WO1998012003A1 - Treatment of waste - Google Patents

Treatment of waste Download PDF

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Publication number
WO1998012003A1
WO1998012003A1 PCT/GB1997/002535 GB9702535W WO9812003A1 WO 1998012003 A1 WO1998012003 A1 WO 1998012003A1 GB 9702535 W GB9702535 W GB 9702535W WO 9812003 A1 WO9812003 A1 WO 9812003A1
Authority
WO
WIPO (PCT)
Prior art keywords
waste
temperature
wet oxidation
minus
water
Prior art date
Application number
PCT/GB1997/002535
Other languages
French (fr)
Inventor
Ian Geoffrey Ferguson
Original Assignee
The Boc Group Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Boc Group Plc filed Critical The Boc Group Plc
Priority to EP97919170A priority Critical patent/EP0927084A1/en
Priority to AU43103/97A priority patent/AU4310397A/en
Publication of WO1998012003A1 publication Critical patent/WO1998012003A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/06—Treatment of sludge; Devices therefor by oxidation
    • C02F11/08—Wet air oxidation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L11/00—Methods specially adapted for refuse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/0075—Disposal of medical waste
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing

Definitions

  • This invention relates to the treatment of waste and, more particularly to the treatment and/or sterilisation of organic, medical, animal/human tissue and low level radioactive wastes.
  • waste material are continually being generated, for example in the medical industry and in hospitals, which requires disposal by treatment, including incineration or vitrification involving the burning of such waste, or by storage in landfill sites with or without such treatment.
  • a method of treating waste material which comprises cooling the material to a temperature below 0°C in the presence of water, fragmenting the cooled waste and subjecting the fragmented waste to a wet oxidation process.
  • the waste material may already be in an aqueus environmental in its original form but generally sufficient water or liquid waste should be added to the material, for example in a mixer or blender, prior to the cooling stage to dampen or to wet any dry components of the waste; alternatively a fine water spray may be used.
  • the dampening/wetting step is essential as the water droplets are absorbed in to at least certain components of the waste, for example cloth, linen, gauze and other fabrics and fibrous substances, and therefore can ease the fragmentation step by rigidifying fibres not normally rigidified by simple cooling of the material.
  • the overall temperature of the waste material is reduced during the cooling step to at least minus 20°C, and more preferably to at least minus 30°C.
  • the temperature is reduced to between minus 40°C and minus 100°C.
  • the waste material comprises or contains plastics, for example nylon, PTFE, polyethylene, etc temperatures as low as minus 120°C or lower will generally be required.
  • plastic material is separated from other waste prior to the cooling step and thereafter separately fragmented, for example at ambient temperatures.
  • a liquid cryogen such as liquid nitrogen or liquid carbon dioxide is employed in heat exchange apparatus for example a rotary drum or freezing tunnel or by direct injection in to, or fine spray on to, the waste material.
  • the fragmentation step can be effected by any suitable types of equipment, for example a heavy duty hammer, vertical disintegrator or a suitable grinding device.
  • the fragmentation step is a multi-stage (two or more) process in which the waste is first broken in to coarse fragments and then fragmented in to finer particles, for example within the ranges of 0.1 to 1 mm in the subsequent stage or stages.
  • the waste material particles from the first fragmentation process is from 3 to 10 mm, for example of the order of 6 mm, although longer stands of fibrous substances may also be present.
  • the finer particles are then achieved in the subsequent stage(s).
  • cryogen may be used in the fragmentation stage(s) as appropriate to retain the desired low temperature.
  • Cryogen for example liquid nitrogen, consumption will generally be determined by the desired temperature and the specific grinding energy as expressed, for example, by KW/kg of material being processed.
  • the fragmented waste should be mixed with water (or other liquid waste) and subjected to wet oxidation, preferably at an elevated temperature or elevated pressure (or both), to effect oxidation of the waste, primarily to carbon-dioxide and water and a non-toxic end product.
  • a temperature of up to 320°C is preferred. Most preferably the temperature is from 200 to 300°C, for example from 240 to 290°C.
  • a pressure of up to 150 bar is preferred. Most preferably, the pressure is from 30 to 170 bar, for example from 50 to 160 bar.
  • An oxygen-containing gas is necessary to support the wet oxidation step.
  • the step is conducted with a gas containing at least 80%, more preferably 90%, oxygen.
  • the gas is substantially pure oxygen.
  • the presence of a high percentage of oxygen reduces the volume of inert gases resulting from the wet oxidation step and therefore tends to minimise heat losses from the oxidation step and emissions of unreacted contaminants to the atmosphere.
  • the waste may be rendered acidic through the addition of, for example, sulphuric acid.
  • the wet oxidation stage can be or can be followed by a supercritical water oxidation in order to break down more resistant, for example refractory, substances.
  • Supercritical water oxidation employs the high temperatures required for supercritical water to increase the rate of oxidation of the organic waste. As the water is heated above its critical temperature of 374°C and critical pressure of about 22.1 MPa, its density drops considerably - typical operating densities are 0.15 to 0.2 g/cm 3 - and the dielectric constant substantially decreases also. With these changes to the physical properties of the waste, organic waste is highly soluble but ionic waste is not. The organic waste is dissolved in an oxygen-containing environment and oxidation occurs rapidly in the high temperatures employed.
  • the basic waste material may be separated to remove metal or plastic or other potentially undesirable substances prior to the first cooling step.
  • additions of organic matter may be made to the waste prior to the wet oxidation step in order to improve the organic to inorganic material ratio to be fed in to the wet oxidation system for the purpose of an additional waste stream process and/or to improve and potentially enhance the performance of the wet oxidation system.
  • organic matter for example sewage sludge
  • the wet oxidation step may be carried out using an oxygen/ozone injection if required.
  • soiled waste material comprising primarily hospital waste including cottons, gauzes, bandages and other substances was subjected to a moisturising step by spraying with water and thereafter to a cooling step in a rotary drum in to which a spray of liquid nitrogen cryogen was injected to reduce the temperature of the wetted waste of the order of minus 40°C. cryogen was injected to reduce the temperature of the wetted waste of the order of minus 40°C.
  • the cooled waste was then subjected to a first fragmentation stage in a vertical disintegration apparatus employing a heavy duty hammer to reduce the waste to particles of about 6 mm in size but including some longer fibres.
  • an industrial grinding machine was employed to reduce the waste down to a particle size of the order of 0.5 mm (and some longer fibres).
  • the waste was then placed in a wet oxidation system in which, in a semi-continuous process in which the waste was acidified and fed through a chamber at a temperature of 275 °C and at a pressure of 100 bar, the waste was oxidised primarily to carbon dioxide and water leaving a sterile waste as the end product which could be safely disposed.
  • the wet oxidation system may advantageously include a tall cylindrical chamber in which the waste is placed with an oxygen/ozone injection towards the bottom of the chamber so that an increased pressure is achieved from the weight of the waste above the oxidation zone of the chamber. Means may also be employed continually to remove oxidised material from the base of the chamber at a rate corresponding to the rate of production of oxidation products therein.

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A method of treating waste material which comprises cooling the material to a temperature below 0 °C in the presence of water, fragmenting the cooled waste and subjecting the fragmental waste to a wet oxidation process.

Description

TREATMENT OF WASTE
This invention relates to the treatment of waste and, more particularly to the treatment and/or sterilisation of organic, medical, animal/human tissue and low level radioactive wastes.
Large quantities of waste material are continually being generated, for example in the medical industry and in hospitals, which requires disposal by treatment, including incineration or vitrification involving the burning of such waste, or by storage in landfill sites with or without such treatment.
None of the presently known methods for the treatment of waste is particularly satisfactory on environmental and other grounds. With increasing demands to meet more rigid environmentally acceptable targets, disposal of untreated waste, or even waste treated by known methods, is quite properly becoming increasingly difficult and therefore more expensive to achieve.
There is therefore a clear need for a new method by which a more effective treatment of such material can be effected.
In accordance with the invention, there is provided a method of treating waste material which comprises cooling the material to a temperature below 0°C in the presence of water, fragmenting the cooled waste and subjecting the fragmented waste to a wet oxidation process.
The waste material may already be in an aqueus environmental in its original form but generally sufficient water or liquid waste should be added to the material, for example in a mixer or blender, prior to the cooling stage to dampen or to wet any dry components of the waste; alternatively a fine water spray may be used. The dampening/wetting step is essential as the water droplets are absorbed in to at least certain components of the waste, for example cloth, linen, gauze and other fabrics and fibrous substances, and therefore can ease the fragmentation step by rigidifying fibres not normally rigidified by simple cooling of the material.
Preferably the overall temperature of the waste material is reduced during the cooling step to at least minus 20°C, and more preferably to at least minus 30°C.
Advantageously the temperature is reduced to between minus 40°C and minus 100°C.
If in particular the waste material comprises or contains plastics, for example nylon, PTFE, polyethylene, etc temperatures as low as minus 120°C or lower will generally be required.
Although such temperatures may be employed, in alternative embodiments of the invention plastic material is separated from other waste prior to the cooling step and thereafter separately fragmented, for example at ambient temperatures.
Any types of cooling process and/or apparatus can be employed to good effect. Preferably a liquid cryogen such as liquid nitrogen or liquid carbon dioxide is employed in heat exchange apparatus for example a rotary drum or freezing tunnel or by direct injection in to, or fine spray on to, the waste material.
The fragmentation step can be effected by any suitable types of equipment, for example a heavy duty hammer, vertical disintegrator or a suitable grinding device. Preferably the fragmentation step is a multi-stage (two or more) process in which the waste is first broken in to coarse fragments and then fragmented in to finer particles, for example within the ranges of 0.1 to 1 mm in the subsequent stage or stages.
Ideally the waste material particles from the first fragmentation process is from 3 to 10 mm, for example of the order of 6 mm, although longer stands of fibrous substances may also be present. The finer particles are then achieved in the subsequent stage(s).
A cryogen may be used in the fragmentation stage(s) as appropriate to retain the desired low temperature. Cryogen, for example liquid nitrogen, consumption will generally be determined by the desired temperature and the specific grinding energy as expressed, for example, by KW/kg of material being processed.
In the wet oxidation stage, the fragmented waste should be mixed with water (or other liquid waste) and subjected to wet oxidation, preferably at an elevated temperature or elevated pressure (or both), to effect oxidation of the waste, primarily to carbon-dioxide and water and a non-toxic end product.
A temperature of up to 320°C is preferred. Most preferably the temperature is from 200 to 300°C, for example from 240 to 290°C.
A pressure of up to 150 bar is preferred. Most preferably, the pressure is from 30 to 170 bar, for example from 50 to 160 bar.
An oxygen-containing gas is necessary to support the wet oxidation step. Presumably the step is conducted with a gas containing at least 80%, more preferably 90%, oxygen. Advantageously the gas is substantially pure oxygen. Generally, the presence of a high percentage of oxygen reduces the volume of inert gases resulting from the wet oxidation step and therefore tends to minimise heat losses from the oxidation step and emissions of unreacted contaminants to the atmosphere.
In advanced wet oxidation processes, certain catalysts may be employed and, separately or simultaneously, the waste may be rendered acidic through the addition of, for example, sulphuric acid. For certain wastes, for example those containing medications or low level radioactive substances, the wet oxidation stage can be or can be followed by a supercritical water oxidation in order to break down more resistant, for example refractory, substances. Supercritical water oxidation employs the high temperatures required for supercritical water to increase the rate of oxidation of the organic waste. As the water is heated above its critical temperature of 374°C and critical pressure of about 22.1 MPa, its density drops considerably - typical operating densities are 0.15 to 0.2 g/cm3 - and the dielectric constant substantially decreases also. With these changes to the physical properties of the waste, organic waste is highly soluble but ionic waste is not. The organic waste is dissolved in an oxygen-containing environment and oxidation occurs rapidly in the high temperatures employed.
If necessary, the basic waste material may be separated to remove metal or plastic or other potentially undesirable substances prior to the first cooling step.
Again if necessary, additions of organic matter, for example sewage sludge, may be made to the waste prior to the wet oxidation step in order to improve the organic to inorganic material ratio to be fed in to the wet oxidation system for the purpose of an additional waste stream process and/or to improve and potentially enhance the performance of the wet oxidation system.
The wet oxidation step may be carried out using an oxygen/ozone injection if required.
As an example of the carrying out of the method of the invention, soiled waste material comprising primarily hospital waste including cottons, gauzes, bandages and other substances was subjected to a moisturising step by spraying with water and thereafter to a cooling step in a rotary drum in to which a spray of liquid nitrogen cryogen was injected to reduce the temperature of the wetted waste of the order of minus 40°C. cryogen was injected to reduce the temperature of the wetted waste of the order of minus 40°C.
The cooled waste was then subjected to a first fragmentation stage in a vertical disintegration apparatus employing a heavy duty hammer to reduce the waste to particles of about 6 mm in size but including some longer fibres.
In a second fragmentation stage, an industrial grinding machine was employed to reduce the waste down to a particle size of the order of 0.5 mm (and some longer fibres).
The waste was then placed in a wet oxidation system in which, in a semi-continuous process in which the waste was acidified and fed through a chamber at a temperature of 275 °C and at a pressure of 100 bar, the waste was oxidised primarily to carbon dioxide and water leaving a sterile waste as the end product which could be safely disposed.
The wet oxidation system may advantageously include a tall cylindrical chamber in which the waste is placed with an oxygen/ozone injection towards the bottom of the chamber so that an increased pressure is achieved from the weight of the waste above the oxidation zone of the chamber. Means may also be employed continually to remove oxidised material from the base of the chamber at a rate corresponding to the rate of production of oxidation products therein.

Claims

1. A method of treating waste material which comprises cooling the material to a temperature below 0°C in the presence of water, fragmenting the cooled waste and subjecting the fragmental waste to a wet oxidation process.
2. A method according to Claim 1 in which the material is cooled to a temperature of minus 20°C or lower.
3. A method according to Claim 1 or Claim 2 in which the material is cooled to a temperature of minus 30° or lower.
4. A method according to any preceding claim in which the material is cooled to a temperature of between minus 40°C and minus 100°C.
5. A method according to any preceding claim in which the fragmentation step is a multi-stage process.
6. A method according to Claim 5 in which the particles form the first fragmentation process are from 3 to 10 mm.
7 A method according to Claim 5 or Claim 6 in which the particles for a subsequent fragmentation process are from 0.1 to 1 mm.
8. A method according to any preceding claim in which a temperature of up to 320°C is employed: the wet oxidation step.
9. A method according to any preceding claim in which a pressure of up to 180 bar is employed in the wet oxidation step.
10. A method according to any preceding claim in which the wet oxidation step is a superintical water oxidation process.
PCT/GB1997/002535 1996-09-19 1997-09-19 Treatment of waste WO1998012003A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP97919170A EP0927084A1 (en) 1996-09-19 1997-09-19 Treatment of waste
AU43103/97A AU4310397A (en) 1996-09-19 1997-09-19 Treatment of waste

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9619523.5A GB9619523D0 (en) 1996-09-19 1996-09-19 Ferguson cryonator/cryotory
GB9619523.5 1996-09-19

Publications (1)

Publication Number Publication Date
WO1998012003A1 true WO1998012003A1 (en) 1998-03-26

Family

ID=10800138

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1997/002535 WO1998012003A1 (en) 1996-09-19 1997-09-19 Treatment of waste

Country Status (4)

Country Link
EP (1) EP0927084A1 (en)
AU (1) AU4310397A (en)
GB (1) GB9619523D0 (en)
WO (1) WO1998012003A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001064587A2 (en) * 2000-03-03 2001-09-07 Micromining Technologies Int'l. Inc. Method and unit for achieving highly effective oxidation treatments
WO2003017288A1 (en) * 2001-08-17 2003-02-27 Framatome Anp Gmbh Method for treating radioactive waste and system for implementing the method

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1507142A (en) * 1974-04-10 1978-04-12 Boc International Ltd Treatment of waste material
US4338199A (en) * 1980-05-08 1982-07-06 Modar, Inc. Processing methods for the oxidation of organics in supercritical water
US4349465A (en) * 1979-04-21 1982-09-14 Kewa Kernbrennstoff-Wiederaufarbeitungs-Gesellschaft Mbh Process for the treatment of combustible, solid radioactive wastes
JPS61141947A (en) * 1984-12-14 1986-06-28 三菱重工業株式会社 Method of micronizing used ion exchange resin
US4686068A (en) * 1984-07-10 1987-08-11 Toyo Engineering Corporation Method of batchwise treating radioactive organic wastes
US4770783A (en) * 1986-01-15 1988-09-13 Aktiebolaget Asea-Atom Method of processing waste from a nuclear power plant, said waste comprising ion-exchange resin containing radioactive metals
EP0454513A2 (en) * 1990-03-23 1991-10-30 Framatome Process and furnace for treating wastes which can be incinerated

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1507142A (en) * 1974-04-10 1978-04-12 Boc International Ltd Treatment of waste material
US4349465A (en) * 1979-04-21 1982-09-14 Kewa Kernbrennstoff-Wiederaufarbeitungs-Gesellschaft Mbh Process for the treatment of combustible, solid radioactive wastes
US4338199A (en) * 1980-05-08 1982-07-06 Modar, Inc. Processing methods for the oxidation of organics in supercritical water
US4338199B1 (en) * 1980-05-08 1988-11-15
US4686068A (en) * 1984-07-10 1987-08-11 Toyo Engineering Corporation Method of batchwise treating radioactive organic wastes
JPS61141947A (en) * 1984-12-14 1986-06-28 三菱重工業株式会社 Method of micronizing used ion exchange resin
US4770783A (en) * 1986-01-15 1988-09-13 Aktiebolaget Asea-Atom Method of processing waste from a nuclear power plant, said waste comprising ion-exchange resin containing radioactive metals
EP0454513A2 (en) * 1990-03-23 1991-10-30 Framatome Process and furnace for treating wastes which can be incinerated

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8632, Derwent World Patents Index; Class J01, AN 86-208999, XP002050621 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001064587A2 (en) * 2000-03-03 2001-09-07 Micromining Technologies Int'l. Inc. Method and unit for achieving highly effective oxidation treatments
WO2001064587A3 (en) * 2000-03-03 2001-12-13 Micromining Technologies Int L Method and unit for achieving highly effective oxidation treatments
WO2003017288A1 (en) * 2001-08-17 2003-02-27 Framatome Anp Gmbh Method for treating radioactive waste and system for implementing the method

Also Published As

Publication number Publication date
AU4310397A (en) 1998-04-14
EP0927084A1 (en) 1999-07-07
GB9619523D0 (en) 1996-10-30

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