WO1996011360A2 - Method and installation for thermal treatment of waste containing metallic compounds - Google Patents

Method and installation for thermal treatment of waste containing metallic compounds Download PDF

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Publication number
WO1996011360A2
WO1996011360A2 PCT/PL1995/000022 PL9500022W WO9611360A2 WO 1996011360 A2 WO1996011360 A2 WO 1996011360A2 PL 9500022 W PL9500022 W PL 9500022W WO 9611360 A2 WO9611360 A2 WO 9611360A2
Authority
WO
WIPO (PCT)
Prior art keywords
combustion chamber
combustion
gases
chamber
filter
Prior art date
Application number
PCT/PL1995/000022
Other languages
English (en)
French (fr)
Other versions
WO1996011360A3 (en
Inventor
Juliusz Czaja
Henryka Czaja
Miko$m(D)aj PODLISIECKI
Original Assignee
Juliusz Czaja
Henryka Czaja
Podlisiecki Mikodaj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Juliusz Czaja, Henryka Czaja, Podlisiecki Mikodaj filed Critical Juliusz Czaja
Priority to EP95932979A priority Critical patent/EP0803041A2/en
Publication of WO1996011360A2 publication Critical patent/WO1996011360A2/en
Publication of WO1996011360A3 publication Critical patent/WO1996011360A3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/025Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/006General arrangement of incineration plant, e.g. flow sheets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/26Biowaste
    • F23G2209/261Woodwaste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/00001Exhaust gas recirculation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Definitions

  • Fine-grained component and/or dry dust wastes and/or liquid wastes with low- temperature oven gas are burnt, producing combustion gases and molten slag, whereas coarse grained component is separated.
  • the solution according to P-263647 enables only to separate coarse grained assortment in a form of metallic alloy pieces. Non-utilised metallic compounds, however, remain is slag. This method does not allow the recovery of pure metals from toxic metallic compounds subject to utilisation.
  • Patent application P-293027/PCT/NL 91/00058 puts forward a method of combined processing of wastes where a waste of relatively high energetic value is subject to the process of pyrolysis in order to obtain gas and/or oil with coal residue.
  • pyrolysis residuum is mixed with waste of a relatively low energetic value so as to form a mixture with water
  • the mixture that has been obtained is shaped into pieces until it gets the form of ceramic products.
  • the method proposes to add sawdust to it. This method does not make it possible to recover metals whose compounds are contained in utilised wastes.
  • Oxygen is obtained from gas products of the process of the charge combustion owing to a cathode located in the area of free space inside the charge in the combustion chamber, and anodes inside each of the filter chambers with closed cycle of gases, and feeding the electrodes, from constant voltage source of safe value, during this process, and maintaining current density on a constant level, most desirably ranging from 2 to 10 A/m 2 .
  • combustion is enriched with hydrogen, educed on the cathode, bonding a part of oxygen in the chamber and catalysing a reduction reaction of metallic oxides into metals.
  • the installation for thermal utilisation of wastes that contain metallic compounds is characterised by a hermetic combustion chamber in oxidising-reducing conditions with cooling coil installed around the chamber, on its full height, and within the lid.
  • the bottom is provided with a grid under which the air inflow is situated.
  • the installation is equipped with the outlet of gases and steams tightly connected with the lower part of the first filter chamber where the cooling coil of gases and steams is embedded.
  • the dry filter is over the cooling coil.
  • the first filter chamber is closed on its top with a lid having a cooling coil installed. In the lid there is also the outlet of refined gases connected, through a scrubber, with a fan that is, from its other side, joined with the inlet of the second filter chamber.
  • the ash being the remains of the process, after separation of pure metals in a form of powder, can be used as a high-quality binding agent, ecologically clean, useful for producing building elements of high mechanical and insulating parameters.
  • the instances of the use of the installation presented on a draught - a scheme of the device - provide us with a more detailed description of the installation in the process of utilisation.
  • the installation for thermal utilisation of wastes containing metallic compounds is equipped with the combustion chamber 111, surrounded on its full height with a cooling coil /14/ that is also installed in the lid 161.
  • a cooling coil /14/ that is also installed in the lid 161.
  • the combustion chamber 111 is tightly closed with the lid 161 in which a steel cathode 191 is embedded.
  • the cathode 191 is inside it, placed in the free space 151 of the charge III.
  • the chamber 111 is connected, through a cable /15/, with the lower part of the first filter chamber 712/ where the cooling coil /16/ is embedded.
  • the second filter chamber /13/ on its top, is tightly closed with a lid /24/ that has the outlet to the other fan IS/ connected, through a cable /25/, both to the pressure regulation valve /26/ and to the air inlet of the combustion chamber 111, placed under the grid.
  • a lid /24/ that has the outlet to the other fan IS/ connected, through a cable /25/, both to the pressure regulation valve /26/ and to the air inlet of the combustion chamber 111, placed under the grid.
  • the lids /18,24/ of each of the filter chambers 111,13/ there are graphite anodes /10,11/ fed from the source of constant voltage 727/.
  • the outlet of the cooling coil /14/ is connected, through the cooling coil /28/, with the heat receiver /29/ from which water, through a pump /30/ and the cooling coil /19/ goes to the inlet of the cooling coil /16/ placed in the lower part of this chamber /12/.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture And Refinement Of Metals (AREA)
PCT/PL1995/000022 1994-10-06 1995-10-05 Method and installation for thermal treatment of waste containing metallic compounds WO1996011360A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP95932979A EP0803041A2 (en) 1994-10-06 1995-10-05 Method and installation for thermal treatment of waste containing metallic compounds

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PLP.305371 1994-10-06
PL94305371A PL174063B1 (pl) 1994-10-06 1994-10-06 Sposób termicznej utylizacji odpadów zawierających związki metali i urządzenie do termicznej utylizacji odpadów zawierających związki metali

Publications (2)

Publication Number Publication Date
WO1996011360A2 true WO1996011360A2 (en) 1996-04-18
WO1996011360A3 WO1996011360A3 (en) 1996-06-20

Family

ID=20063414

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL1995/000022 WO1996011360A2 (en) 1994-10-06 1995-10-05 Method and installation for thermal treatment of waste containing metallic compounds

Country Status (3)

Country Link
EP (1) EP0803041A2 (pl)
PL (1) PL174063B1 (pl)
WO (1) WO1996011360A2 (pl)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69020908T2 (de) * 1989-12-15 1996-02-15 Boehringer Mannheim Corp Redox-vermittlungs-reagenz und biosensor.

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH284748A (de) * 1949-10-20 1952-08-15 Kuntschick Hubert Füllofen für Abfallbrennstoffe.
DE1813759A1 (de) * 1968-10-17 1970-05-14 Ragnar Blomqwist Kleinverbrennungsofen mit nichtmechanischem Rost,insbesondere zur Muellvernichtung,und Verfahren zu seinem Betrieb
US4409020A (en) * 1983-01-24 1983-10-11 The United States Of America As Represented By The Secretary Of The Interior Recovery of metals from grinding sludges
US5050508A (en) * 1990-10-09 1991-09-24 Hcr System for the incineration of refuse and the treatment of the incineration exhaust gasses
DE4224777C1 (de) * 1992-07-27 1993-11-18 Hampel Heinrich Verfahren zur kontrollierbaren und umweltschonenden Verbrennung von leicht brennbaren Stoffen sowie zur Durchführung dieses Verfahrens geeignete Verbrennungsvorrichtung
US5335609A (en) * 1993-04-29 1994-08-09 University Of Chicago Thermal and chemical remediation of mixed waste

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH284748A (de) * 1949-10-20 1952-08-15 Kuntschick Hubert Füllofen für Abfallbrennstoffe.
DE1813759A1 (de) * 1968-10-17 1970-05-14 Ragnar Blomqwist Kleinverbrennungsofen mit nichtmechanischem Rost,insbesondere zur Muellvernichtung,und Verfahren zu seinem Betrieb
US4409020A (en) * 1983-01-24 1983-10-11 The United States Of America As Represented By The Secretary Of The Interior Recovery of metals from grinding sludges
US5050508A (en) * 1990-10-09 1991-09-24 Hcr System for the incineration of refuse and the treatment of the incineration exhaust gasses
DE4224777C1 (de) * 1992-07-27 1993-11-18 Hampel Heinrich Verfahren zur kontrollierbaren und umweltschonenden Verbrennung von leicht brennbaren Stoffen sowie zur Durchführung dieses Verfahrens geeignete Verbrennungsvorrichtung
US5335609A (en) * 1993-04-29 1994-08-09 University Of Chicago Thermal and chemical remediation of mixed waste

Also Published As

Publication number Publication date
EP0803041A2 (en) 1997-10-29
PL305371A1 (en) 1996-04-15
PL174063B1 (pl) 1998-06-30
WO1996011360A3 (en) 1996-06-20

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