WO1999026936A3 - Procede d'oxydation selective de composes organiques - Google Patents

Procede d'oxydation selective de composes organiques Download PDF

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Publication number
WO1999026936A3
WO1999026936A3 PCT/US1998/024176 US9824176W WO9926936A3 WO 1999026936 A3 WO1999026936 A3 WO 1999026936A3 US 9824176 W US9824176 W US 9824176W WO 9926936 A3 WO9926936 A3 WO 9926936A3
Authority
WO
WIPO (PCT)
Prior art keywords
organic compounds
selective oxidation
silica
disclosed
catalyst
Prior art date
Application number
PCT/US1998/024176
Other languages
English (en)
Other versions
WO1999026936A2 (fr
Inventor
Amore Michael Brian D
Stephan Schwarz
Original Assignee
Du Pont
Amore Michael Brian D
Stephan Schwarz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont, Amore Michael Brian D, Stephan Schwarz filed Critical Du Pont
Priority to EP98958553A priority Critical patent/EP1044196A2/fr
Priority to JP2000522094A priority patent/JP2001524475A/ja
Publication of WO1999026936A2 publication Critical patent/WO1999026936A2/fr
Publication of WO1999026936A3 publication Critical patent/WO1999026936A3/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B01J31/0247—Imides, amides or imidates (R-C=NR(OR))
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé d'oxydation de composés organiques. On utilise du péroxyde d'hydrogène pour oxyder un substrat organique oxydable en présence d'un catalyseur contenant silice/oxyde de titane modifié par de la silice. La présente invention concerne également un procédé de préparation d'un catalyseur à l'aide d'un copolymère de diéthoxysilane et d'éthyl titanate.
PCT/US1998/024176 1997-11-24 1998-11-12 Procede d'oxydation selective de composes organiques WO1999026936A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP98958553A EP1044196A2 (fr) 1997-11-24 1998-11-12 Procede d'oxydation selective de composes organiques
JP2000522094A JP2001524475A (ja) 1997-11-24 1998-11-12 有機化合物の選択的酸化方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6642997P 1997-11-24 1997-11-24
US60/066,429 1997-11-24

Publications (2)

Publication Number Publication Date
WO1999026936A2 WO1999026936A2 (fr) 1999-06-03
WO1999026936A3 true WO1999026936A3 (fr) 1999-09-02

Family

ID=22069448

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/024176 WO1999026936A2 (fr) 1997-11-24 1998-11-12 Procede d'oxydation selective de composes organiques

Country Status (3)

Country Link
EP (1) EP1044196A2 (fr)
JP (1) JP2001524475A (fr)
WO (1) WO1999026936A2 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19918431A1 (de) 1999-04-23 2000-10-26 Bayer Ag Verfahren zur Herstellung eines Katalysators zur selektiven Oxidation von Kohlenwasserstoffen
DE19954322A1 (de) 1999-11-10 2001-05-17 Basf Ag Oxid und Verfahren zu dessen Herstellung
DE19959525A1 (de) * 1999-12-09 2001-06-13 Bayer Ag Katalysatoren auf Basis Edelmetall- und Titan-haltiger, organisch-anorganisch Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen
DE10023717A1 (de) * 2000-05-17 2001-11-22 Bayer Ag Formkörper, Verfahren zu dessen Herstellung und Verwendung dieser Formkörper zur selektiven Oxidation von Kohlenwasserstoffen
JP2002145872A (ja) * 2000-11-01 2002-05-22 Maruzen Petrochem Co Ltd エポキシ化合物の製造方法
FR2824565B1 (fr) * 2001-05-09 2003-07-04 Solvay Procede de desulfuration d'un melange d'hydrocarbures
WO2003074179A1 (fr) * 2002-03-04 2003-09-12 Sumitomo Chemical Company, Limited Procede permettant d'ameliorer un catalyseur de silicate de titane cristallin a structure mww
JP2004285055A (ja) * 2003-03-06 2004-10-14 Sumitomo Chem Co Ltd プロピレンオキサイドの製造方法
CN102766032B (zh) * 2011-05-05 2014-10-01 中国石油化工股份有限公司 一种环己烷氧化的方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640093A (en) * 1969-03-10 1972-02-08 Owens Illinois Inc Process of converting metalorganic compounds and high purity products obtained therefrom
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
DE3309669A1 (de) * 1982-03-19 1983-09-29 Anic S.P.A., Palermo Verfahren zur hydroxylierung von aromatischen kohlenwasserstoffen
US4410501A (en) * 1979-12-21 1983-10-18 Snamprogetti S.P.A. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
US4937216A (en) * 1986-01-28 1990-06-26 Eniricerche S.P.A. Process for the epoxidation of olefinic compounds and catalysts used therein
EP0634212A1 (fr) * 1993-07-12 1995-01-18 Degussa Aktiengesellschaft Catalyseur structuré, comprenant des oxides microporeux d'aluminium, de silicium et de titanium
EP0734764A2 (fr) * 1995-03-30 1996-10-02 Sumitomo Chemical Company Limited Catalyseur et procédé de production de composé d'oxirane
DE19545042A1 (de) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung
US5759945A (en) * 1997-03-26 1998-06-02 Arco Chemical Technology, L.P. Preparation of titanium-containing catalysts using titanosiloxane polymers

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640093A (en) * 1969-03-10 1972-02-08 Owens Illinois Inc Process of converting metalorganic compounds and high purity products obtained therefrom
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
US4410501A (en) * 1979-12-21 1983-10-18 Snamprogetti S.P.A. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
DE3309669A1 (de) * 1982-03-19 1983-09-29 Anic S.P.A., Palermo Verfahren zur hydroxylierung von aromatischen kohlenwasserstoffen
US4937216A (en) * 1986-01-28 1990-06-26 Eniricerche S.P.A. Process for the epoxidation of olefinic compounds and catalysts used therein
EP0634212A1 (fr) * 1993-07-12 1995-01-18 Degussa Aktiengesellschaft Catalyseur structuré, comprenant des oxides microporeux d'aluminium, de silicium et de titanium
EP0734764A2 (fr) * 1995-03-30 1996-10-02 Sumitomo Chemical Company Limited Catalyseur et procédé de production de composé d'oxirane
DE19545042A1 (de) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung
US5759945A (en) * 1997-03-26 1998-06-02 Arco Chemical Technology, L.P. Preparation of titanium-containing catalysts using titanosiloxane polymers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 128, no. 18, 4 May 1998, Columbus, Ohio, US; abstract no. 222074, TATSUMI ET AL.: "Remarkable activity enhancement by trimethylsilylsation in oxidation of alkenes and alkanes with H2O2 catalyzed by titanium-containing mesoporous molecular sieves" XP002095333 *
THANGARAJ A ET AL: "STUDIES ON THE SYNTHESIS OF TITANIUM SILICALITE, TS-1", ZEOLITES, vol. 12, no. 8, November 1992 (1992-11-01), pages 943 - 950, XP002073984 *

Also Published As

Publication number Publication date
EP1044196A2 (fr) 2000-10-18
WO1999026936A2 (fr) 1999-06-03
JP2001524475A (ja) 2001-12-04

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