WO1997045335A1 - Systeme et procede d'emballage de vrac retardant l'agglomeration de composes chimiques organiques ou non organiques - Google Patents

Systeme et procede d'emballage de vrac retardant l'agglomeration de composes chimiques organiques ou non organiques Download PDF

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Publication number
WO1997045335A1
WO1997045335A1 PCT/US1997/008669 US9708669W WO9745335A1 WO 1997045335 A1 WO1997045335 A1 WO 1997045335A1 US 9708669 W US9708669 W US 9708669W WO 9745335 A1 WO9745335 A1 WO 9745335A1
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WIPO (PCT)
Prior art keywords
compound
desiccant
bag
packaging system
receptacle
Prior art date
Application number
PCT/US1997/008669
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English (en)
Inventor
Philip H. Merrell
Original Assignee
Mallinckrodt Chemical, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mallinckrodt Chemical, Inc. filed Critical Mallinckrodt Chemical, Inc.
Priority to AU30757/97A priority Critical patent/AU3075797A/en
Publication of WO1997045335A1 publication Critical patent/WO1997045335A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
    • B65D81/268—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package

Definitions

  • This invention relates to the packaging of bulk quantities of powdered, crystalline or granular organic and inorganic compounds which cake, and in particular a packaging system and method which substantially reduces or eliminates caking of the compounds to maintain the compounds in a substantially free flowing or scoopable state for an extended period of time.
  • powdered or crystalline compounds such as NaCl, KI, KNOIT or other organic or inorganic cakable compounds
  • the compound was normally placed inside a fiberboard drum having a polyethylene liner. The drum was then covered with a fiberboard lid. The compound, when so packaged, invariably cakes, even if measures are taken to prevent or retard caking.
  • the compound can cake so severely that it becomes rock solid and must be beaten or crushed before it can be used. This has been especially true of certain salts and other organic and inorganic compounds. Companies spend hundreds of thousands of dollars annually to beat or crush caked compounds so packaged, so that the compounds can be made flowable, or at least scoopable. This severe caking occurs even though desiccant is placed in the drum. Crushing of caked compounds must, of course, be carried out under controlled circumstances. Procedures must be followed to prevent cross-contamination of compounds and to prevent other impurities from contaminating the compound. This is especially true of drug grade chemicals, the handling of which is governed by the USP. For USP listed chemicals, the chemicals must be processed in accordance with the cGMP (current good manufacturing procedures).
  • the caking of chemical compounds has long plagued the industry. Many attempts have been made to alleviate the problem. However, no one has found an acceptable solution. For example in some applications, the compound is heated to 400-500°C. to dry the compound thoroughly before packaging. However, when the moisture leaves the compound in the course of this prior method, it may alter the physical shape and size of the compound in a detrimental manner.
  • Another method includes adding anti-caking agents to the compound to be protected. These anti-caking agents coat the particles of the compound to protect them from moisture. However, a specific anti-caking agent may not be acceptable for a wide variety of compounds. The anti-caking agent therefore must be carefully chosen. Further, the use of anti-caking agents is not acceptable in many circumstances.
  • anti-caking agents cannot have anti-caking agents mixed with them.
  • the anti-caking agents can detrimentally alter the efficacy of the resulting medicine, or the process for producing the medicine.
  • the use of anti-caking agents is also costly.
  • the anti-caking agent cannot simply be added to the compound to be protected. It must be fully blended into the compound to be protected.
  • current research in the prevention or reduction of caking appears to be directed to the development of further anti-caking agents.
  • the current invention provides an inexpensive and practical solution which substantially reduces or prevents the caking of even KI and 2 ⁇ NaCl and maintains the compounds in a substantially free flowing or scoopable state without adding any anti-caking agents to the compound to be protected.
  • One object is to provide a packaging system and method for packaging bulk quantities of powdered, crystalline, or granular organic and inorganic cakable compounds and mixtures thereof which will substantially retard or eliminate the caking of the compounds.
  • Another object is to provide such a packaging system and method which will maintain the chemical compounds in a substantially free flowing or scoopable state.
  • Yet another object is to provide such a packaging system and method which eliminates or reduces the need to use anti-caking agents.
  • a further object is to provide such a packaging system and method which will retard caking in a wide variety of compounds.
  • An additional object is to provide such a packaging system and method which is not complex and which is inexpensive to implement.
  • the packaging system comprises a moisture impermeable container having a moisture impermeable cover which closes the container to define an enclosure in which the compound is placed, and a desiccant.
  • Means such as a gasket, can be positioned between the container and cover to create a moisture tight seal therebetween.
  • the compound can be placed directly in the container or it can be placed in a moisture permeable bag.
  • the bag if used, preferably is sealed after the compound has been placed therein.
  • the container is filled with the compound so that there will be a void space in the enclosure.
  • the desiccant is placed in the void space.
  • the drum is preferably a fiber board drum lined with a moisture impermeable substance, such as aluminum, plastic, etc.
  • the cover is preferably a plastic cover.
  • Any desiccant may be used. It can be, for example, a silicon based desiccant, such as a desiccant which comprises about 70% silicon oxide, about 20% aluminum oxide, about 5% magnesium oxide, about 3% calcium oxide, and about 2% ferric oxide.
  • One commonly available desiccant has a particle size of which 99% by weight passes 10 mesh and 4% passes 80 mesh and has an apparent bulk density of 60 lbs./ft 3 (0.96 gm/cc).
  • the permeable bag may be a crepe paper bag, such as a bag made of 50# kraft paper (ArkelTM paper), or it may be a permeable polypropylene bag, such as a bag made from a woven polypropylene.
  • a crepe paper bag such as a bag made of 50# kraft paper (ArkelTM paper)
  • a permeable polypropylene bag such as a bag made from a woven polypropylene.
  • FIG. 1 is a cross-sectional view of an illustrative packaging system of the present invention
  • FIG. 1A is a section view, partly broken away, illustrating a modification of the packaging system, showing a basket for holding desiccant mounted to the side of the receptacle lining;
  • FIG IB is a orthogonal projection view of the modification showing the basket of FIG. 1 A, with some parts broken away;
  • FIG. 1 C is a section view, partly broken away, illustrating another modification of the packaging system, showing a basket for holding desiccant that is mounted to the inside of the cover;
  • FIG. ID is a orthogonal projection view of the modification showing the basket of FIG. 1C, with some parts broken away;
  • FIG. 2 is a top plan view of a another embodiment of a container of the packaging system with the cover not shown;
  • FIG. 3 is a cross-sectional view taken along line 3—3 of FIG. 2;
  • FIG. 4 is a chart comparing the relative humidity in the packaging system of the present invention with conventional packaging.
  • FIG. 5 is a graph charting the relative humidity in the packaging system, the relative humidity in a conventional packaging, and the relative humidity of the ambient atmosphere.
  • FIG. 1 A packaging system 10 of the present invention is shown in FIG. 1.
  • the packaging system 10 comprises a container illustrated as a drum 1 1.
  • the drum 1 1 includes a receptacle section 12 and a cover 13.
  • the receptacle section 12 is illustrated as having a cylindrical side wall 14 with a curved annular upper end, and a bottom 15.
  • a moisture impermeable lining 16 covers the side wall 14 and bottom 15 of the drum 11.
  • the drum 1 1 can be a fiber board drum, and the lining 16 is provided as a moisture barrier to prevent moisture from entering the drum.
  • aluminum is preferred for the lining 16 of the drum 1 1, the drum 1 1 can be lined with any moisture impermeable substance, including, for example, plastic.
  • the lining 16 is not needed if the drum used is itself moisture impermeable.
  • an aluminum or plastic drum which acts as, or creates, a moisture barrier could be used without the moisture impermeable lining 16.
  • the cover 13 is moisture impermeable and is preferably made of plastic, but can be made of any moisture impermeable product (such as metal, for example) which will withstand the elements to which the container will be exposed.
  • the cover 13 covers the receptacle 12.
  • Means are provided for forming a moisture tight seal between the cover 13 and the drum receptacle 12.
  • the means can be a gasket 19 made of an elastomer or rubber, for example.
  • the sealing means can also be provided by the cover itself being made of, or including, elastomeric material or rubber, so that it seals at its point of contact with the upper end of the receptacle 12.
  • a lock band 21 is then applied to the receptacle 12 and cover 13 to secure the cover 13 to the receptacle 12.
  • the lock band 21 can be replaced with a tape which will tape closed the container. Once the drum 11 is so closed, moisture is substantially prevented from entering or exiting the drum 11.
  • the inside surfaces of the cover 13 and of the liner 16 define the surface boundaries B of an enclosed container volume V. If a gas impermeable receptacle is used, then the inside surface of receptacle side wall 14 and bottom 15, and the inside of cover 13 define such boundaries B of volume V.
  • the chemical compound C is placed for storage in the drum 11.
  • a moisture permeable bag 23 is first placed within receptacle 12 and then compound C is poured into the bag 23.
  • the bag 23 can be filled with compound C while outside the receptacle 12, then loaded into the receptacle 12. Less desirably, the compound C can be placed directly into the receptacle 12 without bag 23.
  • the bag 23 can be a crepe paper bag made of 50# kraft paper (such as ArkelTM paper), a polypropylene bag, or GORTEX ® material. If a polypropylene bag is used, the bag is preferably a woven polypropylene bag, such as is available from Essex Plastics of Pompano Beach, FL.
  • a moisture permeable polypropylene bag can be formed in other manners, including, for example, perforating a moisture impermeable bag.
  • the receptacle 12 is filled with the compound C (either directly in the drum or in the bag 23) such that there is a head or void space 25 in the volume V.
  • the top of the bag 23 can be closed by a clip 26 which can be of plastic. If the compound C is placed in the bag 23, the void space 25 is defined by the outer wall 24 of the bag 23 and the boundaries B of the volume V.
  • a supply of desiccant 27 is placed in the void space 25.
  • the desiccant 27 is preferably inside moisture permeable bags 28 so that the desiccant particles will not be loose in the drum 1 1.
  • the bags 28 in which the desiccant 27 is placed will also physically separate the desiccant 27 from the compound C. If the bag 23 is also used, the wall 24 of bag 23 further physically separates the desiccant 27 from compound C.
  • the void space tested was between 10% and 90% of the volume of the drum.
  • the desiccant 27 is shown as placed between the cover 13 and the top of the bag 23 in FIG. 1, the bag 23 could be supported in the drum 11, such that the desiccant 27 is placed at the bottom 15 of the drum 1 1 and/or adjacent the sides 14 of the drum 1 1 or adjacent the cover 13. For example, FIGS.
  • FIG. 1A and IB show a modification wherein a basket 29, which can be of plastic, is secured to the inside of the lining 16' as by an adhesive or any other manner which will not affect the moisture impermeable characteristic of the drum 1 1.
  • the basket 29 can have a frame formed by interior longitudinal struts 31 and exterior longitudinal struts 33 that can be adhered to lining 16'.
  • Struts 31 are connected at their ends to a pair of interior arcuate struts 35.
  • Four transverse struts 37 are connected to the ends of the struts 31 and struts 33.
  • Diagonal strands of cross webs 39 which can be of plastic can be integrally molded with struts 31, 33, 35 and 37 to extend from struts 31, 33 and 37 to make a box-like basket. No cross webs connect the upper struts 37, so that an opening 41 is formed at the top of basket 29.
  • a bag of desiccant such as bag 28 can be inserted through opening 41 into basket 29, with the cross webs 39 at the bottom of basket 29 and the cross webs 39 on three sides of basket 29, along with the lining 16 located toward the outside of basket 29 acting to hold the desiccant bag therein.
  • the strands of webs 39 are spaced apart so that a plurality of holes extend through the webbing to make the webbing 39 moisture permeable and permit ease of gas flow therethrough.
  • the desiccant bags placed in the basket 29 are thus physically spaced from the compound bag 23.
  • the basket 29 can be attached to the inside of receptacle side wall 14' as by adhesive, or integrally molded with side wall 14'.
  • FIG. 1C and ID show another modification where a basket 42 of similar web construction as basket 29 is secured to the inside surface of cover 13" as for example by adhesives or being integrally molded with a plastic cover 13".
  • Basket 42 has four upper struts 44 that form a square frame that can be secured to cover 13". Extending from the ends of the struts 44 are four longitudinal struts 45 that depend downwardly to connect to the ends of four transverse struts 46. Struts 46 also form a square. Webbing 47 is connected to the struts 46 across the basket bottom.
  • Webbing 47 is also connected to struts 44, 45 and 46 on the sides of basket 42 to enclose those sides, except at the front of the basket where an opening 48 is formed at the basket front as viewed in Fig. ID.
  • a bag of desiccant 27 can be inserted through opening 48 and held within basket 42 to be physically spaced from compound bag 23.
  • the baskets are provided in sufficient number and size to contain at least the amount of desiccant desired.
  • the basket openings could be covered with a pivotally mounted webbed lid and have latches to hold the lid shut.
  • a drum 1 1'" is shown which would permit the desiccant to be placed adjacent the sides of the drum l l'"or at the bottom of the drum 1 1'".
  • the drum 1 1"' includes vertical ribs 49 (which are shown to be T-shaped in cross-section) extending along the receptacle side wall 14"' and a platform 51 at the bottom 15'" of the receptacle 12'".
  • the ribs 49 and platform 51 would support the compound bag 23 (not shown in Fig. 2-3) in spaced relationship from the receptacle sides 14'" and bottom 15'” such that the void space 25'" would substantially surround the bag 23.
  • the platform has perforations 53.
  • the platform could also be formed as a plurality of ribs which support the bag 23 above the receptacle bottom 15'".
  • the void space 25'" thus permits gas flow substantially around the bag 23 to facilitate absorption or adsorption of the moisture by the desiccant 17.
  • the desiccant can be mounted to the inner surfaces of the cover 13'" or sides 14'" of the drum 1 1'" by use of baskets such as illustrated in Figs. 1A and IB.
  • the bags of desiccant can be adhered directly to the surfaces of the cover 13'" or sides 14'" of the drum 1 1 '", for example by taping or gluing the bag 19 of desiccant directly to the desired inner surface of the drum 1 1 '".
  • the desiccant 27 preferably is a silicon based desiccant, such as Desiccite 25TM available from The Harshaw Chemical Co. of Iselin, New Jersey.
  • Desiccite 25TM is 70% silicon oxide, 20% aluminum oxide, 5% magnesium oxide, 3% calcium oxide, and 2% ferric oxide. It has a particle size 99% by weight of which passes 10 mesh and 4% by weight of which passes 80 mesh and an apparent bulk density of 60 lbs./ft 1 (0.96 gm/cc).
  • the water vapor absorption characteristics of the desiccant, at equilibrium at 77°F (25°C) are as follows:
  • This desiccant is available in bags of 8 to 80 units each.
  • a unit of desiccant is the amount of desiccant which will absorb or adsorb in seven hours at 25°C 3 gm of water at 20% relative humidity, and 6 gm of water at 40% relative humidity.
  • Thirty-three grams (33 gm) of the Desiccite 25TM is equivalent to one unit of desiccant.
  • the amount of desiccant needed in each package depends on the amount of moisture that will be trapped in the drum when the drum is sealed. I have found that two bags (eighteen units) of the desiccant in the drum works well for up to at least 100 lbs of compound with less than 0.1 % moisture.
  • the desiccant was added at a ratio of 0.16 to 1.6 units of desiccant per pound of compound. Less desiccant may also have worked equally as well.
  • the exact amount (i.e., weight) of desiccant needed to extract the moisture from the compound depends, among other factors, the actual amount of free moisture in the compound, the humidity of the air in the drum, the efficacy of the drum desiccant, etc.
  • the eighteen units of desiccant used is believed to be in excess of the amount actually needed for 100 pounds at 0.1 % moisture. However, the use of an excess amount of desiccant is preferred to ensure that the moisture which would otherwise lead to caking of the compound will be absorbed or adsorbed by the desiccant.
  • the desiccant is preferably dry (i.e., not loaded with moisture) when it is placed in the drum 1 1.
  • any other desiccant should work.
  • Such other desiccants include, for example, silica gel, activated alumina (AIO), barium oxide (BaO), calcium chloride (CaCl 2 ), calcium oxide (CaO), calcium sulfate (CaS0 4 ), lithium chloride (LiCl), perchlorates (such as barium perchlorate [Ba(C10 4 ) 2 ], lithium perchlorate [LiClO 4 ], and magnesium perchlorate [Mg(C10 4 ) 2 ]), phosphorus pentoxide (P 2 0 5 ), sodium (NaOH) and potassium (KOH) hydroxides, and molecular sieves.
  • This list is not meant to be exclusive, and other desiccants could also work equally well or better than those listed.
  • the desiccant chosen should preferably be inert with respect to the compound being stored in
  • the noted compounds were placed in a packaging system of the present invention and a control sample was placed in a conventionally packaging system (such as outlined above) at the same time.
  • the chemical compounds were free flowing when placed in the packaging systems.
  • the experimental and control samples for the different compounds tested were stored adjacent each other throughout the experiment so that they would be subject to the same conditions.
  • the drum contents were checked on the noted dates to determine the condition of the powder contained therein.
  • the compounds were evaluated according to the following schedule:
  • any compound which rates a 5 or less is acceptable. If the compound rates a 7 or greater, the compound must then be processed to make it at least scoopable. Whether or not a compound cakes to a rating of 6 is acceptable or needs further processing depends upon the amount of crusting and its scoopability.
  • Table I Those examples that include a "C" in their number are controls.
  • drums used were cylindrical in shape.
  • Example 37C it can be seen that within merely 13 days the KI caked to the point where it had to be beaten just to break it into lumps. Whereas in the packaging system of the present invention the KI remained free flowing, even after almost four months. (See Example 36).
  • Example 21 The potassium nitrate (KN0 3 ) tests (Examples 21 and 22C) were both performed with the compound in Arkel paper (i.e., moisture permeable) bags. The only difference between the two was that in Example 21 , the fiber drum was lined with aluminum to make the receptacle moisture impermeable.
  • the bismuth nitrate pentahydrate (Bi(N0 3 ) 3 '5H 2 0) test Example 29
  • the paper liner disintegrated.
  • Example 30 The series of tests on the guanidine hydrochloride (Examples 30-35 C) indicated that the liner or bag in which the compound is placed is important. In the tests in which the guanidine hydrochloride was placed in polyethylene liners (i.e. essentially water impermeable liners) the product caked, even though desiccant was placed in the receptacle with the bag of product. The tests also show that receptacles made of materials other than aluminum lined drums will work well. In Example 30, a polyethylene receptacle was used without a lining 16. The receptacle used was one available from The United States Can Company (formerly The Sherwin-Williams Company) of Cleveland Ohio under the name POLY-PAIL ® . Polyethylene is known to be moisture impermeable and thus the lining 16 was not needed.
  • polyethylene liners i.e. essentially water impermeable liners

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  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
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Abstract

La présente invention concerne un système et un procédé permettant sensiblement de retarder ou de réduire l'agglomération, non seulement de composés chimiques organiques et non organiques pulvérulents, cristallins ou granulaires, susceptibles de s'agglomérer, mais également de mélanges de tels composés. Ce retard et cette réduction de l'agglomération améliore la fluidité et l'aptitude au prélèvement du composé. Le système et le procédé d'emballage rassemblent un récipient (11) imperméable à l'humidité, un couvercle (13) imperméable à l'humidité pour fermer le récipient, un joint (19) assurant une fermeture étanche à l'humidité entre le récipient et le couvercle, et un agent déshydratant (27). Le composé (C) peut être mis directement dans le récipient ou dans un sac (23) perméable à l'humidité que l'on ferme après y avoir mis le composé. Le sac est rempli ou calibré de façon qu'il reste un volume libre (25) dans le récipient une fois qu'il est fermé. L'agent déshydratant se met dans le volume libre. Le baril peut être en panneau de fibres garni d'une doublure (16) imperméable à l'humidité telle que de l'aluminium. Le couvercle est de préférence en plastique. Le sac perméable est de préférence en papier kraft crêpé ou en polypropylène tissé.
PCT/US1997/008669 1996-05-29 1997-05-22 Systeme et procede d'emballage de vrac retardant l'agglomeration de composes chimiques organiques ou non organiques WO1997045335A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU30757/97A AU3075797A (en) 1996-05-29 1997-05-22 Bulk packaging system and method for retarding caking of organic and inorganic chemical compounds

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US1837896P 1996-05-29 1996-05-29
US1857096P 1996-05-29 1996-05-29
US60/018,570 1996-05-29
US60/018,378 1996-05-29
US2770796P 1996-10-11 1996-10-11
US60/027,707 1996-10-11

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
WO2000026115A1 (fr) * 1998-11-03 2000-05-11 Werner Kallweit Recipient de stockage
EP1038795A1 (fr) * 1999-03-23 2000-09-27 Tosoh Corporation Emballage pour une zéolithe et son utilisation pour remplir une unité d'adsorption
DE10132251A1 (de) * 2001-07-04 2003-01-23 Honeywell Speciality Chemicals Verpackung für einen Feststoff
DE102004039387A1 (de) * 2004-08-13 2006-02-23 Klebchemie M.G. Becker Gmbh & Co. Kg Deckel für einen Behälter zur Lagerung und/oder Bereitstellung und/oder zum Transport von feuchtigkeitsempfindlichen Materialien
EP4414347A1 (fr) * 2023-02-08 2024-08-14 Acand Procédé et dispositif de stockage d'un produit cristallin sous forme de grains ou de paillettes

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WO1993014996A1 (fr) * 1992-01-23 1993-08-05 Bror Gustafsson Procede et dispositif d'absorption d'humidite dans un recipient
WO1994005161A1 (fr) * 1992-09-09 1994-03-17 Wm. Wrigley Jr. Company Composition coulante de gomme a macher et de bonbon
EP0633013A1 (fr) * 1993-01-22 1995-01-11 Otsuka Pharmaceutical Factory, Inc. Recipient de stockage d'un medicament en poudre contenant du bicarbonate, et procede de stabilisation dudit medicament

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US1541127A (en) * 1923-05-14 1925-06-09 Oscar B Elmer Air drier for candy jars
US2758932A (en) * 1953-07-31 1956-08-14 Ben L Sarett Deoxygenating process and product
SU592806A1 (ru) * 1975-03-03 1984-12-07 Коммунарский горно-металлургический институт Способ устранени слеживаемости минеральных удобрений
US4813791A (en) * 1987-09-18 1989-03-21 Multiform Desiccants, Inc. Bag with integral material treating packets
US5144003A (en) * 1990-11-13 1992-09-01 Eastman Kodak Company Trifunctional monomer compounds, polyesters derived therefrom and thermosetting coating compositions containing the polyesters
WO1993014996A1 (fr) * 1992-01-23 1993-08-05 Bror Gustafsson Procede et dispositif d'absorption d'humidite dans un recipient
WO1994005161A1 (fr) * 1992-09-09 1994-03-17 Wm. Wrigley Jr. Company Composition coulante de gomme a macher et de bonbon
EP0633013A1 (fr) * 1993-01-22 1995-01-11 Otsuka Pharmaceutical Factory, Inc. Recipient de stockage d'un medicament en poudre contenant du bicarbonate, et procede de stabilisation dudit medicament

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000026115A1 (fr) * 1998-11-03 2000-05-11 Werner Kallweit Recipient de stockage
EP1038795A1 (fr) * 1999-03-23 2000-09-27 Tosoh Corporation Emballage pour une zéolithe et son utilisation pour remplir une unité d'adsorption
US6401432B1 (en) 1999-03-23 2002-06-11 Tosoh Corporation Method for packing and sealing a zeolite adsorbent with a dehydrating agent
US6523329B2 (en) * 1999-03-23 2003-02-25 Tosoh Corporation Method for packing and sealing a zeolite adsorbent with a dehydrating agent
DE10132251A1 (de) * 2001-07-04 2003-01-23 Honeywell Speciality Chemicals Verpackung für einen Feststoff
DE102004039387A1 (de) * 2004-08-13 2006-02-23 Klebchemie M.G. Becker Gmbh & Co. Kg Deckel für einen Behälter zur Lagerung und/oder Bereitstellung und/oder zum Transport von feuchtigkeitsempfindlichen Materialien
EP4414347A1 (fr) * 2023-02-08 2024-08-14 Acand Procédé et dispositif de stockage d'un produit cristallin sous forme de grains ou de paillettes
WO2024165604A1 (fr) * 2023-02-08 2024-08-15 Acand Procede et dispositif de stockage d'un produit cristallin sous forme de grains ou de paillettes

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