | 2005-04-29 | 엘에스전선 주식회사 | Optical fiber for WDM transmission system |
KR100651506B1 (en) * | 2004-05-13 | 2006-11-29 | 삼성전자주식회사 | Optical fiber for long-distance optical network |
KR100735239B1 (en) * | 2004-05-28 | 2007-07-03 | 삼성전자주식회사 | Optical fiber for metro network |
KR100826053B1 (en) * | 2006-10-18 | 2008-04-28 | 엘에스전선 주식회사 | Optical fiber for WDM transmission system, Optical transmission line and Optical transmission system using the same |
CN114153021A (en) * | 2021-08-25 | 2022-03-08 | 山东富通光导科技有限公司 | Low dispersion slope large effective area non-zero dispersion displacement optical fiber |
WO2023228743A1 (en) * | 2022-05-26 | 2023-11-30 | 住友電気工業株式会社 | Optical fiber |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5748824A (en) * | 1995-11-17 | 1998-05-05 | Corning Incorporated | Positive dispersion optical waveguide |
US5835655A (en) * | 1995-01-26 | 1998-11-10 | Corning Incorporated | Large effective area waveguide fiber |
US5894537A (en) * | 1996-01-11 | 1999-04-13 | Corning Incorporated | Dispersion managed optical waveguide |
-
1999
- 1999-07-22 CN CNB998086460A patent/CN1134680C/en not_active Expired - Fee Related
- 1999-07-22 WO PCT/US1999/016615 patent/WO2000007048A1/en active IP Right Grant
- 1999-07-22 BR BR9912650-8A patent/BR9912650A/en not_active IP Right Cessation
- 1999-07-22 CA CA002339010A patent/CA2339010A1/en not_active Abandoned
- 1999-07-22 KR KR1020017001299A patent/KR100667408B1/en not_active IP Right Cessation
- 1999-07-22 ID IDW20010456A patent/ID28769A/en unknown
- 1999-07-22 AU AU52232/99A patent/AU5223299A/en not_active Abandoned
- 1999-07-22 JP JP2000562782A patent/JP2003522337A/en active Pending
- 1999-07-29 ZA ZA9904882A patent/ZA994882B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5835655A (en) * | 1995-01-26 | 1998-11-10 | Corning Incorporated | Large effective area waveguide fiber |
US5748824A (en) * | 1995-11-17 | 1998-05-05 | Corning Incorporated | Positive dispersion optical waveguide |
US5894537A (en) * | 1996-01-11 | 1999-04-13 | Corning Incorporated | Dispersion managed optical waveguide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6789960B2 (en) | 2001-07-06 | 2004-09-14 | Corning Incorporated | Method of connecting optical fibers, an optical fiber therefor, and an optical fiber span therefrom |
JP2006525551A (en) * | 2003-05-02 | 2006-11-09 | コーニング・インコーポレーテッド | High SBS threshold optical fiber with large effective area |
Also Published As
Publication number | Publication date |
---|---|
CN1309778A (en) | 2001-08-22 |
KR20010072124A (en) | 2001-07-31 |
JP2003522337A (en) | 2003-07-22 |
ZA994882B (en) | 2000-03-31 |
CA2339010A1 (en) | 2000-02-10 |
KR100667408B1 (en) | 2007-01-10 |
ID28769A (en) | 2001-06-28 |
AU5223299A (en) | 2000-02-21 |
BR9912650A (en) | 2001-05-02 |
CN1134680C (en) | 2004-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0724171B1 (en) | Large effective area waveguide fiber | |
KR100694365B1 (en) | Positive dispersion low dispersion slope fiber | |
US6829423B2 (en) | Low slope dispersion managed waveguide | |
AU750557B2 (en) | Low slope dispersion managed waveguide | |
JP2004246375A6 (en) | Positive dispersion low dispersion gradient fiber | |
US6343176B1 (en) | Long haul single mode waveguide | |
WO2000007048A1 (en) | Long haul single mode waveguide | |
KR20020038781A (en) | Optical fiber with large effective area and low dispersion slope for submarine applications | |
JP2004520607A (en) | Low dispersion single mode optical fiber | |
EP0984305B1 (en) | Long haul single mode waveguide fiber | |
EP1105758A1 (en) | Single mode optical waveguide | |
AU689673B2 (en) | Controlled dispersion optical waveguide | |
MXPA01001210A (en) | Long haul single mode waveguide | |
MXPA00008215A (en) | Low slope dispersion managed waveguide | |
MXPA01000467A (en) | Single mode optical waveguide | |
MXPA00004792A (en) | High performance single mode waveguide |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 99808646.0 Country of ref document: CN |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 52232/99 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: IN/PCT/2001/00032/MU Country of ref document: IN |
|
ENP | Entry into the national phase |
Ref document number: 2000 562782 Country of ref document: JP Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2339010 Country of ref document: CA Ref document number: 2339010 Country of ref document: CA Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020017001299 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2001/001210 Country of ref document: MX |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWP | Wipo information: published in national office |
Ref document number: 1020017001299 Country of ref document: KR |
|
122 | Ep: pct application non-entry in european phase | ||
WWG | Wipo information: grant in national office |
Ref document number: 1020017001299 Country of ref document: KR |