WO1994029121A1 - Variable data clear mark imagin - Google Patents
Variable data clear mark imagin Download PDFInfo
- Publication number
- WO1994029121A1 WO1994029121A1 PCT/US1994/006342 US9406342W WO9429121A1 WO 1994029121 A1 WO1994029121 A1 WO 1994029121A1 US 9406342 W US9406342 W US 9406342W WO 9429121 A1 WO9429121 A1 WO 9429121A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- toner
- indicia
- paper
- recited
- substrate
- Prior art date
Links
- 239000000758 substrate Substances 0.000 claims abstract description 50
- 238000003384 imaging method Methods 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- 239000003550 marker Substances 0.000 claims abstract description 11
- 239000012628 flowing agent Substances 0.000 claims abstract description 9
- 229920001225 polyester resin Polymers 0.000 claims abstract description 9
- 239000004645 polyester resin Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000012141 concentrate Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003801 milling Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 31
- 239000002245 particle Substances 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 12
- 239000000976 ink Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000010902 jet-milling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- KVWDHTXUZHCGIO-UHFFFAOYSA-N olanzapine Chemical compound C1CN(C)CCN1C1=NC2=CC=CC=C2NC2=C1C=C(C)S2 KVWDHTXUZHCGIO-UHFFFAOYSA-N 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F3/00—Board games; Raffle games
- A63F3/06—Lottos or bingo games; Systems, apparatus or devices for checking such games
- A63F3/065—Tickets or accessories for use therewith
- A63F3/0685—Tickets or accessories for use therewith having a message becoming legible after a chemical reaction or physical action has taken place, e.g. applying pressure, heat treatment, spraying with a substance, breaking microcapsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S283/00—Printed matter
- Y10S283/901—Concealed data
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
Definitions
- a method and product are provided in which essentially invisible indicia or spots are easily applied, utilizing conventional equipment, to a paper substrate.
- a simple conventional highlighting marker, or the like one can easily test the document for authenticity, or otherwise utilize the document, by making the hidden indicia clearly visible.
- the invention utilizes very simple components, conventional equipment, and simple techniques, it can produce a security document such as a ticket, bank check, stock certificate, coupon, or the like, at almost no increase in cost compared to a non-protected document.
- the basic aspect of the present invention is the utilization of a clear toner which can be electrostatically imaged onto a piece of paper, as by using a dual roller fluidized electrostatic bed applicator.
- the toner which is simple to construct, is initially applied to the paper, in its virgin form, as a snow white deposit, which has a clear contrast with the surface of the paper (even if itself white) .
- the toner is heated to fuse it, as by a conventional infra-red heat fuser, it melts into the fibers of the paper and turns clear so that it is essentially invisible to the naked eye when illuminated by any wavelength of light (unless a particular dye is added to it to intentionally make it visible when illuminated by infra-red or UV light).
- the applied toner is hydrophobic, so that when a water base low concentrate ink, such as in a colored felt tip marker, or the like, is applied to the paper substrate at the area of the imaged toner, the toner itself repels the marker, but the surrounding paper readily absorbs it, so that the toner is clearly visible as a "negative" image.
- a water base low concentrate ink such as in a colored felt tip marker, or the like
- the person checking the ski lift ticket need only use a conventional marker, and know where to mark the presented ticket to render visible the security indicia.
- the clear security indicia cannot be reproduced successfully even by a modern color copier.
- a method of providing and using security indicia on a paper substrate utilizing a substantially clear hydrophobic toner comprises the following steps: (a) Charging and applying the toner in the form of security indicia to the paper substrate. (b) Heat fusing the toner so that it blends into the paper and becomes substantially invisible to the naked eye and color copiers regardless of the wavelength of light directed onto it.
- Step (c) when it is desired to view the indicia, applying an aqueous based solvent system having a distinctly different color than the paper substrate to the paper substrate over the toner, the paper surrounding the toner indicia absorbing the solvent while the toner indicia does not, making the toner indicia visible.
- Step (a) is practiced by imaging the toner onto the paper electrostatically, e.g. using ionographic, laser, and ion deposition imaging techniques, and step (b) is typically practiced by infra-red heat fusing.
- Step (a) is further practiced by using a polyester resin based toner which has been milled and classified so that the particle size is very uniform, and mixed with a silica flowing agent.
- the toner may be variably imaged on the paper, and also visible indicia corresponding to the invisible indicia may also be variably imaged onto the paper. Alternatively, it can be overprinted, or overcoated, for example by applying foil over it. If it is desirable to make the indicia visible in certain light wavelengths, a UV responsive dye or an infra-red absorbing dye may be added to the toner.
- the invention also contemplates a security document made by the method described above.
- a security document comprising: A substantially paper substrate; and indicia imaged on the substrate comprising a hydrophobic toner blended into the paper substrate so that it is substantially invisible to the naked eye and color copiers when illuminated with ambient light.
- the invention also comprises another type of security document, particularly useful in making lotto tickets or the like which has a different receptivity to overprinted inks and coatings for rub off or image permanence considerations.
- the security document according to this aspect of the invention comprises: A paper substrate. A spot of hydrophobic toner imaged onto and blended into the paper substrate so that it is substantially invisible to the naked eye and color copiers when illuminated with ambient light. And, an overcovering or overprinting on the spot.
- the invention also contemplates a method of treating a substrate comprising the following steps: (a) Producing a clear toner by milling a polyester resin to an average particle size of about 15 microns, and classifying the resin to reduce particles of less than about 5 microns to under about 10% of the total distribution of particles, and blending the milled and classified particles with a silica flowing agent, and intimately mixing them together. (b) Electrostatically imaging the toner onto a paper substrate. And, (c) heat fusing the toner, so that it blends into the paper substrate and becomes substantially invisible to the naked eye and color copiers when illuminated with ambient light. Step (b) is typically practiced by imaging the toner on the surface as human or machine readable indicia, and there is typically the further step of imaging visible toner on the substrate corresponding to the invisible toner imaged thereon by the practice of step (b).
- FIGURE 1 is a schematic box diagram illustrating exemplary method steps according to the method of the present invention
- FIGURES 2 through 4 are perspective views of exemplary security documents according to the present invention.
- FIGURE 5 is a greatly enlarged perspective illustration of a security document according to the present invention showing a conventional highlighting marker being moved over the security indicia printed thereon to render the indicia visible.
- FIGURE 1 Exemplary method for making and using a security document, or like document with invisible indicia or areas that are easily rendered visible, is schematically illustrated in FIGURE 1.
- a polyester resin is acted upon in stage 11 by milling it (e.g. jet-milling it) to a predetermined average particle size, and after that it is passed to the classifying stage 12 where it is classified to reduce the number of particles below a certain size.
- a flowing agent is added to it, and the flowing agent and resin are intimately mixed at stage 14 to produce a toner.
- the toner produced thereby will be clear when illuminated by all wavelengths of light after heat fusing, but if it is desirable to render it visible when illuminated by certain wavelengths of light, a conventional infra-red absorbing dye, or a conventional UV responsive dye, may be added as indicated by dotted line 15 in FIGURE 1. If an infra-red absorbing dye is added then indicia printed with the toner is visible when illuminated with infra-red light, and if a UV responsive dye is added, indicia printed with the toner fluoresces when illuminated with UV light.
- a polyester resin (such as ATLAC 382 E by Reichold) was jet milled to an average particle size of about 15 microns, and then classified to reduce particles of less than about 5 microns to under about 10% of the total distribution.
- the resin powder produced was post-blended with about 0.75% by weight of a treated fumed silica flowing agent, such as Cabot TS-530 or its equivalent, and mixed in a high speed blender such as a Henschell or Omni.
- the toner so produced was readily available for use in a conventional Midax 300 ionographic print engine and could be imaged onto a paper substrate in a snow white form, and then became clear after heat fusing.
- the toner After the toner is produced in stage 14, it is electrostatically imaged onto a substrate as indicated schematically at 16 in FIGURE 1.
- Any of a wide variety of electrostatic imaging techniques and equipment can be utilized.
- ionographic, laser, and ion deposition imaging techniques are useful, as well as their corresponding print engines, such as a Midax 300 ionographic print engine for ionographic techniques.
- the toner When utilizing an ionographic print engine, the toner is applied with a dual roller fluidized electrostatic bed applicator such as shown in co-pending application serial no. 07/639,360 filed January 8, 1991 (atty. dkt. 263-511; 90-42) , the disclosure of which is hereby incorporated by reference herein.
- the paper may also be variably imaged with visible indicia (using a visible toner) , as indicated schematically at 17.
- visible indicia using a visible toner
- the toner is acted upon by heat to melt it into the paper, rendering it clear.
- the toner is snow white, but when infra-red heated, the subsequent melting and fusing of the toner causes it to become substantially invisible to the naked eye, and to all presently commercial color copies, including those of Canon (e.g. the Canon laser copier) and Xerox.
- the heating/fusing step is illustrated by box 18 in FIGURE 1.
- the toner can be overprint or overcoated.
- the toner may be overprinted with visible indicia illustrated schematically by stage 19 in FIGURE 1. This is particularly useful for lottery and game type applications where the spot would be of a different receptivity to overprinting inks and coatings for rub off or image performance considerations.
- visible indicia can be overprinted on the clear toner indicia.
- stage 20 is practiced.
- an aqueous based colored solvent system is applied to the toner.
- the colored solvent is readily absorbed by the surrounding paper, but is repelled by the hydrophobic invisible toner applied in stage 16, thereby rendering it readily visible to the naked eye in a "negative" image form.
- solvent systems may be utilized, but preferably are water based low concentrate ink aqueous base solvent systems such as are provided in conventional highlighting marks.
- Examples of numerous commercially available highlighting markers which have been tested as functional and suitable for this purpose are purple and blue "Pilot Spotlighter” markers, fluorescent green “Magic Marker Brand” markers, fluorescent yellow and blue “BIC Brightliner” markers, black and blue “BIC Ultrafine Marking Pen” markers, and red and black “Papermate Flair Pen” markers.
- FIGURE 2 An exemplary security document produced utilizing the basic method illustrated in FIGURE 1 is shown schematically at 23 in FIGURE 2.
- the security document includes a paper substrate 24, with various visible indicia thereon such as the "Pay to" indicia 25 and the dollar amount indicia 26, imaged onto the substrate 24 with conventional visible toner.
- visible alpha numeric indicia 27 is provided, and the invisible indicia according to the invention -- shown schematically in dotted line at 28 in FIGURE 2 (it is shown in dotted line because it is impossible to illustrate it otherwise since it is invisible) — corresponding to the indicia 27 is provided.
- the security document 23 which typically is a bank check or money order — in order to test its authenticity, all one need do is to rub a magic marker of a distinctly different color than the paper substrate 24 (e.g. non-white, and preferably also non-yellow) over the left bottom area of the paper substrate 24 which will render the indicia 28 visible. If the then visible indicia 28 is not present, then the document is a fraud, or if for some reason it illustrates different indicia than the indicia 27, it is fraudulent.
- a magic marker of a distinctly different color than the paper substrate 24 e.g. non-white, and preferably also non-yellow
- FIGURE 3 schematically illustrates another security document 30 according to the invention, this time in the form of a lotto or gaming ticket.
- a paper substrate 31 e.g. substantially white paper
- Indicia 34 may be overprinted on the spot 33, and the spot 33 can also be applied over preexisting visible indicia on the substrate 31, so that the spot 33 may comprise a rub off spot, or provide for different printing receptivity of the indicia 34, or the like.
- FIGURE 4 illustrates another exemplary security document 37 according to the invention, this time in the form, schematically, of a stock certificate.
- a paper substrate 38 has conventional visible indicia 39 printed thereon, as well as overprinting 40 over the invisible alpha numeric indicia 41 that has been applied according to the invention.
- FIGURE 5 schematically illustrates how the invisible indicia according to the invention is rendered visible, in this particular case schematically illustrated with respect to a ski lift or other admission ticket comprising a white paper substrate 44 that has the invisible indicia 46 imaged thereon (e.g. letter saying "THIS IS A VALID TICKET").
- the colored area 47 which renders the previously invisible toner indicia 46 visible is a water based low concentrate ink (e.g. blue as shown in FIGURE 5) which has been applied by the nib 48 of a conventional highlighting marker 49, such as "BIC Brightliner" marker.
- the indicia 46 is clearly visible as a negative image.
Landscapes
- Finance (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Multimedia (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Chemical & Material Sciences (AREA)
- Printing Methods (AREA)
- Developing Agents For Electrophotography (AREA)
- Cleaning In Electrography (AREA)
- Credit Cards Or The Like (AREA)
- Inspection Of Paper Currency And Valuable Securities (AREA)
- Slot Machines And Peripheral Devices (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94919375A EP0658146B1 (en) | 1993-06-10 | 1994-06-06 | Variable data clear mark imagin |
AU70542/94A AU676344B2 (en) | 1993-06-10 | 1994-06-06 | Variable data clear mark imagin |
BR9405398-7A BR9405398A (en) | 1993-06-10 | 1994-06-06 | Formation of images with clear variable data mark |
CA002140886A CA2140886C (en) | 1993-06-10 | 1994-06-06 | Variable data clear mark imaging |
DE69413362T DE69413362T2 (en) | 1993-06-10 | 1994-06-06 | METHOD FOR PRODUCING AN INVISIBLE MARKING CHARACTER |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/074,670 US5368334A (en) | 1993-06-10 | 1993-06-10 | Variable data clear mark imaging |
US074,670 | 1993-06-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994029121A1 true WO1994029121A1 (en) | 1994-12-22 |
Family
ID=22120946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/006342 WO1994029121A1 (en) | 1993-06-10 | 1994-06-06 | Variable data clear mark imagin |
Country Status (9)
Country | Link |
---|---|
US (1) | US5368334A (en) |
EP (1) | EP0658146B1 (en) |
JP (1) | JP2719236B2 (en) |
CN (1) | CN1041070C (en) |
AU (1) | AU676344B2 (en) |
BR (1) | BR9405398A (en) |
CA (1) | CA2140886C (en) |
DE (1) | DE69413362T2 (en) |
WO (1) | WO1994029121A1 (en) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8500720A (en) * | 1984-05-22 | 1985-07-01 | Highland Supply Corp | SYSTEM FOR FORMING ARTICLES. |
US5718456A (en) * | 1994-01-26 | 1998-02-17 | Michael F. Detwiler, Jr. | Method for verifying authenticity of sales record |
BR9601506A (en) * | 1995-08-01 | 1998-03-17 | Brugada Jorge Clemen Bernardes | Security support printed with micro-pattern preventing document forgery when using high-precision copiers |
US5991055A (en) * | 1996-09-23 | 1999-11-23 | Hewlett-Packard Company | Underpulsed scanner with variable scan speed, P. W. M. color balance, scan modes and column reversal |
US6106110A (en) * | 1996-10-09 | 2000-08-22 | Nocopi Technologies, Inc. | Secure thermal ink jet printing composition and substrate and method and apparatus utilizing same |
US6770687B1 (en) | 1996-11-21 | 2004-08-03 | Ncr Corporation | Water-based dual security ink |
US5883043A (en) * | 1997-08-27 | 1999-03-16 | Ncr Corporation | Thermal paper with security features |
US5794981A (en) * | 1997-02-19 | 1998-08-18 | Lps Industries Inc. | Packaging system for protection against theft by overlabeling |
JP2001511728A (en) | 1997-03-03 | 2001-08-14 | テムテック インク | Substrate having hidden image and method of expressing hidden image |
US6409592B1 (en) | 1997-10-20 | 2002-06-25 | Moore North America | White ink security feature for mailer type business forms |
IL130585A0 (en) * | 1999-06-21 | 2000-06-01 | Curie Authentication Technolog | Marked difficult-to-counterfeit documents |
CA2334193A1 (en) | 2000-03-23 | 2001-09-23 | Eastman Kodak Company | A method for printing and verifying limited edition stamps |
US6783991B1 (en) | 2002-02-06 | 2004-08-31 | The Standard Register Company | Reversible and reusable authentication system for secure documents |
US8805745B1 (en) * | 2004-07-27 | 2014-08-12 | Stamps.Com Inc. | Printing of computer-based value-bearing items |
ES2606489T5 (en) * | 2004-09-15 | 2022-03-02 | Crane & Co Inc | Security device and new anti-counterfeiting product employing the same |
JP2006098423A (en) * | 2004-09-28 | 2006-04-13 | Osaka Sealing Printing Co Ltd | Label |
US20060230273A1 (en) * | 2005-04-08 | 2006-10-12 | Eastman Kodak Company | Hidden MIRC printing for security |
US7748748B2 (en) * | 2005-04-12 | 2010-07-06 | International Business Machines Corporation | Method and system for generating and authenticating documents having stored electrostatic pattern information |
US8285651B1 (en) | 2005-12-30 | 2012-10-09 | Stamps.Com Inc. | High speed printing |
US8101326B2 (en) | 2006-05-19 | 2012-01-24 | Eastman Kodak Company | Secure document printing method and system |
US10839332B1 (en) | 2006-06-26 | 2020-11-17 | Stamps.Com | Image-customized labels adapted for bearing computer-based, generic, value-bearing items, and systems and methods for providing image-customized labels |
JP5558722B2 (en) * | 2009-01-16 | 2014-07-23 | 大日本印刷株式会社 | Printed materials and containers |
US8211490B2 (en) * | 2009-03-17 | 2012-07-03 | Xerox Corporation | Double layer UV variable data text |
RU2500542C2 (en) * | 2009-07-31 | 2013-12-10 | Нэшнл Принтинг Бюро, Инкорпорейтед Эдминистрейтив Эдженси | Object formed by concealed image stencils |
US11007795B2 (en) | 2014-04-07 | 2021-05-18 | Avery Dennison Retail Information Services, Llc | Heat transfer ticket |
CN108960674A (en) * | 2018-07-24 | 2018-12-07 | 广东海外建设监理有限公司 | The Supervision that process joins in project supervision |
Citations (13)
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---|---|---|---|---|
US1002600A (en) * | 1909-08-14 | 1911-09-05 | Edward Robert Morris | Means for detecting counterfeit bank-notes, bonds, coupons, and the like. |
GB1255445A (en) * | 1969-02-05 | 1971-12-01 | Fuji Photo Film Co Ltd | Process for developing electrostatic latent images and developer therefor |
US3989279A (en) * | 1975-06-04 | 1976-11-02 | Levy Leon M | Latent indicia carrier |
US4051283A (en) * | 1968-09-03 | 1977-09-27 | A. B. Dick Company | Printed sheets containing concealed images and method and materials for preparation and visual development of same |
EP0090130A1 (en) * | 1982-03-25 | 1983-10-05 | Billett-Automation Dipl.-Ing. Klaus Schwarz OHG | Process for checking the authenticity of security documents, and distributing device for carrying out the process |
US4465754A (en) * | 1981-10-27 | 1984-08-14 | Kuin Nicolaas P J | Water-fixable electrostatic toner powder containing hydrolyzed polyvinyl ester |
US4477593A (en) * | 1977-12-02 | 1984-10-16 | Lockley Services Pty. Ltd. | Sheet printed with invisible inks, developers and erasure compounds _for invisible inks |
GB2153107A (en) * | 1984-01-05 | 1985-08-14 | Harold E Clark | Photoreceptive sheet |
US4940690A (en) * | 1988-07-27 | 1990-07-10 | The Standard Register Company | Clean release laminate construction with latent image |
US4992347A (en) * | 1987-02-13 | 1991-02-12 | Courtaulds Plc | Marking |
US5058925A (en) * | 1989-12-13 | 1991-10-22 | The Standard Register Company | Leach resistant ink for protecting documents from alteration and document protected thereby |
US5139572A (en) * | 1989-06-20 | 1992-08-18 | Kiyoharu Kawashima | Reusable hidden indicia printed sheet |
US5286061A (en) * | 1992-10-09 | 1994-02-15 | Scientific Games, Inc. | Lottery ticket having validation data printed in developable invisible ink |
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PH24144A (en) * | 1987-06-03 | 1990-03-22 | Erba Carlo Spa | A method of treating nephropathies using n-imidazolyl derivatives of bicyclic compounds |
JPH01101558A (en) * | 1987-10-14 | 1989-04-19 | Hitachi Metals Ltd | Toner for developing electrostatic charge image |
JPH01126659A (en) * | 1987-11-11 | 1989-05-18 | Hitachi Metals Ltd | Two-component developer and image forming method using said developer |
JPH01142689A (en) * | 1987-11-30 | 1989-06-05 | Mita Ind Co Ltd | Method for reproducing confidential document |
US5786061A (en) * | 1991-05-03 | 1998-07-28 | Velcro Industries B.V. | Separable fastener having a perimeter cover gasket |
US5208630A (en) * | 1991-11-04 | 1993-05-04 | Xerox Corporation | Process for the authentication of documents utilizing encapsulated toners |
JPH111558A (en) * | 1997-04-18 | 1999-01-06 | Mitsui Chem Inc | Production of crosslinked polysuccinimide |
JP3241639B2 (en) * | 1997-06-30 | 2001-12-25 | 日本電気株式会社 | Multi-chip module cooling structure and method of manufacturing the same |
-
1993
- 1993-06-10 US US08/074,670 patent/US5368334A/en not_active Expired - Lifetime
-
1994
- 1994-06-06 JP JP7502015A patent/JP2719236B2/en not_active Expired - Lifetime
- 1994-06-06 AU AU70542/94A patent/AU676344B2/en not_active Ceased
- 1994-06-06 WO PCT/US1994/006342 patent/WO1994029121A1/en active IP Right Grant
- 1994-06-06 BR BR9405398-7A patent/BR9405398A/en not_active IP Right Cessation
- 1994-06-06 EP EP94919375A patent/EP0658146B1/en not_active Expired - Lifetime
- 1994-06-06 CN CN94190365A patent/CN1041070C/en not_active Expired - Fee Related
- 1994-06-06 DE DE69413362T patent/DE69413362T2/en not_active Expired - Fee Related
- 1994-06-06 CA CA002140886A patent/CA2140886C/en not_active Expired - Fee Related
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1002600A (en) * | 1909-08-14 | 1911-09-05 | Edward Robert Morris | Means for detecting counterfeit bank-notes, bonds, coupons, and the like. |
US4051283A (en) * | 1968-09-03 | 1977-09-27 | A. B. Dick Company | Printed sheets containing concealed images and method and materials for preparation and visual development of same |
GB1255445A (en) * | 1969-02-05 | 1971-12-01 | Fuji Photo Film Co Ltd | Process for developing electrostatic latent images and developer therefor |
US3989279A (en) * | 1975-06-04 | 1976-11-02 | Levy Leon M | Latent indicia carrier |
US4477593A (en) * | 1977-12-02 | 1984-10-16 | Lockley Services Pty. Ltd. | Sheet printed with invisible inks, developers and erasure compounds _for invisible inks |
US4465754A (en) * | 1981-10-27 | 1984-08-14 | Kuin Nicolaas P J | Water-fixable electrostatic toner powder containing hydrolyzed polyvinyl ester |
EP0090130A1 (en) * | 1982-03-25 | 1983-10-05 | Billett-Automation Dipl.-Ing. Klaus Schwarz OHG | Process for checking the authenticity of security documents, and distributing device for carrying out the process |
GB2153107A (en) * | 1984-01-05 | 1985-08-14 | Harold E Clark | Photoreceptive sheet |
US4992347A (en) * | 1987-02-13 | 1991-02-12 | Courtaulds Plc | Marking |
US4940690A (en) * | 1988-07-27 | 1990-07-10 | The Standard Register Company | Clean release laminate construction with latent image |
US5139572A (en) * | 1989-06-20 | 1992-08-18 | Kiyoharu Kawashima | Reusable hidden indicia printed sheet |
US5058925A (en) * | 1989-12-13 | 1991-10-22 | The Standard Register Company | Leach resistant ink for protecting documents from alteration and document protected thereby |
US5286061A (en) * | 1992-10-09 | 1994-02-15 | Scientific Games, Inc. | Lottery ticket having validation data printed in developable invisible ink |
Also Published As
Publication number | Publication date |
---|---|
EP0658146A4 (en) | 1995-08-09 |
AU676344B2 (en) | 1997-03-06 |
DE69413362T2 (en) | 1999-04-01 |
CA2140886A1 (en) | 1994-12-22 |
EP0658146B1 (en) | 1998-09-16 |
CN1041070C (en) | 1998-12-09 |
DE69413362D1 (en) | 1998-10-22 |
CA2140886C (en) | 2004-12-07 |
CN1110872A (en) | 1995-10-25 |
BR9405398A (en) | 1999-09-08 |
EP0658146A1 (en) | 1995-06-21 |
US5368334A (en) | 1994-11-29 |
AU7054294A (en) | 1995-01-03 |
JPH07508944A (en) | 1995-10-05 |
JP2719236B2 (en) | 1998-02-25 |
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