WO1998047616A1 - Catalyseur comprenant un liquide ionique tamponne et procede de transformation d'hydrocarbures telle qu'une oligomerisation - Google Patents

Catalyseur comprenant un liquide ionique tamponne et procede de transformation d'hydrocarbures telle qu'une oligomerisation Download PDF

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Publication number
WO1998047616A1
WO1998047616A1 PCT/GB1998/000992 GB9800992W WO9847616A1 WO 1998047616 A1 WO1998047616 A1 WO 1998047616A1 GB 9800992 W GB9800992 W GB 9800992W WO 9847616 A1 WO9847616 A1 WO 9847616A1
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WO
WIPO (PCT)
Prior art keywords
ionic liquid
catalyst
buffered
liquid according
alkyl
Prior art date
Application number
PCT/GB1998/000992
Other languages
English (en)
Inventor
Peter Wasserscheid
Willi Keim
Original Assignee
Bp Chemicals Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chemicals Limited filed Critical Bp Chemicals Limited
Priority to AU69268/98A priority Critical patent/AU6926898A/en
Publication of WO1998047616A1 publication Critical patent/WO1998047616A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Abstract

L'invention concerne un liquide ionique tamponné comprenant: (A) un composé de formule RnMX3-n ou de formule RmM2X6-m. M représente un métal du groupe des aluminum, gallium, bore et fer (III). R représente un C1-C6 alkyle, X représente un atome d'halogène ou un groupe alcoxy dans lequel l'alkyle comporte 1 à 4 atomes de carbone, n vaut 0, 1 ou 2 et m vaut 1, 2 ou 3. (B) un sel haloïde organique et, éventuellement, (C) une base organique, les rapports molaires relatifs de (A), (B) et (C) dans le liquide ionique étant situés respectivement dans les plages de 0,50 à 0,67 : de 0,33 à 0,50 : et de 0,0 à 0,20. L'invention concerne également l'utilisation de ces liquides ioniques comme solvants ou activateurs pour des catalyseurs de transformation d'hydrocarbures, par exemple pendant l'oligomérisation d'oléfines avec un complexe nickel comme catalyseur.
PCT/GB1998/000992 1997-04-18 1998-04-03 Catalyseur comprenant un liquide ionique tamponne et procede de transformation d'hydrocarbures telle qu'une oligomerisation WO1998047616A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU69268/98A AU6926898A (en) 1997-04-18 1998-04-03 Catalyst comprising a buffered ionic liquid and hydrocarbon conversion process, e.g. oligomerisation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9707842.2A GB9707842D0 (en) 1997-04-18 1997-04-18 Oligomerisation process
GB9707842.2 1997-04-18

Publications (1)

Publication Number Publication Date
WO1998047616A1 true WO1998047616A1 (fr) 1998-10-29

Family

ID=10810962

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1998/000992 WO1998047616A1 (fr) 1997-04-18 1998-04-03 Catalyseur comprenant un liquide ionique tamponne et procede de transformation d'hydrocarbures telle qu'une oligomerisation

Country Status (3)

Country Link
AU (1) AU6926898A (fr)
GB (1) GB9707842D0 (fr)
WO (1) WO1998047616A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032658A1 (fr) * 1998-12-04 2000-06-08 Symyx Technologies, Inc. Liquides ioniques et procedes de fabrication de polyisoolefines a poids moleculaire eleve
WO2000040673A1 (fr) * 1999-01-06 2000-07-13 The Secretary Of State For Defence Procede industriel et catalyseurs
WO2001038270A1 (fr) * 1999-11-26 2001-05-31 Sasol Technology (Pty) Ltd Traitement de conversion d'hydrocarbures
DE10123467A1 (de) * 2001-05-15 2002-11-21 Studiengesellschaft Kohle Mbh Verfahren zur Aktivierung und Immobilisierung kationischer Übergangsmetallkatalysatoren unter Verwendung von ionischen Flüssigkeiten und komprimiertem CO¶2¶
US20110004040A1 (en) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Organometallic complexes as catalyst precursors for selective olefin dimerization and processes therefor
WO2011003044A1 (fr) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Dimérisation sélective d'oléfines par des complexes métalliques supportés activés par des composés alkylaluminium ou des liquides ioniques
WO2011003047A1 (fr) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Dimérisation hétérogène d'alpha-oléfines par des complexes de métallocène activés
WO2011029691A1 (fr) * 2009-09-08 2011-03-17 Evonik Oxeno Gmbh Procédé d'oligomérisation d'oléfines
WO2011112514A1 (fr) * 2010-03-09 2011-09-15 Conocophillips Company Liquides ioniques tamponnés pour la dimérisation des oléfines
US8936719B2 (en) 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
CN104341704A (zh) * 2005-07-11 2015-02-11 陶氏环球技术有限责任公司 硅烷接枝的烯烃聚合物、组合物和由其制备的制品,及其制备方法
DE102014200072A1 (de) 2014-01-08 2015-07-09 Evonik Industries Ag Dimerisierung von Olefinen
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
US10214697B2 (en) 2013-03-15 2019-02-26 Ultraclean Fuel Pty Limited Process for removing sulphur compounds from hydrocarbons
US11713364B2 (en) * 2019-04-01 2023-08-01 Exxon Mobil Technology and Engineering Company Processes for polymerizing alpha-olefins, internal olefins and compositions thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021872A1 (fr) * 1994-02-10 1995-08-17 Bp Chemicals Limited Liquides ioniques
US5550304A (en) * 1993-09-22 1996-08-27 Institut Francais Du Petrole Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5550304A (en) * 1993-09-22 1996-08-27 Institut Francais Du Petrole Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process
WO1995021872A1 (fr) * 1994-02-10 1995-08-17 Bp Chemicals Limited Liquides ioniques

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BOON J A ET AL: "AN ELECTROCHEMICAL INVESTIGATION OF THE 1-METHYL-3 -ETHYLIMIDAZOLIUM BROMIDE ALUMINUM BROMIDE MOLTEN SALT SYSTEM", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 138, no. 2, 1 February 1991 (1991-02-01), pages 465 - 469, XP000278362 *
RIECHEL T L ET AL: "THE ELECTROCHEMISTRY OF ALUMINUM AND PROTONS IN ROOM TEMPERATURE CHLORO-ALUMINATE MOLTEN SALTS BUFFERED WITH SODIUM CHLORIDE", 1 January 1992, EXTENDED ABSTRACTS, VOL. 92/1, PAGE(S) 774/775, XP000549348 *
Y. CHAUVIN ET AL.: "Oligomerization of n-Butenes catalyzed by Ni Complexes dissolved in Organochloroaluminate Ionic Liquids", JOURNAL OF CATALYSIS, vol. 165, 1997, pages 275 - 278, XP002070945 *

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032658A1 (fr) * 1998-12-04 2000-06-08 Symyx Technologies, Inc. Liquides ioniques et procedes de fabrication de polyisoolefines a poids moleculaire eleve
WO2000040673A1 (fr) * 1999-01-06 2000-07-13 The Secretary Of State For Defence Procede industriel et catalyseurs
WO2001038270A1 (fr) * 1999-11-26 2001-05-31 Sasol Technology (Pty) Ltd Traitement de conversion d'hydrocarbures
DE10123467A1 (de) * 2001-05-15 2002-11-21 Studiengesellschaft Kohle Mbh Verfahren zur Aktivierung und Immobilisierung kationischer Übergangsmetallkatalysatoren unter Verwendung von ionischen Flüssigkeiten und komprimiertem CO¶2¶
CN104341704A (zh) * 2005-07-11 2015-02-11 陶氏环球技术有限责任公司 硅烷接枝的烯烃聚合物、组合物和由其制备的制品,及其制备方法
US8936719B2 (en) 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
WO2011003047A1 (fr) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Dimérisation hétérogène d'alpha-oléfines par des complexes de métallocène activés
US20110004039A1 (en) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Selective olefin dimerization with supported metal complexes activated by alkylaluminum compounds or ionic liquids
WO2011003044A1 (fr) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Dimérisation sélective d'oléfines par des complexes métalliques supportés activés par des composés alkylaluminium ou des liquides ioniques
US8487153B2 (en) * 2009-07-01 2013-07-16 Phillips 66 Company Selective olefin dimerization with supported metal complexes activated by alkylaluminum compounds or ionic liquids
US8816146B2 (en) * 2009-07-01 2014-08-26 Phillips 66 Company Organometallic complexes as catalyst precursors for selective olefin dimerization and processes therefor
US20110004040A1 (en) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Organometallic complexes as catalyst precursors for selective olefin dimerization and processes therefor
WO2011029691A1 (fr) * 2009-09-08 2011-03-17 Evonik Oxeno Gmbh Procédé d'oligomérisation d'oléfines
US9200216B2 (en) 2009-09-08 2015-12-01 Evonik Degussa Gmbh Process for oligomerizing olefins
US20120136189A1 (en) * 2010-03-09 2012-05-31 Conocophillips Company - Ip Services Group Buffered ionic liquids for olefin dimerization
WO2011112514A1 (fr) * 2010-03-09 2011-09-15 Conocophillips Company Liquides ioniques tamponnés pour la dimérisation des oléfines
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
US10214697B2 (en) 2013-03-15 2019-02-26 Ultraclean Fuel Pty Limited Process for removing sulphur compounds from hydrocarbons
DE102014200072A1 (de) 2014-01-08 2015-07-09 Evonik Industries Ag Dimerisierung von Olefinen
WO2015104185A1 (fr) 2014-01-08 2015-07-16 Evonik Degussa Gmbh Système contenant un catalyseur au ni(ii), un halogénure organométallique, un précurseur d'anion et un tampon, et son utilisation pour la dimérisation d'oléfines
US11713364B2 (en) * 2019-04-01 2023-08-01 Exxon Mobil Technology and Engineering Company Processes for polymerizing alpha-olefins, internal olefins and compositions thereof

Also Published As

Publication number Publication date
AU6926898A (en) 1998-11-13
GB9707842D0 (en) 1997-06-04

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