WO1998046869A1 - Systeme de brulage d'une masse biologique visant a produire du gaz chaud - Google Patents

Systeme de brulage d'une masse biologique visant a produire du gaz chaud Download PDF

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Publication number
WO1998046869A1
WO1998046869A1 PCT/US1997/023647 US9723647W WO9846869A1 WO 1998046869 A1 WO1998046869 A1 WO 1998046869A1 US 9723647 W US9723647 W US 9723647W WO 9846869 A1 WO9846869 A1 WO 9846869A1
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WO
WIPO (PCT)
Prior art keywords
biomass
cyclone
annulus
air
combustor
Prior art date
Application number
PCT/US1997/023647
Other languages
English (en)
Inventor
Joseph W. Rizzie
Franck Picker
Original Assignee
Bioten Gp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bioten Gp filed Critical Bioten Gp
Priority to BR9710691-7A priority Critical patent/BR9710691A/pt
Priority to AU57125/98A priority patent/AU5712598A/en
Publication of WO1998046869A1 publication Critical patent/WO1998046869A1/fr
Priority to NO985899A priority patent/NO985899L/no

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • F23G7/105—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses of wood waste
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B45/00—Engines characterised by operating on non-liquid fuels other than gas; Plants including such engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/26—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C7/00—Combustion apparatus characterised by arrangements for air supply
    • F23C7/002—Combustion apparatus characterised by arrangements for air supply the air being submitted to a rotary or spinning motion
    • F23C7/004—Combustion apparatus characterised by arrangements for air supply the air being submitted to a rotary or spinning motion using vanes
    • F23C7/006—Combustion apparatus characterised by arrangements for air supply the air being submitted to a rotary or spinning motion using vanes adjustable
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C7/00—Combustion apparatus characterised by arrangements for air supply
    • F23C7/02—Disposition of air supply not passing through burner
    • F23C7/06—Disposition of air supply not passing through burner for heating the incoming air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/027—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using cyclone separators
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23M—CASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M5/00—Casings; Linings; Walls
    • F23M5/08—Cooling thereof; Tube walls
    • F23M5/085—Cooling thereof; Tube walls using air or other gas as the cooling medium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/10—Drying by heat
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/60—Separating
    • F23G2201/603—Separating recyclable material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/80—Shredding
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00—Combustion
    • F23G2202/30—Combustion in a pressurised chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00—Waste feed arrangements
    • F23G2205/12—Waste feed arrangements using conveyors
    • F23G2205/121—Screw conveyor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00—Waste feed arrangements
    • F23G2205/14—Waste feed arrangements using hopper or bin
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00—Waste feed arrangements
    • F23G2205/18—Waste feed arrangements using airlock systems
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00—Waste feed arrangements
    • F23G2205/20—Waste feed arrangements using airblast or pneumatic feeding
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00—Waste heat recuperation
    • F23G2206/20—Waste heat recuperation using the heat in association with another installation
    • F23G2206/203—Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00—Special features of, or arrangements for incinerators
    • F23G2900/50214—Separating non combustible matters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/12—Heat utilisation in combustion or incineration of waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/30—Use of alternative fuels, e.g. biofuels

Definitions

  • This invention relates to the field of power plants and more specifically to a system for prducing hot gas to pwoer a trubine, or for a fossil booster or incinerator.
  • a turbine system consists generally of a combustion chamber for burning fuel in the presence of compressed air provided by an air compressor gas generator, a turbine into which high pressure combustion gas flows, expands and produces power to drive the air compressor, and an electrical generator which is powered by the power turbine .
  • Wood combusts at a substantially higher temperature than traditional fossil fuels.
  • the life and effectiveness of the turbine will be substantially affected by high temperatures and ash, a byproduct of burning wood. Further, the abrasiveness of sawdust and the combustion of sawdust must be considered when feeding the sawdust into the combustion chamber.
  • the '266 patent teaches a portable, self contained power plant for converting wood waste to electrical energy.
  • a chamber is utilized to burn and pyrolize wood on a grate to form combustible products which are in turn injected into a second combustion chamber for complete combustion.
  • the system generates a relatively low amount of energy due to low wood burning rates inherent with burning on a grate or pile.
  • the system does not provide a sufficient means for removing ash from the combustion gas. Also, a control system is not provided for controlling various aspects of the system during operation thereof.
  • the '786 and '637 patents teach wood burning systems for fueling a turbine. Each system is designed to generate a large amount of energy.
  • the '786 patent does not teach a control system sufficient for commercial operation of the system.
  • the systems taught in both patents teach combustors wherein the biomass is fed into the combustor from the top or proximate the top. Combustion of wood particles is inefficient with this configuration because the larger particles move out of the combustion zone, due to gravity, before they entirely combust. Further, the feeding system disclosed in both patents is not sufficient for commercial application.
  • slag is prone to collect on the walls of the chamber.
  • the combustion chamber and cyclone filter design of the '637 patent tend to foster pressure drops.
  • the control system disclosed in the '637 patent does not provide for environmental concerns.
  • the present invention provides a system for burning biomass to produce hot gas for powering a turbine .
  • the system of the present invention includes a wood processing system, a combustor, a cyclone ash separator, a gas generator, a turbine and a control system.
  • the wood processing system serves to process, dry and prepare the biomass for injection into the combustor.
  • the biomass is injected into the bottom of the combustor. Combustion of the biomass takes place in the combustor.
  • the resultant combustion gas enters the cyclone ash separator for removal of ash from the combustion gas.
  • the combustion gas exits the cyclone ash separator via a duct.
  • An air bypass assembly permits the injection of bypass air into the stream of the combustion gas at the exit of the cyclone.
  • the combustion gas and bypass air enter the turbine, where they expand to power the turbine which drives an electrical generator.
  • FIG 1 illustrates the biomass burning system of the present invention
  • Figure 2 illustrates the wood processing system of the present invention
  • FIG. 3 illustrates an alternate embodiment of the sawdust preparation system of the present invention
  • Figure 4 illustrates an enlarged view of the combustor and cyclone
  • Figure 4A illustrates an injector region for a combustor to accommodate the use of very fine particulate fuel.
  • Figure 5 is a top view of the vanes and vane actuator at the lower end of the combustor
  • Figure 6 is an alternate embodiment of the air bypass assembly
  • FIG. 7 is a block diagram of the control system for the system for burning biomass of the present invention.
  • FIG. 8 illustrates the major CCP input and output signals and controller functions.
  • a system for burning biomass to produce hot gas to power a turbine incorporating various features of the present invention is illustrated generally at 10 in Figure 1. It will be noted that although a system for providing hot gas to power a turbine is described herein, it is not intended to limit the system to this particular use and can be utilized as a hot air source for a fossil power plant booster or an incinerator.
  • the system for burning biomass 10 is designed to provide an improved wood processing system. Further, the system provides an improved manner for injecting the biomass into the combustor 14. Moreover, an extensive control system 22, shown in Figure 7, is provided for monitoring and controlling various aspects of the system 10, as well as exhausts and byproducts of the system 10.
  • the system for burning biomass 10 of the present invention generally includes a biomass (typically wood sawdust) processing system 12 (shown in Figure 2) , a combustor 14, a cyclone ash separator 16, a gas generator 18 (including both a gas generator turbine 20 and a compressor 21) , a power turbine 19, an electrical generator 17 (shown in Figure 1) , and a control system 22 (shown in Figure 7) .
  • the power turbine 19 is coupled to the generator 17 through a gear box 123 and a brake 125.
  • the wood processing system 12 includes a reclaiming system 26, a sawdust preparation system 28, a storage unit 30 and a pressurized lock vessel assembly 32.
  • the reclaiming system 26 includes a dump hopper 34 into which the sawdust is dumped.
  • the sawdust is fed from the dump hopper 34, by a reclaimer 35, onto a drag conveyor system 36 including a first 130, second 131 and third drag conveyor 132.
  • the first conveyor 130 includes a magnet 38 at its terminal end for removing iron and other ferrous metals from the sawdust.
  • the second and third conveyors 131, 132 are used to divert biomass into aspirator bins 40A, 40B.
  • the drag conveyor system 36 is designed to convey a maximum of ten tons per hour.
  • the drag conveyor system 36 feeds the sawdust into a destoner or aspirator 40 (A and B) which removes rocks, bark, bottles and other remaining debris. From the destoner/aspirator 40, the sawdust is fed pneumatically into the sawdust preparation system 28.
  • the sawdust preparation system 28 consists of two or more parallel paths to obtain the desired flow rate of biomass fuel .
  • the (e . g ., sawdust) biomass preparation system 28 includes at least one air swept pulverizer 42A (and preferably a second air swept pulverizer
  • the air swept pulverizers 42A, 42B can be operated in an ambient pressure mode or high pressurized mode.
  • the ambient pressure mode has the advantage of being able to blend different types of fuels with different moisture content prior to combustion.
  • the high pressurized mode has the advantage of processing only wet sawdust outside of the combustor thereby eliminating the potential explosion problem. Additionally, the process directs to the combustor all wood fuel ingredients including the wood alcohol vapors lost in the unpressurized system.
  • two air swept pulverizers 42A, 42B are utilized and they are operated in the ambient pressure mode.
  • the sawdust enters the air swept pulverizers 42 at approximately forty- five weight percent water in a fluidized air stream from the aspirators 40A, OB.
  • the sawdust is dried in the air swept pulverizers 42 to approximately
  • turbine exhaust air from the system 10 is pulled through the pulverizers 42 to dry the biomass and each air swept pulverizer 42 pulverizes and dries 9,300 pounds per hour at
  • each air swept pulverizer 42 processes 9,300 pounds per hour of sawdust at 45 weight percent moisture to approximately 6,480 pounds per hour of wood fuel at 20 weight percent moisture.
  • the preferred air swept pulverizer 42 is a Jacobson air swept pulverizer, model number 48-H.
  • Radial materials fans 43A, 43B are used to pull drying air (47) and biomass fuel which is being dried in the pulverizers 42A, 42B through the drying system and forces the air through cyclones 44A, 44B.
  • the fluidized transfer process greatly increases the efficiency of the drying process .
  • An elevated loop in the fluidized transport ducts 41A, 41B totally eliminates the possibility of introducing any high mass objects such as stones and metals into the biomass fuel pulverizers 42A, 42B.
  • Cyclones 44A, 44B are in communication with each of the air swept pulverizers 42A,
  • the biomass fuel from the pulverizers 42A, 42B is fed into the cyclones 44A, 44B by the materials fans 43A, 43B.
  • the lower end of the cyclones 44A, 44B define rotary feeders 46A, 46B which pass the biomass into a pneumatic conveyor 48.
  • the pneumatic conveyor 48 moves the biomass into the top of a storage cyclone 30.
  • the biomass is discharged from the bottom of the cyclone 30 into a live bin 52.
  • Inclined drag conveyors could also be used in the place of the pneumatic conveyor to fill the live bin 52.
  • the live bin 52 has a reversing cross auger and eight feed augers 51 that will move the fuel dust to one of two lock vessels 56A, 56B.
  • the pressurized fuel dust ejector assembly 32 includes one or two pressurized lock vessels
  • Each lock vessel 56A, 56B which communicate in a parallel manner to the charging vessel 57.
  • Each lock vessel 56A, 56B can be cross-charged with compressed air from the other and topped off with mechanical compressed air before it is connected to the charging vessel 56. This eliminates pressure surge in the feed system and pressure surges in the gas compressor system. Again the charge vessels are repressurized before feeding the biomass into the charging vessel 57.
  • An auger 58 at the bottom of the charging vessel 57 typically meters out biomass at 1-3.54 pounds per second into the pressurized combustor 14. Compressed air from the compressor 21 is input to a high temperature and pressure blower 59 which is used to boost the fuel dust conveying air which discharges into the combustor 14.
  • Plant compressed air is used to activate rubber vibrator jets 49 on the side of the lock vessels 56A, 56B and the walls of the charge vessel 57. These jets fluidize the fuel dust so it does not bridge or plug the holes in the ejector lock vessels 56A, 56B and/or the charge vessel 57.
  • the charge vessel 57 also has a centerline-mounted rotating mechanical and air jet bridge breaker 50 that keeps the fuel dust in a fluidized state so that it moves to the discharge auger 58 without bridging or rat holing in the charge vessel.
  • the lock vessels 56A, 56B and the charge vessel 57 are equipped with internal rotating vessels and a fixed bridge breaking screw auger to move the fuel out of the lock vessels into the charge vessel 57 and to break the bridge in the charge vessel and move the fuel dust through a metering screw so that it can be pneumatically injected into the combustor.
  • the wood processing system 12 further includes a manually tillable receptacle 60 positioned at the front end of the pneumatic conveyor 48. The receptacle 60 provides a location for manually loading fuel dust or additives to the system.
  • biomass e.g., sawdust
  • Pneumatically feeding of biomass (e.g., sawdust) from the aspirator bins 40A, 40B and metering augers to the pulverizers 42A, 42B , and pneumatically conveying the biomass fuel dust to the live bin 52 with materials fan 45 reduces the temperature of the drying air from the turbine to 250° or less eliminating the possibility of explosion of fuel dust in the pulverizers, their cyclones 44A, 44B, the live bin fan 45 and the live bin cyclone 30.
  • the dust discharged from the pulverizer cyclones 44A, 44B and live bin cyclone 30 is recycled to a bag house 47 through a rotary lock 46 back into the conveyor line 48 by fan 43.
  • the sawdust preparation system 28 includes the use of a pressurized air swept pulverizer system 162.
  • two air swept pulverizer systems 162 are utilized in a parallel manner (as in Figure 2) to feed into one high pressure and high temperature cyclone 171. It will be noted that one or more than one air swept pulverizer system 162 can be utilized.
  • Each air swept pulverizer system 162 includes a biomass surge hopper 163, a first isolation valve 164, a lock hopper 165, a second isolation valve 166, a charge hopper 167, a metering screw 168, an air swept pulverizer feed hopper 169 and an air swept pulverizer 170.
  • the biomass surge hopper 163 includes a biomass surge hopper 163, a first isolation valve 164, a lock hopper 165, a second isolation valve 166, a charge hopper 167, a metering screw 168, an air swept pulverizer feed hopper 169 and an air
  • the sawdust is pressurized and raised in temperature.
  • the sawdust is pressurized to 125 psi and brought to a temperature of 150 °F.
  • the sawdust moves through the second isolation valve 166 into the charge hopper 167.
  • the sawdust is maintained at the same pressure and brought up to 200 °F.
  • the metering screw 168 meters the sawdust into the air swept pulverizer feed hopper 169 which feeds the sawdust into the air swept pulverizer 170 at a rate of 5 tons/hour at 45 weight percent water.
  • the sawdust is dried and pulverized in the air swept pulverizer 170.
  • the sawdust is dried with hot air from the compressor 21 (see Figure 1) .
  • ducts 197, 198 are in communication with the combustor duct 25 to feed air into the pulverizers 170.
  • the wood fuel is fed into a high pressure, high temperature cyclone 171, where the wood fuel 152 is separated from the gas.
  • the cyclone 171 is held at 350°F and 125.5 psi.
  • the high temperature air is exhausted through the top of the cyclone 171 and is injected into the combustor 14 via the port 95 to increase power and BTU input.
  • the wood fuel 152 exits through the lower end of the cyclone 171 through a high temperature rotary air lock 172 and enters a pneumatic feed line 173.
  • Primary air 150 from a conveying air line 174 is fed into the rotary air lock 172 to mix with the wood fuel 152.
  • the rotary air lock 172 is held at 605°F and a pressure differential of 0.5 psi and the conveying air line 174 is at 126.5 psi and delivers air into the rotary air lock 172 at a temperature of 605°F and a rate of 2-4 pounds/sec.
  • the wood fuel 152 and primary air 150 are fed into the bottom of the combustor 14 via the pneumatic air line 173.
  • the air 150 and wood fuel 152 mixture is delivered at a temperature of
  • the air 150 is delivered at a rate of 8 pounds/second and the wood fuel 152 at a rate of 1-5 pounds /second at 20 weight percent water.
  • the primary air 150 is fed from the air compressor 21 which delivers the air at 600°F and a pressure of 125 psi .
  • a booster fan 175 mounted in a pressure vessel 176 is utilized to boost the pressure and temperature of the primary air 150 before it enters the conveying air line 174.
  • pressurized air swept pulverizer system it is advantageous to use the pressurized air swept pulverizer system because there is no dry fuel handling. This decreases the potential fire problem, and all volatile organic compounds are burned. Further, this system offers better fuel efficiency and emissions control and added power. Moreover, less capital equipment is required to process the sawdust .
  • the combustor 14, shown clearly in Figure 4, is a pressure balanced bottom fuel feed combustor.
  • the combustor 14 includes an outer shell 66, a combustor lining 68 defining a network of openings 71 and annular slots 70, an annulus 72 between the outer shell 66 and the combustor lining 68, a bottom fuel injector 74, a gas burner 78, and a commercial gas burner controller 190.
  • the outer shell 66 defines a port 95 at a lower end thereof. During operation of the system 10, the port 95 receives secondary and tertiary air 128 from the air compressor 21, which is powered by the gas generator turbine 20.
  • a check valve 24 ( Figure 1) is included in the air vent 25 to the combustor 14 at port 95 to prevent back flow from the combustor 14 such that damage to the compressor 21 is prevented.
  • a pressure relief valve 65 is in communication with the duct 25 for relieving pressure in the system.
  • an alternate embodiment includes a steam injector 134 to inject steam into the tertiary air 128 of the annulus 72 of the combustor 14 and/or the annulus 98 of the cyclone 16. Steam is injected to boost turbine power after reaching 90% of achievable power by using wood fuel only.
  • the outer shell 66 is fabricated from 0.5 in. thick carbon steel or the equivalent and the inside of the outer shell 66 is insulated with 3" thick fiberfraxTM insulation retained by a 0.078" stainless steel floating liner.
  • the bottom fuel injector 74 injects the wood fuel 152 from the wood processing system 12 into the bottom of the combustor 14.
  • the fuel is metered into the pneumatic line entering the fuel injector 74 by the metering screw 58.
  • Bottom injection of fuel into the combustor 14 increases residence time of the fuel in the combustor 14 and reduces the required energy for injection. Bottom injection also prevents accumulation of unburned, ashes and slag inside the combustor 14.
  • the combustion zone at the orifice of the fuel injector 74 is lined with a refractory casting of Andalucast LCV (FSS-1151) cured to 650°F.
  • the lower end of the combustor 14 is configured to promote thorough burning of the wood fuel 152 fed into the combustor 14.
  • the lower end of the combustor 14 includes a refractory cone 80 and a secondary air flow controller 178, shown in Figure 5, for controlling the air 128 flowing from the combustor annulus 72 into the refractory cone section 153.
  • the refractory cone 80 serves to accumulate and radiate heat to stabilize initial combustion.
  • the control of the secondary air flow 128 is accomplished by a plurality of movable vanes 179 which are controlled by a vane actuator 180, shown generally in Figure 4.
  • a vane actuator 180 shown generally in Figure 4.
  • FIG. 4A An embodiment of such a fuel injector 74' is illustrated in Figure 4A.
  • a liquid fuel line 75 is disposed within the lower end of the combustor 14 to convey fuel to a nozzle 76 positioned proximate the cone 80.
  • This fuel line 75 is protected from extreme the incoming regular fuel 152 with a barrier 77.
  • the liquid fuel is ignited in any normal manner at the nozzle 76 to raise the temperature of the dust of regular fuel to initial combustion temperature.
  • a top view of the vanes 179 is shown in Figure 5.
  • the vanes 179 encircle the exit of the fuel injector 74.
  • Each of the vanes 179 pivots relative to one end such that the vanes 179 can be maneuvered to control air flow therethrough.
  • the vanes are positioned in a fully open position thereby permitting a maximum air flow.
  • Controlling the amount of secondary air 128 flowing into the lower end of the combustor 14 controls both the secondary air 128 to wood fuel 152 ratio and the flame temperature in the refractory section 153 of the combustor and promotes swirling of the wood fuel 152 for a more thorough combustion of the wood fuel 152.
  • the degree of opening between the vanes 179 is achieved with the actuator 180 which either draws the vanes closer or separates them via the connecting linkage 181.
  • the combustor liner 68 defines a plurality of spaced annular slots 70, as shown in Figure
  • the annular slots 70 permit cooling- dilution air 129 flowing in the annulus 72 to enter into the combustion zone 122 for supporting combustion throughout the combustor 14 and controlling the flame and gas temperature.
  • the combustor liner 68 is manufactured from 0.125 in. thick INCONEL 625, 309 SST or 310 SST. Cooling-dilution air 129 circulates within the annulus 72 to cool the combustor liner 68.
  • the combustor liner 68 is cooled to below the ash slagging temperature such that
  • bypass assembly 104 are provided proximate the exit of the cyclone ash separator 16.
  • the outer shell 94 of the cyclone 16 is fabricated from carbon steel or the equivalent.
  • Cooling-dilution air 129 is circulated in the annulus 98 between the outer shell 94 and the cyclone liner 96 from the combustor annulus 72.
  • the cooling-dilution air 129 flows around the cyclone liner 96 to cool the cyclone liner 96 and keep the liner 96 below slagging temperature. Further, the circulating air serves to cool the outside shell 94 of the cyclone 16 to reduce thermal losses .
  • the ash collector 100 is located at the lower end of the cyclone liner 96 and defines two ash lock hoppers 106, 108 for receiving and holding the ash collected.
  • Each ash lock hopper 106, 108 defines a discharging valve 109
  • the generator break 125 and emergency shutdown button in the control room are operated by the system pressure.
  • the air bypass assembly 104 permits and controls the flow of air 128 (air flowing in the annulus 98 of the cyclone 16) combining with the cleaned combustion gas 126 as the gas 126 exits the cyclone 16 through the duct 110.
  • the air bypass assembly 104 includes a fixed sleeve
  • the fixed sleeve 182 is defined by the first end of the duct 110 exiting the cyclone 16.
  • the fixed sleeve 182 encircles the outlet pipe 184 in a manner such that an annular space
  • the fixed sleeve 182 supports the lower end of the outlet pipe 184 such that it is retained within the fixed sleeve 182. Further, the fixed sleeve 182 defines a plurality of openings 183 at an upper portion thereof, as shown in Figure 1.
  • the control sleeve 185 is annularly received by an outer surface of the fixed sleeve 182 proximate the plurality of openings 183 and defines a plurality of openings 187 which correspond to the openings 183 defined by the fixed sleeve 182, as shown in Figure 1.
  • the control sleeve 185 rotates to control the flow of air 128 flowing from the annulus 98 of the cyclone 16 through the upper portion of the annular space 186 defined between the fixed sleeve 182 and the outlet pipe 184.
  • This air 128 combines with the combustion gas 126 exiting the upper end of the outlet pipe 184.
  • the control sleeve 185 rotates in a limited manner, in one direction to fully block the openings 183 of the fixed sleeve 182 and in the opposing direction to reveal partially or fully the openings 183 of the fixed sleeve 182 thereby controlling the flow rate of the tertiary air or cooling-dilution air 129.
  • outlet pipe 184 defines a plurality of vents 188. Air flowing in the lower portion of the annular space 186 serves to cool the outlet pipe 184 and exits through the vents 188 into the entrance of the outlet pipe 184 to combine with the cleaned combustion gas 126.
  • Air flowing in the lower portion of the annular space 186 serves to cool the outlet pipe 184 and exits through the vents 188 into the entrance of the outlet pipe 184 to combine with the cleaned combustion gas 126.
  • the air bypass assembly 104 includes a casing 112 sealed around the first end of the duct 110 and a pressure controlled bypass flow valve 114.
  • the first end of the duct 110 defines a plurality of openings 116 open to the casing 112.
  • the bypass flow valve 114 is manufactured from SST 309 or an equivalent material .
  • the flame temperature and cyclone exit air temperature are monitored and controlled with excess air by modulating the bypass flow.
  • the bypassed air 128 is directed into the cyclone exit vortex to decrease cyclone pressure loss and to increase cyclone efficiency during operation of the system.
  • a steam injector 118 is in communication with the duct 110 to inject steam into the stream of cleaned combustion gas 126 and bypassed air for added power.
  • steam injectors 134 are utilized to inject steam into the secondary air 128 at the lower end of the combustor 14 and the lower end of the cyclone 16.
  • the gas generator 18 is rotated at low speed with a hydraulic starter (not shown) to create a gentle draft and purge the system 10.
  • Natural gas, oil or LPG is injected into the bottom of the combustor 14, through the starter fuel inlet or gas burner 78, and ignited by a high temperature electrical spark to warm the combustor 14 and cyclone 16 and preheat the refractory cone 80.
  • the gas burner 78 is utilized and is controlled via the commercial gas burner controller 190 which includes a gas pressure control 192 and an air flow control 194.
  • the gas generator 18 is accelerated by the starter engine, and sawdust fuel 152 injection is started. After the sawdust fuel 152 is ignited and the speed of the gas generator turbine 20 is increased by a combination of energy input from the starter engine and the progressively increased combustion rate, the natural gas fuel/oil is turned off. When the gas generator 18 reaches a self-sustaining energy balance speed, the starter engine is turned off.
  • the sawdust fuel feed rate is 3.5 lb/sec with 2 - 4 lb/sec primary air.
  • Secondary and tertiary air 128 are supplied from the compressor 21 and function to support combustion and control flame and gas temperature.
  • the air 128 enters the combustor via the port 95 at the bottom of the combustor
  • the air enters the port 95 at a rate of 121.5 lb/sec, a temperature of 600°F and a pressure of 125 psi with a density of 0.318 ftVsec.
  • the secondary air 128 flows through the vanes 179 at the lower end of the combustor 14 and enters the refractory section 153.
  • the secondary air 128 flowing through the vanes 179 serves two main functions: to swirl the wood fuel 152 as it feeds into the refractory section 153; and to control the flame temperature in the refractory section 153.
  • the vanes 179 are configured such that as the air/wood fuel mixture enters the refractory section 153 it establishes a swirling action such that the wood fuel 152 is retained within the refractory section 153 for an extended period to encourage more thorough heating of the wood fuel 152, ultimately encouraging combustion of all wood fuel 152.
  • the conditions in the refractory section 153 are below stoichiometric conditions such that complete combustion does not take place in the refractory section 153.
  • the majority of the tertiary air 130 enters the combustion zone 154 just above the refractory 80 through a network of holes and/or slots 71 defined by the combustor liner 68 to complete combustion in a super stoichiometric condition.
  • the amount of air fed into the combustion zone 122 is such that the oxygen content is above stoichiometry .
  • the surface temperatures inside the combustor liner 68 are about 1400°F maximum due to cooling by the cooling-dilution air 129 which is at approximately 640°F.
  • Surface temperatures of the outside of the combustor liner 68 are approximately 910°F while the insulated outer wall of the outer shell 66 is about 269°F.
  • the resulting outside ambient air is about 100°F.
  • the primary air 150 for injection with the wood fuel 152 comes directly from the compressor 21.
  • the air is fed through a booster fan.
  • the sawdust fuel 152 enters from the bottom of the pressurized charge vessel assembly 32 and is carried by the primary air 150 to the bottom of the combustor 14 where it is injected.
  • the booster fan 175, mounted in a pressure vessel 176 is utilized to boost the pressure and temperature of the primary air 150 before it is ultimately delivered to the bottom of the combustor 14.
  • Combustion temperatures inside the refractory section 153 at the bottom of the combustor 14 reach approximately 2200°F (for a short period of time, e.g., less that 1 sec.) and decrease along the combustor as the cooling-dilution air 129 flows into the combustion zones through the combustor annular slots 70.
  • the cooling of the inner wall of the combustor liner 68 by the cooling-dilution air 129 flow prevents slag formation and residue inside the combustor liner wall.
  • the temperature of the combustion gas cools to 1600°F maximum as it turns into the communication pipe 84 joining the combustor 14 and the cyclone 16.
  • Clean combustion gas 126 exits at the top of the cyclone 16 at a maximum temperature of 1580°F, at 70 lb/sec and at 122 psi. As it exits, the clean combustion gas 126 is mixed with diverted air 128 from the air bypass assembly 104 and then is routed to the turbine 20 via the duct 110, at a pressure of approximately 122 psi and a temperature of 1350°F.
  • the use of the bypass air allows the combustor volume to be reduced.
  • the lower air- gas flow rate through the combustor 14 and the cyclone 16 decreases ash carry over and allows the design of a more efficient cyclone 16. This feature reduces the ash grains per cubic foot in the turbine exhaust by 50%.
  • the gas generator 18 utilized in the system 10 has a split shaft to allow the gas generator turbine 20 and power turbine 19 to rotate at different revolutions per minute.
  • the gas generator 18 is a modified commercial gas turbine with a special center section and automatic check valves 121 to allow off-board firing without blowback. These automatic check valves 121 reduce the pressure drop between the compressor discharge and the turbine inlet, as well as reducing compressor air back-pressure for easy start of the gas generator.
  • the combustion gas 126 Upon entering the gas generator turbine 20, the combustion gas 126 expands to produce work.
  • the gas generator turbine 20 powers the air compressor 21 via a drive shaft.
  • the power turbine 19 drives the electrical generator 17 which is linked to any suitable electrical power transmission line. The power in excess of that required to drive the biomass burning system 10 is supplied to the outside user.
  • a load rejection device is not needed due to the internal use of electrical power in the biomass burning system 10 and specifically in the wood drying process and the use of a special brake between the turbine gear box 123 and generator 17. If the generator 17 should be disconnected from the power grid or lose its field, the central control system 136 would automatically stop the biomass fuel dust, open the pressure relief valves 127 and apply a caliper brake 125 to prevent a generator overspeed. Steam is injected (as at 118) to boost turbine power after reaching 90% of achievable power by using wood fuel only.
  • the control system 22 includes a combustion control processor (CCP) 136 which is utilized to monitor and control the biomass burning system 10.
  • the CCP 136 is a distributed process controller that regulates the combustion process and monitors the combustion gas 125 and cleaned combustion gas 126.
  • the distributed process controller is a Bristol Babcock 3335 DPC.
  • the purpose of the control system 22 is to monitor functions from the biomass burning system 10, a generator instrument package (GIP) 140, a turbine instrument package (TIP) 138 and a continuous emissions monitor (CEM) 142, and to use these inputs to provide a safe and efficient control of the biomass burning system 10 and to instruct the speed tachometer 146 and power controller 148.
  • the GIP is an Allen Bradley line synchronization module
  • the TIP is manufactured by General Electric (model number 7LM1500 GD102)
  • the CEM is an EPI 410.
  • FIG. 8 illustrates the major CCP input and output signals and controller functions. Each are labeled according to the various elements of the system.
  • the biomass burning process includes the wood processing and the combustion process. Selected conditions within the wood processing system 12, the combustor 14, the cyclone 16 and the gas generator 18 are monitored by the CCP 136. Within the wood processing system 12, the temperature of the hot exhaust for drying and the dryer inlet and outlet air temperatures are monitored. Moisture monitors 63 are located throughout the wood processing system 12 to monitor the moisture of the wood fuel 152 as it is processed for use. In the combustor 14, the temperature of the combustion zone 122 is monitored, and preferably the first 154, second 156, fourth 158 and fifth zones 160 are individually monitored. Moreover, the temperature at the entrance of the first combustion zone 154 and the temperature at the exit of the first zone 154 are specifically monitored.
  • the temperatures at these various locations are measured with high temperature thermocouples, type S (as at 211 in Figure 4) .
  • the temperature of the combustor 122 liner walls is controlled by modulating the cyclone bypass valve 185 to flow the proper amount of cooling-dilution air 129 through the combustor cooling annulus 72.
  • the position of the cyclone bypass vlave 185 is controlled by the CCP 136.
  • thermocouples 150 after the cooler and after water injection, and the temperature of the secondary air 128 before and after steam injection are monitored, preferably, with type K thermocouples.
  • the mass flow, the fuel feed rate and pressure in the injection line 173 are monitored.
  • the mass flow rate is measured with a Kurz mass flow monitor.
  • the injection line fuel feed rate is measured with a pressure transmitter.
  • the feed rate of fuel is a function of the revolutions per minute (RPM) of the injector screw.
  • the pressure at the exit of the combustor 14, the pressure across the pneumatic feed booster and the compressor 21 air flow into the combustor 14 are monitored, preferably, with pressure transmitters. Further, the temperature of the combustion gas 125 entering the cyclone and the cleaned combustion gas 126 exiting the cyclone are monitored.
  • the temperature of the gas entering the gas generator turbine 20, the temperature of the gas leaving the power turbine 19, the flow rate of air flowing in the gas generator air vent 25 and the pressure at the exit of the compressor 21 are also monitored with similar transducers. Further, the gas generator speed and the power turbine speed are monitored and, in the preferred embodiment, the load of the turbine 19 is also monitored such that the control system 22 can maintain the turbine 19 at a constant speed with a variable load. a more rapid response is provided when both the speed and the load are monitored.
  • the generator instrument package (GIP) 140 and the turbine instrument package (TIP) 138 function as industrial systems maintaining the turbine 19 and generator 18 functions and monitor certain aspects of the generator 18 and the turbine 19, respectively, such as vibration, lube oil pressure and temperature, power turbine and gas generator RPM, generator volts, amps etc.
  • the GIP 140 and TIP 138 provide controls for shutting down the system when preestablished limits have been passed.
  • the continuous emissions monitor (CEMS) 142 controls emissions, regulates combustion and provides environmental reporting. Specifically, the continuous emissions monitor 142 monitors the level of carbon monoxide, particulates, and N0 X in the turbine exhaust gas.
  • the CEMS controls emissions by monitoring the exhaust carbon monoxide level and regulating the combustor air via the CCP.
  • the controls are implemented to control the level of CO when it exceeds EPA standards .
  • the CCP 136 uses a software program to control the steam injector 118 at the exit of the cyclone 16, the steam injectors
  • the vane actuator 180 for controlling the flow of the secondary air 128 into the combustor 14, the fuel feed injector 74, the gas burner controller 190, the air bypass assembly 104 and the thermal relief valve, 102.
  • the CCP 136 outputs a current which provides a pressure signal to the vane actuator 180.
  • the air bypass assembly 104 is set according to the system power level.
  • the thermal relief valve 102 is interlocked with the distributed process controller and is opened with a key switch electro-pneumatic system.
  • the speed of the power turbine 19 is controlled in one of two manners depending upon whether the system 10 is linked to an outside system or not .
  • the speed is controlled by the 60 cycle balance of the transmission line.
  • the speed of the power turbine 19 and the gas generator 18 are under the control of the combustion control processor 136.
  • a mechanical speed governor is utilized as a control loop independent of the combustion control processor 136 for controlling the speed of the gas generator 18 in the event of a control system 22 failure.
  • the bypass valves 121 are opened and closed during the start cycle according to compressor RPM and compressor discharge pressure schedule, and closed and opened during the shut down process to prevent compressor stalls and surges.
  • valves 121 are controlled by the CCP 136.
  • the system for burning biomass provides an improved manner for injecting the wood fuel 152 or biomass into the combustor 14.
  • the control system includes an air bypass assembly 104 for injecting air into the stream of the combustion gas 126 to control the combustion process.
  • the use of the bypass assembly 104 permits the use of smaller cyclone 16, increases the efficiency of the cyclone filter and controls slagging and emissions.
  • a thermal relief valve 102 is included for rapid cooling of the gas generator turbine 20 and the combustor 14.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Fuel Combustion (AREA)
  • Incineration Of Waste (AREA)

Abstract

Cette invention concerne un système de brûlage d'une masse biologique visant à produire du gaz chaud. Ce système comprend un système de traitement du bois (28), une unité de combustion (14), un séparateur de cendres de type cyclone (16), une turbine (18) et un système de commande (136). Un dispositif de dérivation d'air va contrôler un flux d'air de dérivation (128) et le combiner aux gaz de combustion avant que ces derniers ne soient envoyés dans la turbine (18).
PCT/US1997/023647 1997-04-16 1997-12-18 Systeme de brulage d'une masse biologique visant a produire du gaz chaud WO1998046869A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR9710691-7A BR9710691A (pt) 1997-04-16 1997-12-18 Sistema para a queima de biomassa para a produção de gás quente.
AU57125/98A AU5712598A (en) 1997-04-16 1997-12-18 System for burning biomass to produce hot gas
NO985899A NO985899L (no) 1997-04-16 1998-12-16 System til forbrenning av biomasse for Õ produsere varm gass

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US84274897A 1997-04-16 1997-04-16
US08/842,748 1997-04-16

Publications (1)

Publication Number Publication Date
WO1998046869A1 true WO1998046869A1 (fr) 1998-10-22

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Application Number Title Priority Date Filing Date
PCT/US1997/023647 WO1998046869A1 (fr) 1997-04-16 1997-12-18 Systeme de brulage d'une masse biologique visant a produire du gaz chaud

Country Status (5)

Country Link
AU (1) AU5712598A (fr)
BR (1) BR9710691A (fr)
CA (1) CA2258579A1 (fr)
NO (1) NO985899L (fr)
WO (1) WO1998046869A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6862877B1 (en) 1999-04-06 2005-03-08 James Engineering (Turbines) Limited Gas turbines
EP2078151A1 (fr) * 2006-10-18 2009-07-15 LARSSON, Martin Moteur de véhicule
US9791351B2 (en) 2015-02-06 2017-10-17 General Electric Company Gas turbine combustion profile monitoring
US9790834B2 (en) 2014-03-20 2017-10-17 General Electric Company Method of monitoring for combustion anomalies in a gas turbomachine and a gas turbomachine including a combustion anomaly detection system
CN109059002A (zh) * 2018-08-01 2018-12-21 合肥右传媒科技有限公司 一种垃圾处理装置
CN111156106A (zh) * 2020-01-13 2020-05-15 黄菊青 一种蓄热式废气焚烧炉

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2171535A (en) * 1935-03-08 1939-09-05 Charles W Nichols Sr Incineration of high moisture refuse
US4409786A (en) * 1977-06-30 1983-10-18 Biomass Energy Systems, Incorporated Wood burning system and method
US5341637A (en) * 1992-12-22 1994-08-30 Hamrick Joseph T System for burning biomass to fuel a gas turbine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2171535A (en) * 1935-03-08 1939-09-05 Charles W Nichols Sr Incineration of high moisture refuse
US4409786A (en) * 1977-06-30 1983-10-18 Biomass Energy Systems, Incorporated Wood burning system and method
US5341637A (en) * 1992-12-22 1994-08-30 Hamrick Joseph T System for burning biomass to fuel a gas turbine

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6862877B1 (en) 1999-04-06 2005-03-08 James Engineering (Turbines) Limited Gas turbines
EP2078151A1 (fr) * 2006-10-18 2009-07-15 LARSSON, Martin Moteur de véhicule
EP2078151A4 (fr) * 2006-10-18 2014-05-14 Martin Larsson Moteur de véhicule
US9790834B2 (en) 2014-03-20 2017-10-17 General Electric Company Method of monitoring for combustion anomalies in a gas turbomachine and a gas turbomachine including a combustion anomaly detection system
US9791351B2 (en) 2015-02-06 2017-10-17 General Electric Company Gas turbine combustion profile monitoring
CN109059002A (zh) * 2018-08-01 2018-12-21 合肥右传媒科技有限公司 一种垃圾处理装置
CN111156106A (zh) * 2020-01-13 2020-05-15 黄菊青 一种蓄热式废气焚烧炉
CN111156106B (zh) * 2020-01-13 2021-07-20 绍兴钱康机械科技有限公司 一种蓄热式废气焚烧炉

Also Published As

Publication number Publication date
BR9710691A (pt) 2000-01-11
AU5712598A (en) 1998-11-11
NO985899L (no) 1999-02-02
CA2258579A1 (fr) 1998-10-22
NO985899D0 (no) 1998-12-16

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