WO1999025662A1 - Plaque de ceramique marbree et son procede de fabrication - Google Patents
Plaque de ceramique marbree et son procede de fabrication Download PDFInfo
- Publication number
- WO1999025662A1 WO1999025662A1 PCT/CN1998/000270 CN9800270W WO9925662A1 WO 1999025662 A1 WO1999025662 A1 WO 1999025662A1 CN 9800270 W CN9800270 W CN 9800270W WO 9925662 A1 WO9925662 A1 WO 9925662A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- color
- silicate
- plate according
- colors
- pattern
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/005—Devices or processes for obtaining articles having a marble appearance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/008—Producing shaped prefabricated articles from the material made from two or more materials having different characteristics or properties
Definitions
- the invention relates to a porcelain imitation stone plate used as a decorative material and a manufacturing method thereof, and more particularly to a marble-like material suitable for decoration of permanent floors, walls and furniture panels, and a manufacturing method thereof.
- the present inventor has proposed a three-dimensional porcelain granite and marble technology (WO 97/36840, published on October 9, 1997).
- the patterns of imitation granite and marble products obtained according to this technology each color area It is made of silicate material, and the boundary between each color area is clear.
- the color area is basically consistent within a certain thickness range from the surface to the inside. Therefore, even if the imitation granite and marble products are polished by the surface, The pattern remains unchanged. However, the pattern color transition of this imitation granite and marble product is not good. This is inconsistent with the pattern characteristics of natural marble, so the effect of imitation marble according to this prior art is not ideal. Summary of invention
- the object of the present invention is to provide a porcelain imitation marble plate and a manufacturing method thereof, so as to overcome the defects of the prior art, and provide a technology in which the pattern color transition is good and the pattern is closer to natural marble.
- one aspect of the present invention is to provide a porcelain imitation marble plate, which is a pattern composed of a plurality of different-colored silicate brick color blocks, in a part of the silicate brick color blocks Add at least one pattern of bleed-out color; fine particles of different colors on the boundary line of the two silicate brick color blocks of different colors are mixed with each other, and the mixing width is 1-10mm.
- Another aspect of the present invention provides a porcelain imitation stone plate.
- the surface of the plate has a plurality of silicate brick color block areas composed of silicate materials, and at least part of the silicate brick color block areas.
- the present invention also provides a method for manufacturing a porcelain imitation stone plate, which includes the following steps: (a) preparing a mold having a plurality of powder materials corresponding to the respective silicate brick body color block areas through a die mouth ; (B) preparing powder for each silicate brick body color block area; (c) adding each silicate brick The powder for the body color block area is separately provided to the plurality of powders through the die openings to be molded to obtain a green body; (d) applying a material for forming a permeation color on the green body; and (e) The obtained scab was sintered.
- each color zone is at the boundary line There is a better transition as natural marble than the three-dimensional porcelain granite and marble of the prior art.
- the fine-grained color particles are mixed with each other above 1 mm.
- the invention has the advantages of high efficiency, good transition and good pattern stability; (4) this The method of the invention has good process repeatability, and for each imitation marble plate formed by the same mold, more than 80% of the color block patterns of each other can maintain consistency and overlap, which can control the variety of natural marble in a controlled manner. Rich and beautiful colors such as black, dark gray, red, orange, green, dark green, yellow, orange. Because the imitation marble of the present invention has process advantages such as pattern stability and consistency (also known as superimposable pattern features), it can be added with a repeating screen printing technique for more rich and more layers. The combination enables the fine slits and light-colored transitions in dark marble to be expressed with the seepage pattern technology, and overcomes the disadvantages of making too small patterns in three-dimensional porcelain granite and marble technology. Brief description of the drawings
- FIG. 1 is a plan view of a porcelain imitation marble according to a preferred embodiment of the present invention.
- FIG. 2 is a partially enlarged plan view of the boundary lines of different silicate color regions of the porcelain imitation marble of the embodiment shown in FIG. 1;
- 3A-F are comparison diagrams of the pattern positions of six articles in a batch of porcelain imitation marble manufactured according to the present invention, which are used to show the repeatability of the process of the present invention.
- the shapes and positions of the patterns in each color zone are basically acceptable. Superimposed; and
- Fig. 4 is a plan view of a mold die used for manufacturing the porcelain imitation marble of the present invention. Detailed description of the preferred embodiment
- FIG. 1 shows a plan view of a 200 mm x 200 mm piece of porcelain imitation marble according to a preferred embodiment of the present invention.
- the shaded part 1 in the figure represents the orange of the silicate material.
- the red color area indicates the white color area of the silicate material
- the black part 3 indicates the gray-black color area of the silicate material
- the small black dot portion 4 indicates that a light gray color is added to the white silicate material.
- the circled part 5 indicates that a milky white penetrating color is added to the orange-red silicate material, and a light milky red color area is obtained after sintering.
- the above five partial color areas constitute the pattern of imitation Norwegian red marble.
- the oblique line portion 1 represents the orange-red color area of the silicate material
- the white portion 2 represents the white color area of the silicate material.
- the discontinuous part 6 between the dotted line and the solid line indicates that the red powder is naturally mixed in the white powder, and the white powder is naturally mixed in the red powder.
- orange-red and white fine particles are mixed with each other, and the mixed width is about 2mm.
- 3A-F are comparison diagrams of the pattern positions of six panels in a batch of porcelain imitation marble slabs manufactured according to the present invention, which are used to show the repeatability of the process of the present invention.
- the shapes and positions of the patterns in each color zone are basically Can be superimposed.
- the position and shape of the color blocks above 80O / O in the block pattern of different colors of each marble-like plate can be superimposed, and the superimposed portions can be in the range of front, back, left, and right.
- the error does not exceed ⁇ 3cm.
- the silicate powders which can be formed into orange-red, white and gray-black after sintering are respectively filled into three containers.
- a combination mold having a die opening as shown in FIG. 4 which has a die opening corresponding to the color region of FIG. 1.
- the oblique line la indicates a die-passing area of one color material (for example, an orange-red material);
- the white portion 2a indicates a die-passing area of another color material (for example, a white material); white points in black
- the part 3a indicates the black-grey material passing area;
- the thick line part 7 indicates the plan view position of the steel die.
- the semi-finished product is screen-printed, and the light gray color is printed on the white part of the pattern once, and the light milky color is printed on the orange-red part.
- the product is sent to a firing process with a maximum temperature of about 1200 ° C to produce this product.
- the material used to form the silicate brick color block is insoluble in water, and the material used to form the flower color is soluble in water, so that the material used to form the flower color can be used. Dissolved in water, and then imprinted into the surface of the green body composed of silicate brick color blocks.
- the above method can have various changes, such as using only two color materials, or using four or more color materials.
- the structure of the die can be flexibly changed as required.
- the pattern of the present invention is printed by a prescribed die opening and screen printing, in the same batch of products, more than 80% of the shape and position of the color block pattern can be superimposed, and it can be superimposed.
- the error range of the front, back, left and right of the joint is not more than ⁇ 3cm.
- the present invention expresses the texture and gradation effect of natural marble, at least 10 pieces of the general color area are at least 5 cm 2 in area.
- patterns such as red, yellow, white, blue, black, green, orange, purple and other silicate brick color blocks can be used and patterns such as light gray, light brown, gray blue , Red, dark green and other different infiltration colors make up the pattern.
- red, yellow, white, blue, black, green, orange, purple and other silicate brick color blocks can be exemplified. For example, by using or adding Fe 2 0 3 , 2NaO V 2 0 5 , CoO, Fe 2 0 3 CoO, Mn0 2 , Cr 2 0 3 , CuO and the like.
- the powder for each silicate brick color block area is insoluble in water, and the material used to form the bleed-out color is water-soluble, and the bleed-out color is formed by screen printing.
- the steps of dissolving the material for forming a bleed-out color in water, and infiltrating the material for forming the bleed-out color that is soluble in water to a predetermined portion of the blank are achieved.
- the silicate brick color block may be two or more color blocks composed of a mixture of two or more color particles such as red, yellow, white, blue, black, and green, or a mixed color and A color block composed of a single color.
- the silicate brick color block can also be a pattern consisting of four or more different color silicate brick color blocks and a total of seven kinds of silicate brick color blocks added with three or more oozing colors A pattern composed of the above different colors.
- the silicate brick color block is preferably formed of a material with a small particle size.
- the particle size of the part where the color blocks are mixed with each other is more than 60%.
- the granularity of the part of each silicate brick color block mixed with each other is more than 60% for 500 mesh.
- the color blocks may also have a boundary line that is substantially perpendicular to the front surface of the panel, and the verticality error does not exceed ⁇ 40 degrees. This boundary line appears on the front surface of the panel as Clear borders that do not mix.
- the area of the silicate brick color block can range from 40 cm 2 like Masek to 10 m 2 like a huge marble slab, with a thickness of 3mm-1000mm, and its overall geometry can be a flat plate shape, a cylinder Shape, curved panel shape, partial cylindrical shape, spherical shape, polygonal shape, round shape, bar shape or square shape.
- the silicate brick color block also has large particles of a single color or large particles of multiple colors with a diameter of 1 to 15 mm, so as to match with other types of color regions, it looks more natural. Texture.
- a colorless transparent, translucent, or any color such as black, blue, red, yellow, or any other transparent or opaque or high refractive index glassy component is added.
- a pattern consisting of silicate components with granular or arbitrary geometric shapes with a flashing rate.
- the surface of the marble-like plate is composed of a concave-convex non-slip pattern with a depth of 0.1mm-5mm to form a more three-dimensional pattern, and the protruding surface plane pattern portion may not be polished, or Can be polished.
- the controllable sifting or vibration process of front, back, left and right, and up and down directions is adopted, so the controllable natural effect of the blending of the borders of the product's color zones can be controlled Sex.
- the pattern composed of the silicate color region of the stone-like plate of the present invention is mainly determined by a specific mold die mouth that is consistent with the pattern, it has process stability and very good repeatability. Therefore, based on this basic technology, it is possible to perform the infiltration flower process.
- bleed-through screen printing technology can show natural performance on materials such as black, dark gray, red, orange red, green, dark green, yellow, orange, white, blue, pink and other materials using silicate and the process of the present invention.
- the infiltration screen printing process can also be used to help express the small dots and line textures of natural marble.
- the pattern of the silicate brick body color block region is used as the main pattern, which can make the color difference of the products produced in batches smaller and the yield rate higher than that of the simple bleeding pattern technology.
- the product of the present invention not only has a variety of color silicates, which can have gorgeous, stable, deep, light patterns, and natural textures like natural marble transition between various color blocks.
- Exquisite patterns like natural marble and it has the comprehensive advantages of being more wear-resistant, harder, brighter, more resistant to corrosion, no radioactive radon hazards, etc. than natural marble.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Finishing Walls (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU11400/99A AU1140099A (en) | 1997-11-13 | 1998-11-12 | Marble-like ceramic sheet material and method for manufacturing the same |
EP98954107A EP1038852A4 (en) | 1997-11-13 | 1998-11-12 | MARBLE-LIKE CERAMIC PLATE MATERIAL AND METHOD FOR MANUFACTURING THEREOF |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 97114289 CN1184039A (zh) | 1997-11-13 | 1997-11-13 | 立体瓷质彩色图案渗花大理石 |
CN97114289.0 | 1997-11-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999025662A1 true WO1999025662A1 (fr) | 1999-05-27 |
Family
ID=5172853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN1998/000270 WO1999025662A1 (fr) | 1997-11-13 | 1998-11-12 | Plaque de ceramique marbree et son procede de fabrication |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1038852A4 (zh) |
CN (1) | CN1184039A (zh) |
AU (1) | AU1140099A (zh) |
WO (1) | WO1999025662A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112010657A (zh) * | 2020-08-26 | 2020-12-01 | 深圳陶陶科技有限公司 | 彩色陶瓷材料及其制备方法和应用 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9186819B1 (en) | 2014-08-19 | 2015-11-17 | Cambria Company Llc | Synthetic molded slabs, and systems and methods related thereto |
US9289923B1 (en) | 2015-01-30 | 2016-03-22 | Cambria Company Llc | Synthetic molded slabs, and systems and methods related thereto |
CN109795017B (zh) * | 2019-03-29 | 2020-12-15 | 东莞市唯美陶瓷工业园有限公司 | 稳定斑点砖的制备方法 |
US12030260B1 (en) | 2020-01-02 | 2024-07-09 | Cambria Company Llc | Stone slabs, systems, and methods |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86108043A (zh) * | 1986-12-06 | 1988-06-22 | 张晶亭 | 用大理石碎片组合饰面板的方法 |
CN88100494A (zh) * | 1988-01-27 | 1988-12-07 | 陈景秀 | 一种大理石废料制板材的方法 |
CN1079214A (zh) * | 1993-04-13 | 1993-12-08 | 赵颖 | 仿瓷大理石砖及其制作工艺 |
CN1153751A (zh) * | 1995-09-29 | 1997-07-09 | 杨德宁 | 立体瓷质花岗石、大理石 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2610703B2 (de) * | 1976-03-13 | 1978-05-24 | Ostara-Fliesen Gmbh & Co Kg, 4005 Meerbusch | Verfahren und Vorrichtung zum Bedrucken von keramischen Platten |
EP0605930B1 (en) * | 1993-01-08 | 1995-05-10 | CERAMICA MIRAGE S.p.A. | Method for the manufacture of dry-moulded tiles, with relative moulding plant and tile |
IT1268838B1 (it) * | 1994-07-21 | 1997-03-13 | L B Engineering Srl | Attrezzatura per alimentare il carrello di carico dello stampo nella fabbricazione di piastrelle ceramiche |
-
1997
- 1997-11-13 CN CN 97114289 patent/CN1184039A/zh active Pending
-
1998
- 1998-11-12 EP EP98954107A patent/EP1038852A4/en not_active Withdrawn
- 1998-11-12 WO PCT/CN1998/000270 patent/WO1999025662A1/zh active Application Filing
- 1998-11-12 AU AU11400/99A patent/AU1140099A/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86108043A (zh) * | 1986-12-06 | 1988-06-22 | 张晶亭 | 用大理石碎片组合饰面板的方法 |
CN88100494A (zh) * | 1988-01-27 | 1988-12-07 | 陈景秀 | 一种大理石废料制板材的方法 |
CN1079214A (zh) * | 1993-04-13 | 1993-12-08 | 赵颖 | 仿瓷大理石砖及其制作工艺 |
CN1153751A (zh) * | 1995-09-29 | 1997-07-09 | 杨德宁 | 立体瓷质花岗石、大理石 |
Non-Patent Citations (1)
Title |
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See also references of EP1038852A4 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112010657A (zh) * | 2020-08-26 | 2020-12-01 | 深圳陶陶科技有限公司 | 彩色陶瓷材料及其制备方法和应用 |
CN112010657B (zh) * | 2020-08-26 | 2023-01-13 | 深圳陶陶科技有限公司 | 彩色陶瓷材料及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN1184039A (zh) | 1998-06-10 |
AU1140099A (en) | 1999-06-07 |
EP1038852A4 (en) | 2006-06-14 |
EP1038852A1 (en) | 2000-09-27 |
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