WO1997044002A1 - Compositions de colorant capillaire - Google Patents

Compositions de colorant capillaire Download PDF

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Publication number
WO1997044002A1
WO1997044002A1 PCT/EP1997/002713 EP9702713W WO9744002A1 WO 1997044002 A1 WO1997044002 A1 WO 1997044002A1 EP 9702713 W EP9702713 W EP 9702713W WO 9744002 A1 WO9744002 A1 WO 9744002A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
composition
colorant composition
hair colorant
agent
Prior art date
Application number
PCT/EP1997/002713
Other languages
English (en)
Inventor
Rajesh Savji
Brian Hanrahan
Original Assignee
The Boots Company Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Boots Company Plc filed Critical The Boots Company Plc
Priority to AU29618/97A priority Critical patent/AU2961897A/en
Publication of WO1997044002A1 publication Critical patent/WO1997044002A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/004—Preparations used to protect coloured hair

Definitions

  • the present invention relates to compositions used to colour the hair, to methods of preparing such compositions, to methods of using such compositions to treat hair and means to dispense such a compositions onto the hair.
  • hair colorant composition as used herein comprises any composition which colours, tints and/or dyes the hair.
  • Such compositions may comprise so-called “hot oil” treatments, shampoos, conditioners, hair dyes, mousses, foams, gels, creams, lotions and rinses.
  • Prior art compositions used to colour the hair have various disadvantages.
  • the new colour fades after typically 6 to 8 subsequent washes of the hair.
  • Such colorant compositions are said to semi-permanently colour the hair.
  • a semi-permanent colorant treatment as used herein is one in which one or more coloured chemical entities are applied to the hair and are absorbed thereon to give the desired coloration which is progressively removed each time the hair is shampooed.
  • Conventionally such semi-permanent hair colorant compositions are progressively removed over 6 to 8 shampooings.
  • the ingredients used in many hair colorant compositions are often fairly noxious and therefore it may also be desirable to reduce the number of times hair is exposed to such compositions and / or reduce or remove the more noxious ingredients from such hair colorant compositions.
  • an alkali metal bicarbonate is added to a hair colorant composition the colour produced lasts longer and in particular is more resistant to washing of the hair.
  • a particularly advantageous alkali metal bicarbonate comprises sodium bicarbonate.
  • Sodium bicarbonate (baking soda) is well known to be an effective deodoriser and helps absorb odours. It has been used traditionally in the home where its gentle alkaline characteristics neutralise the acidic results of bacterial attack such as sour milk and oxidised wine. More unpleasant acidic odours such as vomit are quickly rendered inoffensive by baking soda.
  • Sodium bicarbonate has also been used in oral hygiene products.
  • the alkalinity of the baking soda neutralises the unpleasant tastes and odours of decaying food trapped between the teeth.
  • the sodium bicarbonate also imparts a tingly slightly bitter flavour to give an impression of freshness that can be quite addictive and encourages more frequent attention to dental hygiene.
  • Sodium bicarbonate has also been incorporated into toiletry products to treat body odours.
  • Such prior art products comprising sodium bicarbonate include for example: Johnson & Johnson's "Shower to shower” shower talc; underarm deodorants available commercially from inter alia Home Health, St Ives Laboratories, Church & Dwight and Colgate Palmolive; hair shampoos and / or conditioners available commercially from inter alia Western Pleasure and Jherri Redding; and Andrew Jergens' "Jergens Natural” soap bar.
  • sodium bicarbonate is a widely used ingredient in cosmetic and toiletries compositions.
  • sodium bicarbonate produces enhanced and / or synergistic effects in the colour produced by hair colorant compositions.
  • a hair colorant composition comprising an agent which will colour, tint and / or dye the hair and a alkali metal bicarbonate present in an amount sufficient to enhance the retention and intensity of the hair colour produced by the composition, preferably the enhancement is synergistic.
  • the hair colouring agent comprises one or more suitable cationic dyes.
  • the alkali metal bicarbonate comprises sodium bicarbonate.
  • the alkali metal bicarbonate used in the present invention particularly sodium bicarbonate, are believed to act to swell the hair thus aiding absorption of the hair colouring agent by the hair. This aids production of in an artificial colour on the hair which has improved resistance to fading during subsequent washing.
  • the hair colorant composition may be applied once to produce a hair colour lasting for at least 8, typically 18 to 21 , washes before fading significantly.
  • the sodium bicarbonate is present in amount from about 1 % by weight of the total composition to an amount which produces the maximum value of pH in the hair colorant composition which would be cosmetically acceptable.
  • a alkali metal bicarbonate in particular sodium bicarbonate
  • hair colorant compositions of the present invention may have one or more of the following further advantages which are useful for hair care compositions: it may mop up free fatty acids on the skin and scalp and have an anti-acne and / or anti- dandruff effect; it may act as a deodorant by absorbing acidic odours; it may act as a mild exfolient (at concentrations above about 5 % by weight NaHCO 3 may also as an abrasive); it may dissolve or neutralise dandruff flakes before they occur; it may act as a protein denaturant to improve absorption of active ingredients on the hair; and it may act as a toner for skin and / or hair by saponifying free acids to emulsify oils on the skin and / or hair which is particularly useful for greasy skin.
  • the hair colorant compositions of the present invention are gentle on the skin in that they comprise ingredients other than hydrogen peroxide (H 2 O 2 ) and / or ammonia (NH 3 ).
  • H 2 O 2 hydrogen peroxide
  • NH 3 ammonia
  • the absence of such noxious ingredients permits use of greater amounts of alkali metal bicarbonate without raising the pH of the hair colorant composition to a level which would be cosmetically unacceptable.
  • Free radicals which are generated by factors such as UV radiation (present in sunlight), heat and/or by chemical reaction, are implicated in the process of damage to hair and fading of hair colour.
  • the hair colorant compositions of the present invention are provided with means to generate lower levels of free radicals than known hair colorant compositions to provide improved protection against the fading of the coloured hair by sunlight and against damage to hair caused by exposure to factors such as sunlight, environmental and/or atmospheric pollution, heat from styling the hair and / or chemical treatment of the hair (for example curling, perming, straightening, dyeing and/or bleaching).
  • the hair colorant composition according to the present invention may further comprise an anti-free-radical agent
  • an anti-free-radical agent Such anti-free-radical compositions are further described in the applicant's co-pending international patent application WO96/36312, the disclosure of which is hereby incorporated herein by reference.
  • the anti-free-radical agent may be, for example ascorbic acid, vitamin E (tocopherol), lipacide LHL, phytoamine or herbal extract such as mimosa tenuiflora AA (available commercially from A & E Cannock), ginkgo biloba extract (available commercially from Indena), or birch extract.
  • Preferred anti-free-radical agents are selected from one or more of: ascorbic acid, tocopherol and herbal extract.
  • Particularly preferred anti-free- radical agents are selected from ginkgo biloba extract and birch extract.
  • Ginkgo biloba extract may be produced by extracting the leaves of the ginkgo biloba tree with a suitable solvent.
  • Birch extract may be produced by extracting the dried leaves of Betula alba with a suitable solvent. It is believed that the anti-free radical activity of birch extract arises due to the presence of flavonoids such as hyperosid, quencitrosid and/or myricetol-3-digalactosid which may be free-radical inhibitors.
  • a suitable birch extract comprises those available from Cosmetochem (U.K.) Ltd under the trade names "Super
  • Herbasol Extract Birch and "HP Herbasol Betula” and those available from
  • the anti-free-radical agent may consist of active ingredients which are free-radical inhibitors or may also comprise suitable diluents and/or carriers (such as when the anti-free radical agent is some of the products mentioned herein). It will be appreciated that the anti-free-radical agent is not limited to one or more of those anti-free-radical agents listed above and is not limited to those anti-free-radical agents comprising the ingredients described above.
  • the anti-free-radical agent may be present in an amount of from about 0.01% to about 10% by weight, more preferably from about 0.05% to about 5% by weight, most preferably from about 0.15% to about 3.0% by weight of the composition.
  • hair colorant compositions of the present invention may further comprise any acceptable sunscreening agent (that is an agent which acts to absorb and/or reflect UV radiation present in sunlight) and which would be acceptable for use in a hair-care composition (for example suitable for use on the human head).
  • any acceptable sunscreening agent that is an agent which acts to absorb and/or reflect UV radiation present in sunlight
  • Such sunscreening agents may comprise inorganic sunscreens (for example zinc oxide and/or titanium dioxide preferably of microfine ( ⁇ 100 nm) particle size) and/or organic sunscreens (for example p-aminobenzoic acids, esters and derivatives, methoxycinnamate esters, benzophenones [such as benzophenone-4 ⁇ available commercially under the trade name Uvinul MS40 ⁇ ]; dibenzoylmethanes and / or salicylate esters).
  • the sunscreening agents may be present in an amount of from about 0.1 % to about 10% by weight of the composition.
  • the hair colorant composition according to the present invention may further comprise a polymeric conditioning agent prepared from monomer entities selected from one or more of: acrylic acid, acrylamide dimethyldiallylammonium chloride and any mixtures thereof.
  • a polymeric conditioning agent prepared from monomer entities selected from one or more of: acrylic acid, acrylamide dimethyldiallylammonium chloride and any mixtures thereof.
  • the polymeric conditioning agent is a copolymer of acrylic acid and acrylamide monomer entities, and may comprise further co-monomers.
  • the polymeric conditioning agent is a polymer of dimethyldiallylammonium chloride monomer entities, more preferably a copolymer further comprising acrylamide co-monomer entities, most preferably the copolymer still further comprising acrylic acid co-monomer entities.
  • the polymeric conditioning agent is a terpolymer comprising acrylic acid, acrylamide and dimethyldiallylammonium chloride co-monomers.
  • these co-monomers are present in weight ratios of about 1 to about 2 to about 1 respectively.
  • Particularly preferred polymeric conditioning agents are the polymers known under the following CTFA designations: ' polyquatemium 39' which is a terpolymer of dimethyldiallylammonium chloride, acrylamide and acrylic acid co-monomers (available commercially from Chemviron Speciality Chemicals under the trade names ' Merquat Plus 3330' and ' Merquat Plus 3331'); ' polyquaternium T which is a copolymer of dimethyl-diallylammonium chloride and acrylamide co-monomers (available commercially from Chemviron Speciality Chemicals under the trade name ' Merquat S'); and ' polyquaternium 6' which is a homopolymer of dimethyldiallylammonium chloride monomers (available commercially from Chemviron Speciality Chemicals under the trade name ' Merquat 100').
  • the polymeric conditioning agent may be present in the composition in an amount of from about 0.001 % to about 10% by weight, suitably from about
  • preservatives may be added to the composition such as 2-bromo-2-nitropropane-1 ,3-diol (bronopol, which is available commercially under the trade name Myacide), benzyl alcohol, diazolidinyl urea, imidazolidinyl urea, methyl paraben, phenoxy ethanol, propyl paraben, sodium methyl paraben and sodium propyl paraben, suitably in an amount of from about 0.01% to about 10% by weight of the composition.
  • bronopol which is available commercially under the trade name Myacide
  • benzyl alcohol diazolidinyl urea
  • imidazolidinyl urea imidazolidinyl urea
  • methyl paraben methyl paraben
  • propyl paraben sodium methyl paraben and sodium propyl paraben
  • suitably in an amount of from about 0.01% to about 10% by weight of the composition suitably in an amount of from about 0.01% to about
  • Thickeners and viscosity modifying agents may be added to the composition, such as amine oxides, block polymers of ethylene oxide and propylene oxide (for example, those available from BASF Wyandotte under the trade name "Pluronic"), ethoxylated fatty alcohols, cellulosic derivatives such as hydroxypropylmethyl cellulose, salt (NaCI), phthalic acid amide, polyvinyl alcohols and fatty alcohols, suitably in an amount of from about 0.5% to about 10% by weight of the composition.
  • amine oxides block polymers of ethylene oxide and propylene oxide (for example, those available from BASF Wyandotte under the trade name "Pluronic")
  • ethoxylated fatty alcohols ethoxylated fatty alcohols
  • cellulosic derivatives such as hydroxypropylmethyl cellulose, salt (NaCI), phthalic acid amide
  • polyvinyl alcohols and fatty alcohols suitably in an amount of from about 0.5% to about 10% by
  • Sequestering agents may be added to the composition, such as ethylenediamine tetraacetic acid and salts thereof, suitably in an amount of from about 0.005% to about 0.5% by weight of the composition.
  • the composition may also include vitamins such as biotin, suitably in an amount of from about 0.01% to about 1.0% by weight of the composition.
  • the composition may also include gelling agents such as PVM, MA, or a decadiene crosspolymer (available under the trade name Stabiiez 06), suitably in an amount of from about 0.1 % to about 2% by weight of the composition.
  • composition may aiso comprise suitable, cosmetically acceptable diluents or carriers.
  • Perfumes may be added suitably in an amount of from about 0.01 % to about 2% by weight of the composition, as may water soluble dyes such as tartrazine, suitably in an amount of from about a trace amount (such as 1 x 10 "5 %) to about 0.1 % by weight of the composition.
  • the composition may be buffered by additional buffering means well known in the art, for example by use of buffer systems comprising succinic acid, citric acid, lactic acid, and acceptable salts thereof, phosphoric acid, mono- or disodium phosphate and sodium carbonate.
  • buffer systems comprising succinic acid, citric acid, lactic acid, and acceptable salts thereof, phosphoric acid, mono- or disodium phosphate and sodium carbonate.
  • the composition may have a pH in a range in which the advantageous properties of the hair colorant compositions described herein are present, preferably a pH of between about 7 and about 10, more preferably about 9.
  • Surfactants may be included, such as cosmetically acceptable salts of alkyl ether sulphates, alkyl and alkylamidoalkyl betaines, ethoxylated alcohols, polyethyleneglycol carboxylates, acceptable salts of alkyl sulphates (such as ammonium lauryl sulphate), sulphosuccinates (such as disodium laureth sulphosuccinate), amphoacetates and amphodiacetates (such as disodium cocoamphodiacetate), alkylpolyglucosides and alcohol sulphonates.
  • acceptable salts of alkyl sulphates such as ammonium lauryl sulphate
  • sulphosuccinates such as disodium laureth sulphosuccinate
  • amphoacetates and amphodiacetates such as disodium cocoamphodiacetate
  • alkylpolyglucosides and alcohol sulphonates such as cosmetically acceptable salts of alkyl
  • a method of preparing a hair colorant composition as described herein comprising mixing in a suitable manner a alkali metal bicarbonate (such as any of those described herein), a hair colouring agent (such as a suitable cationic dye) and a suitable carrier.
  • a hair colouring agent such as a suitable cationic dye
  • a suitable carrier such as any of those described herein
  • any other suitable ingredients may be added such as those described herein.
  • a preferred method of preparation is described in the example.
  • the hair colorant compositions of the present invention may be stored sold and/or applied to the hair from a container comprising an integral brush head through which the composition may flow on application to the hair.
  • a container aids complete and even application of the hair colorant composition to the hair to avoid or reduce unintentional streaking or uneven colour intensity in the resultant artificially coloured hair.
  • a container comprising a chamber comprising a flowable hair colorant composition as described herein, the chamber being in fluid connection with a dispensing means such that composition is capable of being applied to the hair by the dispensing means.
  • the dispensing means comprises a brush or sponge through which the composition may flow.
  • compositions of the present invention will now be illustrated by the following non-limiting example.
  • the term "% w/w” indicates percentage mass of an ingredient per total mass of the composition.
  • the above ingredients were used as follows to prepare a hair colorant composition.
  • the Natrosol 250 HR was added to water and the mixture was stirred.
  • the Sequestrene NA2 was dissolved in water and added to the Natrosol mixture, followed by the cetyl alcohol, Cetomacrogol and
  • the hair swatches used were a) hair which had not been treated with any perming agent (hereinafter virgin hair), b) hair which had been treated with a perming agent for half the recommended processing time, and c) hair which had been treated with a perming agent for the full recommended processing time.
  • the swatches were coloured using the above formulation and the intensity of the colour determined colorimetrically.
  • the swatches were then washed in a shampoo, rinsed and blow dried. The intensity of the colour was determined colormetrically and by visual comparison with a swatch of virgin hair which had been coloured at the same time and in the same way as the test samples.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition de colorant capillaire qui comprend un agent destiné à colorer et/ou à teinter les cheveux, et un bicarbonate d'un métal alcalin, notamment du bicarbonate de sodium, présent en quantité suffisante pour accroître la durée et l'intensité de la couleur de cheveux produite par ladite composition. L'agent de coloration capillaire peut contenir un pigment cationique convenable. La composition peut comprendre en outre un agent anti-radicaux libres et/ou un agent de conditionnement polymère préparé à partir d'entités monomères choisies entre l'acide acrylique et/ou le chlorure d'acrylamide diméthyldiallylammonium et leurs mélanges. L'invention concerne également un récipient constitué d'une chambre qui contient la composition de colorant capillaire et qui est en communication fluidique avec un système de distribution, de façon que la composition puisse être appliquée sur les cheveux par le système de distribution, ce dernier comprenant de préférence une brosse à travers laquelle peut s'écouler la composition.
PCT/EP1997/002713 1996-05-17 1997-05-17 Compositions de colorant capillaire WO1997044002A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU29618/97A AU2961897A (en) 1996-05-17 1997-05-17 Hair colorant compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9610378.3 1996-05-17
GBGB9610378.3A GB9610378D0 (en) 1996-05-17 1996-05-17 Hair colorant composition

Publications (1)

Publication Number Publication Date
WO1997044002A1 true WO1997044002A1 (fr) 1997-11-27

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Application Number Title Priority Date Filing Date
PCT/EP1997/002713 WO1997044002A1 (fr) 1996-05-17 1997-05-17 Compositions de colorant capillaire

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AU (1) AU2961897A (fr)
GB (1) GB9610378D0 (fr)
WO (1) WO1997044002A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0970685A1 (fr) * 1998-07-09 2000-01-12 L'oreal Composition de teinture pour fibres kératiniques avec un colorant direct cationique et un polymère épaississant
EP1048290A2 (fr) * 1999-04-30 2000-11-02 Bristol-Myers Squibb Company Teinture d'oxydation pour les cheveux avec des propriétés conditionnantes et une déposition améliorée de la couleur
EP1172081A1 (fr) * 2000-05-11 2002-01-16 HairMarker LLC Composition et méthode de teinture des cheveux
FR2817467A1 (fr) * 2000-12-04 2002-06-07 Oreal Composition de teinture pour fibres keratiniques comprenant un polymere associatif et un polymere a motifs acrylamide, halogenure de dialkyldiallylammonium et acide carboxylique vinylique
US6613102B2 (en) 1998-07-09 2003-09-02 L'oreal S.A. Composition for dyeing keratin fibers with a cationic direct dye and a thickening polymer
US7060113B1 (en) 2000-05-11 2006-06-13 Hairmarker Llc Hair coloring composition and method
US7300473B2 (en) 1998-07-09 2007-11-27 L'oreal S.A. Composition for dyeing keratin fibers with a cationic direct dye and a thickening polymer
US7306632B2 (en) 2000-05-11 2007-12-11 Hairmarker Llc Leave-in color conditioner

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1292212A (fr) * 1960-05-17 1962-05-04 Oreal Nouvelle teinture pour cheveux et autres fibres kératiniques
US3567363A (en) * 1965-09-20 1971-03-02 Gillette Co Modification of keratin to the s-sulfo form
US3973900A (en) * 1971-03-29 1976-08-10 Wella Ag Hair dye
EP0658339A1 (fr) * 1993-11-30 1995-06-21 Bristol-Myers Squibb Company Procédé et kit pour la teinture des cheveux

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1292212A (fr) * 1960-05-17 1962-05-04 Oreal Nouvelle teinture pour cheveux et autres fibres kératiniques
US3567363A (en) * 1965-09-20 1971-03-02 Gillette Co Modification of keratin to the s-sulfo form
US3973900A (en) * 1971-03-29 1976-08-10 Wella Ag Hair dye
EP0658339A1 (fr) * 1993-11-30 1995-06-21 Bristol-Myers Squibb Company Procédé et kit pour la teinture des cheveux

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 98, no. 26, 27 June 1983, Columbus, Ohio, US; abstract no. 217077, MATSUMOTO, TASUKU: "Swelling treatment of silk yarn and fabrics" XP002040400 *
DAIICHI KOGYO SEIYAKU SHAHO (1983), 422, 12-16 CODEN: DKSSAB, 1983 *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6613102B2 (en) 1998-07-09 2003-09-02 L'oreal S.A. Composition for dyeing keratin fibers with a cationic direct dye and a thickening polymer
FR2780882A1 (fr) * 1998-07-09 2000-01-14 Oreal Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un polymere epaississant
US7300473B2 (en) 1998-07-09 2007-11-27 L'oreal S.A. Composition for dyeing keratin fibers with a cationic direct dye and a thickening polymer
EP0970685A1 (fr) * 1998-07-09 2000-01-12 L'oreal Composition de teinture pour fibres kératiniques avec un colorant direct cationique et un polymère épaississant
EP1048290A2 (fr) * 1999-04-30 2000-11-02 Bristol-Myers Squibb Company Teinture d'oxydation pour les cheveux avec des propriétés conditionnantes et une déposition améliorée de la couleur
EP1048290A3 (fr) * 1999-04-30 2001-05-02 Bristol-Myers Squibb Company Teinture d'oxydation pour les cheveux avec des propriétés conditionnantes et une déposition améliorée de la couleur
US7060113B1 (en) 2000-05-11 2006-06-13 Hairmarker Llc Hair coloring composition and method
US6506374B1 (en) 2000-05-11 2003-01-14 Hair Marker Llc Hair coloring composition and method
EP1172081A1 (fr) * 2000-05-11 2002-01-16 HairMarker LLC Composition et méthode de teinture des cheveux
US7306632B2 (en) 2000-05-11 2007-12-11 Hairmarker Llc Leave-in color conditioner
WO2002045674A1 (fr) * 2000-12-04 2002-06-13 L'oreal Composition de teinture pour fibres keratiniques comprenant un polymere associatif et un polymere a motifs acrylamide, halogenure de dialkyldiallylammonium, et acide carboxylique vinylique
FR2817467A1 (fr) * 2000-12-04 2002-06-07 Oreal Composition de teinture pour fibres keratiniques comprenant un polymere associatif et un polymere a motifs acrylamide, halogenure de dialkyldiallylammonium et acide carboxylique vinylique
EP1889606A1 (fr) * 2000-12-04 2008-02-20 L'Oréal Composition de teinture pour fibres kératiniques comprenant un polymère associatif anionique et un polymère à motifs acrylamide, halogenure de dialkyldiallylammonium et acide carboxylique vinylique

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GB9610378D0 (en) 1996-07-24
AU2961897A (en) 1997-12-09

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