WO1995009218A1 - Procede de conversion de dechets organiques et de melanges d'hydrocarbures secondaires en carburant - Google Patents

Procede de conversion de dechets organiques et de melanges d'hydrocarbures secondaires en carburant Download PDF

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Publication number
WO1995009218A1
WO1995009218A1 PCT/RU1994/000220 RU9400220W WO9509218A1 WO 1995009218 A1 WO1995009218 A1 WO 1995009218A1 RU 9400220 W RU9400220 W RU 9400220W WO 9509218 A1 WO9509218 A1 WO 9509218A1
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WO
WIPO (PCT)
Prior art keywords
gasoline
gas
pressure
raw materials
small
Prior art date
Application number
PCT/RU1994/000220
Other languages
English (en)
Russian (ru)
Inventor
Kazimira Gavrilovna Ione
Viktor Georgievich Stepanov
Gennady Viktorovich Echevsky
Vladislav Mikhailovich Mysov
Original Assignee
Institut Kataliza Imeni G.K.Boreskova Sibirskogo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institut Kataliza Imeni G.K.Boreskova Sibirskogo filed Critical Institut Kataliza Imeni G.K.Boreskova Sibirskogo
Priority to NL9420032A priority Critical patent/NL9420032A/nl
Priority to DE4497286T priority patent/DE4497286T1/de
Priority to KR1019960701660A priority patent/KR100293908B1/ko
Publication of WO1995009218A1 publication Critical patent/WO1995009218A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Definitions

  • the methods of disposal of the above-mentioned raw materials are known by means of distribution, compression of (1.2) incineration, and pumping into the land (3).
  • the duration of the intergenerational conversion of such a catalytic converter is up to 20 to 70 hours depending on the rate
  • the essence of the proposed method is to utilize all of the aforementioned organic waste and carbohydrate mixtures Indicated raw materials
  • She (1) has a charge of 4+ and is in a thermo-acid circuit
  • Her (2) is in a charge of 3+ and is also in a short circuit. In such a system, due to the development of a negative charge for oxygen sources,
  • Such a system has strong acid-basic properties - 10 years and is a catalyst for acid-based operation, accelerating the processing of decompression, degradation, and distillation.
  • the presence of the second main dynamic sphere (1) is not greater than the other one (2), for example
  • Example 1 ( ⁇ Segment 1 ( ⁇ Segment 1).
  • the gas fraction of the ⁇ -140 C gas condensate with an immediate number of (04) 68 ⁇ (optional) is contacted at a temperature of 420 ° ⁇ ,
  • She (1) has a charge of 4+ and is in a tetrahedral oxygen supply
  • She (2) has a charge of 3+ and also
  • the second is a dynamic field that (1) is present
  • the catalyst is prepared in the following way: ⁇ 43.1 g 10% of the land (0.54 wt.% - ° '32.45 wt.% 0 ⁇ and
  • the resulting gel is heated in an autoclave at 170 ° C for 4-6 hours.
  • ⁇ is ⁇ alliz ⁇ vanny ⁇ du ⁇ ⁇ myvayu ⁇ v ⁇ d ⁇ y ⁇ izby ⁇ a schel ⁇ chi, za ⁇ em, ⁇ dve ⁇ gayu ⁇ ⁇ b ⁇ ab ⁇ e 0.1N ⁇ as ⁇ v ⁇ m ⁇ 0., ⁇ i ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e 90 C.
  • PRINCIPLE 5 It is similar to Example 3.
  • the catalyst is prepared by the following method. ⁇ 20 ml of crustemol (30.9 wt.% 0-, 0.4 wt.% 2 ⁇ and 68.7 wt.% ⁇ _0) are investigated
  • the industrial product is filtered, washed, the water is processed by 0.1 n of the processing ⁇ _ ⁇ . ⁇ i ⁇ em- 5 ⁇ e ⁇ a ⁇ u ⁇ e 95 C. ⁇ echenie 3 chas ⁇ v, ⁇ myvayu ⁇ v ⁇ d ⁇ y d ⁇ neutron ⁇ aln ⁇ y ⁇ , ⁇ b ⁇ aba ⁇ yvayu ⁇ ⁇ as ⁇ v ⁇ m s ⁇ ley ⁇ ZE or sul ⁇ - ⁇ isl ⁇ , sn ⁇ va ⁇ myvayu ⁇ v ⁇ d ⁇ y, susha ⁇ ⁇ i ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e 110 ° C, and binder g ⁇ anuli ⁇ uyu ⁇ s ⁇ ⁇ dve ⁇ gayu ⁇ ⁇ a ⁇ v ⁇ y ⁇ b ⁇ ab ⁇ e ⁇ i ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e 550 C for 0.5 hours. ⁇ a
  • PRINCIPLE 6 It is similar to Example 4. Use catalysis-
  • the process is driven by a water and a temperature of 400 C, a pressure of 2.0 PSa, a weighted rate of raw material supply of 0.4 hours and a volumetric flow rate of 3000 hourly output.
  • the degree of conversion of all organic substances is 100%.
  • the yield of gasoline produced by commercially available raw materials is 64.5% (21.2% of industrial water, 14.3% of hydrocarbon gases).
  • the calculated total gasoline fraction is at least 76 ⁇ . 10.
  • the yield of gasoline from the sale of raw materials is 62.3%.
  • Example 12 Raw materials for the production of gasoline fractions use gas-containing gases (typical, in-gas gases, gas condensing gases), which are supplied with gas, are free of charge.
  • the distribution of raw materials at the entrance to the first reaction is equal to 300 C, the temperature drop is at a constant input to the output of 120%
  • the raw material input at the input of the second reactant is 360-5 380 C, the output is at a constant temperature of 60%, and the Trust ⁇ du ⁇ m ⁇ nve ⁇ sii ⁇ le ⁇ in ⁇ s ⁇ de ⁇ zhaschi ⁇ gaz ⁇ v yavlyae ⁇ sya uglev ⁇ d ⁇ dny ⁇ ndensa ⁇ , vy ⁇ i ⁇ ayuschy ⁇ edela ⁇ at 40-230 0 C.
  • Example 13 It is similar to Example 12. It is different from the fact that the process is subject to a pressure of 0.9 ⁇ Pa, with a volume of supply of raw materials of 1250 hours.
  • the raw material input at the inlet to the processing unit is 350–380 ° C.
  • the differential circuit at the input to the catalytic converter is 150–180 ° ⁇ .
  • the degree of conversion of olefins is 95%.
  • Example 14 The quality of raw materials for the production of high-quality components of gasoline uses foodstuffs as a food product. This fraction contains 94% of ethyl alcohol, other esters, aldehydes, water. Sy ⁇ e ⁇ ev ⁇ aschayu ⁇ on ⁇ a- ⁇ aliza ⁇ e ⁇ ⁇ ime ⁇ u 3 ⁇ ; ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e and 370 C, a pressure of 1, 0 ⁇ Pa ⁇ i ves ⁇ v ⁇ y s ⁇ s ⁇ i ⁇ dachi zhid ⁇ g ⁇ sy ⁇ ya 2 h- ⁇ .0 Pe ⁇ e ⁇ ad ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y in ⁇ ea ⁇ e s ⁇ s ⁇ avlyae ⁇ 60 C.
  • Pavlova S.P., ⁇ ai ⁇ v ⁇ .I., Paak D. ⁇ . Conventional gas treatment of gas condensates with the production of fuel. - Gas production and gas processing and gas processing. - ⁇ . , ⁇ IIEgaz ⁇ admir, 1982, vyp. 3, p. 1-47.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Les déchets organiques et les mélanges d'hydrocarbures secondaires sont mis en contact avec un catalyseur dans des conditions de température et de pression élevées en présence ou non de l'hydrogène. Le catalyseur est constitué de systèmes d'oxyde binaire d'éléments des groupes III, IV, V et VI, se présentant sous la forme d'une enveloppe dotée d'un système de canaux de dimensions moléculaires, l'enveloppe présentant une substitution isomorphe de cations d'une charge 4+ sur des cations ayant une charge 3+, avec a) pas plus d'un cation d'un élément de substitution isomorphe dans la seconde sphère coordonnée d'atomes de silicium dans le réseau cristallin, et b) virtuellement aucun cation d'éléments de substitution isomorphe, ou des formations d'oxydes (non-phase) de ceux-ci, de l'enveloppe sur la surface externe de cristaux.
PCT/RU1994/000220 1993-09-29 1994-09-27 Procede de conversion de dechets organiques et de melanges d'hydrocarbures secondaires en carburant WO1995009218A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NL9420032A NL9420032A (nl) 1993-09-29 1994-09-27 Werkwijze voor het verwerken van organisch afvalmateriaal en koolwater- stofmengsels van lagere afkomst in motorbrandstof.
DE4497286T DE4497286T1 (de) 1993-09-29 1994-09-27 Verfahren zur Verarbeitung von organischen Abfällen und Kohlenwasserstoffgemischen sekundärer Herkunft zu Motorkraftstoffen
KR1019960701660A KR100293908B1 (ko) 1993-09-29 1994-09-27 유기폐기물과2차의탄화수소혼합물을모타연료로가공하는방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU93046140/04A RU2082748C1 (ru) 1993-09-29 1993-09-29 Способ получения жидких моторных топлив
RU93046140 1993-09-29

Publications (1)

Publication Number Publication Date
WO1995009218A1 true WO1995009218A1 (fr) 1995-04-06

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ID=20147831

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU1994/000220 WO1995009218A1 (fr) 1993-09-29 1994-09-27 Procede de conversion de dechets organiques et de melanges d'hydrocarbures secondaires en carburant

Country Status (6)

Country Link
KR (1) KR100293908B1 (fr)
CN (1) CN1134719A (fr)
DE (1) DE4497286T1 (fr)
NL (1) NL9420032A (fr)
RU (1) RU2082748C1 (fr)
WO (1) WO1995009218A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106701148B (zh) * 2015-07-17 2018-05-18 中国石油化工股份有限公司 一种催化裂化工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4090981A (en) * 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4093560A (en) * 1976-05-20 1978-06-06 Mobil Oil Corporation Ultra high silicon-content zeolites and preparation thereof
US4632739A (en) * 1985-07-19 1986-12-30 Lavalley Industrial Plastics, Inc. Electrolytic cell head with replaceable insert and method of protecting the same
US4663025A (en) * 1986-08-14 1987-05-05 Phillips Petroleum Company Catalytic cracking processes

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1007991B (zh) * 1984-12-18 1990-05-16 联合碳化公司 用含铝硅磷酸盐分子筛催化剂的加氢裂化法
US4867863A (en) * 1988-03-29 1989-09-19 Mobil Oil Corporation Resid catalytic cracking process utilizing ZSM-5 for increased gasoline octane
US5275720A (en) * 1990-11-30 1994-01-04 Union Oil Company Of California Gasoline hydrocracking catalyst and process
US5098555A (en) * 1991-01-24 1992-03-24 Mobil Oil Corp. Use of SZM-57 in catalytic cracking for gasoline octane improvement and co-production of light olefins

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4093560A (en) * 1976-05-20 1978-06-06 Mobil Oil Corporation Ultra high silicon-content zeolites and preparation thereof
US4090981A (en) * 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4632739A (en) * 1985-07-19 1986-12-30 Lavalley Industrial Plastics, Inc. Electrolytic cell head with replaceable insert and method of protecting the same
US4663025A (en) * 1986-08-14 1987-05-05 Phillips Petroleum Company Catalytic cracking processes

Also Published As

Publication number Publication date
KR100293908B1 (ko) 2001-11-14
DE4497286T1 (de) 1996-09-26
CN1134719A (zh) 1996-10-30
NL9420032A (nl) 1996-11-01
KR960705000A (ko) 1996-10-09
RU2082748C1 (ru) 1997-06-27

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