WO1998016613A1 - A method of washing fabrics using a detergent composition comprising a terpolymer - Google Patents
A method of washing fabrics using a detergent composition comprising a terpolymer Download PDFInfo
- Publication number
- WO1998016613A1 WO1998016613A1 PCT/US1996/016652 US9616652W WO9816613A1 WO 1998016613 A1 WO1998016613 A1 WO 1998016613A1 US 9616652 W US9616652 W US 9616652W WO 9816613 A1 WO9816613 A1 WO 9816613A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- terpolymer
- compositions
- acid
- surfactant
- monomeric unit
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 188
- 239000003599 detergent Substances 0.000 title claims abstract description 100
- 239000004744 fabric Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 42
- 229920001897 terpolymer Polymers 0.000 title claims abstract description 42
- 238000005406 washing Methods 0.000 title claims abstract description 28
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000002253 acid Substances 0.000 claims abstract description 22
- 239000000178 monomer Substances 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 6
- 229920001567 vinyl ester resin Polymers 0.000 claims description 6
- 150000007942 carboxylates Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 150000003926 acrylamides Chemical class 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 2
- 239000002563 ionic surfactant Substances 0.000 claims 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims 2
- -1 Fe(OH)3) Chemical class 0.000 description 56
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- 239000000463 material Substances 0.000 description 27
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- 229920001223 polyethylene glycol Polymers 0.000 description 24
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 18
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 16
- 235000019421 lipase Nutrition 0.000 description 16
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- 239000011734 sodium Substances 0.000 description 13
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
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- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 10
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 108010084185 Cellulases Proteins 0.000 description 7
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- 229920002125 Sokalan® Polymers 0.000 description 7
- 238000004851 dishwashing Methods 0.000 description 7
- 230000001590 oxidative effect Effects 0.000 description 7
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- 239000003381 stabilizer Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
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- 239000002245 particle Substances 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
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- 235000019832 sodium triphosphate Nutrition 0.000 description 6
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 6
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- 150000003863 ammonium salts Chemical class 0.000 description 5
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- 229940106157 cellulase Drugs 0.000 description 5
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
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- 150000001298 alcohols Chemical class 0.000 description 4
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- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- MGNVWUDMMXZUDI-UHFFFAOYSA-N propane-1,3-disulfonic acid Chemical class OS(=O)(=O)CCCS(O)(=O)=O MGNVWUDMMXZUDI-UHFFFAOYSA-N 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical class CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- FQUAWOQWQIVZLB-UHFFFAOYSA-M sodium;2-(2,3-dihydroxypropoxy)ethanesulfonate Chemical compound [Na+].OCC(O)COCCS([O-])(=O)=O FQUAWOQWQIVZLB-UHFFFAOYSA-M 0.000 description 1
- SZINDZNWFLBXKV-UHFFFAOYSA-M sodium;2-(2-hydroxyethoxy)ethanesulfonate Chemical compound [Na+].OCCOCCS([O-])(=O)=O SZINDZNWFLBXKV-UHFFFAOYSA-M 0.000 description 1
- XRQFJUYYMJOWCT-UHFFFAOYSA-M sodium;2-[2-(2-hydroxyethoxy)ethoxy]ethanesulfonate Chemical compound [Na+].OCCOCCOCCS([O-])(=O)=O XRQFJUYYMJOWCT-UHFFFAOYSA-M 0.000 description 1
- CVXNPALMJQXREE-UHFFFAOYSA-M sodium;2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethanesulfonate Chemical compound [Na+].OCCOCCOCCOCCS([O-])(=O)=O CVXNPALMJQXREE-UHFFFAOYSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- KQHKITXZJDOIOD-UHFFFAOYSA-M sodium;3-sulfobenzoate Chemical compound [Na+].OS(=O)(=O)C1=CC=CC(C([O-])=O)=C1 KQHKITXZJDOIOD-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical group NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical group C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C11D2111/12—
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002268531A CA2268531A1 (en) | 1996-10-17 | 1996-10-17 | A method of washing fabrics using a detergent composition comprising a terpolymer |
JP9536158A JPH11500182A (en) | 1996-10-17 | 1996-10-17 | Method for washing a fabric using a detergent composition comprising a terpolymer |
PCT/US1996/016652 WO1998016613A1 (en) | 1996-10-17 | 1996-10-17 | A method of washing fabrics using a detergent composition comprising a terpolymer |
ARP970104807A AR013847A1 (en) | 1996-10-17 | 1997-10-17 | METHOD FOR WASHING FABRICS USING A DETERGENT COMPOSITION CONTAINING A TERPOLIMERO |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1996/016652 WO1998016613A1 (en) | 1996-10-17 | 1996-10-17 | A method of washing fabrics using a detergent composition comprising a terpolymer |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998016613A1 true WO1998016613A1 (en) | 1998-04-23 |
Family
ID=22255980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/016652 WO1998016613A1 (en) | 1996-10-17 | 1996-10-17 | A method of washing fabrics using a detergent composition comprising a terpolymer |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPH11500182A (en) |
AR (1) | AR013847A1 (en) |
CA (1) | CA2268531A1 (en) |
WO (1) | WO1998016613A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003006593A2 (en) * | 2001-07-07 | 2003-01-23 | Henkel Kommanditgesellschaft Auf Aktien | Non-aqueous '3 in 1' dishwasher products |
EP1284283A1 (en) * | 2001-08-13 | 2003-02-19 | Unilever N.V. | Cleaning and rinsing of textile fabrics |
US7153816B2 (en) | 2001-08-17 | 2006-12-26 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Dishwasher detergent with improved protection against glass corrosion |
WO2007020949A1 (en) * | 2005-08-15 | 2007-02-22 | Kao Corporation | Process for washing and powder detergent composition |
DE10133136B4 (en) * | 2001-07-07 | 2007-07-12 | Henkel Kgaa | Non-aqueous "3in1" -Geschirrspülmittel |
US9127236B2 (en) | 2013-10-09 | 2015-09-08 | Ecolab Usa Inc. | Alkaline detergent composition containing a carboxylic acid terpolymer for hard water scale control |
US9127235B2 (en) | 2013-10-09 | 2015-09-08 | Ecolab Usa Inc. | Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control |
US9487738B2 (en) | 2013-10-09 | 2016-11-08 | Ecolab Usa Inc. | Solidification matrix comprising a carboxylic acid terpolymer |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3643334A1 (en) * | 1985-12-19 | 1987-07-09 | Lion Corp | Addition for a granular detergent and cleaner |
US4711725A (en) * | 1985-06-26 | 1987-12-08 | Rohm And Haas Co. | Method of stabilizing aqueous systems |
EP0584709A2 (en) * | 1992-08-22 | 1994-03-02 | Hoechst Aktiengesellschaft | Use of water soluble copolymers based on acrylamidoalkylenesulfonic acids as detergent additives |
DE4303448A1 (en) * | 1993-02-05 | 1994-08-11 | Henkel Kgaa | Builder for detergents or cleaners |
DE4343993A1 (en) * | 1993-12-22 | 1995-06-29 | Stockhausen Chem Fab Gmbh | Graft copolymers of unsaturated monomers and polyhydroxy compounds, process for their preparation and their use |
EP0727448A1 (en) * | 1995-02-17 | 1996-08-21 | National Starch and Chemical Investment Holding Corporation | Water soluble polymers containing allyloxybenzenesulfonic acid monomer and methallyl sulfonic acid monomer |
-
1996
- 1996-10-17 WO PCT/US1996/016652 patent/WO1998016613A1/en active Application Filing
- 1996-10-17 CA CA002268531A patent/CA2268531A1/en not_active Abandoned
- 1996-10-17 JP JP9536158A patent/JPH11500182A/en active Pending
-
1997
- 1997-10-17 AR ARP970104807A patent/AR013847A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4711725A (en) * | 1985-06-26 | 1987-12-08 | Rohm And Haas Co. | Method of stabilizing aqueous systems |
DE3643334A1 (en) * | 1985-12-19 | 1987-07-09 | Lion Corp | Addition for a granular detergent and cleaner |
EP0584709A2 (en) * | 1992-08-22 | 1994-03-02 | Hoechst Aktiengesellschaft | Use of water soluble copolymers based on acrylamidoalkylenesulfonic acids as detergent additives |
DE4303448A1 (en) * | 1993-02-05 | 1994-08-11 | Henkel Kgaa | Builder for detergents or cleaners |
DE4343993A1 (en) * | 1993-12-22 | 1995-06-29 | Stockhausen Chem Fab Gmbh | Graft copolymers of unsaturated monomers and polyhydroxy compounds, process for their preparation and their use |
EP0727448A1 (en) * | 1995-02-17 | 1996-08-21 | National Starch and Chemical Investment Holding Corporation | Water soluble polymers containing allyloxybenzenesulfonic acid monomer and methallyl sulfonic acid monomer |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7192911B2 (en) | 2001-07-07 | 2007-03-20 | Henkel Kgaa | Nonaqueous 3 in 1 dishwasher products |
WO2003006593A3 (en) * | 2001-07-07 | 2003-11-20 | Henkel Kgaa | Non-aqueous '3 in 1' dishwasher products |
WO2003006593A2 (en) * | 2001-07-07 | 2003-01-23 | Henkel Kommanditgesellschaft Auf Aktien | Non-aqueous '3 in 1' dishwasher products |
DE10133136B4 (en) * | 2001-07-07 | 2007-07-12 | Henkel Kgaa | Non-aqueous "3in1" -Geschirrspülmittel |
EP1284283A1 (en) * | 2001-08-13 | 2003-02-19 | Unilever N.V. | Cleaning and rinsing of textile fabrics |
US7153816B2 (en) | 2001-08-17 | 2006-12-26 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Dishwasher detergent with improved protection against glass corrosion |
WO2007020949A1 (en) * | 2005-08-15 | 2007-02-22 | Kao Corporation | Process for washing and powder detergent composition |
US9127236B2 (en) | 2013-10-09 | 2015-09-08 | Ecolab Usa Inc. | Alkaline detergent composition containing a carboxylic acid terpolymer for hard water scale control |
US9127235B2 (en) | 2013-10-09 | 2015-09-08 | Ecolab Usa Inc. | Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control |
US9487738B2 (en) | 2013-10-09 | 2016-11-08 | Ecolab Usa Inc. | Solidification matrix comprising a carboxylic acid terpolymer |
US9840683B2 (en) | 2013-10-09 | 2017-12-12 | Basf Se | Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control |
US10364409B2 (en) | 2013-10-09 | 2019-07-30 | Ecolab Usa Inc. | Solidification matrix comprising a carboxylic acid terpolymer |
US10858613B2 (en) | 2013-10-09 | 2020-12-08 | Ecolab Usa Inc. | Alkaline detergent composition containing a carboxylic acid terpolymer for hard water scale control |
Also Published As
Publication number | Publication date |
---|---|
JPH11500182A (en) | 1999-01-06 |
AR013847A1 (en) | 2001-01-31 |
CA2268531A1 (en) | 1998-04-23 |
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