WO1998036041A1 - Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside - Google Patents

Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside Download PDF

Info

Publication number
WO1998036041A1
WO1998036041A1 PCT/US1998/000215 US9800215W WO9836041A1 WO 1998036041 A1 WO1998036041 A1 WO 1998036041A1 US 9800215 W US9800215 W US 9800215W WO 9836041 A1 WO9836041 A1 WO 9836041A1
Authority
WO
WIPO (PCT)
Prior art keywords
carbon atoms
ether sulfate
composition
foam stabilizer
alkyl
Prior art date
Application number
PCT/US1998/000215
Other languages
English (en)
Inventor
Virginia Lazarowitz
Mary Frances Frazer
Original Assignee
Henkel Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corporation filed Critical Henkel Corporation
Priority to AU58163/98A priority Critical patent/AU5816398A/en
Priority to BR9807407-5A priority patent/BR9807407A/pt
Priority to EP98901706A priority patent/EP0981594A4/fr
Publication of WO1998036041A1 publication Critical patent/WO1998036041A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the present invention generally relates to enhancing the foam stability of light-duty liquid compositions. More particularly, by employing a surfactant mixture containing an alkyl ether sulfate and an alkyl polyglycoside, the foam stability of known foam stabilizer compositions can be enhanced.
  • surfactants have been found to be useful in cleaning compositions, such as shower gels, shampoos, and light duty detergents such as dish washing detergents. In these types of compositions, good foamability is a prerequisite.
  • anionic surfactants such as alkyl sulfates, alkyl ether sulfates, sulfonates, sulfosuccinates and sarcosinates.
  • Foam stability relates to the ability of the foam, once formed, to remain intact for extended periods of time in the presence of varying amounts of soil, thus enhancing the cleaning performance of the surfactant compositions.
  • foam stabilizers which are mixtures of surfactants in cleaning compositions when the surfactants can serve different functions, e.g., one serving to improve foamability and another serving to adjust viscosity.
  • known surfactant mixtures typically provide a compromise between what can be achieved with the surfactant ingredients alone.
  • a mixture of more costly surfactants such as amine oxides, betaines and alkanolamides which provide good foamability by themselves, with less expensive surfactants such as alkyl ether sulfonates, which provide poorer foamability, will result in the formulation of a cleaning composition having an intermediate degree of foamability and poor foam stability.
  • the present invention is directed to a process for making a cleaning composition having enhanced foam stability involving the steps of:
  • the present invention is also directed to a cleaning composition having enhanced foam stability properties consisting essentially of:
  • a surfactant mixture consisting essentially of: (i) an alkyl ether sulfate having from 1 to about
  • R is a monovalent organic radical having from about 6 to about 30 carbon atoms
  • R- is divalent alkylene radical having from 2 to 4 carbon atoms
  • Z is a saccharide residue having 5 or 6 carbon atoms
  • b is a number having a value from 0 to about 12
  • a is a number having a value from 1 to about 6, wherein components (a) (i) and (a) (ii) , respectively, are combined in a ratio by weight of from about 1: 1 to about 4:1; and
  • a foam stabilizer selected from the group consisting of a betaine, an alkanolamide, an amine oxide, and mixtures thereof.
  • Alkyl ether sulfates are generally defined as salts of sulfated adducts of ethylene oxide with fatty alcohols containing from about 10 to about 18 carbon atoms.
  • the alkyl ether sulfates employed in the present invention are commercially available and contain a linear aliphatic group having from about 8 to about 18 carbon atoms, and preferably from about 12 to about 14 carbon atoms.
  • the degree of ethoxylation is from 1 to about 4 moles of ethylene oxide, and preferably about 3 moles of ethylene oxide.
  • a particularly preferred alkyl ether sulfate for use in the present invention is sodium lauryl ether sulfate.
  • alkyl polyglycosides which can be used in the surfactant mixture according to the present invention have the general formula I:
  • Preferred alkyl polyglycosides which can be used in the compositions according to the invention have the formula I wherein Z is a glucose residue and b is zero.
  • alkyl polyglycosides are commercially available, for example, as APG®, GLUCOPON®, or PLANTAREN® surfactants from Henkel Corporation, Ambler, PA 19002.
  • surfactants include but are not limited to:
  • APG® 225 Surfactant - an alkyl polyglycoside in which the alkyl group contains 8 to 10 carbon atoms and having an average degree of polymerization of 1.7.
  • APG® 325 Surfactant - an alkyl polyglycoside in which the alkyl group contains 9 to 11 carbon atoms and having an average degree of polymerization of 1.6.
  • GLUCOPON® 600 Surfactant - an alkyl polyglycoside in which the alkyl group contains 12 to 16 carbon atoms and having an average degree of polymerization of 1.4.
  • PLANTAREN® 2000 Surfactant - a C 8 . 16 alkyl polyglycoside in which the alkyl group contains 8 to 16 carbon atoms and having an average degree of polymerization of 1.4.
  • PLANTAREN® 1300 Surfactant - a C 12 . 16 alkyl polyglycoside in which the alkyl group contains 12 to 16 carbon atoms and having an average degree of polymerization of 1.6.
  • alkyl polyglycoside surfactant compositions which are comprised of mixtures of compounds of formula I wherein Z represents a moiety derived from a reducing saccharide containing 5 or 6 carbon atoms; a is a number having a value from 1 to about 6; b is zero; and R 1 is an alkyl radical having from 8 to 20 carbon atoms.
  • compositions are characterized in that they have increased surfactant properties and an HLB in the range of about 10 to about 16 and a non-Flory distribution of glycosides, which is comprised of a mixture of an alkyl monoglycoside and a mixture of alkyl polyglycosides having varying degrees of polymerization of 2 and higher in progressively decreasing amounts, in which the amount by weight of polyglycoside having a degree of polymerization of 2, or mixtures thereof with the polyglycoside having a degree of polymerization of 3, predominate in relation to the amount of monoglycoside, said composition having an average degree of polymerization of about 1.8 to about 3.
  • compositions also known as peaked alkyl polyglycosides
  • the relative distribution of the various components, mono- and poly-glycosides, in the resulting product changes and the concentration in the product of the polyglycosides relative to the monoglycoside increases as well as the concentration of individual polyglycosides to the total, i.e.
  • alkyl polyglycosides which can be used in the compositions according to the invention are those in which the alkyl moiety contains from 6 to 18 carbon atoms in which the average carbon chain length of the composition is from about 9 to about 14 comprising a mixture of two or more of at least binary components of alkyl polyglycosides, wherein each binary component is present in the mixture in relation to its average carbon chain length in an amount effective to provide the surfactant composition with the average carbon chain length of about 9 to about 14 and wherein at least one, or both binary components, comprise a Flory distribution of polyglycosides derived from an acid-catalyzed reaction of an alcohol containing 6-20 carbon atoms and a suitable saccharide from which excess alcohol has been separated.
  • the preferred alkyl polyglycosides are those of formula I wherein R, is a monovalent organic radical having from about 10 to about 16 carbon atoms; b is zero; Z is a glucose residue having 5 or 6 carbon atoms; a is a number having a value from 1 to about 2 , and most preferably is 1.4.
  • the surfactant mixture of the present invention is prepared by mixing an alkyl ether sulfate with an alkyl polyglycoside, respectively, in a ratio by weight of from about 1:1 to about 4:1, and preferably about 2:1.
  • Foam stabilizers are typically employed in cleaning compositions in order to maintain the integrity of the foam in the presence of soil. Whereas the foam is formed by the surfactants contained in the cleaning composition, the foam stabilizer maintains the integrity of the foam once formed.
  • foam stabilizers which may be employed in the present invention are those selected from the group consisting of betaines, alkanolamides, amine oxides, and mixtures thereof.
  • Betaines also known as zwitterionics, are derivatives of aliphatic quaternary ammonium, phosphonium and sulphonium compounds in which the aliphatic radical may be straight chained or branched, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water-solubilizing group such as carboxy, sulpho, sulphato, phosphato or phosphono.
  • Those betaines encompassed by the present invention are generally alkyl betaines, alkyl amino betaines and alkyl amido betaines. Specific examples thereof include, but are not limited to, coco-betaine and cocamidopropyl betaine.
  • the fatty acid alkanolamides which may be used in the present invention contain from about 8 to about 18, and preferably from about 12 to about 14 carbon atoms in the alkyl group of the fatty acid residue.
  • the amide group may be substituted either by two C j -C. hydroxyalkyl groups, such as, for example, a dialkanolamide, or by one such hydroxyalkyl group and by one hydrogen or a C ⁇ C. alkyl group.
  • alkanolamides which may be used include, but are not limited to, cocodiethanolamide and laurylmyristic monoethanolamide.
  • Amine oxides which may be used in accordance with the present invention are of general formula II:
  • R 1 is an alkyl or alkenyl radical having from about 8 to about 18 carbon atoms
  • R 2 and R 3 are individually alkyl or hydroxyalkyl radicals having from 1 to about 3 carbon atoms.
  • amine oxides which may be employed include, but are not limited to, cocamine oxide and cocamidopropylamine oxide.
  • a process for making a surfactant composition having enhanced foam stability involves combining from about 5% to about 40% by weight, and preferably from about 20% to about 40% by weight of the above-disclosed surfactant mixture with from about 1% to about 10% by weight, and preferably from about 2% to about 5% by weight of the above-disclosed foam stabilizer, the remainder, up to 100%, water.
  • the surfactant mixture consists of a C 12 -C u alkyl ether sulfate having 2 moles of ethylene oxide in admixture with an alkyl polyglycoside of formula I wherein R, is a monovalent organic radical having from about 12 to about 16 carbon atoms, b is zero and a is a number having a value of about 1.4.
  • R is a monovalent organic radical having from about 12 to about 16 carbon atoms
  • b is zero
  • a is a number having a value of about 1.4.
  • the cleaning composition contains from about 5 to about 40% by weight, and preferably from about 20 to about 40% by weight, of the above-disclosed surfactant mixture in combination with from about 1 to about 10% by weight, and preferably from about 2 to about 5% by weight of the above-disclosed foam stabilizer.
  • the cleaning composition may also contain auxilliaries such as solvents, antimicrobials, thickeners, corrosion inhibitors, preservatives, dyes and perfume oils.
  • the remainder of the cleaning composition comprises water.
  • the present invention will be better understood from the examples which follow, all of which are intended to be illustrative only and not meant to unduly limit the scope of the invention. Unless otherwise indicated, percentages are on a weight-by-weight basis.
  • the cleaning compositions of Examples 1-6 were formulated on a 28% total actives basis, i.e., 12% active C 12 -C alkyl ether sulfate containing from 1 to 3 moles of ethylene oxide, 12% active GLUCOPON® 600, and 4% active foam stabilizer.
  • Foam stability performance was evaluated using the Modified Shell Terg-o-tometer test which involved adding 0.5 gram pellets of a soil consisting of Crisco, potato, milk and olive oil, every 30 seconds, to 400 ml of each surfactant solution in diluted form, in a tergotometer. Foam was generated by agitation of each solution for two minutes at 125 rpm.
  • Comparative examples 7-12 comprised a combination of the above ether sulfate at 24% actives and the various foam stablizers at 4% actives, for a total actives concentration of 28%.
  • the results of these foam stability tests are found in Table II. Table II
  • Comparative examples 13-18 comprised a combination of the GLUCOPON® 600 at a percent active of 24% and the various foam stabilizers at a percent actives of 4% for a total actives concentration of 28%. The results of these foam stability tests are found in Table III.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un procédé pour accroître la stabilité de la mousse d'une composition aqueuse de nettoyage, consistant: (a) à utiliser une composition de tensioactifs comprenant essentiellement: (i) un sulfate d'éther d'alkyle contenant 1 à environ 4 moles d'oxyde d'éthylène; et (ii) un alkylpolyglycoside de formule (I): R1O(R2O)b(Z)a, dans laquelle R1 représente un radical organique monovalent comportant environ 6 à environ 30 atomes de carbone; R2 représente un radical alkylène divalent comportant 2 à 4 atomes de carbone; Z représente un reste saccharide comportant 5 à 6 atomes de carbone; b est un nombre compris entre 0 et environ 12; a est un nombre compris entre 1 et environ 6, les composants (a)(i) et (a)(ii) respectivement, étant combinés dans un rapport des constituants actifs en pourcentage allant de 1:1 à environ 4:1; ledit procédé consiste également (b) à utiliser un stabilisateur de mousse sélectionné dans le groupe comprenant une bétaïne, une alcanolamide, un oxyde d'amide, et leurs mélanges; (c) à combiner les composants (a)-(c) pour former la composition aqueuse de nettoyage.
PCT/US1998/000215 1997-02-18 1998-01-15 Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside WO1998036041A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU58163/98A AU5816398A (en) 1997-02-18 1998-01-15 Improved light-duty liquid performance of ether sulfate using alkyl polyglycoside
BR9807407-5A BR9807407A (pt) 1997-02-18 1998-01-15 Processo para fabricar uma composição de limpeza aquosa tendo melhorada estabilidade de espuma, e , composição de limpeza aquosa
EP98901706A EP0981594A4 (fr) 1997-02-18 1998-01-15 Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80232497A 1997-02-18 1997-02-18
US08/802,324 1997-02-18

Publications (1)

Publication Number Publication Date
WO1998036041A1 true WO1998036041A1 (fr) 1998-08-20

Family

ID=25183392

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/000215 WO1998036041A1 (fr) 1997-02-18 1998-01-15 Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside

Country Status (4)

Country Link
EP (1) EP0981594A4 (fr)
AU (1) AU5816398A (fr)
BR (1) BR9807407A (fr)
WO (1) WO1998036041A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1003605A1 (fr) * 1997-06-12 2000-05-31 Henkel Corporation Emploi de polyglycosides d'alkyle ameliorant la stabilisation des mousses des amphoacetates
WO2000063134A1 (fr) * 1999-04-19 2000-10-26 Halliburton Energy Services, Inc. Laitiers de ciment petrolier en mousse, additifs et procedes
WO2000065012A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Detergents pour surfaces dures
WO2000065013A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Agents de nettoyage pour surfaces dures
WO2000065011A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Detergents pour surfaces dures
WO2006050788A1 (fr) * 2004-11-10 2006-05-18 The Procter & Gamble Company Produit de coiffure transparent, biphasique et moussant en aérosol
WO2011091875A3 (fr) * 2010-01-29 2013-05-16 Henkel Ag & Co. Kgaa Colorants sous forme de mousse
EP2121888B1 (fr) 2007-03-08 2015-04-22 Rhodia Operations Utilisation d'une betaïne a titre d'agent de reduction du drainage de la mousse
WO2015086270A1 (fr) * 2013-12-11 2015-06-18 Henkel Ag & Co. Kgaa Colorant sous forme de mousse présentant des propriétés d'application améliorées
US9249374B2 (en) 2010-10-25 2016-02-02 Stepan Company Light-duty liquid detergents based on compositions derived from natural oil metathesis

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4844821A (en) * 1988-02-10 1989-07-04 The Procter & Gamble Company Stable liquid laundry detergent/fabric conditioning composition
US5503779A (en) * 1995-03-20 1996-04-02 Colgate Palmolive Company High foaming light duty liquid detergent
US5646100A (en) * 1994-02-14 1997-07-08 Colgate-Palmolive Company Mild, aqueous skin cleansing composition

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3534082A1 (de) * 1985-09-25 1987-04-02 Henkel Kgaa Fluessiges reinigungsmittel
MY106599A (en) * 1988-12-19 1995-06-30 Kao Corp Detergent composition
GB2292562A (en) * 1994-07-13 1996-02-28 Procter & Gamble Liquid Detergent Compositions
US5476614A (en) * 1995-01-17 1995-12-19 Colgate Palmolive Co. High foaming nonionic surfactant based liquid detergent
DE19521351A1 (de) * 1995-06-12 1996-12-19 Henkel Kgaa Verdünnte wäßrige Tensidlösungen mit erhöhter Viskosität

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4844821A (en) * 1988-02-10 1989-07-04 The Procter & Gamble Company Stable liquid laundry detergent/fabric conditioning composition
US5646100A (en) * 1994-02-14 1997-07-08 Colgate-Palmolive Company Mild, aqueous skin cleansing composition
US5503779A (en) * 1995-03-20 1996-04-02 Colgate Palmolive Company High foaming light duty liquid detergent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0981594A4 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1003605A1 (fr) * 1997-06-12 2000-05-31 Henkel Corporation Emploi de polyglycosides d'alkyle ameliorant la stabilisation des mousses des amphoacetates
EP1003605A4 (fr) * 1997-06-12 2001-04-18 Henkel Corp Emploi de polyglycosides d'alkyle ameliorant la stabilisation des mousses des amphoacetates
WO2000063134A1 (fr) * 1999-04-19 2000-10-26 Halliburton Energy Services, Inc. Laitiers de ciment petrolier en mousse, additifs et procedes
WO2000065012A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Detergents pour surfaces dures
WO2000065013A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Agents de nettoyage pour surfaces dures
WO2000065011A1 (fr) * 1999-04-22 2000-11-02 Cognis Deutschland Gmbh Detergents pour surfaces dures
WO2006050788A1 (fr) * 2004-11-10 2006-05-18 The Procter & Gamble Company Produit de coiffure transparent, biphasique et moussant en aérosol
EP2121888B1 (fr) 2007-03-08 2015-04-22 Rhodia Operations Utilisation d'une betaïne a titre d'agent de reduction du drainage de la mousse
WO2011091875A3 (fr) * 2010-01-29 2013-05-16 Henkel Ag & Co. Kgaa Colorants sous forme de mousse
US9249374B2 (en) 2010-10-25 2016-02-02 Stepan Company Light-duty liquid detergents based on compositions derived from natural oil metathesis
WO2015086270A1 (fr) * 2013-12-11 2015-06-18 Henkel Ag & Co. Kgaa Colorant sous forme de mousse présentant des propriétés d'application améliorées

Also Published As

Publication number Publication date
EP0981594A1 (fr) 2000-03-01
AU5816398A (en) 1998-09-08
BR9807407A (pt) 2000-03-14
EP0981594A4 (fr) 2001-03-21

Similar Documents

Publication Publication Date Title
EP0509608B1 (fr) Compositions détergentes liquides pour lavage délicat
DE69413888T2 (de) Flüssiges Reinigungsmittel auf der Basis von starkschäumenden nichtionischen oberflächenaktiven Mitteln
US4599188A (en) Foaming surfactant compositions
US5514369A (en) Mild shampoo composition
EP0554991B1 (fr) Compositions détergentes
US5866529A (en) High foaming nonionic surfactant base liquid detergent comprising gelatin beads
EP0518925B1 (fr) Compositions de detergents de lavage de vaisselle liquides pour lavages delicats
US5480586A (en) Light duty liquid detergent compostion comprising a sulfosuccinamate-containing surfactant blend
US5565146A (en) Light duty liquid detergent compositions
WO1998036041A1 (fr) Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside
US5503779A (en) High foaming light duty liquid detergent
DE69414040T2 (de) Flüssiges Reinigungsmittel auf der Basis von starkschäumenden nichtionischen oberflächenaktiven Mitteln
WO1990002164A1 (fr) Compositions de detergents liquides pour lavages delicats
US5773406A (en) Foaming composition
CA2251376A1 (fr) Carboxylates d'alkyl polyglycoside ether
EP0387063A2 (fr) Compositions détergentes
US6248792B1 (en) Use of carboxylate alkyl polyglycoside surfactant to increase the foam of other anionic surfactants
KR20000010806A (ko) 특정의 폴리쿼터늄 성분과 조합된 당 계면활성제
EP1003605A1 (fr) Emploi de polyglycosides d'alkyle ameliorant la stabilisation des mousses des amphoacetates
CA1209010A (fr) Compositions moussantes tensio-actives
MXPA99007617A (en) Improved light-duty liquid performance of ether sulfate using alkyl polyglycoside
US6576603B2 (en) Process for making low viscosity ether sulfates
US5888960A (en) Surfactant composition
MXPA98000506A (en) Foam composition
JPH09302382A (ja) 液体洗浄剤組成物

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM GW HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: PA/a/1999/007617

Country of ref document: MX

WWE Wipo information: entry into national phase

Ref document number: 1998901706

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1998901706

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: JP

Ref document number: 1998535720

Format of ref document f/p: F

WWW Wipo information: withdrawn in national office

Ref document number: 1998901706

Country of ref document: EP