WO1997014819A1 - Procede de traitement thermique d'un produit en feuillard d'alliage de nickel, et produit obtenu - Google Patents
Procede de traitement thermique d'un produit en feuillard d'alliage de nickel, et produit obtenu Download PDFInfo
- Publication number
- WO1997014819A1 WO1997014819A1 PCT/FR1996/001579 FR9601579W WO9714819A1 WO 1997014819 A1 WO1997014819 A1 WO 1997014819A1 FR 9601579 W FR9601579 W FR 9601579W WO 9714819 A1 WO9714819 A1 WO 9714819A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- product
- temperature
- annealing
- period
- minutes
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
Definitions
- the invention relates to a method of heat treatment of a product obtained from a strip of a nickel alloy known under the name of alloy 718 and in particular of a rod holding spring for a fuel assembly. for 718 alloy nuclear reactor.
- the nickel alloy known by the designation alloy 718 is used in particular in the form of a strip, that is to say a flat product with a thickness of less than one millimeter, to produce springs for holding rods in an assembly. of fuel for a pressurized water nuclear reactor. These retaining springs are provided in particular on the end grids of the fuel assemblies.
- the nickel-based alloy 718 contains, by weight, at most, 0.08% carbon, 0.35% manganese, 0.35% silicon, 0.015% phosphorus and 0.015% sulfur, 17 to 21% chromium, 50 to 55% nickel and cobalt, the cobalt being in a weight proportion at most equal to 1%, from 2.80 to 3.30% molybdenum, from 4.75 at 5.50% niobium and tantalum, 0.65 to 1.15% titanium, 0.35 to 0.80% aluminum, 0.001 to 0.006% boron, a maximum proportion of copper of 0.15%, the balance of the alloy, with the exception of any impurities being made up of iron.
- Such an alloy used in the form of a strip to obtain by cutting and by folding, products such as springs for holding fuel rods, undergoes conventionally a treatment comprising a solution annealing followed by an aging treatment at 718 ⁇ C.
- a first technique for producing the springs which consists in cutting and forming the springs in the plates constituting the grid of the fuel assembly which is then produced in mono-metallic form and consisting solely of alloy 718.
- the plates constituting the grid are cut and stamped to produce the springs, prior to their assem ⁇ blage which is achieved by soldering.
- the brazing operation generally requires maintaining the grid at a temperature between 920 and 1050 ° C.
- the aging treatment of the grids is carried out following the brazing operation.
- the grids are produced in bimetallic form and are constituted by plates coated with a zirconium alloy on which are resistance welded with small 718 alloy springs obtained by cutting and stamping a strip. The plates are then assembled together by souda ⁇ ge.
- the manufacture of the springs of added bimetallic lattices differs appreciably from the manufacture of mono-metallic grids, insofar as the bimetallic grills do not undergo a thermal cycle equivalent to the soldering cycle requiring maintaining the temperature of the grid between 920 and 1050 ° C.
- the first three criteria retained are linked to the thermomechanical development and transformation of the material under the responsibility of the steelmaker supplying the strip.
- the three criteria numbered 4, 5 and 6 are directly linked to the manufacturing process of the springs, during the production of the springs by cutting and stamping a strip supplied by the steel manufacturer.
- the metallurgical knowledge concerning the practice of annealing treatment for dissolving and de-wrenching alloy 718 which constitute the prior art known to those skilled in the art tends to show that the annealing treatment can be carried out in a wide range temperature and time range.
- the indicated temperature range extends between 940 ° C and 1090 ° C for holding times between a few seconds and several hours, depending on the size of the parts and the industrial applications targeted.
- annealing treatment conditions with regard to the annealing temperature range and the duration of holding at the annealing temperature, to avoid the presence of phase ⁇ , of work hardening due to forming springs and a heterogeneity of grain sizes too important, in the spring material in the formed and heat treated state.
- the product is free of phase ⁇ , if the residual volume proportion of phase ⁇ in the product after heat treatment is less than 5% by volume of the maximum quantity of precipitable phase ⁇ .
- This maximum quantity is 5% by volume of the product for the niobium contents of the alloy 718. It can therefore be considered that a product is free of phase ⁇ , according to the requirements, if the volume proportion of phase ⁇ after heat treatment is less than 0.25%.
- the data provided by the prior art does not make it possible to obtain conditions for complying with the first criterion (absence of phase ⁇ ) since the precipitation domain of phase ⁇ in alloy 718 cannot be defined in general. Indeed, the kinetics of formation of phase formation is very dependent on the thermomechanical treatments undergone by the piece of alloy 718 before the annealing and aging treatment.
- the object of the invention is therefore to propose a process for heat treatment of a product obtained from a strip of a nickel alloy containing, by weight, at most, 0.08% carbon, 0.35% of manganese, 0.35% of silicon, 0.015% of phosphorus and 0.015% of sulfur, from 17 to 21% of chromium, from 50 to 55% of nickel and cobalt, the cobalt being in a proportion by weight at most equal to 1%, 2.80 to 3.30% molybdenum, 4.75 to 5.50% niobium and tantalum, 0.65 to 1.15% titanium, 0.35 to 0 , 80% aluminum, from 0.001 to 0.006% boron, a maximum proportion of copper of 0.15%, the balance of the alloy, with the exception of unavoidable impurities, consisting of iron, comprising annealing solution and aging, this heat treatment being carried out so as to optimize the mechanical characteristics of the product, in particular for long-term use and at high temperature.
- the product is annealed in solution using one of the following processes: a - maintaining the product at a temperature between 975 and 1010 ⁇ C for a period of between 15 minutes and 2 hours, b - maintaining the product at a temperature between 1020 and 1060 ⁇ C for a period of less than 30 minutes. c - maintaining the product at a temperature between 1000 and 1080 ° C for a period of less than 10 minutes.
- the product is kept, prior to annealing, at a temperature between 650 and 740 ⁇ C for a duration of between 1 hour and 10 hours, in order to carry out a precipitation of a ⁇ "phase rich in niobium; the niobium content of the matrix of the alloy is thus lowered, which makes it possible to limit the formation of phase 6 at a very low level.
- a spring is produced for a fuel assembly grid of a pressurized water nuclear reactor by cutting and stamping a strip of nickel alloy 718, that is to say a flat product of alloy 718 whose thickness is less than or equal to lmm.
- micro-structure of the spring material is examined after annealing and aging at 718 ° C for eight hours (standard treatment), to determine whether the micro-structure of the material contains phase matériau.
- the springs After forming, the springs have very different work hardening rates from one formed area to another. In addition, certain zones formed do not reach the critical work hardening necessary for the recrystallization of the material. It has however been possible to show that the material presents a sufficiently uniform grain size, when the annealing treatment is carried out at a temperature above 1010 "C.
- a treatment which can be selected comprises, for example, annealing in a dormant oven at 985 "C for a period of one hour. It is also possible to preferably carry out a treatment at a temperature above 985 ° C and below 1010 ⁇ C for a duration at most equal to one hour.
- the processing time is limited, in this case, to a duration of 30 minutes. Studies have shown that the material has a grain size which is not too heterogeneous and a satisfactory microstructure by a dormant oven treatment between 1020 and 1060 "C for a period of less than 30 minutes.
- a typical dormant oven treatment of a material containing the origin of phase de is a treatment at 1040 ° C. for a period of 20 minutes.
- the studies carried out have shown that the criteria used are met when the annealing temperature is between 1000 and 1080 ⁇ C.
- the annealing temperature is between 1000 and 1080 ⁇ C.
- an excessive magnification of the grains of the material is avoided and too strong heterogeneity of the grain size by limiting the treatment in the passage oven to a duration of less than 10 minutes.
- a typical treatment in the passing of a spring formed from a strip of alloy 718 is carried out in the passage furnace at a temperature of 1060 "C, the passage time of the spring being treated inside the furnace being 50 seconds.
- the springs formed from a strip of nickel alloy 718 have a micro-structure practically free of phase ⁇ , that is to say - say containing less than 0.25% by volume of phase ⁇ , and collapsed zones and a grain size which is substantially homogeneous and constant in all the parts of the spring.
- the annealing treatment can be applied to parts or products which have been shaped by forming operations of any type, from a strip of alloy 718.
- the thermal treatment according to the invention can be applied to parts that have undergone prior thermomechanical treatment cycles of different types.
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96934888A EP0856069A1 (fr) | 1995-10-18 | 1996-10-10 | Procede de traitement thermique d'un produit en feuillard d'alliage de nickel, et produit obtenu |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR95/12239 | 1995-10-18 | ||
FR9512239A FR2740143B1 (fr) | 1995-10-18 | 1995-10-18 | Procede de traitement thermique d'un produit en feuillard d'alliage de nickel, et produit obtenu |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997014819A1 true WO1997014819A1 (fr) | 1997-04-24 |
Family
ID=9483661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1996/001579 WO1997014819A1 (fr) | 1995-10-18 | 1996-10-10 | Procede de traitement thermique d'un produit en feuillard d'alliage de nickel, et produit obtenu |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0856069A1 (fr) |
FR (1) | FR2740143B1 (fr) |
WO (1) | WO1997014819A1 (fr) |
ZA (1) | ZA968679B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111607721A (zh) * | 2020-05-19 | 2020-09-01 | 金川集团股份有限公司 | 一种核电用gh4169a合金带材的制备方法 |
CN113718137A (zh) * | 2021-08-12 | 2021-11-30 | 江苏贯森新材料科技有限公司 | 一种in718合金及in718合金制备的半成品合金带的加工方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0402168A1 (fr) * | 1989-06-09 | 1990-12-12 | The Babcock & Wilcox Company | Procédé pour augmenter la résistance à la fissuration par corrosion sous contraintes d'alliage 718 |
GB2267507A (en) * | 1992-06-03 | 1993-12-08 | Snecma | Heat treatment process for a nickel based superalloy |
-
1995
- 1995-10-18 FR FR9512239A patent/FR2740143B1/fr not_active Expired - Fee Related
-
1996
- 1996-10-10 EP EP96934888A patent/EP0856069A1/fr not_active Withdrawn
- 1996-10-10 WO PCT/FR1996/001579 patent/WO1997014819A1/fr not_active Application Discontinuation
- 1996-10-15 ZA ZA9608679A patent/ZA968679B/xx unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0402168A1 (fr) * | 1989-06-09 | 1990-12-12 | The Babcock & Wilcox Company | Procédé pour augmenter la résistance à la fissuration par corrosion sous contraintes d'alliage 718 |
GB2267507A (en) * | 1992-06-03 | 1993-12-08 | Snecma | Heat treatment process for a nickel based superalloy |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111607721A (zh) * | 2020-05-19 | 2020-09-01 | 金川集团股份有限公司 | 一种核电用gh4169a合金带材的制备方法 |
CN113718137A (zh) * | 2021-08-12 | 2021-11-30 | 江苏贯森新材料科技有限公司 | 一种in718合金及in718合金制备的半成品合金带的加工方法 |
Also Published As
Publication number | Publication date |
---|---|
FR2740143A1 (fr) | 1997-04-25 |
FR2740143B1 (fr) | 1998-01-09 |
ZA968679B (en) | 1998-04-15 |
EP0856069A1 (fr) | 1998-08-05 |
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