WO1999035889A1 - Electroluminescent lamps having improved interfacial adhesion - Google Patents
Electroluminescent lamps having improved interfacial adhesion Download PDFInfo
- Publication number
- WO1999035889A1 WO1999035889A1 PCT/US1998/027485 US9827485W WO9935889A1 WO 1999035889 A1 WO1999035889 A1 WO 1999035889A1 US 9827485 W US9827485 W US 9827485W WO 9935889 A1 WO9935889 A1 WO 9935889A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- polyureasilazane
- phosphor
- dielectric layer
- polymeric matrix
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/22—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/62—Nitrogen atoms
Definitions
- the present invention relates to electroluminescent lamps
- the present invention relates to electroluminescent lamps having improved interfacial adhesion and improved environmental resistance
- Electroluminescent lamps provide an attractive alternative to conventional lighting systems, especially for display and backlighting devices.
- An electroluminescent (hereinafter "EL") lamp is electrically similar to a capacitor.
- a typical EL lamp consists of a dielectric layer and a light-emitting phosphor layer sandwiched between two conductive surfaces, a transparent front electrode and a rear electrode.
- the primary purpose of the dielectric layer is to allow the lamp to withstand higher voltages without shorting between the conductive surfaces
- the phospor layer comprises phosphor particles, typically zinc sulfide or other phosphorescent particles known in the art, suspended in a polymeric matrix.
- EL lamps illuminate when powered with alternating current (AC-power) As voltage is applied to the conductive surfaces, an electric field is generated across the phosphor and dielectric layers. Twice during each cycle electrons are excited from the valence band into the conduction band Many of these excited electrons emit light though the transparent front electrodes as they return to their ground state.
- AC-power alternating current
- One of the major technological barriers to widespread use of EL lamps has historically been their sensitivity to environmental conditions, particularly moisture. As is well-known, phosphor particles degrade in the presence of moisture, and thus must be protected from environmental humidity.
- One method of protecting phosphor particles has been to shield the particles by encapsulating the EL lamp assembly in a fused, water-resistant poly(chlorotrifluoroethylene) envelope
- Another particularly successful method employs microencapsulation of the individual phosphor particles in a glass-like coating, as described in U.S. Patent Nos. 5,593,782, 5,439,705; and 5,418,062 to Kenton D. Budd and assigned to Minnesota Mining and Manufacturing Company, the relevant portions of which are herein incorporated by reference
- microencapsulation has provided EL lamps with greatly improved resistance to environmental moisture, there still remains a need for additional methods to meet the exacting environmental performance standards required by many users of EL lamps
- the EL assembly and method of manufacture thereof wherein at least one of the phosphor layer or the dielectric layer comprises a polyureasilazane polymer.
- the polyureasilazane may be added to the fluoropolymer resin of the phosphor layer or the dielectric layer, or the polyureasilazane may be used to coat the phosphor particles within the phosphor layer or the inorganic filler particles within the dielectric layer, or a combination of the preceding may be used.
- the polyureasilazane provides better adhesion between and within the layers, probably due to forming a covalent chemical bond between the ceramic filler and the fluoropolymeric matrix Covalent bonding between the filler and matrix is expected to improve environmental resistance, particularly to high humidity
- Polyureasilazane may also be used in other EL assembly layers described below
- FIGURE 1 is a schematic diagram of an EL lamp assembly in accordance with the present invention.
- FIGURE 2 is the structure of a polyureasilazane useful in accordance with the present invention.
- FIG 1 An EL assembly according to the present invention is shown generally at FIG 1, comprising a front transparent electrode 12, a light-emitting phosphor layer 14, a dielectric layer 16, and rear electrode 18
- Front transparent electrode 12 itself comprises a transparent substrate layer 12A and an electrode layer 12B
- Transparent substrate 12A is typically a hard plastic such as polyethylene terepthalate
- a preferred transparent substrate material is available from E. I DuPont de Nemours under the trade name MYLAR.
- Electrode layer 12B is typically indium tin oxide (ITO) deposited onto transparent substrate layer 12A by methods known in the art, for example by sputtering
- Light-emitting phosphor layer 14 is formed by printing luminescent ink onto the transparent electrode layer 12B
- the luminescent ink comprises luminescent particles 14A in a polymeric matrix 14B
- the luminescent particles may be zinc sulfide (ZnS) doped with copper, or other compositions that exhibit fluorescence
- Polymeric matrix 14B is typically a fluoride resin binder, for example polymers derived from vinylidene fluoride, ethylene fluoride, vinyl fluoride, ethylene trifluoride, ethylene chloride trifluoride, ethylene tetrafluoride, propylene hexafluoride, and the like, as well as copolymers (including terpolymers) of the preceding.
- Preferred resins include copolymers containing poly(vinylidene fluoride) (PvDF) available from Pennwalt Corporation under the trade names KYNAR 7201 and KYNAR 9301.
- Dielectric layer 16 comprises a high dielectric composite material comprising a fluoride resin binder and an inorganic, particulate filler.
- Suitable fluoride resin binders include polymers derived from vinylidene fluoride, ethylene fluoride, vinyl fluoride, ethylene trifluoride, ethylene chloride trifluoride, ethylene tetrafluoride, propylene hexafluoride, and the like, as well as copolymers of the preceding.
- Preferred resins include copolymers containing poly(vinylidene fluoride) available from Pennwalt Corporation under the trade names KYNAR 7201 and KYNAR 9301.
- the KYNAR PvDF copolymers are typically made into a screen printable ink by dissolution in an amount of about 20 to 50% by weight in a suitable solvent such as NN- dimethylacetamide (DMAc).
- a suitable solvent such as NN- dimethylacetamide (DMAc).
- DMAc NN- dimethylacetamide
- Higher boiling point solvents such as 2-butoxyethyl acetate (EB acetate) may also be added to decrease the solvent evaporation rate of the ink.
- Suitable inorganic, particulate fillers include high dielectric materials such as barium titanate (BaTi0 3 ), titania (Ti0 2 ) and the like.
- the inorganic particulate fillers are commonly pre-treated to reduce moisture uptake with compounds such as alkoxyorganosilanes, organotitanates, and zirconates.
- organosilanes to improve moisture resistance of EL lamps is taught in U.S. Patent 5,552,668 to Hirose et al., assigned to Seiko Precision, Inc., the relevant parts of which are incorporated herein by reference. Silicone resins are also sometimes added to the particulate-filled ink to reduce water absorption.
- Rear electrode 18 is generally a screen-printable conductive ink and also comprises a polymeric composite, including for example a polyester, epoxy, or acrylic resin and a conductor such as carbon black, nickel, copper, or silver flake, fibers or particles.
- the transparent electrode layer 12B is formed on the transparent substrate 12A by evaporative methods such as sputtering
- the phosphor layer 14 is then formed from a luminescent ink onto electrode layer 12B by screen printing or other methods known in the art, and heated and dried.
- a dielectric ink formed by mixing the high dielectric filler into the resin binder, along with additives known in the art, then applied to the surface of phosphor layer 14, heated, and dried.
- the rear electrode is also applied to the assembly in the form of a conductive ink, heated, and dried.
- polyureasilazane polymer confers greater adhesion, as well as improved environmental resistance.
- a preferred polyureasilazane is available from Lanxide Performance Materials, Newark, Delaware, under the trade name CERASET
- polyureasilazanes accrues from the multiple functional groups present in polyureasilazanes, in particular the ureasilazane moieties (Si-NH-CO-NR-) These functional groups may react with the matrix resins present in the various assembly layers.
- Polyureasilazanes may also strongly associate with ceramic, metal, and metal oxide surfaces.
- the combination of reaction with polymer and association with ceramic, metal, and metal oxide surfaces provides enhanced adhesion upon exposure to high temperature and high humidity environments.
- the polyureasilazane may be added to the fluoropolymer resin of the phosphor layer or the fluoropolymer resin of the dielectric layer When added to the fluoropolymer resin portions of these layers, the polyureasilazane serves to increase adhesion between the ITO electrode layer and the phosphor layer, as well as adhesion between the phosphor particles and the polymeric matrix and the filler particles and the polymeric matrix.
- the polyureasilazane is added to the ink in an amount of between about 0.01% to about 10% by weight on a dry solids basis.
- the polyureasilazane is added to the ink in an amount of between about 0.01% to about 0.5% ⁇ by weight on a dry solids basis, in order to optimize adhesion, while minimizing discoloration of the ink.
- An amount of about 1% by weight on a dry solids basis of polyureasilazane results in an ink having a pale yellow color.
- Addition of polyureasilazane to fluoropolymer inks results in foaming and gelation, indicative of reaction (cross-linking) with the fluoropolymer resin..
- the particles When used to coat the phosphor particles of the phosphor layer or the inorganic filler particles of the dielectric layer, the particles are treated with polyureasilazane to provide particles that are used in a ratio in the range from about 0.5: 1 to about 4: 1 particles:fluoropolymer by weight, and preferably a ratio of about 0.8: 1 to 3: 1. Coupons of the dielectric layer made with this ratio of filler and polyureasilazane exhibit flex and tensile moduli higher than coupons made with conventional silane-treated particles. Use of the polyureasilazane polymer provides therefore provides enhanced adhesion between the filler and the polymeric matrix, as well as enhanced hydrolytic stability. The following non-limiting examples will further serve to illustrate the present invention.
- a screen printable ink was prepared consisting of 25 weight % KYNAR 7201 PVdF copolymer dissolved in a mixture of 66 weight % DMAc and 9 weight % EB acetate. Either 0.1% or 0.5% CERASET polyureasilazane by weight on a dry solids basis was added to the KYNAR 7201 ink. The inks were allowed to sit either 20 minutes or overnight after mixing, and then coated onto the electrode side of coupons of a transparent front electrode consisting of Mylar sputtered with indium tin oxide. After coating, the assembly was dried in an oven at 150 °C for 30 minutes.
- Similar 3:1 fille ⁇ resin inks were also prepared using conventionally treated fillers for the purposes of comparison.
- the "AT-silane” sample was made using COF-70 barium titanate that was pre-treated with a proprietary organotrialkoxysilane compound.
- the "RJ-silicone” sample was prepared by adding a proprietary silicone resin to the mixture of "untreated” COF-70 barium titanate and KYNAR 7201 ink. The "untreated” sample simply using the COF-70 filler as received from the manufacturer.
- the coupons were also plied up to about 0.040 inches, and laminated at 150 °C at 330 psi in a laboratory press. "Dog bone" shaped samples were cut for tensile testing at a rate of 0.05 inches per minute. The sample with untreated filler was too fragile and brittle to cut for a test specimen. Results are also reported in the Table below. Finally, the samples were molded to approximately 0.060 inch thick plaques in a 4- inch diameter disk mold at 375 °C at 330 psi for about 30 minutes. The samples were cut into 3 -inch by '/2-inch strips and tested for flexural modulus on an Instron set at a speed of 0.05 inches/minute with a 2-inch span. The results are reported in the Table below. speed of 0.05 inches/minute with a 2-inch span. The results are reported in the Table below.
- the treated filler was mixed with KYNAR 7201 ink in a ratio of about 3: 1 fille ⁇ resin solids, cast on Mylar, dried, molded, and flex tested as described in Example 2.
- the treated phosphor was also mixed with KYNAR 7201 resin in a ratio of about 1.8: 1 phosphor: resin on a dry weight basis, molded into samples and flex tested as in Example 2. The results are shown in the Table below.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000528136A JP2002501293A (en) | 1998-01-06 | 1998-12-23 | Electroluminescent lamp with improved interfacial adhesion |
EP98965481A EP1044585A4 (en) | 1998-01-06 | 1998-12-23 | Electroluminescent lamps having improved interfacial adhesion |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7055898P | 1998-01-06 | 1998-01-06 | |
US60/070,558 | 1998-01-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999035889A1 true WO1999035889A1 (en) | 1999-07-15 |
Family
ID=22096028
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/027485 WO1999035889A1 (en) | 1998-01-06 | 1998-12-23 | Electroluminescent lamps having improved interfacial adhesion |
Country Status (4)
Country | Link |
---|---|
US (1) | US6198216B1 (en) |
EP (1) | EP1044585A4 (en) |
JP (1) | JP2002501293A (en) |
WO (1) | WO1999035889A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6198216B1 (en) * | 1998-01-06 | 2001-03-06 | World Properties, Inc. | Electroluminescent lamps having improved interfacial adhesion |
US6787988B2 (en) | 2001-11-13 | 2004-09-07 | Durel Corporation | Process for treating previously coated phosphor particles |
JPWO2003055274A1 (en) * | 2001-12-17 | 2005-04-28 | 植澤 俊一 | ELECTROLUMINESCENT DEVICE AND MANUFACTURING METHOD THEREOF |
DE102004004311A1 (en) * | 2004-01-28 | 2005-08-18 | Fer Fahrzeugelektrik Gmbh | Production method for an El lamp |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6445128B1 (en) * | 1999-08-23 | 2002-09-03 | Durel Corporation | EL panel made with low molecular weight PVDF/HFP resin |
JP2003017264A (en) | 2001-04-27 | 2003-01-17 | Canon Inc | Electroluminescent element and image display device |
CN100408650C (en) * | 2002-04-10 | 2008-08-06 | 弗莱肯公司 | Hydro-insensitive electroluminescent devices and methods of manufacture thereof |
CN1675044A (en) * | 2002-08-20 | 2005-09-28 | 科罗拉多大学董事会 | Polymer derived ceramic materials |
US6774432B1 (en) * | 2003-02-05 | 2004-08-10 | Advanced Micro Devices, Inc. | UV-blocking layer for reducing UV-induced charging of SONOS dual-bit flash memory devices in BEOL |
US7118967B1 (en) | 2003-02-19 | 2006-10-10 | Spansion, Llc | Protection of charge trapping dielectric flash memory devices from UV-induced charging in BEOL processing |
US20050035705A1 (en) * | 2003-08-11 | 2005-02-17 | Haas William S. | Illumination system |
US20050104509A1 (en) * | 2003-11-19 | 2005-05-19 | Fuji Photo Film Co., Ltd. | Electroluminescent device |
US6989563B1 (en) | 2004-02-02 | 2006-01-24 | Advanced Micro Devices, Inc. | Flash memory cell with UV protective layer |
US7202600B2 (en) * | 2004-03-02 | 2007-04-10 | World Properties, Inc. | Dimensionally stable electroluminescent lamp without substrate |
US7091088B1 (en) | 2004-06-03 | 2006-08-15 | Spansion Llc | UV-blocking etch stop layer for reducing UV-induced charging of charge storage layer in memory devices in BEOL processing |
WO2005122651A1 (en) * | 2004-06-07 | 2005-12-22 | Matsushita Electric Industrial Co., Ltd. | Light-emitting device and display |
US9150757B2 (en) * | 2010-08-17 | 2015-10-06 | Texas State University | Durable ceramic nanocomposite thermal barrier coatings for metals and refractories |
BR112013009952B1 (en) * | 2010-10-29 | 2021-08-24 | Rohm And Haas Company | THERMOPLASTIC COMPOSITION, METHOD FOR PRODUCING A THERMOPLASTIC COMPOSITION AND ARTICLE |
US9818499B2 (en) | 2011-10-13 | 2017-11-14 | Flexcon Company, Inc. | Electrically conductive materials formed by electrophoresis |
US8673184B2 (en) | 2011-10-13 | 2014-03-18 | Flexcon Company, Inc. | Systems and methods for providing overcharge protection in capacitive coupled biomedical electrodes |
US9935246B2 (en) | 2013-12-30 | 2018-04-03 | Cree, Inc. | Silazane-containing materials for light emitting diodes |
US9994732B1 (en) * | 2014-09-12 | 2018-06-12 | Steven Martin Johnson | Polysilazane and fluoroacrylate coating composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4950950A (en) * | 1989-05-18 | 1990-08-21 | Eastman Kodak Company | Electroluminescent device with silazane-containing luminescent zone |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2826337B2 (en) | 1988-04-12 | 1998-11-18 | シチズン時計株式会社 | Radiation thermometer |
US4929704A (en) | 1988-12-20 | 1990-05-29 | Hercules Incorporated | Isocyanate- and isothiocyanate-modified polysilazane ceramic precursors |
US5032649A (en) | 1989-11-27 | 1991-07-16 | Hercules Incorporated | Organic amide-modified polysilazane ceramic precursors |
US5155181A (en) | 1989-11-27 | 1992-10-13 | Hercules Incorporated | (Thio)amide-modified silazane polymer composition containing a free radical generator |
US5593782A (en) | 1992-07-13 | 1997-01-14 | Minnesota Mining And Manufacturing Company | Encapsulated electroluminescent phosphor and method for making same |
US5156885A (en) | 1990-04-25 | 1992-10-20 | Minnesota Mining And Manufacturing Company | Method for encapsulating electroluminescent phosphor particles |
JP2844896B2 (en) * | 1990-10-17 | 1999-01-13 | 信越化学工業株式会社 | Heat resistant insulation paint |
US5552668A (en) | 1993-10-15 | 1996-09-03 | Seiko Precision Inc. | Self-waterproofing electroluminescent device |
US5616650A (en) | 1993-11-05 | 1997-04-01 | Lanxide Technology Company, Lp | Metal-nitrogen polymer compositions comprising organic electrophiles |
US5612414A (en) | 1993-11-05 | 1997-03-18 | Lanxide Technology Company, Lp | Organic/inorganic polymers |
US5558908A (en) * | 1994-11-07 | 1996-09-24 | Lanxide Technology Company, Lp | Protective compositions and methods of making same |
US5761367A (en) * | 1996-08-13 | 1998-06-02 | Lanxide Technology Company, Lp | Coated optical devices and methods of making the same |
EP1044585A4 (en) * | 1998-01-06 | 2001-09-26 | Rogers Corp | Electroluminescent lamps having improved interfacial adhesion |
-
1998
- 1998-12-23 EP EP98965481A patent/EP1044585A4/en not_active Withdrawn
- 1998-12-23 WO PCT/US1998/027485 patent/WO1999035889A1/en not_active Application Discontinuation
- 1998-12-23 JP JP2000528136A patent/JP2002501293A/en active Pending
- 1998-12-28 US US09/221,885 patent/US6198216B1/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4950950A (en) * | 1989-05-18 | 1990-08-21 | Eastman Kodak Company | Electroluminescent device with silazane-containing luminescent zone |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6198216B1 (en) * | 1998-01-06 | 2001-03-06 | World Properties, Inc. | Electroluminescent lamps having improved interfacial adhesion |
US6787988B2 (en) | 2001-11-13 | 2004-09-07 | Durel Corporation | Process for treating previously coated phosphor particles |
JPWO2003055274A1 (en) * | 2001-12-17 | 2005-04-28 | 植澤 俊一 | ELECTROLUMINESCENT DEVICE AND MANUFACTURING METHOD THEREOF |
JP4641722B2 (en) * | 2001-12-17 | 2011-03-02 | 植澤 俊一 | ELECTROLUMINESCENT ELEMENT AND MANUFACTURING METHOD THEREOF |
DE102004004311A1 (en) * | 2004-01-28 | 2005-08-18 | Fer Fahrzeugelektrik Gmbh | Production method for an El lamp |
Also Published As
Publication number | Publication date |
---|---|
JP2002501293A (en) | 2002-01-15 |
EP1044585A4 (en) | 2001-09-26 |
EP1044585A1 (en) | 2000-10-18 |
US6198216B1 (en) | 2001-03-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6198216B1 (en) | Electroluminescent lamps having improved interfacial adhesion | |
US5352951A (en) | Electroluminescent device | |
EP0328120B1 (en) | Electroluminescent composition and electroluminescent device therewith | |
EP0830807B1 (en) | Electroluminescent lamp having a terpolymer binder | |
GB1581830A (en) | Phosphors | |
US5068157A (en) | Electroluminescent element | |
US5552668A (en) | Self-waterproofing electroluminescent device | |
CN111286975B (en) | Electroluminescent fiber | |
JPH06310279A (en) | Electroluminescence lamp | |
CA2062278A1 (en) | Electroluminescent device | |
JP2000100571A (en) | Distributed type electroluminescent device | |
JP2526642B2 (en) | Transparent conductive film | |
KR0180070B1 (en) | Organic eletroluminescent device and its manufacturing method | |
JPH0785974A (en) | Dispersion type electroluminescent element | |
JPH07114988A (en) | El element | |
JPH05315072A (en) | El element | |
JP2806651B2 (en) | Dispersion type electroluminescence device | |
JPS62264593A (en) | Electric field light emitting device | |
JPS6041437B2 (en) | electroluminescent device | |
JPS6218254A (en) | Laminate | |
US3290536A (en) | Electroluminescent lamp with homogeneous phosphor-dielectric layer | |
JPH02152194A (en) | Distributed el element | |
JPS6180792A (en) | Manufacture of electroluminescence element | |
KR19980051991A (en) | High adhesive transparent conductive film for electro luminescence display element and manufacturing method thereof | |
JPH07305055A (en) | Dispersion type electric field emission element |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AT CH DE DK ES FI GB JP LU PT SE |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1998965481 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref country code: JP Ref document number: 2000 528136 Kind code of ref document: A Format of ref document f/p: F |
|
WWP | Wipo information: published in national office |
Ref document number: 1998965481 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 1998965481 Country of ref document: EP |