WO1997023589A1 - Concentre de lustre nacre - Google Patents

Concentre de lustre nacre Download PDF

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Publication number
WO1997023589A1
WO1997023589A1 PCT/EP1996/005600 EP9605600W WO9723589A1 WO 1997023589 A1 WO1997023589 A1 WO 1997023589A1 EP 9605600 W EP9605600 W EP 9605600W WO 9723589 A1 WO9723589 A1 WO 9723589A1
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WO
WIPO (PCT)
Prior art keywords
pearlescent
concentrate according
group
emulsifiers
acid
Prior art date
Application number
PCT/EP1996/005600
Other languages
German (de)
English (en)
Inventor
Achim Ansmann
Rolf Kawa
Gabriele Strauss
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to AU13716/97A priority Critical patent/AU1371697A/en
Publication of WO1997023589A1 publication Critical patent/WO1997023589A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds

Definitions

  • the invention relates to a pearlescent concentrate in the form of a flowable or pumpable, aqueous dispersion with a content of 5-50% by weight of pearlescent components.
  • Aqueous pearling preparations and cosmetic preparations can be given a pearlescent, aesthetically pleasing appearance by incorporating substances which, after cooling, precipitate out in the form of fine, pearlescent-looking crystals and remain dispersed in the preparations.
  • pearlescent substances are, for. B. the mono-, di- and optionally triesters of ethylene glycol, propylene glycol and oligomeric alkylene glycols of this type or glycerol with C 14 -C 22 fatty acids, fatty acids and monoalkanolamides of fatty acids.
  • the application thus relates to pearlescent concentrates in the form of a flowable, aqueous dispersion with 5 to 50% by weight of pearlescent components and 5 to 55% by weight of emulsifiers, characterized in that acylated amino acids of the general formula (I) are used as emulsifiers,
  • R -CO stands for a saturated or mono- or polyunsaturated, linear or branched, aliphatic acyl residue with 8 to 22 carbon atoms and NH-Y for an amino acid residue, the amino acid being selected from the group consisting of glutamic acid and aspartic acid is formed, or salts of these acylated amino acids are contained.
  • Pearlescent components are fusible or wax bodies which crystallize in the form of fine, pearlescent bodies when their aqueous solutions or emulsions cool in a temperature range of about 30-90 ° C.
  • meltable fat or wax bodies include
  • R is a linear fatty acyl group with 14 to 22 C atoms, R is hydrogen
  • n 2 or 3 and x is a number from 1 to 4,
  • R is an alkyl group with 8 to 22 C atoms, in particular with 8 to 18
  • Atoms, and X represents a group -CH -CH -OH, a group -CH -CH -CH -OH or a group -C (CH) -OH,
  • mono- and diesters of the named glycols with fatty acid mixtures eg. B. with hardened tallow fatty acid, Palm fatty acid or with the saturated C -C fatty acid fraction of tallow fat
  • the ethylene glycol mono- and / or diester of palmitic and / or stearic acid are particularly suitable.
  • Preferred monoalkanolamides are the monoethanolamides. These compounds can contain a uniform alkyl radical. However, it is common in the manufacture of the alkanolamides of fatty acid mixtures from natural sources, e.g. Coconut fatty acids to go out, so that there are appropriate mixtures with respect to the alkyl radicals.
  • linear fatty acids such. B. palmitic acid, stearic acid, arachic acid or behenic acid
  • technical fatty acid cuts are also suitable which consist entirely or predominantly of fatty acids with 16 to 22 carbon atoms, for.
  • B. palmitic stearic acid fractions such as those obtained from tallow fatty acid or palm fatty acid by separating the fatty acids liquid at +5 ° C.
  • palmitic stearic acid fractions such as are obtainable by hardening tallow fatty acid or palm fatty acid.
  • esters "of glycerol include the mono-, di- and tri particular with lauric acid, palmitic acid, stearic acid and behenic acid, and mixtures of these fatty acids.
  • the pearlescent concentrates according to the invention can contain exclusively representatives of one of these classes of compounds as well as mixtures of representatives of several of these classes of compounds.
  • Preferred pearlescent components are representatives of the first three classes. Fatty acid mono- or dialkanolamides and their derivatives have recently been suspected of being involved in the formation of nitrosamines. It may therefore be desirable to formulate cosmetic preparations without such alkanolamines and alkanolamine derivatives. For this reason, linear fatty acids and in particular compounds of the formula (II) can be particularly preferred pearlescent components.
  • Pearlescent concentrates whose pearlescent components comprise at least 70% by weight, in particular at least 90% by weight, of ethylene glycol distearate are very particularly preferred.
  • mixtures of ethylene glycol fatty acid esters may also be preferred, as disclosed in German patent application 195 11 569.4.
  • the pearlescent concentrates according to the invention contain emulsifiers of the N-acylated amino acid type according to the general formula (I).
  • the group in the R -CO represents a saturated or mono- or polyunsaturated, linear or branched, aliphatic acyl radical having 8 to 22 carbon atoms.
  • This group preferably stands for the acyl radical of caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadoleic acid, behenic acid or erucic acid or mixtures thereof, in particular, or mixtures thereof, such as, technical processing of natural oils and fats.
  • Saturated, linear or branched aliphatic acyl radicals having 12-18 carbon atoms are particularly preferred.
  • the group NH-Y in formula (I) represents an amino acid residue, the amino acid being glutamic acid or aspartic acid.
  • Compounds of the formula (I) in which the group NH-Y represents glutamic acid have proven to be particularly suitable according to the invention.
  • emulsifiers of the formula (I) can be used in the acid form and neutralized with suitable bases in the course of the dispersion. However, it has proven advantageous to use the compounds directly in salt form. Suitable salts are, for example
  • Alkali metal salts such as in particular the sodium and potassium salts
  • Alkaline earth metal salts such as in particular the magnesium and calcium salts
  • Sodium N-acylglutamates whose acyl groups are natural mixtures, in particular derived from coconut oils, have proven to be very particularly suitable emulsifiers.
  • the pearlescent concentrates according to the invention can contain the amino acid derivatives of the formula (I) mentioned as the only emulsifiers. This is a preferred embodiment of the invention. 97/23589 PC17EP96 / 05600
  • a further preferred embodiment may also contain further emulsifiers.
  • these emulsifiers can be both nonionic and ionic emulsifiers. Both ionic and, in particular, anionic, zwitterionic and ampholytic emulsifiers can be used as ionic emulsifiers.
  • Anionic emulsifiers to be used according to the invention are, for example, alkyl sulfates and alkyl polyethylene glycol ether sulfates with 8 to 22 carbon atoms in the alkyl chain and 1 to 15, in particular 1 to 6, ethylene glycol ether groups in the molecule, which in the form of their alkali metal, magnesium, ammonium, mono-, di- or trialkanolammonium salts with 2 to 3 carbon atoms in the alkanol group.
  • anionic surfactants are alkane sulfonates, alpha-olefin sulfonates, alpha-sulfofatty acid methyl esters, fatty alcohol (polyglycol ether) carboxylates, sulfosuccinic acid mono- and dialkyl esters, sulfosuccinic acid ester salts, acyl isethionates, acyl taurides and acyl bisar 22, each with 12 , C atoms in the alkyl or acyl chain.
  • Soaps can also be used as emulsifiers. This can e.g. B. can be achieved by a small part, i.e. about 1 to 20 wt .-% - of the linear, saturated fatty acids saponified by added alkali hydroxide and in this way converted into an anionic emulsifier.
  • Preferred anionic emulsifiers are the alkyl polyethylene glycol ether sulfates, such as sodium lauryl polyglycol ether sulfate.
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and
  • zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N- dimethylammonium glycinate, for example the cocoalkyldimethylammonium glycinate, N-acylaminopropyl-NN-dimethylammoniumglycinate, for example the cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl-3-hydroxyethyl-imidazolines each with 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8 -C 18 -alkyl or acyl group, have at least one free one in the molecule
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylamino-butyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamido propylglycines, N-alkyl taurines, N-alkyl sarcosines, 2-alkyl aminopropionic acids and with each about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkyl aminopropionate, cocoacylaminoethyl aminopropionate and C 12- ⁇ 8 - sarcosine.
  • Quaternary ammonium surfactants for example alkyltrimethylammonium chlorides and dialkyldimethylammonium chlorides, e.g. As cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride and lauryldimethylbenzylammonium chloride, cetylpyridinium chloride and tallow alkyl tris (oligooxy-alkyl) ammonium phosphate. Furthermore, the very readily biodegradable quaternary ester compounds, such as, for example, the dialkylammonium methosulfates sold under the trademark Stepantex R. and methyl-hydroxyalkyl-dialkoyloxyalkyl-ammonium methosulfates can be used as cationic surfactants.
  • the dialkylammonium methosulfates sold under the trademark Stepantex R.
  • nonionic emulsifiers can also be used, the z. B. contain a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • Such connections are, for example
  • C 8-22 fatty acids preference being given to those compounds which contain 2-4 glycerol units and / or branched, unsaturated or hydroxy-substituted fatty acids, and also
  • nonionic emulsifiers are alkyl polyglycosides of the general formula (IV) R 5 O- (Z) y (IV)
  • R stands for an alkyl radical with 6 to 22 carbon atoms
  • Z for a mono- or oligosaccharide
  • y for a number from 1.1 to 5, or their addition products with 1 to 10 molecules of ethylene oxide and / or propylene oxide are.
  • alkyl polyglycosides according to formula (IV) are further characterized by the following parameters:
  • the alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.
  • alkyl glycosides which can be used according to the invention can only contain one
  • 5 voted alkyl radical R contain. Usually, however, these compounds are made from natural fats and oils or mineral oils. In this case, the alkyl radicals are mixtures corresponding to the starting compounds or corresponding to the respective working up of these compounds.
  • alkyl polyglycosides in which R consists essentially of C and C alkyl groups, essentially of C and C alkyl groups, essentially from C - to C -alkyl groups or
  • Any mono- or oligosaccharides can be used as sugar building block Z.
  • Sugar with 5 or 6 carbon atoms and the corresponding oligosaccharides are usually used.
  • Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, old rose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar units are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • alkyl polyglycosides which can be used according to the invention contain on average 1.1 to 5 sugar units. Alkyl glycosides with y values of 1.1 to 2 are preferred. Alkyl glycosides in which y is 1.1 to 1.4 are very particularly preferred.
  • alkoxylated homologs of the alkyl polyglycosides mentioned can also be used according to the invention.
  • These homologues can contain an average of up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • These products also usually do not represent uniform compounds, but instead have a corresponding homolog distribution depending on the ethoxylation process chosen.
  • Such alkoxylated compounds can be obtained, for example, by using ethoxylated fatty alcohols for the synthesis of the alkyl polyglycosides.
  • the use of the non-alkoxylated compounds is preferred.
  • the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is generally preferred to use native vegetable and animal raw materials, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution and those with a narrow homolog distribution can be used.
  • “Normal” homolog distribution is understood to mean mixtures of homologs which are obtained as catalysts from the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates.
  • narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with a narrow homolog distribution can be preferred.
  • the pearlescent concentrates can contain representatives of one or more of the surfactant classes mentioned.
  • pearlescent concentrates are mainly added to formulations with anionic surfactants, in a preferred embodiment the pearlescent concentrates according to the invention contain only anionic and / or nonionic emulsifiers as further emulsifiers.
  • the pearlescent concentrates according to the invention can additionally contain low molecular weight, polyhydric alcohols.
  • Low molecular weight, polyhydric alcohols of a group preferably used contain 2-12 carbon atoms and 2-10 hydroxyl groups.
  • Such alcohols are, for example, ethylene glycol, 1,2-and 1,3-propylene glycol, glycerin, erythritol, arabitol, adonitol, xylitol, sorbitol, mannitol, dulcitol, glucose and sucrose.
  • glycerol, 1,2-propylene glycol, 1,3-propylene glycol, sorbitol and / or glucose is particularly preferred.
  • glycerin as a low molecular weight, polyhydric alcohol leads to pearlescent concentrates that give the end products a particularly brilliant pearlescent.
  • Another group of preferably used low molecular weight, polyhydric alcohols is formed from oligomeric ethers, in particular based on ethylene glycol, propylene glycol and glycerol. Products whose average molecular weight is below about 700 daltons are particularly suitable.
  • the oligomers, especially the di-, tri- and tetramers, of ethylene glycol and glycerol can be used according to the invention.
  • the low molecular weight, polyhydric alcohols are preferably added in amounts of 0.1 to 40% by weight, based on the overall preparation. Amounts of 0.1 to 10 wt .-% of low molecular weight, polyhydric alcohols have a particularly positive effect on the pumping and flow behavior, while amounts of more than 10 wt .-%, each based on the entire pearlescent concentrate, in many cases can replace special preservation.
  • the pearlescent concentrates according to the invention essentially contain water.
  • buffer substances can be used in minor amounts to adjust the pH to values between 2 and 8, e.g. As citric acid and / or sodium citrate, and inorganic cations, for example sodium chloride, may be included as thickeners.
  • the pearlescent concentrates according to the invention are provided with the usual preservatives known to those skilled in the art.
  • preservatives are formic acid, benzoic acid and pHB esters.
  • the pearlescent concentrates are free of preservatives.
  • preservative-free means pearlescent concentrates to which no preservatives have been added. They therefore preferably do not contain any preservatives or preservatives only in the amounts in which they are introduced due to the selected individual raw materials.
  • the pearlescent concentrates according to the invention can be prepared in such a way that components (A), (B) and (C) are first heated together to a temperature which is about 1 to 30 ° C. above the melting point. In most cases this will be a temperature of around 60 to 90 ° C. The water heated to approximately the same temperature is then added to this mixture. If an ionic, water-soluble emulsifier is used as the emulsifier, it may be preferred to dissolve it in the water phase and to introduce it into the mixture together with the water. The aqueous phase can also optionally already contain the buffer substances in solution. The resulting dispersion is then cooled to room temperature, ie to about 25 ° C., with constant stirring. The viscosity of the pearlescent concentrate is so in most cases low that the use of special stirring units such as homogenizers or other high-speed mixing devices can be dispensed with.
  • the pearlescent concentrates according to the invention are suitable for producing cloudy and pearlescent liquid, aqueous preparations of water-soluble surface-active substances.
  • You can e.g. in liquid detergents and cleaners such as dishwashing detergents, liquid mild detergents and liquid soaps, but preferably in liquid personal cleansing and care products such as Hair detergents (shampoos), liquid hand and body detergents, shower bath preparations, bath additives (foam baths), hair rinsing agents or hair dye preparations are incorporated.
  • the pearlescent concentrates according to the invention are added to the clear aqueous preparations at 0 to 40 ° C. in an amount of 0.5 to 20% by weight, in particular 1.5 to 10% by weight, of the preparation and distributed therein with stirring. Depending on the preparation and use concentration, a metallic gloss, dense to slightly glossy, extremely dense pearlescence is produced.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

L'invention concerne un concentré de lustre nacré sous forme d'une dispersion fluide, aqueuse comprenant 5 à 50 % en poids de composants formant le lustre nacré et 5 à 55 % en poids d'émulsifiants. Le concentré est caractérisé en ce que les émulsifiants sont des aminoacides acylés de la formule générale (I): R1-CO-NH-Y, où R1-CO représente un reste acyle aliphatique linéaire ou ramifé, saturé ou insaturé une ou plusieurs fois et renfermant 8 à 22 atomes de carbone et NH-Y représente un reste aminoacide, l'aminoacide étant sélectionné dans le groupe formé par l'acide glutamique et l'acide aspartique, ou les émulsifiants sont des sels de ces aminoacides acylés. Le concentré est caractérisé notamment par un lustre nacré particulièrement brillant. Les concentrés peuvent contenir d'autres émulsifiants et de préférence des alcools polyvalents à faible poids moléculaire.
PCT/EP1996/005600 1995-12-22 1996-12-13 Concentre de lustre nacre WO1997023589A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU13716/97A AU1371697A (en) 1995-12-22 1996-12-13 Nacreous lustre concentrate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19548315.4 1995-12-22
DE19548315A DE19548315A1 (de) 1995-12-22 1995-12-22 Perlglanzkonzentrat

Publications (1)

Publication Number Publication Date
WO1997023589A1 true WO1997023589A1 (fr) 1997-07-03

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PCT/EP1996/005600 WO1997023589A1 (fr) 1995-12-22 1996-12-13 Concentre de lustre nacre

Country Status (3)

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AU (1) AU1371697A (fr)
DE (1) DE19548315A1 (fr)
WO (1) WO1997023589A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1005902A2 (fr) * 1998-11-18 2000-06-07 Zschimmer & Schwarz Italiana S.p.A. Système d'emulsion preformé

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10102007A1 (de) * 2001-01-18 2002-10-10 Cognis Deutschland Gmbh Tensidgemisch
DE102016213569A1 (de) * 2016-07-25 2018-01-25 Henkel Ag & Co. Kgaa Acylglutamate als textilpflegende Inhaltsstoffe

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61137812A (ja) * 1984-12-07 1986-06-25 Ajinomoto Co Inc パ−ル光沢を有する洗浄剤組成物
DE3617306A1 (de) * 1985-05-23 1986-11-27 Lion Corp Verfahren zur herstellung einer hochkonzentrierten perliermitteldispersion
EP0268992A2 (fr) * 1986-11-28 1988-06-01 Henkel Kommanditgesellschaft auf Aktien Concentrés nacrés fluidisables
EP0376083A2 (fr) * 1988-12-23 1990-07-04 Henkel Kommanditgesellschaft auf Aktien Concentré d'agent nacré s'écoulant librement
JPH02212598A (ja) * 1989-02-13 1990-08-23 Kawaken Fine Chem Co Ltd 液体洗浄剤組成物
JPH07101838A (ja) * 1993-10-01 1995-04-18 Kao Corp シャンプー組成物の製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61137812A (ja) * 1984-12-07 1986-06-25 Ajinomoto Co Inc パ−ル光沢を有する洗浄剤組成物
DE3617306A1 (de) * 1985-05-23 1986-11-27 Lion Corp Verfahren zur herstellung einer hochkonzentrierten perliermitteldispersion
EP0268992A2 (fr) * 1986-11-28 1988-06-01 Henkel Kommanditgesellschaft auf Aktien Concentrés nacrés fluidisables
EP0376083A2 (fr) * 1988-12-23 1990-07-04 Henkel Kommanditgesellschaft auf Aktien Concentré d'agent nacré s'écoulant librement
JPH02212598A (ja) * 1989-02-13 1990-08-23 Kawaken Fine Chem Co Ltd 液体洗浄剤組成物
JPH07101838A (ja) * 1993-10-01 1995-04-18 Kao Corp シャンプー組成物の製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8632, Derwent World Patents Index; Class D21, AN 86-207149, XP002029900 *
DATABASE WPI Section Ch Week 9040, Derwent World Patents Index; Class D21, AN 90-301362, XP002029899 *
DATABASE WPI Section Ch Week 9524, Derwent World Patents Index; Class D21, AN 95-182873, XP002029898 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1005902A2 (fr) * 1998-11-18 2000-06-07 Zschimmer & Schwarz Italiana S.p.A. Système d'emulsion preformé
EP1005902A3 (fr) * 1998-11-18 2000-11-08 Zschimmer & Schwarz Italiana S.p.A. Système d'emulsion preformé

Also Published As

Publication number Publication date
DE19548315A1 (de) 1997-06-26
AU1371697A (en) 1997-07-17

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