WO1997028947A1 - Method for extruding a frame-shaped profiled rim onto a glass pane, extrusion die therefor, and resulting product - Google Patents

Method for extruding a frame-shaped profiled rim onto a glass pane, extrusion die therefor, and resulting product Download PDF

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Publication number
WO1997028947A1
WO1997028947A1 PCT/FR1997/000226 FR9700226W WO9728947A1 WO 1997028947 A1 WO1997028947 A1 WO 1997028947A1 FR 9700226 W FR9700226 W FR 9700226W WO 9728947 A1 WO9728947 A1 WO 9728947A1
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WO
WIPO (PCT)
Prior art keywords
slide
extrusion
glazing
plate
lip
Prior art date
Application number
PCT/FR1997/000226
Other languages
French (fr)
Inventor
Helmut Krumm
Herbert Joeris
Ulrich MÖLLEKEN
Heinz Scholl
Original Assignee
Saint-Gobain Vitrage
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint-Gobain Vitrage filed Critical Saint-Gobain Vitrage
Priority to JP9528222A priority Critical patent/JPH11503381A/en
Priority to BR9702069A priority patent/BR9702069A/en
Priority to EP97904491A priority patent/EP0819050A1/en
Publication of WO1997028947A1 publication Critical patent/WO1997028947A1/en
Priority to MXPA/A/1997/007659A priority patent/MXPA97007659A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/70Sealing arrangements specially adapted for windows or windscreens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/154Coating solid articles, i.e. non-hollow articles
    • B29C48/155Partial coating thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/302Extrusion nozzles or dies being adjustable, i.e. having adjustable exit sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/20Sealing arrangements characterised by the shape
    • B60J10/21Sealing arrangements characterised by the shape having corner parts or bends

Definitions

  • the present invention relates to a method for the extrusion on the marginal zone of a plate comprising at least one angle, in particular a glazing, of a profiled cord in the form of a frame, having a lip projecting from the plate, into an elastomer , using an extrusion die, the profiled bead being placed in an arc in the corner area.
  • the invention also relates to an extrusion die for carrying out this process and to the product obtained.
  • the known methods for the extrusion of a profiled frame comprising a centering and sealing lip projecting beyond the edge of the glazing in which, in general, a robot guides the extrusion head to the periphery of the glazing or where a robot moves the glazing in front of a fixed extrusion head, can be executed without difficulty, as long as the glazing or such shaped objects of plates, which are provided with the profiled frame, have rounded corners or a radius of at least about 20 mm.
  • the known machines must then, if the extrusion speed must still be economical, deposit in the corner areas the profiled bead in an arc, the axis of the profiled bead then describing an arc of a radius of about 20 mm.
  • the sealing lip directly in the angle would no longer extend beyond the edges, but would follow an arc inside the angle.
  • the peripheral lip the function of which is to bear on the bodywork all around the glazing, could not fulfill its function.
  • the frame is completed by a method similar to the injection molding process.
  • the marginal area to be completed is inserted into an injection mold, and a suitable polymer is injected into the injection mold and hardens in the mold.
  • This process has proven its worth, but is however linked to additional labor costs due to the additional process steps required.
  • the object of the invention is to improve the process mentioned at the beginning of this specification so that the lip projecting beyond the edge of the glazing is extended or completed in specific areas of the frame, without an additional process step. is not necessary.
  • an extrusion die comprising an elongated slot and a slide closing the end of the slot and that the slide is moved on command in a radial direction during the extrusion of the arc of a circle in the corner of the plate.
  • the process according to the invention is therefore based on the use of an extrusion die with a variable die cross section, by the controlled modification of which the width of sealing lip in the corner area is continuously modified as desired in the area concerned and, in the case of a sharp angle, in which the lip is lengthened before reaching the angle and is then shortened again continuously to the initial length.
  • the frame completely extruded during the extrusion operation in such a way that a post-molding of the sealing lip, especially in the areas of angle is no longer necessary.
  • the method according to the invention can be carried out in principle in the case of extrusion using an extrusion die carried along a stationary plate as well as using a die extrusion arranged in a fixed manner, at the level of which the glazing is moved.
  • the controlled displacement of the slide for lengthening and shortening the slot can be achieved in different ways.
  • the slide can thus, for example, be provided with an electric or pneumatic drive, which is controlled by the central microprocessor of the installation.
  • the slider can also be coupled to a lateral guide roller, which rolls on the peripheral surface of the plate to be provided with the profiled frame and moves the slider in the desired way, in particular when angle bypass.
  • Figure 1 shows a corner area of a glazing unit comprising an extruded frame according to the state of the art
  • Figure 2 shows the corner area of a glazing according to Figure 1, but with an extruded frame according to the method of the invention
  • Figure 3 is a side elevational view of an extrusion head driven by a robot comprising an extrusion die according to the invention during the extrusion operation
  • Figure 4 is a schematic view of the extrusion operation in the corner area of the glazing.
  • the process of the invention can, of course, also be used in the case of the extrusion of profiled frames on other objects, such as, for example, metal plates, doors, trunk lids, etc. as far as these objects also have the need to modify the width of the lip, in particular when they have one or more sharp angles and the profiled frame is provided with a profile segment projecting beyond the edge of the object .
  • the glazing 1 shown in the drawings has a sharp angle 2 in the corner area, in this case an angle with a value of 90 °.
  • Certain automobile windows are sometimes configured so as to present such a sharp angle, while their outline for the rest describes curves having a greater or lesser radius.
  • Such forms of glazing are often found in fixed rear side glazing. Glazing with two sharp angles is often used for automobile rear windows; in this case, the two lower corners are usually in the form of sharp angles, while the two upper corners are more or less strongly rounded.
  • glazing all of whose corners are right angles, is used. The process according to the invention can be used in all these cases.
  • a layer 3 in the form of a frame of an opaque material as a rule a baking ink. This is generally baked in the surface of the glass during the heat treatment to which the glazing is subjected with a view to bending and / or tempering.
  • the profiled frame 4 is then extruded onto this layer 3 on the glazing at the level of the marginal zone of the glazing 1.
  • the profiled frame 4 has a base segment 5 and a wing 7 extending perpendicular thereto.
  • the sealing lip 8 projecting outwards beyond the edge of the glazing is connected to the wing 7.
  • This profile segment 5 is applied, during the mounting of the glazing, the mass of adhesive with which the glazing is glued to the fixing edge of the window frame of the bodywork.
  • This profile segment 5 can also, in principle, have another cross section; if necessary, this base segment 5 can also be completely removed and the adhesive mass is then directly deposited on the glazing, preferably on the opaque layer 3.
  • the die extrusion in its relative movement to the periphery of the glazing must describe in the corner a circular path, along which the axis of the profiled bead describes a curve of radius R, of dimension at least about 20 mm.
  • the outer side 10 of the lip will also thus describe an arc of a circle around the same center of a circle with the consequence that, from the start of the rotation of the extrusion die, the lip part 8 protruding beyond the edge of the glazing will shorten.
  • the lip 8 does not even extend at all to the edge of the glazing. The phenomena are the same if the edge of the bay has a meander whose edge of the glazing does not have the equivalent, then the lip deviates or approaches the body unduly.
  • a suitable shape of the lip 8 is obtained and, in the case of a wedge, as it appears in FIG. 2. Since, in the angle zone, the pivoting movement of the extrusion die and its movement along a circular path remain in principle unchanged, the shape and shape of the profile segments 5 and 7 are, in principle, the same as in the case shown in Figure 1.
  • the length I of the sealing lip 8 projecting outwards increases however continuously, from the point where the circular and rotational movement of the extrusion die begins, until the extrusion die has traversed half of the arc of a circle. At this point, the lip 8 has the length L.
  • the length of the lip 8 decreases continuously, until it has again reached its original length I at the end of the circular arc.
  • the lip 8 now has in the corner area of the glazing the shape as shown in FIG. 2, that is to say that the part of the lip protruding beyond the edges of the glazing also extends into the corner area parallel to the edge of the glazing, and only the extreme outer corner of the lip is somewhat rounded.
  • Figure 3 is a side elevational view of an extrusion head for the manufacture of the extruded profile frame according to the invention.
  • the extrusion head comprises, inter alia, the die body proper 14 comprising the calibrated die orifice 1 5, the slide 1 6 being able to move horizontally and, in the case shown, where the extrusion head is controlled mechanically, a guide roller 1 7 connected to the slide 1 6, which rolls on the peripheral surface 1 8 of the glazing 1.
  • the slot 1 5 ′ of the die orifice 1 5, forming the sealing lip has a length L, which is substantially greater than the length I of the sealing lip in the region of the longitudinal edges of the glazing.
  • the slot 1 5 ′ is closed at its end by the slide 1 6 to the point that the free lip slot 1 5 ′, has in the region of the rectilinear longitudinal edges of the glazing, the desired length I.
  • the slide 1 6 and the bearing 1 9 carrying the guide roller 1 7, which are fixedly connected to each other, are slidably mounted via a sliding bearing 20 on a horizontal guide rod 21.
  • a pressing force is exerted by the helical spring 22 on the slide device connected to the guide roller 1 7, the guide roller 1 7 therefore being pressed against the peripheral surface 1 8 of the glazing 1.
  • the attachment 23 carrying the guide rod 21 is rigidly connected to the extrusion head carrying the extrusion die.
  • the extrusion die 14 is provided with two channels 26, 27 separated from each other, through which the polymer to be extruded is brought to the die orifice 1 5, 1 5 '.
  • the volume flow rate of the polymer can be adjusted in the two channels 26, 27 independently of each other, as described in the document EP O 444 998 B1. Valves regulating the volume flow in the two channels
  • volume flow rates are therefore adapted to the different mass requirements of polymer inside the die orifice during the rotation of the extrusion head.
  • FIG. 4 shows in a plan view the sequence of movements of the die 14 and of the slide 1 6 during the extrusion of the profiled frame 4 in a corner area of the glazing 1. It is recognized that the guide roller 1 7 progressing on the peripheral surface 1 8 moves, during the pivoting movement of the die 1 4, outward in the direction of arrow F with the slide 1 6 coupled to the roller guide, the die slot 1 5 ′ forming the lip 8 being thereby progressively released continuously. As soon as the guide roller reaches the angle 2 of the glazing during the pivoting movement of the die 14 which continues, the direction of movement of the slide 1 6 reverses, whereby the die slot 1 5 'becomes shorter again continuously, until it has reached its final position at the end of the pivoting movement of the die 14.
  • the method of the invention makes it possible to obtain a product, automobile glazing in particular, which comprises in the corners, a frame whose lip, as the rest of the cord constitutes a continuity with the neighboring linear parts.
  • a product, automobile glazing in particular which comprises in the corners, a frame whose lip, as the rest of the cord constitutes a continuity with the neighboring linear parts.
  • the connection between the new part molded in the corner and the parts of the neighboring extruded profile was visible except in the case where a cosmetic correction was made.

Abstract

A method for extruding a frame-shaped profiled rim (4) of elastomeric material onto the edge of a glass pane (1) having one or more sharp corners (2). The profiled rim (4) is provided with a radial sealing lip (8) projecting beyond the edge of the pane (1). In the corner area (2), the profiled rim (4) is laid along an arc of a circle. The extrusion die (14) used has an elongate slot covered at one end by a slide (16). The slide (16) is preferably coupled to a guide roller (17) rolling along the edge surface of the pane (1). The lip (8) is thus continuously elongated in the corner region, then continuously shortened again back to its original length. The resulting product, particularly glazing for use in motor vehicles, comprises, at the corners, a frame of which the lip, like the rest of the rim, is continuous with the adjacent linear portions.

Description

PROCEDE POUR L'EXTRUSION D'UN CORDON PROFILE PROCESS FOR THE EXTRUSION OF A PROFILED CORD
EN FORME DE CADRE SUR UN VITRAGE, FILIERE D'EXTRUSIONFRAME SHAPED ON GLAZING, EXTRUSION PATHWAY
POUR L'EXECUTION DU PROCEDE ET PRODUIT OBTENUFOR THE EXECUTION OF THE PROCESS AND PRODUCT OBTAINED
La présente invention concerne un procédé pour l'extrusion sur la zone marginale d'une plaque comportant au moins un angle, en particulier un vitrage, d'un cordon profilé en forme de cadre, présentant une lèvre débordant de la plaque, en un élastomère, à l'aide d'une filière d'extrusion, le cordon profilé étant déposé en arc de cercle dans la zone de l'angle. L'invention a trait, en outre, à une filière d'extrusion pour l'exécution de ce procédé et au produit obtenu.The present invention relates to a method for the extrusion on the marginal zone of a plate comprising at least one angle, in particular a glazing, of a profiled cord in the form of a frame, having a lip projecting from the plate, into an elastomer , using an extrusion die, the profiled bead being placed in an arc in the corner area. The invention also relates to an extrusion die for carrying out this process and to the product obtained.
Il est connu d'extruder des profilés en forme de cadres en un élastomère, comportant une lèvre d'étanchéité faisant saillie radialement, directement sur la zone marginale d'un vitrage. Ceci peut être effectué, par exemple, en déplaçant la filière d'extrusion à l'aide d'un robot le long du bord du vitrage. Des procédés de ce type sont décrits, par exemple, dans les documents EP O 421 833 A2, 0 61 1 672 A2, 0 444 998 B1 et 0 479 677 B1 . Le procédé pour l'extrusion peut également être exécuté en déplaçant le vitrage à l'aide d'un robot par rapport à une filière d'extrusion montée fixe. Des procédés opérant de cette façon sont décrits dans les documents EP 0 585 1 29 A1 , 0 634 263 A1 ,It is known to extrude profiles in the form of frames in an elastomer, comprising a sealing lip projecting radially, directly on the marginal zone of a glazing. This can be done, for example, by moving the extrusion die using a robot along the edge of the glazing. Processes of this type are described, for example, in documents EP 0 421 833 A2, 0 61 1 672 A2, 0 444 998 B1 and 0 479 677 B1. The extrusion process can also be carried out by moving the glazing using a robot relative to a fixed mounted extrusion die. Processes operating in this way are described in documents EP 0 585 1 29 A1, 0 634 263 A1,
0 662 384 A1 et 0 707 657 A1 .0 662 384 A1 and 0 707 657 A1.
Les procédés connus pour l'extrusion d'un cadre profilé comportant une lèvre de centrage et d'étanchéité faisant saillie au-delà du bord du vitrage dans lesquels, en général, un robot guide la tête d'extrusion à la périphérie du vitrage ou bien où un robot déplace le vitrage devant une tête d'extrusion fixe, peuvent être exécutés sans difficulté, tant que les vitrages ou de tels objets en forme de plaques, qui sont pourvus du cadre profilé, présentent des angles arrondis ou d'un rayon d'au moins environ 20 mm. Si le rayon de l'angle arrondi est inférieur à environ 20 mm, ou si la plaque présente un ou plusieurs angles vifs, les machines connues doivent alors, si la vitesse d'extrusion doit être encore économique, déposer dans les zones d'angle le cordon profilé en arc de cercle, l'axe du cordon profilé décrivant alors un arc de cercle d'un rayon d'environ 20 mm. Ceci a pour conséquence que la lèvre d'étanchéité ne peut plus faire saillie dans la zone d'angle d'une longueur constante au-delà des bords du vitrage. Dans le cas d'un angle droit par exemple, la lèvre d'étanchéité directement dans l'angle ne déborderait plus des bords, mais suivrait un arc à l'intérieur de l'angle. Dans un tel cas, la lèvre périphérique dont la fonction est d'être en appui sur la carrosserie tout autour du vitrage ne pourrait remplir son office.The known methods for the extrusion of a profiled frame comprising a centering and sealing lip projecting beyond the edge of the glazing in which, in general, a robot guides the extrusion head to the periphery of the glazing or where a robot moves the glazing in front of a fixed extrusion head, can be executed without difficulty, as long as the glazing or such shaped objects of plates, which are provided with the profiled frame, have rounded corners or a radius of at least about 20 mm. If the radius of the rounded angle is less than about 20 mm, or if the plate has one or more sharp angles, the known machines must then, if the extrusion speed must still be economical, deposit in the corner areas the profiled bead in an arc, the axis of the profiled bead then describing an arc of a radius of about 20 mm. This has the consequence that the sealing lip can no longer protrude in the corner area of a constant length beyond the edges of the glazing. In the case of a right angle, for example, the sealing lip directly in the angle would no longer extend beyond the edges, but would follow an arc inside the angle. In such a case, the peripheral lip, the function of which is to bear on the bodywork all around the glazing, could not fulfill its function.
Il est par conséquent nécessaire dans l'état de la technique de compléter, dans une étape de procédé ultérieure, le cadre profilé extrudé dans les zones d'angle. Selon le procédé décrit dans le document EP 0 524 060 A1 , on complète le cadre au moyen d'une méthode semblable au procédé de moulage par injection. Dans ce cas, la zone marginale à compléter est insérée dans un moule à injection, et un polymère approprié est injecté dans le moule à injection et durcit dans le moule. Ce procédé a fait ses preuves, mais est cependant lié à un surcroît de frais de main-d Oeuvre à cause des étapes de procédé supplémentaires nécessaires.It is therefore necessary in the prior art to complete, in a subsequent process step, the extruded profile frame in the corner areas. According to the process described in document EP 0 524 060 A1, the frame is completed by a method similar to the injection molding process. In this case, the marginal area to be completed is inserted into an injection mold, and a suitable polymer is injected into the injection mold and hardens in the mold. This process has proven its worth, but is however linked to additional labor costs due to the additional process steps required.
Il est également intéressant d'une manière générale de pouvoir modifier, en un ou plusieurs endroits de la périphérie du vitrage, la position relative du cordon du cadre périphérique et de l'extrémité de la lèvre débordante. C'est le cas en particulier si le bord de la baie où est inséré le vitrage possède en certains endroits une modulation, élargissement ou rétrécissement, qu'il peut être intéressant de ne suivre qu'avec la lèvre sans que l'essentiel du cordon suive complètement le méandre en question. Alors c'est essentiellement la lèvre qui, grâce à sa largeur variable à l'endroit concerné, permettra de résoudre le problème.It is also advantageous in general to be able to modify, in one or more places on the periphery of the glazing, the relative position of the bead of the peripheral frame and of the end of the projecting lip. This is particularly the case if the edge of the bay where the glazing is inserted has in certain places a modulation, widening or shrinking, which it may be interesting to follow only with the lip without the essential part of the cord completely follow the meander in question. So it is essentially the lip which, thanks to its variable width in the place concerned, will resolve the problem.
L'invention a pour but de perfectionner le procédé mentionné au début du présent mémoire de telle sorte que la lèvre faisant saillie au-delà du bord du vitrage soit prolongée ou complétée dans des zones déterminées du cadre, sans qu'une étape de procédé supplémentaire ne soit nécessaire.The object of the invention is to improve the process mentioned at the beginning of this specification so that the lip projecting beyond the edge of the glazing is extended or completed in specific areas of the frame, without an additional process step. is not necessary.
Ce but est atteint selon l'invention par le fait qu'on utilise une filière d'extrusion comportant une fente allongée et un coulisseau obturant l'extrémité de la fente et que le coulisseau est déplacé sur commande en direction radiale pendant l'extrusion de l'arc de cercle dans l'angle de la plaque. Le procédé selon l'invention est donc basé sur l'utilisation d'une filière d'extrusion à section transversale de filière variable, par la modification commandée de laquelle la largeur de lèvre d'étanchéité dans la zone d'angle est modifiée en continu de la façon souhaitée dans la zone concernée et, s'il s'agit d'un angle vif, dans laquelle la lèvre est rallongée avant d'atteindre l'angle et est ensuite raccourcie à nouveau en continu jusqu'à la longueur initiale. Ainsi, il est possible, également dans la zone d'angles droits ou même aigus, de former le cadre extrudé complètement lors de l'opération d'extrusion de telle manière qu'un postmoulage de la lèvre d'étanchéité notamment dans les zones d'angle ne soit plus nécessaire. Le procédé selon l'invention peut être exécuté en principe dans le cas de l'extrusion à l'aide d'une filière d'extrusion menée le long d'une plaque immobile ainsi qu'à l'aide d'une filière d'extrusion disposée de manière fixe, au niveau de laquelle le vitrage est déplacé.This object is achieved according to the invention by the fact that an extrusion die is used comprising an elongated slot and a slide closing the end of the slot and that the slide is moved on command in a radial direction during the extrusion of the arc of a circle in the corner of the plate. The process according to the invention is therefore based on the use of an extrusion die with a variable die cross section, by the controlled modification of which the width of sealing lip in the corner area is continuously modified as desired in the area concerned and, in the case of a sharp angle, in which the lip is lengthened before reaching the angle and is then shortened again continuously to the initial length. Thus, it is also possible, also in the area of right or even acute angles, to form the frame completely extruded during the extrusion operation in such a way that a post-molding of the sealing lip, especially in the areas of angle is no longer necessary. The method according to the invention can be carried out in principle in the case of extrusion using an extrusion die carried along a stationary plate as well as using a die extrusion arranged in a fixed manner, at the level of which the glazing is moved.
Le déplacement commandé du coulisseau pour le rallongement et le raccourcissement de la fente peut être réalisé de différentes manières. Le coulisseau peut ainsi, par exemple, être pourvu d'un entraînement électrique ou pneumatique, qui est commandé par le microprocesseur central de l'installation. Au lieu de cela, en particulier dans les angles, le coulisseau peut aussi être couplé à un galet de guidage latéral, qui roule sur la surface périphérique de la plaque à pourvoir du cadre profilé et déplace le coulisseau de la façon souhaitée, notamment lors du contoumement de l'angle.The controlled displacement of the slide for lengthening and shortening the slot can be achieved in different ways. The slide can thus, for example, be provided with an electric or pneumatic drive, which is controlled by the central microprocessor of the installation. Instead, in particular in the corners, the slider can also be coupled to a lateral guide roller, which rolls on the peripheral surface of the plate to be provided with the profiled frame and moves the slider in the desired way, in particular when angle bypass.
D'autres particularités et avantages de l'invention ressortiront des revendications dépendantes et de la description suivante d'un exemple de réalisation préféré sur la base des dessins annexés.Other features and advantages of the invention will emerge from the dependent claims and from the following description of an example of preferred embodiment based on the accompanying drawings.
Dans les dessins annexés :In the accompanying drawings:
la figure 1 montre une zone d'angle d'un vitrage comportant un cadre extrudé selon l'état de la technique; la figure 2 montre la zone d'angle d'un vitrage selon la figure 1 , mais avec un cadre extrudé selon le procédé de l'invention; Figure 1 shows a corner area of a glazing unit comprising an extruded frame according to the state of the art; Figure 2 shows the corner area of a glazing according to Figure 1, but with an extruded frame according to the method of the invention;
la figure 3 est une vue en élévation de côté d'une tête d'extrusion conduite par un robot comportant une filière d'extrusion selon l'invention pendant l'opération d'extrusion, et • la figure 4 est une vue schématique de l'opération d'extrusion dans la zone d'angle du vitrage. Figure 3 is a side elevational view of an extrusion head driven by a robot comprising an extrusion die according to the invention during the extrusion operation, and • Figure 4 is a schematic view of the extrusion operation in the corner area of the glazing.
L'invention sera illustrée et décrite ci-après dans le contexte d'une utilisation pour des vitrages, en particulier des vitrages automobiles. Mais le procédé de l'invention peut, bien entendu, être également utilisé dans le cas de l'extrusion de cadres profilés sur d'autres objets, comme par exemple des plaques métalliques, des portières, des couvercles de coffres, etc., pour autant que ces objets présentent également la nécessité de modifier la largeur de la lèvre, notamment lorsqu'ils possèdent un ou plusieurs angles vifs et que le cadre profilé soit pourvu d'un segment de profilé faisant saillie au-delà du bord de l'objet.The invention will be illustrated and described below in the context of use for glazing, in particular automotive glazing. However, the process of the invention can, of course, also be used in the case of the extrusion of profiled frames on other objects, such as, for example, metal plates, doors, trunk lids, etc. as far as these objects also have the need to modify the width of the lip, in particular when they have one or more sharp angles and the profiled frame is provided with a profile segment projecting beyond the edge of the object .
Le vitrage 1 représenté dans les dessins présente dans la zone de coin un angle vif 2, en l'occurrence un angle d'une valeur de 90° . Certains vitrages automobiles sont parfois configurés de manière à présenter un tel angle vif, alors que leur contour pour le reste décrit des courbes présentant un rayon plus ou moins grand. De telles formes de vitrage se présentent souvent dans des vitrages latéraux arrière fixes. Des vitrages comportant deux angles vifs sont souvent utilisés pour les lunettes arrière d'automobiles; dans ce cas, les deux coins inférieurs ont habituellement la forme d'angles vifs, tandis que les deux coins supérieurs sont plus ou moins fortement arrondis. Dans d'autres cas, des vitrages, dont tous les coins sont des angles droits, sont utilisés. Le procédé conforme à l'invention peut être utilisé dans tous ces cas.The glazing 1 shown in the drawings has a sharp angle 2 in the corner area, in this case an angle with a value of 90 °. Certain automobile windows are sometimes configured so as to present such a sharp angle, while their outline for the rest describes curves having a greater or lesser radius. Such forms of glazing are often found in fixed rear side glazing. Glazing with two sharp angles is often used for automobile rear windows; in this case, the two lower corners are usually in the form of sharp angles, while the two upper corners are more or less strongly rounded. In other cases, glazing, all of whose corners are right angles, is used. The process according to the invention can be used in all these cases.
Sur le vitrage 1 est tout d'abord appliquée, dans la zone marginale, une couche 3 en forme de cadre en une matière opaque, en règle générale en une encre à cuire. Celle-ci est en général cuite dans la surface du verre lors du traitement thermique auquel sont soumis les vitrages en vue du bombage et/ou de la trempe. Le cadre profilé 4 est ensuite extrudé sur cette couche 3 sur le vitrage au niveau de la zone marginale du vitrage 1 .On the glazing 1 is first of all applied, in the marginal zone, a layer 3 in the form of a frame of an opaque material, as a rule a baking ink. This is generally baked in the surface of the glass during the heat treatment to which the glazing is subjected with a view to bending and / or tempering. The profiled frame 4 is then extruded onto this layer 3 on the glazing at the level of the marginal zone of the glazing 1.
Le cadre profilé 4 présente un segment de base 5 et une aile 7 s'étendant perpendiculairement à celui-ci. La lèvre d'étanchéité 8 faisant saillie vers l'extérieur au-delà du bord du vitrage est reliée à l'aile 7. Sur le segment de baseThe profiled frame 4 has a base segment 5 and a wing 7 extending perpendicular thereto. The sealing lip 8 projecting outwards beyond the edge of the glazing is connected to the wing 7. On the base segment
5 est appliquée, lors du montage du vitrage, la masse de colle avec laquelle le vitrage est collé au rebord de fixation du cadre de fenêtre de la carrosserie. Ce segment de profilé 5 peut aussi présenter, en principe, une autre section transversale ; le cas échéant, ce segment de base 5 peut aussi être totalement supprimé et la masse de colle est alors directement déposée sur le vitrage, de préférence sur ia couche opaque 3. Pour obtenir dans la zone d'angle une section transversale régulière, la filière d'extrusion dans son déplacement relatif à la périphérie du vitrage doit décrire dans l'angle un trajet circulaire, selon lequel l'axe du cordon profilé décrit une courbe de rayon R, de dimension au moins environ 20 mm. Inévitablement, le côté extérieur 1 0 de la lèvre décrira de la sorte également, un arc de cercle autour du même centre de cercle avec pour conséquence que, dès le début de la rotation de la filière d'extrusion la partie de lèvre 8 faisant saillie au-delà du bord du vitrage se raccourcira. Dans la zone d'angle extérieure extrême 1 1 , la lèvre 8 ne s'étend même plus du tout jusqu'au bord du vitrage. Les phénomènes sont les mêmes si le bord de la baie comporte un méandre dont le bord du vitrage ne possède pas l'équivalent, alors la lèvre s'écarte ou se rapproche indûment de la carrosserie.5 is applied, during the mounting of the glazing, the mass of adhesive with which the glazing is glued to the fixing edge of the window frame of the bodywork. This profile segment 5 can also, in principle, have another cross section; if necessary, this base segment 5 can also be completely removed and the adhesive mass is then directly deposited on the glazing, preferably on the opaque layer 3. To obtain in the corner area a regular cross section, the die extrusion in its relative movement to the periphery of the glazing must describe in the corner a circular path, along which the axis of the profiled bead describes a curve of radius R, of dimension at least about 20 mm. Inevitably, the outer side 10 of the lip will also thus describe an arc of a circle around the same center of a circle with the consequence that, from the start of the rotation of the extrusion die, the lip part 8 protruding beyond the edge of the glazing will shorten. In the extreme outer corner area 1 1, the lip 8 does not even extend at all to the edge of the glazing. The phenomena are the same if the edge of the bay has a meander whose edge of the glazing does not have the equivalent, then the lip deviates or approaches the body unduly.
Dans le cas de l'exécution du procédé selon l'invention, on obtient, par contre, une forme de la lèvre 8 adaptée et, dans le cas d'un coin, telle qu'elle apparaît sur la figure 2. Puisque, dans la zone d'angle, le mouvement de pivotement de la filière d'extrusion et son déplacement selon un trajet circulaire restent en principe inchangés, la forme et l'allure des segments de profilé 5 et 7 sont, en principe, les mêmes que dans le cas représenté sur la figure 1 . La longueur I de la lèvre d'étanchéité 8 faisant saillie vers l'extérieur augmente cependant continûment, à partir de l'endroit où débute le mouvement circulaire et de rotation de la filière d'extrusion, jusqu'à ce que la filière d'extrusion ait parcouru la moitié de l'arc de cercle. A cet endroit, la lèvre 8 a la longueur L.In the case of carrying out the method according to the invention, on the other hand, a suitable shape of the lip 8 is obtained and, in the case of a wedge, as it appears in FIG. 2. Since, in the angle zone, the pivoting movement of the extrusion die and its movement along a circular path remain in principle unchanged, the shape and shape of the profile segments 5 and 7 are, in principle, the same as in the case shown in Figure 1. The length I of the sealing lip 8 projecting outwards increases however continuously, from the point where the circular and rotational movement of the extrusion die begins, until the extrusion die has traversed half of the arc of a circle. At this point, the lip 8 has the length L.
Ensuite, la longueur de la lèvre 8 décroît continûment, jusqu'à ce qu'elle ait atteint à nouveau sa longueur I d'origine à la fin de l'arc de cercle. De cette manière, la lèvre 8 a à présent dans la zone d'angle du vitrage la forme telle qu'elle est représentée sur la figure 2, c'est-à-dire que la partie de la lèvre faisant saillie au-delà des bords du vitrage s'étend aussi dans la zone d'angle parallèlement au bord du vitrage, et seul le coin extérieur extrême de la lèvre est quelque peu arrondi.Then, the length of the lip 8 decreases continuously, until it has again reached its original length I at the end of the circular arc. In this way, the lip 8 now has in the corner area of the glazing the shape as shown in FIG. 2, that is to say that the part of the lip protruding beyond the edges of the glazing also extends into the corner area parallel to the edge of the glazing, and only the extreme outer corner of the lip is somewhat rounded.
La figure 3 est une vue en élévation de côté d'une tête d'extrusion pour la fabrication du cadre profilé extrudé selon l'invention. La tête d'extrusion comprend, entre autres, le corps de filière proprement dit 14 comportant l'orifice de filière calibré 1 5, le coulisseau 1 6 pouvant se déplacer horizontalement et, dans le cas représenté, où la tête d'extrusion est commandée mécaniquement, un galet de guidage 1 7 relié au coulisseau 1 6, qui roule sur la surface périphérique 1 8 du vitrage 1 . La fente 1 5' de l'orifice de filière 1 5, formant la lèvre d'étanchéité, présente une longueur L, qui est sensiblement supérieure à la longueur I de la lèvre d'étanchéité dans la zone des bords longitudinaux du vitrage. La fente 1 5' est obturée à son extrémité par le coulisseau 1 6 au point que la fente à lèvre 1 5' libre, présente dans la zone des bords longitudinaux rectilignes du vitrage, la longueur I souhaitée. Le coulisseau 1 6 et le palier 1 9 portant le galet de guidage 1 7, qui sont reliés l'un à l'autre de manière fixe, sont montés à coulissement via un palier à glissement 20 sur une tige de guidage horizontale 21 . Une force de pression est exercée par le ressort hélicoïdal 22 sur le dispositif à coulisseau relié au galet de guidage 1 7, le galet de guidage 1 7 étant de ce fait pressé contre la surface périphérique 1 8 du vitrage 1 . La fixation 23 portant la tige de guidage 21 est reliée de manière rigide à la tête d'extrusion portant la filière d'extrusion. La filière d'extrusion 14 est pourvue de deux canaux 26, 27 séparés l'un de l'autre, à travers lesquels le polymère à extruder est amené à l'orifice de filière 1 5, 1 5' . Le débit volumique du polymère peut être réglé dans les deux canaux 26, 27 indépendamment l'un de l'autre, comme décrit dans le document EP O 444 998 B1 . Les valves réglant le débit volumique dans les deux canauxFigure 3 is a side elevational view of an extrusion head for the manufacture of the extruded profile frame according to the invention. The extrusion head comprises, inter alia, the die body proper 14 comprising the calibrated die orifice 1 5, the slide 1 6 being able to move horizontally and, in the case shown, where the extrusion head is controlled mechanically, a guide roller 1 7 connected to the slide 1 6, which rolls on the peripheral surface 1 8 of the glazing 1. The slot 1 5 ′ of the die orifice 1 5, forming the sealing lip, has a length L, which is substantially greater than the length I of the sealing lip in the region of the longitudinal edges of the glazing. The slot 1 5 ′ is closed at its end by the slide 1 6 to the point that the free lip slot 1 5 ′, has in the region of the rectilinear longitudinal edges of the glazing, the desired length I. The slide 1 6 and the bearing 1 9 carrying the guide roller 1 7, which are fixedly connected to each other, are slidably mounted via a sliding bearing 20 on a horizontal guide rod 21. A pressing force is exerted by the helical spring 22 on the slide device connected to the guide roller 1 7, the guide roller 1 7 therefore being pressed against the peripheral surface 1 8 of the glazing 1. The attachment 23 carrying the guide rod 21 is rigidly connected to the extrusion head carrying the extrusion die. The extrusion die 14 is provided with two channels 26, 27 separated from each other, through which the polymer to be extruded is brought to the die orifice 1 5, 1 5 '. The volume flow rate of the polymer can be adjusted in the two channels 26, 27 independently of each other, as described in the document EP O 444 998 B1. Valves regulating the volume flow in the two channels
26, 27 peuvent être commandées de préférence en fonction de la position du coulisseau 16, et de telle sorte que le débit volumique dans le canal 27 est augmenté et le débit volumique dans le canal 26 diminué à mesure que la fente à lèvre 1 5' est ouverte davantage. Les débits volumiques sont de ce fait adaptés aux besoins en masse de polymère différents à l'intérieur de l'orifice de filière pendant la rotation de la tête d'extrusion.26, 27 can be controlled preferably according to the position of the slide 16, and so that the volume flow in the channel 27 is increased and the volume flow in the channel 26 decreases as the lip slot 1 5 ' is more open. The volume flow rates are therefore adapted to the different mass requirements of polymer inside the die orifice during the rotation of the extrusion head.
La figure 4 montre dans une vue en plan la séquence de mouvements de la filière 14 et du coulisseau 1 6 lors de l'extrusion du cadre profilé 4 dans une zone d'angle du vitrage 1 . On reconnaît que le galet de guidage 1 7 progressant sur la surface périphérique 1 8 se déplace, lors du mouvement de pivotement de la filière 1 4, vers l'extérieur dans la direction de la flèche F avec le coulisseau 1 6 couplé au galet de guidage, la fente de filière 1 5' formant la lèvre 8 étant de ce fait progressivement libérée de manière continue. Dès que le galet de guidage atteint l'angle 2 du vitrage lors du mouvement de pivotement de la filière 14 qui se poursuit, la direction de mouvement du coulisseau 1 6 s'inverse, grâce à quoi la fente de filière 1 5' se raccourcit à nouveau continûment, jusqu'à ce qu'elle ait atteint sa position finale au terme du mouvement de pivotement de la filière 14.FIG. 4 shows in a plan view the sequence of movements of the die 14 and of the slide 1 6 during the extrusion of the profiled frame 4 in a corner area of the glazing 1. It is recognized that the guide roller 1 7 progressing on the peripheral surface 1 8 moves, during the pivoting movement of the die 1 4, outward in the direction of arrow F with the slide 1 6 coupled to the roller guide, the die slot 1 5 ′ forming the lip 8 being thereby progressively released continuously. As soon as the guide roller reaches the angle 2 of the glazing during the pivoting movement of the die 14 which continues, the direction of movement of the slide 1 6 reverses, whereby the die slot 1 5 'becomes shorter again continuously, until it has reached its final position at the end of the pivoting movement of the die 14.
A la différence des procédés antérieurs, notamment de celui exposé dans le document EP O 524 060 B1 , le procédé de l'invention permet d'obtenir un produit, vitrage automobile notamment, qui comporte dans les angles, un cadre dont la lèvre, comme le reste du cordon constitue une continuité avec les parties linéaires voisines. Dans les techniques antérieures en revanche, le raccord entre la nouvelle partie moulée dans le coin et les parties du profilé extrudé voisines était visible sauf dans le cas où une correction cosmétique était apportée. Unlike the previous methods, in particular that described in document EP 0 524 060 B1, the method of the invention makes it possible to obtain a product, automobile glazing in particular, which comprises in the corners, a frame whose lip, as the rest of the cord constitutes a continuity with the neighboring linear parts. In the prior techniques on the other hand, the connection between the new part molded in the corner and the parts of the neighboring extruded profile was visible except in the case where a cosmetic correction was made.

Claims

REVENDICATIONS
1 . Procédé pour l'extrusion sur la zone marginale d'une plaque comportant au moins un angle, en particulier un vitrage, d'un cordon profilé en forme de cadre, présentant une lèvre débordant de la plaque, en un élastomère, à l'aide d'une filière d'extrusion, le cordon profilé étant déposé en arc de cercle dans la zone de l'angle, caractérisé en ce qu'on utilise une filière d'extrusion, comportant une fente allongée et un coulisseau obturant l'extrémité de la fente et en ce que le coulisseau est déplacé sur commande en direction radiale pendant l'extrusion de l'arc de cercle dans l'angle de la plaque. 1. Method for the extrusion on the marginal zone of a plate comprising at least one angle, in particular a glazing, of a profiled bead in the form of a frame, having a lip projecting from the plate, made of an elastomer, using an extrusion die, the profiled bead being deposited in an arc of a circle in the corner area, characterized in that an extrusion die is used, comprising an elongated slot and a slide closing the end of the slot and in that the slider is moved on command in the radial direction during the extrusion of the arc in the corner of the plate.
2. Procédé suivant la revendication 1 , caractérisé en ce que la commande de déplacement du coulisseau est réalisée par un microprocesseur commandant également le déplacement relatif de la filière d'extrusion et du vitrage.2. Method according to claim 1, characterized in that the movement control of the slide is performed by a microprocessor also controlling the relative movement of the extrusion die and the glazing.
3. Procédé suivant la revendication 1 , caractérisé en ce que la commande de déplacement du coulisseau est réalisée par un galet de guidage accouplé au coulisseau, qui progresse sur la surface périphérique de la plaque et est pressé contre son bord périphérique.3. Method according to claim 1, characterized in that the movement control of the slide is performed by a guide roller coupled to the slide, which advances on the peripheral surface of the plate and is pressed against its peripheral edge.
4. Plaque, notamment vitrage automobile, équipée par extrusion selon la revendication 1 , d'un cordon profilé en forme de cadre possédant une lèvre débordant de la plaque, la plaque comportant au moins un angle dans lequel le cordon est déposé en arc de cercle, caractérisé en ce que dans l'angle de la plaque, l'extrémité de la lèvre s'écarte du reste du cordon et en ce que dans l'angle, la lèvre comme le reste du cordon constitue une continuité avec les parties linéaires voisines.4. Plate, in particular automobile glazing, equipped by extrusion according to claim 1, of a profiled cord in the form of a frame having a lip projecting from the plate, the plate comprising at least one angle in which the cord is deposited in an arc of a circle. , characterized in that in the corner of the plate, the end of the lip moves away from the rest of the bead and in that in the corner, the lip like the rest of the bead constitutes a continuity with the neighboring linear parts .
5. Dispositif pour l'exécution du procédé selon la revendication 1 , comportant une tête d'extrusion portant une filière d'extrusion, un dispositif de fixation soit pour la plaque à pourvoir du cordon profilé extrudé soit pour la tête d'extrusion et un manipulateur automatique déplaçant la filière d'extrusion et le vitrage l'un par rapport à l'autre selon un programme prédéterminé, caractérisé en ce que la filière d'extrusion (14) présente une fente ( 1 5') allongée et un coulisseau (1 6) obturant la fente allongée, coulisseau dont le mouvement de coulissement peut être commandé pour le rallongement et le raccourcissement de la fente à lèvre dans la zone d'angle de la plaque en fonction du mouvement de pivotement angulaire entre le vitrage et la filière d'extrusion. 5. Device for carrying out the method according to claim 1, comprising an extrusion head carrying an extrusion die, a fixing device either for the plate to be provided with the extruded profiled bead or for the extrusion head and a automatic manipulator moving the extrusion die and the glazing relative to each other according to a predetermined program, characterized in that the extrusion die (14) has an elongated slot (1 5 ') and a slide ( 1 6) closing the elongated slot, a slide whose sliding movement can be controlled for lengthening and shortening the lip slot in the corner area of the plate as a function of the angular pivoting movement between the glazing and the die extrusion.
6. Dispositif selon la revendication 5, caractérisé en ce que le coulisseau est pourvu d'un entraînement, qui est commandé par un microprocesseur central du dispositif.6. Device according to claim 5, characterized in that the slide is provided with a drive, which is controlled by a central microprocessor of the device.
7. Dispositif selon la revendication 5, caractérisé en ce que le coulisseau (1 6) est relié à un galet de guidage (1 7) roulant sur la surface périphérique (18) de la plaque, qui est monté à coulissement sur une tige de guidage (21 ) conjointement avec le coulisseau (1 6) parallèlement au plan de sortie de l'orifice de filière ( 1 5).7. Device according to claim 5, characterized in that the slide (1 6) is connected to a guide roller (1 7) rolling on the peripheral surface (18) of the plate, which is slidably mounted on a rod guide (21) together with the slide (1 6) parallel to the outlet plane of the die orifice (1 5).
8. Dispositif selon la revendication 7, caractérisé en ce que le contact du galet de guidage ( 1 7) avec la surface périphérique est assuré par un moyen de pression élastique tel qu'un ressort hélicoïdal (22). 8. Device according to claim 7, characterized in that the contact of the guide roller (1 7) with the peripheral surface is ensured by an elastic pressure means such as a helical spring (22).
PCT/FR1997/000226 1996-02-07 1997-02-05 Method for extruding a frame-shaped profiled rim onto a glass pane, extrusion die therefor, and resulting product WO1997028947A1 (en)

Priority Applications (4)

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JP9528222A JPH11503381A (en) 1996-02-07 1997-02-05 Method for extruding frame-shaped modified rim onto glass pane, extrusion die therefor, and resulting product
BR9702069A BR9702069A (en) 1996-02-07 1997-02-05 Process for extrusion over the marginal zone of a plate that has at least one angle, in particular a pane of a cord or a profile in the form of a plate, notably a motor vehicle pane and device for carrying out the process
EP97904491A EP0819050A1 (en) 1996-02-07 1997-02-05 Method for extruding a frame-shaped profiled rim onto a glass pane, extrusion die therefor, and resulting product
MXPA/A/1997/007659A MXPA97007659A (en) 1996-02-07 1997-10-06 Procedure for extruding a profiled cord frame enforma on a crystal, extrusion row for executing the procedure and productobten

Applications Claiming Priority (2)

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DE19604397A DE19604397C1 (en) 1996-02-07 1996-02-07 Device for extruding a frame-like profile strand onto a glass pane
DE19604397.2 1996-02-07

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WO1997028947A1 true WO1997028947A1 (en) 1997-08-14

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EP (1) EP0819050A1 (en)
JP (1) JPH11503381A (en)
KR (1) KR19980703615A (en)
BR (1) BR9702069A (en)
CZ (1) CZ317297A3 (en)
DE (1) DE19604397C1 (en)
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US5233805A (en) * 1989-10-14 1993-08-10 Tokai Kogyo Kabushiki Kaisha Molding for automotive front glass and molding apparatus
DE4326179A1 (en) * 1992-08-10 1994-02-17 Volkswagen Ag Bonding frameless glass pane on to support in car window production - by extruding two overlapping e.g. adhesive beads on to edges which meet at small radius corners and pressing to uniform thickness.
EP0634263A1 (en) * 1993-06-25 1995-01-18 Asahi Glass Company Ltd. A method of making a window frame and a window panel with a window frame
EP0638408A1 (en) * 1993-08-09 1995-02-15 Saint Gobain Vitrage International Method and apparatus for making a window panel with a frame of polymeric material
EP0727298A1 (en) * 1995-02-16 1996-08-21 Mercedes-Benz Ag Method of applying a viscous material to the edging strip and to the corner regions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3294548B1 (en) 2015-05-15 2022-05-25 Saint-Gobain Glass France Pane with thermal radiation reflecting coating, opaque masking print applied directly to the thermal radiation reflecting coating and fastening or sealing element applied on the opaque masking print

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KR19980703615A (en) 1998-12-05
JPH11503381A (en) 1999-03-26
DE19604397C1 (en) 1997-07-31
EP0819050A1 (en) 1998-01-21
MX9707659A (en) 1997-11-29
PL322595A1 (en) 1998-02-02
BR9702069A (en) 1998-07-07
CZ317297A3 (en) 1998-02-18

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