WO1999057781A1 - Empilage de piles a combustible - Google Patents

Empilage de piles a combustible Download PDF

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Publication number
WO1999057781A1
WO1999057781A1 PCT/GB1999/001169 GB9901169W WO9957781A1 WO 1999057781 A1 WO1999057781 A1 WO 1999057781A1 GB 9901169 W GB9901169 W GB 9901169W WO 9957781 A1 WO9957781 A1 WO 9957781A1
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WIPO (PCT)
Prior art keywords
stack
fuel cell
fuel
cell stack
oxidant
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PCT/GB1999/001169
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English (en)
Inventor
Zuomin Dong
Original Assignee
Ballard Power Systems Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ballard Power Systems Inc. filed Critical Ballard Power Systems Inc.
Priority to AU36139/99A priority Critical patent/AU3613999A/en
Priority to CA002330946A priority patent/CA2330946A1/fr
Publication of WO1999057781A1 publication Critical patent/WO1999057781A1/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0223—Composites
    • H01M8/0228—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H01M8/0254—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form corrugated or undulated
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • H01M8/0263—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant having meandering or serpentine paths
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074—Heat exchange unit structures specially adapted for fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0206—Metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0213—Gas-impermeable carbon-containing materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a stack assembly primarily for an electrochemical fuel cell of the proton exchange membrane (PEM) type, and to a multi-function stratum for inclusion in a PEM-type fuel cell stack.
  • the multi- function stratum serves as (i) a heat dissipator; (ii) a compression spring arrangement for maintaining the stack in compression; and (iii) an electrical conductor between successive electrochemically active strata in the stack.
  • Electrochemical fuel cells convert fuel and oxidant to direct electric current and reaction product.
  • the reaction product is water.
  • Solid polymer fuel cells of the PEM type include a membrane electrode assembly (MEA) layer comprising a solid polymer electrolyte serving as an ion exchange membrane disposed between two electrode layers.
  • the electrode layers typically comprise porous, electrically conductive sheet material and an electrocatalyst at each membrane-electrode interface to promote the desired electrochemical reaction.
  • fuel from the fuel supply moves into and through the porous electrode material and is oxidized with the aid of the anode electrocatalyst.
  • the reaction forms cations (typically protons obtained from the hydrogen fuel supply), that migrate through the membrane to the cathode, and electrons that move into an electric circuit that includes a load and is connected to the cathode.
  • cations typically protons obtained from the hydrogen fuel supply
  • the oxidant moves into and through the porous electrode material and reacts with the aid of the cathode electrocatalyst to form anions.
  • the anions so formed react with the cations arriving through the PEM from the anode to produce a reaction product, typically water.
  • the cathode reaction requires the electric circuit to supply the electrons needed to provide the negative charge for the anions that neutralize the arriving cations and form with the cations the electrically neutral reaction product.
  • the MEA is interposed between two substantially fluid-impermeable, electrically conductive plates (sometimes referred to as separator plates) to form a fuel cell unit.
  • the plates serve as current collectors and conductors, provide structural support for the electrode layers, typically include conduits for directing the fuel and oxidant to the anode and cathode layers, respectively, and typically provide means for removing reaction products, typically water, formed during operation of the fuel cell.
  • the plates are sometimes referred to as fluid flowfield plates. Since in stacked fuel cell arrangements a given separator plate typically has an anode adjacent the obverse broad surface and a cathode adjacent the reverse broad surface, such plates are sometimes referred to as bipolar plates.
  • Individual fuel cells are typically electrically interconnected in series in a stacked array between stack end plates (to which terminals for connection to the external electrical load are connected) in order to generate usable electrical power.
  • the dimension through the stack from one terminal end plate to the other is referred to in this specification as the stack dimension.
  • the stack must be retained between the terminal end plates under compression to maintain sealing between MEA and plate subassemblies and to provide adequate electrical conductivity between subassemblies.
  • Conduits must be provided adjacent the electrode layers for the supply of fuel and oxidant gases respectively; these conduits are typically formed in the separator plates, as mentioned.
  • MEA layers alternate in the stack dimension with separator plates; similarly fuel supply flowpaths alternate in the stack dimension with oxidant supply flowpaths so that the fuel supply is isolated from the oxidant supply.
  • These flowpaths and associated exhaust conduits must also be supplied to remove the spent reactant gases and the reaction product (typically water).
  • the reaction product typically water
  • means such as auxiliary cooling passages for flow of cooling water through the stack must be provided to remove heat from the stack, as the chemical reactions are exothermic.
  • one broad surface of a given fluid flow field plate, bipolar plate, or separator plate serves as the anode conductor for one cell, and the other broad surface of the plate serves as the cathode conductor for the adjacent cell.
  • Fluid reactant streams are typically supplied to channels in the flowfield plates via internal plena or manifolds formed by aligning openings formed within the plates and MEA layers in the stack.
  • fluid exhaust manifolds for spent gases and reaction products are also typically located internally within the stack; suitable apertures in the separator plates and MEA strata are frequently provided for this purpose.
  • Some types of fuel cell operate at relatively high temperatures. For example, phosphoric acid fuel cells operate at about 200°C. Heat may be readily removed from such cells by air cooling. By contrast, a conventional PEM fuel cell operates at about 80°C. Unless a given PEM-type fuel cell stack is of sufficiently low power (say, lower than about 30 kW) and of sufficiently small dimensions that heat can be dissipated into the environment without special assistance (see Fletcher et al. U.S. Patent No. 5,470,671 granted to Ballard Power Systems Inc. on 28 November 1995 for an example of such small low-power fuel cell stack), some heat dissipation means must be designed into the fuel cell configuration so that the low-grade heat generated from the fuel cell stack during its operation may be removed to maintain the desired working temperature.
  • conventional stacks typically also have coolant passageways extending within them for circulating a coolant liquid that absorbs the heat generated by the exothermic fuel cell reaction.
  • the coolant liquid typically flows out of the stack to a heat exchanger and then the re-cooled liquid recycles into the stack.
  • the requirement for such coolant flow necessitates the use of a circulating pump as well as the heat exchanger and coolant flow conduits, thereby adding to the cost, weight and bulk of conventional PEM fuel cell stack and associated assemblies.
  • PEM fuel cell stacks are otherwise suitable for use in mobile applications such as powering vehicles, bulk and weight should be kept to a minimum.
  • external manifolds connected to the sides of the stack for providing side-located supply and exhaust plena for the reactant gases may be provided instead of internal plena or manifolds.
  • the use of external manifolds with a fuel cell stack allows reactant and oxidant gases to be fed directly to the sides of the stack and thence to the internal reactant fuel and oxidant gas conduits.
  • a stack with external manifolds has simple manifold interfaces and assembly requirements, which translate into lower manufacturing and assembly costs.
  • External manifolds have been used for molten carbonate fuel cells.
  • stack expansion-compensating compression springs are used at one or both ends of the stack to compensate for the expansion and compression of the stack.
  • the compressive force exerted by these springs maintains internal seals between adjacent MEA/plate subassemblies and their associated conduits for fuel, oxidant, and coolant supply, and reaction product disposal ,despite the tendency over time for the stack strata (subassemblies) to shrink in the stack dimension, and despite intermittent expansions and contractions of the stack strata.
  • Such springs also facilitate adequate electrical conductivity between the serially connected strata.
  • PEM fuel cell stacks tend not to be stable in the stack dimension; motion along the stack dimension is then propagated to all reactant and oxidant gas delivery plates. Consequently, in accordance with conventional PEM fuel cell stack design, manifolding and associated seals are internally located, since external seal and manifold conduit alignment cannot pursuant to conventional design be properly maintained in the stack dimension. If external manifolding were attempted in such conventional PEM stacks, the continual motion of the plates would tend to break the seals between the edges of the plates and the fixed external manifolds coupled to the stack, thereby rendering unworkable the otherwise desirable external manifolding for high- power fuel cell stacks.
  • PEM-type fuel cell stack with resilient spring plates between adjacent cells with resilient spring plates between adjacent cells.
  • Bette does not teach any manifolding of the fuel cell stack. Bette apparently uses the spring plates to adjust voltage drop; the specification teaches that the voltage drop within the fuel cell stack is "adjustable within wide limits, which is achieved, for instance, by inserting additional, or differently shaped spring plates 10, or other intervening layers" (column 4, line 60ff). There is no disclosure of the use of such spring plates for the purpose of maintaining dimensional stability within the stack dimension, nor any teaching as to how such spring plates could be adapted for use in multiple-function configurations nor in conjunction with an external manifold.
  • Mattejat U.S. Patent No. 5,472,801, granted 5 December 1995, discloses a PEM-type fuel cell with intervening contact plates provided with "stamped out contact tongues" (column 6, line 57) that might arguably function as spring plates similar to those of Bette. Mattejat's teaching suffers from the same deficiencies as the Bette teaching mentioned above.
  • Such cells are not susceptible to the same sort of dimensional instability as PEM fuel cell stacks. There is nothing in the Kothmann teaching to suggest that compression occurs, and nothing to suggest the use of compensating springs or the like. Kothmann discloses the use of a solid cooling block between two bipolar plates. The cooling block cannot accommodate the expansion and contraction of fuel cell components. Further, the cooling block is bulky, adding to the weight and volume of the fuel cell stack, and tends to be inefficient for heat dissipation. It would not be expected to be suitable for dissipating low-grade heat generated by medium to high power PEM fuel cells.
  • Siemens AG German Patent Application Serial No. DE 44 42 285 Cl published 8 February 1996, discloses a stamped metal fuel cell configuration.
  • An intermediate panel is disclosed whose functions include improving mechanical support, transferring electric current and providing a contact surface for air cooling of the stack.
  • Siemens teaches that interwoven or tangled wire or wire mesh may be used as the panel material (none of which would have any appreciable springiness), nevertheless the panel may have sufficient spring properties to generate a modest internal thrust force against fuel cell plates.
  • the rigid frames of the component fuel cells must remain in contact. These frames determine the stack dimension. Any thermal or hydro expansion has to be accommodated by external springs.
  • This fuel cell stack design uses internal manifolds; there is no discussion of the possibility of external manifolding nor of the need to maintain dimensional stability in the stack dimension to accommodate such possibility.
  • Baker U.S. Patent No. 4,169,917, granted 2 October 1979, discloses an air-cooled fuel cell incorporating layers configured as rectangular corrugations and other geometries for use as corrugated layers. Baker does not disclose any dimensional stability problems, nor any use of the corrugated layer or any other layer as a compression spring, nor the use of internal springs of any sort to maintain dimensional stability. There is no discussion of the manifolding for the fuel cell.
  • Leonida U.S. Patent No. 5,446,354, granted 14 November 1995, is not directed to fuel cell design at all, but rather to electrolysis cell design.
  • Leonida discloses a metal compression pad interposed between pairs of stacked electrolysis cells in order to compress the cells so as to compensate for dimensional variations and thermal expansion, and to provide electrical connection.
  • Leonida does not teach the use of such pads for use in fuel cell stacks, nor is Leonida concerned with manifolding or heat dissipation.
  • the invention comprises improvements in fuel cell stack design, primarily for PEM-type fuel cell stacks, including a novel multi-function stratum (panel) for use in such stack, and an external manifolding arrangement suitable for use with such stack.
  • a fuel cell stack assembly according to the invention (particularly useful for a PEM-type fuel cell stack) in a preferred embodiment includes an aligned series of uniform multi-function strata or panels alternating with and interposed between a mating series of uniform electrochemically active fuel cell strata, which in a PEM-type fuel cell stack are either fuel cell units or membrane electrode assembly (MEA) layers. (Obviously a terminating one of such strata must be provided adjacent the terminal end plate at either end of the stack.) Each stratum is a discrete sub-assembly. Each fuel cell stratum may be of conventional manufacture; such stratum includes the electrode layers, electrocatalytic layers, and polymeric proton exchange membrane electrolytic
  • Each multi-function stratum comprises an interior open spring layer or equivalent sandwiched between a pair of relatively rigid conductive layers.
  • Such rigid conductive layers in an orthogonal stack configuration i.e., a stack having the overall shape of a rectangular parallelepiped
  • Such rigid conductive layers in an orthogonal stack configuration are generally planar in the form of a thin, flat, parallelepiped, so that the multi- function stratum has the overall shape of a generally flat panel, the interior open spring layer being sandwiched between the rigid conductive layers.
  • the rigid conductive layers need not be rigid in the sense that a desktop, say, is rigid, but should impart sufficient rigidity to the sandwich structure that the multi-function panel maintains its structural integrity within the stack. As will be discussed below, it may in some circumstances in which fuel cell units are used as fuel cell strata be possible to depart from strict alternation of fuel cell strata with multi-function strata and to have two or possibly more fuel cell strata in immediate succession in the stack followed by a multi-function stratum, but such is not normally preferred.
  • each multi-function stratum may conveniently be in the form of a corrugated or other undulate sheet.
  • the open spring layer could be formed as a spaced array of fins of identical transverse cross-section shaped to provide the function of a compression spring; that cross-section could for example be S-shaped or undulate.
  • the open spring layer could be an array of coil springs whose axes are parallel to the stack dimension.
  • the open spring layer could be manufactured from a single sheet of elastic material subjected to cutting and punching to create an inset array of integrally connected springs. (In this last embodiment, the cut and punched sheet could function both as one of the rigid layers and as the spring layer.)
  • 11 layer could be a corrugated metal mesh.
  • Further suitable structures may be imagined. Not all will be equally convenient to manufacture nor equally effective to provide spring compression, conduct electricity, or dissipate heat.
  • the common characteristics of all of these alternative choices for the open spring layer are elasticity (springiness), heat and electrical conductivity, and an open structure permitting cooling air to flow through the multi-function stratum and absorb heat from the open spring material, which is conveniently a springy (elastic) metal.
  • the spring layer is electrically and physically bonded to each of the rigid layers between which it is sandwiched; if for example the spring layer is a continuous undulate sheet, then the apices of the undulations are bonded to the contiguous rigid layers.
  • the spring layer must be shaped to provide continuous open spaces therethrough so that when the fuel cell stack is operational, heat from the spring layer material (to which heat has been transferred from the fuel cell strata adjacent) may be transferred efficiently to cooling fluid (typically air) passed through the open spaces in the spring layer.
  • cooling fluid typically air
  • the spring layer is preferably uniformly constructed from one airflow end to the other; it is desirably invariant in the airflow dimenstion, subject to any need to generate some turbulence in the airflow to increase the rate of heat dissipation.
  • the open spring layer sandwiched between each pair of rigid conductive sheets in a multi-function stratum constitutes a distributed spring exerting a compressive force acting in the stack dimension on the rigid conductive sheets between which it is sandwiched and consequently acting on all of the strata in the stack.
  • the set of such layers in the stack constitutes a distributed spring array that can eliminate the need for a separate compression spring at the end of the stack.
  • the stack dimension is the dimension extending from one extremity of the fuel cell stack to the other, pe ⁇ endicular to the layers of the stack and pe ⁇ endicular to the broad working surfaces of the fuel cell strata.
  • this dimension is presented as the vertical dimension.
  • the airflow dimension is the dimension parallel to the flow of cooling air or other cooling fluid through the multi-function panels.
  • the transverse dimension is the dimension from one manifold cover plate (see description below) to the other, pe ⁇ endicular to the other two dimensions. Where the open spring layer is formed as an undulate layer, this dimension extends from the beginning of the waveform to the end of the waveform of the layer.
  • the outer surfaces of the rigid conductive sheets (i.e., the surfaces that are in contact with adjacent MEA layers in the stack) of each multi-function stratum should be inert to reactant gases (i.e., the fuel and oxidant gases) in the
  • An inert coating or protective layer may be applied to the outer surfaces rigid sheets, or the rigid conductive sheets themselves may be made of material inert to the reactant gases and non-poisonous to the fuel cell MEA layers, such as graphite.
  • the use in fuel cells of certain selected types of fuel- cell compatible stainless steel such as 316L stainless steel has also been proposed in the literature.
  • the rigid conductive layers also serve as protective layers for the spring layer, so that reactant gases do not reach such spring layer to react with it.
  • Suitable protective layers include graphite foil and curable graphite-containing inks or pastes.
  • the open spring layer may preferably be an undulate or corrugated sheet.
  • the terms "undulate layer”, “undulate sheet”, “corrugated sheet” or “corrugated layer” used herein mean any sheet or layer of a suitable degree of springiness having undulations that provide suitable apices for physical and electrical contact with the rigid conductive plates or layers, and which undulations also define air passageways to permit cooling air to flow from one end of the corrugations or undulations to the other (each end being exposed to the ambient air or coupled to a forced air circuit that forces cooling air over the undulations).
  • Such undulate layers do not include, for example, corrugated sheets having a rectangular waveform, because these lack the requisite springiness, and would tend to buckle or crumple rather than flex under load.
  • the physical contact of the corrugated sheet with the protective rigid plates or layers permits heat to flow from fuel cell strata through the rigid plates and thence to the corrugated sheet, which thus serves as a heat exchanger or dissipator to dissipate heat into the cooling air passing over the corrugations.
  • This heat dissipation arrangement thus functions in a manner similar to the operation of a conventional automobile radiator.
  • the corrugated layer must be made of metal or other suitable springy material so that the requisite degree of
  • the undulate layer must be both thermally and electrically conductive; thermal conductivity is necessary for adequate heat dissipation, and electrical conductivity is necessary to enable low-resistance current flow through the stack.
  • any such substitute layer is likely to be appreciably more expensive to manufacture and install than a continuous corrugated or undulating sheet or layer, so the latter is preferred.
  • the fuel cell stack of the invention has been and will be for the most part described as including planar strata and layers (apart from corrugations and the necessary flowpath structures), it is apparent that other configurations are possible, for example generally parallel curved subassemblies (strata) could be devised in lieu of planar strata.
  • the rigid sheets of the multi-function panel will usually be planar, as that choice lends design and manufacturing convenience to the implementation of the present invention, in which case the stack dimension is pe ⁇ endicular to the plane of the multi-function panel sheets, and the stack lends itself to an orthogonal description. But it is possible to construct the fuel cell strata and multi-function panels as themselves undulate overall, or arcuate, or otherwise departing from planar.
  • the concepts described herein using the named dimensions as applied to such planar and orthogonal stack configurations may
  • the protective coating or layer is made of material that is conductive, non- poisonous to the MEA layers, and inert to reactant gases (graphite being a suitable choice), then no problem arises, as the entirety of the multi-function stratum will then be both conductive and non-reactive. Otherwise, if the rigid plate is not entirely conductive or a protective layer applied to it is not conductive, some means such as an array of spaced chemically inert conductors extending from or through the protective coating or rigid layer or both could be provided.
  • a PEM-type fuel cell stack fuel gas is supplied to one active layer of a fuel cell stratum and oxidant gas is supplied to the other active layer of each fuel cell stratum.
  • active layer is one to which fuel or oxidant, as the case may be, is delivered to enable the electrochemical reaction to take place.
  • active layer is typically a porous cathode layer or
  • the gas delivery means may be conveniently integrally formed on the outer surface of the conductive rigid layer of the multi- function panel as a pattern of flowpath channels if the fuel cell stratum is an MEA layer, or the gas delivery means may be formed integrally within the fuel cell stratum if the fuel cell stratum is a fuel cell unit.
  • the means for providing fuel gas comprises a configuration of one or (depending upon fuel cell dimensions) preferably two or more meandering fuel channels formed in the outer surface of one of each pair of the protective layers associated with each of said multiple- function panels.
  • a similar set of meandering oxidant channels is formed in the outer surface of the other of each such pair of protective layers.
  • the meandering channels may be of conventional design. By “meandering” is meant that each channel typically has a length appreciably greater than either dimension of the major broad surface of the protective layer, and accordingly is provided with a number of reverse curves to enable the channel to supply gas to a relatively large portion of the MEA porous electrode layer adjacent.
  • the pattern of meandering channels on either surface of the multiple-function panel is designed to be sufficient to provide gas to almost the entirety of the exposed MEA porous electrode layer surface adjacent.
  • the meandering fuel channel pattern or configuration is exposed to an adjacent porous anode layer of an adjacent MEA layer, while the meandering oxidant channel pattern or configuration is exposed to an adjacent porous cathode layer of an adjacent MEA layer.
  • such meandering channels are typically se ⁇ entine.
  • the channel walls should be of uniform height and should contact the adjacent membrane electrode assembly throughout the length of the walls, but if all the fuel channels are formed on one side of the multiple- function panel and all the oxidant channels are formed
  • each channel in the fuel supply channel configuration is provided with an inlet fuel port and an outlet fuel port.
  • the inlet fuel port may conveniently communicate with a fuel supply plenum and the outlet fuel port may conveniently communicate with a fuel exhaust plenum.
  • each channel in the oxidant supply channel configuration is provided with an inlet oxidant port and an outlet oxidant port, the inlet oxidant port advantageously communicating with an oxidant supply plenum and the outlet oxidant port advantageously communicating with an oxidant exhaust plenum.
  • Each plenum is isolated from every other plenum (except via the reactant flowpaths) by means of walls that may be formed in a manifold external to the various layers within the fuel cell stack.
  • the manifold is provided with conduits, at least one conduit per plenum, for connecting each plenum to a respective associated source of fuel or oxidant gas, or sink of spent fuel or oxidant gas, as the case may be.
  • the invention comprises a fuel cell stack of the type heretofore described, but it also comprises a multi-function stratum (composite panel) of the type described.
  • multi-function stratum is particularly suitable for use as a stratum or panel alternating with MEA layers in a PEM-type fuel cell stack assembly of the type defined above.
  • Such multi-function strata or panels may each suitably comprise a corrugated metal sheet sandwiched between two flat metal sheets.
  • multi-function strata serve as both the heat dissipating elements of the stack and the springs to compensate for thermal and hydro
  • the multi-function strata also provide structural support for the porous electrode layers adjacent and serve as current collectors to interconnect all fuel cells in the stack.
  • the multi-function panels form a distributed spring system that force the "floating" (otherwise free to move in the stack dimension) fuel cells and their reactant gas delivery plates into fixed positions. Undesired motion of the fuel cells and their associated plates along the stack dimension is effectively eliminated, making the sealing of external manifolds easy to accomplish, and thus making feasible the use of external manifolds for a high-power PEM-type fuel cell stack.
  • the associated structure of the fuel cell stack may advantageously include pillars disposed peripherally about the stack and extending in the stack dimension.
  • the terminal plates may be fixed to the pillars and may form with the pillars a structurally sound "cage" or frame for the stack.
  • the pillars thereby provide both structural integrity and mounting surfaces for mounting external manifold cover plates.
  • the fuel cell stack is thus seen to comprise, within the framework of the pillars and terminal plates, an aligned series of repeated combinations of elements, each of which combinations consists in one preferred embodiment of the invention, of an MEA layer, a pair of reactant gas delivery plates, and a multi-function panel and, in a second preferred embodiment of the invention, of an MEA layer and a multi-function panel.
  • These repeated elements are flexible in the stack dimension and are constrained by the solid frame of the stack.
  • the fuel cell stack requires seals to prevent reactant gases from commingling, to prevent such gases from reacting with other materials in the stack (notably the metal in the corrugated layer), etc.
  • seals for the stack may include gaskets or sealant-filled channels around the reactant and oxidant flowpath channels, gaskets at the mamfold interface with support pillars or other stack side surfaces, spacers inserted between the supply and exhaust plena and the sides of the multi-function strata thereadjacent, and applied sealing cement where required.
  • Each multifunction panel includes: (i) a pair of relatively rigid thermally and electrically conductive layers; and (ii) an electrically and thermally conductive elastic open spring layer sandwiched between and in mechanical, thermal and electrical contact with the rigid layers, the open spring layer when the associated multifunction panel is installed in a fuel cell stack providing electrical and thermal conductivity between the rigid layers, providing heat dissipation into the surrounding fluid medium of heat transferred to the multi-function panel from the fuel cells in the stack, and serving as a compression spring exerting on the rigid layers a compressive force generally pe ⁇ endicular to the panel for providing compressive force within the stack in the stack dimension.
  • Each fuel cell unit in the fuel cell stack includes a membrane electrode assembly (sometimes referred to herein as “MEA” or “MEA assembly” or “MEA sandwich”) formed as a “sandwich” having as the two outermost layers of the sandwich an anode electrode comprising porous anode material, and a cathode electrode comprising porous cathode material.
  • MEA membrane electrode assembly
  • MEA assembly or “MEA sandwich”
  • MEA sandwich formed as a “sandwich” having as the two outermost layers of the sandwich an anode electrode comprising porous anode material, and a cathode electrode comprising porous cathode material.
  • the "filling" of the sandwich comprises an electrolytic membrane layer disposed between the two electrodes, an anode electro-catalyst layer disposed between the electrolytic membrane
  • a fuel cell unit is formed when this MEA sandwich is installed between a first flow-field plate, a selected side of which provides flow channels of a flow field for hydrogen, and a second flow-field plate, a selected side of which provides flow channels of a flow field for a selected oxidant.
  • the selected side of the first plate faces and is in contact with the anode electrode and the selected side of second plate faces and is in contact with the cathode electrode so that the hydrogen flow channels are closed to form a conduit for supplying hydrogen to the membrane electrode assembly and the oxidant flow channels are closed to form a conduit for supplying oxidant to the membrane electrode assembly.
  • hydrogen may be used as a fuel gas in a fuel cell stack that includes a plurality of multi-function panels that are another embodiment of the present invention stacked together with the MEA layers of the fuel cell stack, each multi-function panel being inte ⁇ osed between a unique pair of said MEA layers, the multi-function panels acting as a flow- field-defining structures.
  • the membrane electrode assembly as in the previously described embodiment, is formed as a sandwich as described above, but the two flow-field plates are omitted and the flow fields, channels, and conduits are formed by multi-function panels that have been coated or otherwise made inert to reactant gases present in the fuel cell stack and non-poisonous to the membrane electrode assembly, but are otherwise as described in the preceding paragraph.
  • Flow channels are provided on or in the surfaces of the rigid layers.
  • the flow-fields are provided by the separator plates of the fuel cell stratum itself, whereas in the second embodiment the flow-fields are provided by the multi-function panels.
  • the stack is provided with a terminal cathode at one end and a terminal anode at the other, across which terminals the load is connected.
  • hydrogen and oxygen or other suitable oxidant are supplied to the fuel cells in the stack, then in each fuel cell, hydrogen moves from the hydrogen flow field through the porous anode electrode and is ionized at the anode electro-catalyst of the membrane electrode assembly to yield electrons and hydrogen ions.
  • the electrolytic membrane layer of the membrane electrode assembly is permeable to hydrogen ions (protons), but is not conductive. Hence only the hydrogen ions may migrate through the electrolytic membrane layer.
  • the hydrogen ions after migrating through the electrolytic membrane react with oxygen that has moved from the oxidant flow field through the porous cathode electrode to the cathode electrocatalyst and electrons supplied by the circuit.
  • the reaction product is water.
  • the circuit receives electrons from the anode electrode.
  • a fuel cell stack may be formed from two or more of the fuels cells described above in a conventional manner known to those familiar with fuel cell technology and therefore need not be described in detail here.
  • the advantages of all of the described aspects of the invention have particular application to PEM-type fuel cell stack design, some of them can be utilized to good effect in other types of fuel cell stack.
  • the multi-function panels could be used in other types of fuel cell stack as heat dissipators, even if they were not required for dimensional stability of the stack to compensate for thermal and hydro expansion or fuel cell shrinkage with age.
  • the efficiency of the overall stack architecture could be advantageous for other types of fuel cell.
  • the full benefit of the fuel cell stack variants and multi-function panels discussed herein is expected to be achieved only if the fuel cells are PEM-type fuel cells.
  • Figure 1 is a schematic isometric view of an embodiment of a PEM- type fuel cell stack constructed in accordance with the present invention.
  • Figure 2 is a schematic exploded isometric view of the fuel cell stack of Figure 1.
  • Figure 3 is a schematic isometric exploded view of a side portion of the fuel cell stack of Figure 2 showing also gaskets suitable for insertion in the space between the cover plate and side posts of the fuel cell stack of Figure 2.
  • Figure 4 is a schematic front elevation view of the fuel cell stack of
  • Figure 5 is a schematic section view of a representative corrugated sheet layer of the fuel cell stack of Figure 1 taken along the line V-V of Figure 4.
  • Figure 6 is a schematic section view of an embodiment of a fuel flowpath configuration of a representative fuel cell in the stack of Figure 1 taken along the line VI-VI of Figure 4.
  • Figure 7 is a schematic section view of an embodiment of an oxidant flowpath configuration of a representative fuel cell in the stack of Figure 1 taken along the line VII- VII of Figure 4.
  • Figure 8 is a schematic section view of an alternative fuel flowpath configuration that may be substituted for that of Figure 6.
  • Figure 9 is a schematic section view of an alternative oxidant flowpath configuration that may be substituted for that of Figure 7.
  • Figure 10 is a schematic fragmentary exploded view of a multi-function stratum of the fuel cell stack of Figure 1, showing in greater detail the configuration of the corrugated sheet layer.
  • Figure 11 is a schematic front elevation view of two strata of the fuel cell stack of Figure 1 showing in greater detail the configuration of the multifunction stratum.
  • Figure 12 is a schematic exploded fragmentary front elevation view of
  • Figure 13 (prior art) is a schematic diagram representing the conventional spring-loading of fuel cells in a PEM-type fuel cell stack, as practised prior to the present invention.
  • Figure 14 is a schematic diagram illustrating the distributed-spring arrangement of corrugated sheets and fuel cells in a fuel cell stack in accordance with the principles of the present invention.
  • a fuel cell stack 10 constructed in accordance with the principles of the present invention is schematically illustrated in Figure 1 ff.
  • eight fuel cell strata 12 are shown in Figure 1 in stacked arrangement between an upper terminal plate 14 and a lower (base) terminal plate 16 for the fuel cell stack assembly 10.
  • the terminal plates 14, 16 are fixed to corner support pillars or posts 18 and intermediate support pillars or posts 20, all of which pillars 18, 20 rest on the base terminal plate 16.
  • the fixing of the pillars 18 and 20 to the base plate 16 may be conveniently effected by screwing bolts 22 through mating holes (not shown) in base terminal plate 16 and thence into mating threaded holes (not shown) in the bases of pillars 18 and 20.
  • the upper terminal plate 14 may be fixed to the pillars 18 and 20 by means of bolts 24 that penetrate through mating holes 26 in the upper terminal plate 14 and thread into mating threaded receptacle holes 28 in the tops of pillars 18 and 20.
  • a complete repeating unit of the stack 10 comprises a fuel cell stratum 12 and an adjacent multi-function stratum or panel 30.
  • the structure of the multi-function stratum 30 is more clearly illustrated in Figure 11 ; see also the exploded view of Figure 10.
  • FIG 11 illustrates, in schematic vertical sequence, an exemplary pair of consecutive repeating units of the stack, each repeating unit comprising a fuel cell stratum 12 and a multi-function stratum 30.
  • Each fuel call stratum 12 may be a fuel cell unit of conventional manufacture comprising an upper separator/flow-field plate 13 for fuel gas, an intermediate MEA layer 15, and a lower separator/flow field plate 17 for oxidant gas.
  • each fuel cell stratum 12 may include a discrete MEA layer without separator/flow field plates.
  • Fuel cell strata that are fuel cell units are referred to herein as fuel cell units 12 and fuel cell strata that are MEA layers without separator/flow field plates are referred to herein as MEA layers 12, where it is necessary to distinguish between the two forms of fuel cell strata. If it is not necessary to distinguish between the two forms of fuel cell strata, then they are both referred to as fuel cell strata 12. Both forms of fuel cell strata are conventional.
  • the multi-function strata 30 each comprise an upper rigid layer or plate 32, an intermediate open spring layer in the form of corrugated layer 34, and a lower rigid layer or plate 36.
  • the three layers 32, 34, 36 may conveniently be made of metal, provided that care is taken to prevent metal poisoning of the MEA layers if the multi-function strata 30 are to be used with MEA layers 12. While some choices of metal are relatively inert, others, such as copper, would be suitable for electrical and thermal conductivity, but would contaminate the MEA layers 12. So when such fuel cell poisoning materials as copper are
  • Such inert medium can be a graphite coating, for example, applied to the metal, preferably after roughening the metal surface by sandblasting or the like to improve the adhesion of the coating to the rigid layer.
  • a protective coating found suitable for use in fuel cells is a castable graphite tooling material that is similar to monolithic graphite in a manufacturing environment, but has increased strength.
  • One such material is sold as Hyper CastTM Graphite by Hyper Industries of Bonita, California. Such graphite is sold in a paste form for ease of application. It will cure through a catalyzing process. The curing can take place in several steps at both ambient temperature or somewhat elevated temperatures (40°C - 110°C). If the material is sintered at a high temperature, around 700°C, few if any residual organic or inorganic contaminants will be left (leading to a final coating composition of close to 99% carbon).
  • the metal (say) sheets forming rigid layers 32, 36 could be coated with a graphite paint to form a solid graphite coating over the metal.
  • a separate protective layer such as a graphite foil sheet could be inte ⁇ osed between each rigid layer 32, 36 and the neighbouring MEA layer 12.
  • each rigid layer 32, 36 it is possible to form the requisite reactant gas flowfield on the outer surface of each rigid layer 32, 36 so that such layer does double duty, both bearing the walls defining the flowfield structure, and forming a portion of the multi-function sandwich.
  • the castable graphite mentioned in the preceding paragraph can be used to form the flowfield walls on planar layers 32, 36, or the walls may be molded in the
  • the corrugated sheet layer 34 functions as an electrical conductor, as a heat dissipator, and as a spring.
  • the corrugated layer 34 is most easily manufactured if the corrugations are uniform in both the airflow and transverse dimensions, but there may be particular reasons to provide non-uniform corrugations in either or both dimensions, e.g. for generation of air turbulence in the interest of enhancing heat transfer to the cooling air flow.
  • the apices 38 of the corrugated layer 34 make electrical and physical contact with the respective rigid plates 32, 36 adjacent the apices of the corrugated layer 34.
  • the air spaces formed by the corrugations of layer 34 constitute cooling passages 35 for permitting cooling air to flow over the corrugations of the layer 34, thereby resulting in heat transfer from the stack 10 to the cooling air.
  • the cooling air flow can be from the front of the stack 10 to the back (as seen in Figure 1) or vice versa, and may be augmented by fans or the like.
  • Spacer bars 64 made of rubber or similar resilient sealing material seal the multi-function panels 30 from the reactant gas plena of the fuel stack, to be described below.
  • each of the apices of the corrugated layer 34 is preferably welded or soldered to the plate 32 or 36 respectively with which such apex of the corrugated layer 34 comes into contact.
  • This can be accomplished by prefabrication of each multi-function stratum 30, for example by providing a layer of solder on the inner surfaces of sheets 32, 36, placing the corrugated layer 34 therebetween, and placing the assembly thus formed into an oven, permitting the solder to melt and form the connections, and then permitting the assembly to cool so that the liquid solder connections solidify, leaving the corrugated layer 34 firmly electrically and conductively bonded between the
  • each fuel cell stratum 12 is designed so that inlet and outlet ports 90, 94, 104, 106 ( Figures 6 and 7) for the reactant flowpaths provided in the fuel cell strata 12 communicate with associated discrete plenum chambers 76, 78, 80 and 82.
  • Each plenum chamber 76, 78, 80 and 82 has a substantially continuous inner boundary surface formed by the side edges 60 of the fuel cell strata 12 and side surfaces 66 of spacer bars 64 ( Figures 2, 5, 11 and 12), the side surfaces 66 being aligned with the side edges 60 of the fuel cell strata 12. It will be noted that the side edges 60 of the fuel cell strata 12 are inset from the outer side surfaces 62 of the pillars 18 and 20.
  • 29 bars 64 inte ⁇ osed between successive fuel cell strata 12 occupy the entire space between any two adjacent corner and intermediate pillars 18, 20 and between any two consecutive fuel cell strata 12, so as to completely seal off the multi-function panels 30 from the plenum chambers 76, 78, 80 and 82.
  • Plenum chambers 76, 78 can be seen to lie within a left-hand manifold a ⁇ angement on the left side of the fuel cell stack 10 (as seen in Figures 2, 5, 6, 7) and plenum chambers 80, 82 can be seen to lie within a right-hand manifold arrangement on the right side of the fuel cell stack 10.
  • one of the reactant gases is typically hydrogen, which has a tendency to permeate materials and to escape easily if there is any leak, it is important that adequate sealing be provided for the fuel cell stack 10. It is thus important that the plenum chambers 76, 78, 80, 82 be completely sealed off from one another (apart from the flowpaths interconnecting supply and exhaust plenum chambers for a given reactant gas) and from the ambient environment of the fuel cell stack.
  • fuel cell strata are manufactured as discrete composites provided with peripheral margin portions that are made of material that facilitates sealing.
  • the somewhat reslient sealed margins 29 ( Figure 11) of each fuel cell stratum 12 would be expected to provide an adequate seal around the contacting portions of the corner and intermediate posts 18, 20.
  • the spacer bars 64 are preferably formed of resilient material
  • the multi-function panels 30 such as rubber inert to reactant gases, and are preferably made slightly oversized relative to the dimensions of the rigid units of the fuel cell stack 10, so that they are under compression between adjacent intermediate and corner pillars 18, 20 and between consecutive fuel cell strata 12, thereby maintaining a tight seal between the side edges of the multi-function panels 30 and the plenum chambers 76 through 82.
  • Figures 11 and 12 illustrate the spacer bars 64 inserted into cavities 27 ( Figure 12) at the ends of the multi-function strata 30.
  • the spacer bars 64 may be provided with oversize outer end caps 25.
  • the interior dimensions of cavity 27 are preferably slightly smaller than the dimensions of the mating spacer bars 64 so as to facilitate a tight seal, but note that there is normally a positive pressure drop between the outer and inner surfaces of spacer bars 64 (the outer surfaces of spacer bars 64 being under pressure from the reactant gases), so that this pressure drop tends also to maintain the spacer bars 64 in place and to force the inner surfaces of the cap portion 25 of the spacer bars into close contact with the adjacent surfaces of the fuel cell strata 12.
  • spaces 23 outside the boundaries of open spring panels 34 may be filled with a resilient latex sealing compound deposited as a viscous paste.
  • the spacer bars 64 are glued in place within cavities 27 by means of an epoxy glue, or the like.
  • gaskets such as the gaskets 71, 73 illustrated in Figure 3 are preferably provided between the side cover plates 68, 70 and the neighbouring pillars 18, 20 against which they are mounted.
  • Mating recesses 75, 77 to receive gaskets 71, 73 may,
  • Gasket 31 if desired, be provided in the inner surface 74 of side plate 70 (and a similar arrangement would, of course, be devised for cover plate 68).
  • Sealing compound may be applied along the gasket surfaces as required in order to augment the seal.
  • Gaskets 71, 73 may be made of an inert material such as rubber, resistant to reactant gases, or they may simply take the form of seals such as silicone sealing strips applied as a viscous liquid to the inner surfaces of the cover plate 68 and 70 and then permitted to solidify.
  • ports 96, 98 are within the boundary of the recesses 75, 77 and mating gaskets 71, 73; this is, of course, essential in order that the ports 96, 98 communicate properly with the plena 80, 82 within the respective sealed-off areas thus bounded.
  • the mounting arrangement for the cover plates 68, 70 is not critical; no specific mounting means is illustrated in the schematic drawings, but, for example, threaded receptacles (not shown) could be provided along the side edges 62 of pillars 18 and 20, mating holes (not shown) could be provided in the cover plates 68 and 70, and bolts (not shown) could be passed through the mating holes in the cover plate 68 and 70 and threaded into the threaded receptacles (not shown) in the associated pillars 18, 20.
  • plenum chambers 76, 78, 80, 82 having been provided by the fuel cell stack assembly thus far described, it remains to describe the use of these plenum chambers to provide supply and exit passages for the reactant gases.
  • the fuel inlet plenum is the plenum chamber 76 communicating with fuel inlet ports 90 of the flow field 92 in flow field panel 89 illustrated in Figure 6.
  • Flow field 92 comprises a pair of discrete fuel flowpaths 93, 95 running from the inlet ports 90 to
  • the plenum chamber 78 constitutes the exhaust plenum for exhaustion of the spent fuel gas. Since the plenum chambers 76 and 78 cannot function without connection to an external source and sink respectively of fuel gas, a fuel inlet port 108 and a fuel outlet port 110 are provided in end cover plate 68 for coupling to an external source (not shown) and sink (not shown) respectively of fuel gas. For this pu ⁇ ose, any suitable coupling element may be provided at each of the ports 108, 110 for coupling to externally mounted tubing (not shown) for connection to the source and sink respectively of the fuel gas.
  • Figure 7 illustrates a representative set of se ⁇ entine oxidant flowpaths 103, 105, 107, 109, 111, 113 constituting a meandering flowpath arrangment generally indicated as 100 in the associated oxidant flowpath panel 102.
  • An exemplary six flowpaths are illustrated that are provided with a set of inlet ports 104 communicating with supply plenum chamber 80 and a set of outlet ports 106 communicating with exhaust plenum chamber 82.
  • the plenum chambers 80, 82 are provided with a supply port 96 and an exhaust port 98 respectively (Figure 2) in end cover plate 70 for attachment via suitable couplings (not shown) to tubing (not shown) providing a supply and a sink respectively of oxidant gas to the fuel cell stack.
  • auxiliary sealing cement or the like may be applied in more critical areas if need be.
  • the flowpath configurations of Figures 6 and 7 include disconnected spaces 91, 101
  • each fuel flowpath will usually be appreciably longer than each oxidant flowpath; this implies that the number of discrete flowpaths per layer will be higher for the oxidant than for the fuel.
  • Each fuel flowpath may both enter and exit on the same side of the stack and each oxidant flowpath may enter and exit on the opposite side of the stack.
  • the fuel flowpath may enter on one side of the stack and exit on the other side, the oxidant flowpath entering on the fuel path exit side and exiting on the fuel path entrance side.
  • both flowpaths may begin on one side of the stack and both may exit on the opposite side of the stack.
  • the third option mentioned above would be optimal for drainage of any su ⁇ lus water out of the fuel cell stack. (If the stack is designed properly and operating normally, all water should evaporate and be carried off with the effluent spent gases, but sometimes there can be accumulations of liquid water that have to be dealt with.) If the fuel enters and leaves on one side of the stack and the oxidant enters and leaves on the other side of the stack, then it is easier to isolate fuel and oxidant gases from one another so that leaks permitting the two gases to combine outside the fuel cell will be less likely; for this safety reason, the first option mentioned above would be preferred (that is the option embodied in Figures 6 and 7).
  • FIGs 8 and 9 illustrate optional fuel and oxidant flowpath configurations respectively that implement the second design option mentioned above.
  • fuel flow field panel 51 is provided with two meandering fuel flowpaths 47, 49 running from fuel flowpath entry ports 53, 55 to fuel flowpath exit ports 57, 59 Again a se ⁇ entine flowpath arrangement is maintained so that the adjacent porous electrode layer (not shown in Figure 8) next to the flowpaths 47, 49 may be maximally exposed to fuel gas.
  • plenum chamber 76 serves as a fuel supply plenum chamber communicating with the inlet ports 53, 55 of the fuel flowpaths
  • plenum chamber 82 serves as a spent fuel exhaust plenum chamber communicating with the exit ports 57, 59 for the fuel flowpaths.
  • oxidant flowpath entry ports 63 are on the opposite side of the fuel stack 10 from the inlet ports 53, 55 for the fuel flowpaths, and equally the outlet ports for fuel (57, 59) and oxidant (65) flowpaths respectively again are on opposite sides of the fuel stack 10, thereby enabling the objective of the second design option mentioned above to be achieved.
  • plenum chamber 80 now serves as the oxidant supply plenum
  • plenum chamber 78 serves as the spent oxidant exhaust plenum.
  • the appropriate revised connections of the plenum chambers 76 through 82 will be made to external sources and sinks of fuel and oxidant gases.
  • inlet and outlet ports for the flowpaths of Figures 8 and 9 are arbitrary and could be reversed. So ports 57, 59 ( Figure 8) could serve as fuel inlet ports and ports 53, 55 as fuel exhaust ports; similarly inlet and outlet ports 63, 65 could be reversed in Figure 9. If such reversals were made, of course the plenum chamber assignments for plenum chambers 76 through 82 would have to be reallocated. Note that such reversal of inlet and outlet port selection is feasible only if the flow channels are of umform cross-section from end to end. If the flow channels are designed to be tapered, then inlet and
  • MEA layers and separator plates are stacked together in a stack that does not include any constituent elements resembling the corrugated layers 34 inte ⁇ osed between successive fuel cell strata 12 in stack 10.
  • a compression spring is mounted between one terminal end plate of the stack and the nearest separator plate (or other rigid plate such as a special bearing plate) at one end of the stack, so that expansion or contraction of the fuel cell stack layers can be accommodated by corresponding variations in the extent of compression of the compression spring.
  • the ideal, internal pressures within the fuel cell stack can be of the order of 3 bars or higher; the spring stiffness chosen must provide adequate compression over the range of operating conditions of the stack.
  • the spring stiffness chosen should not be so high as to raise the internal pressure above the ideal when the spring is under the maximum compression provided by the operating conditions of the stack. In other words, the spring stiffness must provide a suitable compressive force to maintain the internal pressure within the ideal internal pressure range regardless of whether the spring is relatively compressed, due to, say hydro expansion, or is relatively uncompressed, due to, say,_expected MEA layer shrinkage over time.
  • Figure 13 shows a stack of fuel cells 40 of a representative PEM-type fuel cell stack.
  • the fuel cells 40 are spaced from upper end terminal plate 44 of the fuel cell stack 42 to accommodate a spring 46 that maintains the stack in compression between upper end terminal plate 44 and lower end terminal plate 43 notwithstanding continual compression and expansion of the fuel cells 40 in the stack 42. (In actual practice, a plurality of springs 46 spaced from one another over the area of upper terminal plate 44
  • the multi-function strata 30 schematically illustrated in Figure 14 together provide a distributed-spring arrangement throughout the entire fuel stack 10, so that compression and expansion of fuel cell strata 12 are accommodated locally by variations in the extent of compression.
  • the strata 30 must always be under some compression in order to assure alignment and help avoid leakage. The result is that there is no tendency of any individual fuel cell stratum 12 to move along the stack dimension within the fuel cell stack 10. If a given fuel cell stratum (say) 12 expands or contracts, the extent of compression of the associated adjacent multi- function strata 30 changes to compensate for such expansion or contraction of the fuel cell strata 12.
  • the entire assembly of fuel cell strata 12 and multi-function strata 30 are mounted under compression between terminal plates 14 and 16. The initial compression is chosen to be sufficient to compensate for expected stack shrinkage over the lifetime of the stack 10.
  • spring 46 ( Figure 13) in the conventional design would be under a compression load tending to force together the fuel cells 40 in the stack dimension.
  • each individual spring layer 56 in the distributed-spring arrangement according to the invention would always be under slight compression, such that the overall compressive load provided by the entirety of the springs 56 of Figure 14 would be roughly equal to the single compressive load exerted by spring 46 of Figure 13 (assuming comparable age, materials, dimensions, power capacity and operating conditions of the fuel cell stacks being compared).
  • the expected thermal expansion of fuel cell components can be calculated given expected temperature variations, once the coefficients of thermal expansion of the critical materials are ascertained.
  • the coefficients of thermal expansion are known for virtually all critical materials that may be used in the fuel cell stack; the critical materials are those such as any metals that do expand and contract appreciably with temperature variations. Materials that do not appreciably expand and contract with temperature variations, such as the polymeric electrolytes in PEM fuel cells, can be ignored.
  • the expected range of hydro expansion of the proton exchange membrane layer is also known from previous work in fuel cell design and testing, and in any case is best ascertained empirically. Given the calculated total expected expansion of the stack and the ideal internal pressure to be applied to the stack (which will vary with stack dimensions, materials chosen, etc.), the ideal stiffness of the compression
  • ⁇ - L p + A ⁇ L spring, K, can thus be calculated by where p is the ideal internal pressure of the stack, A is the cross- sectional area of the stack pe ⁇ endicular to the stack dimension, L is the minimum compression of the compression spring, and ⁇ L is the expected change in stack length (in the stack dimension) due to expected net thermal and hydro expansion and age-induced shrinkage. Generally, ⁇ L is small relative to L.
  • the corrugated conductive sheet 34 or equivalent or instead (and preferably) it is the welded assembly 30 of the corrugated conductive sheet (or equivalent) 34 and the two rigid conductive sheets 32, 36 bonded to the corrugated layer 34.
  • the latter is a preferred structure because of its superior stiffness and strength.
  • the collective effect of all multi-function strata 30 in the stack 10 is equivalent to the effect of the single spring or spring combination 46 that is normally used at the end of a conventional stack 42 ( Figure 13).
  • the multifunction strata 30 collectively have a combined spring stiffness equal to the ideal stiffness K given by the above equation, which would be the stiffness of the single spring 46 at the end of an equivalent conventional stack 42.
  • the next step is to calculate the required stiffness £, for each stratum 30
  • K k, K n based upon the series spring formula: where n is the number of multi-function strata in the stack, and k coordinate is the stiffness of the «th multi-function stratum.
  • Selectable parameters include the thickness of the corrugated conductive sheet 34 or equivalent, the thickness (or height) of the stratum 30, the material of which layers 32, 34, 36 are made, and the shape and period of the waveform of layer 34.
  • the deformation of the panel 30 under various loads can be calculated using a finite element analysis computer model. The calculated result may be used to guide the designer to fine-tune the foregoing parameters to make the stratum stiffer or softer until the target stiffness is achieved. Since design criteria and objectives will vary considerably from one fuel cell stack design to another, an empirical approach is recommended.
  • the fuel stack assembly described herein embodies not only an electrochemically effective design that provides cooling efficiency and mechanical stability, but it also embodies a design that can be realized with a relatively small number of constituent elements, many of which perform more than one function.
  • the several functions of the multi-function stratum has already been discussed above - each such stratum contributes to the distributed spring design and maintains dimensional stability in the stack direction.
  • the multi-function stratum also provides electrical contact between fuel cell units and provides heat-dissipating surfaces and cooling passages through the stack. Other constituent elements of the stack equally contribute to economy of manufacture.
  • the pillar/spacer/cover plate design described permits the pillars to serve as strong rigid structural elements extending longitudinally throughout the stack; these pillars also serve to define, with the inset spacer bars and marginal edges of the MEA layer, the spaces inset from the manifold cover that constitute the supply and exhaust plena for fuel and oxidant gases.
  • the space bars function not only as fillers and to the structural
  • the described embodiment also provides for easy maintenance in the event of a failure of an MEA layer or other unit of the stack. It not infrequently happens that in a fuel cell stack, some electrochemical problem arises - for example, an MEA layer fails to function properly. In such cases, with conventional PEM-type fuel cells, it is often necessary to disassemble the entire fuel cell stack and remove and replace the defective unit in order to cure the problem. By contrast, with the design of the present invention, it is possible simply to remove the mamfold cover plates, block the fuel and oxidant inlet and outlet passages of the defective unit, and provide a conductive bridge to pass current from the sound unit on one side of the defective unit to the sound unit lying on the other side of the defective unit, thereby providing electrical continuity throughout the fuel stack assembly.
  • a fuel stack assembly includes 120 fuel cells arranged in series, and one defective unit is bypassed according to the foregoing procedure, there will be a loss of 1 fuel cell, representing a power capacity decline of the 120- unit stack of something less than 1 %, which is tolerable for many fuel cell applications.
  • fuel stack design described herein lends itself to modular construction; modular stacks of, say, twenty fuel cells each could be manufactured and placed end to end in a series configuration to bring the total number of cells in a composite stack to a desired target number (say, 120 fuel cells).
  • target number say, 120 fuel cells.
  • the terminal plates 14, 16 of fuel stack 10 illustrated would, of course, have to be suitably modified for convenient end-to-end physical and electrical
  • the structural characteristics of the open spring layers 34 may be varied to increase heat dissipation.
  • the layers 34 may be provided with punched openings and/or a rough finish for improved heat dissipation capability.
  • Hydrogen may be used as a fuel gas in the fuel cell stack 10 illustrated in Figure 1 and described above. If the fuel cell strata are fuel cell units 12, then conduits for supplying hydrogen to the anode electrode layers and oxidant to the cathode electrode layers are provided by the fuel cell units 12. Alternatively, if the fuel cell strata are MEA layers 12, then when the fuel cell stack 10 is assembled, the hydrogen and oxidant flow channels provided by the rigid plates 32, 36 are thereby closed to form conduits for supplying hydrogen to the anode electrode layers and oxidant to the cathode electrode layers, respectively, of the MEA layers.

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Abstract

Empilage (10) de piles à combustible électrochimiques comprenant une série alignée de strates multifonctionnelles (panneaux) (30) placées de façon alternée entre une série correspondante de strates (12) électrochimiques actives. Dans un empilage de piles à combustible à membrane échangeuse de protons (PEM), les strates de piles à combustible électrochimiques comportent des strates d'ensembles électrodes à membrane (MEA). Les panneaux multifonctionnels servent à obtenir une intégrité structurelle et une continuité de circuit électrique à l'intérieur de l'empilage. Chaque strate multifonctionnelle comprend une couche conductrice (34) ouverte élastique, telle qu'une couche ondulée, prise en sandwich entre une paire de couches conductrices (32, 36) relativement rigides isolant la couche ouverte élastique des gaz réactifs. Les couches de la strate multifonctionnelle constituent ensemble un réseau élastique réparti exerçant une force de compression agissant dans la dimension de l'empilage, chaque couche ouverte élastique exerçant un effet de compression contre les couches conductrices rigides entre lesquelles elle est prise en sandwich. Le réseau élastique réparti permet de conserver l'intégrité dimensionnelle de l'intérieur de l'empilage grâce à un collecteur extérieur servant à alimenter l'empilage en gaz réactifs et à effectuer l'échappement de ces gaz. Les espaces situés entre les éléments élastiques ouverts servent de conduits d'air de refroidissement, de sorte que l'air de refroidissement peut s'écouler au-dessus des ondulations afin de refroidir l'empilage. Une structure de châssis simple et économique, les plaques de couverture associées et les barres de séparation de l'empilage de piles à combustible constituent et limitent un caisson de distribution séparé servant à alimenter les piles à combustible de l'empilage en gaz réactif et à opérer l'échappement de ces gaz.
PCT/GB1999/001169 1998-05-02 1999-04-30 Empilage de piles a combustible WO1999057781A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU36139/99A AU3613999A (en) 1998-05-02 1999-04-30 Fuel cell stack assembly
CA002330946A CA2330946A1 (fr) 1998-05-02 1999-04-30 Empilage de piles a combustible

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9809372.7 1998-05-02
GBGB9809372.7A GB9809372D0 (en) 1998-05-02 1998-05-02 Stack assembly primarily for an electrochemical fuel

Publications (1)

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WO1999057781A1 true WO1999057781A1 (fr) 1999-11-11

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CA (1) CA2330946A1 (fr)
GB (1) GB9809372D0 (fr)
WO (1) WO1999057781A1 (fr)

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WO2001082391A2 (fr) * 2000-04-19 2001-11-01 Millennium Cell, Inc. Cellule electrochimique et assemblage pour celle-ci
WO2002017423A1 (fr) * 2000-08-21 2002-02-28 Proton Motor Fuel Cell Gmbh Systeme de piles a combustible a membrane electrolytique polymere comportant un espace de repartition et un espace collecteur d'agent refrigerant, ainsi qu'un mode de refroidissement par substances fluides
US6566004B1 (en) 2000-08-31 2003-05-20 General Motors Corporation Fuel cell with variable porosity gas distribution layers
US6663997B2 (en) 2000-12-22 2003-12-16 Ballard Power Systems Inc. Oxidant flow field for solid polymer electrolyte fuel cell
US6663994B1 (en) 2000-10-23 2003-12-16 General Motors Corporation Fuel cell with convoluted MEA
EP1387425A1 (fr) * 2002-07-30 2004-02-04 General Electric Company Passages de fluide ameliorés pour equipement de génération d'énergie
WO2004027910A1 (fr) * 2002-09-20 2004-04-01 Powercell Svenska Ab Pile a combustible
US6720101B1 (en) 2001-06-08 2004-04-13 Palcan Fuel Cell Co. Ltd Solid cage fuel cell stack
WO2004045013A2 (fr) * 2002-11-14 2004-05-27 3M Innovative Properties Company Assemblage de piles a combustible a refroidissement liquide
EP1429406A1 (fr) * 2002-12-11 2004-06-16 SFC Smart Fuel Cell GmbH Elements d'encadrement pour assemblage monopolaire de piles à combustible
EP1246289A3 (fr) * 2001-03-31 2004-11-17 Samsung Electronics Co., Ltd. Empilement de piles à combustible à membrane échangeuse de protons
WO2006056044A1 (fr) * 2004-11-23 2006-06-01 Versa Power Systems, Ltd. Pile a combustible a oxyde solide equipee de collecteurs externes
DE112004001327B3 (de) * 2003-07-22 2008-01-17 Toyota Jidosha Kabushiki Kaisha, Toyota Brennstoffzellenanordnung
WO2008054264A1 (fr) * 2006-10-31 2008-05-08 Powercell Sweden Ab Procédé de fabrication de piles à combustible
JP2008218124A (ja) * 2007-03-02 2008-09-18 Toyota Motor Corp 燃料電池および燃料電池用締結装置
JP2009026547A (ja) * 2007-07-18 2009-02-05 Toyota Motor Corp 燃料電池および燃料電池の製造方法
US7592089B2 (en) 2000-08-31 2009-09-22 Gm Global Technology Operations, Inc. Fuel cell with variable porosity gas distribution layers
EP2235778A2 (fr) * 2007-12-28 2010-10-06 Altergy Systems Ensemble pile à combustible à éléments modulaires
US20210119238A1 (en) * 2018-03-30 2021-04-22 Osaka Gas Co., Ltd. Electrochemical Module, Method for Assembling Electrochemical Module, Electrochemical Device, and Energy System
CN113164905A (zh) * 2018-04-17 2021-07-23 以列特环球能源解决方案有限公司 用于氢释放的可更换模块化装置
CN115050988A (zh) * 2022-06-14 2022-09-13 内蒙古工业大学 一种质子交换膜燃料电池双极板加工设备

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JP5479737B2 (ja) 2006-01-09 2014-04-23 ソシエテ ビック 携帯用燃料電池システムおよびそのための方法

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Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001082391A3 (fr) * 2000-04-19 2002-02-28 Millennium Cell Inc Cellule electrochimique et assemblage pour celle-ci
US6544679B1 (en) 2000-04-19 2003-04-08 Millennium Cell, Inc. Electrochemical cell and assembly for same
WO2001082391A2 (fr) * 2000-04-19 2001-11-01 Millennium Cell, Inc. Cellule electrochimique et assemblage pour celle-ci
WO2002017423A1 (fr) * 2000-08-21 2002-02-28 Proton Motor Fuel Cell Gmbh Systeme de piles a combustible a membrane electrolytique polymere comportant un espace de repartition et un espace collecteur d'agent refrigerant, ainsi qu'un mode de refroidissement par substances fluides
US6566004B1 (en) 2000-08-31 2003-05-20 General Motors Corporation Fuel cell with variable porosity gas distribution layers
US7592089B2 (en) 2000-08-31 2009-09-22 Gm Global Technology Operations, Inc. Fuel cell with variable porosity gas distribution layers
US6663994B1 (en) 2000-10-23 2003-12-16 General Motors Corporation Fuel cell with convoluted MEA
US6663997B2 (en) 2000-12-22 2003-12-16 Ballard Power Systems Inc. Oxidant flow field for solid polymer electrolyte fuel cell
EP1246289A3 (fr) * 2001-03-31 2004-11-17 Samsung Electronics Co., Ltd. Empilement de piles à combustible à membrane échangeuse de protons
US7335436B2 (en) 2001-03-31 2008-02-26 Samsung Sdi Co., Ltd. Proton exchange membrane fuel cell stack
US6720101B1 (en) 2001-06-08 2004-04-13 Palcan Fuel Cell Co. Ltd Solid cage fuel cell stack
US7011904B2 (en) 2002-07-30 2006-03-14 General Electric Company Fluid passages for power generation equipment
EP1387425A1 (fr) * 2002-07-30 2004-02-04 General Electric Company Passages de fluide ameliorés pour equipement de génération d'énergie
US10020530B2 (en) 2002-09-20 2018-07-10 Powercell Sweden Ab Fuel cell
WO2004027910A1 (fr) * 2002-09-20 2004-04-01 Powercell Svenska Ab Pile a combustible
WO2004045013A3 (fr) * 2002-11-14 2005-07-28 3M Innovative Properties Co Assemblage de piles a combustible a refroidissement liquide
WO2004045013A2 (fr) * 2002-11-14 2004-05-27 3M Innovative Properties Company Assemblage de piles a combustible a refroidissement liquide
WO2004054024A1 (fr) * 2002-12-11 2004-06-24 Sfc Smart Fuel Cell Ag Elements de cadre pour des empilages de piles a combustibles monopolaires
EP1429406A1 (fr) * 2002-12-11 2004-06-16 SFC Smart Fuel Cell GmbH Elements d'encadrement pour assemblage monopolaire de piles à combustible
US7718300B2 (en) 2002-12-11 2010-05-18 Sfc Smart Fuel Cell Ag Frame elements for monopolar fuel cell stacks
DE112004001327B3 (de) * 2003-07-22 2008-01-17 Toyota Jidosha Kabushiki Kaisha, Toyota Brennstoffzellenanordnung
US7803474B2 (en) 2003-07-22 2010-09-28 Toyota Jidosha Kabushiki Kaisha Thermal stress tolerant fuel cell assembly within a housing
AU2005309264B2 (en) * 2004-11-23 2010-08-05 Versa Power Systems, Ltd. Solid oxide fuel cell with external manifolds
WO2006056044A1 (fr) * 2004-11-23 2006-06-01 Versa Power Systems, Ltd. Pile a combustible a oxyde solide equipee de collecteurs externes
US7291415B2 (en) 2004-11-23 2007-11-06 Versa Power Systems, Ltd. Solid oxide fuel cell with external manifolds
US8945795B2 (en) 2006-10-31 2015-02-03 Powercell Sweden Ab Methods and apparatuses for continuous manufacturing of fuel cells
WO2008054264A1 (fr) * 2006-10-31 2008-05-08 Powercell Sweden Ab Procédé de fabrication de piles à combustible
JP2008218124A (ja) * 2007-03-02 2008-09-18 Toyota Motor Corp 燃料電池および燃料電池用締結装置
JP2009026547A (ja) * 2007-07-18 2009-02-05 Toyota Motor Corp 燃料電池および燃料電池の製造方法
EP2235778A2 (fr) * 2007-12-28 2010-10-06 Altergy Systems Ensemble pile à combustible à éléments modulaires
EP2235778A4 (fr) * 2007-12-28 2013-05-15 Altergy Systems Ensemble pile à combustible à éléments modulaires
US9614232B2 (en) 2007-12-28 2017-04-04 Altergy Systems Modular unit fuel cell assembly
US20210119238A1 (en) * 2018-03-30 2021-04-22 Osaka Gas Co., Ltd. Electrochemical Module, Method for Assembling Electrochemical Module, Electrochemical Device, and Energy System
US11973253B2 (en) * 2018-03-30 2024-04-30 Osaka Gas Co., Ltd. Electrochemical module, method for assembling electrochemical module, electrochemical device, and energy system
CN113164905A (zh) * 2018-04-17 2021-07-23 以列特环球能源解决方案有限公司 用于氢释放的可更换模块化装置
CN113164905B (zh) * 2018-04-17 2024-01-12 以列特环球能源解决方案有限公司 用于氢释放的可更换模块化装置
CN115050988A (zh) * 2022-06-14 2022-09-13 内蒙古工业大学 一种质子交换膜燃料电池双极板加工设备
CN115050988B (zh) * 2022-06-14 2023-05-23 内蒙古工业大学 一种质子交换膜燃料电池双极板加工设备

Also Published As

Publication number Publication date
GB9809372D0 (en) 1998-07-01
AU3613999A (en) 1999-11-23
CA2330946A1 (fr) 1999-11-11

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