WO1997037841B1 - Sealable containers comprising an inorganically filled matrix - Google Patents
Sealable containers comprising an inorganically filled matrixInfo
- Publication number
- WO1997037841B1 WO1997037841B1 PCT/US1997/005494 US9705494W WO9737841B1 WO 1997037841 B1 WO1997037841 B1 WO 1997037841B1 US 9705494 W US9705494 W US 9705494W WO 9737841 B1 WO9737841 B1 WO 9737841B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- manufacture
- article
- fibers
- sealable container
- inorganically filled
- Prior art date
Links
- 239000011159 matrix material Substances 0.000 title claims 28
- 238000004519 manufacturing process Methods 0.000 claims abstract 225
- 239000000835 fiber Substances 0.000 claims abstract 90
- 239000000203 mixture Substances 0.000 claims abstract 61
- 229920002472 Starch Polymers 0.000 claims abstract 54
- 235000019698 starch Nutrition 0.000 claims abstract 54
- 239000008107 starch Substances 0.000 claims abstract 45
- 229920000620 organic polymer Polymers 0.000 claims abstract 20
- 239000000126 substance Substances 0.000 claims abstract 19
- 239000000945 filler Substances 0.000 claims abstract 16
- 239000002491 polymer binding agent Substances 0.000 claims abstract 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000011256 inorganic filler Substances 0.000 claims abstract 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract 2
- 239000007787 solid Substances 0.000 claims 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 21
- 239000011248 coating agent Substances 0.000 claims 18
- 238000000576 coating method Methods 0.000 claims 18
- 239000000463 material Substances 0.000 claims 17
- -1 phycocolloids Polymers 0.000 claims 17
- 239000011521 glass Substances 0.000 claims 15
- 229910052751 metal Inorganic materials 0.000 claims 15
- 239000002184 metal Substances 0.000 claims 15
- 229920003023 plastic Polymers 0.000 claims 15
- 239000004033 plastic Substances 0.000 claims 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 14
- 239000002657 fibrous material Substances 0.000 claims 14
- 239000004927 clay Substances 0.000 claims 12
- 229910052570 clay Inorganic materials 0.000 claims 12
- 150000002739 metals Chemical class 0.000 claims 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 10
- 239000000919 ceramic Substances 0.000 claims 9
- 239000008119 colloidal silica Substances 0.000 claims 9
- 239000002131 composite material Substances 0.000 claims 9
- 239000000123 paper Substances 0.000 claims 9
- 229920000747 poly(lactic acid) polymer Polymers 0.000 claims 9
- 239000004626 polylactic acid Substances 0.000 claims 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 6
- 229920001817 Agar Polymers 0.000 claims 6
- 239000004698 Polyethylene (PE) Substances 0.000 claims 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 6
- 239000002253 acid Substances 0.000 claims 6
- 239000008272 agar Substances 0.000 claims 6
- 235000010419 agar Nutrition 0.000 claims 6
- 229920000159 gelatin Polymers 0.000 claims 6
- 235000019322 gelatine Nutrition 0.000 claims 6
- 235000011852 gelatine desserts Nutrition 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 6
- 229920001888 polyacrylic acid Chemical class 0.000 claims 6
- 229920000573 polyethylene Polymers 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 6
- 150000003839 salts Chemical class 0.000 claims 6
- 239000011780 sodium chloride Substances 0.000 claims 6
- 229920005613 synthetic organic polymer Polymers 0.000 claims 6
- 229960003563 Calcium Carbonate Drugs 0.000 claims 5
- 239000002202 Polyethylene glycol Substances 0.000 claims 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 5
- 229920001223 polyethylene glycol Polymers 0.000 claims 5
- 235000018102 proteins Nutrition 0.000 claims 5
- 108090000623 proteins and genes Proteins 0.000 claims 5
- 102000004169 proteins and genes Human genes 0.000 claims 5
- 239000007788 liquid Substances 0.000 claims 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims 3
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 claims 3
- 240000005337 Agave sisalana Species 0.000 claims 3
- XJKJWTWGDGIQRH-BFIDDRIFSA-N Alginic acid Chemical compound O1[C@@H](C(O)=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C(O)=O)O[C@@H](C)[C@@H](O)[C@H]1O XJKJWTWGDGIQRH-BFIDDRIFSA-N 0.000 claims 3
- 239000005995 Aluminium silicate Substances 0.000 claims 3
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims 3
- 241000609240 Ambelania acida Species 0.000 claims 3
- 241000416162 Astragalus gummifer Species 0.000 claims 3
- 229960005069 Calcium Drugs 0.000 claims 3
- 240000000218 Cannabis sativa Species 0.000 claims 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 3
- 102000008186 Collagen Human genes 0.000 claims 3
- 108010035532 Collagen Proteins 0.000 claims 3
- 229920000742 Cotton Polymers 0.000 claims 3
- 206010011416 Croup infectious Diseases 0.000 claims 3
- 239000001856 Ethyl cellulose Substances 0.000 claims 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims 3
- 108010010803 Gelatin Proteins 0.000 claims 3
- 229920002907 Guar gum Polymers 0.000 claims 3
- 229920000569 Gum karaya Polymers 0.000 claims 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims 3
- 229920000126 Latex Polymers 0.000 claims 3
- 235000019738 Limestone Nutrition 0.000 claims 3
- 240000006240 Linum usitatissimum Species 0.000 claims 3
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 3
- 229920000161 Locust bean gum Polymers 0.000 claims 3
- 240000000907 Musa textilis Species 0.000 claims 3
- 235000005018 Pinus echinata Nutrition 0.000 claims 3
- 241001236219 Pinus echinata Species 0.000 claims 3
- 235000017339 Pinus palustris Nutrition 0.000 claims 3
- 239000004743 Polypropylene Substances 0.000 claims 3
- 239000004115 Sodium Silicate Substances 0.000 claims 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 3
- 229920001615 Tragacanth Polymers 0.000 claims 3
- 150000007513 acids Chemical class 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
- 239000004964 aerogel Substances 0.000 claims 3
- 235000010443 alginic acid Nutrition 0.000 claims 3
- 239000000783 alginic acid Substances 0.000 claims 3
- 229920000615 alginic acid Polymers 0.000 claims 3
- 229960001126 alginic acid Drugs 0.000 claims 3
- 235000012211 aluminium silicate Nutrition 0.000 claims 3
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 claims 3
- 239000010905 bagasse Substances 0.000 claims 3
- 239000011324 bead Substances 0.000 claims 3
- 229920000704 biodegradable plastic Polymers 0.000 claims 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 3
- 229910052791 calcium Inorganic materials 0.000 claims 3
- 239000011575 calcium Substances 0.000 claims 3
- 235000009120 camo Nutrition 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 3
- 239000005018 casein Substances 0.000 claims 3
- 235000021240 caseins Nutrition 0.000 claims 3
- 239000004568 cement Substances 0.000 claims 3
- 235000005607 chanvre indien Nutrition 0.000 claims 3
- 229920001436 collagen Polymers 0.000 claims 3
- 229960005188 collagen Drugs 0.000 claims 3
- 230000000295 complement Effects 0.000 claims 3
- 239000007799 cork Substances 0.000 claims 3
- 201000010549 croup Diseases 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims 3
- 229920001249 ethyl cellulose Polymers 0.000 claims 3
- 239000011888 foil Substances 0.000 claims 3
- 239000005350 fused silica glass Substances 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- 239000008273 gelatin Substances 0.000 claims 3
- 239000003365 glass fiber Substances 0.000 claims 3
- 239000003292 glue Substances 0.000 claims 3
- 150000004676 glycans Polymers 0.000 claims 3
- 239000010439 graphite Substances 0.000 claims 3
- 229910002804 graphite Inorganic materials 0.000 claims 3
- 235000010417 guar gum Nutrition 0.000 claims 3
- 239000000665 guar gum Substances 0.000 claims 3
- 229960002154 guar gum Drugs 0.000 claims 3
- 239000010440 gypsum Substances 0.000 claims 3
- 229910052602 gypsum Inorganic materials 0.000 claims 3
- 239000011121 hardwood Substances 0.000 claims 3
- 239000011487 hemp Substances 0.000 claims 3
- 235000012765 hemp Nutrition 0.000 claims 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims 3
- 238000009413 insulation Methods 0.000 claims 3
- 235000010494 karaya gum Nutrition 0.000 claims 3
- 239000004816 latex Substances 0.000 claims 3
- 239000006028 limestone Substances 0.000 claims 3
- 235000010420 locust bean gum Nutrition 0.000 claims 3
- 239000000711 locust bean gum Substances 0.000 claims 3
- 235000012766 marijuana Nutrition 0.000 claims 3
- 229920000609 methyl cellulose Polymers 0.000 claims 3
- 239000001923 methylcellulose Substances 0.000 claims 3
- 235000010981 methylcellulose Nutrition 0.000 claims 3
- 239000010445 mica Substances 0.000 claims 3
- 229910052618 mica group Inorganic materials 0.000 claims 3
- 239000004005 microsphere Substances 0.000 claims 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 3
- 229920000058 polyacrylate Polymers 0.000 claims 3
- 239000004584 polyacrylic acid Chemical class 0.000 claims 3
- 229920001155 polypropylene Polymers 0.000 claims 3
- 229920001282 polysaccharide Polymers 0.000 claims 3
- 239000005017 polysaccharide Substances 0.000 claims 3
- 150000004804 polysaccharides Polymers 0.000 claims 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims 3
- 239000011118 polyvinyl acetate Substances 0.000 claims 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims 3
- 239000004800 polyvinyl chloride Substances 0.000 claims 3
- 239000008262 pumice Substances 0.000 claims 3
- 239000004576 sand Substances 0.000 claims 3
- 239000000377 silicon dioxide Substances 0.000 claims 3
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 claims 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims 3
- 239000007921 spray Substances 0.000 claims 3
- 229920001059 synthetic polymer Polymers 0.000 claims 3
- 239000001993 wax Substances 0.000 claims 3
- VUKAUDKDFVSVFT-UHFFFAOYSA-N 2-[6-[4,5-bis(2-hydroxypropoxy)-2-(2-hydroxypropoxymethyl)-6-methoxyoxan-3-yl]oxy-4,5-dimethoxy-2-(methoxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)-5-methoxyoxane-3,4-diol Chemical compound COC1C(OC)C(OC2C(C(O)C(OC)C(CO)O2)O)C(COC)OC1OC1C(COCC(C)O)OC(OC)C(OCC(C)O)C1OCC(C)O VUKAUDKDFVSVFT-UHFFFAOYSA-N 0.000 claims 2
- 229920000945 Amylopectin Polymers 0.000 claims 2
- WMGFVAGNIYUEEP-WUYNJSITSA-N Amylopectin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](OC[C@@H]2[C@H]([C@H](O)[C@@H](O)[C@@H](O[C@@H]3[C@H](O[C@H](O)[C@H](O)[C@H]3O)CO)O2)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H]1O WMGFVAGNIYUEEP-WUYNJSITSA-N 0.000 claims 2
- 229920000856 Amylose Polymers 0.000 claims 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 2
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 229920002678 cellulose Polymers 0.000 claims 2
- 239000001913 cellulose Substances 0.000 claims 2
- 235000010980 cellulose Nutrition 0.000 claims 2
- 229920000591 gum Polymers 0.000 claims 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims 2
- 239000002648 laminated material Substances 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- 239000010451 perlite Substances 0.000 claims 2
- 235000019362 perlite Nutrition 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 229920002635 polyurethane Polymers 0.000 claims 2
- 239000004814 polyurethane Substances 0.000 claims 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 2
- 239000010455 vermiculite Substances 0.000 claims 2
- 235000019354 vermiculite Nutrition 0.000 claims 2
- 229910052902 vermiculite Inorganic materials 0.000 claims 2
- ZTHKPSBRWLGUIK-XORBCWOASA-N (2R,3R,4S,5S,6R)-2-[(2R,3S,4R,5R,6S)-6-[[(2R,3S,4R,5R,6R)-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-[(2R,3S,4R,5R,6R)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2R,3S,4R Chemical class O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](OC[C@@H]2[C@H]([C@H](O)[C@@H](O)[C@@H](O[C@@H]3[C@H](O[C@H](O[C@@H]4[C@H](O[C@H](O)[C@H](O)[C@H]4O)CO)[C@H](O)[C@H]3O)CO)O2)O[C@@H]2[C@@H]([C@@H](O)[C@H](O[C@@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)[C@@H](CO)O2)O)[C@H](O)[C@H]1O ZTHKPSBRWLGUIK-XORBCWOASA-N 0.000 claims 1
- 244000215068 Acacia senegal Species 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims 1
- 229920002085 Dialdehyde starch Polymers 0.000 claims 1
- 229920000084 Gum arabic Polymers 0.000 claims 1
- 229920000877 Melamine resin Polymers 0.000 claims 1
- 235000010489 acacia gum Nutrition 0.000 claims 1
- 239000000205 acacia gum Substances 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
- 150000007974 melamines Chemical class 0.000 claims 1
- 229920001592 potato starch Polymers 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Abstract
Sealable, liquid-tight containers (10) and methods for economically manufacturing such containers for storing and dispensing substances and any other purposes for which conventional sealable, liquid-tight containers are utilized. The containers are readily and economically formed from inorganically filled mixtures comprising a water-dispersible organic polymer binder, aggregate fillers, fibers, and water. Alternatively, such containers are formed from high starch-containing compositions which optionally include inorganic fillers up to about 90 %. Such compositions can be directly molded, formed into wet sheets and then molded, formed into dry sheets and then reformed, or extruded into the container components. The containers or components thereof may optionally be coated, lined, laminated, and/or receive printing.
Claims
AMENDED CLAIMS
[received by the International Bureau on 30 September 1997 (30.09 97); original claims 1-3 amended; new claims 4-225 added (20 pages)]
1 An article of manufacture comprising a sealable container having a liquid - tight barrier, at least a substantial poπion of the sealable container comprising an inorganically filled matπx molded from an inorganically filled mixture, the inorganicaliv filled mixture including ϊ water; an organic polymer binder selected from the group consisting of polysaccharides. proteins, and mixtures or derivatives thereof, an inorganic aggregate filler having a concentration in a range from about 20% to about 90% by weight of solids within the mixture; and ) o a fibrous material, wherein the fibrous material is substantially homogeneously dispersed throughout the inorganically filled matrix, wherein the inorganically filled matπx includes organic components in an amount of at least about 5% by weight of solids withm the inorganically filled matrix, and wherem the inorganically filled matπx has a thickness less than about 1 15 cm
2. An aπicle of manufacture comprising a scalable container having a liquid- tight barrier, at least a substantial portion of the sealable container comprising a sheet having an inorganically filled matrix, the matrix including: an organic polymer binder selected from the group consisting of 20 polysaccharides, proteins, and mixtures or derivatives thereof, an inorganic aggregate filler having a concentration in a range from about 20% to about 90% by weight of solids in the inorganically filled matrix; and a fibrous material substantially homogeneously dispersed throughout the inorganically filled matπx, 25 wherein the inorganically filled matrix includes organic components in an amount of at least about 5% by weight of solids within the inorganically filled matrix, and wherein the inorganically filled matrix has a thickness less than about 5 mm
3. An article of manufacture compnsing a sealable container having a liquid- tight bamer, at least a substantial portion of the sealable container comprising a starch-
30 bound sheet, (he starch-bound sheet comprising. a binding matrix including starch in an amount in a range from aoout 5% to about 90% by weight of solids in the starch-bound sheet and a cellulosic ether in an amount in a range from about 0 5% to about 10% by weight of solids in the starch-bound sheet,
35 fibers in an amount in a range from about 3% to about 40% by weight of
AMENDED SHEET (ARηCLE 19)
solids in the starch-bound sheet, and optionally an inorganic filler in an amount in a range from 0% to about 90% bv weight of solids in the starch-bound sheet, wherein the starch-bound sheet has a thickness less than about 1 cm and a density greater than about 0 5 g/cmJ
4 An article of manufacture as defined in claim 1 , wherein the water is included in an amount in a range from about 5% to about 80% by weight of the inorganically filled mixture
5 An article of manufacture as defined in claim I , wherein the water is included in an amount tn a range from about ! 0% to about 70% by weight of the inorganically filled mixture
6 An article of manufacture as defined in claim 1 , wherein the water is included in an amount in a range from about 20% to about 50% by weight of the inorganically filled mixture 7 An article of manufacture as defined in claim 1 , wherein the organic polymer binder is included in an amount in a range from about 1% to about 60% by weight of solids in the inorganically filled mixture
8 An article of manufacture as defined in claim 1, wherein the organic polymer binder is included in an amount in a range from about 2% to about 30% by weight of solids in ihc inorganically filled mixture
9 An article of manufacture as defined in claim 1, wherem the organic polymer binαcr is included in an amount in a range from about 5% to about 20% by weight of solids in the inorganically filled mixture.
10 An article of manufacture as defined in claim 1. wherein the organic polymer binder comprises a cellulosic material selected from the group consisting of rnethylhydroxyethylccltulose, hydroxyrnethylethyicellulose, carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxyethylpropylcellulose, and mixtures or deπvatives thereof
11 An article of manufacture as defined in claim 1 , wherein the organic polymer binder comprises a starch-based mateπaJ selected from the group consisting of amylopectin. amylose. seagel starch acetates, starch hydroxyethyl ethers, ionic starches long-chain alkylstarches, dextπnes, amine starches, phosphate starches, dialdehyde starcnes, ana mixtures or deπvatives thereof
12 An aπiclc of manufacture as defined in claim 1 wherein the organic polymer binder compnses a protein-based mateπal selected from the group consisting of
prolamme. collagen, gelatin, glue, casein, and mixtures or deπvatives thereof
13 An article of manufacture as defined in claim 1, wherein the organic polymer binder compπses a polysaccharide selected from the group consisting of alginic acid, phycocolloids, agar, gum arabic, guar gum, locust bean gum, gum karaya, gum tragacanth. and mixtures or deπvatives thereof
14 An article of manufacture as defined in claim 1 , wherein the inorganically filled mixture further includes a synthetic organic polymer
15 An article of manufacture as defined in claim 14, wherein the synthetic organic polymer is selected from the group consisting of polyvinyl pyrrolidone, polyethylene glycol, polyvinyl alcohol, polyvtnylmethyl ether, polyacrylic acids, polyacrylic acid salts, polyvinylacrylic acids, polyvinylacrylic acid salts, polyacrylimidcs, polylactic acid, ethylene oxide polymers, synthetic clay, latex, and mixtures or deπvatives thereof
16 An article of manufacture as defined in claim 1 , wherein the inorganic aggregate filler is included in an amount in a range from about 20% to about 80% by weight of solids in the inorganically filled mixture
17 An article of manufacture as defined in claim 1, wherein the inorganic aggregate filler is included in an amount in a range from about 30% to about 70% by weight of solids in the inorganically filled mixture.
18 An article of manufacture as defined in claim 1 , wherein the inorganic aggregate filler comprises individual particles that are size optimized in order to achieve a predetermined particle packing density ofthe inorganic aggregate filler
19 An article of manufacture as defined in claim 1 , wherein the inorganic aggregate filler compnses a lightweight aggregate which reduces the density and increases the insulation ability ofthe inorganically filled matrix. 20 An article of manufacture as defined in claim 19, wherein the lightweight aggregate is selected from the group consisting of perlite, vermiculite, hollow glass spheres, porous ceramic spheres, xonotltte, aerogels, xerogels, tabular alumina, expanded clay, lightweight expanded geologic materials, pumice, microspheres, and mixtures thereof 21 An article of manufacture as defined in claim 1, wherein the inorganic aggregate is selected from the group consisting of clay, gypsum, calcium carbonate, mica, silica, fused silica, alumina, metals, sand, gravel, sandstone, limestone, hydrated cement panicles, calcium aluminate, glass beads, and mixtures thereof
22 An article of manufacture as defined in claim 1, wherein the inorganically filled mixture further includes an organic aggregate selected from the group consisting of
seeds, starches, gelatins, polymers, cork, agar materials, plastic spheres and mixtures or deπvatives thereof
23 An article of manufacture as defined in claim 1 wherein the inorganically filled mixture further includes a hydraulically settable mateπal 24 An article of manufacture as defined in claim 1 wherein the fiorous mateπal is included in an amount in a range from about 0 5% to about 60% by weight of solids in the inorganically filled mixture
25 An article of manufacture as defined in claim 1 , wherein the fibrous mateπai is included in an amount in a range from about 2% to about 40% by weight of solids in the inorganically filled mixture
26 An article of manufacture as defined in claim 1 , wherein the fibrous mateπal is included in an amount in a range from about 5% to about 20% by weight of solids in the inorganicaliv filled mixture
27 An article of manufacture as defined in claim I wherem the fibrous material comprises natural organic fibers
28 An article of manufacture as defined in claim 27, wherein the natural organic fibers are selected from the group consisting of hemp fibers, sisal fibers, cotton fibers, bagasse fibers, abaca fibers, flax fibers, southern pine fibers, southern hardwood fibers, and mixtures thereof 29 An article of manufacture as defined in claim 1 , wherein the fibrous mateπal compnses inorganic fibers.
30 An article of manufacture as defined in claim 29, wherein the inorganic fibers are selected from the group consisting of glass fibers, silica fibers, ceramic fibers, graphite fibers, metal fibers, and mixtures thereof 31 An article of manufacture as defined in claim 1 , wherein the fibrous mateπal comprises synthetic organic fibers
32 An article of manufacture as defined in claim 31 , wherein the synthetic organic fibers are selected from the group consisting of plastic fibers, polyaramide fibers, polylactic acid fibers, polyethylene fibers, polypropylene fibers, and mixtures thereof 33 An article of manufacture as defined in claim 1, wherein the fibrous mateπal compπses individual fibers having an aspect ratio greater than about 10 1
34 An article of manufacture as defined in claim 1, wherein the fibrous mateπal comprises individual fibers having an aspect ratio greater than about 100 1 mateπal includes continuous fibers 35 An article of manufacture as defined in claim 1 wherein the fibrous
mateπal includes continuous fibers
36 An article of manufacture as defined in ciaim 35. wherein the continuous fibers are wrapped around ihe inorganically filled matrix of the sealable container
37 An article of manufacture as defined in claim 35, wherein the continuous fibers are emDcddcd within the inorganically filled matπx of the sealable container
38 An article of manufacture as defined in claim 35, wherein the continuous fibers are spiral wound
39 An article of manufacture as defined in claim I , wherein the fibrous material is selected from the group consisting of a fibrous mesh, mat, and fabnc. 40 An article of manufacture as defined in claim 1 , wherein the inorganically filled maiπx has a thickness less than about 5 mm
41 An article of manufacture as defined in claim 1 , wherein the inorganically filled matπx nas a thickness less than about 3 mm.
42 An article of manufacture as defined in claim 1 , wherein the inorganically filled matπx has a thickness less than about I mm
43 An article of manufacture as defined in claim 1, wherem the liquid-tight bamer is pressure-tight, wherein the sealable container has an interior and an extenor, and wherem the inorganically filled matrix can withstand a differential in pressure between the interior and the extenor ofthe sealable container of up to about 10 MPa of pressure. 44. An article of manufacture as defined in claim 1 , further including a coating on at least a portion of a surface ofthe inorganically filled matrix ofthe sealable container
45 An article of manufacture as defined in claim 44, wherein the coating renders (he poπion of the inorganically filled matrix impermeable to gases.
46 An article of manufacture as defined in claim 44, wherein the coating renders the portion ofthe inorganically filled matrix impermeable to liquids.
47 An article of manufacture as defined in claim 44, wherein the coating strengthens the portion of the inorganically filled matrix.
48 An article of manufacture as defined in claim 44, wherein the coating is selected from the group consisting of sodium silicate, orthosiiicates, siloxanes, colloidal silica tn organic polymer dispersions, colloidal silica in films, colloidal silica in fibers, caicium carbonate, kaolin clay, ceramics, and mixtures thereof
49 An article of manufacture as defined in claim 44, wherem the coating is selected from the group consisting of biodegradable plastics, acrylics, polyacrylates, polyurethanes. melamines. polyethylene, synthetic polymers, hydroxypropylmethyl- cellulose, cthvlcellulose. polyethylene glycol, prolaminc, polyvinyl chloride, polyvinyl
alcohol, polyvinyl acetate, polylactic acid, waxes, and mixtures thereof
50 An article of manufacture as defined in claim I , further including a liner on at least a portion of a surface of the inorganically filled matrix of the scalable container
5 1 An article of manufacture as defined in claim 50, wherein the liner compnses blow-molded glass
52 An article of manufacture as defined in claim 1, further including a laminated material on at least a portion of a surface ofthe inorganically filled matπx of the sealable container
53. An article of manufacture as defined in claim I , wherein the sealable container comprises a can,
54 An article of manufacture as defined in claim I , wherein the sealable container comprises a carton
55 An article of manufacture as defined in claim I , wherein the sealable container comprises a box 56 An article of manufacture as defined in claim I, wherein the sealable container comprises a bottle
57 An article of manufacture as defined in claim 1 , wherein the sealable container comprises ajar.
58 An article of manufacture as defined in claim 1 , wherein the sealable container compnses a pouch
59 An article of manufacture as defined in claim I , wherein the sealable container has a circular cross-section.
60 An article of manufacture as defined in claim 1 , wherein the seaiable container has a rectangular cross-section 61. An article of manufacture as defined in claim 1 , wherein the sealable container has a square-shaped cross-section.
62. An article of manufacture as defined in claim I , wherein the sealable container has an oval-shaped cross-section.
63 An article of manufacture as defined in claim 1 , wherein at least a portion of the inorganically filled matπx ofthe sealable container is hinged
64 An article of manufacture as defined in ciaim 1 , wherein the sealable container has structural components compnsmg a hollow body portion having side walls connected to a bottom portion and an open end; and a closure means for engaging the open end of the hollow body portion to
86
seal substances within the sealable container.
65 An article of manufacture as defined in claim 1. wherein the sealable container has structural components comprising. a hollow body portion having side walls connected to a bottom portion and an open end, and a closure means for engaging the open end of the hollow body portion to seal substances within the scalable container, for dispensing substances, and for rcsealing substances within the sealable container.
66. An article of manufacture as defined in claim 1, wherein the sealable container has structural components comprising. a hollow body portion having side walls connected to a bottom portion and an open end: and a closure means for engaging the open end ofthe hollow body portion to seal substances within the sealable container and for dispensing substances. 67 An article of manufacture as defined in claim 66, wherein the bottom portion of the hollow body portion comprises a material selected from the group consisting of metals, glass, plastics, and paper composites.
68. An article of manufacture as defined in ciaim 66, wherein the side walls of the hollow body portion compπse a material seieαed from the group consisting of metals, glass, plastics, and paper composites.
69 An article of manufacture as defined in claim 66, wherein the closure means comprises a material selected from the group consisting of metals, glass, plastics, and paper composites
70. An article of manufacture as defined in claim 66, wherein the bottom portion of the hollow body portion and the side walls of the hollow body portion are integrally formed together.
71. An article of manufacture as defined in claim 66, wherein the closure means compπses a lid.
72. An article of manufacture as defined in claim 66, wherein the closure means comprises a foil covering
73. An article of manufacture as defined in claim 66. wherein the closure means compπses a top having a conical portion and a nozzle portion, and a cap. 74 An article of manufacture as defined in claim 73, wherein the cap has
internal threads and the nozzle portion of the top has complementary external threads configured to engage the internal threads of the cap to create a seal.
75 An article of manufacture as defined in claim 73, wherein the cap is a cnmped bottle cap. 76. An article of manufacture as defined in claim 66. wherein the closure means compπses a flat cover and a pulltab
77. An article of manufacture as defined in claim 66, wherein the closure means comprises a top and a spray mechanism
78. An article of manufacture as defined in claim 2, wherein the organic polymer binder is included in an amount in a range from about 1 % to about 60% by weight of solids in the inorganically filled matrix.
79. An article of manufacture as defined in claim 2, wherein the organic polymer binder is included in an amount in a range from about 2% to aϋout 30% by weight of solids in the inorganically filled matrix. 80 An article of manufacture as defined in claim 2, wherein the organic polymer binder is included in an amount in a range from about 5% to about 20% by weight of solids in the inorganically filled matrix.
81 . An article of manufacture as defined in claim 2, wherein the organic polymer binder comprises a cellulosic material selected from the group consisting of methylhydroxyethylcellulose, hydroxymethylcthylcellulose, carboxymethylcellulose, methylcellulose, ethylcellulose. hydroxyethylcellulose, hydroxyethylpropylcellulose, and mixtures or derivatives thereof.
82. An article of manufacture as defined in claim 2, wherein the organic polymer binder comprises a starch-based material selected from the group consisting of amylopectin, amylose, seagel, starch acetates, starch hydroxyethyl ethers, ionic starches, long-chain alkyistarches, dextπnes, amine starches, phosphate starches, dialdehyde starches, and mixtures or derivatives thereof.
83. An article of manufacture as defined in claim 2, wherein the organic polymer binder comprises a protein-based material selected from the group consisting of prolaminc, collagen, gelatin, glue, casein, and mixtures or derivatives thereof.
84. An article of manufacture as defined in claim 2, wherein the organic polymer binder comprises a polysacchande selected from the croup consisting of alginic acid, phycocolloids, agar, gum arable, guar gum. locust bean gum, gum karaya, gum tragacanth, and mixtures or denvatives thereof. 85 An article of manufacture as defined Ln claim 2, wherein the inorganically
88
filled mixture further includes a synthetic organic polymer
86 An article of manufacture as defined in claim 85, wherein the synthetic organic polymer is selected from the yroup consisting of polyvinyl pyrrolidone, polyethvtene glycol, polyvinyl alcohol, polyvmylmcthyl ether, polyacrylic acids, polyacrylic acid salts, polyvinylacrylic acids, polyvinylacrylic acid salts, polyacrylimides, polylactic acid, cthvlene oxide polymers, synthetic clay, latex, and mixtures or deπvatives thereof
87 An article of manufacture as defined m claim 2, wherein the inorganic aggregate filler is included in an amount in a ranee from about 20% to about 80% by weight of solids in the inorganically filled matnx 88 An article of manufacture as defined in claim 2, wherein the inorganic aggregate filler is included in an amount in a range from about 30% to about 70% by weight of solids in the inorganically filled matπx.
89 An article of manufacture as defined in claim 2, wherein the inorganic aggregate filler compπses individual particles that are size optimized in order to achieve a predetermined particle packing density ofthe inorganic aggregate filler.
90 An article of manufacture as defined in ciaim 2, wherein the inorganic aggregate filler comprises a lightweight aggregate which reduces the density and increases the insulation ability ofthe inorganically filled matπx
91 An article of manufacture as defined in claim 90, wherein the lightweight aggregate is selected from the group consisting of periite, vermiculitc, hollow glass spheres, porous ceramic spheres, xonotbte, aerogels, xerogels, tabular alumina, expanded clay, lightweight expanded geologic materials, pumice, microspheres, and mixtures thereof
92 An article of manufacture as defined in ciaim 2, wherein the inorganic aggregate is selected from the group consisting of clay, gypsum, calcium carbonate, mica, silica, fused silica, alumina, metals, sand, gravel, sandstone, limestone, hydrated cement particles, calcium aluminate, glass beads, and mixtures thereof.
93 An article of manufacture as defined in claim 2, wherein the inorganically filled matrix further includes an organic aggregate selected from the group consisting of seeds starches, gelatins, polymers, cork, agar mateπals, plastic spheres, and mixtures or deπvatives thereof
94 An article of manufacture as defined in claim 2, wherein the inorganically filled matπx further includes a hydraulically settable material
95 An article of manufacture as defined in claim 2, wherein the fibrous mateπal is included in an amount m a range from about 0 5% to aoout 60% by weight of
89
solids in the inorganically filled matπx
96 An article of manufacture as defined in claim 2, wherein the fibrous mateπal is included in an amount in a range from about 2% to about 40% by weight of solids in the inorganically filled matπx 97 An article of manufacture as defined in claim 2, wherein the fibrous material is included in an amount in a range from about 5% to about 20% by weight of solids in the inorganically filled matπx.
98 An article of manufacture as defined in claim 2, wherein the fibrous material comprises natural organic fibers 99 An article of manufacture as defined in claim 98, wherein the natural organic fibers are selected from the group consisting of hemp fibers, sisal fibers, cotton fibers, bagasse fibers, abaca fibers, flax fibers, southern pine fibers, southern hardwood fibers, and mixtures thereof
100 An article of manufacture as defined in claim 2, wherein the fibrous mateπal comprises inorganic fibers
101 An article of manufacture as defined in claim 100, wherein the inorganic fibers arc selected from the group consisting of glass fibers, silica fibers, ceramic fibers, graphite fibers, metal fibers, and mixtures thereof
102 An article of manufacture as defined in ciaim 2, wherein the fibrous material compnses synthetic organic fibers
103 An article of manufacture as defined in claim 102, wherein the synthetic organic fibers are selected from the group consisting of plastic fibers, polyaramide fibers, polylactic acid fibers, polyethylene fibers, polypropylene fibers, and mixtures thereof
104 An article of manufacture as defined in claim 2, wherein the fibrous material compπses individual fibers having an aspect ratio greater than about 10; 1
105 An article of manufacture as defined in claim 2, wherein the fibrous matenal comprises individual fibers having an aspect ratio greater than about 100: 1
106 An article of manufacture as defined in claim 2, wherein the fibrous material includes continuous fibers 107 An article of manufacture as defined in claim 106, wherein the continuous fibers are wrapped around the inorganically filled matrix of the sealable container
108 An article of manufacture as defined in claim 106, wherein the continuous fibers are embedded within the inorganically filled matnx of the sealable container
109 An article of manufacture as defined in claim 106 wherein the continuous fibers are spiral wound
90
1 10 An article of manufacture as defined in claim 2, wherein the fibrous material is selected from the croup consisting of a fibrous mesh, mat, and fabnc
1 1 1 .An article of manufacture as defined in claim 2, wherein the inorganically filled matrix has a thickness less than about 3 mm 1 12 An aπicle of manufacture as defined in claim 2. wherein the inorganically filled matπx has a thickness less than about I mm
1 13 An article of manufacture as defined in claim 2, wherein the liquid-tight bamer is pressure-tight, wherein the scalable container has an inteπor and an extenor, and wherein the inorganically filled matπx can withstand a differential in pressure between the inteπor and the exterior ofthe sealable container of up to about 10 MPa of pressure
1 14 An article of manufacture as defined in claim 2, further including a coating on at least a portion of a surface ofthe inorganically filled matπx ofthe scalable container
1 15 An article of manufacture as defined in claim 1 14, wherein the coating renders the portion ofthe inorganically filled matnx impermeable to gases 1 16 An article of manufacture as defined in claim 114, wherein the coating renders the ponton ofthe inorganically filled matrix impermeable to liquids.
117 An article of manufacture as defined in claim 1 14, wherein the coating strengthens the portion ofthe inorganically filled matrix
118 An article of manufacture as defined in claim 114, wherein the coating is selected from the group consisting of sodium silicate, orthosiiicates, siloxanes, colloidal silica in organic polymer dispersions, colloidal silica in films, colloidal silica in fibers, calcium carbonate, kaolin clay, ceramics, and mixtures thereof
1 19 An article of manufacture as defined in claim 114, wherein the coating is selected from the group consisting of biodegradable plastics, acrylics, polyacrylates, polyurethanes, mclaminεs, polyethylene, synthetic polymers, hydroxypropylmethyl- cellulose, cthylcellulose, polyethylene glycol, prolamine, polyvinyl chloride, polyvinyl alcohol, polyvinyl acetate, polylactic acid, waxes, and mixtures thereof
120 An article of manufacture as defined in claim 2, further including a liner on at least a portion of a surface ofthe inorganically filled matπx ofthe sealable container 121 An article of manufacture as defined in claim 120, wherein the liner comprises blow-molded glass
122 An article of manufacture as defined in claim 2, further including a laminated mateπal on at least a portion of a surface ofthe inorganically filled matπx ofthe sealable container 123 An article of manufacture as defined in ciaim 2, wherein the sealable
container compnses a can
124 An article of manufacture as defined in claim 2. wherein the scalable container comoπses a carton
125 An article of manufacture as defined in claim 2. wherein the sealable > container compπses a box
126 An article of manufacture as defined in claim 2. wherein the sealable container comprises a bottle
127 An article of manufacture as defined in claim 2, wherein the sealable container compπses ajar 0 128 An article of manufacture as defined m claim 2. wherein the sealable container compnses a pouch
129 An article of manufacture as defined in claim 2, wherein the sealable container has a circular cross-section.
130 An article of manufacture as defined in claim 2, wherein the sealable ! 5 container has a rectangular cross-section
131 An article of manufacture as defined in ciaim 2, wherein the sealable container has a square-shaped cross-section
132 An article of manufacture as defined in claim 2. wherein the sealable container has an oval-shaped cross-section.
20 133 An article of manufacture as defined in claim 2, wherein at least a portion ofthe inorganically filled matrix of the sheet is hinged
134 An article of manufacture as defined in claim 2, wherem the sealable container has structural components comprising: a hollow body portion havmg side walls connected to a bottom portion and 25 an open end; and a closure means for engaging the open end of the hollow body portion to seai substances within the sealable container.
135 An article of manufacture as defined in claim 2, wherein the sealable container has structural components compnsmg:
30 a hollow body ponton having side walls connected to a bottom portion and an open end; and a closure means for encaging the ooen end of the hollow body portion to seal substances within the scalable container, for dispensing substances, and for rescaling substances within the sealable container 35 136 An article of manufacture as defined in ciaim 2. wnerein the sealable
container has structural components compnsmg a hollow body portion having side walls connected to a bottom poπion and an open end, and a closure means for engaging the open end of the hollow body portion to seal substances within the sealable container and for dispensing substances
137 An article of manufacture as defined in claim 136, wherein the bottom portion of the hollow body portion comprises a matenal selected from the group consisting of metals, glass, plastics, and paper composites
138 An article of manufacture as defined in claim 136, wherein the side walls of the hollow body portion compπse a matenal selected from the group consisting of metals, glass, plastics, and paper composites.
139 An article of manufacture as defined in claim 136, wherein the closure means comprises a mateπal selected from the group consisting of metals, glass, plastics and paper composites 140 An article of manufacture as defined in claim 136, wherein the bottom portion of the hollow body portion and the side walls of the hollow body portion are integrally formed together
141 An article of manufacture as defined in claim 136, wherein the closure means compπses a lid 142 An article of manufacture as defined in claim 136, wherein the closure means compπses a foil covering
143 An article of manufacture as defined in claim 136, wherein the closure means compnses a top having a conical portion and a nozzle portion, and a cap
144 An article of manufacture as defined in claim 143, wherein the cap has internal threads and the nozzle portion of the top has complementary external threads configured to engage the internal threads ofthe cap to create a seal
145 An article of manufacture as defined in claim 143, wherem the cap is a cπmped bottle cap
146 An article of manufacture as defined in claim 136, wherein the closure means comprises a fiat cover and a pulltab
147 An article of manufacture as defined in claim 136, wherein the closure means compπses a top and a spray mechanism 148 An article of manufacture as defined in claim 2, wherein the sheet has been
spiral wound to form the portion of the sealable container
149 An article of manufacture as defined in claim 2, wherein the sheet has been rolled to form the portion of the sealable container
150 An article of manufacture as defined in claim 2, wherein the sheet has been folded to form the portion of the scalable container
151 An article of manufacture as defined in claim 3, wherein the starch is included in an amount in a range from about 15% to about 75% by weight of solids in the siarch-bound sheet
152 An article of manufacture as defined in claim 3, wherein the starch is included in an amount tn a range from about 30% to about 70% by weight of solids in the starch-bound sheet
153 An article of manufacture as defined in claim 3, wherein the starch compπses unmodified potato starch
154 An article of manufacture as defined in claim 3, wherein the starch compnses unmodified com starch.
155 An article of manufacture as defined in ciaim 3, wherein the starch comprises unmodified waxy corn starch
156 An article of manufacture as defined in claim 3, wherein the cellulosic ether is included in an amount in a range from about 1% to about 5% by weight of solids in the starch-bound sheet
157 An article of manufacture as defined in ciaim 3, wherein the cellulosic ether is included in an amount in a range from about 2% to about 4% by weight of solids in the starch-bound sheet
158 An article of manufacture as defined in claim 3, wherein the cellulosic ether is selected from the group consisting of methylhydroxyethylcellulose, hydroxymethyiethyl- cellulose, carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxyethylpropylcellulose, and mixtures or deπvatives thereof
159 An article of manufacture as defined in claim 3, wherein the binding matnx further includes a protein-based material selected from the group consisting of proiamine, collagen, gelatin, glue, casein and mixtures or deπvatives thereof.
160 An article of manufacture as defined in claim 3, wherein the binding matrix further includes a polysacchaπde selected from the group consisting of alginic acid, phycocolloids. agar, gum arabjc, guar gum, locust bean gum, gum karaya, gum tragacanth, and mixtures or derivatives tnereof 161 An article of manufacture as defined in claim 3, wherein the binding matπx
94
further includes a synthetic organic polymer
162 An article of manufacture as defined in claim 161 , wherein the synthetic organic polymer is selected from the group consisting of polyvinyl pynolidonc, polyethylene glycol, polyvinyl alcohol, polyvinyimethyl ether, polyacrylic acids, polyacrylic acid salts, polyvinylacrylic acids, polyvinylacrylic acid salts, polyacrylimides. polylactic acid, ethylene oxide polymers, synthetic clay, latex, and mixtures or deπvanves thereof
163 An article of manufacture as defined in claim 3, wherein the inorganic aggregate filler is included in an amount in a range from about 20% to about 80% by weight of solids in the starch-bound sheet 164 An article of manufacture as defined in claim 3, wherein the inorganic aggregate filler is included in an amount in a range from about 30% to about 70% by weight of solids in the starch-bound sheet
165 An article of manufacture as defined in claim 3, wherem the inorganic aggregate filler comprises a lightweight aggregate which reduces the density and increases the insulation ability of the starch-bound sheet.
166 An article of manufacture as defined in claim 165, wherein the lightweight aggregate is selected from the group consisting of perlite, vermiculite, hollow glass spheres, porous ceramic spheres, xonothte, aerogels, xerogels, tabular alumina, expanded clay, lightweight expanded geologic materials, pumice, microspheres, and mixtures thereof.
167 An article of manufacture as defined tn claim 3, wherein the inorganic aggregate is selected from the group consisting of clay, gypsum, calcium carbonate, mica, silica, fused silica, alumina, metals, sand, gravel, sandstone, limestone, hydrated cement particles, calcium aluminate, glass beads, and mixtures thereof. 168 An article of manufacture as defined in claim 3, wherein the starch-bound sheet further includes an organic aggregate selected from the group consisting of seeds, starches, gelatins, polymers, cork, agar materials, plastic spheres, and mixtures or denvatives thereof.
169 An article of manufacture as defined in claim 3, wherein the starch-bound ' sheet further includes a hydraulically settable material
170 An article of manufacture as defined in claim 3, wherein the fibrous mateπal is included in an amount in a range from about 5% to about 30% by weight of solids in the starch-bound sheet
171 An article of manufacture as defined in claim 3, wherein the fibrous material is included in an amount in a range from about 7% to about 20% by weight of
solids in the starch-bound sheet
172 An article of manufacture as defined in claim 3, wherein the fibrous mateπal comprises natural organic fibers
173 An article of manufacture as defined in claim 172, wherein the natural organic fibers are selected from the group consisting of hemp fibers, sisal fibers cotton fibers, bagasse fibers, abaca fibers, flax fibers, southern pine fibers, southern hardwood fibers, and mixtures thereof
174 An article of manufacture as defined in claim 3, wherein the fibrous mateπal compπses inorganic fibers 175 An article of manufacture as defined in claim 174, wherein the inorganic fibers are selected from the group consisting of glass fibers, silica fibers, ceramic fibers, graphite fibers, metal fibers, and mixtures thereof
176 An article of manufacture as defined m claim 3, wherein the fibrous mateπal compnses synthetic organic fibers 177 An article of manufacture as defined in claim 176, wherein the synthetic organic fibers are selected from the group consisting of plastic fibers, polyaramide fibers, polylactic acid fibers, polyethylene fibers, polypropylene fibers, and mixtures thereof
178 An article of manufacture as defined in claim 3, wherein the fibrous material compπses individual fibers having an aspect ratio greater than about 10 I 179 An article of manufacture as defined in claim 3, wherein the fibrous mateπal comprises individual fibers having an aspect ratio greater than about 100 1
180 An article of manufacture as defined tn claim 3, wherein the fibrous mateπal includes continuous fibers
181 An article of manufacture as defined in ciaim 180, wherein the continuous fibers are wrapped around the starch-bound sheet of the sealable container
182 An article of manufacture as defined in claim 180, wherein the continuous fibers are embedded within the starch-bound sheet ofthe sealable container
183 An article of manufacture as defined in claim 180, wherein the continuous fibers are spiral wound 184 An article of manufacture as defined in claim 3, wherein the fibrous material is selected from the group consisting of a fibrous mesh, mat, and fabric
185 An article of manufacture as defined in ciaim 3, wherein the starch-oound sheet has a thickness less than about 5 mm
186 An article of manufacture as defined in claim 3, wherem the starch-bound sheet has a thickness iess than about 3 mm
1 87 An aπicle ot manufacture as defineα in ciaim 3. wherein tne starch-bound sheet has a truckncss less than about I mm
1 88 An article of manufacture as denned in claim 3, wherem the liquid-tight barπcr is pressure-tight, wherein the scalable container has an tnteπor and an exterior, wnerein me starch-bound sheet can withstand a differential in pressure between the inteπor and the exterior of the scalable container of up to about 10 MPa of pressure
189 An article of manufacture as defined in claim 3, further including a coating on at least a portion of a surface of the starch-bound sheet of the sealable container.
190 An article of manufacture as defined in claim 189, wherein the coating renders the portion ofthe starch-bound sheet impermeable to gases
191 An article of manufacture as defined in claim 189, wherein the coating renders the poπion ofthe starch-bound sheet impermeable to liquids
192 An article of manufacture as defined in claim 189, wherein the coating strengthens the poπion of the starch-bound sheet 193 An article of manufacture as defined in claim 189, wherein the coating is selected from the group consisting of sodium silicate, orthosiiicates. siloxanes, colloidal silica in organic polymer dispersions, colloidal silica in films, colloidal silica in fibers, calcium carbonate, kaolin clay, ceramics, and mixtures thereof
194 An article of manufacture as defined in ciaim 189, wherein the coating is selected from the group consisting of biodegradable plastics, acrylics, polyacrylates, poiyurethanes. meiamines, polyethylene, synthetic polymers, hydroxypropylmεthyl- cellulose. ethylccllulose, polyethylene glycol, prolamine, polyvinyl chloride, polyvinyl alcohol, polyvinyl acetate, polylactic acid, waxes, and mixtures thereof.
195 An article of manufacture as defined in claim 3, further including a liner on at least a portion of a surface of the starch-bound sheet of the sealable container
196 An article of manufacture as defined in claim 195, wherein the liner compnses blow-molded glass
197 An article of manufacture as defined in claim 3, further including a laminated material on at least a portion of a surface of the starch-bound sheet of the sealable container.
198 An article of manufacture as defined in claim 3, wherein the sealable container comDπses a can
199 An article of manufacture as defined in ciaim 3. wherein the sealable container compπses a carton 200 An article of manufacture as defined in claim 3, wherein the sealable
container comrjπscs a box
201 An article of manufacture as derineα in claim 3 wherein the sealable container compπses a oottlc
202 An article of manufacture as defined in claim 3 wherein the sealable container compπses a jar
203 An article of manufacture as defined in claim 3 wherein the sealable container compπses a pouch
204 An article of manufacture as defined in claim 3 wherein the sealable container has a circular cross-section 205 An article of manufacture as defined in claim 3 wherein the sealable container has a rectangular cross-section
206 An article of manufacture as defined in claim 3, wherein the sealable container has a square-shaped cross-section
207 An article of manufacture as defined in claim 3, wherein the sealable container nas an oval-shaped cross-section
208 An article of manufacture as defined in claim 3, wherein at least a portion of the starch-bound sheet is hinged.
209 An article of manufacture as defined m claim 3 , wherein the sealable container has structural components comprising. a hollow body portion having side walls connected to a bottom portion and an open end, and a closure means for engaging the open end of the hollow body portion to seal substances within the sealable container
210 An article of manufacture as defined in claim 3 wherein the sealable container has structural components compnsmg a hollow body portion having side walls connected to a bottom portion and an open end, and a closure means for engaging the open end of the hollow body portion to seal substances within the sealable container, for dispensing substances, and for resealmg substances within the sealable container
21 1 An article of manufacture as defined in claim 3 wherein the scalable container has structural components compnstnc a hollow body portion having side wails connected to a bottom portion and an open end, and a closure means for encaging the open end of tne hollow body portion to
seal substances within the sealable container and for dispensing substances 212 An article of manufacture as defined in claim 21 1 , wherein the bottom
Dortion of the hollow body poπion comprises a mateπal selected from the croup consisting of metals, glass, plastics, and paper composites 213 An article of manufacture as defined in claim 21 1. wherein the side walls of the hollow body portion compπse a material selected from the group consisting of metals, glass, plastics, and paper composites
214 An article of manufacture as defined in claim 21 1, wherein the closure means compπses a material selected from the group consisting of metals, glass, plastics, and paper composites.
215 An article of manufacture as defined in ciaim 21 1 , wherein the bottom portion of the hollow body portion and the side walls of the hollow body portion are integrally formed together
216 An article of manufacture as defined in claim 21 1 , wherein the closure means comprises a lid.
217 An article of manufacture as defined in ciaim 21 1, wherein the closure means comprises a foil covering.
218 An article of manufacture as defined in claim 21 1, wherein the closure means comprises a top having a conical portion and a nozzle portion, and a cap.
219 An article of manufacture as defined in claim 218, wherein the cap has internal threads and the nozzle portion of the top has complementary external threads configured to engage the internal threads of the cap to create a seal 220 An article of manufacture as defined in ciaim 218, wherein the cap is a crimped bottle cap.
221 An article of manufacture as defined in claim 21 1 , wherein the closure means compnses a flat cover and a puiltab
222 An article of manufacture as defined in ciaim 21 1, wherein the closure means compπses a top and a spray mechanism
223 An article of manufacrure as defined in ciaim 3, wherein the starch-bound sheet has been spiral wound to form the poπion ofthe sealable container.
224 An article of manufacture as defined in claim 3, wherein the starch-bound sheet has been rolled to form the portion ofthe sealable container 225 An article of manufacture as defined in claim 3, wherein the starch-bound
sheet has been folded to form the portion of the scalable container.
STATEMENT UNDER ARTICLE 19
Please amend the claims in the above-identified application by cancelling sheets 78-80 of this application, and substitute therefor, sheets 78-98 attached hereto, which contain the new claims to be entered in this application. The abstract is found on substitute page 98 and is substantially identical to the abstract as originally filed with minor changes being made to comply with the textual changes made thereto in the Intemationai Search Report.
The amendments submitted herein are intended to correct obvious typographical errors and place this application into conformity with the amendments entered in the corresponding U.S. application No new matter has been introduced by these amendments Applicant believes that the amended claims submitted herewith more accurately and distinctly point out the inventive concepts Applicant wishes to claim.
Original claims 1, 2. and 3 are amended by this document, and claims 4 -225 are added
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97920072A EP0892717A1 (en) | 1996-04-09 | 1997-04-09 | Sealable containers comprising an inorganically filled matrix |
BR9710427A BR9710427A (en) | 1996-04-09 | 1997-04-09 | Sealable containers comprising an inorganically filled matrix |
AU24355/97A AU709034B2 (en) | 1996-04-09 | 1997-04-09 | Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix |
NZ332040A NZ332040A (en) | 1996-04-09 | 1997-04-09 | Sealable containers comprising an inorganically filled matrix |
JP53630797A JP2001523196A (en) | 1996-04-09 | 1997-04-09 | Composition and manufacturing method of a sealable liquid-tight container composed of an inorganic-filled matrix |
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US08/629,972 | 1996-04-09 |
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-
1996
- 1996-04-09 US US08/629,972 patent/US5738921A/en not_active Expired - Fee Related
-
1997
- 1997-04-09 WO PCT/US1997/005494 patent/WO1997037841A1/en not_active Application Discontinuation
- 1997-04-09 KR KR1019980707450A patent/KR20000004908A/en active IP Right Grant
- 1997-04-09 NZ NZ332040A patent/NZ332040A/en unknown
- 1997-04-09 AU AU24355/97A patent/AU709034B2/en not_active Ceased
- 1997-04-09 EP EP97920072A patent/EP0892717A1/en not_active Withdrawn
- 1997-04-09 CA CA 2248906 patent/CA2248906A1/en not_active Abandoned
- 1997-04-09 JP JP53630797A patent/JP2001523196A/en not_active Ceased
- 1997-04-09 BR BR9710427A patent/BR9710427A/en active Search and Examination
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