WO1998020092A3 - Laundry detergent compositions comprising soil release polymer - Google Patents

Laundry detergent compositions comprising soil release polymer Download PDF

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Publication number
WO1998020092A3
WO1998020092A3 PCT/US1997/019899 US9719899W WO9820092A3 WO 1998020092 A3 WO1998020092 A3 WO 1998020092A3 US 9719899 W US9719899 W US 9719899W WO 9820092 A3 WO9820092 A3 WO 9820092A3
Authority
WO
WIPO (PCT)
Prior art keywords
surfactant
units
moles
sulfonate
soil release
Prior art date
Application number
PCT/US1997/019899
Other languages
French (fr)
Other versions
WO1998020092A2 (en
Inventor
Luisa Navarro De-Cerda
Ricardo Alfredo Prada-Silvy
Anju Deepali Massey-Brooker
Nour-Eddine Guedira
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble filed Critical Procter & Gamble
Priority to CA002270465A priority Critical patent/CA2270465A1/en
Priority to BR9712863-5A priority patent/BR9712863A/en
Publication of WO1998020092A2 publication Critical patent/WO1998020092A2/en
Publication of WO1998020092A3 publication Critical patent/WO1998020092A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The subject invention involves laundry detergent compositions, preferably in granular form, particularly useful for machine laundry operations. The compositions comprise: a) from about 6 % to about 18 % surfactant comprising 1) from about 5 % to about 10 % anionic surfactant selected from alkylbenzene sulfonate surfactant, alkyl sulfate surfactant and alkyl ethoxy ether sulfate surfactant; 2) from about 0.2 % to about 4 % hydroxyalkyl quaternary ammonium cationic surfactant; and 3) from 0.4 % to about 8 % nonionic surfactant selected from alkyl ethoxy alcohol surfactant, amine oxide surfactant, and polyhydroxy fatty acid amide surfactant; b) from about 0.05 to about 4 % polymeric soil release agent comprising: 1) from about 10 % to about 99.5 % esters comprising, per mole of said ester: i) from about 1 to about 2 moles of sulfonated polyethoxy/propoxy end-capping units; ii) from about 0.5 to about 66 moles of units selected from the group consisting of a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy-1,2-propyleneoxy units; and c) a mixture of a) or b) with poly(oxyethylene)oxy units; iii) from about 1.5 to about 40 moles of terephthaloyl units; and iv) from 0 to about 26 moles of 5-sulfoisophthaloyl units; 2) from about 0.5 % to about 20 % crystallization-reducing stabilizer selected from sulfonate-type hydrotrope, alkylbenzene sulfonate, paraffin sulfonate, and mixtures thereof; and c) from about 80 % to about 94 % other components.
PCT/US1997/019899 1996-11-01 1997-11-03 Laundry detergent compositions comprising soil release polymer WO1998020092A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA002270465A CA2270465A1 (en) 1996-11-01 1997-11-03 Laundry detergent compositions comprising soil release polymer
BR9712863-5A BR9712863A (en) 1996-11-01 1997-11-03 Detergent compositions for hand washing containing a combination of surfactants and dirt release polymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3075796P 1996-11-01 1996-11-01
US60/030,757 1996-11-01

Publications (2)

Publication Number Publication Date
WO1998020092A2 WO1998020092A2 (en) 1998-05-14
WO1998020092A3 true WO1998020092A3 (en) 1998-10-08

Family

ID=21855863

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/019899 WO1998020092A2 (en) 1996-11-01 1997-11-03 Laundry detergent compositions comprising soil release polymer

Country Status (5)

Country Link
CN (1) CN1113955C (en)
AR (1) AR010265A1 (en)
BR (1) BR9712863A (en)
CA (1) CA2270465A1 (en)
WO (1) WO1998020092A2 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1222606C (en) * 1998-08-07 2005-10-12 荷兰联合利华有限公司 Mild particulate laundry detergent compositions for washing textile fabrics by hand
EP1158040B1 (en) 2000-05-16 2005-11-23 Clariant International Ltd. Use of cationic compounds
EP2423180B1 (en) 2002-12-04 2016-07-06 Clariant International Ltd Quaternary ammonium composition
US20100080767A1 (en) * 2006-11-13 2010-04-01 Croda Uniqema, Inc. Compounds
EP2103678A1 (en) * 2008-03-18 2009-09-23 The Procter and Gamble Company Detergent composition comprising a co-polyester of dicarboxylic acids and diols
WO2010124823A1 (en) * 2009-04-28 2010-11-04 Clariant International Ltd Laundry detergent compositions
US8188027B2 (en) * 2009-07-20 2012-05-29 The Procter & Gamble Company Liquid fabric enhancer composition comprising a di-hydrocarbyl complex
WO2011120799A1 (en) 2010-04-01 2011-10-06 Unilever Plc Structuring detergent liquids with hydrogenated castor oil
EP2495300A1 (en) 2011-03-04 2012-09-05 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Structuring detergent liquids with hydrogenated castor oil
ES2421162T3 (en) 2011-04-04 2013-08-29 Unilever Nv Fabric washing procedure
WO2013139702A1 (en) 2012-03-21 2013-09-26 Unilever Plc Laundry detergent particles
WO2015054564A1 (en) * 2013-10-10 2015-04-16 Childress Rodney Cleaning compositions and methods of use thereof
BR112017019942A2 (en) 2015-04-02 2018-06-12 Unilever Nv liquid laundry detergent composition and polymer release for dirt release
WO2017133879A1 (en) 2016-02-04 2017-08-10 Unilever Plc Detergent liquid
CN109312259A (en) 2016-06-09 2019-02-05 荷兰联合利华有限公司 Laundry product
WO2017211700A1 (en) 2016-06-09 2017-12-14 Unilever Plc Laundry products
WO2018127390A1 (en) 2017-01-06 2018-07-12 Unilever N.V. Stain removing composition
WO2018224379A1 (en) 2017-06-09 2018-12-13 Unilever Plc Laundry liquid dispensing system
WO2019038186A1 (en) 2017-08-24 2019-02-28 Unilever Plc Improvements relating to fabric cleaning
WO2019038187A1 (en) 2017-08-24 2019-02-28 Unilever Plc Improvements relating to fabric cleaning
BR112020006342A2 (en) 2017-09-29 2020-09-24 Unilever N.V. combination of reservoirs and device
WO2019068473A1 (en) 2017-10-05 2019-04-11 Unilever Plc Laundry products

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0199403A2 (en) * 1985-04-15 1986-10-29 The Procter & Gamble Company Stable liquid detergent compositions
EP0311342A2 (en) * 1987-10-05 1989-04-12 The Procter & Gamble Company Sulfoaroyl end-capped ester oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
EP0456569A1 (en) * 1990-05-08 1991-11-13 Colgate-Palmolive Company Liquid softening and anti-static nonionic detergent composition with soil release promoting pet-poet copolymer
WO1992006152A1 (en) * 1990-09-28 1992-04-16 The Procter & Gamble Company Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions
WO1995002028A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
DE4440956A1 (en) * 1994-11-17 1996-05-23 Henkel Kgaa Dirt-repellent detergent with a specific combination of surfactants

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4721580A (en) * 1987-01-07 1988-01-26 The Procter & Gamble Company Anionic end-capped oligomeric esters as soil release agents in detergent compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0199403A2 (en) * 1985-04-15 1986-10-29 The Procter & Gamble Company Stable liquid detergent compositions
EP0311342A2 (en) * 1987-10-05 1989-04-12 The Procter & Gamble Company Sulfoaroyl end-capped ester oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
EP0456569A1 (en) * 1990-05-08 1991-11-13 Colgate-Palmolive Company Liquid softening and anti-static nonionic detergent composition with soil release promoting pet-poet copolymer
WO1992006152A1 (en) * 1990-09-28 1992-04-16 The Procter & Gamble Company Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions
WO1995002028A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
DE4440956A1 (en) * 1994-11-17 1996-05-23 Henkel Kgaa Dirt-repellent detergent with a specific combination of surfactants

Also Published As

Publication number Publication date
BR9712863A (en) 1999-12-07
CN1113955C (en) 2003-07-09
WO1998020092A2 (en) 1998-05-14
CN1242796A (en) 2000-01-26
CA2270465A1 (en) 1998-05-14
AR010265A1 (en) 2000-06-07

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