WO1995011753A1 - Procede et catalysateur d'hydrotraitement - Google Patents
Procede et catalysateur d'hydrotraitement Download PDFInfo
- Publication number
- WO1995011753A1 WO1995011753A1 PCT/EP1994/003543 EP9403543W WO9511753A1 WO 1995011753 A1 WO1995011753 A1 WO 1995011753A1 EP 9403543 W EP9403543 W EP 9403543W WO 9511753 A1 WO9511753 A1 WO 9511753A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- hydrogen
- molybdenum
- metal component
- hydrotreating
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
Definitions
- SPC-1, SPC-2 and SPC-3 Three silicon-promoted catalysts (SPC-1, SPC-2 and SPC-3) were tested for their hydrodesulphurization activity and hydrodenitrific ⁇ ation activity on a diesel feedstock.
- CC-1 comparativative catalyst 1
- the catalysts were sulfided with 5% hydrogen sulfide in hydrogen at a gas flow rate of 4.0 SCF/hr. Gas flow was established at room temperature and then the reactor temperature was increased to 204 °C for 2 hours, increased to 316 °C and held for 1 hour, and finally increased to 371°C and held for 2 hours.
- a base catalyst As a base catalyst was used a commercially available hydrotreating catalyst comprising nickel, molybdenum and phosphorous supported on a gamma alumina support.
- the base catalyst was dried at 400°C for 1 hour and 201 grams were weighed into a 400 milliliter round bottom flask and 26.5 grams of silicone fluid obtained from Dow Corning (Dow Corning 200 (50cSt) ) was used to impregnate the catalyst. After impregnation, the catalyst was then heated from 121 °C (250°F) to 538°C (1000°F) over a period of 30 minutes and then the catalyst was held at 538°C (1000°F) for 2 hours. The catalyst was then cooled to room temperature in a desiccator. The catalyst contained about 3%wt of silicon, measured as the metal. This catalyst is denoted SPC-4.
- the catalyst testing was performed in pilot scaled micro- eactors using whole pellets.
- the catalysts were loaded and sulphided in the same way as described in Example 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU81051/94A AU8105194A (en) | 1993-10-26 | 1994-10-26 | Hydrotreating catalyst and process |
EP95900092A EP0725680A1 (fr) | 1993-10-26 | 1994-10-26 | Procede et catalysateur d'hydrotraitement |
JP7512416A JPH09504228A (ja) | 1993-10-26 | 1994-10-26 | 水素処理触媒及び水素処理方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14275993A | 1993-10-26 | 1993-10-26 | |
US142,759 | 1993-10-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995011753A1 true WO1995011753A1 (fr) | 1995-05-04 |
Family
ID=22501160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/003543 WO1995011753A1 (fr) | 1993-10-26 | 1994-10-26 | Procede et catalysateur d'hydrotraitement |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0725680A1 (fr) |
JP (1) | JPH09504228A (fr) |
AU (1) | AU8105194A (fr) |
CA (1) | CA2174947A1 (fr) |
NZ (1) | NZ275799A (fr) |
WO (1) | WO1995011753A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999016547A1 (fr) * | 1997-09-30 | 1999-04-08 | Studiengesellschaft Kohle Mbh | Alkylation selective de composes aromatiques avec des oxydes mixtes microporeux modifies en surface |
WO2013175085A1 (fr) | 2012-05-24 | 2013-11-28 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur a base d'un metal du groupe viii et contenant du silicium et procede d'hydrogenation selective mettant en oeuvre ledit catalyseur |
CN111318286A (zh) * | 2018-12-13 | 2020-06-23 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
CN114433040A (zh) * | 2020-10-19 | 2022-05-06 | 中国石油化工股份有限公司 | 一种高活性加氢处理催化剂及其制备方法和应用 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2805276B1 (fr) * | 2000-02-23 | 2004-10-22 | Inst Francais Du Petrole | Procede de conversion d'hydrocarbures sur catalyseur a acidite controlee |
FI128115B2 (en) * | 2018-07-20 | 2024-08-20 | Neste Oyj | Cleaning of recycled and renewable organic material |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2280614A1 (fr) * | 1974-08-02 | 1976-02-27 | Snam Progetti | Procede de preparation d'olefines tertiaires |
EP0128721A2 (fr) * | 1983-06-09 | 1984-12-19 | Mobil Oil Corporation | Catalyseur modifié avec du silica et son application pour la production sélective de para-dialcoyl benzènes |
EP0451941A1 (fr) * | 1990-03-21 | 1991-10-16 | Mobil Oil Corporation | Catalyseur et procédé pour la préparation sélective de benzènes paradialcoyle substitués |
EP0494528A1 (fr) * | 1990-12-24 | 1992-07-15 | Exxon Research And Engineering Company | Catalyseurs sur support pour l'hydrogénation et l'hydrotraitement et procédé |
EP0551519A1 (fr) * | 1991-06-06 | 1993-07-21 | Mitsubishi Rayon Co., Ltd. | Catalyseur moule ou monte sur support possedant d'excellentes resistances mecaniques et servant a la synthese de la methacroleine et de l'acide methacrylique, et production de ce catalyseur |
EP0586196A1 (fr) * | 1992-09-01 | 1994-03-09 | JOSEPH CROSFIELD & SONS LTD. | Catalyseurs d'hydrotraitement modifiés par du silicone |
-
1994
- 1994-10-26 CA CA 2174947 patent/CA2174947A1/fr not_active Abandoned
- 1994-10-26 EP EP95900092A patent/EP0725680A1/fr not_active Withdrawn
- 1994-10-26 WO PCT/EP1994/003543 patent/WO1995011753A1/fr not_active Application Discontinuation
- 1994-10-26 AU AU81051/94A patent/AU8105194A/en not_active Abandoned
- 1994-10-26 JP JP7512416A patent/JPH09504228A/ja active Pending
- 1994-10-26 NZ NZ27579994A patent/NZ275799A/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2280614A1 (fr) * | 1974-08-02 | 1976-02-27 | Snam Progetti | Procede de preparation d'olefines tertiaires |
EP0128721A2 (fr) * | 1983-06-09 | 1984-12-19 | Mobil Oil Corporation | Catalyseur modifié avec du silica et son application pour la production sélective de para-dialcoyl benzènes |
EP0451941A1 (fr) * | 1990-03-21 | 1991-10-16 | Mobil Oil Corporation | Catalyseur et procédé pour la préparation sélective de benzènes paradialcoyle substitués |
EP0494528A1 (fr) * | 1990-12-24 | 1992-07-15 | Exxon Research And Engineering Company | Catalyseurs sur support pour l'hydrogénation et l'hydrotraitement et procédé |
EP0551519A1 (fr) * | 1991-06-06 | 1993-07-21 | Mitsubishi Rayon Co., Ltd. | Catalyseur moule ou monte sur support possedant d'excellentes resistances mecaniques et servant a la synthese de la methacroleine et de l'acide methacrylique, et production de ce catalyseur |
EP0586196A1 (fr) * | 1992-09-01 | 1994-03-09 | JOSEPH CROSFIELD & SONS LTD. | Catalyseurs d'hydrotraitement modifiés par du silicone |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999016547A1 (fr) * | 1997-09-30 | 1999-04-08 | Studiengesellschaft Kohle Mbh | Alkylation selective de composes aromatiques avec des oxydes mixtes microporeux modifies en surface |
WO2013175085A1 (fr) | 2012-05-24 | 2013-11-28 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur a base d'un metal du groupe viii et contenant du silicium et procede d'hydrogenation selective mettant en oeuvre ledit catalyseur |
CN111318286A (zh) * | 2018-12-13 | 2020-06-23 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
CN111318286B (zh) * | 2018-12-13 | 2023-08-01 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
CN114433040A (zh) * | 2020-10-19 | 2022-05-06 | 中国石油化工股份有限公司 | 一种高活性加氢处理催化剂及其制备方法和应用 |
CN114433040B (zh) * | 2020-10-19 | 2023-09-01 | 中国石油化工股份有限公司 | 一种高活性加氢处理催化剂及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
JPH09504228A (ja) | 1997-04-28 |
NZ275799A (en) | 1997-03-24 |
CA2174947A1 (fr) | 1995-05-04 |
EP0725680A1 (fr) | 1996-08-14 |
AU8105194A (en) | 1995-05-22 |
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