WO1995016191A1 - Temperature recorder - Google Patents

Temperature recorder Download PDF

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Publication number
WO1995016191A1
WO1995016191A1 PCT/GB1994/002713 GB9402713W WO9516191A1 WO 1995016191 A1 WO1995016191 A1 WO 1995016191A1 GB 9402713 W GB9402713 W GB 9402713W WO 9516191 A1 WO9516191 A1 WO 9516191A1
Authority
WO
WIPO (PCT)
Prior art keywords
track
temperature recorder
liquid
indicator
indicator liquid
Prior art date
Application number
PCT/GB1994/002713
Other languages
French (fr)
Inventor
David Peter Gratwick Sarll
Original Assignee
David Peter Gratwick Sarll
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by David Peter Gratwick Sarll filed Critical David Peter Gratwick Sarll
Priority to AU11976/95A priority Critical patent/AU1197695A/en
Publication of WO1995016191A1 publication Critical patent/WO1995016191A1/en

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K3/00Thermometers giving results other than momentary value of temperature
    • G01K3/02Thermometers giving results other than momentary value of temperature giving means values; giving integrated values
    • G01K3/04Thermometers giving results other than momentary value of temperature giving means values; giving integrated values in respect of time

Definitions

  • This invention relates to a temperature recorder which may be used as a defrost indicator for frozen food or other packages.
  • all frozen food contains bacteria and fungi and also enzymes which were used by the food when alive.
  • the bacteria and fungi cannot breed and the enzymes cannot react with the tissues around them, so that therefore spoilage of the food is halted.
  • the bacteria and fungi multiply, and the enzymes react with the surrounding tissues so that spoilage of the food recommences. If the food is refrozen the bacteria and fungi stop breeding but their numbers do not decrease: further, the damage caused by the enzymes ceases but is not repaired. If the food is defrosted again, spoilage of the food recommences from this new level. This cycle can continue until a critical point is reached at which the food becomes unsafe and/or unpalatable. However this condition of the food may not be apparent by mere visual inspection of the refrozen food package.
  • a temperature recorder which can be used to alleviate the above-described problem.
  • a temperature recorder which comprises a track and a capsule of coloured indicator liquid, arranged for a frangible membrane of the capsule to break due to anomalous expansion of the indicator liquid upon freezing of the latter, and for the indicator liquid to migrate along said track by capillary action when subsequently thawed.
  • this temperature recorder is primed upon initial freezing in that at this time its indicator liquid expands and breaks the frangible membrane of the capsule: however, the frozen indicator liquid remains substantially wholly within the capsule. Then if the temperature rises sufficiently, the indicator liquid melts and migrates along the track by capillary attraction.
  • the temperature recorder mimics the biological action of the bacteria and other agents in the food.
  • the track is formed by a piece of porous material.
  • the track may be formed by a gap between a base layer and a cover layer, the gap being sufficiently small that the liquid will migrate along the track by capillary attraction.
  • the track of the temperature recorder follows a generally spiral path, which may comprise a continuous curve or a series of straight lines followed by bends, extending for 360° or more.
  • the temperature recorder compensates for the randomness of orientations in which the products to which it is applied may be stored.
  • the distance which the indicator liquid migrates along the track will tend to average out regardless of the orientation of the recorder.
  • a temperature recorder which comprises a reservoir of coloured indicator liquid and a track arranged for the indicator liquid to migrate along said track when the indicator liquid thaws, said track following a generally spiral path.
  • the track narrows progressively, in the direction away from the capsule of indicator liquid, so that its rate of migration remains uniform regardless of its position along the track.
  • the track may be expanded in width at predetermined points along its length, to delay the migration at these points. These points can thus indicate that the temperature has exceeded a limit of thawed time and/or temperature, such that the product should not be refrozen, or alternatively where it is sufficiently thawed to cook.
  • the track may be arranged to reveal a message at a predetermined point when the indicator liquid reaches that point: for example a non-absorbent print may be formed on the track, which prevents the indicator liquid from migrating into the region so printed.
  • the temperature recorder can be used on products other than frozen food, e.g. drugs and medicines.
  • FIGURE 1 is a view of a frozen food package provided with a first embodiment of temperature recorder in accordance with this invention, in the form of a defrost indicator;
  • FIGURE 2 consists of a plan, side and end views of the defrost indicator shown in Figure 1;
  • FIGURE 3 consists of plan, side and end views of a second embodiment of defrost indicator;
  • FIGURE 4 consists of three enlarged sectional views of a part of the defrost indicator of Figure 2, shown before freezing, after freezing and after subsequent thawing (or partial thawing) .
  • a frozen food package 10 is shown with a defrost indicator 12 fixed to its outer surface, preferably as shown the top surface of the package.
  • the defrost indicator comprises a track 20 and a reservoir 22 at one end of the track 20: the track follows a curved, spiral path which extends inwardly from the reservoir 22, over about 1% turns.
  • the track 20 follows a straight line path which turns through a right angle at intervals, again spiralling inwardly from the reservoir 22 and, in this case over two full turns.
  • the defrost indicator comprises a base layer 30 and a top layer 32, both e.g. of plastics material, and of shape corresponding to the spiral track just described.
  • the base and top layers are joined together along their edges, but a capsule 34 of liquid 35 is enclosed between the two layers at one end of the track, to form the reservoir described above.
  • a strip 36 of absorbent material e.g. porous paper such as blotting paper
  • absorbent material is also enclosed between the base and top layers 30,32 and extends along the track 20.
  • the liquid 35 within the reservoir capsule 34 is water to which a suitably coloured dye has been added: the liquid may include a further additive to give the liquid a predetermined melting point lower than 0°C.
  • the condition of the reservoir capsule 34 prior to freezing is shown at (a) in Figure 4.
  • the liquid 35 expands and breaks a frangible membrane 37 of the capsule: the condition of the capsule at this time is shown at (b) in Figure 4.
  • this indicator liquid will start to flow and will migrate into the absorbent strip 36 and along the track 20, as shown at (c) in Figure 4. If the temperature drops again, the liquid will freeze, and its migration along the track 20 will stop: thus, the liquid will not migrate any further, nor will it return to the reservoir.
  • the position to which the indicator liquid migrates along the track 20 gives an indication of the length of time for which the temperature of the package has temporarily been above the melting point of the indicator liquid.
  • the spiral nature of the track 20 compensates against the randomness of the orientation at which the package 10 may be stored, as explained above.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Measuring Temperature Or Quantity Of Heat (AREA)

Abstract

A temperature recorder, e.g. for indicating the length of time that frozen food has been defrosted, comprises a reservoir 22 of coloured liquid which breaks upon freezing, and a track 20 arranged for the indicator liquid to migrate along when the liquid subsequently thaws. The position to which the liquid migrates along the track 20 gives an indication of the length of time for which the temperature of the frozen food has been above the melting point of the indicator liquid.

Description

TEMPERATURE RECORDER
This invention relates to a temperature recorder which may be used as a defrost indicator for frozen food or other packages.
It is a problem that if a frozen food package has been thawed or partially thawed and then refrozen again, it is not possible to tell from the package that it has been temporarily thawed since originally being frozen. In some cases it does not matter that a frozen food package has thawed temporarily, providing its temperature was not above a predetermined level for too long a period of time and/or the temperature which it reached was not too high.
Thus, all frozen food contains bacteria and fungi and also enzymes which were used by the food when alive. When the food is frozen, the bacteria and fungi cannot breed and the enzymes cannot react with the tissues around them, so that therefore spoilage of the food is halted. When the food is defrosted, the bacteria and fungi multiply, and the enzymes react with the surrounding tissues so that spoilage of the food recommences. If the food is refrozen the bacteria and fungi stop breeding but their numbers do not decrease: further, the damage caused by the enzymes ceases but is not repaired. If the food is defrosted again, spoilage of the food recommences from this new level. This cycle can continue until a critical point is reached at which the food becomes unsafe and/or unpalatable. However this condition of the food may not be apparent by mere visual inspection of the refrozen food package.
I have now devised a temperature recorder which can be used to alleviate the above-described problem. In accordance with this invention as seen from a first aspect, there is provided a temperature recorder which comprises a track and a capsule of coloured indicator liquid, arranged for a frangible membrane of the capsule to break due to anomalous expansion of the indicator liquid upon freezing of the latter, and for the indicator liquid to migrate along said track by capillary action when subsequently thawed. It will be appreciated that this temperature recorder is primed upon initial freezing in that at this time its indicator liquid expands and breaks the frangible membrane of the capsule: however, the frozen indicator liquid remains substantially wholly within the capsule. Then if the temperature rises sufficiently, the indicator liquid melts and migrates along the track by capillary attraction. If the product is then frozen again, the migration stops but does not retreat. If the product is subsequently thawed again, the migration of the indicator liquid along the track recommences, and so on. In effect, the temperature recorder mimics the biological action of the bacteria and other agents in the food.
Preferably the track is formed by a piece of porous material. Instead, the track may be formed by a gap between a base layer and a cover layer, the gap being sufficiently small that the liquid will migrate along the track by capillary attraction.
Preferably the track of the temperature recorder follows a generally spiral path, which may comprise a continuous curve or a series of straight lines followed by bends, extending for 360° or more. In this way the temperature recorder compensates for the randomness of orientations in which the products to which it is applied may be stored. Thus, the distance which the indicator liquid migrates along the track will tend to average out regardless of the orientation of the recorder.
In accordance with this invention as seen from a second aspect, there is provided a temperature recorder which comprises a reservoir of coloured indicator liquid and a track arranged for the indicator liquid to migrate along said track when the indicator liquid thaws, said track following a generally spiral path.
Preferably the track narrows progressively, in the direction away from the capsule of indicator liquid, so that its rate of migration remains uniform regardless of its position along the track.
The track may be expanded in width at predetermined points along its length, to delay the migration at these points. These points can thus indicate that the temperature has exceeded a limit of thawed time and/or temperature, such that the product should not be refrozen, or alternatively where it is sufficiently thawed to cook.
The track may be arranged to reveal a message at a predetermined point when the indicator liquid reaches that point: for example a non-absorbent print may be formed on the track, which prevents the indicator liquid from migrating into the region so printed.
It will be appreciated that the temperature recorder can be used on products other than frozen food, e.g. drugs and medicines.
Embodiments of this invention will now be described by way of examples only and with reference to the accompanying drawings, in which: FIGURE 1 is a view of a frozen food package provided with a first embodiment of temperature recorder in accordance with this invention, in the form of a defrost indicator;
FIGURE 2 consists of a plan, side and end views of the defrost indicator shown in Figure 1; FIGURE 3 consists of plan, side and end views of a second embodiment of defrost indicator; and
FIGURE 4 consists of three enlarged sectional views of a part of the defrost indicator of Figure 2, shown before freezing, after freezing and after subsequent thawing (or partial thawing) .
Referring to Figure 1, a frozen food package 10 is shown with a defrost indicator 12 fixed to its outer surface, preferably as shown the top surface of the package. As shown more clearly in Figure 2, the defrost indicator comprises a track 20 and a reservoir 22 at one end of the track 20: the track follows a curved, spiral path which extends inwardly from the reservoir 22, over about 1% turns. In the alternative embodiment shown in Figure 3, the track 20 follows a straight line path which turns through a right angle at intervals, again spiralling inwardly from the reservoir 22 and, in this case over two full turns.
As shown in Figure 4 , the defrost indicator comprises a base layer 30 and a top layer 32, both e.g. of plastics material, and of shape corresponding to the spiral track just described. The base and top layers are joined together along their edges, but a capsule 34 of liquid 35 is enclosed between the two layers at one end of the track, to form the reservoir described above. A strip 36 of absorbent material (e.g. porous paper such as blotting paper) is also enclosed between the base and top layers 30,32 and extends along the track 20.
The liquid 35 within the reservoir capsule 34 is water to which a suitably coloured dye has been added: the liquid may include a further additive to give the liquid a predetermined melting point lower than 0°C. The condition of the reservoir capsule 34 prior to freezing is shown at (a) in Figure 4. When the capsule 34 is frozen, the liquid 35 expands and breaks a frangible membrane 37 of the capsule: the condition of the capsule at this time is shown at (b) in Figure 4. Should the temperature of the defrost indicator rise and the indicator liquid 35 thaw, then this indicator liquid will start to flow and will migrate into the absorbent strip 36 and along the track 20, as shown at (c) in Figure 4. If the temperature drops again, the liquid will freeze, and its migration along the track 20 will stop: thus, the liquid will not migrate any further, nor will it return to the reservoir.
Accordingly, the position to which the indicator liquid migrates along the track 20 gives an indication of the length of time for which the temperature of the package has temporarily been above the melting point of the indicator liquid.
The spiral nature of the track 20 compensates against the randomness of the orientation at which the package 10 may be stored, as explained above.

Claims

1) A temperature recorder which comprises a track and a capsule of coloured indicator liquid, arranged for a frangible membrane of the capsule to break due to anomalous expansion of the indicator liquid upon freezing of the latter, and for the indicated liquid to migrate along said track by capillary action when subsequently thawed.
2) A temperature recorder as claimed in claim 1, in which the track comprises a piece of porous material.
3) A temperature recorder as claimed in claim 1, in which the track comprises a gap formed between a bare layer and a cover layer, the gap being sufficiently small that the liquid will migrate along the track by capillary action.
4) A temperature recorder according to any preceding claim, in which the track follows a generally spiral path.
5) A temperature recorder as claimed in claim 4, in which the spiral path comprises a continuous curve.
6) A temperature recorder as claimed in claim 4, in which the spiral path comprises a series of straight lines followed by bends, extending for 360° or more.
7) A temperature recorder comprising a reservoir of coloured indicator liquid and a track arranged for the indicator liquid to migrate along said track when the indicator liquid thaws, said track following a generally spiral path.
8) A temperature recorder as claimed in claim 7, in which the track narrows progressively, in the direction away from the capsule of indicator liquid, so the rate of migration of the liquids remains uniform regardless of its position along the track. 9) A temperature recorder according to claims 7 cr ε , m which the track is expanded in width at predetermined points along its length, to delay the migration of the liquids at these points.
10) A temperature recorder according to any of claims 7 to 9, in which the track is arranged to reveal a message at a predetermined point when the indicator reaches that point.
11) A temperature recorder according to claim 10, in which the message is printed on the track in a non-absorbent print.
PCT/GB1994/002713 1993-12-11 1994-12-12 Temperature recorder WO1995016191A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU11976/95A AU1197695A (en) 1993-12-11 1994-12-12 Temperature recorder

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB939325400A GB9325400D0 (en) 1993-12-11 1993-12-11 Temperature recorder
GB9325400.1 1993-12-11

Publications (1)

Publication Number Publication Date
WO1995016191A1 true WO1995016191A1 (en) 1995-06-15

Family

ID=10746480

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1994/002713 WO1995016191A1 (en) 1993-12-11 1994-12-12 Temperature recorder

Country Status (3)

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AU (1) AU1197695A (en)
GB (1) GB9325400D0 (en)
WO (1) WO1995016191A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004092697A1 (en) * 2003-04-16 2004-10-28 NYGÅRDH, Mats A temperature indicator, a package for goods and a method of monitoring the freshness of goods kept in packages
WO2007065223A1 (en) * 2005-12-07 2007-06-14 John Riemelmoser Temperature history indicating device
WO2011080375A1 (en) * 2009-12-31 2011-07-07 Valtion Teknillinen Tutkimuskeskus Tampering detector and method
ITUD20120141A1 (en) * 2012-08-08 2014-02-09 Salvatore Bongarzone DEVICE AND METHOD OF CHECKING AND VERIFYING THE CONSERVATION OF A COLD PRESERVED PRODUCT
US8778962B2 (en) 2001-02-19 2014-07-15 Novartis Pharmaceuticals Corporation Treatment of solid tumors with rapamycin derivatives

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3399284A (en) * 1961-12-18 1968-08-27 Miles Lab Indicating device
US3414415A (en) * 1965-10-22 1968-12-03 Robert L. Broad Jr. Thaw indicator
DE1648263A1 (en) * 1967-11-24 1972-04-06 Johann Michel Process and device for marking the quality of frozen goods

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3399284A (en) * 1961-12-18 1968-08-27 Miles Lab Indicating device
US3414415A (en) * 1965-10-22 1968-12-03 Robert L. Broad Jr. Thaw indicator
DE1648263A1 (en) * 1967-11-24 1972-04-06 Johann Michel Process and device for marking the quality of frozen goods

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8778962B2 (en) 2001-02-19 2014-07-15 Novartis Pharmaceuticals Corporation Treatment of solid tumors with rapamycin derivatives
WO2004092697A1 (en) * 2003-04-16 2004-10-28 NYGÅRDH, Mats A temperature indicator, a package for goods and a method of monitoring the freshness of goods kept in packages
WO2007065223A1 (en) * 2005-12-07 2007-06-14 John Riemelmoser Temperature history indicating device
WO2011080375A1 (en) * 2009-12-31 2011-07-07 Valtion Teknillinen Tutkimuskeskus Tampering detector and method
US20130017609A1 (en) * 2009-12-31 2013-01-17 Basf Se Apparatus and method for indicating a physical or chemical phenomenon
ITUD20120141A1 (en) * 2012-08-08 2014-02-09 Salvatore Bongarzone DEVICE AND METHOD OF CHECKING AND VERIFYING THE CONSERVATION OF A COLD PRESERVED PRODUCT

Also Published As

Publication number Publication date
AU1197695A (en) 1995-06-27
GB9325400D0 (en) 1994-02-16

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