WO1999027895A2 - Pate a empreinte dentaire a virage de teinte - Google Patents

Pate a empreinte dentaire a virage de teinte Download PDF

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Publication number
WO1999027895A2
WO1999027895A2 PCT/US1998/025523 US9825523W WO9927895A2 WO 1999027895 A2 WO1999027895 A2 WO 1999027895A2 US 9825523 W US9825523 W US 9825523W WO 9927895 A2 WO9927895 A2 WO 9927895A2
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WO
WIPO (PCT)
Prior art keywords
composition
teeth
dental impression
impression
dental
Prior art date
Application number
PCT/US1998/025523
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English (en)
Other versions
WO1999027895A3 (fr
Inventor
John P. Curtis
Lisa Christina-Beck
Scott Jacobs
Original Assignee
Colgate-Palmolive Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate-Palmolive Company filed Critical Colgate-Palmolive Company
Priority to AU16179/99A priority Critical patent/AU1617999A/en
Publication of WO1999027895A2 publication Critical patent/WO1999027895A2/fr
Publication of WO1999027895A3 publication Critical patent/WO1999027895A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/90—Compositions for taking dental impressions

Definitions

  • the present invention relates to the a composition and method for the taking of dental impressions and the delivery of actives to the tooth and gum surfaces and more particularly, wherein a temperature indicator is present to signal when the dental impression material is at the proper temperature for application and removal.
  • a dental impression provides a mold which is, in essence, an exact replica of the reverse image of a dental arch or arches or area of a dental arch.
  • a dental impression is classified as full arch upper maxillary, full arch lower mandibular, antior, quadrant, or bite registration.
  • Dental impression focuses on the precise size and position of the teeth, the gingival tissues, and any surgical alterations so that a working model may be produced. It is on this working model that a dental prosthetic device will be fabricated for eventual insertion into the mouth of a dental patient.
  • the reverse image mold of the particular dental arch, or arches, or area of dental arch forms a well into which medicinal or hygiene agents can be held and when this mold is reapplied about the teeth and gums the agent is correspondingly so applied thereon.
  • Dental trays are one example of a dental impression device.
  • Dental trays are receptacles used to carry a medicine or dental hygiene material, such as a bleaching agent or fluoride for application to the teeth and/or gums, or to provide within a malleable material carried therein an impression of the teeth and/or gums.
  • the dental tray confines the particular malleable material next to the teeth and/or gums during the application or impression process.
  • U.S. Patent 5,616,027 discloses a dental tray system which includes a pliable resilient outer carrier tray and an inner tray both of thermoplastic material, the inner tray nests inside the outer carrier tray. The outer configuration of both trays adapt to fit over the upper or lower teeth.
  • the thermoplastic material of which the inner tray is formed becomes pliable and moldable to readily take an impression of the teeth or gums, while the outer tray maintains its pliable resilient, supportive structure within this temperature range.
  • the tray assembly is submerged into hot water or other suitable non-solvent liquid, so that the inner tray will substantially lose integrity of its shape and form during the heating process, while in the temperature range of 145° to 160° F, and will regain shape integrity when cooled to below of 145°F.
  • a drawback to this method of customizing the dental tray to an individual patient's teeth is that there has been no practical means to identify when the material of the inner tray has reached 145° to 160° F and can be applied to the teeth or when it has sufficiently cooled so as to be removed from the teeth and still maintain an accurate impression.
  • U.S. Patent 5,503,552 discloses an extruded thermoplastic ethylene vinyl acetate copolymer usable for dental impressions.
  • a device used to form a dental impression, of the copolymer is placed into a container of hot water from 150° to 180° F for a period of from 30 to 300 seconds to soften the copolymer, prior to application into the mouth.
  • the pre-form after being heated, has a minimum time for removal from the mouth of less than 10 minutes.
  • a drawback is identifying when the pre-form has reached a temperature sufficient to soften it so as to accept the desired dental impression and subsequently when it has cooled sufficiently to be removed from the mouth while retaining the desired dental impression therein.
  • U.S. Patents 5,596,025 and 4,788,240 disclose the use of color change indicators for estabUshing the cure point of certain silicone based polymeric systems, to signal when the mixture becomes "gelled” and has been cured irreversibly into a cross-Linked polymer indicating that the setting process has been completed.
  • U.S. 4,788,240 discloses a polyorganosiloxane composition, which can be obtained by adding anthraquinone dyes and/or azo dyes to a silicone elastomer composition which is cured by reaction of hydrosilyl radicals with alkenyl radicals bonded to silicon atoms, so that a change in color or fading out of color will occur as the cure thereof goes on.
  • 5,596,025 discloses the use of a cure-indicating dye, which exhibits a color change in the presence of a silicon-bonded-hydrogen compound and a precious metal hydrosilation catalyst.
  • the particular color change indicators of U.S. Patents 5,596,025 and 4,788,240 exhibit only a single color change and are not helpful for indicating when the polymeric system has softened to accept the desired dental impression.
  • U.S. Patent 4,768,951 discloses a transparent thermoplastic dental tray containing a light-cuiing resin on the inside face thereof or containing a conventional impression- taking material cured by chemical reactions such as an alginate or rubber based material.
  • U.S. 4,768,951 further discloses that the thermoplastic dental tray may contain for convenience, a temperature indicator, to change in color tone to indicate the softened state of the dental tray by heat. This single color change is not helpful for indicating when the light-curing resin on the inside face of the dental tray has hardened so as to be removed from the mouth without any distortion in the dental impression occurring.
  • an indicator of the warming of a dental impression material to be softened, so as to accept a dental impression, and the cooling of that dental impression material to allow removal from the mouth without any distortion of the dental impression therein.
  • a dental impression composition of a thermoplastic polymer material and containing therein from about 2 to about 10% by weight of a thermal color indicator; which thermoplastic polymer material changes color at the warm impression temperature of the thermoplastic polymer composition to indicate that the thermoplastic polymer composition is soft and malleable and ready for application to the teeth, and which thermoplastic polymer composition upon cooling changes back to its original color, indicating the thermoplastic polymer composition has cooled to a solid state sufficient for removal from the teeth, while maintain an impression thereof.
  • thermoplastic impression materials of the present invention are heat softenable substances that are solid at temperatures of from about 100° F to about 120° F and below. Preferably they are free of objectionable taste or odor, and safe for use in the mouth.
  • the malleable or softened (“warm impression") state is characterized by appreciable mass flow of the thermoplastic impression material under moderate (hand) pressure at some temperature between the from about 100° F to about 120° F (i.e. the warm impression transition temperature is from about 100°F to about 120°F) and the maximum temperature that can comfortably be withstood by oral tissues. This maximum temperature is generally thought to be about 170° F to about 180° F, although a maximum of about 150° F to about 160° F is preferred.
  • the thermoplastic impression material should have sufficient warm impression fluidity and malleability to conform accurately to adult dentition and the gingival margin.
  • thermoplastic impression materials of the present invention include polycaprolactones, which are aliphatic polyester elastomers; ethylene vinyl acetate copolymer (EVA) elastomers; styrene based plastics, such as polystyrene and its copolymers; acrylate based plastic, including polyacrylate and polymethacrylate resins; fluorine based plastics, such as polytetrafluoroethylene; polyvinyl fluoride, and polychlorotrifluorethylene; the diene based plastics, polybutadiene and its derivatives, and polyisoprene and its derivatives; urethane based plastics, such as polyurethane and its derivatives; and ethylenical based plastics, such as ethylene copolymers and their ionomer resins, and blends of these various resins, plastics and elastomers.
  • EVA ethylene vinyl acetate copolymer
  • EVA copolymers are particularly useful in the practice of the present invention, and are commercially available as under the trade name designations: "Elvax” resins 40- W, 150, 220, 250, 260, and 350 from E.I. DuPont de Nemours & Co; "Ultrathene” EVA resins from Quantum Chemical Corp. ; and "Escorene” EVA resins from Exxon Chemicals Co.
  • the ionomer resins of ethylene copolymers are preferred. Such ionomer resins may be obtained by the reaction of the base copolymers with metal ions capable of ionizing them.
  • the base copolymers used may include ethylene/acrylic acid copolymers, ethylene/methacrylic acid copolymers, and ethylene/itaconic acid copolymers, and the metal ions to react with and ionize such base copolymers include Na+ , and K+.
  • thermoplastic resin particularly useful in the present invention includes high molecular weight polycaprolactones, as well as, blends of high and low molecular weight polycaprolactones, referring to high molecular weight polycaprolactones as epsilon-caprolactone homopolymers or copolymers whose molecular weight is of the order of 20,000 or more, and low molecular weight polycaprolactones as having a molecular weight of less than about 10,000.
  • polycaprolactones are available from Union Carbide Corporation, Danbury, Ct, 06817, such as under the tradename of PCL polycaprolactones.
  • a preferred high molecular weight polycaprolactone preferably used in combination with other resins, plastics and elastomers is an aliphatic polyester elastomer having a molecular weight of 40,000 to 80,000, available under the tradename of Capra 650, from Solvoy-Interox,
  • thermoplastic impression composition of the present invention fillers, plasticizers, stabilizers, and antioxidants may be added thereto.
  • a preferred stabilizer is tris(2,4-di-tert-butylphenyl) phosphite.
  • Preferred antioxidants include antioxidant tetrakis[methylene(3,5-di-tert-butyl 1,4- hydroxyhydrocinnamate)] methane and Ingraox 1010 and Igraphos 160, available from Ciba Geige.
  • the total amount of additives should preferably be less than 70 weight % based on the total weight of the thermoplastic impression composition. With the additives used in an amount greater than about 70 weight %, no sufficient heat softening property may be obtained.
  • fillers are calcium carbonate, molten powdery calcium, titanium dioxide, zirconium silicate, aluminum silicate, silica, M. M. A. polymers, vinyl chloride powders, alumina, glass, kaolin, anhydrous silicic acid, hydrous silicic and the like.
  • a preferred silica filler is Hisil 233, available from PPG Industries.
  • Useful natural plasticizers e.g. oils
  • Useful synthetic plasticizers e.g. phthalate esters
  • thermoplastic impression composition having heat softening properties according to the present invention also excel in the resistance to attack by chemicals such as alcohols, carbolic acid, chlorohexyzine and cationic soap etc. , since they may be sterilized and cleaned by immersion in aqueous solutions thereof for repeated use.
  • An essential feature of the present invention is the addition of from about 2 to about 10% by weight of a thermal color change indicator to the thermoplastic polymer material (which is hard at room/ambient temperature), to provide a color change when the combined thermoplastic impression composition has been heated to a temperature sufficient to become softened and malleable for application to the dentition and supporting gums (i.e.
  • thermoplastic impression composition the composition's warm impression state
  • thermoplastic impression composition also to indicate when the thermoplastic impression composition has cooled to a rehardened state, to allow removal from the dentition and gums while maintain an accurate impression thereof.
  • Identification of the precise point at which the thermoplastic impression composition reaches the desired warm impression state is not only important as a time saving feature; but, certain thermoplastic materials, such as polyvinyl acetate; tend to swell and become too soft when immersed in water too long.
  • U.S. Patent 4,717,710 discloses a thermal color change indicator disclosed to be useful in printing inks, coating and inco orated into waxes, soaps and synthetic resins, such as in the present invention, which when heated to a critical temperature will change from its original color to clear and which when subsequently cooled below the critical temperature will return to its original color.
  • the thermal color change indicator is composed of (1) an electron-donating chromogenic material; (2) a 1,2,3-triazole compound; (3) a weakly basic, sparingly soluble aromethine or carboxylic acid primary amine salt; and (4) an alcohol, amide or ester serving as a solvent.
  • the electron- donating chromogenic material is the color providing component and is from 0.1 to 20% by weight of the thermal color change indicator.
  • Particular electron-donating chromogenic materials which may be used individually or in combination include substituted phenylmethanes and fluorans such as 3,3'-dimethoxyfluoran (yellow), 3- chloro-6-phenylaminofluoran (orange), Crystal Violet lactone (blue), Malachite Green lactone (green) and 3,3'-bis-(p-dimethylaminophenyl)phthalide (green).
  • the triazole compound component of the thermal color indicator is present in an amount of from 0.1 to 40% by weight of the thermal color change indicator and includes such compounds as 1,2,3-benzotriazole, 1,2,3-triazole ethyl 4-methyl-5- carboxylate, 4(5)-hydroxy-l,2,3-triazole and 5(6)-methyl-l,2,3-benzotriazole.
  • the azomethine or carboxylic acid primary amine salt component of the thermal color indicator is present in an amount of from 0.5 to 50% by weight of the thermal color change indicator.
  • Useful azomethines include those having the following formula:
  • R-CH N-R'
  • R-CH N-R'-N-CH-R
  • R and R' are each an aliphatic residue, substituted aliphatic residue, aromatic residue, substituted aromatic residue, heterocyclic residue or substituted amino group, wherein each of the formulae include one aromatic residue and one substituted aromatic residue.
  • R and R' are defined above, and x and y are each an integer.
  • useful carboxylic acids include aliphatic carboxylic acids such as caprylic acid, capric acid, lauric acid, myristic acid and stearic acid.
  • primary amines which are to be reacted with such carboxylic acids include aliphatic primary amines such as caprylamine, laurylamine, myristylamine, stearylamine and coconut amine.
  • Suitable solvents for use as the fourth component of the thermal color change indictor include alcohols, amides, or esters in an amount of 1 to 50% by weight of the color change indicator.
  • the alcohols can be saturated monohydric alcohols including octyl alcohol, nonyl alcohol, and cetyl alcohol, as well as, unsaturated alcohols, which include geraniol, nerol, linalool and oleyl alcohol.
  • the amides which are useful as solvents include acetamide, caprylic acid amide, lauric acid amide, myristic acid amide, stearic acid amide and benzimidazole.
  • the esters which are useful as solvents include stearic acid glyceride, lanolin, diphenyl phthalate, lauric acid glyceride, and palmitic acid glyceride.
  • This particular thermal color change indicator will be appear blue at temperatures of about 140°F or less, and over about 140°F will become clear.
  • the thermoplastic impression materials of the present invention which are generally white in color, the mixture will appear blue below about 140°F and white above about 140°F.
  • thermocolor indicators compatible with the thermoplastic impression materials of the present invention and which provide the desired softening/hardening indication of the thermoplastic impression composition, at above 120° F, are available from Chroma Corporation, McHenry, Illinois, under the trade designations Chromacolor Type 60 PP-mauve and PP-light green.
  • Chromacolor PP- light Green Type 60 is green at ambient room temperature and turns the white of the underlying thermoplastic impression composition above 120° F, remaining white to at least the maximum comfortable temperature of about 160° to about 180° F and returning to green upon cooling and Chromacolor PP-mauve Type 60 is purple at ambient room temperature, turning white at above 120° F, remaining white to at least the maximum comfortable temperature of about 160° F to about 180° F and returning to purple upon cooling. Chromacolor PP-mauve Type 60 is preferred, due to its more "striking" color change.
  • thermoplastic impression composition of the present invention is about
  • polycaprolactone such as Capra 650
  • polycaprolactone such as Capra 650
  • EVA ethylene vinyl-acetate
  • a proportion of vinyl acetate being in the range of 24.3 % to 25.7% by weight and a melt index between 17.3 and 20.9 decigrams/minute, such as Elvax 350 by DuPont
  • about 5% to about 20% styrene-butadiene-styrene or styrene butadiene copolymer such as Stereon 840A by Firestone
  • silica filler such as Hisil 233 from PPG Industries
  • a primary process stabilizer such as tris(2,4-di-tert-butylphenyl) phosphite
  • an antioxidant tetrakis[methylene(3,5-di-tert-buty
  • a most preferred formulation is approximately 61.2% by weight polycaprolactone, such as Capra 650 by Solvoy-Interox; approximately 6% by weight of ethylene vinylacetate co-polymer such as Elvax 350 by DuPont; approximately 9% by weight polystyrene butadiene copolymer, such as Stereon 840A by Firestone; approximately 14% by weight of silica filler, such as Hisil 233; approximately 0.2% by weight of a primary antioxidant, such as Ingraox 1010 and approximately 0.2% by weight of a secondary antioxidant such as Igraphos 168, to which is added about 3 % thermal color change indicator Chromacolor PP-mauve Type 60 from Chroma Corporation.
  • polycaprolactone such as Capra 650 by Solvoy-Interox
  • approximately 6% by weight of ethylene vinylacetate co-polymer such as Elvax 350 by DuPont
  • polystyrene butadiene copolymer such as Stereon 840A by Firestone
  • thermoplastic impression composition containing the requisite thermal color indicator of the present invention
  • the thermoplastic impression composition can be extruded, molded, or otherwise formed under heat and pressure into sheets, strips, rods, or bars.
  • the formed thermoplastic impression composition can be supported by a dental tray or directly applied to the dental arch or portion thereof.
  • the formed thermoplastic impression composition, with or without a supporting dental tray can be immersed in a container of hot water or other suitable non-solvent liquid, so as to cause the thermoplastic impression composition to raise in temperature and become sufficiently malleable and pliable to conform easily to the patient's teeth and gums, as indicated by a color change of the thermoplastic impression composition.
  • thermoplastic impression composition should be applied, by hand, into the patient's mouth, so that the thermoplastic impression composition molds itself on and about the patient's teeth and gums.
  • the thermoplastic impression composition is allowed to remain on and about the tooth and gum for sufficient time to cool sufficiently to maintain that impression, the thermoplastic impression composition is removed from the mouth, as indicated by the color change indicator changing back to its original color.
  • U.S. Patent 5,616,027 discloses the application of a thin, 0.01 to 0.05 mm, silicone-based elastomer sheet as a blocker to cover the teeth and gums, usable to separate the tooth surfaces and gums from the thermoplastic impression composition molded thereon.
  • This thin silicone-based elastomer is sandwiched between the teeth surfaces and the thermoplastic impression composition, usually by being placed on the exterior thermoplastic impression composition when it is first forced onto and about the teeth and gums.
  • This thin silicone-based elastomer is subsequently removed from between the inner tray and the teeth and gums, causing the impression within the inner tray to be 0.01 to 0.05 mm larger than the teeth and gums themselves (depending upon the exact width of the elastomer sheet).
  • thermoplastic impression composition This 0.01 to 0.05 mm separation allows enough space to facilitate easy removal of the thermoplastic impression composition from irregular tooth surfaces, such as undercuts or edges of fillings, and space so that when applying the medicinal and hygiene agents to the inner surface of the inner tray, after the tooth impression has been made therein, and repositioning the inner tray over the teeth and gums, there is adequate separation for the medicinal or hygiene agent.
  • the therapeutic agent can be formulated into the thermoplastic impression composition as an ingredient therein and the agent can then be applied in the initial molding of the thermoplastic impression composition onto and about the tooth and gums.
  • thermoplastic impression composition can be blended by hand or by mechanical mixing.
  • the ingredients preferably are warmed sufficiently to melt the thermoplastic portion, but if desired can be mixed at lower temperatures.
  • Any suitable mixing device can be used, including kettles equipped with mechanical stirrer, extruders, rubber mills, and the like.
  • the thermoplastic impression composition can be sold unwrapped, loosely wrapped in a package, or packaged in tubes, syringes, flexible outer plastic skins, plastic or metal trays, or the like.
  • various medicinal and/or hygiene agents can be applied to the teeth or gums by being sandwiched into the interface between the thermoplastic impression composition and the teeth and gums, or by formulated an effective amount of such agent into the thermoplastic impression composition itself.
  • Useful medicinal and hygiene agents include, antibacterial agents, such as triclosan; bleaching or w tening agents, such as peroxide; anticavity agents, such as fluoride gel; desensitizing agents, such as potassium nitrate; and the like.
  • thermoplastic impression composition of the present invention designated Sample 1 which reaches its warm impression state at over 120° F.
  • the inner tray was formed by standard compression molding, a technique well known in the art, into the U-shaped cross-section and overall horseshoe shaped configuration which is the general channel profile of inner dental trays.
  • Table I The formulation used for the thermoplastic impression composition of Sample 1 is presented in Table I, below:
  • a series of comparative inner trays were formulated, containing other EVA compatible, thermal color change indicators from Chroma Corporation, designated Samples 2 through 14; using the formulation of Table I; except, that the Chromacolor PP-mauve Type 60 color change indicator was replaced by an equal amount of the comparative thermal color change indicator.
  • the procedure of Example I was repeated using Samples 2 through 14 and the results therefrom are also recorded in Table -Q, below.

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  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dental Preparations (AREA)

Abstract

Cette invention concerne une pâte pour empreinte dentaire ainsi qu'un procédé de prise d'empreinte des dents et des gencives et/ou l'administration de principes actifs dans cette zone. Cette pâte renferme un agent qui provoque un virage de teinte au moment où elle a atteint la température de 'prise d'empreinte à chaud' correspondant au stade où ladite pâte est suffisamment molle et malléable pour envelopper les dents et les gencives et en épouser la forme. Un nouveau virage de teinte intervient ultérieurement lorsque la pâte a refroidi et s'est suffisamment solidifiée pour être retirée de la dentition sans risque de déformation de l'empreinte.
PCT/US1998/025523 1997-12-03 1998-12-02 Pate a empreinte dentaire a virage de teinte WO1999027895A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU16179/99A AU1617999A (en) 1997-12-03 1998-12-02 Color indicator for dental impression material

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US98461697A 1997-12-03 1997-12-03
US08/984,616 1997-12-03
US20402898A 1998-12-01 1998-12-01
US09/204,028 1998-12-01

Publications (2)

Publication Number Publication Date
WO1999027895A2 true WO1999027895A2 (fr) 1999-06-10
WO1999027895A3 WO1999027895A3 (fr) 1999-08-12

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PCT/US1998/025523 WO1999027895A2 (fr) 1997-12-03 1998-12-02 Pate a empreinte dentaire a virage de teinte

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1258239A1 (fr) * 2001-05-17 2002-11-20 Kettenbach GmbH & Co. KG Composition de blanchissement des dents chimiquement durcissable
WO2005074863A1 (fr) * 2004-01-09 2005-08-18 Bisco, Inc. Materiaux dentaires polymerisables a changement de couleur et d'opacite
US7018622B2 (en) * 1997-06-06 2006-03-28 The Procter & Gamble Company Structures and compositions increasing the stability of peroxide actives
WO2008064904A1 (fr) 2006-11-30 2008-06-05 Kettenbach Gmbh & Co. Kg Matériau thermoplastique et procédé de fabrication d'un produit dentaire
US20080206713A1 (en) * 2005-06-15 2008-08-28 Zhermack S.P.A. Thermochromic Material for Dental Impression and Method
WO2014130603A1 (fr) 2013-02-25 2014-08-28 3M Innovative Properties Company Composition stabilisée pour empreinte dentaire, kit d'éléments et leur utilisation
WO2016164436A1 (fr) * 2015-04-07 2016-10-13 Dentsply Sirona Inc. Matériau d'obturation endodontique indiquant la température
US10285916B2 (en) 2012-10-17 2019-05-14 The Procter & Gamble Company Strip for the delivery of an oral care active and methods for applying oral care actives
WO2019188919A1 (fr) * 2018-03-30 2019-10-03 株式会社ユニックスジャパン Article dentaire moulé et matière de résine dentaire
US10493016B2 (en) 2002-09-11 2019-12-03 The Procter & Gamble Company Tooth whitening product

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US4717710A (en) * 1985-01-17 1988-01-05 Matsui Shikiso Chemical Co. Ltd. Thermochromic composition
US5415544A (en) * 1990-02-23 1995-05-16 Minnesota Mining And Manufacturing Company Preloaded thermoplastic dental impression tray
US5616027A (en) * 1995-04-18 1997-04-01 Jacobs; Allison J. Custom dental tray

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US4717710A (en) * 1985-01-17 1988-01-05 Matsui Shikiso Chemical Co. Ltd. Thermochromic composition
US5415544A (en) * 1990-02-23 1995-05-16 Minnesota Mining And Manufacturing Company Preloaded thermoplastic dental impression tray
US5616027A (en) * 1995-04-18 1997-04-01 Jacobs; Allison J. Custom dental tray

Non-Patent Citations (1)

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Title
PATENT ABSTRACTS OF JAPAN vol. 095, no. 008, 29 September 1995 & JP 07 118118 A (MORITA TOKYO SEISAKUSHO:KK), 9 May 1995 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7018622B2 (en) * 1997-06-06 2006-03-28 The Procter & Gamble Company Structures and compositions increasing the stability of peroxide actives
EP1258239A1 (fr) * 2001-05-17 2002-11-20 Kettenbach GmbH & Co. KG Composition de blanchissement des dents chimiquement durcissable
US10493016B2 (en) 2002-09-11 2019-12-03 The Procter & Gamble Company Tooth whitening product
WO2005074863A1 (fr) * 2004-01-09 2005-08-18 Bisco, Inc. Materiaux dentaires polymerisables a changement de couleur et d'opacite
US20080206713A1 (en) * 2005-06-15 2008-08-28 Zhermack S.P.A. Thermochromic Material for Dental Impression and Method
US8410191B2 (en) * 2005-06-15 2013-04-02 Zhermack S.P.A. Thermochromic material for dental impression and method
WO2008064904A1 (fr) 2006-11-30 2008-06-05 Kettenbach Gmbh & Co. Kg Matériau thermoplastique et procédé de fabrication d'un produit dentaire
US10285916B2 (en) 2012-10-17 2019-05-14 The Procter & Gamble Company Strip for the delivery of an oral care active and methods for applying oral care actives
US10285915B2 (en) 2012-10-17 2019-05-14 The Procter & Gamble Company Strip for the delivery of an oral care active and methods for applying oral care actives
US9549881B2 (en) 2013-02-25 2017-01-24 3M Innovative Properties Company Stabilized dental impression composition, kit of parts and use thereof
JP2016509057A (ja) * 2013-02-25 2016-03-24 スリーエム イノベイティブ プロパティズ カンパニー 安定化歯科用印象組成物、部品キット、及びそれらの使用
WO2014130603A1 (fr) 2013-02-25 2014-08-28 3M Innovative Properties Company Composition stabilisée pour empreinte dentaire, kit d'éléments et leur utilisation
WO2016164436A1 (fr) * 2015-04-07 2016-10-13 Dentsply Sirona Inc. Matériau d'obturation endodontique indiquant la température
JP2018510888A (ja) * 2015-04-07 2018-04-19 デントスプリー シロナ インコーポレイテッド 温度を表示する歯内充填材料
US9980883B2 (en) 2015-04-07 2018-05-29 Dentsply Sirona Inc. Temperature indicating endodontic obturation material
JP2019073565A (ja) * 2015-04-07 2019-05-16 デンツプライ シロナ インコーポレイテッド 温度を表示する歯内充填材料
WO2019188919A1 (fr) * 2018-03-30 2019-10-03 株式会社ユニックスジャパン Article dentaire moulé et matière de résine dentaire
JP2019178098A (ja) * 2018-03-30 2019-10-17 株式会社ユニックスジャパン 歯科用成形体及び歯科用樹脂材料

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WO1999027895A3 (fr) 1999-08-12

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