WO1995004537A1 - Cosmetic compositions - Google Patents
Cosmetic compositions Download PDFInfo
- Publication number
- WO1995004537A1 WO1995004537A1 PCT/US1994/008838 US9408838W WO9504537A1 WO 1995004537 A1 WO1995004537 A1 WO 1995004537A1 US 9408838 W US9408838 W US 9408838W WO 9504537 A1 WO9504537 A1 WO 9504537A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cosmetic composition
- composition according
- weight
- acid
- oil
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Definitions
- a foundation composition can be applied to the face and other parts of the body to even skin tone and texture and to hide pores, imperfections, fine lines and the like.
- a foundation composition is also applied to moisturize the skin, to balance the oil level of the skin and to provide protection against the adverse effects of sunlight, wind and the harsh environment.
- Make-up compositions are generally available in the form of liquid or cream suspensions, emulsions, gels, pressed powders or anhydrous oil and wax compositions.
- US Patent No. 3,444,291 discloses a method of filling and camouflaging skin cavities by applying a composition which includes 65 to 75 parts by weight of a microcrystalline wax and about 25 to 35 parts of a mineral oil.
- the composition includes a colourant, preferably a coal tar dye, for example, D &C Red No. 17, which matches the colour of the user's skin.
- a cosmetic make-up composition comprising water-in-oil emulsions comprising pigment coated with poly siloxane, a silicone phase, a water phase and a polydiorganosiloxane-polyoxyalkylene copolymeric surfactant.
- Polyvinylpyrrolidone is known for use as a solubilizing/complexing agent in a variety of compositions.
- GB-A-2, 041 ,963 discloses an aqueous detergent composition for cleansing oily skin comprising a water-soluble salt of an N-acyl ester of sarcosine, a polyvinylpyrrolidone cosolubilizer and a protein and/or protein hydrolysate.
- the composition can also contain salicylic acid as a keratolytic agent and a buffer such as citric acid/citrate.
- a cosmetic composition in the form of an emulsion, gel or lotion comprising an aqueous/alcoholic solution of an acidic anti-acne active and a pyrrolidone-based complexing agent therefor, and wherein the aqueous/alcoholic solution has a pH of less than about pK a + 1 , where pK a is the logarithmic acidity constant for the fully protonated anti-acne active.
- the cosmetic compositions of the present invention provide anti-acne efficacy together with improved product and colour stability.
- a make-up composition in the form of a water-in-oil or oil-in-water emulsion comprising an acidic anti-acne active dissolved in the aqueous phase and a pigment or mixture of pigments dispersed in the oil phase.
- the cosmetic composition according to one aspect of the present invention comprises an aqueous/alcoholic solution of an acidic anti- acne active and a pyrrolidone-based complexing agent.
- the composition is in the form of an emulsion, gel or lotion.
- a first essential component is an aqueous/alcoholic solution of an anti-acne active.
- Suitable anti-acne actives for use herein include salicylic acid, retinoic acid and its derivatives, azelaic acid and its derivatives, lactic acid, glycolic acid, pyruvic acid, flavonoids, and mixtures thereof.
- the anti-acne active used in the composition herein is preferably selected from salicylic acid and azelaic acid, and mixtures thereof, more preferably salicyclic acid.
- the anti-acne active is present at a level of from about 0.1 % to about 10% , preferably from about 0.1 % to about 5% , more preferably from about 0.5% to about 3 % , by weight of composition.
- the anti-acne active is solubilized in water or an alcoholic solution, for example, solutions based upon C2-C6 alcohols, diols and polyols, preferred alcohols being selected from ethanol, dipropylene glycol, butylene glycol, hexylene glycol, and mixtures thereof. Alcohol is preferably present in the compositions herein at a level of from about 1 % to about 20% .
- the final aqueous/alcoholic anti-acne active solution preferably has a pH at ambient temperature (25 °C) of less than about pK a + 1 , where pK a is the logarithmic acidity constant for the fully protonated anti-acne active. In preferred embodiments, the pH of the final solution is less than about pK a .
- H n A is the fully protonated acid
- n is the number of protons in the fully protonated acid
- H n _ ⁇ A is the conjugate base of the acid corresponding to loss of one proton.
- acidity constants are defined at 25 °C and at zero ionic strength.
- Literature values are taken where possible (see Stability Constants of Metal-Ion Complexes, Special Publication No. 25, The Chemical Society, London); where doubt arises they are determined by potentiometric titration using a glass electrode.
- the pH of the final aqueous/alcoholic anti-acne active solution is preferably in the range of from about 1 to about 7, more preferably from about 2 to about 5, especially from about 2 to about 4.
- the aqueous phase is preferably free of acid labile species such as acrylic acid/ethyl acrylate copolymers and polygly eery lmethacry late.
- a second essential component of the compositions of the first aspect of the present invention is a pyrrolidone-based complexing agent.
- the most preferred pyrrolidone-based complexing agent herein is a polyvinylpyrrolidone complexing agent.
- PVP is commercially available under the trade name Luviskol (RTM) from BASF.
- RTM Luviskol
- a preferred PVP complexing agent herein is Luviskol K17 which has a viscosity-average molecular weight of about 9,000.
- Other pyrrolidone-based complexing agents for use herein include C ⁇ - Cig alkyl or hydroxy alkyl pyrrolidones such as lauryl pyrrolidone.
- composition of the present invention can be in emulsion (w/o or o/w), gel or lotion form but is preferably in the form of a water-in-oil emulsion, wherein in preferred embodiments the oil phase comprises a mixture of volatile silicones and non-volatile silicones.
- the silicone oil is present in an amount of from about 1 % to about 50% by weight.
- Suitable volatile silicone oils include cyclic and linear volatile polyorganosiloxanes (as used herein, "volatile” refers to those materials which have a measurable vapour pressure at ambient conditions). A description of various volatile silicones is found in Todd, et al.. "Volatile Silicone Fluids for Cosmetics” , 91 Cosmetics and Toiletries 27-32 (1976).
- Suitable non-volatile silicones preferably have an average viscosity of from about 1 ,000 to about 2,000,000 mm 2 ⁇ " 1 at 25°C. more preferably from about 10,000 to about 1 ,800,000 mm ⁇ .s-l , even more preferably from about 100,000 to about 1 ,500,000 mm 2 . ⁇ 1 .
- Lower viscosity non-volatile silicone conditioning agents can also be used. Viscosity can be measured by means of a glass capillary viscometer as set forth in Dow Corning Corporate Test Method CTM0004, July 20, 1970.
- the poly ether siloxane copolymer that may be used includes, for example, a polypropylene oxide modified dimethylpolysiloxane (e.g., Dow Corning DC-1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used.
- a polypropylene oxide modified dimethylpolysiloxane e.g., Dow Corning DC-1248
- ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used.
- Suitable humectants are selected from glycerine and polyglycerylmethacrylate lubricant having a viscosity at 25°C of 300,000 to 1 , 100,000 cps; a specific gravity at 25°C of 1 to 1.2g/ml, a pH of 5.0 to 5.5; a bound water content of 33 to 58% ; and, a free water content from 5 to 20% .
- Polyglycerylmethacrylate lubricants having the desired properties are marketed by Guardian Chemical Corporation under the trademark "Lubrajel".
- the "Lubrajels” identified as “Lubrajel DV” , “Lubrajel MS” , and “Lubrajel CG” are preferred in the present invention.
- the gelling agents sold under these trademarks contain about 1 % propylene glycol.
- Other suitable humectants include sorbitol, panthenols, propylene glycol, butylene glycol, hexylene glycol, alkoxylated glucose derivatives, such as Glucam (RTM) E-20, hexanetriol, and glucose ethers, and mixtures thereof.
- Urea is also suitably added as a humectant in the internal aqueous phase.
- the balance of the composition of the present invention is deionized water.
- the composition preferably comprises from about 30% to about 95 % , more preferably from about 40% to about 80% by weight of the oil phase, and from about 5% to about 70%, more preferably from about 20% to about 60% by weight of the water phase.
- the make-up compositions of the present invention can also comprise a paniculate cross-linked hydrophobic acrylate or methacrylate copolymer. This copolymer is particularly valuable for reducing shine and controlling oil while helping to provide effective moisturization benefits.
- the cross-linked hydrophobic polymer is preferably in the form of a copolymer lattice with at least one active ingredient dispersed uniformly throughout and entrapped within the copolymer lattice.
- the hydrophobic polymer can take the form of a porous particle having a surface area (N2-BET) in the range from about 50 to 500, preferably 100 to 300m2/g and having the active ingredient absorbed therein.
- Preferred emollients are selected from hydrocarbons such as isohexadecane, mineral oils, petrolatum and squalane, lanolin alcohol, and stearyl alcohol. These emollients may be used independently or in mixtures and may be present in the composition of the present invention in an amount from about 1 % to about 30% by weight, and preferably are present in an amount from about 5% to about 15 % by weight of the total composition.
- the mixture of components of phase A is stirred for approximately 5 minutes with sheer mixing until homogeneous.
- the materials of phase B are added gradually to A and the batch is mixed for 20 minutes until dispersed.
- phase C and then phase D are slowly added to the mixture of phases A and B with high shear mixing until dispersed. Silica is added at this point and dispersed through the mixture.
- the resulting batch heated to 90 °C before the addition of the components of phase E.
- the vessel is cooled to 55 °C and the premixed phase F is added.
- the batch is mixed until homogeneous.
- the mixture is cooled to 30 °C and phase G is added.
- a premix of phase H is made by mixing all the components until completely dissolved. At 30°C the premix of phase H is added to the batch mixture with high shear, ensuring that there is no excess water on the surface. The mixture is then milled for 15 minutes.
- the resulting make-up composition is ready for packaging.
- the make-up compositions of the Examples exhibit anti-acne activity and improved formulation and colour stability.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU75206/94A AU673623B2 (en) | 1993-08-06 | 1994-08-05 | Cosmetic compositions |
EP94925189A EP0717627A4 (en) | 1993-08-06 | 1994-08-05 | Cosmetic compositions |
JP7506527A JPH09501176A (en) | 1993-08-06 | 1994-08-05 | Cosmetic composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB939316323A GB9316323D0 (en) | 1993-08-06 | 1993-08-06 | Cosmetic compositions |
GB9316323.6 | 1993-08-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995004537A1 true WO1995004537A1 (en) | 1995-02-16 |
Family
ID=10740067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/008838 WO1995004537A1 (en) | 1993-08-06 | 1994-08-05 | Cosmetic compositions |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0717627A4 (en) |
JP (1) | JPH09501176A (en) |
CN (1) | CN1130875A (en) |
AU (1) | AU673623B2 (en) |
CA (1) | CA2168425A1 (en) |
CZ (1) | CZ34796A3 (en) |
GB (1) | GB9316323D0 (en) |
TW (1) | TW401306B (en) |
WO (1) | WO1995004537A1 (en) |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0676194A2 (en) † | 1994-04-01 | 1995-10-11 | Roussel Uclaf | Cosmetic or dermatological compositions comprising an alpha-hydroxy acid, salicylic acid and a retinoid |
GB2292080A (en) * | 1994-08-09 | 1996-02-14 | Revlon Consumer Prod Corp | Cosmetic formulations having keratolytic and/or anti-acne activity their preparation and use |
WO1996005806A1 (en) * | 1994-08-19 | 1996-02-29 | Schering-Plough Healthcare Products, Inc. | Compositions for treating corns and calluses |
GB2299023A (en) * | 1995-03-18 | 1996-09-25 | Procter & Gamble | An anti-acne cosmetic composition |
GB2299022A (en) * | 1995-03-18 | 1996-09-25 | Procter & Gamble | Anti-acne cosmetic composition |
WO1996039119A1 (en) * | 1995-06-06 | 1996-12-12 | Neutrogena Corporation | Topical vehicles containing solubilized and stabilized azelaic acid |
EP0767658A1 (en) * | 1994-08-09 | 1997-04-16 | The Procter & Gamble Company | Anti-acne cosmetic compositions |
WO1999025332A1 (en) * | 1997-11-19 | 1999-05-27 | Schering Aktiengesellschaft | Composition with azelaic acid |
WO1999058104A1 (en) * | 1998-05-12 | 1999-11-18 | Interhealth Ab | Therapeutic compositions |
JP2002503211A (en) * | 1996-06-27 | 2002-01-29 | ザ、プロクター、エンド、ギャンブル、カンパニー | Cosmetic composition |
WO2002028361A2 (en) * | 2000-09-29 | 2002-04-11 | Johnson & Johnson Consumer Companies, Inc. | Compositions for cleansing skin and treating acne |
US6372791B1 (en) | 2000-06-29 | 2002-04-16 | Johnson & Johnson Consumer Companies, Inc. | Method of promoting skin cell metabolism |
US6432424B1 (en) | 2000-06-29 | 2002-08-13 | Johnson & Johnson Consumer Companies, Inc. | Cosmetic compositions containing creatine, carnitine, and/or pyruvic acid |
WO2003026596A1 (en) * | 2001-09-26 | 2003-04-03 | The Procter & Gamble Company | Topical compositions containing solid particulates and a silicone resin copolymer fluid |
US6630175B1 (en) | 2000-06-29 | 2003-10-07 | Johnson & Johnson Consumer Companies, Inc. | Method of reducing eye irritation |
US6649176B1 (en) | 2000-06-29 | 2003-11-18 | Johnson & Johnson Consumer Companies, Inc. | Compositions containing mineral water |
US6858202B2 (en) * | 1999-05-27 | 2005-02-22 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
WO2005025548A1 (en) * | 2003-09-10 | 2005-03-24 | Dow Corning Corporation | Topical preparations comprising a hydrophilic carrier and a silicone matrix |
US6887859B2 (en) | 2001-09-26 | 2005-05-03 | The Procter & Gamble Company | Topical compositions containing fluid-absorbent solids and adhesive fluids |
DE102004004969A1 (en) * | 2004-01-28 | 2005-08-18 | Beiersdorf Ag | UV-light-protective filters are used in reducing microcomedones or (optionally together with hydroxy-acids) in increasing the therapeutic effectiveness in acne treatment |
US7122174B2 (en) | 2002-09-30 | 2006-10-17 | L'oreal S.A. | Compositions comprising at least one silicone compound and at least one amine compound, and methods for using the same |
US9125919B2 (en) | 2008-12-17 | 2015-09-08 | Ei Llc | Acne treatment powder foundation |
US11357714B2 (en) | 2020-07-21 | 2022-06-14 | Chembeau LLC | Diester cosmetic formulations and uses thereof |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9316322D0 (en) * | 1993-08-06 | 1993-09-22 | Procter & Gamble | Cosmetic compositions |
JP3487390B2 (en) * | 1995-06-01 | 2004-01-19 | 株式会社資生堂 | Emulsion powder cosmetic |
JPH10324615A (en) * | 1997-05-21 | 1998-12-08 | Pola Chem Ind Inc | Discrimination of cosmetic for pollinosis |
US6200964B1 (en) * | 1999-05-28 | 2001-03-13 | Neutrogena Corporation | Silicone gel containing salicylic acid |
CZ303482B6 (en) * | 2011-11-29 | 2012-10-10 | Neofyt Spol. S R.O. | Composition for removing warts and coarse skin |
CN108553411B (en) | 2018-07-25 | 2020-05-12 | 成都卓阳生物科技有限公司 | Azelaic acid gel and preparation method and application thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4826681A (en) * | 1985-02-26 | 1989-05-02 | L'oreal | Anhydrous solution of hydrogen peroxide in an organic solvent and the use of the same in therapeutic and cosmetic formulations |
US5145685A (en) * | 1991-04-08 | 1992-09-08 | Dow Corning Corporation | Skin treatment method and composition |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US4147782A (en) * | 1976-06-24 | 1979-04-03 | William H. Rorer, Inc. | Pharmaceutical detergent composition |
FR2479819A1 (en) * | 1980-04-04 | 1981-10-09 | Fabre Sa Pierre | ZINC RETINOATE, PREPARATION AND TOPICAL COMPOSITIONS CONTAINING THE SAME |
KR890001556A (en) * | 1987-07-01 | 1989-03-27 | 권선주 | Pharmaceutical composition |
US4906305A (en) * | 1988-08-18 | 1990-03-06 | Allegheny Ludlum Corporation | Method of making a composite drawn article |
-
1993
- 1993-08-06 GB GB939316323A patent/GB9316323D0/en active Pending
-
1994
- 1994-08-05 WO PCT/US1994/008838 patent/WO1995004537A1/en not_active Application Discontinuation
- 1994-08-05 CN CN 94193324 patent/CN1130875A/en active Pending
- 1994-08-05 JP JP7506527A patent/JPH09501176A/en active Pending
- 1994-08-05 CA CA 2168425 patent/CA2168425A1/en not_active Abandoned
- 1994-08-05 AU AU75206/94A patent/AU673623B2/en not_active Ceased
- 1994-08-05 CZ CZ96347A patent/CZ34796A3/en unknown
- 1994-08-05 EP EP94925189A patent/EP0717627A4/en not_active Withdrawn
- 1994-10-22 TW TW83109792A patent/TW401306B/en active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4826681A (en) * | 1985-02-26 | 1989-05-02 | L'oreal | Anhydrous solution of hydrogen peroxide in an organic solvent and the use of the same in therapeutic and cosmetic formulations |
US5145685A (en) * | 1991-04-08 | 1992-09-08 | Dow Corning Corporation | Skin treatment method and composition |
Non-Patent Citations (1)
Title |
---|
See also references of EP0717627A4 * |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0676194B2 (en) † | 1994-04-01 | 2015-01-07 | Beiersdorf AG | Cosmetic or dermatological compositions comprising an alpha-hydroxy acid, salicylic acid and a retinoid |
EP0676194A2 (en) † | 1994-04-01 | 1995-10-11 | Roussel Uclaf | Cosmetic or dermatological compositions comprising an alpha-hydroxy acid, salicylic acid and a retinoid |
GB2292080B (en) * | 1994-08-09 | 1998-11-25 | Revlon Consumer Prod Corp | Cosmetic formulations having keratolytic and/or anti-acne activity,their preparations and use |
GB2292080A (en) * | 1994-08-09 | 1996-02-14 | Revlon Consumer Prod Corp | Cosmetic formulations having keratolytic and/or anti-acne activity their preparation and use |
EP0767658A4 (en) * | 1994-08-09 | 2001-06-20 | Procter & Gamble | Anti-acne cosmetic compositions |
EP0767658A1 (en) * | 1994-08-09 | 1997-04-16 | The Procter & Gamble Company | Anti-acne cosmetic compositions |
WO1996005806A1 (en) * | 1994-08-19 | 1996-02-29 | Schering-Plough Healthcare Products, Inc. | Compositions for treating corns and calluses |
GB2299023A (en) * | 1995-03-18 | 1996-09-25 | Procter & Gamble | An anti-acne cosmetic composition |
GB2299022B (en) * | 1995-03-18 | 1999-03-31 | Procter & Gamble | Cosmetic compositions |
GB2299023B (en) * | 1995-03-18 | 1999-03-31 | Procter & Gamble | Cosmetic compositions |
GB2299022A (en) * | 1995-03-18 | 1996-09-25 | Procter & Gamble | Anti-acne cosmetic composition |
WO1996039119A1 (en) * | 1995-06-06 | 1996-12-12 | Neutrogena Corporation | Topical vehicles containing solubilized and stabilized azelaic acid |
JP2002503211A (en) * | 1996-06-27 | 2002-01-29 | ザ、プロクター、エンド、ギャンブル、カンパニー | Cosmetic composition |
WO1999025332A1 (en) * | 1997-11-19 | 1999-05-27 | Schering Aktiengesellschaft | Composition with azelaic acid |
CZ299116B6 (en) * | 1997-11-19 | 2008-04-30 | Intendis Gmbh | Composition containing azelaic acid |
KR100534511B1 (en) * | 1997-11-19 | 2005-12-08 | 쉐링 악티엔게젤샤프트 | Composition with Azelaic Acid |
US6534070B1 (en) | 1997-11-19 | 2003-03-18 | Schering Aktiengesellschaft | Composition with azelaic acid |
WO1999058104A1 (en) * | 1998-05-12 | 1999-11-18 | Interhealth Ab | Therapeutic compositions |
US6406708B1 (en) | 1998-05-12 | 2002-06-18 | Interhealth Ab | Therapeutic compositions |
US6858202B2 (en) * | 1999-05-27 | 2005-02-22 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
US6908889B2 (en) | 1999-05-27 | 2005-06-21 | Johnson & Johnson Consumer Companies, Inc. | Detergent composition with enhanced depositing, conditioning and softness capabilities |
US6432424B1 (en) | 2000-06-29 | 2002-08-13 | Johnson & Johnson Consumer Companies, Inc. | Cosmetic compositions containing creatine, carnitine, and/or pyruvic acid |
US6649176B1 (en) | 2000-06-29 | 2003-11-18 | Johnson & Johnson Consumer Companies, Inc. | Compositions containing mineral water |
US6630175B1 (en) | 2000-06-29 | 2003-10-07 | Johnson & Johnson Consumer Companies, Inc. | Method of reducing eye irritation |
US6372791B1 (en) | 2000-06-29 | 2002-04-16 | Johnson & Johnson Consumer Companies, Inc. | Method of promoting skin cell metabolism |
WO2002028361A2 (en) * | 2000-09-29 | 2002-04-11 | Johnson & Johnson Consumer Companies, Inc. | Compositions for cleansing skin and treating acne |
WO2002028361A3 (en) * | 2000-09-29 | 2002-07-04 | Johnson & Johnson Consumer | Compositions for cleansing skin and treating acne |
US6887859B2 (en) | 2001-09-26 | 2005-05-03 | The Procter & Gamble Company | Topical compositions containing fluid-absorbent solids and adhesive fluids |
WO2003026596A1 (en) * | 2001-09-26 | 2003-04-03 | The Procter & Gamble Company | Topical compositions containing solid particulates and a silicone resin copolymer fluid |
US7223386B2 (en) | 2002-03-11 | 2007-05-29 | Dow Corning Corporation | Preparations for topical skin use and treatment |
US7122174B2 (en) | 2002-09-30 | 2006-10-17 | L'oreal S.A. | Compositions comprising at least one silicone compound and at least one amine compound, and methods for using the same |
KR101121461B1 (en) * | 2003-09-10 | 2012-03-16 | 다니스코 유에스 인크. | Topical preparations comprising a hydrophilic carrier and a silicone matrix |
WO2005025548A1 (en) * | 2003-09-10 | 2005-03-24 | Dow Corning Corporation | Topical preparations comprising a hydrophilic carrier and a silicone matrix |
DE102004004969A1 (en) * | 2004-01-28 | 2005-08-18 | Beiersdorf Ag | UV-light-protective filters are used in reducing microcomedones or (optionally together with hydroxy-acids) in increasing the therapeutic effectiveness in acne treatment |
US9125919B2 (en) | 2008-12-17 | 2015-09-08 | Ei Llc | Acne treatment powder foundation |
US11357714B2 (en) | 2020-07-21 | 2022-06-14 | Chembeau LLC | Diester cosmetic formulations and uses thereof |
US11491092B2 (en) | 2020-07-21 | 2022-11-08 | Chembeau LLC | Hair treatment formulations and uses thereof |
US11801211B2 (en) | 2020-07-21 | 2023-10-31 | Chembeau LLC | Hair treatment formulations and uses thereof |
Also Published As
Publication number | Publication date |
---|---|
CA2168425A1 (en) | 1995-02-16 |
AU7520694A (en) | 1995-02-28 |
TW401306B (en) | 2000-08-11 |
CZ34796A3 (en) | 1996-07-17 |
JPH09501176A (en) | 1997-02-04 |
CN1130875A (en) | 1996-09-11 |
EP0717627A4 (en) | 1997-09-10 |
GB9316323D0 (en) | 1993-09-22 |
AU673623B2 (en) | 1996-11-14 |
EP0717627A1 (en) | 1996-06-26 |
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