WO1997036029A1 - Process for producing cellulose fibres and cellulosic fibre products - Google Patents
Process for producing cellulose fibres and cellulosic fibre products Download PDFInfo
- Publication number
- WO1997036029A1 WO1997036029A1 PCT/EP1997/001365 EP9701365W WO9736029A1 WO 1997036029 A1 WO1997036029 A1 WO 1997036029A1 EP 9701365 W EP9701365 W EP 9701365W WO 9736029 A1 WO9736029 A1 WO 9736029A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- range
- zinc chloride
- acid
- fibers
- fiber
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 126
- 238000000034 method Methods 0.000 title claims abstract description 55
- 229920003043 Cellulose fiber Polymers 0.000 title claims abstract description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 98
- 239000011592 zinc chloride Substances 0.000 claims abstract description 49
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 49
- 239000002253 acid Substances 0.000 claims abstract description 37
- 238000005406 washing Methods 0.000 claims abstract description 23
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 13
- 229920002678 cellulose Polymers 0.000 claims description 22
- 239000001913 cellulose Substances 0.000 claims description 21
- 239000004744 fabric Substances 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 238000009987 spinning Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000004753 textile Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000000717 retained effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 34
- 235000010980 cellulose Nutrition 0.000 description 20
- 239000000047 product Substances 0.000 description 19
- 206010061592 cardiac fibrillation Diseases 0.000 description 17
- 230000002600 fibrillogenic effect Effects 0.000 description 17
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- -1 knitwear Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 238000005200 wet scrubbing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000007431 microscopic evaluation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- COEZWFYORILMOM-UHFFFAOYSA-M sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonate Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000006076 specific stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/02—Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- the invention relates to a method for reducing the tendency of cellulose fibers to fibrillate, which at the same time brings about a reduced formation of gray fog, improved dyeability and levelness and a softer feel of textile products which were produced from the fibers treated according to the invention.
- NMMO N-methylrriorpholine-N-oxide
- a disadvantage of this method is that the fibers obtained tend to fibrillate relatively strongly, which is perceived as very disruptive for very many applications. It has been shown that cellulosic fibers which are produced by the NMMO process, particularly when wet, have a great tendency to fibrillate, especially when mechanical forces act on the fibers. This occurs in particular when dyeing and washing yarns which have been produced from the fibers just mentioned.
- Fibrils have a disturbing effect on dyed textiles in that along folds which arise when washing in the washing machine, as a result of the increased abrasion at these points, a gray haze which is undesirable for aesthetic reasons is formed, which increases with each washing cycle.
- fabrics made of fibers which have been produced by the process mentioned have a lower dye absorption than viscose fibers and have an increasingly harder grip with each wash. Textiles made from fibers that tend to fibrillate therefore do not meet the expectations of the customer from the outset with regard to comfort, which also worsens with every wash.
- the international patent application WO-Al-92/14871 describes a process in which an effort is made to control the pH value in the different wash baths to reduce the tendency of the threads to fibrillate.
- WO-Al-95/16063 describes a method in which a surfactant is added to the precipitation bath and / or the washing baths.
- Vulkanfiber a material which is produced by treating paper with an aqueous solution of zinc chloride with a concentration of 65 to 73% by weight of zinc chloride, the solution being 30 is warm up to 50 ° C.
- the paper is vulcanized, i.e. the cellulose filaments are intensively glued together.
- the object of the invention is therefore to provide a method which does not require changes to the known spinning, drawing and precipitation bath technology which is optimized at high cost and which eliminates or at least substantially reduces the disadvantages mentioned .
- This object is achieved by a process for the production of cellulosic fibers by spinning a solution of cellulose in a tertiary amine oxide, possibly also containing water and possibly a stabilizer, precipitation, washing, squeezing and drying of the fibers, which is characterized in that is that the fibers are treated either after washing or after squeezing or after drying with a zinc chloride solution which may contain an acid at a temperature in the range from about 10 to 250 ° C., the Zinc chloride solution has a zinc chloride concentration in the range from about 30 to 70% by weight and an acid concentration in the range from 0 to about 10% by weight, after which the fibers are washed free of zinc chloride and, if appropriate, of acid, optionally squeezes and dries.
- a zinc chloride solution which may contain an acid at a temperature in the range from about 10 to 250 ° C.
- the Zinc chloride solution has a zinc chloride concentration in the range from about 30 to 70% by weight and an acid concentration in the
- the zinc chloride and possibly an acid-containing solution is preferably aqueous.
- Acetic acid has proven to be a preferred suitable acid.
- the addition of acid leads to an accelerated occurrence of the desired effects, so that the acid is preferably used when, for example, very high spinning speeds are required or when a fiber with a high titer is to be treated.
- One embodiment of the invention is that the fibers are treated in a single device with the zinc chloride and optionally an acid-containing solution.
- any device is suitable for this which is capable of completely providing the fiber with the treatment solution and of allowing the necessary mass and heat transport processes to take place sufficiently quickly.
- a bath is preferably used in which there is an acidic zinc chloride solution and in which the fibers are treated.
- turbulence or pressure waves can be generated in the bath, for example by ultrasound.
- a zinc chloride concentration in the range from approximately 40 to 65% by weight, in particular in the range from approximately 50 to 60% by weight, an acid concentration in the range from approximately 0 to 5% by weight is preferred.
- the treatment times will move in the direction of the lower limit of the time ranges mentioned, the higher the treatment temperatures are selected, whereas the longer the treatment times, the lower the treatment temperatures.
- the fibers require a longer treatment time the higher their average degree of polymerization.
- a further embodiment of the invention is that the fibers are first completely provided with the zinc chloride and possibly an acid-containing solution in the device already described, preferably in a bath, the bath temperature being in the range from about 20 to 25 ° C. lies. The same applies to the zinc chloride and acid concentration said. The fibers are then heat-treated outside of the device mentioned.
- any heat transfer medium that is capable of allowing the necessary mass and heat transport processes to run sufficiently quickly is suitable for the heat treatment.
- a zone of warm or hot gas is preferably used, the fibers being blown with the gas.
- gases or vapors can be used which are inert with cellulose, zinc chloride, water and possibly with the acid under the conditions according to the invention.
- Air is preferably used.
- a temperature in the range from approximately 40 to 250 ° C., in particular in the ranges from approximately 150 to 250 ° C. and 40 to 70 ° C. is preferred for the heat treatment Dwell time of the fiber in the bath in the range of about 0.1 to 5 seconds, in particular in the range of about 0.5 to 3 seconds, and a dwell time of the fiber in the heat treatment zone in the range of about 0.1 to 10 seconds, especially in the range of about 0.2 to 5 seconds.
- the treatment according to the invention can be carried out not only as already described at various points in the spinning process, but also on cellulosic fiber products, the fibers of which are obtained by spinning a solution of cellulose in a tertiary amine oxide which may also contain water and possibly a stabilizer , Cases, washing, squeezing and drying were obtained, the washed and optionally dried or unwashed fiber products with an acidic zinc chloride solution at a temperature in the range from about 10 to 250 ° C.
- the zinc chloride solution has a zinc chloride concentration in the range of about 30 to 70% by weight and an acid concentration in the Has a range from 0 to about 10% by weight, after which the fibers are washed free from zinc chloride and possibly from acid, if necessary squeezed and dried.
- the invention is applicable to all linear and flat cellulosic fiber products.
- textile fabrics such as e.g. Fabrics, knitwear, nonwovens or laid scrims or yarns, fiber sheets or tapes are treated.
- Staple fibers, short cuts or flakes or mixed yarns made of cellulosic and synthetic fibers can also be treated.
- the zinc chloride and possibly an acid-containing solution is preferably aqueous.
- Acetic acid has proven to be a preferred suitable acid.
- the addition of acid leads to an accelerated occurrence of the desired effects, so that the acid is preferably used when very high treatment speeds of the cellulosic fiber product are required or when a fiber product with a very dense structure is to be treated.
- One embodiment of the invention consists in treating the cellulosic fiber products in a single device with the zinc chloride and possibly an acid-containing solution.
- any device is suitable for this, which is capable of completely providing the treatment solution to the cellulosic fiber products and of allowing the necessary mass and heat transport processes to take place sufficiently quickly.
- the cellulosic fiber products are preferably treated in a bath in which the zinc chloride solution, which may contain an acid, is present. To accelerate the necessary heat and mass transfer processes, turbulence or pressure waves can be generated in the bathroom, for example by ultrasound.
- a further embodiment of the invention consists in first providing the cellulosic fiber products completely with the zinc chloride and possibly an acid-containing solution having a temperature in the range from approximately 20 to 25 ° C. in the device already described and then heat-treating outside the device .
- the wet scrub test apparatus shown schematically in FIG. 1 is used to measure the tendency to fibrillation of individual threads.
- the wet abrasion test is carried out with threads which have been removed from the products mentioned.
- the wet abrasion test equipment essentially consists of the elements (1) to (6), which are explained in the following:
- the thread (2) is fixed in a PVC block (1).
- the scouring load is generated in that the thread (2) is guided over an arrangement rotating at 25 revolutions per minute, which consists of a 2.5 mm thick ceramic rod (4) attached to a glass rod (5) with a diameter of 6 mm Diameter exists.
- the wet scrub test was run for 1 minute.
- the defined and reproducible fibrillation produced with the described apartment was assessed on a scale with the marks 1 to 6 by microscopic evaluation of the scrubbed, approximately 3 mm long fiber area.
- Primary fibrillation means that fibrils are only observed on the fiber surface.
- Secondary fibrillation means that the fibrils are also observed in the deeper layers of the filaments. The more secondary fibrillation progresses, the longer and thicker the fibrils become.
- a grade scale from 1 to 6 was defined using the terms just described. The means
- Primary and secondary fibrillation such as those on untreated
- the dyeing of the fabrics takes 1 hour and is carried out at 50 ° C and a liquor ratio of 1: 160.
- a paddle serves as the coloring unit. This is followed by a 20 minute boiling soap with Perilan VF (4.0 g / 1) and the detergent Kieralon Jet B.
- the brightness which is determined with the Minolta Chroma Meter, is used to measure the color depth.
- the fibers or fiber products treated according to the invention show a significantly reduced tendency to fibrillation with notes between 2 and 3, have no gray haze before washing in the washing machine or after 10 washes, and are distinguished by a pleasantly soft handle, which itself does not become harder after washing 10 times in the washing machine.
- the fiber products treated and dyed in accordance with the invention are surprising in that they have a higher level of levelness and a significantly deeper dyeability, the properties just mentioned not decreasing even after washing 10 times.
- the invention is not restricted to the use of a certain average degree of polymerization DP of the cellulose raw material. Rather, cellulose or cotton linters with a DP in the range from about 400 to 7000 can be used individually or as a mixture of celluloses with a high and low degree of polymerization.
- the invention is not restricted to a specific stabilizer in the spinning solution. Rather, all additives suitable as stabilizers can be used, e.g. Pyrrogallol, gallic acid or propyl gallate.
- the invention is not restricted to a specific cellulosic fiber type, but encompasses all cellulosic fiber types such as e.g. Continuous filaments or fibers, and staple or short cut fibers, flakes or blended yarns made of cellulosic and synthetic fibers.
- the invention is also not limited to the fact that the fibers or a textile fabric produced therefrom under a ner certain mechanical tension must stand. Rather, the fibers or the textile fabrics produced therefrom can be used without mechanical tension or in a state of mechanical tension.
- the invention is not restricted to the use of a certain tertiary amine oxide, but preferably uses N-methylmorpholine-N-oxide (NMMO).
- NMMO N-methylmorpholine-N-oxide
- the invention is further illustrated by the following examples.
- the zinc chloride used was purchased from Fluka and has a purity of 98%.
- a desized and dried fabric made of fibers (75 dtex, f 50) spun from an NMMO-containing cellulose solution is treated for 8 minutes in a bath containing a solution of 55% by weight zinc chloride in water.
- the bath has a temperature of 22 ⁇ 3 ° C.
- the fabric is then squeezed, washed and dried in a known manner.
- the fabric treated and dyed in this way shows no gray haze and is further characterized by a 25% deeper staining, a softer feel and a very high level of levelness in comparison to untreated fabric which has a clear gray haze and whose levelness is desirable leaves little.
- the tendency to fribrillation of fibers taken from the treated tissue was given a rating of 2, while untreated fibers were rated 6.
- the treated fabric shows no gray haze and is still characterized by a high level of levelness, an unchanged soft feel and a 25% deeper staining compared to the untreated fabric, the handle of which is significantly harder.
- the tendency to fribrillation of fibers taken from the treated tissue was given a grade of 2-3, while untreated fibers were rated 6.
- a fiber (75 dtex f 50) spun, precipitated, washed and squeezed from an NMMO / cellulose solution is treated in a bath which contains a solution of 60% by weight zinc chloride in water.
- the solution has a temperature of 22 + 3 ° C.
- the fiber speed and the dimensions of the treatment bath are adjusted so that a fiber residence time of about 1.5 ⁇ 0.5 seconds results.
- the fiber is then drawn through a hot air zone and blown with hot air at 225 ⁇ 25 ° C.
- the fiber speed and the dimensions of the hot air zone are adjusted so that a fiber residence time of about 2 seconds results.
- the fiber is squeezed, washed and dried in a known manner. The tendency to fribrillation of fibers treated in this way was given a grade of 2-3, while untreated fibers were rated 6.
- a fiber spun, precipitated, washed, squeezed and dried from an NMMO / cellulose solution (75 dtex f 50) is treated in a 22 + 3 ° C. bath containing a solution of 50% by weight zinc chloride in water.
- the fiber speed and the dimensions of the treatment bath are set in such a way that a fiber residence time of about 1 + 0.5 seconds results.
- the fiber is then placed in a warm air zone conducted and blown with 55 + 5 ° C warm air.
- the fiber speed and the dimensions of the warm air zone are set such that a fiber dwell time of about 2 seconds results.
- the fiber is then squeezed, washed and dried in a known manner. The tendency to fribrillation of fibers treated in this way was rated 2-3, while untreated fibers were rated 6.
- a fiber spun, precipitated, washed, squeezed and dried from an NMMO / cellulose solution (75 dtex f 50) is treated in a 22 ⁇ 3 ° C. bath containing a solution of 55% by weight zinc chloride in water.
- the fiber speed and the dimensions of the treatment bath are set so that a fiber residence time of about 2 minutes results.
- the fiber is then squeezed, washed and dried in a known manner.
- a fabric is produced from the fiber treated in this way, which shows the same properties as the treated fabric of Example 1.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97914266A EP0889978A1 (en) | 1996-03-27 | 1997-03-19 | Process for producing cellulose fibres and cellulosic fibre products |
JP9534003A JP2000507315A (en) | 1996-03-27 | 1997-03-19 | Cellulose fiber and method for producing cellulose fiber |
AU21578/97A AU2157897A (en) | 1996-03-27 | 1997-03-19 | Process for producing cellulose fibres and cellulosic fibre products |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19612145 | 1996-03-27 | ||
DE19612145.0 | 1996-03-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997036029A1 true WO1997036029A1 (en) | 1997-10-02 |
Family
ID=7789612
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/001365 WO1997036029A1 (en) | 1996-03-27 | 1997-03-19 | Process for producing cellulose fibres and cellulosic fibre products |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0889978A1 (en) |
JP (1) | JP2000507315A (en) |
AU (1) | AU2157897A (en) |
WO (1) | WO1997036029A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015101543A1 (en) | 2014-01-03 | 2015-07-09 | Lenzing Aktiengesellschaft | Cellulose fiber |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1272445A (en) * | 1968-08-29 | 1972-04-26 | Budd Co | Machine for continuously treating vulcanized fibre |
DE2164385A1 (en) * | 1971-01-05 | 1973-06-28 | Johnson & Johnson | PROCESS FOR TREATMENT OF FIBER MATERIALS IN ORDER TO MAKE THESE MATERIALS ACCESSIBLE TO THE FOLLOWING TEXTILE PROCESSES WITH Aqueous MEDIA |
DE2838799A1 (en) * | 1978-09-06 | 1980-03-13 | Dynamit Nobel Ag | VOLCANIC FIBER AND METHOD FOR THEIR PRODUCTION |
SU1158644A1 (en) * | 1984-03-29 | 1985-05-30 | Всесоюзное Ордена Трудового Красного Знамени Научно-Производственное Объединение Целлюлозно-Бумажной Промышленности | Method of producing fibre |
JPH01156599A (en) * | 1987-12-08 | 1989-06-20 | Hokuetsu Paper Mills Ltd | Production of vulcanized fiber |
JPH07189019A (en) * | 1993-12-22 | 1995-07-25 | Kohjin Co Ltd | Production of regenerated cellulose formed product |
-
1997
- 1997-03-19 WO PCT/EP1997/001365 patent/WO1997036029A1/en not_active Application Discontinuation
- 1997-03-19 JP JP9534003A patent/JP2000507315A/en active Pending
- 1997-03-19 AU AU21578/97A patent/AU2157897A/en not_active Abandoned
- 1997-03-19 EP EP97914266A patent/EP0889978A1/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1272445A (en) * | 1968-08-29 | 1972-04-26 | Budd Co | Machine for continuously treating vulcanized fibre |
DE2164385A1 (en) * | 1971-01-05 | 1973-06-28 | Johnson & Johnson | PROCESS FOR TREATMENT OF FIBER MATERIALS IN ORDER TO MAKE THESE MATERIALS ACCESSIBLE TO THE FOLLOWING TEXTILE PROCESSES WITH Aqueous MEDIA |
DE2838799A1 (en) * | 1978-09-06 | 1980-03-13 | Dynamit Nobel Ag | VOLCANIC FIBER AND METHOD FOR THEIR PRODUCTION |
SU1158644A1 (en) * | 1984-03-29 | 1985-05-30 | Всесоюзное Ордена Трудового Красного Знамени Научно-Производственное Объединение Целлюлозно-Бумажной Промышленности | Method of producing fibre |
JPH01156599A (en) * | 1987-12-08 | 1989-06-20 | Hokuetsu Paper Mills Ltd | Production of vulcanized fiber |
JPH07189019A (en) * | 1993-12-22 | 1995-07-25 | Kohjin Co Ltd | Production of regenerated cellulose formed product |
Non-Patent Citations (5)
Title |
---|
BETRABET S M ET AL: "Electron-Microscope Study of Cotton Treated with Inter- and Intracrystalline Swelling Agents", TEXTILE RESEARCH JOURNAL, vol. 40, no. 10, October 1970 (1970-10-01), pages 917 - 924, XP002034641 * |
BETRABET S M ET AL: "Part I. INTRACRYSTALLINE SWELLING AND DECRYSTALLIZATION IN ZINC CHLORIDE-TREATED COTTON CELLULOSE", CELLULOSE CHEMISTRY AND TECHNOLOGY, vol. 3, February 1969 (1969-02-01), pages 309 - 323, XP002034642 * |
DATABASE WPI Section Ch Week 8550, Derwent World Patents Index; Class F09, AN 85-315347, XP002034645 * |
DATABASE WPI Section Ch Week 8930, Derwent World Patents Index; Class F09, AN 89-217702, XP002034644 * |
DATABASE WPI Section Ch Week 9538, Derwent World Patents Index; Class A11, AN 95-290979, XP002034643 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015101543A1 (en) | 2014-01-03 | 2015-07-09 | Lenzing Aktiengesellschaft | Cellulose fiber |
US10883196B2 (en) | 2014-01-03 | 2021-01-05 | Lenzing Aktiengesellschaft | Cellulose fiber |
Also Published As
Publication number | Publication date |
---|---|
JP2000507315A (en) | 2000-06-13 |
AU2157897A (en) | 1997-10-17 |
EP0889978A1 (en) | 1999-01-13 |
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