WO1998041094A1 - Melange fongicide - Google Patents

Melange fongicide Download PDF

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Publication number
WO1998041094A1
WO1998041094A1 PCT/EP1998/001034 EP9801034W WO9841094A1 WO 1998041094 A1 WO1998041094 A1 WO 1998041094A1 EP 9801034 W EP9801034 W EP 9801034W WO 9841094 A1 WO9841094 A1 WO 9841094A1
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WO
WIPO (PCT)
Prior art keywords
co2ch3
compound
phenyl
noch
compounds
Prior art date
Application number
PCT/EP1998/001034
Other languages
German (de)
English (en)
Inventor
Oliver Wagner
Herbert Bayer
Ulf Misslitz
Ulrich Schirmer
Eberhard Ammermann
Gisela Lorenz
Siegfried Strathmann
Original Assignee
Basf Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Aktiengesellschaft filed Critical Basf Aktiengesellschaft
Priority to AU67240/98A priority Critical patent/AU6724098A/en
Publication of WO1998041094A1 publication Critical patent/WO1998041094A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products

Definitions

  • the present invention relates to a fungicidal mixture which
  • R is a C-organic residue which is directly or via a
  • n 0, 1, 2 or 3, where the radicals X can be different if n is greater than 1;
  • X is cyano, nitro, halogen, C ⁇ -C -alkyl, C 4 haloalkyl, C ⁇ -C 4 -alkoxy, C 4 haloalkoxy, C ⁇ -C4-alkylthio;
  • n> 1 a C 3 -C 5 alkylene, C 3 -C 5 alkenylene, oxy-C 2 -C 4 alkylene, oxy bonded to two adjacent C atoms of the phenyl ring -C ⁇ -C 3 -alkyl- noxy-, oxy-C -C 4 -alkenylene, oxy-C 2 -C 4 -alkenyleneoxy or butadienediyl group, these chains in turn can carry one to three of the following radicals: halogen, C ⁇ -C 4 alkyl, C 1 -C 4 haloalkyl, C ⁇ -C 4 -alkoxy, C 4 -haloalkoxy or C ⁇ -C 4 alkylthio,
  • Y C- or -N-;
  • Q cyclopentenyl, cyclohexenyl, phenyl, pyrrolyl, thienyl, furyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, thiadiazolyl, triazolyl, pyridinyl, 2-pyridonyl, pyrimidinyl and triazinyl;
  • the invention also relates to processes for the preparation Derar ⁇ term mixtures, and using the mixtures, for combating harmful fungi in the field of crop and Materialschut ⁇ zes.
  • the herbicidal active ingredient II (trade name: Dicamba) is from the literature (cf. for example "The Pesticide Manual", British Crop Protection Council, 10th edition 1994; US-A 3,013,054), for example for combating broad-leaved plants in cereals (as Herbicide) as well as an auxin-like growth regulator.
  • Active ingredient III (proposed trade name: diflufenzopyr) is also known from the literature (cf. AGROW No. 261, Aug. 2, 1996) as a herbicide with an auxin transport-inhibiting action.
  • the active ingredients IA and IB are, for example, in the following
  • the present invention was based on the object of mixtures which are suitable when using smaller amounts of the compounds IA and IB to develop an improved action against the harmful fungi (synergistic action).
  • Aryloxy optionally subst. Hetaryloxy, optionally subst. Aryl oxymethylene, if necessary subst. Hetaryloxymethylene, optionally subst. Aryl - ethenylene, optionally subst.
  • R ⁇ , R ß R ⁇ , R ⁇ and R ⁇ in general and in particular those in the have the meanings described below: EP-A 370 629, EP-A 414 153, EP-A 426 460, EP-A 460 575, EP-A 463 488, EP-A 472 300, EP-A 498 188, EP A 498 396, EP-A 515 901, EP-A 585 751, EP-A 619 301, EP-A 658 547, WO-A 90 / 07,493,
  • radicals "optionally substituted aryloxy, optionally substituted hetaryloxy" generally and in particular correspond to the meanings described in the following documents: EP-A 178 826, EP-A 242 070, EP-A 242 081, EP- A 253 213, EP-A 254 426, EP-A 256 667, EP-A 260 794, EP-A 280 185, EP-A 307 103, EP-A 341 845, EP-A 382 375, EP-A 393 861, EP-A 398 692, EP-A 405 782, EP-A 430 471, EP-A 468 684, EP-A 468 695, EP-A 477 631, EP-A 483 985, EP-A 498 188, EP-A 513 580, EP-A 515 901, EP-A 623 604, EP-A 634 405, EP-A 647 631, EP-A 658 547, EP-A 667 343, EP-A 669
  • radicals "optionally substituted aryloxymethylene, optionally substituted hetaryloxymethylene” generally and in particular correspond to those described in the following documents Meanings: EP-A 178 826, EP-A 226 917, EP-A 253 213, EP-A 254 426, EP-A 278 595, EP-A 280 185, EP-A 299 694,
  • radicals "optionally substituted arylethenylene, optionally substituted hetarylethenylene” generally and in particular correspond to the meanings described in the following documents: EP-A 178 826, EP-A 203 606, EP-A 253 213, EP- A 254 426, EP-A 280 185, EP-A 378 755, EP-A 398 692, EP-A 402 246,
  • EP-A 474 042 EP-A 475 158, EP-A 477 631, EP-A 487 409, EP-A 498 188, EP-A 498 396, EP-A 513 580, EP-A 515 901, EP- A 528 245, EP-A 544 587, EP-A 658 547, EP-A 669 315, EP-A 691 332, WO-A 93 / 15,046, WO-A 94 / 11,334, WO-A 95 / 01,973, WO -A 96 / 17,851, WO-A 96 / 22,983, WO-A 96 / 31,463, WO-A 96 / 35,669, WO-A 96 / 35,690, and FR-A 2 670 781.
  • EP-A 398 692 EP-A 463 488, EP-A 477 631, EP-A 515 901, EP-A 579 124, EP-A 585 751, EP-A 617 014, EP-A 621 277 , EP-A 622 355, EP-A 623 604, EP-A 627 411, EP-A 628 540, EP-A 647 631, EP-A 656 351, EP-A 667 343, EP-A 669 315, EP -A 669 319, EP-A 673 923, EP-A 691 332,
  • R ' represents -N (OCH 3 ) C0 2 CH 3 , -N (CH 3 ) -C0 2 CH 3 or -N (CH 2 CH 3 ) -C0 2 CH 3 , correspond in general and in particular to the compounds described in the following documents: EP-A 498 396, EP-A 619
  • n has the value 0, R "for optionally subst.
  • active ingredients IA or IB and II When preparing the mixtures, preference is given to using the pure active ingredients IA or IB and II, to which, as required, further active ingredients can be added to combat pests (e.g. insects, arachnids or nematodes) or harmful fungi or else herbicidal or growth-regulating active ingredients or fertilizers.
  • pests e.g. insects, arachnids or nematodes
  • harmful fungi e.g. insects, arachnids or nematodes
  • herbicidal or growth-regulating active ingredients or fertilizers e.g. insects, arachnids or nematodes
  • mixtures of the compounds IA or IB and II or the simultaneous joint or separate use of the compounds IA and II or IB and II are distinguished by an excellent action against a broad spectrum, in particular of phytopathogenic fungi. They are partly systemically effective (i.e. when used for crop protection, they can be absorbed by the treated plant without loss of activity and possibly transported in the plant) and can therefore also be used as leaf and soil fungicides.
  • Botrytis cinerea (gray mold) on strawberries, vegetables, ornamental plants and vines
  • Erysiphe graminis (powdery mildew) on cereals, Fusarium and Verticillium species on various plants, Helmin thosporium species on cereals, Mycosptiaerella species on bananas,
  • the mixtures according to the invention are also suitable for combating harmful fungi such as Paecilomyces variotii in the protection of materials (e.g. wood, paper, dispersions for addressing, fibers or fabrics) and in the protection of stored goods.
  • harmful fungi such as Paecilomyces variotii in the protection of materials (e.g. wood, paper, dispersions for addressing, fibers or fabrics) and in the protection of stored goods.
  • the compounds IA or IB and II and / or III can be applied simultaneously, that is together or separately or in succession, the sequence in the case of separate application generally not having any effect on the success of the control measures.
  • the compounds IA and II or IB and II are usually in a weight ratio of 10: 1 to 0.1: 1, preferably 5: 1 to 0.2: 1, in particular 2: 1 to 0.5: 1 (IA: II or IB: II) applied.
  • the compounds IA or IB and III are usually in a weight ratio of 25: 1 to 0.25: 1, preferably
  • the compounds IA or IB and II and III are usually in a weight ratio of 10: 1: 0.4 to 0.1: 1: 0.4, preferably 5: 1: 0.4 to 0.2: 1: 0 , 4, in particular 2: 1: 0.4 to 0.5: 1: 0.4 (IA: II: III or IB: II: III), applied.
  • the application rates of the mixtures according to the invention are from 2 to 0.1 kg / ha, preferably from 1.25 to 0.2 kg / ha, in particular from 0.75 to 0.3, depending on the type of effect desired kg / ha.
  • the application rates for the compounds IA and IB are 1 to 0.01 kg / ha, preferably 0.5 to 0.02 kg / ha, in particular 0.25 to 0.03 kg / ha.
  • the application rates for the compounds II are generally from 0.5 to 0.001 kg / ha, preferably 0.25 to 0.005 kg / ha, in particular 0.1 to 0.01 kg / ha.
  • the application rates for the compound III are in general from 0.001 to 0.3 kg / ha, preferably 0.005 to 0.2 kg / ha, into ⁇ particular 0.01 to 0.1 kg / ha.
  • the mixing ratios with respect to the compounds II and III are generally 4: 1, preferably 3: 1, in particular 2.5: 1 (II: III).
  • application rates of mixture of 0.1 to 100 g / 100 kg of seed, preferably 0.5 to 50 g / 100 kg of seed, in particular 1 to 10 g / 100 kg of seed, are generally used.
  • the application rates of the mixtures according to the invention are from 0.01 to 20 g / m 3 , preferably 0.05 to 10 g / m 3 , in particular 0.1 to 5, depending on the type of effect desired g / m 3 .
  • the compounds IA or IB and II and / or III or the mixtures of the compounds IA or IB and II and / or III are applied jointly or separately by spraying or dusting the seeds, the Plants or the soil before or after sowing the plants or before or after the plants germinate.
  • the fungicidal synergistic mixtures according to the invention or the compounds IA or IB and II and / or III can be used, for example, in the form of directly sprayable solutions, powders and suspensions or in the form of high-strength aqueous, oily or other suspensions, dispersions, emulsions, oil dispersions, pastes , Dusts, scattering agents or granules are prepared and applied by spraying, atomizing, dusting, scattering or pouring.
  • the form of application depends on the intended use; in any case, it should ensure as fine and uniform a distribution of the mixture according to the invention as possible.
  • the formulations are prepared in a manner known per se, for example by adding solvents and / or carriers.
  • Inert additives such as emulsifiers or dispersants are usually added to the formulations.
  • the surface-active substances are the alkali, alkaline earth and ammonium salts of aromatic sulfonic acids, for example lignin, phenol, naphthalene and dibutylnaphthalenesulfonic acid, and of fatty acid, alkyl and alkylarylsulfonates, alkyl, lauryl ether and fatty alcohol sulfates, and salts of sulfated hexa- , Hepta- and octadecanols or fatty alcohol glycol ethers, condensation products of sulfonated naphthalene and its derivatives with formaldehyde, condensation products of naphthalene or naphthalenesulfonic acids with phenol and formaldehyde, poly
  • Powders, materials for broadcasting and dusts can be prepared by mixing or jointly grinding the compounds IA or IB and II and / or III or the mixtures of the compounds IA or IB and II and / or III with a solid carrier.
  • Granules e.g. coating, impregnation or homogeneous granules
  • a solid carrier e.g., a wax, a wax, or a wax.
  • Mineral earths such as silica gel, silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics serve as fillers or solid carriers, for example. and fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell flour, cellulose powder and other solid carriers.
  • fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell flour, cellulose powder and other solid carriers.
  • the formulations generally contain 0.1 to 95% by weight, preferably 0.5 to 90% by weight, of one of the compounds IA or IB or II or III or the mixture of the compounds IA or IB and II and / or III.
  • the active ingredients are in a purity of 90% to
  • the compounds IA, IB, II and III or their mixtures or the corresponding formulations are used by adding the harmful fungi, their habitat or those prior to fungal attack protective materials, plants, seeds, soils, areas or spaces with a fungicidally effective amount of the mixture or of the compounds IA or IB and II and / or III treated separately.
  • the treatment can be carried out before or after the 5 infection by the harmful fungi.
  • the active compounds were prepared separately or together as a 10% emulsion in a mixture of 67% by weight cyclohexanone and 23% by weight 5 emulsifier and diluted with water in accordance with the desired concentration.
  • W (1 - ⁇ ) -100 / ß 5 ⁇ corresponds to the fungal attack of the treated plants in% and ß corresponds to the fungal attack of the untreated (control) plants in%
  • the infection of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants showed no infection.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

L'invention concerne un mélange fongicide à action synergique contenant a) un composé à action fongicide de la formule IA ou IB où - - - représente une liaison simple ou double et où l'indice et les substituants ont la signification suivante: R' représente -C[CO2CH3] =CHOCH3, -C[CO2CH3] =NOCH3, -C[CONHCH3] =NOCH3, -C[CO2CH3] =CHCH3, -C[CO2CH3] =CHCH2CH3, -C[COCH3] =NOCH3, -C[COCH2CH3] =NOCH3, -N(OCH3) -CO2CH3, -N(CH3) -CO2CH3, -N(CH2CH3) -CO2CH3; R'' est un reste organique de carbone lié directement ou par l'intermédiaire d'un groupe oxy, mercapto, amino ou alkylamino; et représente, conjointement avec un groupe X et le cycle Q et T auquel il est lié, un système bicyclique partiellement ou entièrement insaturé, éventuellement substitué: Rx représente -OC[CO¿2?CH3] =CHOCH3, -OC[CO2CH3] =CHCH3, -OC[CO2CH3] =CHCH2CH3, -SC[CO2CH3] =CHOCH3, -SC[CO2CH3] =CHCH3, -SC[CO2CH3] =CHCH2CH3, -N(CH3)C[CO2CH3] =CHOCH3, -N(CH3)C[CO2CH3] =NOCH3, -CH2C[CO2CH3] =CHOCH3, -CH2C[CO2CH3] =NOCH3, -CH2C[CONHCH3] =NOCH3; R?y¿ représente oxygène, soufre, =CH- ou =N-; n vaut 0, 1, 2 ou 3; X représente cyano, nitro, halogène, alkyle, halogénure d'alkyle, alcoxy, halogénure d'alcoxy, alkylthio; si n⊃1, un groupe alkylène, un groupe alcénylène, un groupe oxyalkylène, un groupe oxyalcylénoxy, un groupe oxyalcénylène, un groupe oxyalcénylénoxy ou un groupe butadiendiyle éventuellement substitué et lié à deux atomes de carbone voisins du cycle phényle, Y =C- ou -N-; Q représente cyclopentényle, cyclohexényle, phényle, pyrrolyle, thiényle, furyle, pyrazolyle, imidazolyle, oxazolyle, isoxazolyl, thiazolyle, thiadiazolyle, triazolyle, pyridinyle, 2-pyridonyle, pyrimidinyle et triazinyle; T représente phényle, oxazolyle, thiazolyle, thiadiazolyle, oxadiazolyle, pyridinyle, pyrimidinyle et triazinyle. Le mélange contient également b) le principe actif II herbicide et/ou b2) le principe actif III herbicide. L'invention concerne enfin le procédé de production d'un tel mélange ainsi que le procédé d'utilisation du mélange pour lutter contre les champignons nuisibles dans le domaine de la protection des plantes et des matériaux.
PCT/EP1998/001034 1997-03-14 1998-02-23 Melange fongicide WO1998041094A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU67240/98A AU6724098A (en) 1997-03-14 1998-02-23 Fungicide mixture

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19710760.5 1997-03-14
DE1997110760 DE19710760A1 (de) 1997-03-14 1997-03-14 Fungizide Mischung

Publications (1)

Publication Number Publication Date
WO1998041094A1 true WO1998041094A1 (fr) 1998-09-24

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PCT/EP1998/001034 WO1998041094A1 (fr) 1997-03-14 1998-02-23 Melange fongicide

Country Status (5)

Country Link
AR (1) AR012558A1 (fr)
AU (1) AU6724098A (fr)
CO (1) CO5060422A1 (fr)
DE (1) DE19710760A1 (fr)
WO (1) WO1998041094A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000030450A1 (fr) * 1998-11-19 2000-06-02 Basf Aktiengesellschaft Melanges fongicides
WO2000036921A1 (fr) * 1998-12-22 2000-06-29 Basf Aktiengesellschaft Melange fongicide
WO2006120231A2 (fr) * 2005-05-12 2006-11-16 Basf Aktiengesellschaft Procede d'amelioration de la resistance de cultures
WO2010149732A2 (fr) 2009-06-25 2010-12-29 Basf Se Utilisation de mélanges agrochimiques pour augmenter la santé d'une plante

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CN1972594A (zh) * 2004-05-13 2007-05-30 巴斯福股份公司 基于三唑并嘧啶衍生物的杀真菌混合物

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WO1996032015A1 (fr) * 1995-04-08 1996-10-17 Basf Aktiengesellschaft Compositions fongicides synergiques constituees de derives de quinoleine et en inhibiteurs de cytochrome b/c

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DE4309856A1 (de) * 1993-03-26 1994-09-29 Basf Ag Fungizide Mischung
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6503936B1 (en) 1998-11-19 2003-01-07 Basf Aktiengesellschaft Fungicidal mixtures
WO2000030450A1 (fr) * 1998-11-19 2000-06-02 Basf Aktiengesellschaft Melanges fongicides
AU767577B2 (en) * 1998-11-19 2003-11-20 Basf Aktiengesellschaft Fungicidal mixtures
CN1293809C (zh) * 1998-12-22 2007-01-10 巴斯福股份公司 杀菌混剂
CZ301438B6 (cs) * 1998-12-22 2010-03-03 Basf Aktiengesellschaft Fungicidní smesi a jejich použití
JP2002532524A (ja) * 1998-12-22 2002-10-02 ビーエーエスエフ アクチェンゲゼルシャフト 殺真菌剤混合物
AU769532B2 (en) * 1998-12-22 2004-01-29 Basf Aktiengesellschaft Fungicide mixture
US6541500B1 (en) 1998-12-22 2003-04-01 Basf Aktiengesellschaft Fungicide mixture
WO2000036921A1 (fr) * 1998-12-22 2000-06-29 Basf Aktiengesellschaft Melange fongicide
WO2006120231A2 (fr) * 2005-05-12 2006-11-16 Basf Aktiengesellschaft Procede d'amelioration de la resistance de cultures
WO2006120231A3 (fr) * 2005-05-12 2007-08-23 Basf Ag Procede d'amelioration de la resistance de cultures
WO2010149732A2 (fr) 2009-06-25 2010-12-29 Basf Se Utilisation de mélanges agrochimiques pour augmenter la santé d'une plante
WO2010149732A3 (fr) * 2009-06-25 2011-06-30 Basf Se Utilisation de mélanges agrochimiques pour augmenter la santé d'une plante
CN102458111A (zh) * 2009-06-25 2012-05-16 巴斯夫欧洲公司 农化混合物在提高植物健康中的用途
CN102458111B (zh) * 2009-06-25 2014-07-30 巴斯夫欧洲公司 农化混合物在提高植物健康中的用途
EA023113B1 (ru) * 2009-06-25 2016-04-29 Басф Се Применение агрохимических смесей для увеличения жизнеспособности растения
EA027489B1 (ru) * 2009-06-25 2017-07-31 Басф Се Применение агрохимических смесей для увеличения жизнеспособности растения
EP3213635A1 (fr) 2009-06-25 2017-09-06 Basf Se Utilisation de mélanges agrochimiques pour améliorer la santé d'une plante

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CO5060422A1 (es) 2001-07-30
AU6724098A (en) 1998-10-12
DE19710760A1 (de) 1998-09-17
AR012558A1 (es) 2000-11-08

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