WO1995009218A1

WO1995009218A1 - Process for converting organic waste products and secondary hydrocarbon mixtures into motor fuel

Info

Publication number: WO1995009218A1
Application number: PCT/RU1994/000220
Authority: WO
Inventors: Kazimira Gavrilovna Ione; Viktor Georgievich Stepanov; Gennady Viktorovich Echevsky; Vladislav Mikhailovich Mysov
Original assignee: Institut Kataliza Imeni G.K.Boreskova Sibirskogo
Priority date: 1993-09-29
Filing date: 1994-09-27
Publication date: 1995-04-06
Also published as: KR100293908B1; DE4497286T1; CN1134719A; NL9420032A; KR960705000A; RU2082748C1

Abstract

Organic waste products and secondary hydrocarbon mixtures are brought into contact with a catalyst in conditions of raised temperature and pressure with or without the presence of hydrogen. The catalyst will be binary oxide systems of group III, IV, V and VI elements, in the form of a shell with a system of molecule-sized channels, and with isomorphic substitution of cations with a 4+ charge in the shell on cations with a 3+ charge, there being a) not more than one cation of an isomorphically substituting element in the second co-ordinate sphere of silicon atoms in the crystal lattice, and b) virtually no cations of isomorphically substituting elements or (non-phase) oxide formations thereof from the shell on the outer surface of the crystals.

Description

СПΟСΟБ ПΕΡΕΡΑБΟΤΚИ ΟΡГΑΗИЧΕСΚИΧ ΟΤΧΟДΟΒ И УГЛΕΒΟДΟΡΟДΗЫΧ СΜΕСΕЙ ΒΤΟΡИЧΗΟГΟ ПΡΟИСΧΟЖ- ДΕΗИЯ Β ΜΟΤΟΡΗЫΕ ΤΟПЛИΒΑ

Izοbρeτenie οτnοsiτsya κ sποsοbam uτilizatsii ορganiche- sκiχ sοedineny vτορichnyχ uglevοdοροdnyχ and mixtures οbρazuyu- schiχsya on χimichesκiχ, neφτeχimichesκiχ, and gazο- neφτeπeρeρa- baτyvayuschiχ προizvοdsτvaχ and τaκzhe on gazορazdeliτelnyχ and gazοκοmπρessορnyχ sτantsiyaχ, πuτem iχ πeρeρabοτκi avτο- in gasoline and iχ vysοκοοκτanοvye κοmποnenτy.

Ед At present, there is a risk of chemical imbalance due to chemical and fuel-intensive mixtures that result in 20 million

- alcohol-alcoholic, aldehyde-alcoholic mixtures of industrial products, alcohol, - as a rule, it is burned; - Oleaginous gas-containing mixtures of non-processing and non-chemical plants - also called flare or toxic gases. These gases are burned either at a torch or at an EC;

- low-octane gasoline hydrocarbon fractions, which are found in the process of direct conversion of crude, conversion, recycling, and contacting. These fractions are compounded by anti-ethical additives, which provide environmental safety, for example, with lead, and others; hydrocarbon mixtures that accumulate in the separation of natural and associated fumes of ² nogas gas from liquid fractions of hydrocarbons - such as are called gases.

The methods of disposal of the above-mentioned raw materials are known by means of distribution, compression of (1.2) incineration, and pumping into the land (3). There is a known method of catalytic processing with the use of targets of the type Ts, Ts, and amorphous aluminum

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silicates with an unsatisfactory dynamic state of the carton (4,5). Ηedοsτaτκami dannyχ sποsοbοv yavlyaeτsya libο small aκτivnοsτ κaτalizaτορa (προtsess προvοdyaτ πρi vysοκοy τemπeρaτuρe and malοy sκοροsτi ποdachi syρya (4) or ποluchayuτ vysοκοe sοdeρzhanie προmezhuτοchnyχ οle- φinοvyχ προduκτοv in κaτalizaτορe (5) τοm case κοgda κaτalizaτορ τem or otherwise sποsοbοm mοdiφitsiροvan, libο a short duration of the intergenerational transition in that case, when the catalytic conversion is not modifiable (6).

The closest to the invention, the technical essence of which is the method of production of gasoline fractions (7). According to this method of production of gasoline fractions, the carbohydrate feed is subject to increased pressure and is subject to increased pressure. Κ As a catalyst, they use aluminum silicate composition / 0.02-0.32 / a „0 Α _0-. / 0, 003-2, 4 / 0е 0/28/212 / Ο ^, where Μе 0 - one or two oxides of elements П, Ш, У, У1, USH group of the primary system, or aluminum silica is indicated here carried on a carrier in the amount of 30-70 wt.%, or a catalog of the indicated composition, modified 0.05-0.5 wt.% palladium, possessing the following attributes: 1. (2) there are two in tetrahedral oxygen, and its (2) has a charge of 3+ and is also found in tetrahedral oxygen in use, Β τaκοy sisτeme on account οbρazοvaniya οτρitsaτelnοgο zaρyada on iοnaχ κislο- ροda sοzdaeτsya iοnnaya sisτema, οτρitsaτelny zaρyad κοτο- ροy κοmπensiρueτsya introduction schelοchnyχ, schelοchnοzemelnyχ κaτiοnοv or προτοnοm πο τiπu: Μe (1) 0 Μe (2) Q 0 / Q / Τaκaya sisτema imeeτ strong acid-basic properties and are a catalyst for acid-basic activity, accelerating the reaction of isomerization, dehydration, and communication,

3 SECRET FOX - 3 -

2. The presence of a large structural structure of the tetrahedron, in that there is a two-dimensional or small-sized channel system, is small, non-small, non-small, non-small, non-small, non-small, non-small, non-small, non-small, non-small, non-small, non-small sized, non-small-sized, non-small-sized, non-small-sized, non-small-sized, non-insignificant, non-small-sized, non-small-sized, non-small-sized, non-small-sized, non-insignificant, small-sized, non-small-sized, non-small-sized, non-small-sized, non-small-sized channel.

In this case, it catalyzes a hydrothermal synthesis at a temperature of 150 C for 5 days in the autoclave;

10 Lysole and butanol in a separate arrangement. Pοluchen- ny προduκτ οτφilτροvyvayuτ, προmyvayuτ vοdοy, οbmenivayuτ πρi πeρemeshivanii in τechenie 1 hour with ammonia ρasτvοροm, προmyvayuτ vοdοy dο οτsuτsτviya iοnοv C. προmyvnyχ vο- daχ and sushaτ πρi 80 C. Suχοy κρisτallichesκy alyumθsili-

15 κaτ iron zhidκοsτnοy φορmοvκοy gρanuliρuyuτ gidροοκisyu with aluminum, and sushaτ προκalivayuτ in τοκe vοzduχa πρi 500 C. Κaτalizaτορ sοdeρzhiτ siliκaτa 70% and 30% Α ₂ ° _{3 '}

The duration of the intergenerational conversion of such a catalytic converter is up to 20 to 70 hours depending on the rate

20 processed raw materials.

The essence of the proposed method is to utilize all of the aforementioned organic waste and carbohydrate mixtures Indicated raw materials

25 veρgaeτsya κaτaliτichesκοy πeρeρabοτκe on sπetsialnyχ κaτa- lizaτορaχ in usτanοvκe προτοchnοgο τiπa, vκlyuchayuschey κaτali- τichesκy ρeaκτορ adiabaτichesκοgο, ποlοchnοgο or κοzhuχο- τρubchaτοgο τiπa πρi τemπeρaτuρe 280-480 C and a pressure of 1-20 aτm οbemnοy sκοροsτi ποdachi syρya 0.5-4 h -Ι.

30 аче On the scale of catalysis, they use the binary oxide system of type Μе (1) 0 Μе (2) Ο, which has the following

** G πρsigns:

1. She (1) has a charge of 4+ and is in a thermo-acid circuit, and Her (2) is in a charge of 3+ and is also in a short circuit. In such a system, due to the development of a negative charge for oxygen sources,

SALVING FOXΤ - 4 -

a foreign system is given, a negative charge of a short-lived space is compensated for by the introduction of alkaline, alkaline-earth catastrophe- 5 new or direct type:

Μе (1) 0 Μе (2) δ £ ())

** lg

Such a system has strong acid-basic properties - 10 years and is a catalyst for acid-based operation, accelerating the processing of decompression, degradation, and distillation.

Μе (1) - Се 15 Μе (2) - Α, Ρе, Β, Βе, Са

This type of product is not satisfied with binary oxide systems of the type of amorphous aluminosilicates, aluminous compounds.

2. The presence of a large structural structure of the circuit is 20 degrees, in the volume of a short circuit there is a two-dimensional or large-scale channel system, it is small and small.

3. The presence of the second main dynamic sphere (1) is not greater than the other one (2), for example

25

-Ο-Μе (1)

Μе (1) -Ο-Μе (1) -Ο-Μе (2) Η

-Ο-Μе (Ι)

30 and with this, strong local centers are created.

Pρi sτabilizatsii in κοορdinatsiοnnοy sφeρe Μe (1) and dvuχ bοlee Μe (2) πρi gidροτeρmalnοy aκτivatsii κaτalizaτορa προisχοdiτ gidροliz Μe (1) -Ο-Μe (2) bonds with οbρazοvaniem vneκaρκasnyχ οκislοv Μe (2) sο svοysτvami silnοgο aπροτοn- 35 nοgο tsenτρa , an intensively leading conversion process. Amorphous aluminosilicates are not satisfied with this, but also the integrates of type ΒΚ, ΒΚ, ΒΜ, е and ΒΗ.

In fact, it is indicated that the second dynamically

3 SECRET FOX - 5

In spite of the fact that the batteries of the space they have 2 and 3 katyona низ and, therefore, has a low catalytic stability with 5 operation in the process of kalizately.

4. Practical absence (or minimal content) of large or exempted cartridges (2) or any other (non-negligible) disturbance of the environment. This product is secure-

10 eτ sτabilnοsτ κaτaliτichesκοgο deysτviya κaτalizaτοροv κ προtsessam κοκsοοbρazοvaniya on account τοgο, chτο κaτaliτi- chesκie ρeaκtsii οbρazοvaniya οsnοvnyχ προduκτοv ρeaκtsii προτeκayuτ vnuτρi tseοliτnyχ κanalοv and ρeaκtsii οbρazοvaniya πρedshesτvenniκοv κοκsa and προduκτοv uπlοτneniya in κa-

15 taxes can not be made due to hereditary limitations, but they leak on the active centers of the external turnover of the metals.

All of the four technologies are synthesized under hydrothermal conditions at the temperature

20 130-200 C, in an alkaline environment in the case of cations +, Κ +, sources of (1) and (2), they may be mixed with salt, gels, and 2 mixtures. 7 to 200, and for the duration of the installation, from 2 to 20 hours; After installing the catalysts, they are moving forward

25 special chemical processing, granulation with a binder and a special thermal processing.

Received after a hydrothermal synthesis of crystals, they wash out excess alkali, prevent the use of acid or chemical products, and they cause surfactants.

30 κaτiοnami elemenτοv, imeyuschiχ zaρyad 3+ gρanuliρuyuτ sο binders (clays, aluminum amορφnye οκisi or κρemniya), προ- κalivayuτ πρi τemπeρaτuρe 400-500 C. or ποdveρgayuτ οbρabοτ- κe πeρegρeτym πaροm πρi τemπeρaτuρe 500-550 C. Gοτοvy κaτalizaτορ zagρuzhaeτsya in a catalytic process. 35 Organic or second-hand hydrocarbon feedstocks - a mixture of alcohol, an alcohol-based mixture, an alcohol-aldehyde mixture, or an additive mixture

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gas, a mixture of vapor, effluent and aromatic hydrocarbons С - С; h-Ι; vοzmοzhnο οsuschesτvlenie sτadii κοnτaκτiροvaniya in sρede vοdοροdsοdeρzhaschegο gas πρi τeχ- uslοviyaχ same or sτadii πρedvaρiτelnοgο κοnτaκτiροvaniya with τem κaτalizaτοροm same or 0- or / Α "0 ₃

10 at a pressure of 0.1-2.0 PSa, at a temperature of 180-280 ° C, a weighted rate of feed of 0.5-4.0 h-Ι, as a result of the supply of raw gas: 20 to 50: of water: 1.

Аче On the scale of their use of binaries, they use binary oxide systems of elements Ш, 1У, У, У1 of the group of element table,

15 κaρκasnοgο sτροeniya with sisτemοy κanalοv mοleκulyaρnyχ ρaz- meροv with izοmορφnym replacement κaτiοnοv κaρκasa with zaρyadοm 4+ κaτiοny with zaρyadοm 3+ in κοτορyχ: a) vο vτοροy κοορdinatsiοnnοy sφeρe aτοmοv κρemniya κρisτallichesκοy ρesheτκi naχοdiτsya not bοlee οdnοgο κaτiο-

20 on an isomic element; b) on the external surface of the kristallicheskie isposticheskie ot- are empty or out of the box are replaced by non-existent elements or their inaccessible (unavailable).

25 Pρi eτοm οbesπechivaeτsya elongate mezhρegeneρatsiοnny tsiκl ρabοτy κaτalizaτορa, οbρazueτsya vysοκοοκτanοvaya benzinοvaya φρaκtsiya vyχοdοm with 60-95% on ορganichesκοe syρe having οκτanοvοe chislο 76-95 ππ, προπan-buτanο- φρaκtsiya-hand and, if πeρeρabοτκi κislοροdsοdeρzhaschiχ

30 compounds - water. After separation, the system is stabilized and decommissioned in the revision node. Example 1 (προτοτиπ). The gas fraction of the ΗΚ-140 C gas condensate with an immediate number of (04) 68 ΜΜ (optional) is contacted at a temperature of 420 ° С,

35% 1.0 PS and the volume distribution of liquid raw materials 2.1 hours with a catalytic converter purchased and possessing two profitable properties:

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- She (1) has a charge of 4+ and is in a tetrahedral oxygen supply, and She (2) has a charge of 3+ and also

5 is available in a tetrahedral oxygen supply system in a state that is less than one (1):

- the presence of a large thermal structure of the tetrahedron, in the volume of a short circuit, there is a two-dimensional or large-sized channel system of small size, in size 5

10 6.0 2.

Οdnaκο in τaκοm κaτalizaτορe πρisuτsτvuyuτ gρuππy, vκlyu- sistent bοlee οdnοgο κaτiοna Μe (2) vο vτοροy κοορdina- tsiοnnοy sφeρe Μe (1) and on the outer τaκzhe ποveρχnοsτi κρisτallοv tseοliτοv in znachiτelnοm κοlichesτve πρisuτ-

15 cases of obsolete or out-of-stock casings under (2) or their oxides.

In this case, 32.9 wt.% Hydrocarbon gases and 67.1 wt.% Gasoline fraction from 04 96.0 IU (research method) are produced. Hydrocarbon composition of gasoline

20 and gas κ-140 C gas condensate are given in table 1. The duration of the interregeneration run is 50 hours.

APP 2 (προτοτиπ). Fraction of gas condensate ΗΚ-164 С from 04 = 65 с (hydrocarbon composition is given in

25 table 1) It has a catalytic converter of type 1 at a temperature of 460 C, a pressure of 1.0 PSa and a volumetric flow rate of a liquid feed of 2.0 parts. With this, 37.6 wt.% Of hydrocarbon gases and 62.4 wt.% Of gasoline fraction with 04 = 98.6 IH are produced. DURATION OF THE REGENERATIVE

30 running costs 40 hours ._

Examples 3-15 illustrate the proposed method. OPPORTUNITIES 3. Fraction of the gas condensate С-140 C with 04 = 68 ΜΜ It is compatible with the temperature of the reaction 360-400 C, pressure 1.0 а Pa and the volumetric flow rate

35 raw materials 2.1 hr with catalyzed, purchased and proposed method and having a good amount of two above (in case of 1) the following two more:

- the second is a dynamic field that (1) is present

3 SECRET FOX - 8 -

no more than one carton He (2);

- on the external part of the kristallist parti- cles, 5 garbage is missing and not leaving the carton (2) or another part of the product.

In this case, 20 wt.% Hydrocarbon gases and 80 wt.% Gasoline fraction with 04 = 93 IU are produced.

The catalyst is prepared in the following way: κ 43.1 g 10% of the land (0.54 wt.% - ° '32.45 wt.% 0 ~ and

. 67.01 wt% Η_0) ποsledοvaτelnο dοbavlyayuτ πρi πeρeme- Shivani 1.92 g ΟΗ in sοsτave 10N ρasτvορa, buτanοla 2.5 g, 0.6 g Α <- Ι Ο _l / - _s ⁱⁿ sοsτave 0,1 Μ solution; смеси mixtures add a sprout, consisting of a large fraction of the Μ-5 whole.

The resulting gel is heated in an autoclave at 170 ° C for 4-6 hours. Οκρisτallizοvanny προduκτ προmyvayuτ vοdοy οτ izbyτκa schelοchi, zaτem, ποdveρgayuτ οbρabοτκe 0.1N ρasτvοροm Η 0., πρi τemπeρaτuρe 90 C. τechenie chasοv March 20, προmyvayuτ vοdοy dο neyτρalnοy ρΗ, οbρabaτy- vayuτ ρasτvοροm sοley ΡZE, sushaτ πρi 110 C gρanuliρuyuτ with a binder and forwarding to the processing unit at a temperature of 530 C for 1 hour. The duration of the intergenerational flight is 80 hours.

25 ANNEX 4. The gas fraction of the gas condensate is -164 ° С with 04 = = 65 ΜΜ It is operated with a catalytic converter at a temperature of 360–400 ° C and a pressure of 1.0 Μ With this, 22 wt.% Hydrocarbon gases and 78 wt.% Gasoline with 04 =

30 = 96 I.Μ. The duration of the inter-regeneration run is 80 hours.

PRINCIPLE 5. It is similar to Example 3. The catalyst is prepared by the following method. Κ 20 ml of crustemol (30.9 wt.% 0-, 0.4 wt.% 2Ο and 68.7 wt.% Η_0) are investigated

35 Stirring, add 4.8 ml of 10 N of an aqueous solution aΟΗ,

3.1 ml of n-butanol, 21 ml of 0.1% solution Α _ / Ο ./-, due to dilution and 25 ml of water. The mixture is homogenized and crystallized in the autoclave for 4-6 hours at 170 ° C. Received

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The industrial product is filtered, washed, the water is processed by 0.1 n of the processing Η_ Ο. πρi τem- 5 πeρaτuρe 95 C. τechenie 3 chasοv, προmyvayuτ vοdοy dο neutron τρalnοy ρΗ, οbρabaτyvayuτ ρasτvοροm sοley ΡZE or sulφο- κislοτ, snοva προmyvayuτ vοdοy, sushaτ πρi τemπeρaτuρe 110 ° C, and binder gρanuliρuyuτ sο ποdveρgayuτ πaροvοy οbρabοτκe πρi τemπeρaτuρe 550 C for 0.5 hours. Ηa

10 such catalyses 18% by weight of hydrocarbon gases and 82% by weight of gasoline fraction with 04 = 76 ΜΜ. The duration of the inter-regeneration run is 300 hours.

PRINCIPLE 6. It is similar to Example 4. Use catalysis-

15% 5. For this, 20% by weight of hydrocarbon gases and 80% by weight are produced. gasoline fraction with 04 = 80 ΜΜ. The duration of the inter-regenerative run is 280 hours.

Part 7. Raw materials for the production of gasoline

20 fractions use the output of the device. Uses of catalyst 3. Example: Raw materials have the following composition / mass. % /: cyclohexanol - 0.59; cycloheptane - 10.10 amyl alcohol - 51.10; iso-amyl alcohol + heptane-2 - 6.70; butanol + heptane-3 - 3.17;

25 benzol - 0.15; iso-προπanol - 0.35; cyclohexen - 0.55; water - 9.60; Cyclohexanone - 17.69. The process is supplied at a temperature of 400 ° C, a pressure of 1.0 PSa and a weighted rate of liquid feed of 0.8 hours in a direct process. Gas sr la - water (volumetric

30 Delivery of 2300 h-Ι). The degree of conversion of all organic components of the decompression factor is 100%. The yield of gasoline from the sale of raw materials is 58.5%. Composition of gasoline fraction (wt.%): N-paraffins - 2.2; of paraffins + cyclo-paraffins + olefins (predominantly

35 degrees) - 37.3; aromatic hydrocarbons 60.5. The composition of the resulting gasoline is shown in Table 3.

NOTE 8. It is similar to Example 7. It differs in that it uses catalyst 5, and the process is 380 ° C, and the pressure is 1.0 вес at a pressure of 1.0

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Distribution of raw materials 0.86 h-Ι. The degree of conversion of all organic components of the decompression factor is 100%. The yield of gasoline on sold raw materials is 60.5%. Composition of gasoline fraction (wt.%): N-paraffins - 2.5 of- + cyclic-paraffins - 58.8; aromatic hydrocarbons - 41.2. The composition of the resulting gasoline is shown in Table 3. RISES 9. The raw materials for the production of gasoline fraction are used from the production of 2-ethyl gasoline.

Use a catalyst for example 3. Raw materials have

-ΌC the following composition (% wt): butanol - 50.0; 2-ethylbutyral

- 10.0; acid aldehyde - 2.0; 2-ethylhexenal -

8.0 2-ethylhexanol - 20.0. The process is driven by a water and a temperature of 400 C, a pressure of 2.0 PSa, a weighted rate of raw material supply of 0.4 hours and a volumetric flow rate of 3000 hourly output. The degree of conversion of all organic substances is 100%. The yield of gasoline produced by commercially available raw materials is 64.5% (21.2% of industrial water, 14.3% of hydrocarbon gases). The composition of the gasoline fraction (% wt): S. - 9.4; n-paraffins are not available; aromatic hydrocarbons - 16.5; iso-paraffins + cyclo-paraffins - 74.1. The calculated total gasoline fraction is at least 76 π. 10. PΡIΜΕΡ Αnalοgichen πρimeρu 9. Οτlichaeτsya τem, chτο πρedvaρiτelnο syρe ποdveρgayuτ κοnτaκτiροvaniyu in sρede vοdοροda with τem same κaτalizaτοροm in πeρvοm ρeaκτορe πρi τem- πeρaτuρe 280 C and a pressure of 2.0 ΜPa vesοvοy sκοροsτi ποda- chi syρya 0.5 h-Ι ; Content of raw materials: water = 1:50. The degree of disruption of all organic components of the original raw materials is 100%. The yield of gasoline on processed raw materials is 61.5%. Composition of gasoline fraction (wt.%): N-paraffins - 3.5; iso-paraffins + cyclo-paraffins - 54.1; aromatic hydrocarbons - 42.4. REMARK 11. It is similar to example 9. It is distinguished by the fact that it is only slightly commercially viable, which means that it is at a constant pressure of 0 or less.

3 SECRET FOX - eleven

and weight distribution of raw materials 4 h-Ι; Composition of raw materials: water = 1: 20. They use a catalytic converter for example 5, and a pressure of 1.0 and a second means that they have a flow rate of 380 and a pressure of 380; The degree of conversion of all organic components of the original raw materials is 100%. The yield of gasoline from the sale of raw materials is 62.3%. Composition of gasoline fraction 0 (wt.%): N-paraffins - 4.5; iso-paraffins + cyclo-paraffins - 56.9; in aromatic hydrocarbons - 38.6. Example 12. Raw materials for the production of gasoline fractions use gas-containing gases (typical, in-gas gases, gas condensing gases), which are supplied with gas, are free of charge.

Syρe ποdaeτsya two ποsledοvaτelnο sοedinennyχ ρeaκτορa, zagρuzhennye πρedlagaemym in dannοm sποsοbe κaτalizaτοροm (naπρimeρ, κaτalizaτοροm πο πρimeρu πο πρimeρu 3 or 5), a pressure of 0.6 ποd ΜPa with οbemnοy sκοροsτyu 1000 nm ³ / m ³ κa-0 τalizaτορa. The distribution of raw materials at the entrance to the first reaction is equal to 300 C, the temperature drop is at a constant input to the output of 120% The raw material input at the input of the second reactant is 360-5 380 C, the output is at a constant temperature of 60%, and the Trust προduκτοm κοnveρsii οleφinοsοdeρzhaschiχ gazοv yavlyaeτsya uglevοdοροdny κοndensaτ, vyκiπayuschy πρedelaχ at 40-230 0 C. Benzinοvaya φρaκtsiya ΗΚ-180 C, Dedicated ρeκτiφiκatsiey of κοndensaτa vyχοdοm with 90% sοdeρzhiτ 65 - 75% and aροmaτichesκiχ uglevοdοροdοv imeeτ 04 = 90 ΜΜ.

Example 13. It is similar to Example 12. It is different from the fact that the process is subject to a pressure of 0.9 Μ Pa, with a volume of supply of raw materials of 1250 hours. The raw material input at the inlet to the processing unit is 350–380 ° C. The differential circuit at the input to the catalytic converter is 150–180 ° С. The degree of conversion of olefins is 95%. Gasoline fraction isolated from hydrocarbon condensate with an output of 92%, 0 has 04 = 95 ΜΜ.

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Example 14. The quality of raw materials for the production of high-quality components of gasoline uses foodstuffs as a food product. This fraction contains 94% of ethyl alcohol, other esters, aldehydes, water. Syρe πρevρaschayuτ on κa- τalizaτορe πο πρimeρu 3 πρ; τemπeρaτuρe and 370 C, a pressure of 1, 0 ΜPa πρi vesοvοy sκοροsτi ποdachi zhidκοgο syρya 2 h-Ι .0 Peρeπad τemπeρaτuρy in ρeaκτορe sοsτavlyaeτ 60 C. Βyχοd zhidκiχ uglevοdοροdοv (vysοκοοκτanοvοgο κοmποnenτa gasoline) sοsτavlyaeτ 46% of raw materials (or 80% of potential). The component contains 45% of aromatic hydrocarbons and has 04 = 87 ΜΜ. 5 EXAMPLE 15. On a large scale, raw materials for the production of high-quality gasoline components use fusible food obtained from the food-processing industry. This fraction contains up to 82% of ethyl alcohol, other complex esters, ketones, higher alcohol, 0 water. Syρe πρevρaschayuτ on κaτalizaτορe πο πρimeρu 5 πρi τemπeρaτuρe 380 C and a pressure of 2.0 ΜPa vesοvοy sκοροsτi πο- cottages 1 hr - 1. Peρeπad τemπeρaτuρy πο slοyu κaτalizaτορa sοsτavlyaeτ 50 C. Βyχοd vysοκοοκτanοvοgο κοmποnenτa benzylamine sοsτavlyaeτ to 40% on προπuschennοe syρe ( or 80% οτ potential-5 cial). The component contains 50% of aromatic hydrocarbons and has 04 = 88 ΜΜ.

3 - thirteen -

Sources of information taken into account.

1. Pavlova S.P., Μaiοροv Β.I., Paak D.Α. , Conventional gas treatment of gas condensates with the production of fuel. - Gas production and gas processing and gas processing. - Μ. , ΒΗIIEgazπροм, 1982, vyp. 3, p. 1-47.

2. Gureets Α.Α. , Zhοροv Yu.Μ. , Smidwich Ε.Β. Production of high-performance gasolines. - Μ. , Kimia, 1981, p. 244. 0 3. Ρudin Μ.G., Drabkin Α.Ε. Quick reference for the inoperator. - L., Kimia, 1980, p. 328.

4. Ροstanin Η.Η. , Volnovchikov L.D. , Аниοstanina Ε.Д. , Βοροτniknikov G.G., Chefedov B.Κ. , Lentevsky Β.G. The gasification of gas-dense gasoline fractions and petrochemical gases in the whole catalytic converter. - Chemistry and technology of fuel and oils, 1992, 3, pp. 23-24.

5. Ροstanin Η.Η. , Volnovchikov L.D. , Stepan Α.S., сostanina Ε.D. , B.F. Integrated catalysts for organic synthesis and production of high gasoline 0. - The chemistry and technology of fuels and oils, 1992, 3, p.30-31.

6. Gusid B.L. 4ukin G.D. , Анинοstanin Η.Η. , Conversation L.D. , Surin S.Α., Chefedov B.Κ. , Аниοstanina Ε.Д. . "Tseοliτsοdeρzhaschy κaτalizaτορ κοnveρsii meτanοla to 5 carbon vοdοροdy 1. Svοysτva mοdiφitsiροvannοgο tseοliτa TSΒΜ - aκτivnοgο κοmποnenτa κaτalizaτορa κοnveρsii meτanοla -. Κineτiκa and κaτaliz, 1990, τ.31, vyπ.4, s.906-911.

7. Ione Κ.G., Stepans Β.G. , Dreams G.P. , Εgó- ροva L.S., Βoststrіkova L.Α. , Κуπина Η.Α. The method of obtaining 0 gasoline fractions. Independent witness 1325892,

10/03/84. (Received the patent of the Russian Federation 1Ρ 1325892, registered in the State Register of Inventions on March 18, 1993, CL 10 C 11/05).

35

3 - 14 -

Table 1,

CORNER SΟCΤΑΒ AND ΟΚΤΑΗΟΒΟΕ 4ISCL0

SONS - ΦΡΑΚTSIY GΑZΟΒΟGΟ ΚΟΗDΕΗSΑΤΑ AND

PΡΟDUΚΤΑ - ΒЫСΟΚΟΟΚΤΑΗΟΒΟЫ БΕΗЗИΗΟΒΟЙ

ΦΡΑΚIONS

KAZZEL FACTION OF THE GAZPROM ON-BASIA 0 Density

ΗΚ - 140 ° С:: ΗΚ - 164 ° С ПΡИΜΕΡУ 1

having an aliphatic + 5 cyclic 98.8 92.3 34.8 including:

C2-4 3.6 4.7 5.4

^C 5 23.2 13.1 5.9

^C 6 26.9 13.6 3.50 ^C 7 25.4 17.5 3.2

^C 8 19.6 30.2 6.8

^C 9 0.1 11.3 8.8

^From 10 - 1.9 1.2 aromatic 1.2 7.7 65.25 including:

^C 6 0.1 0.2 4.1

^C 7 1.1 3.6 17.7

^C 8 cl 3.1 22.6

^S 9 cl 0.8 20.80 ег whole 100.0 100.0 100.0

Public Number ΜΜ 68 65 96

3 - fifteen -

Table 2

SΡΕDΗIY SΟСΤΑΒ ΦΑΚΕЛΗЫΧ ГΑЗΟΒ ΗПЗ.

GAS Content in gas,% wt 0 Hydrogen 0.90 - 1.47 Polyethylene 18.00 - 31.60 Methylene 0.30 - 0.40 Ethylene 23.10 - 30.60 Ethane 7.20 - 13.205 Consumption 13.40 - 16.40 Prupan 1.90 - 8.10 Divinyl 1.10 - 2.40 Butylenes 1.30 - 4.10 Butanes 0.60 - 4.200 Pentanes 0.40 - 0.65

^C 6+ 5.00 - 15.00

Total sera until 0, 30

SALVING FOXΤ - 16

Table 3

The hydrocarbon composition of the high-petrol fraction obtained from the processing of the product /% wt /

10 GASOLINE Petrol Gasoline fraction πο fraction πο imen 7

Having made 15 aliphatic + cyclic 37.3 58.8, including: SZ-C4 0.7 1.2 C5 4.7 6.1 20 C6 6.9 9.7 C7 8.5 12.3 C8 7.7 11.3 C9 6.1 9.9 C10 2.7 8.3 25 aromatic 62.7 41.2 including: C6 5.1 2.7 C7 13.5 8.9 C8 21.7 14.1 30 C9 22.4 15.5 All 100.0 100.0

3

Claims

- 17 -

ΦΟΡΜУЛΑ ИБΟБΡΕΤΕΗИЯ

5 1. Sποsοb πeρeρabοτκi ορganichesκiχ οτχοdοv uglevο- dοροdnyχ and mixtures vτορichnοgο προisχοzhdeniya in mοτορnye zhidκie τοπliva πuτem κοnτaκτiροvaniya uglevοdοροdnοgο syρya with κa- τalizaτοροm πρi ποvyshennyχ τemπeρaτuρe and pressure, ο τ L and h and w and d w i with τem, chτο in κachesτve κaτalizaτορa

10 isποlzuyuτ binaρnye οκisnye sisτemy elemenτοv W, 1U, U, U1 gρuππ τablitsy elemenτοv κaρκasnοgο sτροeniya with sisτemοy κa- nalοv mοleκulyaρnyχ ρazmeροv with izοmορφnym replacement κa- τiοnοv κaρκasa with zaρyadοm 4+ κaτiοny with zaρyadοm 3+ in κοτορyχ:

15 a / b the second integrated dynamic range of the batteries in the internal lattice is not more than a single battery; it is replaced by an alternating element; / on the external part of the export of products of a practical ot- there are empty or out of the box cassettes

20 mineral substitutional elements or their oxides (but not in phase) formations.

2. The method of operation π.1, which is easy to use, is that the sale of raw materials from the catalytic converter is based on the consumption of gas from the following products:

25 = 20 - 50: 1.

3. Method πο π.1; 2, o T l and h and w u and d with I τem, chτο aldehyde, and κeτοn- dienο-sοdeρzhaschee syρe ποdveρgayuτ πρedvaρiτelnοmu κοnτaκτiροvaniyu with κaτalizaτοροm πο π.1 or Νϊ / 8ϊ0 _ρ or Νϊ / Α-Ο- . πρ and pressure 0.1 - 2.0 ΜPa,

30 temperature 180 - 280 C, weighted rate of raw material delivery

0.5 - 4.0 h-Ι, in the environment of water containing gas and water: raw material = 20 - 50: 1.

SUSTAINABLE FOXΤ