WO1996010156A2 - Verfahren und vorrichtung zum kühlen von gasen - Google Patents
Verfahren und vorrichtung zum kühlen von gasen Download PDFInfo
- Publication number
- WO1996010156A2 WO1996010156A2 PCT/AT1995/000187 AT9500187W WO9610156A2 WO 1996010156 A2 WO1996010156 A2 WO 1996010156A2 AT 9500187 W AT9500187 W AT 9500187W WO 9610156 A2 WO9610156 A2 WO 9610156A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- refrigerant
- heat exchanger
- gas
- line
- pressure
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B47/00—Arrangements for preventing or removing deposits or corrosion, not provided for in another subclass
- F25B47/02—Defrosting cycles
- F25B47/022—Defrosting cycles hot gas defrosting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/265—Drying gases or vapours by refrigeration (condensation)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B13/00—Compression machines, plants or systems, with reversible cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/20—Disposition of valves, e.g. of on-off valves or flow control valves
Definitions
- the invention relates to a method and an apparatus for compressing gases, as described in the preamble of claims 1 and 2, and 23 and 24.
- a method and a device for compressing gases is already known - according to DE-Al-36 37071 - in which the gas drawn in by the compressor is previously cooled in a cooling section below 0 ° C. using a refrigeration dryer. The air sucked in by the compressor is sucked in alternately via one of two refrigeration dryers connected in parallel. While the suction gas is cooled with one, with the other the condensate produced in the form of ice when the suction gas cools is eliminated.
- the hot gaseous refrigerant is fed to the refrigerant dryer to be defrosted instead of a supercooled refrigerant, which flows through the heat exchanger arranged in this refrigerant dryer and thereby heats it, so that the ice adhering to the heat exchanger or the refrigerant dryer defrosts. If a temperature is found in the refrigerant flowing out of the heat exchanger that is in the range of greater than + 0 ° C., the supply of hot refrigerant to the heat exchanger is interrupted and the cold exchanger then flows through again with expanded cold refrigerant, which leads to a Pre-cooling of the heat exchanger comes.
- a desired minimum operating temperature of the heat exchanger for example -10 ° C.
- the air required by the compressor can already be sucked in again via the pre-cooled heat exchanger, whereupon the other heat exchanger is thawed.
- This alternating cooling and defrosting of the two heat exchangers means that the supercooled are continuously drawn in. Gas for the compressor is possible, and damage due to ice particles in the compressor, which can be entrained with the sucked-in air, can also be avoided by the pre-cooling.
- the cooled coolant emerging from the outlet of the heat exchanger when it is defrosted is fed via lines to a liquid gas tank immediately after the condenser connected downstream of the refrigerant compressor and mixed there with the refrigerant which has already been cooled beforehand.
- the object of the present invention is to improve the overall efficiency of a method and a device for producing a dried compressed air.
- the exact regulation of the intake temperature of the gas drawn in by the compressor can be controlled via the expansion valve arranged upstream of the heat exchanger used for subcooling the gas, which surprisingly changes the pressure and temperature in the heat exchanger during the cooling process ⁇ conditions in the refrigerant can be compensated with the already existing control.
- This object of the invention can also be achieved independently of this by the measures specified in the characterizing part of patent claim 2.
- the advantage of this solution is that a so-called overheating of the refrigerant vapor is achieved, i.e. that the difference between the temperature at which the refrigerant condenses and changes from the gaseous to the liquid phase is exceeded by a few degrees, so that even in the event of an unforeseen cooling in the course of the line system in the area of the suction line, no change in state, in particular no sudden change State change, can be done to avoid that liquid refrigerant can be sucked into the suction line of the refrigerant compressor. This results in a significantly higher level of operational safety in such processes and prevents damage to the systems.
- a procedure according to claim 4 ensures that this degree of overheating of the refrigerant can be maintained even during operation.
- a process sequence according to claim 5 is also advantageous, since a better energy balance in the intake air subcooling and thus a greater energy saving can be achieved, since the heat removal required for condensing from the refrigerant can be used to defrost the heat exchanger or the heat exchangers that are not in operation .
- a procedure according to claim 7 is also advantageous, since as a result the liquefied amount of refrigerant coming from the heat exchanger (s) to be defrosted is equal to or less than the amount of refrigerant regulated by the expansion valve and cooled via the condenser, and thus via the regulation of the Expansion valve, in spite of the fact that the quantity of refrigerant supplied by the defrosted heat exchangers is used in an uncontrolled manner, it is possible to clearly control and regulate the temperature to be cooled.
- a problem-free admixture of the refrigerant supplied by the defrosted heat exchanger can be achieved by the measures according to claim 8.
- a more refined control of the heat transfer in the heat exchanger can be achieved by the procedure according to claim 9.
- the measures according to claim 11 also provide a surprising additional advantage, since as a result the degree of icing on the heat exchanger arranged in the cold zone is reduced and the changeover between the parallel suction paths has to be carried out less frequently, which means that the defrosting requires less energy and is more economical is achievable.
- the surfaces of the heat exchangers are wet due to the precipitation of the condensate separated from the gas, and through these wet surfaces these heat exchangers can be used as particle filters, in particular dirt filters, whereby these Contamination with the drainage of the condensate can already be drained from the heat exchanger during continuous operation.
- a procedure according to claim 13 is also advantageous, since it makes it easier to remove particles entrained in the sucked-in gas, in particular dust and dirt.
- a higher efficiency in cooling and by optimized line length of the refrigerant lines in the heat exchanger can be achieved by the measures according to claim 14.
- the object of the invention can also be achieved by the independent solution according to the Part of claim 25 can be solved, whereby the device can be used to ensure that the refrigerant flowing out of the heat exchanger, via which the gas or air has been cooled, is heated above the pressure dew point and thus condenses the refrigerant flowing back to the refrigerant compressor is reliably prevented.
- the object of the invention can also be achieved independently of this by the measures of claim 26 specified in the characterizing part.
- the advantage of this solution is that a simple return of the refrigerant condensed in the heat exchanger to be cooled is possible in the circuit provided for cooling the heat exchanger running in parallel, and thus an increase in efficiency or considerable energy savings in the compression of gases can be achieved
- the refinement according to claim 27 makes it possible in a simple manner to ensure overheating of the refrigerant emerging from the heat exchanger used to cool the sucked-in gas.
- An almost real-time control of the operation of the device can be achieved by the features according to claim 28.
- a high level of operational safety can be achieved through the training according to claim 29.
- an embodiment according to claim 30 is also advantageous, as a result of which the ice covering can be quickly defrosted from the heat exchanger.
- the embodiment variant according to claim 31 is also advantageous, since it enables a gradual cooling of the sucked-in gas and thus a targeted and rapid removal of the condensate contained in the sucked-in gas.
- a sensitive regulation of the temperature of the sucked-in gas and, associated with this, also a good efficiency of the entire device can be achieved by the design according to claim 33.
- the invention is described in more detail below with reference to the embodiment variants shown in the exemplary embodiments.
- FIG. 1 shows a block diagram of a device according to the invention for compressing gases in a simplified, diagrammatic representation
- FIG. 2 shows a block diagram of the device according to the invention for compressing gases with two refrigeration dryers arranged parallel to one another and a hot gas defrosting;
- FIG. 3 shows a block diagram of the device according to the invention for compressing gases with two refrigeration dryers arranged parallel to one another and a hot gas defrosting;
- FIG. 5 shows a block diagram of another embodiment variant of the device according to the invention in a simplified, diagrammatic representation
- FIG. 6 shows a block diagram of a further embodiment of the device according to the invention, only one of several cold dryers being shown, which comprises a plurality of heat exchangers arranged one behind the other in the flow direction, in a simplified, diagrammatic representation;
- FIG. 7 shows a block diagram of a further embodiment of the device according to the invention.
- FIG. 8 shows a block diagram of a further embodiment of the device according to the invention.
- Fig. 9 is a block diagram of another embodiment variant of the invention.
- FIG. 10 is a block diagram of a system in which several devices according to the invention gen are interconnected for the compression of gases, in a simplified, schematic representation;
- FIG. 11 shows a block diagram of a system according to the invention, in which a plurality of refrigeration dryers are connected together on the pressure side of a compressor, in a simplified, schematic representation;
- FIG. 12 shows a block diagram of another embodiment of the device according to the invention in a simplified, diagrammatic representation.
- This device 1 shows a device 1 for compressing a gas 2, which is indicated schematically by arrows 3.
- This device 1 comprises a compressor 4, whereby screw compressors as well as piston compressors or radial compressors with or without oil injection can be used for this purpose, and two refrigeration dryers 5, 6 arranged upstream of them.
- the two refrigeration dryers 5, 6 are connected to one another via suction lines 7, 8 intake-side intake 9 of the compressor 4 connected.
- Airtight flaps 12, 13 are arranged between an outlet 10, 11 of the refrigeration dryers 5, 6 and the suction lines 7, 8. Cylinder-piston arrangements or electromagnetic arrangements, from the closed position shown in the closure flap 12 can be adjusted into the open position shown in the closure flap 13.
- At least one heat exchanger 15, 16 is arranged in each cold dryer 5, 6.
- Each heat exchanger 15, 16 is connected to a connecting line 17, 18 or a suction line 19, 20 of a refrigerant circuit.
- the gaseous refrigerant coming from the heat exchanger 15, 16 in the suction lines 19, 20 is sucked in by a refrigerant compressor 23 in particular via a solenoid valve 21, a suction line 22.
- a control device 24 is provided for controlling or regulating the device 1 of which the individual solenoid valves 21 or drives 14 are connected.
- the refrigerant is further supplied by the refrigerant compressor 23 or a downstream condenser via pressure lines 25, 26, adjustable or controllable expansion valves 27, 28, which e.g. can also be used as a check valve, conveyed into the connecting lines 17, 18, that is, to the input of the heat exchanger 15, 16. Furthermore, it is also possible that when using expansion valves 27, 28 which cannot be shut off, a magnetic valve is arranged upstream or downstream of them in order to interrupt the refrigerant circuit.
- connecting line 17 or 18 is connected via a bypass line 29, 30 with intermediate Circuit of a solenoid valve 31, 32 for the hot gas connected to the line between the refrigerant compressor 23 and the condenser.
- refrigeration dryers 5, 6 have further closure flaps 33, which in the closed state are gas-tight at least with respect to the entry of gases 2 from the direction of an intake connector 34.
- the cold dryers 5, 6 are connected to one another via a connecting line 35.
- This connecting line 35 connects the openings of the refrigeration dryers 5, 6 opposite the closure flaps 12, 13.
- the connecting line 35 and the refrigeration dryers 5, 6 have a drain 36 which is on the suction side of the refrigeration dryers 5, 6 and for removing the condensate is arranged.
- a connecting flap 37 is arranged on this connecting line 35, which is preferably, but not necessarily, gas-tight in the closed state, at least with respect to the entry of gases 2 from the direction of the intake port 34.
- the suction lines 19, 20 are each connected to a return line 38 and 39 at the outlet of the heat exchanger 15, 16 in front of the solenoid valves 21, the return line 38, which is connected to the suction line 19, acting against reverse flows from the connecting line 18
- Check valve 40 is interposed so that the return line 38 can be connected to the connecting line 18, whereas the suction line 20 is connected to the connecting line 17 via the return line 39 and a check valve 41 effective against the inflow of refrigerant gas from the connecting line 17.
- the gas 2 to be compressed is sucked in the device 1 shown with the flap 33 of the refrigeration dryer 5 open through the compressor 4 via the intake port 34 into the refrigeration dryer 5.
- the sucked-in gas 2 then passes through the heat exchanger 15, which is thawed at this time, ie is freed from the condensate that has accumulated as ice.
- the warm air sweeps past the ice or heat exchanger 15 fogged with ice by cold condensation, the gas 2 which has been sucked in is already cooled and excretes part of the moisture contained in the gas 2 in the form of water vapor.
- the gas 2 flows through the heat exchanger 16 cooled to the desired temperature and is thereby cooled to the desired predetermined temperature, whereupon the gas 2 still contained in the sucked-in gas in the form of water vapor Liquid is excreted.
- the liquid which has separated out is deposited as hoarfrost or ice due to the temperatures of the heat exchanger 16 below 0 ° C. on the heat exchanger 16 or on the walls of the refrigeration dryer 6.
- the gas cooled below 0 ° C. preferably to temperatures between -10 ° C. and -50 ° C., enters the opened closure flap 13, which is gastight in both directions, to the suction-side suction port 9 of the compressor 4.
- the heat exchanger 16 is cooled using a refrigerant.
- This refrigerant is compressed in the refrigerant compressor 23 and then cooled in a condenser (not described in more detail) so that it changes to the liquid state and is then fed via the pressure line 26 to an expansion valve 28.
- the refrigerant expands, the refrigerant extracts heat from the environment and cools the heat exchanger 16, depending on the amount of refrigerant supplied, the control being carried out via the expansion valves 27 and 28 by means of the control device 24.
- the control of the individual solenoid valves 21 of the expansion valves 27, 28, of the shutters 12, 13, 33, 37 takes place via control lines 42 to 47.
- this is also connected to the condenser downstream of the refrigerant compressor 23 via the pressure line 25, in which the liquefied refrigerant is fed to the expansion valve 27, in which the pressure drop for gasifying the refrigerant takes place, and via a connecting line 17 is connected to the heat exchanger 15.
- the refrigerant is returned to the refrigerant compressor 23 via the suction line 19 and 22.
- the gas 2 to be compressed for example air
- the gas 2 to be compressed for example air
- the gas 2 then flows through or flows around the heat exchanger 16 and enters the intake line 8 through the closure flap 13, which leads the now dehumidified and supercooled gas 2 to the intake port 9 of the compressor 4
- the airtight flap 12 is closed in both directions of flow, as is the flap 33 associated with the refrigeration dryer 6 and the air flap 37 arranged in the connecting line 35.
- the heat exchanger 16 of the refrigeration dryer 6 is iced up, ie water droplets are separated from the sucked-in gas 2, so that only dry gas 2 is sucked in by the compressor 4.
- Another advantage of this subcooling of the sucked-in gas 2 is that the operating temperature of the compressors 4 is extremely low, so that even with the compressors 4 with oil injection, there is no gasification or evaporation of the oil and thus is avoided the evaporated oil mixes with the gas 2 since there is no longer any moisture in the gas 2.
- oil and water mixtures do not occur and the otherwise very difficult to dispose of oil-water emulsions are prevented.
- the closure flap 37 in the connecting line 35 is initially opened, so that the gas 2 required by the compressor 4 is now sucked in via the intake port 34 assigned to this closure flap 37.
- the control device 24 cools the heat exchanger 15 to the desired operating range by supplying liquid refrigerant via the pressure line 25, the expansion valve 27 of the connecting line 17 to the heat exchanger 15.
- closure flap 33 of the refrigeration dryer 5 is closed. If sufficient cooling of the heat exchanger 15 is achieved, the closure flap 13 is closed and the closure flap 12 is opened. Thereupon the gas 2 to be compressed is now passed via the intake port 34 past the closure flap 37 to the refrigeration dryer 6 and through this the gas 2 is cooled and dried and then fed to the intake port 9 of the compressor 4 via the opened closure flap 12
- the closing flap 33 of the refrigeration dryer 6 opened and the closure flap 37 in the connecting line 35 closed simultaneously or immediately after the closure flap 33 was opened.
- control device 24 controls the solenoid valve 32 for hot gas via the control line 47, whereby the refrigerant compressor 23, bypassing the condenser, transfers the gaseous refrigerant at a high temperature the bypass line 30 can flow through the heat exchanger 16.
- the hot refrigerant now flows through the iced-over heat exchanger 16, as a result of which the heat exchanger 16 heats up and the condensate frozen on it thaws.
- the refrigerant cooled by the icy heat exchanger 16 flows through the return line 39 and the check valve 41 to the connecting line 17.
- the refrigerant cooled and liquefied by the heat exchanger 16 flows into the connecting line 17 due to the resulting pressure drop in the gaseous form transferred state and thereby supports the cooling of the heat exchanger 15 in the refrigeration dryer 5.
- the exact temperature of the heat exchanger 15 is maintained by means of the control of the expansion valve 27, so that depending on the defrost condition of the heat exchanger 16 and the resulting changing temperatures of the inflowing liquefied refrigerant Much as much liquefied refrigerant can pass through the expansion valve 27 that the desired cooling of the heat exchanger 16 is achieved.
- the control device 24 opens the closure flap 37 and at the same time closes the closure flap 33 of the refrigeration dryer 6, as a result of which the gas 2 is now sucked in via the closure flap 37.
- the control valve 24 closes the solenoid valve 32 and the expansion valve 28 is activated by the control device 24. Thereby, the refrigeration dryer 6 is cooled to a certain temperature in order to ensure rapid cooling of the gas 2 when switching from the refrigeration dryer 5 to the refrigeration dryer 6.
- the flaps 12, 13, 33, 37 can be switched over again by flap 12 is closed and the flap 13 is opened and thus the gas 2 sucked in via the flap 37 in the connecting line 35 is now dried and cooled again via the refrigeration dryer 6 and is fed via the flap 13 to the suction port 9 of the compressor 4 .
- the appropriate switching of the closure flap 33 of the refrigeration dryer 5 can then take place, after which the defrosting of the heat exchanger 15 now iced up by the operation is carried out accordingly, as described for the heat exchanger 16.
- the switchover between cooling the intake gas 2 and defrosting the heat exchanger 15 or 16 is carried out after a certain programmable time period or after detection of a corresponding icing.
- the device 1 according to the invention for compressing a gas 2 is shown on the basis of a detailed schematic circuit diagram of the control device 24.
- Refrigeration dryers 5, 6 or their heat exchangers 15, 16 are in turn connected via the connecting lines 17, 18 to the expansion valves 27, 28 with the interposition of solenoid valves 48, 49 with the pressure line 25, 26.
- Each of the expansion valves 27, 28 also has a pressure sensor 50, 51 with which the pressure of the gaseous refrigerant can be determined directly or indirectly by the connection via pressure lines 52, 53 to the suction line 19, 20. It is therefore also possible to monitor the temperature of the refrigerant via the pressure and, accordingly, can regulate the amount of refrigerant to be supplied to the heat exchangers 15, 16 on the basis of the changing pressure values in the suction line 19, 20 via the expansion valves 27, 28 become.
- the suction lines 19, 20 are connected to the suction line 22 via the solenoid valves 21.
- a temperature sensor 54, 55 is arranged between the solenoid valve 21 and each heat exchanger 15, 16.
- a pressure measuring device it is also possible for a pressure measuring device to be used instead of the temperature sensor 54, 55, the temperature of the refrigerant being determinable via the pressure of the refrigerant.
- the pressure sensors 50, 51 connected to the pressure lines 52, 53 are between the solenoid valves 21 and the temperature sensors 54, 55 connected to the suction line 19, 20.
- the outlet of the solenoid valves 21 is connected to the suction line 22, which opens into a heat exchanger 56.
- the heat exchanger 56 is connected via a suction line 57 to an inlet of the refrigerant compressor 23.
- the refrigerant compressor 23 is driven by a motor 58.
- a condenser 59 At the outlet of the refrigerant compressor 23 is a condenser 59, in which the hot compressed gaseous refrigerant is cooled via a cooling water circuit 60, preferably in the counterflow principle, until it condenses, connected via a line 61.
- the condenser 59 which is operated in countercurrent, is usually designed such that it can hold a corresponding amount of refrigerant and at the same time fulfills the function of a tank.
- a condenser 59 is used, for example, in which the refrigerant is cooled by air, a tank must also be arranged in the refrigerant circuit in order to keep a corresponding reserve of refrigerant in stock.
- the condenser 59 is connected via a line 62 to an input 63 of the heat exchanger 56 with the interposition of a liquid converter 64.
- This liquid converter 64 serves to separate any moisture contained in the refrigerant, ie water vapor or water droplets, and to prevent an inadmissible increase in moisture or water in the refrigerant.
- the heat exchanger 56 in which the hot refrigerant coming from the liquid converter 64 flows, serves to dry the gaseous refrigerant flowing through on the suction side, i.e.
- An outlet 65 of the heat exchanger 56 is via a pressure line 66, which is divided into the pressure lines 25, 26 for the heat exchangers 15, 16 and possibly with the interposition of a sight glass 67 with the expansion valves 27, 28 via the solenoid valves 48, 49 connected, whereby the circuit for a refrigerant 68 is closed.
- a hot gas regulator 69 is connected to the line 61 via a line 70.
- the hot gas regulator 69 in turn comprises a pressure sensor 71, which is connected to the outlet of the hot gas regulator 69 via a pressure line 72.
- the outlet of the hot gas regulator 69 is connected to a bypass line 73, which in turn is divided into the bypass lines 29 and 30 for each heat exchanger 15, 16.
- the solenoid valves 31, 32 are provided with a drive 74, 75 for remote actuation via the control device 24.
- the temperature sensors 54, 55 are connected to the expansion valves 27, 28 via control lines 76, 77. Of course, it is also possible to transfer the measurement results of the temperature sensors 54, 55 and the pressure sensors 50, 51 and 71 via control lines 78 to the control device 24, as shown by dash-dotted lines, which the expansion valves 27, 28 via the control line 43, 46 can control.
- the control device 24 is connected via feed lines 79, 80 to a power source 81, which is preferably formed from a network of an electrical supply company.
- the magnetic valves 31, 32 can also be connected to the control device 24 via the control lines 42, 47.
- the solenoid valves 21, the solenoid valves 48, 49 and the solenoid valves 31, 32 are provided with a drive 82.
- the drive 82 is connected via control lines 42, 44, 45, 47, 83, 84 to the control device 24, which can be formed by electromagnets or electric actuators, for example stepping motors or the like.
- the expansion valves 27, 28 are connected to the control device 24 via the control lines 43, 46, as a result of which the amount of the refrigerant 68 to be expanded can be regulated or monitored.
- the output of the heat exchanger 15 is connected via the return line 38 with the interposition of the check valve 40 to the input of the heat exchanger 16 or the connecting line 18.
- the output of the heat exchanger 16 is connected to the input of the heat exchanger 15 via the return line 39 with the interposition of the check valve 41.
- the gas 2 to be compressed is sucked in by the compressor 4 via the heat exchanger 16 of the refrigeration dryer 6, the opened closure flap 13, the suction line 8 and the suction nozzle 9 and compressed in the compressor 4 to the desired extent
- the heat exchanger 16 is arranged in a refrigerant circuit in order to enable the sucked-in gas 2 to cool down and the liquid contained in the sucked-in gas 2 to be separated and separated.
- the gaseous refrigerant 68 which is highly compressed by the refrigerant compressor 23, is passed through the condenser 59 and thereby brought into the liquid state by cooling and then fed to the liquid converter 64. From there, the refrigerant 68 passes through the
- Heat exchanger 56, the pressure line 66 and the pressure line 26 to the solenoid valve 49 Is the solenoid valve 49 by the control via the control line 84 from the control device 24 opened, the liquid refrigerant 68 can continue to flow to the expansion valve 28. Due to the pressure drop in the connecting line 18 downstream of the expansion valve 28, the liquid refrigerant 68 now expands and changes into a gaseous state. As with the expansion of the refrigerant 68, energy is consumed to achieve the transition from the liquid to the gaseous state. The energy required is taken from the liquid refrigerant 68 and the heat exchanger 16. Cooling occurs due to the evaporation cold.
- the design can now be such that the refrigerant 68 in the line 61 has a temperature between + 70 ° C. and
- the condenser 59 for example, so much energy is removed from the refrigerant 68 via the cooling water circuit 60 or by means of an appropriate air cooling, whereby it is cooled down to such an extent that it has a temperature between + 25 ° C. and + 60 ° C. under the prevailing pressure conditions , preferably + 35 ° C., the pressure for a refrigerant, in particular of the type R22, being absolutely 13.5 bar.
- the refrigerant 68 is liquefied and is cooled in the downstream heat exchanger 56 by countercurrent cooling with the cold, sucked-in gaseous refrigerant 68 withdraws further thermal energy, so that it flows into the expansion valve 28 at a temperature between + 15 ° C. and + 25 ° C., preferably + 20 ° C.
- the liquefied refrigerant 68 now changes to the gaseous state, the amount of refrigerant 68 supplied via the expansion valve 28 being controlled such that the pressure of the refrigerant 68 monitored via the pressure line 53 in the suction line 20 is, for example, egg ⁇ corresponds to a nominal pressure of 4.8 bar and at the same time the temperature monitored by the temperature sensor 55 is higher than the nominal temperature of 5 ° C corresponding to the nominal pressure of 4.8 bar.
- a larger or smaller amount of heat can be removed from the heat exchanger 16 and thus a predeterminable temperature of the sucked-in gas 2 can be achieved in the area of the intake port 9, for which purpose in the area the intake line 8 or the intake port 9, a temperature measurement of the gas 2 can be taken.
- the amount of refrigerant 68 supplied by the expansion valve 28 can be in one direct control loop takes place via the pressure prevailing in the pressure line 53 by means of the pressure sensor 51, which can change the opening width of the expansion valve 28, wherein these control values or the function of the expansion valve 28 can also be influenced by the control device 24.
- Such an additional influencing of the expansion valve 28 by the control device 24 is necessary above all when an exact temperature of the sucked-in gas 2 in the area of the intake port 9 of the compressor 4 is required for the gas 2.
- the regulation in the control loop is used of the pressure line 53 and the pressure sensor 51 on the basis of the predefined pressure ratios and the temperature conditions in the suction line 20, the temperature of the suctioned gas 2 at the suction nozzle 9 can be dependent on the temperature of the gas 2 in the area of the suction nozzle 34 vary. If it is colder, for example, in winter when air is sucked in by the refrigeration dryer 5, 6, a colder and correspondingly denser air will be present at the intake port 9 of the compressor 4 with the same cooling capacity.
- the temperature sensor 54 detects the actual temperature and the pressure sensor the actual pressure.
- the setpoint temperature and the setpoint pressure are set on the expansion valve 28.
- the refrigerant 68 supplied via the expansion valve 28 is now controlled so that the actual temperature and the actual pressure of the setpoint Temperature and the target pressure correspond.
- the temperature sensors 54, 55 and the pressure sensors 50, 51 may be connected to the control device 24.
- the temperature sensors 54, 55 in turn determine the actual temperature and pressure sensors 50, 51 the actual pressure and transmit them to the control device 24.
- the actual temperature and / or the actual pressure is then compared in the control device 24 with the desired temperature and / or the desired pressure, which can be set via an input device, the control device 24 subsequently depending on the expansion valves 27, 28 controls the difference between the setpoint and actual temperature and / or pressure, and thus the amount of the liquid refrigerant 68 to be expanded can be regulated.
- the refrigerant 68 After the refrigerant 68 has been brought into a gaseous state, it flows through the heat exchanger 16, as a result of which the sucked-in gas 2 is cooled to the corresponding temperature.
- the gaseous refrigerant 68 then flows via the suction line 20 and the magnetic valve 21 to the suction line 22 and from there into the heat exchanger 56 the gaseous refrigerant 68 is sucked in by the refrigerant compressor 23 via the suction line 57.
- the gaseous refrigerant 68 By compressing the gaseous refrigerant 68 from the refrigerant compressor 23, the gaseous refrigerant 68 is compressed to high pressure and then liquefied in the condenser 59 by cooling, which completes the refrigerant cycle.
- the gas 2 required for the compressor 4 is cooled in the refrigeration dryer 5 and the compressor 4 is fed in a cooled form, as shown in FIG. 1.
- the ice jacket on the heat exchanger 16 results from the fact that the moisture contained in the gas 2 is excreted by the supercooling of the sucked-in gas 2 and solidified by the sub-zero temperatures in the area of the heat exchanger 16. Since such an ice jacket has a high insulating effect, it occurs after a certain operating time that the heat absorption of the refrigerant 68 in the heat exchanger 15 or 16 is no longer sufficient to ensure the desired subcooling of the sucked-in gas 2.
- This is monitored, for example, in the heat exchanger 16 in operation in such a way that the temperature or the pressure of the refrigerant 68 is monitored after leaving the heat exchanger 16 by means of the temperature sensor 55 and pressure sensor 51 in the area of the suction line 20.
- the control device 24 taking into account any further parameters, such as the ambient temperature.
- the control for initiating the defrosting process can take place over a presettable period of time.
- the gas 2 required for the compressor 4 is cooled in the refrigeration dryer 5 and fed to the compressor 4 in a cooled form, as described in FIG. 1.
- the gas-tight closure flap 13 assigned to the heat exchanger 16 to be defrosted is then closed by the control device 24 and the expansion valve 28 is acted upon by the control device 24 such that the supply of liquid refrigerant 68 is interrupted.
- the drive device 74 of the solenoid valve 32 is then acted upon by the control device 24, whereby the bypass line 30 is connected to the connecting line 18 and the hot gas emitted by the hot gas regulator 69 is fed into the connecting line 18 to the heat exchanger 16 via the bypass line 73.
- the interior of the heat exchanger 16 is heated.
- the ice that has deposited on the walls of the heat exchanger 16 or on the walls of the refrigeration dryer 6 is thawed and flows through the drain 36, as shown in FIG. 1 , from.
- the hot gaseous refrigerant 68 for example supplied with a temperature between + 70 ° C and + 105 ° C via the bypass line 30 and the solenoid valve 32
- the solenoid valve 21 of the suction line 20 is also closed, the suction line 20 being connected via the return line 39 with the interposition of the check valve 41 to the connecting line 17 and the heat exchanger 15, with which the sucked-in gas 2 is now cooled. supplied with cooled refrigerant 68 of the heat exchanger 16
- the hot, gaseous refrigerant 68 supplied via the bypass line 30, the amount of which is regulated via the hot gas regulator 69, is only a small part, for example 10 to 20% of the total refrigerant 68 expanded by the expansion valve 27.
- the hot, gaseous refrigerant 68 becomes due to the cold in the refrigeration dryer 6 to be defrosted liquefied by cooling and passes from the outlet of the heat exchanger 16, that is to say the suction line 20, via the return line 39 and the check valve 41 to the connecting line 17 of the heat exchanger 15.
- the connecting line 17 is provided with a gaseous, cold refrigerant 68 for the Flows through heat exchanger 15 of the refrigeration dryer 5. Due to the pressure difference between the connecting line 17 and the return line 39, this is from the heat exchanger
- control device 24 After reaching a preset internal temperature of the refrigeration dryer 6 to be defrosted, the control device 24 opens the closure flap 37 and closes the closure flap 33 of the refrigeration dryer 6, so that the air saturated with water during defrosting at a certain temperature cannot be sucked in by the refrigerant compressor 23.
- the refrigerant compressor 23 is assigned a bypass line 85 which extends between the suction line 57 and the line 61.
- a pressure and vacuum control valve 86 is provided in order to avoid damage to the refrigerant compressor 23. Due to the small amount of hot, gaseous refrigerant 68 that is required for defrosting the heat exchangers 15 and 16, a flow cross section of the return lines 38 and 39 is also considerably smaller than the cross section of the connecting lines 17 and 18 By the inflow of the liquid refrigerant 68 into the connecting line
- Cooling of the sucked-in gas 2 of the heat exchanger 15 or 16 is ensured by the fact that the changing conditions, in particular the temperature of the liquid refrigerant 68, which is supplied through the return line 38 or 39, are adjusted and regulated by the expansion valve 27 or 28 is compensated for alternating operation.
- the refrigeration dryer 6 Before the refrigeration dryer 6 is put back into operation, i.e. that the defrost phase is complete, the refrigeration dryer 6 is pre-cooled.
- the solenoid valve 49 is opened by the control device 24.
- the liquid refrigerant 68 thus passes from the refrigerant compressor 23 to the expansion valve 28, by means of which the control device 24 determines the temperature to which the interior of the refrigeration dryer 6 is to be cooled.
- the control device 24 determines the temperature to which the interior of the refrigeration dryer 6 is to be cooled.
- the closure flap 33 of the Cold dryer 6 and the shutter 37 are closed.
- the device 1 shown in FIGS. 1 to 3 can also be designed without the use of the three flaps 33 and 37, in which case the gas 2 to be compressed by the compressor 4 is then sucked into each refrigeration dryer 5 and 6 independently.
- the refrigeration dryers 5 and 6 are operated in different ways, ie the refrigeration dryer 5 is switched from the cooling mode to the defrosting mode and the refrigeration dryer 6 is switched from the defrosting mode to the cooling mode, as the characteristic curve 87 shows.
- the defrost cycle for the heat exchanger 16 is ended at the point in time 89 and the refrigeration dryer 6 is precooled by the control device 24, as described with reference to FIGS. 2 and 3.
- the interior of the refrigeration dryer 6 has cooled to the temperature preset with the control device 24 and it can be switched from the refrigeration dryer 5 to the refrigeration dryer 6.
- the heat exchanger 15 is flowed through by the refrigeration dryer 5 with hot, gaseous refrigerant 68, whereby the temperature in the interior of the refrigeration dryer 5 begins to rise at the same time as Initiation of the defrost cycle for the refrigeration dryer 5, the cooling cycle for the refrigeration dryer 6 is started. This can be seen again at the time 90. Furthermore, it is possible to carry out the pre-cooling phase to the corresponding temperature of the refrigeration dryer 5 in order to ensure a rapid, low-loss switchover from the refrigeration dryer 5 to the refrigeration dryer 6. At time 91, the cold dryer 6 has reached the temperature set by the control device 24 and can cool the sucked-in gas 2 accordingly.
- the internal temperature in the refrigeration dryer 5 increases further.
- the internal temperature of the refrigeration dryer 5 has reached the maximum value, as a result of which the ice begins to melt.
- the defrosting process for the refrigeration dryer 5 is completed and the control device 24 controls the device 1 in such a way that the refrigeration dryer 5 is precooled and thus the state of the time is reached as before for the refrigeration dryer 6, which is then followed by the repeat the following times 91 to 93.
- This state can now be maintained over a few periods if the cold dryer 6 has not yet become too iced up.
- a temperature sensor 94 which is shown in FIG. 1, in the refrigeration dryer 6 that the desired cooling temperature for the sucked-in gas 2 is no longer reached, as a result of which the control device 24 now switches the refrigeration dryer 6 to defrost mode and at the same time switches the Refrigeration dryer 5 activated for cooling the sucked gas 2, whereby the refrigeration dryer 5 is operated in the cooling mode and the refrigeration dryer 6 in the defrost mode.
- FIG. 5 shows a possible embodiment variant of the device 1 according to the invention for compressing gases 2, which is indicated schematically by arrows 3.
- the same reference numerals are used for those parts which correspond to the parts of the embodiment variants described above.
- the gas 2 is drawn in by the compressor 4 via the intake port 34 of the respective refrigeration dryer 5, 6 and cooled in the latter.
- the difference to the embodiment variant described in FIG. 1 lies in the fact that in each of the two refrigeration dryers 5, 6 two heat exchangers 95, 15 and 96, 16 connected in series in the flow direction are arranged. While the heat exchangers 15, 16 in the manner already described above via the refrigerant circuit, consisting of the refrigerant compression ter 23, the various solenoid valves 21, 31, 32 and the expansion valves 27, 28, are controlled, a separate refrigerant circuit is now provided for the further heat exchangers 95, 96.
- Each input of the heat exchangers 95, 96 is thus connected via a separate connecting line 97, 98 with the interposition of an expansion valve 99, 100 to the output of a condenser 59 which is separate for this refrigerant circuit and which is connected downstream of a further refrigerant compressor 23.
- the intake port of the refrigerant compressor 23 is connected via the suction line 57 with the interposition of the solenoid valves 101, 102 with the suction lines 103, 104 connected downstream in the flow direction on the heat exchangers 95, 96.
- the expansion valves 99, 100 and the solenoid valves 101, 102 are in turn connected to the control device 24 via control lines 105 to 108.
- the heat exchangers 95, 96 there is no possibility provided in the refrigerant circuit for the heat exchangers 95, 96 to optionally supply one of the two heat exchangers 95, 96 with hot, gaseous refrigerant 68 for defrosting. Rather, when the heat exchangers 15, 95 or 16, 96 are defrosted alternately, the heat exchangers 15 or 16 are only heated appropriately with the hot, gaseous refrigerant 68, as has been described in detail with reference to FIGS. 2 and 3 the ice on the heat exchangers 95, 96 is also defrosted by the heating of the heat exchangers 15 and 16.
- the heat output of the heat exchangers 15 or 16 is not sufficient to defrost the refrigeration dryers 5 or 6, it is of course also possible to design the refrigerant circuit of the heat exchangers 95, 96 in such a way that the corresponding return lines 38, 39 also form in them and the necessary solenoid valves 31, 32 are installed so that each of the two heat exchangers 95, 96 can be defrosted by the supply of hot, gaseous refrigerant 68 in the same way as the heat exchangers 15, 16.
- the process for compressing gases 2 now proceeds as follows: In the device 1 shown, the gas 2 to be compressed is sucked into the refrigeration dryer 6, for example, via the refrigeration dryer 6, that is to say via the intake port 34 of the opened closure flap 33 of the refrigeration dryer 6.
- the aspirated gas 2 then passes through the heat exchanger 96, in which the sucked gas 2 is pre-cooled. Then the sucked-in gas 2 then passes through the heat exchanger 16 and is cooled by it to the desired temperature and reaches the compressor 4 via the suction line 8 and the opened flap 13.
- the expansion valves 28 and 100 and the solenoid valves 21 and 102 are actuated by the control device 24.
- the cold, gaseous refrigerant 68 can flow via the connecting lines 18 and 98 into the heat exchangers 16 and 96, as a result of which the gas 2 is cooled in the interior of the refrigeration dryer 6.
- the control device 24 controls the solenoid valve 21 and 102 via the control lines 45 and 107, as a result of which the cold, gaseous refrigerant 68 from the heat exchanger 16 and 96 via the suction lines 20 and 104 can flow to the suction lines 22 and 57 and to the refrigerant compressors 23.
- the sucked-in gas 2 is then cooled via the two heat exchangers 16 and 96.
- the two heat exchangers 16 and 96 are operated with different temperature ranges, i.e. that the heat exchanger 96 has a temperature of e.g. -10 ° and the heat exchanger 16 a temperature of e.g. Has -20 °, whereby the sucked gas 2 is pre-cooled as it flows past the heat exchanger 96 and then cooled by the heat exchanger 16 to the predetermined temperature.
- This has the advantage that the suctioned gas 2 can be cooled to a lower temperature, which ensures that the condensate contained in the gas 2 is separated.
- the heated refrigerant 68 in turn flows, as explained in detail in FIG. 3, via the check valve 40 and the return line 38 to the input of the heat exchanger 16 and is fed there into the connecting line 18 so that it is also mixed with the cold, gaseous refrigerant 68 and the refrigerant circuit is closed.
- the heat exchanger 15 heats up, as a result of which the ice on the heat exchanger 15 and on the walls of the cooling dryer 5 is defrosted. At the same time, heat accumulates in the cold dryer 5, as a result of which the heat exchanger 95 is also defrosted and the ice in the form of water flows out of the drain 36.
- FIGS. 1 to 5 show another embodiment variant of the solution according to the invention, only one of the previously described refrigeration dryers 5, 6, namely the refrigeration dryer 5, being shown for reasons of clarity.
- the function and the interconnection of the refrigeration dryer 5 shown with the refrigeration dryer 6, not shown, can be found in FIGS. 1 to 5 described above. Furthermore, the same reference numerals are used for those parts which correspond to the parts in the figures described above.
- the refrigeration dryer 6 is usually, but not necessarily, of the same design.
- the refrigeration dryer 5 shown for drawing in gases 2 for the compressor 4 differs from those in the previously described exemplary embodiments in that a climatic zone 109 and a cold zone 110 are arranged.
- the climatic zone 109 consists of three heat exchangers 111 to 113, whereas the Cold zone 110 consists of four heat exchangers 114 to 117.
- Each of these heat exchangers 111 to 113 and 114 to 117 consists of a continuous tube coil or tube coil, along which the air drawn in passes for cooling.
- the heat exchangers 111 to 113 of the climatic zone 109 and the heat exchangers 114 to 117 in the cold zone 110 are in turn connected via pressure lines 118 to 124 with the interposition of expansion valves 125 to 131 and connecting lines 17, 18. Be further Pressure lines 118 to 124 connected to one or more refrigerant compressors 23, which are not shown because of the overview.
- the outputs of the heat exchangers 111 to 117 are connected to one or more refrigerant compressors 23 via suction lines 132 to 138 with the interposition of solenoid valves 139 to 145, as a result of which the refrigerant circuit for the refrigerant 68 is closed.
- the refrigerant compressors 23 are or have been connected via bypass lines 146 to 152 with the interposition of a solenoid valve 153 to 159 to the connecting lines 17, 18, specifically between the expansion valves 125 to 131 and the heat exchangers 111 to 117.
- the return lines 160 to 166 which are connected between the expansion valves 125 to 131 and the heat exchangers 111 to 117, are also shown schematically. These return lines 160 to 166 are connected to the outlet of the heat exchangers in the refrigeration dryer 6 with the interposition of a check valve. At the output of the heat exchangers 111 to 117, further return lines 167 to 173, but before the solenoid valves 139 to 145, are connected to the suction lines 132 to 138. The ends of the return lines 167 to 173 are connected to the corresponding inputs of the heat exchanger on the refrigeration dryer 6 with the interposition of a check valve 174 to 180.
- heat exchangers 111 to 117 can be arranged both in the climate zone 109 and in the cold zone 110. It is, of course, possible for the individual heat exchangers 111 to 117 to be operated both individually and in parallel or together with the control device 24.
- heat exchangers 111 to 117 are individually controlled by the control device 24, it is possible to determine the internal temperature of the refrigeration dryer 5, 6 by the amount of the active heat exchangers 111 to 117 without the amount of the refrigerant to be expanded 68 must be regulated. Of course, it is possible that any number of heat exchangers 15, 16 can be used in the individual cold dryers 5, 6.
- FIG. 7 shows another embodiment variant of the solution according to the invention, as described in FIG. 6.
- a refrigeration dryer 5 was used and 6, namely the refrigeration dryer 5 shown.
- the function and the interconnection of the refrigeration dryer 5 shown with the refrigeration dryer 6, not shown, can be selected in accordance with any of the exemplary embodiments described above in FIGS. 1 to 6.
- the same reference numerals have been used for those parts which correspond to the parts in the figures described above.
- the refrigeration dryer 6 is usually, but not necessarily, of the same design and is usually two refrigeration dryers 5, 6 arranged in parallel which are operated alternately.
- the advantages can also be achieved when only one refrigeration dryer 5 or 6 is used.
- the difference to the embodiment variant shown in FIG. 6 is that several heat exchangers 114 to 116 are arranged in the cooling zone 110, but these are only supplied with the gaseous refrigerant 68 via a single, common connecting line 17.
- the connecting line 17 is connected to a refrigerant compressor 23 via an expansion valve 125 with a pressure line 119.
- the outlet of the heat exchangers 114 to 116 is in turn connected to the refrigerant compressor 23 via a suction line 132 with the interposition of a solenoid valve 139, as a result of which the refrigerant circuit for cooling the sucked-in gas 2 is closed.
- the feed lines for the heat exchangers 114 to 116 are thereby before entering the cold - Dryer 5 connected to the connecting line 17 or the suction line 132.
- care must be taken that the line length of the individual heat exchangers 114 to 117 and the tube diameter of the heat exchangers 114 to 117 are the same. This is to prevent a pressure difference between the individual heat exchangers 114 to 117 from occurring, since otherwise the gaseous refrigerant 68 seeks the path through the heat exchanger 114 to 117 with the least resistance. It follows that the same amount of gaseous refrigerant 68 is not flowed through the other heat exchangers 114 to 117, which would result in a reduction in performance.
- FIG. 7 also shows a bypass line with a solenoid valve 153, which, as described in FIG. 6, is connected to the refrigerant compressor 23.
- This bypass line 146 is connected to the connecting line 17, specifically between the expansion valve 125 and the crossing of the individual connecting lines for the heat exchangers 114 to 117, as a result of which the heat exchangers 114 to 117 can be defrosted.
- the climate zone 109 is likewise formed from a plurality of individual heat exchangers 111 to 113, which in turn are connected to the expansion valve 129 via a single connecting line 18.
- the expansion valve 129 is in turn connected via a pressure line 118 to the same refrigerant compressor 23 or a further refrigerant compressor. connected closer 23.
- the output of the heat exchangers 111 to 113 is connected via a suction line 136 with the interposition of a solenoid valve 143 to the same refrigerant compressor 23 that feeds the pressure line 118.
- the feed lines of the individual heat exchangers 111 to 113 are spliced outside the refrigeration dryer 5, which in turn allows the refrigerant to flow from the connection line 18 into the individual heat exchangers 111 to 113.
- the line length or the diameter of the lines of the individual heat exchangers 111 to 113 is the same size in order to avoid pressure differences between the individual heat exchangers 111 to 113.
- the climate zone 109 can, for example, also be connected to the connecting line 18 via a bypass line 150 with the interposition of a solenoid valve 157, as a result of which the climate zone 109 can be defrosted by supplying hot refrigerant gas via the bypass line 150
- the cold dryer 5, as described in FIG. 6, has the return lines 160, 164, 167 and 168 for interconnection with the cold dryer 6, as a result of which the defrosting method as used in the previously described FIGS. 1 to 6 is used can.
- FIG. 8 Another embodiment variant is shown in FIG. 8, which is similar to the embodiment previously described with reference to FIGS. 6 and 7.
- FIG. 8 For the sake of clarity, only one of the two refrigeration dryers 5, 6, namely the refrigeration dryer 5, has been shown.
- the function and the interconnection of the refrigeration dryer 5 shown with the refrigeration dryer 6, not shown, can be found in FIGS. 1 to 7 described above.
- the same reference symbols are used for those parts which correspond to parts in the figures described above.
- the refrigeration dryer 6 is usually, but not necessarily, of the same design.
- the climatic zone 110 is formed from only one heat exchanger 114.
- This heat exchanger 114 is formed from a plurality of refrigerant lines 181 to 184, the individual refrigerant lines 181 to 184 in turn being connected to the connecting line 17 outside the refrigerant dryer 5.
- care must be taken to ensure that the line cross section and the length of the individual refrigerant lines 181 to 184 are the same in order to avoid pressure differences, as described above.
- the refrigerant lines 181 to 184 in the individual heat exchangers 114 can be different if these are controlled via their own expansion valve 125.
- the connecting line 17 is in turn connected to the pressure line 119 via the expansion valve 125.
- the pressure line 119 is connected to the refrigerant compressor 23 as in the previously described figures.
- the output of the heat exchanger 114 is again connected via a suction line 132 with the interposition of a solenoid valve 139 to the refrigerant compressor 23, which is connected to the pressure line 119.
- the individual refrigerant lines 181 to 184 are connected between the solenoid valve 139 and the inlet or the outlet of the heat exchanger 114 with the suction line 132.
- the refrigerant compressor 23 connects a bypass line 146 with the interposition of a solenoid valve 153 to the connecting line 17, namely between the expansion valve 125 and the division of the connecting line 17 into the individual refrigerant lines 181 to 184.
- FIG. 109 Another embodiment variant of a heat exchanger 111 is shown in the climate zone 109.
- the heat exchanger now consists of three refrigerant lines 185 to 187.
- the refrigerant lines 185 to 187 are each connected via the connecting line 18 to an expansion valve 129 to 131, so that the individual refrigerant lines 185 to 187 have different lengths and different sizes can, since the arrangement of the expansion valves 129 to 131 allows a precise flow of the refrigerant 68 through the refrigerant lines 185 to 187 to be controlled by the control device 24.
- the expansion valves 129 to 131 are connected via the pressure line 118 to one or more refrigerant compressors 23.
- the refrigerant lines 185 to 187 are connected to the solenoid valves 143 to 145.
- the outputs of the solenoid valves 143 to 145 are then connected to the suction line 136, which in turn is connected to the refrigerant compressor 23.
- each refrigerant line 185 to 187 has its own bypass line 150 to 152 with the interposed solenoid valves 157 to 159, so that the climate zone 109 can also be defrosted. Furthermore, the individual connecting lines 17, 18 and the refrigerant lines 185 to 187 are connected to the return lines 160, 164 to 166, 167, 171 to 173, as a result of which the previously described method can be used.
- FIG. 9 shows a modified embodiment variant of the device 1 described in FIGS. 2 and 3 and the same reference numerals are therefore used for the same parts as in FIGS. 2 and 3.
- the difference from the embodiment variant described in FIGS. 2 and 3 is that in device 1 the return lines 38, 39 led away from the cold dryers 5, 6 are connected to the pressure lines 25, 26 via a venturi valve 188, 189.
- the return lines 38, 39 are connected to the pressure line 66 in front of the solenoid valves 48, 49.
- the pressure of the gaseous refrigerant 68 in the suction line 57 is measured at the refrigerant compressor 23 directly at the entrance by a pressure measuring device 190.
- the pressure in the line 61 of the compressed gaseous refrigerant 68 can also be detected by a pressure measuring device 191 at the outlet of the refrigerant compressor 23. If there is an excessively high pressure difference between the inlet and the outlet of the refrigerant compressor 23, the control device 24 can detect a leak in the line system of the device 1 and, if necessary, switch off the device 1. This safety circuit prevents the refrigerant compressor 23 from sucking gases 2 from the atmosphere which are saturated with water, as a result of which a water hammer on the refrigerant compressor 23 is avoided.
- the pressure measuring devices 190 and 191 can be arranged at any other desired location in the line system of the device 1.
- the advantage of arranging the pressure measuring devices 190, 191 directly on the refrigerant compressor 23 lies in the fact that the pressure of the refrigerant 68 is slightly changed by the line system, and thus an incorrect measurement result could occur when arranged at any other point in the line system.
- FIG. 9 Another embodiment of the return of the refrigerant 68 is also shown in FIG. 9.
- This variant comprises sniffer lines 192, 193, which are shown in broken lines.
- the Sniffer lines 192, 193 are connected to the suction line 19, 20 and to the further suction line 22, as a result of which the solenoid valves 21 in the suction lines 19, 20 are bridged.
- the liquid refrigerant 68 becomes gaseous again and can therefore be sucked in by the refrigerant compressor 23 without a water hammer on the refrigerant compressor 23.
- a compressed air system 194 is shown in FIG.
- the compressed air system 194 consists of several individual devices 195 to 197, the designs of the individual devices 195 to 197 being able to correspond to the devices 1 previously described in FIGS. 1 to 7.
- the devices 195 to 197 are connected to a compressed air tank 199 via manifolds 198.
- hoses 200 Connected to the compressed air tank 199 by hoses 200 are consumers 201, which can be formed, for example, by compressed air pistols 202 or gas or oil burners in power plants or by other compressed air consumers.
- a central control unit 203 is connected to the individual actuators 205 via a bus system 204, wherein each device 195 to 197 can have a plurality of actuators 205 which, as in the figures described above, control the functions of the individual devices 195 to 197. Furthermore, actuators 205 are arranged on the compressors 4 of the devices 195 to 197 and on the compressed air tank 199 in order to be able to control or regulate the switching on and off of the device 195 to 197 and the pressure in the compressed air tank 199 by the central control unit 203.
- the central control unit 203 checks the volume or the pressure of the compressed air in the compressed air tank 199 via the bus system 204 and the actuator 205 of the compressed air tank 199 and simultaneously measures the compressed air consumption of the compressed air 206 at the outlet of the compressed air tank 199 by the consumers 201. After the central control unit 203 has detected the pressure or the volume of the compressed air in the compressed air tank 199 and the consumption 201 of the compressed air 206, the central control unit 203 controls the individual devices 195 to 197 via the bus system 204, ie that with maximum consumption of compressed air 206, the central control unit 203 switches on all devices 195 to 197.
- the central control unit 203 can individually control the devices 195 to 197, as a result of which the volume of the gas 2 sucked in via the individual devices 195 to 197 can be controlled. It is also possible to interconnect different devices 195 to 197 with different capacities in the compressed air system 194, as a result of which a control of the consumption or the compressed air 206 to be generated can be regulated more precisely, since by grading the devices 195 to 197 an adaptation to the consumption of Dmckluft 206 to the consumer 201 can be done exactly.
- the central control unit 203 determines that less compressed air 206 is required by the consumer 201, the pressure in the compressed air tank 199 increases, whereby the central control unit 203 one of the devices 195 to 197, e.g. the device 195 switches off and thus less compressed air is generated, as a result of which the generated quantity of compressed air 206 is adapted to the consumption of the consumers 201.
- the central control unit 203 determines the pressure loss via the actuator 205 and then puts the device 195 back into operation via the bus system 204.
- the devices 195 to 197 each have their own control device 24, as a result of which each device 195 to 197 is controlled by its own control device 24.
- the central control unit 203 it is also possible for the central control unit 203 to cooperate with a plurality of decentralized control devices 24, which are assigned to the individual devices 195 to 197, via a bus system 204.
- the decentralized control devices 24 then take over the regulation of the devices 195 to 197 and only the superordinate control functions, such as for example determining how many of the devices 195 to 197 are put into operation, or a central recording of the performance data and the visualization of the Operating states of the individual devices 195 to 197 or of the entire system in real time or the evaluations necessary for this.
- the central control unit 203 can of course also be formed by corresponding microprocessors, for example commercially available personal computers with graphic terminals or the like.
- FIG. 10 a suction device 207 for sucking the gas 2 is shown in FIG. 10.
- This suction device 207 can be used for all of the aforementioned exemplary embodiments in FIGS. 1 to 9.
- the suction device 207 has two openings 208, 209 for sucking in the gas 2, the opening 208 leading directly into the refrigeration dryer 5 and the other opening 209 via a particle filter 210 into the refrigeration dryer 5.
- the openings 208, 209 can be opened or closed by the central control unit 203 by activating the closure flaps 211, 212 in the tubes, ie the opening 208 is activated when the closure flap 211 and the closure flap 33 are activated and when the activation the closure flap 212 with the closure flap 33 the gas 2 is sucked in via the particle filter 210.
- the particle filter must be activated when the gas 2 that is sucked in contains too little moisture or water in order to wet the surfaces of the heat exchangers, so that the dirt particles are separated out independently. This is the case when the gas 2 is at a low temperature compared to the planned intake temperature, such as in winter.
- FIG. 10 Furthermore, another embodiment of the compressed air system 194 shown in FIG. 10 is shown in FIG. 11, the same reference numerals being used for the same parts.
- the difference from the compressed air system 194 shown in FIG. 10 is that the compressors 4 for sucking in the gas 2 are no longer sucked in via the refrigeration dryers 5, 6, as described in FIG. 10, but rather that the compressors 4 are first a gas 2 aspirate from the atmosphere, compress it and then cool it down to a certain temperature via the refrigeration dryers 5, 6. Furthermore, the water vapor contained in the atmosphere or in the gas 2 is excreted in the cold dryers 5, 6. The cooled air is then forwarded by the individual devices 195 to 197 into the compressed air tank 199, from where it can then be forwarded to the consumer 201.
- the devices 195 to 197 are arranged both on the suction side of the compressors 4 and on the pressure side of the compressors 4.
- refrigeration dryers 5, 6 according to the invention can also be used in smaller systems, not only in the suction area, that is to say upstream of the compressor 4, but also in the pressure area after the outlet of the compressor 4.
- compressors for gases 2 such as, for example, screw compressors, piston compressors, radial compressors or the like.
- FIG. 1 A further embodiment of the solution according to the invention is shown in FIG.
- only one refrigeration dryer 5 or 6, namely the refrigeration dryer 5 has again been shown, the same reference numerals being used for the same parts as are contained in the previously described FIGS. 1 to 11.
- the function and the interconnection of the refrigeration dryer 5 shown with the refrigeration dryer 6 can be selected as desired from one of the previously described exemplary embodiments of FIGS. 1 to 11.
- the refrigeration dryer 6 is usually, but not necessarily, designed in the same way and usually two refrigeration dryers 5, 6 are arranged in parallel and are operated alternately.
- the refrigeration dryer 5 comprises several zones, in particular the cold zone 110 and the climatic zone 109, and one arranged between the cold zone 110 and the climatic zone 109 Intermediate zone 213 is formed.
- a plurality of heat exchangers 214 to 216 are arranged in the cold zone 110.
- the heat exchangers 214 to 216 are arranged one above the other in the flow direction of the sucked-in gas 2, preferably vertically.
- the heat exchangers 214 to 216 in the intermediate zone 213 and the climatic zone 109 are arranged in the same way.
- the heat exchangers 214 to 216 can be activated, for example, as described in FIG. 7. It is of course possible that any other embodiment variant of the previously described FIGS. 1 to 11 can be used to control the heat exchangers 214 to 216. Furthermore, it is also possible for further heat exchangers 214 to 216 to be arranged in the same plane parallel to the individual heat exchangers 214 to 216, so that they are distributed over the cross-sectional area of the refrigeration dryer 5 in a plane vertical to the flow direction or in a plurality of planes lying one behind the other in the flow direction in each case several heat exchangers 214 to 216 are arranged.
- Another advantage of this embodiment variant shown is that by arranging the intermediate zone 213, the intermediate region between the cold zone 110 and the climatic zone 109 can be used as a further cooling stage, so that three different zones with different temperatures are now arranged in the cold dryer 5 .
- further individual zones are also arranged in the refrigeration dryer 5, so that a finer adjustment of the temperature from the climatic zone 109 to the cold zone 110 is achieved.
- the control of the intermediate zone 213 corresponds to the control of the cold zone 110 as described in FIG. 7, the same reference numerals as used in FIG. 7 being used for the intermediate zone 213 for the same parts. Furthermore, it should be mentioned that the control of the individual heat exchangers 214 to 216 can take place independently.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Drying Of Gases (AREA)
- Defrosting Systems (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/809,518 US5865033A (en) | 1994-09-29 | 1995-09-27 | Method and device for cooling gases |
DE19581094T DE19581094D2 (de) | 1994-09-29 | 1995-09-27 | Verfahren und Vorrichtung zum Kühlen von Gasen |
AU34650/95A AU711606B2 (en) | 1994-09-29 | 1995-09-27 | Method and device for cooling gases |
SI9530509T SI0783658T1 (en) | 1994-09-29 | 1995-09-27 | Method and device for cooling gases |
EP95931077A EP0783658B1 (de) | 1994-09-29 | 1995-09-27 | Verfahren und vorrichtung zum kühlen von gasen |
CA 2201111 CA2201111A1 (en) | 1994-09-29 | 1995-09-27 | Method and device for cooling gases |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA1854/94 | 1994-09-29 | ||
AT0185494A AT402026B (de) | 1994-09-29 | 1994-09-29 | Verfahren und vorrichtung zum kühlen von gasen |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1996010156A2 true WO1996010156A2 (de) | 1996-04-04 |
WO1996010156A3 WO1996010156A3 (de) | 1996-06-13 |
Family
ID=3522445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT1995/000187 WO1996010156A2 (de) | 1994-09-29 | 1995-09-27 | Verfahren und vorrichtung zum kühlen von gasen |
Country Status (6)
Country | Link |
---|---|
US (1) | US5865033A (de) |
EP (1) | EP0783658B1 (de) |
AT (1) | AT402026B (de) |
AU (1) | AU711606B2 (de) |
DE (2) | DE29500781U1 (de) |
WO (1) | WO1996010156A2 (de) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI110817B (fi) * | 2000-02-01 | 2003-03-31 | Waertsilae Tech Oy Ab | Lämmöntalteenottolaitteisto ja menetelmä likaantumisen minimoimiseksi lämmöntalteenottolaitteistossa |
US6360549B1 (en) * | 2001-03-12 | 2002-03-26 | Sandia Corporation | Method and apparatus for extracting water from air |
DE102004041785A1 (de) * | 2004-08-21 | 2006-02-23 | Gast, Karl Heinz, Dipl.-Ing. (FH) | Verfahren und Einrichtung zum Betreiben von Systemen mit Aggregatzustand wechselnden Medien |
DE102010033187A1 (de) | 2010-08-03 | 2012-02-09 | Boge Kompressoren Otto Boge Gmbh & Co. Kg | Anordnung mit Luftkompressor und Kältekreislauf |
US9200829B2 (en) * | 2013-09-24 | 2015-12-01 | Walter Stark | Low temperature cooling and dehumidification device with reversing airflow defrost for applications where cooling coil inlet air is above freezing |
WO2015054682A2 (en) * | 2013-10-13 | 2015-04-16 | Cornerstone Resources, Llc | Methods and apparatus utilizing vacuum for breaking organic cell walls |
CN106714937B (zh) * | 2014-05-29 | 2020-05-19 | 机械工业独资股份公司 | 用于被压缩空气的冷却干燥器和对应的方法 |
KR102571438B1 (ko) * | 2014-08-22 | 2023-08-28 | 심플 어프로치 시스템스 인코포레이티드 | 다양한 소스 산업 폐기물을 에너지로 전환시키기 위한 장치, 시스템, 및 방법 |
FR3025300B1 (fr) * | 2014-09-01 | 2016-12-09 | Ereie - Energy Res Innovation Eng | Procede de deshumidification d'air humide |
CN104801143A (zh) * | 2015-05-11 | 2015-07-29 | 中国神华能源股份有限公司 | 工艺气脱水系统及工艺气脱水方法 |
CN114017936B (zh) * | 2022-01-07 | 2022-03-25 | 深圳市森领域电器设备有限公司 | 一种用于空调制冷的螺杆式水冷机 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3637071A1 (de) | 1985-11-08 | 1987-05-14 | Gossler Ewald | Verfahren und vorrichtung zum verdichten von gasen |
US4905476A (en) | 1988-03-07 | 1990-03-06 | Osmi S.R.L. | Device for low temperature refrigerative drying of compressed air (and/) or other gases |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH234745A (de) * | 1943-12-31 | 1944-10-31 | Escher Wyss Maschf Ag | Verfahren zum Belüften von zum Aufenthalt von Personen bestimmten Räumen in Felsen, Schächten, von Schutzräumen und dergleichen, und Luftklimatisierungsanlage mit Kälteerzeugungseinrichtung zum Ausführen dieses Verfahrens. |
US2763132A (en) * | 1953-08-31 | 1956-09-18 | Lawrence S Jue | Dehumidifying apparatus |
DE958845C (de) * | 1953-09-05 | 1957-02-28 | Sulzer Ag | Kompressionskuehlanlage |
US2867988A (en) * | 1955-10-14 | 1959-01-13 | Paul H Brandt | Air dryer construction and method of operation |
US3150498A (en) * | 1962-03-08 | 1964-09-29 | Ray Winther Company | Method and apparatus for defrosting refrigeration systems |
FR2035305A5 (de) * | 1969-02-19 | 1970-12-18 | Streater Ind Inc | |
US3581509A (en) * | 1969-10-27 | 1971-06-01 | Jones & Laughlin Steel Corp | Moisture removal apparatus |
CA1041782A (en) * | 1974-08-15 | 1978-11-07 | Emhart Industries | Control means for refrigeration systems |
US4122688A (en) * | 1976-07-30 | 1978-10-31 | Hitachi, Ltd. | Refrigerating system |
DE2639339A1 (de) * | 1976-09-01 | 1978-03-09 | Motorheizung Gmbh | Vor vereisung gesicherte verdampferanordnung fuer waermepumpen zur aufnahme von waerme aus der umgebungsluft |
DE2948520A1 (de) * | 1979-12-01 | 1981-06-04 | Walfried 8631 Niederfüllbach Ostrecha | Kaeltemittel-doppelverdampfer zur energiesparenden heissgasabtauung fuer kuehlraeume und kuehlgeraete |
US4505125A (en) * | 1981-01-26 | 1985-03-19 | Baglione Richard A | Super-heat monitoring and control device for air conditioning refrigeration systems |
US4523435A (en) * | 1983-12-19 | 1985-06-18 | Carrier Corporation | Method and apparatus for controlling a refrigerant expansion valve in a refrigeration system |
JPH035680A (ja) * | 1989-05-30 | 1991-01-11 | Sharp Corp | 空気調和機 |
DE4022802A1 (de) * | 1990-07-18 | 1992-01-23 | Milorad Bozovic | Vorrichtung zur trocknung von gasen, insbesondere druckluft |
DE4135887A1 (de) * | 1991-10-31 | 1993-05-06 | Wolfram Dr. 4040 Neuss De Seiler | Vorrichtung zum abtauen von kaeltetrocknern unter 0(grad) c |
-
1994
- 1994-09-29 AT AT0185494A patent/AT402026B/de not_active IP Right Cessation
-
1995
- 1995-01-19 DE DE29500781U patent/DE29500781U1/de not_active Expired - Lifetime
- 1995-09-27 EP EP95931077A patent/EP0783658B1/de not_active Expired - Lifetime
- 1995-09-27 DE DE19581094T patent/DE19581094D2/de not_active Expired - Fee Related
- 1995-09-27 US US08/809,518 patent/US5865033A/en not_active Expired - Fee Related
- 1995-09-27 WO PCT/AT1995/000187 patent/WO1996010156A2/de active IP Right Grant
- 1995-09-27 AU AU34650/95A patent/AU711606B2/en not_active Ceased
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3637071A1 (de) | 1985-11-08 | 1987-05-14 | Gossler Ewald | Verfahren und vorrichtung zum verdichten von gasen |
US4905476A (en) | 1988-03-07 | 1990-03-06 | Osmi S.R.L. | Device for low temperature refrigerative drying of compressed air (and/) or other gases |
Also Published As
Publication number | Publication date |
---|---|
ATA185494A (de) | 1996-06-15 |
US5865033A (en) | 1999-02-02 |
EP0783658A1 (de) | 1997-07-16 |
WO1996010156A3 (de) | 1996-06-13 |
DE19581094D2 (de) | 1999-03-11 |
AT402026B (de) | 1997-01-27 |
DE29500781U1 (de) | 1995-03-02 |
AU711606B2 (en) | 1999-10-14 |
EP0783658B1 (de) | 2001-04-18 |
AU3465095A (en) | 1996-04-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3637071C2 (de) | Verfahren und Vorrichtung zum Verdichten von Gasen | |
EP2388543A2 (de) | Vorrichtung zum Trocknen von Schüttgut in wenigstens einem Vorratsbehälter | |
EP3003747B1 (de) | Klimatisierungsvorrichtung für ein kraftfahrzeug und verfahren zu deren betrieb | |
EP2256438B1 (de) | Verbesserte Kälteerzeugungsvorrichtung, insbesondere für Flugzeuge | |
DE102013110224A1 (de) | Verfahren zum Betreiben einer Klimaanlage für ein Kraftfahrzeug | |
CH695869A5 (de) | Mehrstufiger, zwischen Last- und Leerlaufbetrieb umschaltbarer Verdichter. | |
DE10301006A1 (de) | Heiz-Kühlkreislauf für eine Klimaanlage eines Kraftfahrzeuges, Klimaanlage und Verfahren zur Regelung derselben | |
EP3218215B1 (de) | Kühlsystem | |
WO1996010156A2 (de) | Verfahren und vorrichtung zum kühlen von gasen | |
EP0553706A1 (de) | Vorrichtung zum Kühltrocknen von Gasen | |
CH626155A5 (de) | ||
EP3319823A1 (de) | Klimatisierungsvorrichtung für ein kraftfahrzeug und verfahren zu deren betrieb | |
DE102005034826B4 (de) | Wärmepumpe sowie Verfahren zum Betrieb einer Wärmepumpe | |
DE112011100614T5 (de) | Anordnung zum Enteisen eines Ladeluftkühlers | |
DE19808011C1 (de) | Vorrichtung und Verfahren zur kontinuierlichen Kältetrocknung | |
DE102016005957A1 (de) | Verfahren zum Betreiben und Enteisen eines modularen Kühlsystems | |
DE10254109B4 (de) | Kombinierte Kühl- und Heizvorrichtung mit einem gemeinsam genutzten Gaskühler, insbesondere für ein Kraftfahrzeug | |
EP0539816A1 (de) | Vorrichtung zum Abtauen von Kälte-Trocknern unter 0 Grad Celcius | |
DE102004036301A1 (de) | Kältemaschine und Verfahren zum Betreiben einer Kältemaschine | |
DE102006024871A1 (de) | Verfahren zum Abtauen des Verdampfers eines Wärmepumpenheizsystems | |
AT490U1 (de) | Verfahren und vorrichtung zum kuehlen von gasen | |
EP3490825B1 (de) | Klimatisierungsvorrichtung für ein kraftfahrzeug und verfahren zu deren betrieb | |
AT410967B (de) | Verfahren zum verdichten von gasen, insbesondere von luft in einem druckluftleitsystem | |
DE112009000657B4 (de) | Verfahren zum Betrieb eines Kühlgeräts sowie Kühlgerät zum Durchführen eines solchen Verfahrens | |
DE202005008751U1 (de) | Kälte-Trockner für ein Gas |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DE DK EE ES FI GB GE HU IS JP KE KG KP KR KZ LK LR LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TT UA UG US UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): KE MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
AK | Designated states |
Kind code of ref document: A3 Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DE DK EE ES FI GB GE HU IS JP KE KG KP KR KZ LK LR LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TT UA UG US UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): KE MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 08809518 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2201111 Country of ref document: CA Ref document number: 2201111 Country of ref document: CA Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1995931077 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 1995 9092 Country of ref document: AT Date of ref document: 19960404 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 19959092 Country of ref document: AT |
|
WWP | Wipo information: published in national office |
Ref document number: 1995931077 Country of ref document: EP |
|
REF | Corresponds to |
Ref document number: 19581094 Country of ref document: DE Date of ref document: 19990311 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 19581094 Country of ref document: DE |
|
WWG | Wipo information: grant in national office |
Ref document number: 1995931077 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8607 |