WO1998024559A1 - Thioesters utilises en tant que lubrifiants limites - Google Patents

Thioesters utilises en tant que lubrifiants limites Download PDF

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Publication number
WO1998024559A1
WO1998024559A1 PCT/US1997/021399 US9721399W WO9824559A1 WO 1998024559 A1 WO1998024559 A1 WO 1998024559A1 US 9721399 W US9721399 W US 9721399W WO 9824559 A1 WO9824559 A1 WO 9824559A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
weight
fiber
lubricant
textile
Prior art date
Application number
PCT/US1997/021399
Other languages
English (en)
Inventor
Elbert H. Mudge
Original Assignee
Henkel Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corporation filed Critical Henkel Corporation
Publication of WO1998024559A1 publication Critical patent/WO1998024559A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • This invention relates to a composition and process for decreasing fiber-
  • Finishing compositions are generally applied to textile fibers to improve
  • finish composition applied depend on a number of variables which include the
  • spin finishes are usually
  • a fiber tow or yarn with a solution or an emulsion comprising at least one
  • agent wetting agents, additives such as antioxidants, biocides, anti-corrosion
  • Finish compositions can also be applied to tow, yarn, or cut
  • the purpose of a fiber finish is to provide fiber to metal lubrication and
  • denier polypropylene staple fiber which is to be carded into a web and thermally
  • Another example involves a slit film or ribbon type yarn intended for
  • the present invention is directed to a textile fiber finish composition
  • R, and R 2 are each, independently, a C 8 -C 18 alkyl group, all weights
  • the present invention is also directed to a process for treating a textile
  • present invention are the lubricant component and the boundary lubricant
  • the lubricant component of the fiber finish may be selected from the
  • polyols such as glycerin
  • polyol esters such as
  • the lubricant component of this invention is emulsifiable and capable of
  • stable emulsion it is meant
  • composition onto the yarn surface is meant to include oil-in-water finishes
  • an antistatic agent to aid in controlling the
  • An emulsifier may be employed in the composition of the present
  • the emulsifier may comprise any suitable emulsifying
  • Typical emulsifiers include an unethoxylated ester such as sorbitan
  • an ethoxylated ester such as ethoxylated sorbitan monooleate
  • ethoxylated C 8 . 22 fatty acids such as the reaction product of ethylene oxide with
  • an ethoxylated alcohol such as ethoxylated C ⁇ -C ⁇ alcohol or combination
  • An alkali metal soap of a fatty acid such as potassium oleate may be
  • emulsifiers include an ethoxylated sorbitan monooleate (POE(5)) such as
  • An antistatic agent which may be employed generally comprises any one of
  • anionic, cationic, amphoteric or nonionic antistatic agent Suitable anionic, cationic, amphoteric or nonionic antistatic agent.
  • antistatic agents are generally sulfates or phosphates such as the phosphate
  • esters of alcohols or ethoxylated alcohols are typified
  • nonionics include the polyoxyalkylene derivatives.
  • the anionic and cationic materials tend to be more effective antistats.
  • the boundary lubricant additive used in the present invention is a
  • R ⁇ and R 2 are each, independently, a C 8 -C 18 alkyl group.
  • thioesters suitable for use as a boundary lubricant additive are examples of thioesters suitable for use as a boundary lubricant additive
  • the textile lubricant composition of the present invention include, but are not
  • thiodipropionate derivatives such as di-2-ethylhexyl thiodipropionate
  • a particularly preferred thioester for use in the present invention is di-isotridecyl
  • composition of the present invention examples thereof include, but are not
  • wetting agents include wetting agents, biocides, anti-corrosion agents, and pH control agents.
  • the textile fiber finish composition of the present invention may be applied to the textile fiber finish composition of the present invention.
  • olefins such as polyethylene and polypropylene, polybenzimidazole, polyesters
  • copolyesters thereof saran, spandex and vinyon.
  • the process involves applying from about 0.3 to about 2.0% OWF ("on the
  • textile fiber finish composition onto the fiber is
  • the fibers will be contacted with the fiber finish composition at
  • a percent actives concentration ranging from about 2 to about 20% actives
  • Frictional properties can be readily measured by applying known
  • the measurement is carried out by pulling a yarn around a circular
  • finish composition application finish composition concentration on the fiber
  • the fiber to fiber friction measurement is carried out in a similar way
  • Static friction is
  • Example 1 The lubricant composition of Example 1 containing a thioester
  • the lubricant composition may be applied onto the filament according to
  • the polymer is melted and extruded through
  • lubricant applied onto the filaments can be controlled by the concentration of
  • positive metering systems may be used which pump the lubricant composition to a ceramic slot which allows the lubricant composition to contact
  • composition to be applied onto a synthetic filament is also dependent on the end
  • the filament is the desired product of the filament yarn. If staple fiber is the desired product, the filament
  • bundles are combined into large tows, oriented by stretching, crimped, and cut
  • nonwoven webs In this instance, it is the "scroop" of the fibers which is
  • composition have a concentration in the range of from about 0.5 to about 1.0%
  • the filaments are also oriented but as discrete bundles containing a
  • the unoriented or undrawn yarn is wound on a package
  • Texturized yarns are also made as continuous filament yarns. Again,
  • texturized yarns can be made by texturizing a fully oriented yarn or by
  • Fiber to fiber friction is important

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Une composition d'apprêt pour fibres textiles contient: (a) entre environ 95 et environ 99 % en poids d'un constituant lubrifiant; et (b) entre environ 1 et environ 5 % en poids d'un additif de lubrifiant limite de formule (I): R1-OOCCH2CH2-S-CH2CH2COO-R2. Dans cette formule R1 et R2 représentent chacun, indépendamment un groupe alkyle C8-C18, tous les poids étant basés sur le poids de la composition.
PCT/US1997/021399 1996-12-05 1997-12-02 Thioesters utilises en tant que lubrifiants limites WO1998024559A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US76709596A 1996-12-05 1996-12-05
US08/767,095 1996-12-05

Publications (1)

Publication Number Publication Date
WO1998024559A1 true WO1998024559A1 (fr) 1998-06-11

Family

ID=25078463

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/021399 WO1998024559A1 (fr) 1996-12-05 1997-12-02 Thioesters utilises en tant que lubrifiants limites

Country Status (1)

Country Link
WO (1) WO1998024559A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001069323A2 (fr) * 2000-02-24 2001-09-20 Petro-Canada Composition antistatique et procede d'utilisation
WO2015186545A1 (fr) * 2014-06-06 2015-12-10 松本油脂製薬株式会社 Agent de traitement de fibre synthétique et on utilisation
JP7449005B2 (ja) 2022-06-16 2024-03-13 竹本油脂株式会社 合成繊維用処理剤、及び合成繊維

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5464546A (en) * 1994-06-16 1995-11-07 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US5478485A (en) * 1994-06-16 1995-12-26 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5464546A (en) * 1994-06-16 1995-11-07 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US5478485A (en) * 1994-06-16 1995-12-26 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001069323A2 (fr) * 2000-02-24 2001-09-20 Petro-Canada Composition antistatique et procede d'utilisation
WO2001069323A3 (fr) * 2000-02-24 2003-02-06 Petro Canada Inc Composition antistatique et procede d'utilisation
WO2015186545A1 (fr) * 2014-06-06 2015-12-10 松本油脂製薬株式会社 Agent de traitement de fibre synthétique et on utilisation
JPWO2015186545A1 (ja) * 2014-06-06 2017-04-20 松本油脂製薬株式会社 合成繊維用処理剤及びその利用
JP7449005B2 (ja) 2022-06-16 2024-03-13 竹本油脂株式会社 合成繊維用処理剤、及び合成繊維

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