WO1997003758A2 - Spraying system for single or multiple fluids - Google Patents

Spraying system for single or multiple fluids Download PDF

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Publication number
WO1997003758A2
WO1997003758A2 PCT/US1996/010316 US9610316W WO9703758A2 WO 1997003758 A2 WO1997003758 A2 WO 1997003758A2 US 9610316 W US9610316 W US 9610316W WO 9703758 A2 WO9703758 A2 WO 9703758A2
Authority
WO
WIPO (PCT)
Prior art keywords
ofthe
fluid
passageway
proximate
atomizing
Prior art date
Application number
PCT/US1996/010316
Other languages
French (fr)
Other versions
WO1997003758A3 (en
Inventor
W. Bruce Sandison
Russell E. Blette
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to EP96919419A priority Critical patent/EP0837737A2/en
Priority to JP9506670A priority patent/JPH11509472A/en
Priority to AU61767/96A priority patent/AU6176796A/en
Priority to BR9609547A priority patent/BR9609547A/en
Publication of WO1997003758A2 publication Critical patent/WO1997003758A2/en
Publication of WO1997003758A3 publication Critical patent/WO1997003758A3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • B05B7/0807Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets
    • B05B7/0846Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets with jets being only jets constituted by a liquid or a mixture containing a liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/004Arrangements for controlling delivery; Arrangements for controlling the spray area comprising sensors for monitoring the delivery, e.g. by displaying the sensed value or generating an alarm
    • B05B12/006Pressure or flow rate sensors
    • B05B12/008Pressure or flow rate sensors integrated in or attached to a discharge apparatus, e.g. a spray gun
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2402Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
    • B05B7/2405Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle
    • B05B7/2424Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle the carried liquid and the main stream of atomising fluid being brought together downstream of the container before discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2402Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
    • B05B7/2472Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device comprising several containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2489Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device
    • B05B7/2497Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device several liquids from different sources being supplied to the discharge device

Definitions

  • the present invention relates to a method and apparatus for spraying fluids and more particularly, to a system for spraying multiple component fluid systems.
  • the present invention also relates to a flexible polymeric container with an integral pressure relief system for retaining components of a fluid system.
  • Spraying fluid materials such as paints, stains, adhesives, lubricants, and pesticides, through a nozzle onto a substrate is a common and effective method of application.
  • the components may be combined sequentially. This method of combining the components requires more than one pass across the substrate and may require a separate spray applicator for each individual component. Additionally, the components are not mixed prior to contact with the substrate, but rather applied in layers.
  • Another method of combining multiple component fluid systems is to mix the components prior to their application to the substrate. The components may be mixed either before they leave the spray applicator or after they leave the spray applicator, but before reaching the substrate.
  • the individual components of many multiple component fluid systems react in a manner that is undesirable if combined prior to application to the target substrate.
  • the reaction between the components may occur earlier than desired and thereby reduce the performance ofthe multiple component fluid system, either in the application process or after the coating has been applied to the substrate.
  • the components of some multiple component fluid systems may be corrosive to some materials or parts ofthe spray applicator, either in their individual component form or when combined, or may clog the nozzle.
  • the components are generally an adhesive base and an activator or catalyst which causes the adhesive to cure. The two components must be mixed at the time they are applied to the substrate.
  • two adjacent, atomizing nozzles are positioned so that the various components intermingle and mix prior to reaching the substrate.
  • spraying each component through a separate nozzle and combining the components external to the spray applicator the reaction between the components is delayed until immediately prior to contact with the substrate.
  • multiple component spraying systems tend to be heavy and complex. Additionally, current multiple component spraying systems provide inadequate atomization, and consequently, incomplete mixing for some multiple component fluid systems.
  • Spray applicator 10 is connected by connector 12 to air hose 14.
  • Air hose 14 is connected at one end to a source of pressurized air (not shown) and at another end to a handle end 17.
  • a passageway extends through the handle end 17 and barrel end 18 to a spray applicator bracket assembly 21 and nozzle assembly 16.
  • Trigger 20 actuates a valve actuator 19 that controls the flow ofthe pressurized air through the spray applicator 10.
  • a first bottle 22 and a second bottle 24 are each directly mounted on and supported by the spray applicator bracket assembly 21.
  • the first bottle 22 is for receipt of a quantity ofa first fluid and the second bottle 24 is for receipt of a quantity ofa second fluid.
  • Draw tubes 26 and 28 extend into the first and second bottles, respectively, in fluid communication at one end with the first and second fluids.
  • the nozzle assembly 16 is detachably mounted on the spray applicator 10 operatively connected to the passageway.
  • the nozzle assembly 16 utilizes air pressure to draw out the first fluid from the first bottle 22.
  • the second nozzle assembly 31 is mounted on the spray applicator bracket assembly 21 and is operatively connected to the body ofthe spray applicator 10 by air line 30.
  • the nozzle assembly 31 utilizes air pressure from the passageway ofthe spray applicator 10. The two separate air streams through separate passageways are each restricted and then expanded to an orifice.
  • the reduced pressure acts to draw the first and second fluids upwards through the draw tubes 26 and 28 where the fluid stream is atomized and ejected from the spray applicator 10.
  • the atomized sprays ofthe first and second fluids are intermixed at the exterior ofthe spray applicator 10 prior to encountering the surface to which the fluids are to be applied.
  • FIG 2 illustrates another spray applicator arrangement 50, including a spray applicator 10', connector 12' and air hose 14'.
  • a nozzle assembly 16' is connected to the spray applicator 10' and includes draw tube 26' that is in fluid communication with a flexible fluid bag 22'.
  • Support 52 is connected at one end to the bag 22' and at the other end to the spray applicator 10'.
  • the nozzle assembly 16' from the spray applicator 10' utilizes air pressure to draw fluid from the bag 22' and to atomize the fluid, as described with respect to the arrangement shown in Figure 1.
  • a pressurized aerosol container 54 is provided in place ofthe second bottle 24 as in Figure 1, a pressurized aerosol container 54 is provided.
  • FIG. 3 illustrates the exemplary nozzle assembly 16' of Figure 2 connected to the flexible bag 22'.
  • Fitting 56 forms a seal with the flexible bag 22' enabling one end of draw tube 26' to extend into the interior ofthe bag 22'.
  • Fitting 57 is adapted to engage quick connect 58 mounted on the draw tube 26' to secure the tube
  • FIG. 4 further illustrates the nozzle assembly 16'.
  • Port 60 includes conduit 59 communicating with passageway 62 extending from one end ofthe nozzle assembly 16' to an opposing end.
  • the opposite end ofthe nozzle assembly includes shroud 64 defining shoulder 66 within the passageway 62.
  • Nozzle assembly 16' may be connected to the spray applicator such as by "J" slot 67 engaging aligned post (not shown) on the spray applicator.
  • the venturi effect may be induced by insert 68 having passageway 70 with a smaller cross-sectional area than passageway 62.
  • the insert 68 may be positioned within shroud 64, located by contact between annular flange 72 ofthe insert 68 and shoulder 66. Washer 74 having aperture 76 may used to seal the insert when the nozzle assembly 16' is mounted on the spray applicator 10'.
  • the stream of pressurized air flows though aperture 76, passageway 70 and passageway 62. When the air stream emerges from passageway 70, the resulting drop in pressure acts to draw the fluid up from the flexible bag 22' through port 60 into the air stream. It will be appreciated that a similar arrangement may be employed for the spray applicator 10 of Figure 1.
  • the total weight ofthe system may become tiring to carry and operate, particularly over long periods of time. It is also somewhat difficult to remove, refill, or replace the fluid containers while directly connected to a spray applicator.
  • the resulting pattern of adhesive on the substrate is incompletely activated. Applicants have found that approximately less than 30% ofthe adhesive is activated when current two-part water-based adhesives are used in the currently available side injector nozzle assemblies. The remainder ofthe adhesive base remains wet and fails to function correctly.
  • the present invention relates to a nozzle assembly with a preset delivery rate and a fluid spraying system suitable for use with single component or multiple component fluid systems.
  • the nozzle assembly has an atomizing portion defining a passageway in fluid communication at a first end with pressurized air from a spray applicator.
  • the passageway has a first cross-sectional area proximate the first end, a second cross-sectional area less than the first cross-sectional area proximate a middle portion, and a fluid inlet port between the middle portion and a second end.
  • a portion ofthe passageway ofthe first atomizing portion between the middle portion and the second end has a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end so that a reduced pressure condition is created in the passageway proximate the fluid inlet port when pressurized air is supplied to the nozzle assembly.
  • the spraying system includes at least one container for receiving a fluid.
  • a spray applicator is provided for controlling the flow of pressurized air to a nozzle assembly.
  • a flexible tube fluidly connecting the container with the fluid inlet port is provided so that the fluid is drawn through the fluid inlet port and expelled in an atomized stream from the second end ofthe atomizing portion when pressurized air is supplied to the nozzle assembly.
  • Multiple atomizing portions may be provided for independently spraying each component ofa multiple component system in a preset, fixed ratio.
  • an atomized stream is generated for each component ofa multiple component system.
  • the atomized streams may be overlapped to intermix the fluids.
  • the angle of intersection ofthe atomized streams preferably is about 14-19°.
  • the first and second cross-sectional areas of each atomizing portion determine the ratio of each component ofa multiple component fluid system in the resulting atomizing streams.
  • the ratio ofthe fluids in their respective atomizing streams is between 13:1 to 17:1. In another embodiment, the ratio is between 20:1 to 30:1.
  • the container may be a flexible, polymeric bag.
  • the polymeric bag has a seal proximate a perimeter edge.
  • a closable fitting extends into the bag for receiving a flexible tube.
  • a releasable closure is provided proximate a portion ofthe perimeter edge.
  • the releasable closure has a release pressure less than the burst strength ofthe flexible polymeric material.
  • the releasable closure is a rib and trough system.
  • the flexible polymeric bag may include a gusset so as to be self- supporting when in an upright position.
  • the flexible polymeric bags may be retained in a receptacle having a carrying handle.
  • the flexible polymeric bag may also be made with an integral handle shaped into the bag perimeter.
  • the present invention is also directed to a container for receiving a fluid for use with a spraying apparatus.
  • a flexible polymeric material is configured to form a pouch.
  • a seal extending substantially around a perimeter edge ofthe flexible polymeric material retains a fluid within the pouch.
  • a closable fitting extends into the pouch.
  • the closable fitting has a closed position for retaining the fluids within the pouch and an opened position for receiving a flexible tubes in fluid communication with the fluid.
  • a releasable closure is provided proximate a portion ofthe perimeter edge.
  • the releasable closure has a release pressure less than the burst strength ofthe flexible polymeric material.
  • the closable fitting may be retained between first and second layers of flexible polymeric material.
  • the releasable closure is a rib and trough closure system constructed to open in response to pressure within the container in excess ofa predetermined amount.
  • the method ofthe present invention includes providing pressurized air to at least one nozzle assembly ofthe present invention.
  • the pressurized air creates a reduced pressure condition in the passageway proximate the first fluid inlet port.
  • the reduced pressure condition draws a fluid into the first fluid inlet ports.
  • the fluid is expelled from the nozzle assembly and atomized.
  • the multiple atomized streams are overlapped to intermix the components ofa multiple component system. Definitions used in this application:
  • Fluid shall mean any flowable, sprayable material, including, without limit, a paint, varnish, stain, mastic, gel-coat, cleaning solvent, sealant, lubricant, adhesive, pesticide, herbicide, cleaning or degreasing solvent, wear coating, abrasion resistant coating or slip coating.
  • Multiple component fluid system shall mean including, but not limited to, the combination of two or more fluids such as curing systems including a catalyst as one component and a reactive resin such as a two-part urethane, two-part adhesive systems, two-part epoxy systems; two-part latex systems; non-curing systems such as pigment/colorant and base compounds; and diluents and concentrates such as pesticides and herbicides and coatings in which particulate such as granular or encapsulated materials are incorporated into or onto a dispensed fluid.
  • a reactive resin such as a two-part urethane, two-part adhesive systems, two-part epoxy systems; two-part latex systems; non-curing systems such as pigment/colorant and base compounds; and diluents and concentrates such as pesticides and herbicides and coatings in which particulate such as granular or encapsulated materials are incorporated into or onto a dispensed fluid.
  • Figure 1 is a side view of a two-component fluid spraying system
  • Figure 2 is a side view of an alternate two-component fluid spraying system with a flexible bag and an pressurized aerosol container attached to the spray applicator;
  • Figure 3 is a partial side exploded view ofthe attachment of the flexible bag of Figure 2;
  • Figure 4 is a side exploded view ofthe spray nozzle ofthe conventional spray system of Figure 2;
  • Figure 5 is a perspective view of an exemplary multiple component spray system according to the present invention
  • Figure 6 is a top exploded view of an exemplary spray nozzle assembly for a multiple component spray system
  • Figure 7 is a side cross-sectional view perpendicular to plane 7-7 ofa first spray portion ofthe nozzle of Figure 6;
  • Figure 8 is a top cross-sectional view perpendicular to plane 8-8 ofa second spray portion ofthe nozzle of Figure 6;
  • Figures 9 A, 9B and 9C are sequential isometric views illustrating the assembly ofthe spray nozzle assembly of Figure 6;
  • Figure 10 is a top cross-sectional view ofthe spray nozzle assembly of Figure 6;
  • Figure 11 is an isometric view ofthe nozzle of Figure 6, partially exploded to show the connection ofthe fluid conduits;
  • Figures 12 and 12 A illustrate a connection of first and second fluid conduits to first and second fluid containers;
  • Figures 13 and 13 A are isometric views of a receptacle for receiving and securing first and second fluid containers;
  • Figure 14 is an isometric view of an alternate flexible fluid container having a venting member;
  • Figure 15 is a plan view of an alternate flexible fluid container having an integral handle.
  • Multiple fluid spraying systems are useful for simultaneously spraying two or more fluids, either onto a surface or into the air in the case of pesticides. Frequently, it is desirable to intermix the fluid spray with each other prior to encountering the surface.
  • some adhesive compounds such as "Fastbond 2000-NF Adhesive" and "Fastbond Spray Activator,” discussed above, include a first fluid resin and a second fluid activator, catalyst or modifier. Intermixing the first and second fluids in overlapping atomized sprays causes the adhesive to be tacky when applied to a surface.
  • Figure 5 there is shown a multiple fluid spraying system 110 according to the present invention.
  • System 110 includes spray applicator 112 connected by attachment 114 and hose 115 to a source ofa pressurized fluid, most preferably air.
  • the system 110 includes a first fluid container 116 and a second fluid container 118 retained in receptacle 248.
  • the first and second fluid containers 116, 118 are for receipt of first and second fluids 116F, 118F (see Figure 12) to be sprayed by the spraying system 110 of the present invention.
  • first and second fluid containers 116, 118 are for receipt of first and second fluids 116F, 118F (see Figure 12) to be sprayed by the spraying system 110 of the present invention.
  • the present invention may be employed to spray a single fluid or more than two fluids, as may be found advantageous for a particular application or fluid. In such a case, a corresponding number of fluid containers, spray nozzles and ports on the spray applicator may be provided in conjunction with the fluid spraying system described herein.
  • Spray applicator further includes nozzle assembly 120 connected by first and second fluid conduits 122 and 124 to the first and second fluid containers 116 and 118, respectively.
  • Suitable fluid conduits 122, 124 are available from Freelin-Wade Company, McMinnville, Oregon.
  • the spray applicator 112, pressurized air from the hose 115, nozzle assembly 120, first and second fluid containers 116 and 118, and first and second fluid conduits 122 and 124 act to generate atomized sprays ofthe first and second fluids
  • the nozzle assembly 120 directs the atomized sprays into intersecting paths prior to encountering a surface.
  • Spray applicator 112 includes housing 130, most conveniently provided in a "pistol" configuration with a handle portion 132 adapted for manual engagement and manipulation to direct the atomized sprays ofthe first and second fluids towards a desired surface. It will be understood, however, that the housing 130 may take any other suitable configuration as is found advantageous in a particular application. Barrel portion 134 projects generally orthogonally from the handle portion 132 along longitudinal axis 136. Hook 138 may optionally be provided to support the spray applicator 112 from a suitable support structure (not shown).
  • the housing 130 may be constructed from any suitable material, but is preferably constructed from a monolithic molded body ofa polymeric or metallic material compatible with the fluids to be sprayed. Alternatively, the housing may be constructed ofa pair of molded bifurcated mirror image portions (not shown) that are secured in sealing relationship.
  • the following is a non-exclusive list of materials that may be used to construct the housing 130 ofthe spray applicator: aluminum, steel, polycarbonate, composites, epoxy, or some combination thereof.
  • Passageway 140 extends from a first end 142 though the handle portion 132 and the barrel portion 134 to second end 144 in manner that is directed away from the user ofthe spray applicator
  • Attachment 114 is sealingly mounted about first end 142 ofthe passageway 140 and is connected by pressurized air hose 115 to a source of pressurized air (not shown). Pressurized air thus flows though hose 115 and passageway 140 to second end 144.
  • the air pressure supplied to the spray applicator 112 is generally between 15 and 40 p.s.i. at a flow rate of approximately 2-5 c m.
  • Attachment 114 may include an adjustable valve 154 for regulating the flow rate for the air, or alternatively, the pressure.
  • Gauge 156 may also be provided to display the flow rate or pressure ofthe air flowing into the spray applicator 112.
  • a suitable valve/gauge assembly is available from Schrader Bellows located in Des Plaines, Illinois.
  • the flow ofthe pressurized air through the spray applicator 112 is controlled by a valve 158 actuated by trigger 160.
  • the valve 158 permits either a progressive increase in the flow rate ofthe air or a simple on-off arrangement at a pre-set flow rate.
  • the trigger 160 is biased to a closed position.
  • a first fluid atomizing portion 168 is mounted in sealing relation to the spray applicator 112 in fluid communication with the second end 144 ofthe passageway 140.
  • skirt 180 extends concentrically away from the first fluid atomizing portion 168.
  • the skirt 180 is adapted to slidingly receive the end ofthe barrel portion 134 ofthe spray applicator 112.
  • Skirt 180 includes a 'T' slot 182 (see Figure 7) for engagement with a suitably sized post 184 radially projecting from the barrel portion 134.
  • Relative rotation ofthe first fluid atomizing portion 168 with respect to the banel portion in direction 186 around the axis 136 locks the first fluid atomizing portion 168 in place on the barrel portion 134 in fluid communication with the passageway 140 ofthe spray applicator 112.
  • Relative rotation ofthe first fluid atomizing portion 168 with respect to the banel portion 134 in opposing rotational direction 188 disengages the "J" slot 182 and the post 184, enabling the first fluid atomizing portion 168 to be removed from the spray applicator 112.
  • the following is a non ⁇ exclusive list of commercially available spray applicators 112 that may be used in conjunction with the nozzle assembly 120 ofthe present invention: MAFA-Sebald Nertiesbsges of Breckerfeld,
  • nozzle assembly 120 is provided to convey the flow ofthe pressurized air from the spray applicator 112 to draw the first and second fluids 116F, 118F from the first and second fluid containers 116, 118, respectively, in manner to be described in greater detail hereinafter.
  • the first atomizing portion 168 is used in conjunction with the first fluid 116F and the second atomizing portion 170 is used in conjunction with the second fluid 118F.
  • the first and second atomizing portions 168, 170 are generally a venturi device operating under Bernoulli's theorem.
  • Bernoulli's theorem states that when a gas or fluid is flowed through a restricted area, as in a nozzle or venturi, its speed will increase and its temperature and pressure will decrease. If the cross-sectional area is increased as in a diffuser, the reverse is true.
  • the total energy in a flowing gas is made up of static and dynamic temperatures, and static and dynamic pressures.
  • a nozzle or diffuser does not change to total energy level, but rather changes one form of energy to another. For example, a nozzle will increase the flow, or dynamic pressure, at the expense ofthe static pressure.
  • the first fluid atomizing portion 168 includes a passageway 172 extending from a first end 174 to a second end 176.
  • a fluid induction port 178 is formed inte ⁇ nediate the first end 174 and the second end 176 ofthe passageway 172 to provide a "venturi" effect.
  • the passageway 172 includes a first diameter Dl proximate the first end 174, a smaller diameter at D2 at an intermediate point, and an expanded diameter D3 that is larger than diameter D2 proximate the second end 176.
  • This arrangement produces an increase in speed and a reduction in the pressure at D2 as the compressed air flows through the passageway 172 that draws the first fluid 116F into the first atomizing portion 168.
  • the frusto-conical structure having a maximum diameter D3 at the second end 176 directs the resulting atomized stream along the axis 177 (see Figure 10).
  • the passageway 190 includes a first diameter D4 proximate the first end 192, a smaller diameter D5 at an intermediate point and an expanded diameter D6 proximate the second end 194 that is larger than diameter D5. This arrangement produces an increase in speed and a reduction in the pressure at D5 that draws the second fluid 118F into the second atomizing portion 170.
  • the frusto-conical structure having a maximum diameter D6 at the second end 194 directs the resulting atomized stream along the axis 199 (see Figure 10).
  • diameters D1-D6 are circular only for ease of manufacture and that the critical variable is the cross-sectional area ofthe passageways 172, 190 at the locations
  • the cross-sectional shape ofthe passageways 172, 190 may be a variety of symmetrical or asymmetrical shapes.
  • the flow rate and level of atomization ofthe atomized stream from the first atomizing portion 168 is generally a function of the pressure ofthe supplied air, D1-D3, the diameter ofthe induction port 178 and the viscosity ofthe first fluid 116F.
  • the flow rate and level of atomization ofthe atomized stream from the second atomizing portion 170 is generally a function ofthe pressure ofthe supplied air, D4-D6, the diameter ofthe induction port 196 and the viscosity ofthe second fluid 118F.
  • the nozzle assembly 120 is designed to spray a fixed ratio ofthe first fluid 116F to the second fluid 118F at a given pressure of supplied air and viscosity, without any risk of operator error due to improper adjustment ofthe air pressure, flow rates, spray angles ofthe nozzles, etc..
  • the present fixed-ratio nozzle assembly 120 provides a more accurate and reliable spraying ofthe fluids than can generally be achieved by other conventional spraying systems. It will be understood that low-cost nozzle assemblies 120 having different Dl- D6 values may be easily manufactured to provide optimum spraying conditions for various multiple component fluid systems with the same beneficial result.
  • the size, length, angle between the fluid sprays ofthe nozzle assembly 120 may be pre-set, eliminating the need for adjustment. Further, for most applications, it will be economically viable to simply dispose ofthe nozzle assembly 120 after each use, thus eliminating the need for cleaning prior to the next use. Finally, changeover for spraying ofa different set of fluids is also easily and quickly accomplished by substituting a different nozzle assembly 120 fluidly connected to a different set of fluids.
  • Figures 9 A, 9B and 9C sequentially illustrate a method of assembling the first and second atomizing portions 168, 170 and connecting member 200 to each other.
  • the connecting member 200 is inserted at each end into ports 204, 206, but with the second fluid atomizing portion 170 rotated approximately 90° from the final position.
  • the second fluid atomizing portion 170 may then be rotated in direction 221 about the port 204 ofthe first fluid atomizing portion 168.
  • Post 220 is thus positioned for engagement with aperture 218 to secure flanges 214, 216 to each other, as shown in Figure 9C.
  • the post 220 may be frictionally received within the aperture 218 so as to secure the flanges 214, 216, and thus the first and second fluid atomizing portions 168, 170 in a fixed relationship.
  • the fixed relationship ofthe atomizing portions 168, 170 insures that the atomized sprays are emitted in an overlapping pattern.
  • other methods of assembling the first and second fluid atomizing portions 168, 170 of the nozzle assembly 120 may be selected. Further, other configurations may be utilized to construct the nozzle assembly 120, such as by molding a unitary molded polymeric body forming both venturi passageways 172 and 190.
  • the second fluid atomizing portion 170 may be connected to an independent source of pressurized air.
  • a portion ofthe stream of pressurized air adjacent the first end 174 ofthe first atomizing portion 168 is diverted through a passageway 198 to passageway 190.
  • the passageway 198 extends through the connecting member 200.
  • the connecting member 200 is inserted into and secured at each end to ports 204, 206, respectively, as discussed above. Concentric tapered projections 208 enabling the connecting member 200 to be sealingly secured at each end to the first and the second fluid atomizing member 168, 170.
  • Annular flanges 210, 212 define a secured position for the connecting member 200 relative to the first and second fluid atomizing members 168, 170.
  • Passageway 198 extends through the connecting member 200 to provide fluid communication between passageways 172 and 190.
  • the low-cost, disposable nozzle assembly 120 is preferably constructed by premolding a unitary molded body from a polymeric material. The following is a nonexclusive list ofthe polymeric materials that may be utilized to construct the nozzle assembly 120: polystyrene, polypropylene, polyethylene, polyvinylchloride, polyacetal, and nylon.
  • the surface finish ofthe interior ofthe nozzle assembly 120 illustrated in Figure 10 has a surface finish generally in the range of Al to A2 according to the Society ofthe Plastics Industry Standard for Cosmetic Specifications of Injection Molded Parts, 1994.
  • the term “smooth” means to be formed in a manner that is free from irregularities, roughness, indentations, projections, protuberances or any abrupt changes in geometry that provides a location for the accumulation of solidified material.
  • the second end 194 ofthe second atomizing portion 170 extends beyond and forward from the second end 176 ofthe first atomizing portion.
  • the configuration in Figure 10 minimizes coagulation, activation or catalyzation ofthe adhesive, epoxy, etc. on the nozzle assembly 120.
  • Figure 11 illustrates the connection ofthe conduit 122 to the induction port 178 on the first atomizing portion 168 and the second conduit 124 to the induction port 196 on the second atomizing portion 170.
  • a check valve 195 may be interposed between the second conduit 124 and the second atomizing portion 170 to prevent the first fluid 116F from being drawn into the second fluid container 118 and to prevent fluid 118F from dropping back into the container
  • FIG. 12 and 12A illustrate a system for independently moving and flexibly connecting each ofthe fluids to be sprayed from the spray applicator 112. It will be understood that any suitable container may be employed, such as bottles or the like (not shown). However, the flexible fluid containers 116, 118 offer certain advantages.
  • the containers 116, 118 may be constructed from opposing generally rectangular polymeric sheets of laminated or non- laminated films bonded together along aligned edges as at seams in a manner known in the art.
  • the fluid containers 116, 118 are flexible polymeric bags constructed of polyethylene terephthalate (PET), biaxially oriented nylon, linear low density polyethylene laminate available from Kapak Corporation of Minneapolis, MN.
  • the first and second fluid container 116 and 118 are operatively connected to the nozzle assembly 120 by separate first and second fluid conduits 122, 124, respectively, so as to facilitate the carrying and manipulation ofthe spray applicator 112.
  • the first and second fluid conduits 122, 124 are sealingly connected to the containers 116, 118 by frictional engagement with tapered annular projections 242.
  • the tapered annular projections 242 are frictionally connected to draw tubes 175, 176, which extend through closable fitting 244 into the containers 116, 118.
  • a tubing with an outside diameter equal to or less than the inside diameter ofthe opening in the closable fitting 244 may be used in place ofthe tapered annular projections 242.
  • a flexible polymeric tubing such as clear polyvinyl chloride (PNC) available from Freelin-Wade Company of McMinnville, Oregon, is suitable for use as the fluid conduits 122, 124 and draw tubes 175, 176.
  • Increased pressures within the containers 116, 118 may be generated by increased temperatures or chemical reaction ofthe substances, or clogging of either or both ofthe nozzles 168, 170.
  • a vent 245 responsive to the presence of pressure within the container 230 above a selected limit is provided.
  • the vent 245 includes a segment ofthe container sealed by a releasable closure 246 located within the perimeter of seam 234.
  • the releasable closure 246 may be constructed ofa rib and trough closure system such as found on bags marketed under the trademark "Ziploc" pleated bags by Dow Brands, Inc. of Indianapolis, Indiana.
  • the container 230 has a tamper-evident, reclosable, reusable, pourable spout.
  • the seam 234 preferably extends around the entire perimeter ofthe container 230 to retain the fluid within the container 230 during shipping and handling. Prior to use, the operator preferably cuts a notch 247 part-way through the seam 234 in the container material proximate the closure 246.
  • the releasable closure 246 provides a fluid impervious seal during normal use ofthe containers
  • the releasable closure 246 will be forced open at a particular level causing an audible report notifying the operator to release the excess pressure.
  • the releasable closure enables a portion ofthe pressurized material within the container 230 to be released through the releasable closure 246 and notch 247 in the bag material, preventing a discharge ofthe material, with obvious undesirable consequences.
  • the releasable closure 246 may also be opened during use ofthe spraying system 110 so that additional fluid or other material can be added to the container, without the need to suspend use ofthe spraying system 110.
  • the seam 234 may be incomplete proximate the releasable closure 246 and a mechanical fastener substituted for closure 246 to retain the fluid during shipping and handling.
  • the flexible fluid containers 116, 118 are self supporting when in an upright or standing orientation, such as by forming gussets 235 in the bottom thereof (see Figure 14).
  • a receptacle 248 is provided having a cavity 250 (shown in Figures 5, 13 and 13 A).
  • Receptacle 248 is preferably rigid or at least sufficiently self supporting to receive and support the first and second fluid containers 116, 118 in an upright position within cavity 250 during use.
  • the receptacle 248 may be conveniently constructed in a rectangular configuration.
  • the receptacle is preferably constructed ofa light weight material such as #160 high density polyethylene corrugated plastic available from Liberty Carton Company of Golden Valley, Minnesota. Polyethylene is preferred because of its durability and its resistance to water and solvent based products.
  • the receptacle 248 may include handle or like device adapted for manual engagement.
  • handle is illustrated in Figures 13 and 13 A in the form of opposed flaps 252, 254, each hingedly connected to opposed upper edges 256, 258 ofthe receptacle 248.
  • Subflaps 252a, 254a, respectively may be brought together in a "gabletop" arrangement as shown in Figure 13 A.
  • Each ofthe subflaps include aligned handle apertures 260 and 262 that may be manually engaged to carry and manipulate the receptacle.
  • one ofthe subflaps includes securing flap 264 that may be pushed through the opposing handle aperture and frictionally retained therein. In this manner, the flaps and subflaps are maintained in the position shown in Figure 13 A during use. If it is desired to remove or replace either or both ofthe fluid containers
  • the securing flap 264 may be disengaged from the opposing flap 252, 254 and the flaps separated. It will be understood that any other suitable arrangement may be employed to provide an handle for the receptacle, or to releasably secure the flaps and subflaps of Figures 13 and 13 A in the position shown in Figure 13 A, such as hook and loop fasteners, clips, staples, tape, or adhesives. Instructions may be printed on the receptacle 248 for the convenience ofthe operator.
  • Figure 15 illustrates an alternate bag 230' in which a handle 250 is integrally formed in or near seam 234'.
  • One or more ofthe bags 230' may be carried by an operator along with the spray applicator 110.
  • valve 158 is opened, enabling the pressurized air to flow through the spray applicator 112 and the nozzle assembly 120, including both venturi passageways 172, 190.
  • the reduced pressure adjacent to port 178 induces the first fluid 116F to be conveyed through first fluid conduit 122, port 178 and into the passageway 172.
  • the first fluid 116F is thoroughly atomized by the encounter with the stream of pressurized air flowing through the passageway and is ejected along axis 177 from the second end 176 ofthe passageway 172 from the nozzle assembly 120.
  • the axis 177 is aligned with axis 136 of passageway 140 in barrel portion 134 ofthe spray applicator housing 130 (see Figure 5).
  • the reduced pressure adjacent to the port 196 induces the second fluid to be conveyed through second fluid conduit 124 and port 196 into passageway 190.
  • the second fluid 118F is thoroughly atomized by the encounter with the stream of pressurized air flowing through the passageway 190 and is ejected along axis 199 from the second end ofthe passageway 190 ofthe nozzle assembly 120.
  • the axes 177 and 199 ofthe sprays emerging from the first and second fluid atomizing portions 168, 170 intersect and intermix at a desired location spaced from the nozzle assembly 120 (as at "A").
  • the angle 231 between the axes 177 and 199 may be determined, in part, by the configuration ofthe connecting member 200, as shown in Figure 10.
  • the intersection angle ofthe two spray streams is preferably between 14° and 19°
  • the spray system to be tested was secured with a clamp in a vertical position so that the spray nozzle assembly was about 30 cm (12 inches) from the mid-point ofthe surface ofa drum 41 cm (16 inches) high by 38 cm (15 inches) diameter rotating at 18 RPM, on which a transparent film was attached.
  • a two-part, water-based adhesive system was used as the material to be sprayed.
  • the adhesive was a contact adhesive having nominal 49% solids content and Brookfield viscosity of 200-700 cps and the activator was a water thin, inorganic salt solution having nominal 15 % solids content (3M' Fastbond' 2000-NF Adhesive and 3M' Fastbond' Spray Activator, commercially available from Minnesota Mining and
  • the material coated transparent film from the Delivery Rate test was removed from the drum and immediately tested for degree of activation by lightly touching the back area between the first and second knuckle of either the index or middle finger against the adhesive surface.
  • the material was rated as very (v) wet to wet (low adhesive activation), dry to very (v) dry (high adhesive activation), or tacky to slightly (si) tacky (desired adhesive activation).
  • a desired result is an average spray width of 5.0- 10.16 cm (2-4 inches).
  • the material coated transparent film from the Spray Width test was visually inspected for uniformity of particles. If at least 80 percent ofthe spray was of similar size, the spray was observed to be uniform.
  • a spray system ofthe invention was fitted with a spray nozzle assembly having the following dimensions as referenced on Fig. 7: Dl was
  • D2 was 3J75 mm (0J25 inches)
  • D3 was 8.89 mm (0.35 inches)
  • the diameter of port 178 was 2.29 mm (0.090 inches); as referenced on Fig. 8, D4 was 4.47 mm (0J76 inches), D5 was 1.27 mm (
  • the spray nozzle assembly was made of acrylonitrile butadiene styrene copolymer (ABS). Flexible containers containing the material to be sprayed, air lines and supply lines were attached to the spray applicator and the spray system was tested according to the test methods outlined above using varying air pressure for the adhesive and for the activator.
  • ABS acrylonitrile butadiene styrene copolymer
  • a spray system ofthe invention was prepared and tested as in Examples 1-3 with the exception that the spray nozzle assembly had the following dimensions: D2 was 2.794 mm (0J 10 inches) and the diameter of port 178 was 2.39 mm (0.094 inches); as referenced on Fig. 8, D5 was 1.52 mm ( 0.060 inches) and for Example 6, the diameter of port 196 was 0.381 mm (0.015 inches).
  • Example 5 increases the delivery rate ofthe adhesive and the spray width by 25%) and the delivery rate ofthe activator by 7%.
  • a 33% increase ofthe diameter of port 196 results in 17% increase in the activator delivery rate.
  • a spray system ofthe invention was prepared and tested as in Examples 1-3 with the exception that the spray nozzle assembly had the following dimensions: D2 was 2.82 mm (0J 11 inches) and the diameter of port 178 was 3.05 mm (0J20 inches); as referenced on Fig. 8, D5 was 2.36 mm ( 0.093 inches) and the diameter of port 196 was 1.016 mm (0.040 inches), and was made of high density polyethylene.
  • a spray system ofthe invention was prepared and tested as in Examples 7-10 with the exception that the spray nozzle assembly had the following dimension: the diameter of port 196 was 0.508 mm (0.020 inches).

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Abstract

A system and method for spraying single or multiple component fluid systems onto a surface. The spray applicator utilizes a venturi effect to independently draw fluids from separate containers, atomize the fluids and spray the fluids in a desired pattern onto a surface. The atomized streams generally overlap so that the fluids mix prior to contacting the target surface. In one embodiment, the fluids are retained in flexible containers separately connected to a spray applicator by flexible tubes. The flexible containers include a fitting for receiving a fluid draw tube and a releasable closure for expelling excess pressure within the container.

Description

SPRAYING SYSTEM FOR SINGLE OR MULTIPLE FLUIDS
Field ofthe Invention The present invention relates to a method and apparatus for spraying fluids and more particularly, to a system for spraying multiple component fluid systems. The present invention also relates to a flexible polymeric container with an integral pressure relief system for retaining components of a fluid system.
Background ofthe Invention Spraying fluid materials, such as paints, stains, adhesives, lubricants, and pesticides, through a nozzle onto a substrate is a common and effective method of application. When multiple component fluid systems are to be applied, there are several ways that the components may be combined. For example, the multiple components may be applied sequentially. This method of combining the components requires more than one pass across the substrate and may require a separate spray applicator for each individual component. Additionally, the components are not mixed prior to contact with the substrate, but rather applied in layers. Another method of combining multiple component fluid systems is to mix the components prior to their application to the substrate. The components may be mixed either before they leave the spray applicator or after they leave the spray applicator, but before reaching the substrate. The individual components of many multiple component fluid systems react in a manner that is undesirable if combined prior to application to the target substrate. When the components are mixed internal to the spray applicator, the reaction between the components may occur earlier than desired and thereby reduce the performance ofthe multiple component fluid system, either in the application process or after the coating has been applied to the substrate. Additionally, the components of some multiple component fluid systems may be corrosive to some materials or parts ofthe spray applicator, either in their individual component form or when combined, or may clog the nozzle. In the case of multiple component adhesives, the components are generally an adhesive base and an activator or catalyst which causes the adhesive to cure. The two components must be mixed at the time they are applied to the substrate. When a multiple component adhesive is mixed prior to leaving the spray applicator, the mixture is applied through a single spray nozzle. However, upon mixing the adhesive base and activator, the adhesive immediately begins to cure. Premature curing ofthe adhesive can cause a build¬ up of adhesive around the orifice ofthe nozzle, resulting in interference with the nozzle spray pattern and decreased spraying efficiency. Further, internal mixing of multiple component adhesive systems requires meticulous cleaning ofthe internal parts ofthe spray applicator. Additionally, as the adhesive begins to cure, its fluid properties begin to change, with a corresponding deterioration in nozzle spray pattern and spraying efficiency. The above-described disadvantages can be overcome by mixing the components after they leave the spray applicator, but before being applied to the substrate, using a multi-nozzle spraying apparatus. Typically, two adjacent, atomizing nozzles are positioned so that the various components intermingle and mix prior to reaching the substrate. By spraying each component through a separate nozzle and combining the components external to the spray applicator, the reaction between the components is delayed until immediately prior to contact with the substrate. However, currently available multiple component spraying systems tend to be heavy and complex. Additionally, current multiple component spraying systems provide inadequate atomization, and consequently, incomplete mixing for some multiple component fluid systems.
Systems for spraying multiple component fluid systems are known in the art, as is illustrated in Figure 1. Spray applicator 10 is connected by connector 12 to air hose 14. Air hose 14 is connected at one end to a source of pressurized air (not shown) and at another end to a handle end 17. A passageway extends through the handle end 17 and barrel end 18 to a spray applicator bracket assembly 21 and nozzle assembly 16. Trigger 20 actuates a valve actuator 19 that controls the flow ofthe pressurized air through the spray applicator 10.
A first bottle 22 and a second bottle 24 are each directly mounted on and supported by the spray applicator bracket assembly 21. The first bottle 22 is for receipt ofa quantity ofa first fluid and the second bottle 24 is for receipt ofa quantity ofa second fluid.
Draw tubes 26 and 28 extend into the first and second bottles, respectively, in fluid communication at one end with the first and second fluids.
The nozzle assembly 16 is detachably mounted on the spray applicator 10 operatively connected to the passageway. The nozzle assembly 16 utilizes air pressure to draw out the first fluid from the first bottle 22. The second nozzle assembly 31 is mounted on the spray applicator bracket assembly 21 and is operatively connected to the body ofthe spray applicator 10 by air line 30. The nozzle assembly 31 utilizes air pressure from the passageway ofthe spray applicator 10. The two separate air streams through separate passageways are each restricted and then expanded to an orifice.
When the trigger 20 is actuated, a stream of pressurized air from the spray applicator passes over the ends ofthe draw tubes 26 and 28 within the separate passageways within the nozzle assembly
16. The reduced pressure acts to draw the first and second fluids upwards through the draw tubes 26 and 28 where the fluid stream is atomized and ejected from the spray applicator 10. Typically, the atomized sprays ofthe first and second fluids are intermixed at the exterior ofthe spray applicator 10 prior to encountering the surface to which the fluids are to be applied.
The following is a non-exclusive list of commercially available conventional spray applicator systems generally used in the industry: Binks Manufacturing Company of Franklin Park, IL; Graco Incorporated of Minneapolis, MN and Mattson Equipment of Rice Lake, Wisconsin. These commercial spray applicators operate using a pressurized fluid transport system using opposing air streams on either side ofthe fluid stream to give shape and atomization to the exiting fluid. Co-mixing can be accomplished by introducing a second fluid into the shaping air stream or by mounting a separate spray nozzle in much the same fashion as Figure 1.
Figure 2 illustrates another spray applicator arrangement 50, including a spray applicator 10', connector 12' and air hose 14'. A nozzle assembly 16' is connected to the spray applicator 10' and includes draw tube 26' that is in fluid communication with a flexible fluid bag 22'. Support 52 is connected at one end to the bag 22' and at the other end to the spray applicator 10'. The nozzle assembly 16' from the spray applicator 10' utilizes air pressure to draw fluid from the bag 22' and to atomize the fluid, as described with respect to the arrangement shown in Figure 1. In place ofthe second bottle 24 as in Figure 1, a pressurized aerosol container 54 is provided.
Gripping the trigger 20' actuates air pressure which draws fluid from the fluid bag 22' and simultaneously mechanically actuates the aerosol container 54. Both sprays are simultaneously emitted from the spray applicator 10' and intermix prior to encountering a surface to which the sprayed fluids are to be applied. Figure 3 illustrates the exemplary nozzle assembly 16' of Figure 2 connected to the flexible bag 22'. Fitting 56 forms a seal with the flexible bag 22' enabling one end of draw tube 26' to extend into the interior ofthe bag 22'. Fitting 57 is adapted to engage quick connect 58 mounted on the draw tube 26' to secure the tube
26' to the bag 22'. The other end ofthe draw tube 26' is connected by quick connect 58 to connector lock 80 attached to port 60 ofthe nozzle assembly 16'. Securing mechanism 61 secures locking mechanism 80 to fitting 58. Figure 4 further illustrates the nozzle assembly 16'. Port 60 includes conduit 59 communicating with passageway 62 extending from one end ofthe nozzle assembly 16' to an opposing end. The opposite end ofthe nozzle assembly includes shroud 64 defining shoulder 66 within the passageway 62. Nozzle assembly 16' may be connected to the spray applicator such as by "J" slot 67 engaging aligned post (not shown) on the spray applicator. The venturi effect may be induced by insert 68 having passageway 70 with a smaller cross-sectional area than passageway 62. The insert 68 may be positioned within shroud 64, located by contact between annular flange 72 ofthe insert 68 and shoulder 66. Washer 74 having aperture 76 may used to seal the insert when the nozzle assembly 16' is mounted on the spray applicator 10'. The stream of pressurized air flows though aperture 76, passageway 70 and passageway 62. When the air stream emerges from passageway 70, the resulting drop in pressure acts to draw the fluid up from the flexible bag 22' through port 60 into the air stream. It will be appreciated that a similar arrangement may be employed for the spray applicator 10 of Figure 1.
Both ofthe arrangements of Figures 1 and 2, while having their own utility, have several limitations for certain applications.
Specifically, when the fluid containers 22, 22', 24, 54 are directly attached and supported by the spray applicator 10, 10', the total weight ofthe system may become tiring to carry and operate, particularly over long periods of time. It is also somewhat difficult to remove, refill, or replace the fluid containers while directly connected to a spray applicator.
Further, it is important to provide a spraying system that is as accurate as possible in dispensing and fully atomizing (small particle size and uniform spray pattern) the fluids. For instance, for particular fluids that are to be sprayed and intermixed, maintaining certain flow rates and pressure is critical to optimum spraying. In some prior art spraying systems, incorrectly adjusting the required pressure and flow rate settings on the spray applicator will result in less than optimum application. Further, some fluids may be incompatible, requiring thorough cleaning ofthe spray applicator and nozzle assembly, which cleaning process may be bothersome and time consuming.
In some circumstances, such as ifthe nozzle is clogged, pressure in the fluid containers can increase to a critical level. Consequently, the flexible bag 22' illustrated in Figures 2 and 3 may burst due to excess pressure.
Recently, two-part water-based adhesives have been introduced to the adhesive market, such as "Fastbond 2000-NF Adhesive" and "Fastbond Spray Activator," manufactured by Minnesota Mining and Manufacturing Company of St. Paul, Minnesota. This two-part adhesive has different fluid properties than previously available adhesives and requires an accurate ratio of each component. Consequently, current available spraying systems have proven inadequate and/or difficult to use due in part to the adjustability of conventional spray applicators. Specifically, the commonly used nozzle assemblies create a narrow stream of activator fluid exiting the nozzle and impinging upon the spray of adhesive base. When the activator is added to the adhesive base spray in a narrow stream, it is generally only the central portion of the adhesive base spray which is mixed with the activator fluid. The resulting pattern of adhesive on the substrate is incompletely activated. Applicants have found that approximately less than 30% ofthe adhesive is activated when current two-part water-based adhesives are used in the currently available side injector nozzle assemblies. The remainder ofthe adhesive base remains wet and fails to function correctly.
Summary ofthe Invention The present invention relates to a nozzle assembly with a preset delivery rate and a fluid spraying system suitable for use with single component or multiple component fluid systems. The nozzle assembly has an atomizing portion defining a passageway in fluid communication at a first end with pressurized air from a spray applicator. The passageway has a first cross-sectional area proximate the first end, a second cross-sectional area less than the first cross-sectional area proximate a middle portion, and a fluid inlet port between the middle portion and a second end. A portion ofthe passageway ofthe first atomizing portion between the middle portion and the second end has a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end so that a reduced pressure condition is created in the passageway proximate the fluid inlet port when pressurized air is supplied to the nozzle assembly.
The spraying system includes at least one container for receiving a fluid. A spray applicator is provided for controlling the flow of pressurized air to a nozzle assembly. A flexible tube fluidly connecting the container with the fluid inlet port is provided so that the fluid is drawn through the fluid inlet port and expelled in an atomized stream from the second end ofthe atomizing portion when pressurized air is supplied to the nozzle assembly.
Multiple atomizing portions may be provided for independently spraying each component ofa multiple component system in a preset, fixed ratio. In one embodiment, an atomized stream is generated for each component ofa multiple component system. The atomized streams may be overlapped to intermix the fluids. The angle of intersection ofthe atomized streams preferably is about 14-19°. The first and second cross-sectional areas of each atomizing portion determine the ratio of each component ofa multiple component fluid system in the resulting atomizing streams. In one embodiment, the ratio ofthe fluids in their respective atomizing streams is between 13:1 to 17:1. In another embodiment, the ratio is between 20:1 to 30:1.
The container may be a flexible, polymeric bag. In one embodiment, the polymeric bag has a seal proximate a perimeter edge. A closable fitting extends into the bag for receiving a flexible tube. A releasable closure is provided proximate a portion ofthe perimeter edge. The releasable closure has a release pressure less than the burst strength ofthe flexible polymeric material. In one embodiment, the releasable closure is a rib and trough system. The flexible polymeric bag may include a gusset so as to be self- supporting when in an upright position. The flexible polymeric bags may be retained in a receptacle having a carrying handle. The flexible polymeric bag may also be made with an integral handle shaped into the bag perimeter.
The present invention is also directed to a container for receiving a fluid for use with a spraying apparatus. A flexible polymeric material is configured to form a pouch. A seal extending substantially around a perimeter edge ofthe flexible polymeric material retains a fluid within the pouch. A closable fitting extends into the pouch. The closable fitting has a closed position for retaining the fluids within the pouch and an opened position for receiving a flexible tubes in fluid communication with the fluid. A releasable closure is provided proximate a portion ofthe perimeter edge. The releasable closure has a release pressure less than the burst strength ofthe flexible polymeric material. The closable fitting may be retained between first and second layers of flexible polymeric material. In one embodiment, the releasable closure is a rib and trough closure system constructed to open in response to pressure within the container in excess ofa predetermined amount.
The method ofthe present invention includes providing pressurized air to at least one nozzle assembly ofthe present invention. The pressurized air creates a reduced pressure condition in the passageway proximate the first fluid inlet port. The reduced pressure condition draws a fluid into the first fluid inlet ports. The fluid is expelled from the nozzle assembly and atomized. In the preferred embodiment, the multiple atomized streams are overlapped to intermix the components ofa multiple component system. Definitions used in this application:
"Fluid" shall mean any flowable, sprayable material, including, without limit, a paint, varnish, stain, mastic, gel-coat, cleaning solvent, sealant, lubricant, adhesive, pesticide, herbicide, cleaning or degreasing solvent, wear coating, abrasion resistant coating or slip coating.
"Multiple component fluid system" shall mean including, but not limited to, the combination of two or more fluids such as curing systems including a catalyst as one component and a reactive resin such as a two-part urethane, two-part adhesive systems, two-part epoxy systems; two-part latex systems; non-curing systems such as pigment/colorant and base compounds; and diluents and concentrates such as pesticides and herbicides and coatings in which particulate such as granular or encapsulated materials are incorporated into or onto a dispensed fluid.
Brief Description ofthe Drawing
The present invention will be further described with reference to the accompanying drawing wherein like reference numerals refer to like parts in the several views.
Figure 1 is a side view of a two-component fluid spraying system;
Figure 2 is a side view of an alternate two-component fluid spraying system with a flexible bag and an pressurized aerosol container attached to the spray applicator;
Figure 3 is a partial side exploded view ofthe attachment of the flexible bag of Figure 2;
Figure 4 is a side exploded view ofthe spray nozzle ofthe conventional spray system of Figure 2;
Figure 5 is a perspective view of an exemplary multiple component spray system according to the present invention; Figure 6 is a top exploded view of an exemplary spray nozzle assembly for a multiple component spray system;
Figure 7 is a side cross-sectional view perpendicular to plane 7-7 ofa first spray portion ofthe nozzle of Figure 6;
Figure 8 is a top cross-sectional view perpendicular to plane 8-8 ofa second spray portion ofthe nozzle of Figure 6;
Figures 9 A, 9B and 9C are sequential isometric views illustrating the assembly ofthe spray nozzle assembly of Figure 6; Figure 10 is a top cross-sectional view ofthe spray nozzle assembly of Figure 6; Figure 11 is an isometric view ofthe nozzle of Figure 6, partially exploded to show the connection ofthe fluid conduits; Figures 12 and 12 A illustrate a connection of first and second fluid conduits to first and second fluid containers;
Figures 13 and 13 A are isometric views ofa receptacle for receiving and securing first and second fluid containers; Figure 14 is an isometric view of an alternate flexible fluid container having a venting member; and
Figure 15 is a plan view of an alternate flexible fluid container having an integral handle.
While the above-identified drawing features set forth preferred embodiments, this disclosure presents illustrative embodiments ofthe present invention by way of representation and not by limitation. It should be understood that numerous other modifications and embodiments can be devised by those skilled in the art which fall within the spirit and scope ofthe principles of this invention. It should be noted that the figures have not been drawn to scale as it has been necessary to enlarge certain portions for clarity.
Detailed Description ofthe Preferred Embodiments Multiple fluid spraying systems are useful for simultaneously spraying two or more fluids, either onto a surface or into the air in the case of pesticides. Frequently, it is desirable to intermix the fluid spray with each other prior to encountering the surface. For example, some adhesive compounds, such as "Fastbond 2000-NF Adhesive" and "Fastbond Spray Activator," discussed above, include a first fluid resin and a second fluid activator, catalyst or modifier. Intermixing the first and second fluids in overlapping atomized sprays causes the adhesive to be tacky when applied to a surface. Referring now to Figure 5, there is shown a multiple fluid spraying system 110 according to the present invention. System 110 includes spray applicator 112 connected by attachment 114 and hose 115 to a source ofa pressurized fluid, most preferably air. The system 110 includes a first fluid container 116 and a second fluid container 118 retained in receptacle 248. The first and second fluid containers 116, 118 are for receipt of first and second fluids 116F, 118F (see Figure 12) to be sprayed by the spraying system 110 of the present invention. It will be understood that although two fluid containers are illustrated, the present invention may be employed to spray a single fluid or more than two fluids, as may be found advantageous for a particular application or fluid. In such a case, a corresponding number of fluid containers, spray nozzles and ports on the spray applicator may be provided in conjunction with the fluid spraying system described herein.
Spray applicator further includes nozzle assembly 120 connected by first and second fluid conduits 122 and 124 to the first and second fluid containers 116 and 118, respectively. Suitable fluid conduits 122, 124 are available from Freelin-Wade Company, McMinnville, Oregon. The spray applicator 112, pressurized air from the hose 115, nozzle assembly 120, first and second fluid containers 116 and 118, and first and second fluid conduits 122 and 124 act to generate atomized sprays ofthe first and second fluids
116F, 118F. The nozzle assembly 120 directs the atomized sprays into intersecting paths prior to encountering a surface.
The structure and operation of spray applicator 112 will now be described in greater detail. Spray applicator 112 includes housing 130, most conveniently provided in a "pistol" configuration with a handle portion 132 adapted for manual engagement and manipulation to direct the atomized sprays ofthe first and second fluids towards a desired surface. It will be understood, however, that the housing 130 may take any other suitable configuration as is found advantageous in a particular application. Barrel portion 134 projects generally orthogonally from the handle portion 132 along longitudinal axis 136. Hook 138 may optionally be provided to support the spray applicator 112 from a suitable support structure (not shown).
The housing 130 may be constructed from any suitable material, but is preferably constructed from a monolithic molded body ofa polymeric or metallic material compatible with the fluids to be sprayed. Alternatively, the housing may be constructed ofa pair of molded bifurcated mirror image portions (not shown) that are secured in sealing relationship. The following is a non-exclusive list of materials that may be used to construct the housing 130 ofthe spray applicator: aluminum, steel, polycarbonate, composites, epoxy, or some combination thereof.
Passageway 140 extends from a first end 142 though the handle portion 132 and the barrel portion 134 to second end 144 in manner that is directed away from the user ofthe spray applicator
112. Attachment 114 is sealingly mounted about first end 142 ofthe passageway 140 and is connected by pressurized air hose 115 to a source of pressurized air (not shown). Pressurized air thus flows though hose 115 and passageway 140 to second end 144. As will be further discussed in the examples, the air pressure supplied to the spray applicator 112 is generally between 15 and 40 p.s.i. at a flow rate of approximately 2-5 c m. Attachment 114 may include an adjustable valve 154 for regulating the flow rate for the air, or alternatively, the pressure. Gauge 156 may also be provided to display the flow rate or pressure ofthe air flowing into the spray applicator 112. A suitable valve/gauge assembly is available from Schrader Bellows located in Des Plaines, Illinois.
The flow ofthe pressurized air through the spray applicator 112 is controlled by a valve 158 actuated by trigger 160. The valve 158 permits either a progressive increase in the flow rate ofthe air or a simple on-off arrangement at a pre-set flow rate. In the illustrated embodiment, the trigger 160 is biased to a closed position.
A first fluid atomizing portion 168 is mounted in sealing relation to the spray applicator 112 in fluid communication with the second end 144 ofthe passageway 140. A second atomizing portion
170 is fluidly connected to the first atomizing portion 168. Any suitable arrangement may be employed to sealingly mount the first fluid atomizing portion 168 on the spray applicator 112. As is illustrated in Figure 5, skirt 180 extends concentrically away from the first fluid atomizing portion 168. The skirt 180 is adapted to slidingly receive the end ofthe barrel portion 134 ofthe spray applicator 112. Skirt 180 includes a 'T' slot 182 (see Figure 7) for engagement with a suitably sized post 184 radially projecting from the barrel portion 134. Relative rotation ofthe first fluid atomizing portion 168 with respect to the banel portion in direction 186 around the axis 136 locks the first fluid atomizing portion 168 in place on the barrel portion 134 in fluid communication with the passageway 140 ofthe spray applicator 112. Relative rotation ofthe first fluid atomizing portion 168 with respect to the banel portion 134 in opposing rotational direction 188 disengages the "J" slot 182 and the post 184, enabling the first fluid atomizing portion 168 to be removed from the spray applicator 112. The following is a non¬ exclusive list of commercially available spray applicators 112 that may be used in conjunction with the nozzle assembly 120 ofthe present invention: MAFA-Sebald Nertiesbsges of Breckerfeld,
Germany and Off. Meccaniche A.Ν.L S.p.A. of Via Arzignano, 132 Italy.
Referring now also to Figures 6-8 and 10, nozzle assembly 120 is provided to convey the flow ofthe pressurized air from the spray applicator 112 to draw the first and second fluids 116F, 118F from the first and second fluid containers 116, 118, respectively, in manner to be described in greater detail hereinafter. The first atomizing portion 168 is used in conjunction with the first fluid 116F and the second atomizing portion 170 is used in conjunction with the second fluid 118F. The first and second atomizing portions 168, 170 are generally a venturi device operating under Bernoulli's theorem. Most simply stated, Bernoulli's theorem states that when a gas or fluid is flowed through a restricted area, as in a nozzle or venturi, its speed will increase and its temperature and pressure will decrease. If the cross-sectional area is increased as in a diffuser, the reverse is true. The total energy in a flowing gas is made up of static and dynamic temperatures, and static and dynamic pressures. A nozzle or diffuser does not change to total energy level, but rather changes one form of energy to another. For example, a nozzle will increase the flow, or dynamic pressure, at the expense ofthe static pressure.
Ifthe gas is moving through a passageway at so many pounds per second, the air must continue to flow at the same rate through the nozzle. The only way it can do this is to speed up. A diffuser will do the opposite. Thus by varying the cross-sectional area ofa passageway, velocity can be changed into pressure, and pressure into velocity.
As best illustrated in Figure 7, the first fluid atomizing portion 168 includes a passageway 172 extending from a first end 174 to a second end 176. A fluid induction port 178 is formed inteπnediate the first end 174 and the second end 176 ofthe passageway 172 to provide a "venturi" effect. The passageway 172 includes a first diameter Dl proximate the first end 174, a smaller diameter at D2 at an intermediate point, and an expanded diameter D3 that is larger than diameter D2 proximate the second end 176. This arrangement produces an increase in speed and a reduction in the pressure at D2 as the compressed air flows through the passageway 172 that draws the first fluid 116F into the first atomizing portion 168. The frusto-conical structure having a maximum diameter D3 at the second end 176 directs the resulting atomized stream along the axis 177 (see Figure 10). As illustrated in Figure 8, the second fluid atomizing portion
170 includes a passageway 190 extending from a first end 192 to a second end 194. A fluid induction port 196 is formed intermediate the first end 192 and the second end 194 ofthe passageway 190 to provide a "venturi" effect. The passageway 190 includes a first diameter D4 proximate the first end 192, a smaller diameter D5 at an intermediate point and an expanded diameter D6 proximate the second end 194 that is larger than diameter D5. This arrangement produces an increase in speed and a reduction in the pressure at D5 that draws the second fluid 118F into the second atomizing portion 170. The frusto-conical structure having a maximum diameter D6 at the second end 194 directs the resulting atomized stream along the axis 199 (see Figure 10).
It will be understood that the diameters D1-D6 are circular only for ease of manufacture and that the critical variable is the cross-sectional area ofthe passageways 172, 190 at the locations
D1-D6. In particular, the cross-sectional shape ofthe passageways 172, 190 may be a variety of symmetrical or asymmetrical shapes.
The flow rate and level of atomization ofthe atomized stream from the first atomizing portion 168 is generally a function of the pressure ofthe supplied air, D1-D3, the diameter ofthe induction port 178 and the viscosity ofthe first fluid 116F. Likewise, the flow rate and level of atomization ofthe atomized stream from the second atomizing portion 170 is generally a function ofthe pressure ofthe supplied air, D4-D6, the diameter ofthe induction port 196 and the viscosity ofthe second fluid 118F. These variables determine the ratio ofthe first and second fluids emitted from the nozzle assembly 120.
For some multiple component fluid systems, the ratio ofthe individual components is critical to performance. The nozzle assembly 120 is designed to spray a fixed ratio ofthe first fluid 116F to the second fluid 118F at a given pressure of supplied air and viscosity, without any risk of operator error due to improper adjustment ofthe air pressure, flow rates, spray angles ofthe nozzles, etc.. The present fixed-ratio nozzle assembly 120 provides a more accurate and reliable spraying ofthe fluids than can generally be achieved by other conventional spraying systems. It will be understood that low-cost nozzle assemblies 120 having different Dl- D6 values may be easily manufactured to provide optimum spraying conditions for various multiple component fluid systems with the same beneficial result.
Additionally, the size, length, angle between the fluid sprays ofthe nozzle assembly 120 may be pre-set, eliminating the need for adjustment. Further, for most applications, it will be economically viable to simply dispose ofthe nozzle assembly 120 after each use, thus eliminating the need for cleaning prior to the next use. Finally, changeover for spraying ofa different set of fluids is also easily and quickly accomplished by substituting a different nozzle assembly 120 fluidly connected to a different set of fluids.
Figures 9 A, 9B and 9C sequentially illustrate a method of assembling the first and second atomizing portions 168, 170 and connecting member 200 to each other. The connecting member 200 is inserted at each end into ports 204, 206, but with the second fluid atomizing portion 170 rotated approximately 90° from the final position. The second fluid atomizing portion 170 may then be rotated in direction 221 about the port 204 ofthe first fluid atomizing portion 168. Post 220 is thus positioned for engagement with aperture 218 to secure flanges 214, 216 to each other, as shown in Figure 9C. The post 220 may be frictionally received within the aperture 218 so as to secure the flanges 214, 216, and thus the first and second fluid atomizing portions 168, 170 in a fixed relationship. As will be discussed below, the fixed relationship ofthe atomizing portions 168, 170 insures that the atomized sprays are emitted in an overlapping pattern. It will be understood that other methods of assembling the first and second fluid atomizing portions 168, 170 of the nozzle assembly 120 may be selected. Further, other configurations may be utilized to construct the nozzle assembly 120, such as by molding a unitary molded polymeric body forming both venturi passageways 172 and 190.
It will be understood that the second fluid atomizing portion 170 may be connected to an independent source of pressurized air. However, in the preferred embodiment ofthe present invention as illustrated in Figure 10, a portion ofthe stream of pressurized air adjacent the first end 174 ofthe first atomizing portion 168 is diverted through a passageway 198 to passageway 190. In the illustrated embodiment, the passageway 198 extends through the connecting member 200. The connecting member 200 is inserted into and secured at each end to ports 204, 206, respectively, as discussed above. Concentric tapered projections 208 enabling the connecting member 200 to be sealingly secured at each end to the first and the second fluid atomizing member 168, 170. Annular flanges 210, 212 define a secured position for the connecting member 200 relative to the first and second fluid atomizing members 168, 170. Passageway 198 extends through the connecting member 200 to provide fluid communication between passageways 172 and 190. The low-cost, disposable nozzle assembly 120 is preferably constructed by premolding a unitary molded body from a polymeric material. The following is a nonexclusive list ofthe polymeric materials that may be utilized to construct the nozzle assembly 120: polystyrene, polypropylene, polyethylene, polyvinylchloride, polyacetal, and nylon. Additionally, the surface finish ofthe interior ofthe nozzle assembly 120 illustrated in Figure 10 has a surface finish generally in the range of Al to A2 according to the Society ofthe Plastics Industry Standard for Cosmetic Specifications of Injection Molded Parts, 1994. For purposes of this invention, the term "smooth" means to be formed in a manner that is free from irregularities, roughness, indentations, projections, protuberances or any abrupt changes in geometry that provides a location for the accumulation of solidified material.
As is best illustrated in Figure 10, the second end 194 ofthe second atomizing portion 170 extends beyond and forward from the second end 176 ofthe first atomizing portion. For multiple component fluid systems utilizing an activator, the configuration in Figure 10 minimizes coagulation, activation or catalyzation ofthe adhesive, epoxy, etc. on the nozzle assembly 120.
Figure 11 illustrates the connection ofthe conduit 122 to the induction port 178 on the first atomizing portion 168 and the second conduit 124 to the induction port 196 on the second atomizing portion 170. A check valve 195 may be interposed between the second conduit 124 and the second atomizing portion 170 to prevent the first fluid 116F from being drawn into the second fluid container 118 and to prevent fluid 118F from dropping back into the container
118. A check valve may also be included in the first conduit 122. A check valve suitable for use with the nozzle assembly 120 is available from Clippard Instrument Laboratory, Inc. located in Cincinnati, Ohio. Additionally, other fixed ratios can be achieved by inserting a flow restrictor in conduits 122, 124. Figures 12 and 12A illustrate a system for independently moving and flexibly connecting each ofthe fluids to be sprayed from the spray applicator 112. It will be understood that any suitable container may be employed, such as bottles or the like (not shown). However, the flexible fluid containers 116, 118 offer certain advantages. The containers 116, 118 may be constructed from opposing generally rectangular polymeric sheets of laminated or non- laminated films bonded together along aligned edges as at seams in a manner known in the art. In the preferred embodiment ofthe invention, the fluid containers 116, 118 are flexible polymeric bags constructed of polyethylene terephthalate (PET), biaxially oriented nylon, linear low density polyethylene laminate available from Kapak Corporation of Minneapolis, MN.
The first and second fluid container 116 and 118 are operatively connected to the nozzle assembly 120 by separate first and second fluid conduits 122, 124, respectively, so as to facilitate the carrying and manipulation ofthe spray applicator 112. The first and second fluid conduits 122, 124 are sealingly connected to the containers 116, 118 by frictional engagement with tapered annular projections 242. The tapered annular projections 242 are frictionally connected to draw tubes 175, 176, which extend through closable fitting 244 into the containers 116, 118. Alternatively, a tubing with an outside diameter equal to or less than the inside diameter ofthe opening in the closable fitting 244 may be used in place ofthe tapered annular projections 242. A flexible polymeric tubing, such as clear polyvinyl chloride (PNC) available from Freelin-Wade Company of McMinnville, Oregon, is suitable for use as the fluid conduits 122, 124 and draw tubes 175, 176.
Increased pressures within the containers 116, 118 may be generated by increased temperatures or chemical reaction ofthe substances, or clogging of either or both ofthe nozzles 168, 170. In an alternate container 230 illustrated in Figure 14, a vent 245 responsive to the presence of pressure within the container 230 above a selected limit is provided. The vent 245 includes a segment ofthe container sealed by a releasable closure 246 located within the perimeter of seam 234. The releasable closure 246 may be constructed ofa rib and trough closure system such as found on bags marketed under the trademark "Ziploc" pleated bags by Dow Brands, Inc. of Indianapolis, Indiana. The container 230 has a tamper-evident, reclosable, reusable, pourable spout. The seam 234 preferably extends around the entire perimeter ofthe container 230 to retain the fluid within the container 230 during shipping and handling. Prior to use, the operator preferably cuts a notch 247 part-way through the seam 234 in the container material proximate the closure 246. The releasable closure 246 provides a fluid impervious seal during normal use ofthe containers
230. However, if elevated pressures are encountered, the releasable closure 246 will be forced open at a particular level causing an audible report notifying the operator to release the excess pressure. The releasable closure enables a portion ofthe pressurized material within the container 230 to be released through the releasable closure 246 and notch 247 in the bag material, preventing a discharge ofthe material, with obvious undesirable consequences. The releasable closure 246 may also be opened during use ofthe spraying system 110 so that additional fluid or other material can be added to the container, without the need to suspend use ofthe spraying system 110. Alternatively, the seam 234 may be incomplete proximate the releasable closure 246 and a mechanical fastener substituted for closure 246 to retain the fluid during shipping and handling. In the preferred embodiment ofthe invention, the flexible fluid containers 116, 118 are self supporting when in an upright or standing orientation, such as by forming gussets 235 in the bottom thereof (see Figure 14). However, as it is desired to move the fluid spraying system 110 to varying locations, it may become inconvenient to carry both ofthe fluid containers 116, 118 as well as the spray applicator 112. Therefore, in the preferred embodiment of the invention, a receptacle 248 is provided having a cavity 250 (shown in Figures 5, 13 and 13 A). Receptacle 248 is preferably rigid or at least sufficiently self supporting to receive and support the first and second fluid containers 116, 118 in an upright position within cavity 250 during use. The receptacle 248 may be conveniently constructed in a rectangular configuration. The receptacle is preferably constructed ofa light weight material such as #160 high density polyethylene corrugated plastic available from Liberty Carton Company of Golden Valley, Minnesota. Polyethylene is preferred because of its durability and its resistance to water and solvent based products.
To further facilitate the manipulation ofthe first and second fluid containers, the receptacle 248 may include handle or like device adapted for manual engagement. One such handle is illustrated in Figures 13 and 13 A in the form of opposed flaps 252, 254, each hingedly connected to opposed upper edges 256, 258 ofthe receptacle 248. Subflaps 252a, 254a, respectively may be brought together in a "gabletop" arrangement as shown in Figure 13 A. Each ofthe subflaps include aligned handle apertures 260 and 262 that may be manually engaged to carry and manipulate the receptacle.
Most preferably, one ofthe subflaps includes securing flap 264 that may be pushed through the opposing handle aperture and frictionally retained therein. In this manner, the flaps and subflaps are maintained in the position shown in Figure 13 A during use. If it is desired to remove or replace either or both ofthe fluid containers
116, 118, the securing flap 264 may be disengaged from the opposing flap 252, 254 and the flaps separated. It will be understood that any other suitable arrangement may be employed to provide an handle for the receptacle, or to releasably secure the flaps and subflaps of Figures 13 and 13 A in the position shown in Figure 13 A, such as hook and loop fasteners, clips, staples, tape, or adhesives. Instructions may be printed on the receptacle 248 for the convenience ofthe operator.
Figure 15 illustrates an alternate bag 230' in which a handle 250 is integrally formed in or near seam 234'. One or more ofthe bags 230' may be carried by an operator along with the spray applicator 110.
As best illustrated in Figure 5, valve 158 is opened, enabling the pressurized air to flow through the spray applicator 112 and the nozzle assembly 120, including both venturi passageways 172, 190. As best illustrated in Figure 10, the reduced pressure adjacent to port 178 induces the first fluid 116F to be conveyed through first fluid conduit 122, port 178 and into the passageway 172. The first fluid 116F is thoroughly atomized by the encounter with the stream of pressurized air flowing through the passageway and is ejected along axis 177 from the second end 176 ofthe passageway 172 from the nozzle assembly 120. Preferably, the axis 177 is aligned with axis 136 of passageway 140 in barrel portion 134 ofthe spray applicator housing 130 (see Figure 5). Similarly, the reduced pressure adjacent to the port 196 induces the second fluid to be conveyed through second fluid conduit 124 and port 196 into passageway 190. The second fluid 118F is thoroughly atomized by the encounter with the stream of pressurized air flowing through the passageway 190 and is ejected along axis 199 from the second end ofthe passageway 190 ofthe nozzle assembly 120. The axes 177 and 199 ofthe sprays emerging from the first and second fluid atomizing portions 168, 170 intersect and intermix at a desired location spaced from the nozzle assembly 120 (as at "A"). This configuration enables the first and second fluids 116F, 118F to intermix and interact prior to encountering the surface to which they are to be applied. The angle 231 between the axes 177 and 199 may be determined, in part, by the configuration ofthe connecting member 200, as shown in Figure 10. The intersection angle ofthe two spray streams is preferably between 14° and 19°
Examples Delivery Rate
The spray system to be tested was secured with a clamp in a vertical position so that the spray nozzle assembly was about 30 cm (12 inches) from the mid-point ofthe surface ofa drum 41 cm (16 inches) high by 38 cm (15 inches) diameter rotating at 18 RPM, on which a transparent film was attached. A two-part, water-based adhesive system was used as the material to be sprayed. The adhesive was a contact adhesive having nominal 49% solids content and Brookfield viscosity of 200-700 cps and the activator was a water thin, inorganic salt solution having nominal 15 % solids content (3M' Fastbond' 2000-NF Adhesive and 3M' Fastbond' Spray Activator, commercially available from Minnesota Mining and
Manufacturing Company, St. Paul, MN). With fluid container feed lines attached to the spray applicator, air lines connected to the spray nozzle, and the air supply turned on, the fluid containers were each placed on a separate electronic balance to determine their initial weight. The spray applicator was actuated for about 30 seconds, depositing material on the transparent film. The fluid containers were then each weighed again (final weight). The difference between the initial weight and the final weight multiplied by 2 gave the "Delivery Rate" in grams/minute for the adhesive and for the activator. Degree of Activation
The material coated transparent film from the Delivery Rate test was removed from the drum and immediately tested for degree of activation by lightly touching the back area between the first and second knuckle of either the index or middle finger against the adhesive surface. For the adhesive system tested, the material was rated as very (v) wet to wet (low adhesive activation), dry to very (v) dry (high adhesive activation), or tacky to slightly (si) tacky (desired adhesive activation).
Sprav Width
Using the material coated transparent film from the Degree of Activation test, at least 2 measurements ofthe major dimensions were taken and the average was determined to be the "Spray Width". A desired result is an average spray width of 5.0- 10.16 cm (2-4 inches).
Uniformity of Particle Spray
The material coated transparent film from the Spray Width test was visually inspected for uniformity of particles. If at least 80 percent ofthe spray was of similar size, the spray was observed to be uniform.
Examples 1-3
In examples 1-3, the effect of varying the air pressure for the activator and for the adhesive was determined.
A spray system ofthe invention was fitted with a spray nozzle assembly having the following dimensions as referenced on Fig. 7: Dl was
5.94 mm ( 0.234 inches), D2 was 3J75 mm (0J25 inches), D3 was 8.89 mm (0.35 inches) and the diameter of port 178 was 2.29 mm (0.090 inches); as referenced on Fig. 8, D4 was 4.47 mm (0J76 inches), D5 was 1.27 mm (
0.050 inches), D6 was 5.82 mm (0.229 inches); and the diameter of port 196 was 0.508 mm (0.020 inches). The spray nozzle assembly was made of acrylonitrile butadiene styrene copolymer (ABS). Flexible containers containing the material to be sprayed, air lines and supply lines were attached to the spray applicator and the spray system was tested according to the test methods outlined above using varying air pressure for the adhesive and for the activator.
The air pressure for the adhesive and activator, delivery rates ofthe adhesive and activator, the degree of activation, spray width, and uniformity of particle spray are presented in Table 1 below.
TABLE 1
Example Air Pressure, MPa (psig) Delivery Rate g min Spray Width Uniformity of Degree of No. Adhesive Activator Adhesive Activator cm (inches) Particle Spray Activation
1 0.069 (10) 0.069 (10) 60 8 8 (3.1 ) non-uniform si. dry
2 0.103 (15) 0.103 (15) 60 20 8 (3.1) uniform v. dry
3 0.165 (24) 0.165 (24) 60 12 8 (3.1) uniform v. dry
From the data it can be seen that varying the air pressure affects the delivery rate ofthe activator and the uniformity of particle spray.
Examples 4-6
In examples 4-6, the effect of varying the air pressure for the activator and for the adhesive was determined.
A spray system ofthe invention was prepared and tested as in Examples 1-3 with the exception that the spray nozzle assembly had the following dimensions: D2 was 2.794 mm (0J 10 inches) and the diameter of port 178 was 2.39 mm (0.094 inches); as referenced on Fig. 8, D5 was 1.52 mm ( 0.060 inches) and for Example 6, the diameter of port 196 was 0.381 mm (0.015 inches).
The air pressure for the adhesive and activator, delivery rates ofthe adhesive and activator, the degree of activation, spray width, and uniformity of particle spray are presented in Table 2 below. TABLE 2
Example Air Pressure, MPa (psig) Delivery Rate g/min Spray Width Uniformity of Degree of No. Adhesive Activator Adhesive Activator cm (inches) Particle Spray Activation
4 0.165 (24) 0.165 (24) 150 15 10 (4 ) non-uniform dry
5 0.138 (20) 0.138 (20) 120 14 8 (3) non-uniform dry
6 0.138 (20) 0.138 (20) 120 12 8 (3) non-uniform dry
From the data it can be seen that increasing the air pressure of Example 5 by 20% (Ex. 4), increases the delivery rate ofthe adhesive and the spray width by 25%) and the delivery rate ofthe activator by 7%. A 33% increase ofthe diameter of port 196 (Ex. 6 vs. Ex. 5) results in 17% increase in the activator delivery rate.
Examples 7-10
In examples 7-10, the effect of varying the air pressure for the activator and for the adhesive was determined.
A spray system ofthe invention was prepared and tested as in Examples 1-3 with the exception that the spray nozzle assembly had the following dimensions: D2 was 2.82 mm (0J 11 inches) and the diameter of port 178 was 3.05 mm (0J20 inches); as referenced on Fig. 8, D5 was 2.36 mm ( 0.093 inches) and the diameter of port 196 was 1.016 mm (0.040 inches), and was made of high density polyethylene.
The air pressure for the adhesive and activator, delivery rates ofthe adhesive and activator, the degree of activation, spray width, and uniformity of particle spray are presented in Table 3 below. TABLE 3
Example Air Pressure, MPa (psig) Delivery Rate g/min Spray Width Uniformity of Degree of No. Adhesive Activator Adhesive Activator cm (inches) Particle Spray Activation
7 0.193 (28) 0.193 (28) 140 8 10 (4 ) uniform si. tacky
8 0.138 (20) 0.138 (20) 130 8 10 (4) uniform si. tacky
9 0.124 (18) 0.124 (18) 128 4 8-10 (3-4) uniform wet
10 0.103 (15) 0.103 (15) 120 2 8 (3) uniform v. wet
From the data it can be seen that with increasing air pressure, the delivery rate ofthe adhesive, and the spray width increase and the degree of activation changes from very wet to slightly tacky.
Examples 11-14
In examples 11-14, the effect of varying the air pressure for the activator and for the adhesive was determined.
A spray system ofthe invention was prepared and tested as in Examples 7-10 with the exception that the spray nozzle assembly had the following dimension: the diameter of port 196 was 0.508 mm (0.020 inches).
The air pressure for the adhesive and activator, delivery rates ofthe adhesive and activator, the degree of activation, spray width, and uniformity of particle spray are presented in Table 4 below. TABLE 4
Example Air Pressure, MPa (psig) Delivery Rate g/min Spray Width Uniformity of Degree of No. Adhesive Activator Adhesive Activator cm (inches) Particle Spray Activation
11 0.193 (28) 0.193 (28) 130 4 10 (4 ) uniform si. tacky
12 0.138 (20) 0.138 (20) 130 8 10 (4) uniform si. tacky
13 0.124 (18) 0.124 (18) 130 4 8-10 (3*4) uniform si. wet
14 0.103 (15) 0.103 (15) 110 2 8 (3) uniform v. wet
From the data it can be seen that with the nozzle dimensions of Examples 11-14, the delivery rate ofthe activator was maximized at 0J38 MPa.
It will be understood that the exemplary embodiments in no way limit the scope ofthe invention. Other modifications ofthe invention will be apparent to those skilled in the art in view ofthe foregoing descriptions. These descriptions are intended to provide specific examples of embodiments which clearly disclose the invention. Accordingly, the invention is not limited to the described embodiments or to the use of specific elements, dimensions, materials or configurations contained therein. All alternative modifications and variations ofthe present invention which fall within the spirit and broad scope ofthe appended claims are covered.

Claims

What is claimed is:
1. A fluid spraying system, comprising: at least one container for receiving at least one fluid; a spray applicator for controlling the flow of pressurized gas to a nozzle assembly, the nozzle assembly comprising; at least one atomizing portion defining a passageway in fluid communication at a first end with the pressurized gas ofthe spray applicator, the passageway having a first cross- sectional area proximate the first end, a second cross- sectional area less than the first cross-sectional area proximate a middle portion, and a fluid inlet port between the middle portion and a second end so that a reduced pressure condition is created in the passageway proximate the fluid inlet port when pressurized gas is supplied to the nozzle assembly, a portion ofthe passageway ofthe first atomizing portion between the middle portion and the second end having a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end; and at least one tube fluidly connecting the at least one container with the fluid inlet port ofthe atomizing portion so that the a fluid contained within the at least one container is drawn through the fluid inlet port and expelled in an atomized stream from the second end of the atomizing portion when pressurized gas is supplied to the nozzle assembly.
2. The apparatus of claim 1 wherein the at least one container comprises a flexible, polymeric bag.
3. The apparatus of claim 2 wherein the flexible, polymeric bag comprises: a flexible polymeric material having a seal proximate a perimeter edge; a closable fitting for receiving the at least one flexible tube; and a releasable closure proximate a portion ofthe perimeter edge, the releasable closure having a release pressure less than the burst strength ofthe flexible polymeric material.
4. The apparatus of claim 1 wherein the at least one atomizing portion comprises two atomizing portions.
5. An apparatus for spraying a multiple component fluid system, comprising: at least a first and a second container for receipt ofa first and a second fluid, respectively; a spray applicator for controlling the flow of pressurized gas to a nozzle assembly, the nozzle assembly comprising; a first atomizing portion defining a passageway in fluid communication at a first end with the pressurized gas of the spray applicator, the passageway having a first cross- sectional area proximate the first end, a second cross- sectional area less than the first cross-sectional area proximate a middle portion, and a first fluid inlet port between the middle portion and a second end so that a reduced pressure condition is created in the passageway proximate the first fluid inlet port when pressurized gas is supplied to the nozzle assembly; a second adjacent atomizing portion defining a passageway in fluid communication at a first end with the pressurized gas ofthe spray applicator, the passageway having a third cross-sectional area proximate the first end, a fourth cross-sectional area less than the third cross-sectional area proximate a middle portion, and a second fluid inlet port between the middle portion and a second end so that a reduced pressure condition is created in the passageway proximate the second fluid inlet port when pressurized gas is supplied to the nozzle assembly; and at least a first tube fluidly connecting the fluid in the first container with the first fluid inlet port ofthe first atomizing portion and a second tube fluidly connecting the fluid in the second container with the second fluid inlet port ofthe second atomizing portion so that the first and second fluids are drawn through the first and second fluid inlet ports and expelled in first and second atomized streams from the second ends ofthe first and second atomizing portions, respectively, when pressurized gas is supplied to the nozzle assembly.
6. The apparatus of claim 5 wherein the at least first and second containers comprise a plurality of flexible, polymeric bags.
7. The apparatus of claim 6 wherein the at least first and second containers include pressure release means for releasing pressure within the containers in excess ofa predetermined amount.
8. The apparatus of claim 6 wherein the at least first and second containers include a rib and trough closure system constructed to open in response to pressure within the at least first or second containers in excess ofa predetermined amount.
9. The apparatus of claim 5 wherein the at least first and second containers comprise: a flexible polymeric material having a seal proximate a perimeter edge; a closable fitting for receiving the first and second flexible tubes; and a releasable closure proximate a portion ofthe perimeter edge, the releasable closure having a release pressure less than the burst strength ofthe flexible polymeric material.
10. The apparatus of claim 6 wherein the flexible polymeric bag includes a gusset proximate a bottom portion so that the flexible, polymeric bag is self-supporting when in an upright position.
11. The apparatus of claim 6 wherein the first and second flexible bags are retained in a receptacle having a carrying handle.
12. The apparatus of claim 6 wherein the first and second flexible bags further include an integral handle.
13. The apparatus of claim 5 wherein the first and second atomized streams overlap to intermix the first and second fluids.
14. The apparatus of claim 5 wherein the passageways of the first and second atomizing portions define intersecting axes having an angle of intersection of about 14-19°.
15. The apparatus of claim 5 wherein a portion ofthe passageway ofthe first atomizing portion between the middle portion and the second end comprises a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end.
16. The apparatus of claim 5 wherein a portion ofthe passageway ofthe second atomizing portion between the middle portion and the second end comprises a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end.
17. The apparatus of claim 5 wherein the first and second fluids comprise a two-part water based adhesive.
18. The apparatus of claim 17 wherein the two-part water based adhesive comprises an adhesive base and an activator.
19. The apparatus of claim 5 wherein the first and second cross-sectional areas ofthe first atomizing portion and the third and fourth cross-sectional areas ofthe second atomizing portion determine the ratio ofthe first and second fluids in the first and second atomizing streams.
20. The apparatus of claim 5 wherein the ratio ofthe first and second fluids in the first and second atomizing streams comprises between 13. J to 17:1.
21. The apparatus of claim 5 wherein the ratio ofthe first and second fluids in the first and second atomizing streams comprises between 20: 1 to 30: 1.
22. A nozzle assembly for a spray applicator comprising a first atomizing portion defining a passageway in fluid communication at a first end with a source of pressurized air, the passageway having a first cross-sectional area proximate the first end, a second cross- sectional area less than the first cross-sectional area proximate a middle portion, and a first fluid inlet port between the middle portion and a second end so that a reduced pressure condition is created in the passageway proximate the first fluid inlet port when pressurized gas is supplied to the nozzle assembly, a portion ofthe passageway ofthe first atomizing portion between the middle portion and the second end having a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end, whereby the reduced pressure condition is sufficient to draw a fluid through the first fluid inlet port and to expel an atomized stream from the second end of the first atomizing portion.
23. The apparatus of claim 22 further including a second atomizing portion comprising a the passageway having a third cross- sectional area proximate a first end, a fourth cross-sectional area less than the third cross-sectional area proximate a middle portion, and a second fluid inlet port between the middle portion and a second end so that a reduced pressure condition is created in the passageway proximate the second fluid inlet port when pressurized gas is supplied to the second atomizing portion, a portion ofthe passageway ofthe second atomizing portion between the middle portion and the second end having a generally frusto-conical shape with a base ofthe frusto-conical shape proximate the second end, the first end ofthe second atomizing portion fluidly connected proximate to the first end ofthe first atomizing portion by an angled connector, the angled connector retaining the passageway ofthe first atomizing portion in a fixed relationship with respect to the passageway ofthe second atomizing portion.
24. The apparatus of claim 23 wherein the second end of the second atomizing portion extends beyond the second end ofthe first atomizing portion.
25. The apparatus of claim 23 wherein the first atomizing portion comprises a unitary polymeric structure.
26. A container for receiving a fluid for use with a spraying apparatus, comprising: a flexible polymeric material configured to form a pouch; a seal extending substantially around a perimeter edge ofthe flexible polymeric material to retain a fluid within the pouch; a closable fitting extending into the pouch, the closable fitting having a closed position for retaining the fluids within the pouch and an opened position for receiving a flexible tubes in fluid communication with the fluid; and a releasable closure proximate a portion ofthe perimeter edge, the releasable closure having a release pressure less than the burst strength ofthe flexible polymeric material.
27. The container of claim 26 wherein the closable fitting is retained between first and second layers of flexible polymeric material.
28. The container of claim 26 wherein the releasable closure comprises a rib and trough closure system constructed to open in response to pressure within the container in excess ofa predetermined amount.
29. The container of claim 26 further including a handle integrally formed in the seal proximate the perimeter edge.
30. A method of applying a multiple component fluid system, comprising the steps of: providing pressurized gas to a nozzle assembly, the nozzle assembly having a first atomizing portion defining a passageway in fluid communication at a first end with the pressurized air, the passageway having a first cross-sectional area proximate the first end, a second cross-sectional area less than the first cross-sectional area proximate a middle portion, and a first fluid inlet port between the middle portion and a second end; creating a reduced pressure condition in the passageway proximate the first fluid inlet port when pressurized gas is supplied to the nozzle assembly; providing pressurized gas to a second adjacent atomizing portion, the second atomizing portion defining a passageway in fluid communication at a first end with the pressurized air, the passageway having a third cross-sectional area proximate the first end, a fourth cross-sectional area less than the third cross-sectional area proximate a middle portion, and a second fluid inlet port between the middle portion and a second; creating a reduced pressure condition in the passageway proximate the second fluid inlet port when pressurized gas is supplied to the nozzle assembly; drawing first and second fluids into the first and second fluid inlet ports; and expelling first and second atomized streams from the second ends ofthe first and second atomizing portions, respectively, when pressurized gas is supplied to the nozzle assembly.
31. The method of claim 30 further comprising the steps of drawing first and second fluids into the first and second fluid inlet ports comprises the steps of: retaining first and second fluids in first and second flexible 5 polymeric bags, respectively; and extending first and second flexible tube through a closable fitting on the first and second flexible polymeric bags to fluidly couple the first and second fluid inlet ports with the first and second fluids. 10
32. The method of claim 30 further including the step of locating a releasable closure proximate a portion of a perimeter edge ofthe first and second flexible polymeric bags, the releasable closure having a release pressure less than the burst strength ofthe flexible
15 polymeric bags.
33. The method of claim 30 wherein the first and second atomizing portions are positioned to produce overlapping atomized streams.
20
34. The method of claim 30 wherein the passageways of the first and second atomizing portions define intersecting axes having an angle of intersection of about 14-19°.
25 35. The method of claim 30 wherein the passageway of the first atomizing portion between the middle portion and the second end comprises a generally frusto-conical shape with a base of the frusto-conical shape proximate the second end.
30 36. The method of claim 30 wherein the first and second fluids comprise a two-part water based adhesive.
PCT/US1996/010316 1995-07-21 1996-06-14 Spraying system for single or multiple fluids WO1997003758A2 (en)

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EP96919419A EP0837737A2 (en) 1995-07-21 1996-06-14 Spraying system for single or multiple fluids
JP9506670A JPH11509472A (en) 1995-07-21 1996-06-14 Sprayer for single or multiple liquids
AU61767/96A AU6176796A (en) 1995-07-21 1996-06-14 Spraying system for single or multiple fluids
BR9609547A BR9609547A (en) 1995-07-21 1996-06-14 Fluid spray system nozzle set for spray applicator container to store a fluid for use with a spray apparatus and process for applying a multi-component fluid system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/505,088 1995-07-21
US08/505,088 US5713519A (en) 1995-07-21 1995-07-21 Fluid spraying system

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WO1997003758A2 true WO1997003758A2 (en) 1997-02-06
WO1997003758A3 WO1997003758A3 (en) 1997-02-27

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EP (1) EP0837737A2 (en)
JP (1) JPH11509472A (en)
KR (1) KR19990035766A (en)
CN (1) CN1190911A (en)
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5826795A (en) * 1996-08-19 1998-10-27 Minnesota Mining And Manufacturing Company Spray assembly
US5954273A (en) * 1997-04-22 1999-09-21 Minnesota Mining And Manufacturing Company Spray assembly for high viscosity materials
WO2003061842A1 (en) * 2002-01-18 2003-07-31 Anest Iwata Corporation Spray gun with pressure display
WO2010077326A3 (en) * 2008-12-30 2010-09-23 Graco Minnesota Inc. Poppet check valve for air-assisted spray gun
EP2321062A2 (en) * 2008-09-09 2011-05-18 The Fountainhead Group, Inc. Sprayer
CN102773182A (en) * 2011-05-11 2012-11-14 锢德工业有限公司 Fluid ejection device
WO2019012500A1 (en) * 2017-07-14 2019-01-17 3M Innovative Properties Company Fluid delivery assembly for a spray gun
EP3862291A4 (en) * 2018-11-28 2022-07-20 Murata Manufacturing Co., Ltd. Atomizer
WO2022177434A1 (en) * 2021-02-19 2022-08-25 Dispensing Technologies B.V. Product dispensing system comprising a motor driven air pump, a dispensing device and a product container

Families Citing this family (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5759169A (en) * 1996-03-13 1998-06-02 New York Blood Center Inc. Fibrin sealant glue-gun
AU738112B2 (en) * 1997-07-25 2001-09-06 Scorpio Conveyor Products (Proprietary) Limited Conveyor scraper and mounting of scraper blade
US5979797A (en) * 1998-08-14 1999-11-09 Castellano; Michael A. Handheld pressurized hopper gun and method
US6283385B1 (en) * 1999-01-22 2001-09-04 Griffin Llc Method and apparatus for dispensing multiple-component flowable substances
USD429794S (en) * 1999-09-30 2000-08-22 Griffin Llc Sprayer collar
USD431068S (en) * 1999-09-30 2000-09-19 Griffin Llc Sprayer
USD435087S (en) * 1999-09-30 2000-12-12 Griffin Llc Valve seal
USD433482S (en) * 1999-09-30 2000-11-07 Griffin Llc Valve slider
USD432208S (en) * 1999-10-06 2000-10-17 Griffin Llc Sprayer system
GB0004028D0 (en) * 2000-02-22 2000-04-12 Mounteney Nicholas Universal airbrush
US6260772B1 (en) * 2000-06-14 2001-07-17 Ecolab Inc. Dispensing and rinsing gun
DE10031858B4 (en) * 2000-06-30 2008-07-03 Sata Gmbh & Co. Kg spray gun
FR2815553B1 (en) 2000-10-24 2003-09-05 Oreal SPRAYING DEVICE COMPRISING AT LEAST TWO PROPELLANT GAS OUTLET PORTS
DE60133980D1 (en) * 2000-10-24 2008-06-26 Oreal Spray device with at least two Trägergasauslässen
FR2830778B1 (en) 2001-10-11 2004-07-09 Oreal DEVICE FOR SPRAYING AT LEAST ONE PRODUCT ON A SUPPORT, IN PARTICULAR A KERATINIC SUPPORT SUCH AS THE SKIN
US6647584B2 (en) * 2000-11-14 2003-11-18 Eugene J. Pileggi Cleaning apparatus using vapormist spray
US6471194B2 (en) * 2000-12-14 2002-10-29 Bart Keeney Mist fan
FR2818101B1 (en) * 2000-12-15 2003-09-26 Oreal DEVICE FOR SPRAYING A COSMETIC PRODUCT
US20020170981A1 (en) * 2001-02-22 2002-11-21 Decker James D. Method and apparatus for cleaning a surface
FR2824762B1 (en) * 2001-05-15 2004-02-27 Oreal DEVICE FOR SPRAYING A PRODUCT, PARTICULARLY IN THE FORM OF A SAMPLE DOSE OF SAID PRODUCT
DE10135104C1 (en) * 2001-07-19 2002-09-12 Sata Farbspritztechnik Paint spray gun has a link between the piston drilling and a pressure measurement chamber in the pistol grip, to give a display of the compressed air pressure level
US7217442B2 (en) * 2001-12-20 2007-05-15 Ppg Industries, Ohio, Inc. Method and apparatus for mixing and applying a multi-component coating composition
US20070071903A1 (en) * 2001-12-20 2007-03-29 Claar James A Method for mixing and applying a multi-component coating composition
US20030157263A1 (en) * 2001-12-20 2003-08-21 Walters David N. Method and apparatus for mixing and applying a multi-component coating composition
GB0210448D0 (en) * 2002-05-08 2002-06-12 3M Innovative Properties Co Valve closure for spray gun reservoir
US7918369B2 (en) * 2002-09-25 2011-04-05 Illinois Tool Works Inc. Two-component spray gun with solvent flush/blend
US7410674B2 (en) * 2002-09-30 2008-08-12 General Electric Company Method of servicing an electro-dynamic apparatus
DE10349642A1 (en) * 2003-10-21 2005-05-19 Bielomatik Leuze Gmbh + Co Kg Device for aerosol generation and injector unit
US7144170B2 (en) * 2004-01-02 2006-12-05 Richard Parks Corrosion Technologies, Inc. Dual component dispensing and mixing systems for marine and military paints
US7665672B2 (en) * 2004-01-16 2010-02-23 Illinois Tool Works Inc. Antistatic paint cup
US7165732B2 (en) * 2004-01-16 2007-01-23 Illinois Tool Works Inc. Adapter assembly for a fluid supply assembly
US7086549B2 (en) * 2004-01-16 2006-08-08 Illinois Tool Works Inc. Fluid supply assembly
CA2556057C (en) * 2004-02-19 2012-10-16 Itw Limited Pressure monitoring device for a paint spray gun
GB2411234A (en) * 2004-02-19 2005-08-24 Itw Ltd Pressure monitoring device for a paint spray gun
US20050258271A1 (en) * 2004-05-18 2005-11-24 Kosmyna Michael J Disposable paint cup
US7766250B2 (en) 2004-06-01 2010-08-03 Illinois Tool Works Inc. Antistatic paint cup
US7757972B2 (en) * 2004-06-03 2010-07-20 Illinois Tool Works Inc. Conversion adapter for a fluid supply assembly
US7354074B2 (en) * 2004-06-03 2008-04-08 Illinois Tool Works Inc. Adapter assembly for a fluid supply assembly
US7353964B2 (en) * 2004-06-10 2008-04-08 Illinois Tool Works Inc. Fluid supply assembly
US20050286963A1 (en) * 2004-06-28 2005-12-29 Water Works I, Inc. Cleaning tool
PL1835997T3 (en) 2004-12-16 2012-12-31 Saint Gobain Abrasives Inc Liquid supply cup and liner assembly for spray guns
WO2006079981A2 (en) * 2005-01-31 2006-08-03 Illinois Tool Works Inc. Fluid supply assembly with measuring guide
US20070045445A1 (en) * 2005-08-26 2007-03-01 Joseph Hackel Multi-component fluid spraying system
US20070125886A1 (en) * 2005-12-01 2007-06-07 3M Innovative Properties Company Methods of spraying multi-component liquids
WO2007064532A1 (en) * 2005-12-01 2007-06-07 3M Innovative Properties Company Multi-component liquid spray systems
US20070181598A1 (en) * 2006-02-02 2007-08-09 Ppg Industries Ohio, Inc. Packaging system for a multi-component coating composition
US11040360B2 (en) 2006-06-20 2021-06-22 Saint-Gobain Abrasives, Inc. Liquid supply assembly
DK2564937T3 (en) 2006-06-20 2017-05-22 Saint Gobain Abrasives Inc The liquid supply unit
GB0811050D0 (en) * 2008-06-17 2008-07-23 U Pol Ltd A Connector for a gravity feed spray gun, a gravity feed spray gun and a method of preparing a spray paint
US8142855B2 (en) * 2008-09-12 2012-03-27 Ppg Industries Ohio, Inc Michael addition curing using phosphine catalyst
WO2010044864A1 (en) * 2008-10-17 2010-04-22 The Sherwin-Williams Company Paint applicator
US20110200835A1 (en) * 2008-10-31 2011-08-18 E.I. Du Pont De Nemours And Company Method for producing coating layer
US20110197811A1 (en) * 2008-10-31 2011-08-18 E.I. Du Pont De Nemours And Company Device for introducing catalyst into atomized coating composition
MX2011006739A (en) * 2008-12-23 2011-07-13 Du Pont Method for producing sprayable lacquer.
EP2445643A1 (en) * 2009-06-25 2012-05-02 E. I. du Pont de Nemours and Company Method for spraying multiple components
FR2949052B1 (en) * 2009-08-13 2015-03-27 Oreal PROCESS FOR COSMETIC TREATMENT OF SCALP.
EP2519361A4 (en) * 2009-12-29 2013-06-12 Kimco Pte Inc Resin distributor, reservoir bag to be used therewith, vehicle provided with such a system, kit for assembung the same, and methods of assembling and of operating associated thereto
US20160067735A1 (en) 2009-12-29 2016-03-10 Kimco Pte Inc. Resin distributor, reservoir bag to be used therewith, vehicle provided with such a system, kit for assembling the same, and methods of assembling and of operating associated thereto
KR100984055B1 (en) * 2010-02-12 2010-09-28 (주)에코인토트 A nozzle assembly for spraying mixed fluid
US9186688B2 (en) 2010-02-15 2015-11-17 Axalta Coating Systems Ip Co., Llc Method for spraying two-component compositions
MX2012009310A (en) 2010-02-15 2012-09-07 Du Pont Two-component spray device and use thereof.
US8840038B2 (en) 2010-04-22 2014-09-23 Ez-Pro Texture Inc. Texturing a wall or ceiling with non-acoustical joint compound
FR2960148B1 (en) 2010-05-20 2012-07-13 Oreal DEVICES FOR SPRAYING A FRAGRANCE COMPOSITION COMPRISING AT LEAST ONE VOLATILE LIQUID LINEAR ALKANE; PERFUMING PROCESSES
US20130330285A1 (en) * 2011-02-23 2013-12-12 Blakeley Smart Heated spray system for applying tanning solution
US8973522B2 (en) 2011-03-14 2015-03-10 Axalta Coating Systems Ip Co., Llc Dual feeding spray device and use thereof
EP2704847B1 (en) 2011-05-06 2019-11-27 Saint-Gobain Abrasives, Inc Paint cup assembly with an outlet valve
US20120292411A1 (en) * 2011-05-19 2012-11-22 Shiqi Zhu Pneumatic spray gun with finger adjustable spray control
MX371278B (en) 2011-06-30 2020-01-24 Saint Gobain Abrasifs Sa Paint cup assembly.
CN102935619A (en) * 2011-08-15 2013-02-20 鸿富锦精密工业(深圳)有限公司 Sand blasting device
CN108576164B (en) * 2011-09-12 2021-11-23 詹姆斯·B·沃尔夫 Improved processed food products
EP2797697B1 (en) 2011-12-30 2020-11-04 Saint-Gobain Abrasives, Inc. Convertible paint cup assembly with air inlet valve
TW201440894A (en) 2013-02-13 2014-11-01 Graco Minnesota Inc Two component mixing module
ITFI20140032U1 (en) * 2014-05-23 2015-11-23 Hpm Eng S R L A FLEXIBLE DUCT WITH QUICK CONNECTION FOR A SPRAY PAINTING DEVICE
US11148155B2 (en) * 2014-12-22 2021-10-19 San-Ching Chen Spray device
US20180117611A1 (en) * 2014-12-22 2018-05-03 San-Ching Chen Low-pressure and low-noise spray device
JP1535002S (en) 2015-03-17 2015-10-13
DE102015006483A1 (en) * 2015-05-22 2016-11-24 Sata Gmbh & Co. Kg Device for coating surfaces, in particular paint or lacquer surfaces
WO2017123723A1 (en) * 2016-01-15 2017-07-20 Briggs & Stratton Corporation Pressure washer spray gun with multiple chemical containers
US20170203314A1 (en) * 2016-01-19 2017-07-20 Robert J. Rose Two Component Airless Adhesive Spray Gun and Method of Use
CN106111380B (en) * 2016-08-09 2018-11-16 裕东(中山)机械工程有限公司 A kind of venturi powder pump intelligent air control method
CN106824592A (en) * 2017-03-14 2017-06-13 苏州井上高分子新材料有限公司 A kind of outer atomizing spraying system of double-component
US10442678B2 (en) 2017-09-15 2019-10-15 Graco Minnesota Inc. Dispensing meter and nozzle for fluid dispensing
BG2767U1 (en) * 2017-05-05 2017-09-26 "Агро Снайпер" Оод Portable hand-held agricultural sprayer
US20180334587A1 (en) 2017-05-19 2018-11-22 Ppg Industries Ohio, Inc. Dual-cure epoxy-siloxane coating compositions
US10240328B1 (en) * 2017-09-12 2019-03-26 Tracey Estelhomme Dual provision shower head
US11292710B2 (en) 2017-09-15 2022-04-05 Graco Minnesota Inc. Fluid management system and fluid dispenser
US12030770B2 (en) 2017-09-15 2024-07-09 Graco Minnesota Inc. Fluid management system and fluid dispenser
JP7178115B2 (en) 2020-07-13 2022-11-25 新耕産業株式会社 Sterilization and disinfection equipment

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2813751A (en) * 1955-04-18 1957-11-19 Sealzit Company Of America Plastic spraying apparatus
GB1345985A (en) * 1971-02-17 1974-02-06 Economics Lab Combination aspirator and srpay nozzle
US4397422A (en) * 1981-06-04 1983-08-09 Gwyn Marion V Full spectrum selective color producing and spraying device
US4903718A (en) * 1988-10-19 1990-02-27 Ipco Corporation Flexible ultrasonic cleaning bag
EP0371634A2 (en) * 1988-11-28 1990-06-06 Minnesota Mining And Manufacturing Company Spray gun with disposable liquid handling portion
US5031798A (en) * 1988-04-08 1991-07-16 Indag Gesellschaft Fur Industriebedarf Mbh Spraying device

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US868715A (en) * 1906-12-28 1907-10-22 Charles W Skinner Nozzle.
US2739843A (en) * 1951-11-16 1956-03-27 Binks Mfg Co Spray coating means
US2829006A (en) * 1954-06-10 1958-04-01 Binks Mfg Co Spray coating means
US3033472A (en) * 1957-11-18 1962-05-08 Flintkote Co Spraying of liquid plastic and an additive material
US3021079A (en) * 1959-01-09 1962-02-13 Gen Mills Inc Apparatus for applying flock
US2998934A (en) * 1959-12-18 1961-09-05 Arthur E Broughton Spraying apparatus
CH383839A (en) * 1960-08-12 1964-10-31 Willy Dr Ing Wiegand System for the delivery of two-component materials, in particular two-component paints
US3178118A (en) * 1962-12-05 1965-04-13 Fred M New Plural spray nozzle apparatus for producing metallized coating
US3258207A (en) * 1963-08-23 1966-06-28 Russell K Cody Solid particle spray apparatus
US3416709A (en) * 1966-04-11 1968-12-17 Spray Tak Inc Apparatus for applying a plurality of fluid materials
US3606154A (en) * 1968-12-23 1971-09-20 Mono Therm Insulation Systems Spray coating apparatus
US3799914A (en) * 1970-04-29 1974-03-26 Jenos Inc Standable flexible container with straw
US3716190A (en) * 1970-10-27 1973-02-13 Minnesota Mining & Mfg Atomizing method
CA1051063A (en) * 1976-05-27 1979-03-20 Mitsubishi Precision Co. Method of and apparatus for generating mixed and atomized fluids
US4138036A (en) * 1977-08-29 1979-02-06 Liqui-Box Corporation Helical coil tube-form insert for flexible bags
NL8203990A (en) * 1982-10-15 1984-05-01 Cornelis Elizabeth Rijlaarsdam APPARATUS FOR SYNCHRONOUS MIXING AND SPRAYING OF MULTIPLE DYES.
US4854504A (en) * 1983-11-04 1989-08-08 Graves Spray Supply Co., Inc. Fiberglass spray nozzle
US4781329A (en) * 1985-05-17 1988-11-01 London Fog, Inc. Combined power duster and ULV aerosol generator
US4824017A (en) * 1986-07-14 1989-04-25 Glas-Craft, Inc. External mix spraying system
US4718738A (en) * 1986-11-14 1988-01-12 Kapak Corp. Flexible bank for coins
US4928884A (en) * 1986-12-01 1990-05-29 Smith Gary L Fluid assist airless spray nozzle
BR8805445A (en) * 1987-10-23 1989-06-27 Abelardo Antonio Portas PROCESS TO FORM INSECTICIDES AND / OR FUNGICIDES AND APPLIANCE TO DO THE SAME
US4971251A (en) * 1988-11-28 1990-11-20 Minnesota Mining And Manufacturing Company Spray gun with disposable liquid handling portion
SU1717249A1 (en) * 1989-10-11 1992-03-07 В.Е.Р занов, В.С.Павлов и И.А.Павлов Ejector-type paint sprayer
US5147272A (en) * 1990-04-27 1992-09-15 Kapak Corporation Method of making a vented pouch
US5254073A (en) * 1990-04-27 1993-10-19 Kapak Corporation Method of making a vented pouch
US5059036A (en) * 1990-04-27 1991-10-22 Kapak Corporation Vented pouch arrangement and method
DE9005155U1 (en) * 1990-05-07 1990-07-12 Bersch & Fratscher GmbH, 8757 Karlstein Low pressure spray gun
JPH07103691B2 (en) * 1990-06-20 1995-11-08 東亞合成株式会社 Method for spraying quick-setting spray material
US5303865A (en) * 1990-07-26 1994-04-19 Binks Manufacturing Company Plural component external mix spray gun and method
US5135172A (en) * 1991-01-14 1992-08-04 Can-Am Engineered Products, Inc. High volume low pressure spray gun
DE4110127A1 (en) * 1991-03-27 1992-10-01 Herbert Huettlin NOZZLE ASSEMBLY FOR SPRAYING LIQUIDS
US5143294A (en) * 1991-04-08 1992-09-01 Lintvedt Arnold M Pliant container for storage of a liquid and liquid application therefrom
GB9207292D0 (en) * 1992-04-02 1992-05-13 Unilever Plc Fluid dispensers
US5346135A (en) * 1992-06-16 1994-09-13 Vincent Edward C Spraying apparatus for blending liquids in a gaseous spray system
US5255852A (en) * 1992-07-20 1993-10-26 The Testor Corporation Spray-type dispensing apparatus
US5398846A (en) * 1993-08-20 1995-03-21 S. C. Johnson & Son, Inc. Assembly for simultaneous dispensing of multiple fluids

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2813751A (en) * 1955-04-18 1957-11-19 Sealzit Company Of America Plastic spraying apparatus
GB1345985A (en) * 1971-02-17 1974-02-06 Economics Lab Combination aspirator and srpay nozzle
US4397422A (en) * 1981-06-04 1983-08-09 Gwyn Marion V Full spectrum selective color producing and spraying device
US5031798A (en) * 1988-04-08 1991-07-16 Indag Gesellschaft Fur Industriebedarf Mbh Spraying device
US4903718A (en) * 1988-10-19 1990-02-27 Ipco Corporation Flexible ultrasonic cleaning bag
EP0371634A2 (en) * 1988-11-28 1990-06-06 Minnesota Mining And Manufacturing Company Spray gun with disposable liquid handling portion

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5826795A (en) * 1996-08-19 1998-10-27 Minnesota Mining And Manufacturing Company Spray assembly
US5954273A (en) * 1997-04-22 1999-09-21 Minnesota Mining And Manufacturing Company Spray assembly for high viscosity materials
WO2003061842A1 (en) * 2002-01-18 2003-07-31 Anest Iwata Corporation Spray gun with pressure display
EP1477232A1 (en) * 2002-01-18 2004-11-17 Anest Iwata Corporation Spray gun with pressure display
EP1477232A4 (en) * 2002-01-18 2006-09-06 Anest Iwata Corp Spray gun with pressure display
US7422164B2 (en) 2002-01-18 2008-09-09 Anest Iwata Corporation Spray gun with pressure display
EP2321062A4 (en) * 2008-09-09 2014-10-29 Fountainhead Group Inc Sprayer
EP2321062A2 (en) * 2008-09-09 2011-05-18 The Fountainhead Group, Inc. Sprayer
WO2010077326A3 (en) * 2008-12-30 2010-09-23 Graco Minnesota Inc. Poppet check valve for air-assisted spray gun
CN102227269A (en) * 2008-12-30 2011-10-26 格瑞克明尼苏达有限公司 Poppet check valve for air-assisted spray gun
US7971806B2 (en) 2008-12-30 2011-07-05 Graco Minnesota Inc. Poppet check valve for air-assisted spray gun
TWI503179B (en) * 2008-12-30 2015-10-11 Graco Minnesota Inc Poppet check valve for air-assisted spray gun
AU2009333870B2 (en) * 2008-12-30 2015-02-26 Graco Minnesota Inc. Poppet check valve for air-assisted spray gun
CN102773182A (en) * 2011-05-11 2012-11-14 锢德工业有限公司 Fluid ejection device
CN102773182B (en) * 2011-05-11 2015-05-20 锢德工业有限公司 Fluid ejection device
WO2019012500A1 (en) * 2017-07-14 2019-01-17 3M Innovative Properties Company Fluid delivery assembly for a spray gun
WO2019012502A3 (en) * 2017-07-14 2019-02-28 3M Innovative Properties Company Fluid delivery assembly for a spray gun
CN110891693A (en) * 2017-07-14 2020-03-17 3M创新有限公司 Fluid delivery assembly for spray gun
CN110891694A (en) * 2017-07-14 2020-03-17 3M创新有限公司 Fluid delivery assembly for spray gun
CN110891693B (en) * 2017-07-14 2022-07-01 3M创新有限公司 Fluid delivery assembly for spray gun
EP4309801A3 (en) * 2017-07-14 2024-03-27 3M Innovative Properties Company Fluid delivery assembly for a spray gun
EP3862291A4 (en) * 2018-11-28 2022-07-20 Murata Manufacturing Co., Ltd. Atomizer
WO2022177434A1 (en) * 2021-02-19 2022-08-25 Dispensing Technologies B.V. Product dispensing system comprising a motor driven air pump, a dispensing device and a product container

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JPH11509472A (en) 1999-08-24
WO1997003758A3 (en) 1997-02-27
CN1190911A (en) 1998-08-19
CA2226753A1 (en) 1997-02-06
KR19990035766A (en) 1999-05-25
EP0837737A2 (en) 1998-04-29
US5713519A (en) 1998-02-03
BR9609547A (en) 1999-03-02
AU6176796A (en) 1997-02-18

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